ISBN: 2198-7432

Текст
                    Proceedings

Alexander Heintzel Hrsg.

Heavy-Duty-,
On- und
Off-HighwayMotoren 2022
Stand der Energiewende im
Heavy-Duty-Bereich


Proceedings
Ein stetig steigender Fundus an Informationen ist heute notwendig, um die immer komplexer werdende Technik heutiger Kraftfahrzeuge zu verstehen. Funktionen, Arbeitsweise, Komponenten und Systeme entwickeln sich rasant. In immer schnelleren Zyklen verbreitet sich aktuelles Wissen gerade aus Konferenzen, Tagungen und Symposien in die Fachwelt. Den raschen Zugriff auf diese Informationen bietet diese Reihe Proceedings, die sich zur Aufgabe gestellt hat, das zum Verständnis topaktueller Technik rund um das Automobil erforderliche spezielle Wissen in der Systematik aus Konferenzen und Tagungen zusammen zu stellen und als Buch in Springer.com wie auch elektronisch in Springer Link und Springer Professional bereit zu stellen. Die Reihe wendet sich an Fahrzeug- und Motoreningenieure sowie Studierende, die aktuelles Fachwissen im Zusammenhang mit Fragestellungen ihres Arbeitsfeldes suchen. Professoren und Dozenten an Universitäten und Hochschulen mit Schwerpunkt Kraftfahrzeug- und Motorentechnik finden hier die Zusammenstellung von Veranstaltungen, die sie selber nicht besuchen konnten. Gutachtern, Forschern und Entwicklungsingenieuren in der Automobil- und Zulieferindustrie sowie Dienstleistern können die Proceedings wertvolle Antworten auf topaktuelle Fragen geben. Today, a steadily growing store of information is called for in order to understand the increasingly complex technologies used in modern automobiles. Functions, modes of operation, components and systems are rapidly evolving, while at the same time the latest expertise is disseminated directly from conferences, congresses and symposia to the professional world in ever-faster cycles. This series of proceedings offers rapid access to this information, gathering the specific knowledge needed to keep up with cutting-edge advances in automotive technologies, employing the same systematic approach used at conferences and congresses and presenting it in print (available at Springer.com) and electronic (at Springer Link and Springer Professional) formats. The series addresses the needs of automotive engineers, motor design engineers and students looking for the latest expertise in connection with key questions in their field, while professors and instructors working in the areas of automotive and motor design engineering will also find summaries of industry events they weren’t able to attend. The proceedings also offer valuable answers to the topical questions that concern assessors, researchers and developmental engineers in the automotive and supplier industry, as well as service providers.
Alexander Heintzel (Hrsg.) Heavy-Duty-, On- und Off-Highway-Motoren 2022 Stand der Energiewende im Heavy-Duty-Bereich
Hrsg. Alexander Heintzel Springer Fachmedien Wiesbaden Wiesbaden, Deutschland ISSN 2198-7432 ISSN 2198-7440 (electronic) Proceedings ISBN 978-3-658-41476-4 ISBN 978-3-658-41477-1 (eBook) https://doi.org/10.1007/978-3-658-41477-1 Die Deutsche Nationalbibliothek verzeichnet diese Publikation in der Deutschen Nationalbibliografie; detaillierte bibliografische Daten sind im Internet über https://portal.dnb.de abrufbar. © Der/die Herausgeber bzw. der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 Das Werk einschließlich aller seiner Teile ist urheberrechtlich geschützt. Jede Verwertung, die nicht ausdrücklich vom Urheberrechtsgesetz zugelassen ist, bedarf der vorherigen Zustimmung des Verlags. Das gilt insbesondere für Vervielfältigungen, Bearbeitungen, Übersetzungen, Mikroverfilmungen und die Einspeicherung und Verarbeitung in elektronischen Systemen. Die Wiedergabe von allgemein beschreibenden Bezeichnungen, Marken, Unternehmensnamen etc. in diesem Werk bedeutet nicht, dass diese frei durch jedermann benutzt werden dürfen. Die Berechtigung zur Benutzung unterliegt, auch ohne gesonderten Hinweis hierzu, den Regeln des Markenrechts. Die Rechte des jeweiligen Zeicheninhabers sind zu beachten. Der Verlag, die Autoren und die Herausgeber gehen davon aus, dass die Angaben und Informationen in diesem Werk zum Zeitpunkt der Veröffentlichung vollständig und korrekt sind. Weder der Verlag noch die Autoren oder die Herausgeber übernehmen, ausdrücklich oder implizit, Gewähr für den Inhalt des Werkes, etwaige Fehler oder Äußerungen. Der Verlag bleibt im Hinblick auf geografische Zuordnungen und Gebietsbezeichnungen in veröffentlichten Karten und Institutionsadressen neutral. Planung/Lektorat: Markus Braun Springer Vieweg ist ein Imprint der eingetragenen Gesellschaft Springer Fachmedien Wiesbaden GmbH und ist ein Teil von Springer Nature. Die Anschrift der Gesellschaft ist: Abraham-Lincoln-Str. 46, 65189 Wiesbaden, Germany
Foreword Welcome Sustainable climate protection can only be achieved if all the stops are pulled out for energy converters and carriers. This can only be done with openness to technology. Especially in the heavy-duty sector, there is no way around alternative fuels and hydrogen. The 17th International MTZ Conference “Heavy-Duty, On- and Off-Highway Engines” therefore offers engine developers and designers of commercial vehicles and mobile machinery, as well as marine and stationary equipment a platform to inform themselves about and exchange ideas on the latest developments in new power units and alternative energy sources. The conference in Donaueschingen will be supplemented by a guided tour of the MAHLE GmbH plant. I look forward to your participation in the conference. Dr. Alexander Heintzel On behalf of the Scientific Advisory Board Chefredakteur ATZ | MTZ-Gruppe Springer Nature v
Vorwort Herzlich willkommen Nachhaltiger Klimaschutz lässt sich nur dann erreichen, wenn alle Register bei Energiewandlern und -trägern gezogen werden. Dies geht nur mit Technologieoffenheit. Insbesondere im Heavy-Duty-Bereich führt an alternativen Kraftstoffen und Wasserstoff kein Weg vorbei. Die 17. Internationale MTZ-Fachtagung „Heavy-Duty-, On- und Off-Highway-Motoren“ bietet daher Motorenentwicklern und -konstrukteuren von Nutzfahrzeugen, mobilen Maschinen, Marine und stationären Anlagen eine Plattform, sich über die aktuellen Entwicklungen neuer Aggregate und alternativer Energieträger zu informieren und auszutauschen. Ergänzt wird die Tagung in Donaueschingen durch eine Führung im Werk der MAHLE GmbH. Ich freue mich auf Ihre Teilnahme an der Tagung. Dr.Alexander Heintzel Für den Wissenschaftlichen Beirat Chefredakteur ATZ | MTZ-Gruppe Springer Nature vii
Inhaltsverzeichnis The TCG 7.8 H2 – Further Development Steps to Realize a CO2 Free-Powertrain for NRMM. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Georg Töpfer, Heiner Bülte, Benedikt Nork, and Carsten Funke 1 The Development of a 6-Cylinder Hydrogen Engine for the Off-Highway Market. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Bouzid Seba and Ulrich Weiss 13 Investigation of An Ammonia Diesel Dual-Fuel Combustion Process on a Heavy-Duty Single Cylinder Research Engine for the Development of Suitable Simulation Tools for Maritime Applications . . . . . . . . . . . . . . . . . . . Till Mante, Sascha Prehn, Martin Theile, Lars Seidel, Laura Mestre, Bert Buchholz, and Fabian Mauss 24 H2 ICE DI Multicylinder Engine Tests for Thermodynamics and Component Development. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Simon Schneider, Christian Trabold, Thomas Friedrich, Florian Mayer, Fabian Weller, and Roman Stiehl 40 Assessment of a Direct-Injection, Spark-Ignited, Hydrogen-Fuelled Heavy-Duty Engine. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . John Hughes, David Bennet, Angela Loiudice, Nicholas Coles, Trevor Downes, Agam Saroop, Richard Penning, Lukáš Valenta, Peter Rabanser, Jonathan Davis, Jackson Harvey-Bush, Alvaro Concepcion Calero, Richard Osborne, Penny Atkins, Roger Allcorn, and Nigel Fox 53 The Compact Catalytical Heater (CCH): Thermal Management for HD EU-VII/EPA-27 with Low Impact on Existing EATS Architectures. . . . Manuel Presti, Oswald Holz, Mathias Keck, and Dennis Sailer 76 Liebherr’s Approach to Hydrogen Fuel Injection Systems. . . . . . . . . . . . . . . . . . Richard Pirkl, Mario D’Onofrio, Lydia Kapusta, and Dennis Herrmann Hydrogen Dosing Systems for Large Engines: Challenges and Potentials of Three Different Approaches. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Enrico Bärow, Michael Willmann, Andreas Kühner, and Rick Boom 95 112 ix
x Inhaltsverzeichnis Hydrogen Storage Technologies. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Mathias Keck, Dirk Bessey, Frank Buehler, and Manuel Eugen Faiß Well-to-Wheel CO2-Analysis of Different Powertrain Systems on Representative Heavy-Duty Mission Profiles . . . . . . . . . . . . . . . . . . . . . . . . . Nicolas Hummel, Tim Herold, and Christian Beidl Hydrogen in the Gas Network – Challenges and Solutions for High Performance Engines for Power Generation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . Clément Leroux, Robert Böwing, Bernadet Hochfilzer, Alexander Zuschnig, and Manuel Behr 123 131 143 Safe and Sustainable Testing of Hydrogen Powertrains. . . . . . . . . . . . . . . . . . . . Nicolas Weyland 158 Hybrid PEM Fuel Cell Systems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Sönke Gößling, Matthias Bahr, and Felix Smyrek 167 Fuel Cell System Development for Heavy Duty Application. . . . . . . . . . . . . . . . Stephan Schnorpfeil, Arne Kotowski, Hauke Sötje, and Guido Hartmann 172 Autorenverzeichnis. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185
The TCG 7.8 H2 – Further Development Steps to Realize a CO2 Free-Powertrain for NRMM Georg Töpfer(*), Heiner Bülte, Benedikt Nork, and Carsten Funke DEUTZ AG, Cologne, Germany {georg.toepfer,heinrich.buelte, benedikt.nork,carsten.funke}@deutz.com Abstract.  The development of a hydrogen internal combustion engine (HICE) represents special challenges in combustion development. The HICE is being developed with external mixture formation and injection of hydrogen upstream of the intake valves. The paper presents simulation results to show the challenges for the hydrogen injection (H2-injection) system to avoid backfire into the air tract. The achievable engine performance and emission behavior of the PFI-engine are significantly influenced by the turbocharging technology and its ability to rise charge pressure to necessary level. The maximum achievable engine power is optimized by simulating the complete system. The permissible operating conditions are respected to avoid overloading the components. In NRMM applications in particular, the high engine dynamics required (load step) must be considered. Experience in real-world applications enables the suitability of the HICE to be evaluated. It can also be used to evaluate the robustness of the engine concept. For this purpose, several demonstrator projects with different applications are being realized, which are also briefly presented in this paper. Keywords:  Hydrogen · Internal combustion engine · Off-Highway 1 Sustainable Drive Systems for CO2-Reduction at NRMM Currently, most of the EU’s activities are focused on reducing CO2 emissions in the mobility sector. However, there are also opportunities for CO2 reduction in the relevant area of Non-Road Mobile Machinery (NRMM). According to statistics of TREMOD report [1], Germany alone emitted 13,9 million tons of CO2 in the NRMM sector in year 2018. Diesel engines at agricultural applications and construction machinery together account for around 80% of CO2 emissions. Currently, most of NRMM applications run on fossil fuels, with a statistic average lifetime of about 15 years. © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 1–12, 2023. https://doi.org/10.1007/978-3-658-41477-1_1
2     G. Töpfer et al. NRMM vehicles are mostly used for business purposes, i.e., if the machine works reliably and with a high efficiency, the machines will continue to be used. A new acquisition means an investment. Therefore, alternative drive systems are needed in a timely manner, which do not limit the efficiency of the machines regarding the daily work performance (Fig. 1). Fig. 1.  Share of pollutant emissions from Non-Road Mobile Machinery (NRMM) in Germany 2018 by sector [1] The emitted CO2 emissions show that there is a need for action in the sector of mobile machinery. DEUTZ follows two basic approaches for sustainable drivetrains [2]. • Development of electric drivetrains with 48 and 360 V within E-DEUTZ strategy with available power up to 60 kW. An operation range extension and independence from electric charging infrastructure will be envisaged with fuel cell technology in nearby future. • The further development of combustion engines will head forward operation with non-fossil gaseous and liquid fuels. The current focus is on the use of hydrogen, which will be the main energy carrier in Europe due to the German national hydrogen strategy [3] and will therefore have very good availability in nearby future. Thus, the question arises why both a hydrogen internal combustion engine (HICE) and electric drive systems with fuel cell (FC) are in the portfolio. Both drivetrains reveal dedicated advantages which can be explained by evaluating the operating conditions of the work machines using the example of a hydraulic excavator.
The TCG 7.8 H2 – Further Development Steps …    3 Figure 2 shows a characteristic load profile of a hydraulic excavator application. Depending on the power requirement, the vehicle hydraulics operate at specific, controlled engine speeds at which the torque and thus the work output (moving the boom, rotating the upper carriage) are continuously varied in a highly dynamic manner. The engine governor has the task of maintaining the speed in the case of a sudden load increase by the hydraulics, which demands high requirements on the engine dynamics. Fig. 2.  Engine map with characteristic load profile of a hydraulic excavator application A general comparison of the two systems is shown in Fig. 3. The combustion engine as a currently integrated drive system meets these requirements and thus sets the expected development targets for the HICE. An FC system can also be applied. The compact, electric drive system provides an immediately available torque over the complete speed range. The high energy supply for dynamic operation is provided by an energy storage system (battery).
4     G. Töpfer et al. Fig. 3.  Comparison of fuel cell system to hydrogen combustion engine When designing the cooling system, it should be noted that an adjustment should be made for both drive systems. Here, it is to be expected that in high-load applications, the cooling capacity required for a FC is somewhat higher than for a HICE due to low exhaust gas temperatures and enthalpy [4]. This can be compensated by adapting a greater cooler package. Looking on hydrogen purity, the HICE also allows hydrogen with a lower degree of purity. NRMM vehicle often operate in dusty environment. Also, the vehicle is not suspended and hence the drivetrain experience severe vibrations during operation. In summary, there are some special aspects to be considered in the NRMM application for both drive systems. A suitable drive system must be selected regarding efficiency, availability of energy infrastructure, acceptable operation range. Additionally, the Total Cost of Ownership (TCO), especially operating costs and service life, must be considered. 2 Hydrogen Internal Combustion Engine (HICE) The TCG 7.8 H2 is a six-cylinder inline engine with a displacement of 7.8 L, a bore of 110 mm and a stroke of 136 mm (Table 1). The gas engine is based on the series diesel engine TCD 7.8 with further changes to obtain a hydrogen fired engine. The hydrogen combustion engine with hydrogen PFI injection (external mixture formation). Table 1.  Engine specification Cylinder Displacement Bore/Stroke Injection 6 inline 7.8 L 100/136 mm Hydrogen PFI System
The TCG 7.8 H2 – Further Development Steps …    5 To develop a gas engine version several changes were done (Fig. 4). The engine receives a modification of the existing cylinder head to accommodate the ignition system for a hydrogen lean combustion, which avoids a residual spark discharge due to the low ignition energy required and thus unwanted combustion events. The spark plugs especially suited for hydrogen engines with a low heat characteristic and special designed electrodes are used. The gas exchange valves and its seats are improved with wear-reducing measures, which consider the low lubricity of hydrogen. Fig. 4.  Principle, necessary changes of base diesel engine to obtain hydrogen combustion engine The compression ratio is reduced by means of a new piston bowl. The piston ring package is adapted to minimizes oil intake and hence prevent pre-ignition due to small oil droplets. The intake manifold was redesigned to accommodate the injectors in front of each inlet valve. To compensate for intake air supplanting by the high volume of injected hydrogen, the turbocharger is modified so that high boost pressure can be provided over a wide speed range. Boost control is software-based with an electric actuator. The engine has an externally cooled and controlled exhaust gas recirculation (EGR). Depending on the power density and required engine dynamics, the engine is equipped with a conventional exhaust aftertreatment system with SCR for NOx reduction, which is adapted for typical operation with hydrogen (higher amount of water content in exhaust gas, suitable for temperature range). The challenging tasks are the development of a H2-injection system, in particular the injector and the control software for a spark ignited lean burn engine considering low NOx emission during dynamic engine operation.
6     G. Töpfer et al. 2.1 Hydrogen Injectors The injectors are the key component in the development of a hydrogen engine. They must operate with high repeatability over the entire service life in the entire engine map and always close tightly. Since there is also only a very short time slot available for metering into the inlet port, a conflict of objectives arises between the required flow rate of the injectors at the point of maximum power and the metering accuracy at the minimum quantity requirement at idle. In the case of large injection quantities, it is necessary to resolve the conflict of objectives between mixture homogenization and safety against backfire. While the longest possible injection time would be advantageous for good mixing of hydrogen and air, the formation of an ignitable mixture in the intake manifold and the impingement of such a mixture on a potential ignition source must be avoided (Fig. 5). Fig. 5.  Simulation of the hydrogen concentration in the intake manifold during a PFI injection
The TCG 7.8 H2 – Further Development Steps …    7 To prevent ignitable mixture from remaining in front of the closing inlet valve, the end of the injection must also be selected with sufficient time gap before the inlet closes. The location of injection into the inlet port also plays a major role. Here a compromise must be found between the requirements for mixture formation and safety against backfiring, too. 2.2 Charging Concepts The choice of a suitable turbocharging concept for the TCG 7.8 H2 presents a particular challenge, since the conflict of requirements between high specific power and very good dynamic response must be resolved. To keep NOx Engine Out (EO) emissions at a very low level, a hydrogen engine must be operated with an air-fuel ratio λ ≥ 2. In combination with the low mixture calorific value due to external mixture formation (PFI), this leads to very high charge pressures to achieve a specific power up to 28 kW/l. The use of a turbocharger (TC) with variable turbine geometry (VTG) improves dynamic response with nearly comparable limits of maximum power output. For the complete concept, the EGR system is additionally adopted with modifications. Since high-pressure (HP)-EGR reduces the air mass flow through the compressor, the compressor and turbine wheel can be made smaller, resulting in a lower moment of inertia and thus an accelerated buildup of boost pressure in the event of a load jump. In this way, the conflict between high specific power and rapid dynamic load buildup can be resolved without two-stage turbocharging. Due to the requirements for H2-injection and charging described above, there are fixed, limiting operating conditions. With the aim of a series application, the robustness of the combustion process must also be validated and the resulting installation restrictions about pressure losses and max. permissible temperatures must also be included in the evaluation. The simulations carried out show clear performance limits, restrictive boundary conditions are summarized (Table 2). Knocking intensity was also calculated and considered. All simulation results were obtained with a VTG –TC, the center of energy conversion (combustion) is constant. The maximum achievable engine power is limited by the maximum permissible boost pressure. Acceptable air-fuel ratio λ and the associated NOx emissions define the maximum H2-injection quantity. Table 2.  Installation restrictions Max. temperature downstream compressor Max. temperature upstream turbine Max. TC speed Tds. Compr. max. Tus. Turb. max. nTC max.
8     G. Töpfer et al. Figure 6 shows the simulation result for an air-fuel ratio λ1. The respective boundary conditions are shown in the diagram. The max. temperature downstream compressor Tds. Compr. max. is power limiting with increasing EGR rate and compressor mass flow. The turbine inlet temperature increases with decreasing EGR rate and thus also limits the power. This results in a range in which operation is feasible with the given boundary conditions. At this operating point, a maximum power output of 164 kW/2,200 rpm is achievable. For further power gain, a further increase in the H2-injection quantity at constant maximum boost pressure is required. This results in a richer mixture with airfuel ratio λ2(λ2 < λ1). The simulation results are shown in Fig. 7. Compared to the previous operating point, the possible operating range is smaller. A higher EGR rate is required, and to avoid an excessively high intercooler outlet temperature, the air mass flow rate must be limited. Under these assumptions, a rated power of 220 kW/2,200 rpm is achievable. Due to enriched air-fuel ratio λ2, a higher NOx EO emission level should be reduced by a suitable exhaust gas aftertreatment system (SCR). Fig. 6.  Simulation result at rated power, n = 2,200 rpm, λ1, with installation restrictions
The TCG 7.8 H2 – Further Development Steps …    9 Fig. 7.   Simulation result at rated power, n = 2,200 rpm, λ2(λ2 < λ1), with installation restrictions 3 Demonstrator Application and its Use for Series Development In a series development, it is necessary to validate the temporal robustness of the HICE under typical operating conditions. The combustion process shows that a PFI hydrogen engine has a higher tendency to abnormal combustion events (backfire, preignition and knocking) than other gas engines and therefore reacts more strongly to changes of influencing parameters. Over engine lifetime, a change in H2-injection quantity (e.g., due to injector wear), drift of a sensor (e.g., accuracy, measured value), or changes of operation conditions (e.g., filter clogging, higher ambient temperature) could affect combustion. In the case of hydrogen exposed components, the question arises of a possible change in material properties due to hydrogen deposition and a resulting reduction in tensile strength (embrittlement). Especially for cast materials (e.g., cylinder head) almost no information can be found in the literature. Blowby and its possible change due to wear of piston rings must also be evaluated. Hydrogen enters the crankcase through blowby gases and accumulates in the crankcase. It must be ensured that the concentration does not exceed 4% by volume and that an ignitable mixture is present.
10     G. Töpfer et al. In addition to intensive functional testing further experience will be gained by means of field tests, ideally in 4-season operation. Due to the intended short development period, it is necessary to gather experience parallel to series development activities by means of very early applications of demonstrators. Different applications are planned for this purpose. In the case of applications, a distinction must be made between stationary applications operated at constant speed and mobile applications with variable speed and high dynamic requirements. The respective operation has an influence on the engine control and operating strategy. Stationary operation with constant speed and low motor dynamics can be realized in earlier stage of development in terms of the control software. Fig. 8.  Hydrogen genset demonstrator with TCG 7.8 H2 For this purpose, a hydrogen genset (H2-genset) was successfully realized as a demonstrator in June 2022 with a very early development stage of the TCG 7.8 H2 (Fig. 8). The H2-genset generates an electrical power up to 170 kVA in grid-parallel operation at a constant speed of 1,500 rpm. In addition, the TCG 7.8 H2 is being further developed and tested for a truck application in a project funded by the Bundesministerium für Digitales und Verkehr (BMDV). The research project aims to demonstrate the sustainability potential of trucks with hydrogen combustion engines in transport logistics. NRMM applications require further demands on the operation of the hydrogen engine due to high dynamic requirements and the harsh operating conditions. For this reason, DEUTZ and other cooperation partners are building a hydraulic excavator as a demonstrator in another BMBF (Bundesministerium für Bildung und Forschung)funded project.
The TCG 7.8 H2 – Further Development Steps …    11 4 Summary DEUTZ is currently developing a Hydrogen Internal Combustion Engine (HICE) with a displacement of 7.8 liters, the TCG 7.8 H2. It is foreseen, that this new engine type will set up into series production in the year 2024. Studies [4, 5] showed, that HICE reveals several advantages at NRMM applications. In NRMM the powertrain must operate well at rough dust contaminated environment and experience high vibration load at a lot of applications. Operation cycles are mainly highly dynamic, and the engine load factor is quite high, depending on the application. Mobile machinery mainly operates at stable place or with a small vehicle velocity, hence the coolant radiator is always supported by an additional coolant fan. These requirements could very well be fulfilled with a HICE. As with all gaseous fuels, the challenge is to integrate sufficient tank volume into the vehicle to realize an appropriate operation range and high working efficiency, which are the most important duties of the mobile machinery. In the early stage of development, a pilot project was realized within predevelopment and the TCG 7.8 H2 engine was applied at a mobile power generator (H2-genset). At the end of year 2021 the first start of the power generator was realized. The TCG 7.8 achieves a mechanical power of 150 kW at 1,500 rpm. The strategic aim of the pilot project is to demonstrate the concept in a first application and to gather experience in operating HICE over a longer time. The H2-genset is a necessary supplement to the energy supply of the future and allows to produce CO2-free on-site electric energy at places without connection to the power grid, such as construction sites. Next step is to extend the application to the construction machinery, enlarge the operation range (engine speed and torque) and to realize a HICE, which is capable to drive a hydraulic drivetrain. This step enquires an increased engine operation range (speed and power) and improved engine dynamics in transient operation. The high engine dynamic is necessary to realize high torque demands requested from hydraulic systems. In oncoming steps, it is foreseen to build up a 30t hydraulic excavator together with strong development partners within a funded project. The TCG 7.8 H2 is based on the diesel engine with same displacement. Several changes in hardware are necessary to obtain a HICE suitable engine design. It was decided to develop the engine with a Port-Fuel-Injection (PFI). To compensate the lower caloric mixture value with a high boost pressure a suitable turbocharger technology was chosen. Special attention was taken to realize good dynamic response at load steps. The engine is equipped with an EGR system to realize a high-power density at low knocking sensitivity as well as low pumping losses at part load. Turbocharger matching and the EGR system layout were optimized using simulation tools. Development aim was to improve the hardware to minimize flow losses. Due to the chosen PFI for hydrogen, measures must be taken, to avoid backfiring (self-ignition of hydrogen-air mixture) in the inlet port. Hence, additionally optimization steps were investigated to avoid the coincidence of ignitable mixture and potential ignition sources.
12     G. Töpfer et al. Abbreviations CO2 Carbon Dioxide EGR Exhaust Gas Recirculation EO Engine Out FC Fuel Cell HICE Hydrogen Internal Combustion Engine HP-EGR High-Pressure Exhaust Gas Recirculation GHG Greenhouse Gas NOx Nitrogen Oxides NRMM Non-Road Mobile Machinery PEMFC Polymer Electrolyte Membrane Fuel Cell PFI Port Fuel Injection VTG Variable Turbine Geometry References 1. Aktualisierung der Modelle TREMOD/TREMOD-MM für die Emissionsberichterstattung 2020 (Berichtsperiode 1990–2018). Berichtsteil „TREMOD-MM,“ https://www.umweltbundesamt.de/sites/default/files/medien/1410/publikationen/2020-06-29_texte_117-2020_ tremod_mm_0.pdf 2. Schwaderlapp, M., Bülte, H., Plumpe, A.: Solutions for CO2-free powertrains for mobile machinery. In Heavy-Duty-, On- und Off-Highway-Motoren (2021) 3. Die Nationale Wasserstoffstrategie. https://www.bmbf.de/bmbf/shareddocs/downloads/files/ die-nationale-wasserstoffstrategie.pdf?__blob=publicationFile&v=1. BMWi (2020) 4. Systemvergleich zwischen Wasserstoffverbrennungsmotor und Brennstoffzelle im schweren Nutzfahrzeug. e-mobil BW, Studie, https://www.emobil-sw.de/fileadmin/media/e-mobilbw/ Publikationen/Studien/e-mobilBW-Studie_H2-Systemvergleich.pdf (2021) 5. Wasserstoffverbrennungsmotor als alternativer Antrieb. Metastudie, NOW GmbH, https:// www.now-gmbh.de/wp-content/uploads/2021/10/NOW_Metastudie_Wasserstoff-Verbrennungsmotor.pdf (2021)
The Development of a 6-Cylinder Hydrogen Engine for the Off-Highway Market Bouzid Seba(*) and Ulrich Weiss Liebherr Machines Bulle SA, Bulle, Switzerland {bouzid.seba,ulrich.weiss}@liebherr.com Abstract.  Hydrogen internal combustion engine (H2-ICE) has the potenzial to be an enabler for fast decarbonization in several sectors. In this context, Liebherr is developing a hydrogen combustion engine based on spark ignition. This new powertrain is a part of a strategic approach toward zero emission technologies for off-highway sectors. This technology has gained an important interest from the off-highway sector due to several reasons such as: • • • • Robustness of the technology regarding the duty conditions in the Offhighway sector Cost of the power train system Quick time to market solution Similar installation condition compared to the current powertrain Currently, the diesel engine finds its way in a wide range of vehicles in the Off-highway sector and transformation of the current power train to the new zero emission technologies (Hydrogen Engine) will require considering several aspects: • • • • Investigation and analysis of the current vehicle architecture capabilities Development and adaptation of several subcomponents of the powertrain (such as cooling system) Modification of the storage system and the fuel path from the tank to the engine fuel interface Analysis and installation of the required additional elements regarding the safety precaution The development of the technology started with several investigation in the combustion engine test bench; this new power train has been then introduced in vehicle integration and used to build-up a zero emission excavator. This paper reviews the current investigations regarding the transformation/ adaptation of an excavator powertrain (Diesel-hydraulic excavators) to a hydrogen combustion engine powered machine: Description of the excavator characteristics and analysis of the different characteristics of this new powertrain. Thenceforth, the fuel and storage system is explained and illustrated, followed by a review of several safety precaution aspect. The © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 13–23, 2023. https://doi.org/10.1007/978-3-658-41477-1_2
14    B. Seba und U. Weiss paper concludes with an evaluation of the new proposed powertrain in terms of dynamic, efficiency and emission. At the end an outlook regarding the further application of the hydrogen combustion engine in different other type of machines in construction and off-highway sector has been given. Keywords:  ZE (Zero emission) · Future power trains · Hydrogen combustion engine (H2-ICE) · Safety requirement · Hydrogen storage system · Tanks · Offroad vehicles · Excavator 1 Introduction In the last 5 years, the development of the hydrogen combustion engine gained a strong interest from different industries. Several entities in off-road and heavyduty applications now see that the H2-ICE will play an important role in the decarbonisation of their vehicle. As mentioned in literature and in our previously publication [1], the main benefits of the technology are: • The robustness against environmental working condition • The high degree of performance in transient operation • The efficiency in high load operation One of the drivers for the introduction of zero emission technologies is the forecast of future CO2 emissions regulations for different industry sectors. Additionally, several emission restrictions are expected in the cities, impacting the implementation and the deployment of ZE-Technologies for specific applications (Fig. 1). Fig. 1.  EU Regulation for On-Road/Off-Road The off-road sector can expects the combustion engine using hydrogen to be one of the technologies aiming toward these targets. Hydrogen has been the object of several investigations over the years. Different applications such as spatial, automotive and other industrial applications were especially involved. A considerable gain in experience over fuel compatibility with different materials and fuel properties happened thanks to those investigations. Figure 2 summarizes some specific
The Development of a 6-Cylinder Hydrogen …    15 properties of hydrogen and displays a comparison with different fuels. The hydrogen fuel has a high gravimetric calorific value. However, its lower density reduces the energy density of the mixture. This leads to lower performance especially for some injection concepts such as H2 PFI. This characteristic has a direct impact on the torque performance of the engine which decreases with higher air/fuel ratio. This inconvenience is a challenging issue in both heavy-duty and off-road applications due to packaging requirements. H2 direct injection (H2 DI) is one possible solution to improve the mixture heating value especially if the fuel injection occurs after full closure of the inlet valve. However, H2 DI main drawback is the emission level, which is higher due to bad homogeneity of the air/fuel mixture. Fig. 2.  Fuel properties and comparison For the first demonstration of the technology, Liebherr presented an excavator powered by a PFI combustion engine, assuring the deployment capability of the technology for off-road sector. 2 Development Phases of the Technology Following the selection of the combustion technology, several steps ensured the meeting of the requirement of the final product “excavator with H2-ICE”: • • • • Preliminary assessments and target definition Engine design & component selections Engine preparation and optimization Vehicle testing Several challenges emerge when operating in the off-road sector. Here is the summary of the main conditions to consider: • • • • • • • Resistant to hot and cold temperatures environment Higher transient operation (especially notable for application such as excavators) Operation in high humidity environments High vibration/shock intensity Operation at higher altitude (>3000 m) High lifetime expectation
16    B. Seba und U. Weiss • Operation in dusty environment (possible affect the air and fuel quality) The combustion engine with a diesel configuration already proved its capability to fulfill the above-mentioned conditions. The flexibility of the diesel technology also enables one specific unit to cover different application, eliminating the need of hybridization (Figs. 3 and 4). Fig. 3.  Development phases Fig. 4.  Applications with D966 3 Engine Data and Description The engine used for excavator applications is the Liebherr hydrogen engines H96613.5 L. This engine family will find its way in various applications in the off-road sectors. Figure 5 pictures the original diesel engine and the converted hydrogen engine:
The Development of a 6-Cylinder Hydrogen …    17 Fig. 5.  Diesel original engine “left” and hydrogen engine “right” Table 1 summarizes the main specifications and characteristics of the engine. The consideration of several compression ratios and other hardware parameters suggests future optimization of the engine. Expectations point toward improvement of the main performance indicators such as efficiency and engine power density. The design of fuel path components also relies on the necessary optimization. Among the points to address is the rail pressure pulsation level or the time response of the pressure regulation loop in transient operation. Table 1.  Engine data of H966 Several combustion technologies underwent development at Liebherr, revealing their potential regarding the engine performance, power density and NOx emissions. In our previous publication [1], we showed the advantages and drawbacks of both injection strategies (port fuel injection “PFI” and direct injection “DI”) using the measurements performed with a 4-cylindre engine “H964”. For different reasons such as residual pressure level and technology maturity, following activities used the PFI technology.
18    B. Seba und U. Weiss 4 Engine Optimization for Vehicle Application The optimization of the hydrogen combustion engine for vehicle application considered several phases. Figure 6 summarizes the main phases of this H2-ICE development. Fig. 6.  Vehicle optimization phases After the first investigation (in steady state operation), where the engine entered the test bench for performance characterization, several steps aimed to improve the power density by considering the following challenges: • Backfire in certain operating conditions (higher knocking sensitivity) • Safety measures related to hydrogen applications: Fuel system, etc … • Lower NOx emissions by ensuring in the same time an acceptable dynamic behavior of the engine Additionally, the engine-vehicle optimization requires the preparation of the engine for dynamic and transient operation. Considering the excavator is one of the most challenging vehicles dynamically, dynamic evaluation followed these two stages: • Load steps: The engine follows load profiles derived from real operating cycles. As a torque increase happens, analysis of the speed drop and recovery time of the engine speed evaluates the load step response. This is an important criterion for the performance analysis of a vehicle. • NRTC: NRTC cycles demonstrate the general performance of the engine in different off-road vehicles just as transient driving cycle for mobile off-road diesel engines do. This cycle also serves emission evaluation between different combustion technologies.
The Development of a 6-Cylinder Hydrogen …    19 Additionally to the load step with “torque increase”, there are also some technical challenges in the phase of torque decreases “release”. This concerns mainly the injection path optimization. Solution to the later can emerge in the test bench phase using for example dedicated combustion, regulation of the rail pressure and purge procedures. 5 Vehicle Integration The following milestones summarize the identification of the components and their integration to the engine and to the vehicle (Fig. 7): • Analytical investigation using component characteristics • Use of 1D-Simulations and measurement data in order to estimate the accurate fuel consumption • Component identification and creation of specification data communicated to different suppliers • Definition of all interfaces between the tank pressure regulator and engine • Investigation and implementation of all safety items Fig. 7.  Development phases Figure 8 illustrates the main components and layout of the vehicle integration. Key components, such as the pressure regulator, the fuel path elements and the ECU, have been the subject of several investigations. Investigations happened in the component
20    B. Seba und U. Weiss Fig. 8.  Component of the DI hydrogen combustion engine test bench before HiL “Hardware in Loop” testing. This was crucial to assess the interaction between the actuators and the ECU, the electrical interfaces as well as the time response of the components. 6 Storage System The fuel consumption of the combustion engine in different operating point is the reference for hydrogen amount calculation. The storage and integration of the tank is one of the main investigated subjects in the integration of the H2-Technology. The autonomy of the vehicle operation for a certain given packaging is dependent on different parameter such as: • Storage pressure/temperature • Powertrain efficiency • Injection strategy (which determines the minimal pressure level that is required for engine operation) • Tank geometry
The Development of a 6-Cylinder Hydrogen …    21 Fig. 9.  Storage system Figure 9 shows the equivalent volume required for 4 h of the excavator operation. As expected, diesel has the lowest required volume value (150 L) thanks to its higher specific volumetric energy density (10 kWh/L). Hydrogen storage systems with “700 bar” also offer an interesting compromise compared to other ZE-Technology competitors based on electrical storage system. 7 Outlook The hydrogen technology offers a large potenzial for decarbonisation in off-road sectors by using direct fuel combustion. This potenzial covers the current local emission regulations (Tank-to-Wheel) in terms of CO2 reduction as well as the global emissions regulation by using green electricity. The main areas that still require optimization to ensure the entire satisfaction of different aspects of industrialization are: • Storage system optimization • Efficiency of the complete power train • Infrastructure for fuel supply in working site The extension of the technology toward different vehicle type in off-road sector is on-going considering the many advantages of the technology presented in this investigation. 8 Summary and Conclusion Development of an appropriate ZE “zero emission” technology is one of the main investigation subject in the last decade in different industries sector. The target for CO2 emission reduction has been already introduced in heavy duty “On Road sector” with milestones in 2025 (−15 %) and 2030 (−30 %). Furthermore, this CO2 emission reduction target will be extended to several sectors in the future. There is additionally
22    B. Seba und U. Weiss some CO2 regulation that are introduced in some cities in Europe. The combustion engine has already demonstrated its robustness in term of operation in harsh condition such as temperature, altitude, and dusty environment. These characteristics will strength the introduction of CO2 free power train based on combustion. One promising way for decarbonization is to use green energy to produce hydrogen and build CO2 neutral powertrain based on hydrogen combustion engines. This type of technology could even operate with blue or other low carbon hydrogen fuel. The way for production of green hydrogen in large scale will need several years for the building and the installation of necessary infrastructure. In the transition period, several type of (low carbon) hydrogen could be used with combustion engine to ensure decarbonization even in early phase. Hydrogen combustion engine investigation has been performed for several years and in different area/application. Liebherr is developing hydrogen combustion engine in order to be ready for the future CO2 emission reduction target that will be implemented in different area. One of the Offroad vehicle which operate in very harsh condition is the excavator, furthermore the operation with this type of vehicle is challenging in terms of dynamic. This integration of the H2-ICE and the corresponding H2- actuators and sensors has been performed and successfully integrated in the excavator. Several technical challenges has been solved during this phase of integration and testing with the vehicle. Several specific tests related to excavator operation has been successfully realized with H2-ICE and excavator. This activity has demonstrated that operation of the H2-ICE can fulfill the different requirements of the vehicle and generally in Offroad sector. Additional challenge in the vehicle integration phase is to find the optimal size of the tank that cover the necessary autonomy of the vehicle by considering the real operating cycle. In another hand, the H2-storage system has advantages regarding the filling time, which is shorter compared to electrical storage systems, In order to deploy this technology in large scale production, additional infrastructure are required to ensure the transport the fuel in the working sites. Mobile tank station that can ensure the supply of the fuel in the working site could be one of the possible technical solutions to fulfill requirements in terms of necessary tanking frequency. The problem and dilemma of hydrogen network filling stations number and the demand from customers is one of the key elements for a profitable series production. The launch of small series production of hydrogen vehicles in working sites will help to grow the interest to the fuel stations network. In general, the potential of the technology to operate in excavator environment has been shown and demonstrated, the spread out of the technology to other vehicle type in the Offroad sector is one of the next steps and outlook for future horizon. References 1. Seba, B.: Hydrogen Combustion Engine – A Suitable Concept for Decarbonization in the Offroad Sector. ATZ live (2021) 2. Weiss, U.: The Off-Highway Sector in the Field of Tension of Future Powertrain Concepts – What Chances Does the Internal Combustion Engine have in This Industry? Baden Baden Engine congress, Baden Baden (2022)
The Development of a 6-Cylinder Hydrogen …    23 3. Kovacs, D., Rezaei, R., Englert, F., Hayduk, C., Delebinski, T.: High Efficiency HD Hydrogen Combustion Engines: Improvement Potentials for Future Regulations (2022) 4. Krepec, T., Tebilis, T., Kwok, C.: Fuel Control Systems for Hydrogen-Fueled Automotive Combustion Engines – A Prognosis. Elsevier (1984) 5. Heywood, J.B. (2018). Internal Combustion Engine Fundamentals. McGraw-Hill (2018) 6. Freund, E., Lucchese, P.: Hydrogen, the Post-Oil Fuel, Edition Technip (2013) 7. Hermanns, R.T.E.: Laminar Burning Velocities of Methane Hydrogen Air Mixtures, Dissertation, Eindhoven University of Technology (2007) 8. Delneri, D.: Combustion System Optimization for Alternative Fuels, 17th Conference The Working Process of the Internal Combustion Engine (2019) 9. White, C.M., Steeper, R.R, Lutz, A.E.: The hydrogen-fueled internal combustion engine: A technical review. Int. J. Hydrogen Energy (2006) 10. Van der Put, D., et al.: Efficient commercial powertrains – how to achieve a 30% GHG reduction in 2030. In: Proceedings of the FISITA 2020 world congress, Prague, 14–18 September 2020 11. Tang, Q., Liu, J., Zhan, Z., Hu, T.: Influences on combustion characteristics and performances of EGR vs. lean burn in a gasoline engine. SAE technical paper 2013-01-1125 (2013) 12. Das, M.L.: Hydrogen engine: Research and development (R&D) programmers in Indian Institute of Technology (IIT), Delhi. Int. J. Hydrogen Energy (2002) 13. Caton, J.: A comparison of lean operation and exhaust gas recirculation: thermodynamic reasons for the increases of efficiency. SAE Technical Paper 2013-01-0266 (2013) 14. Hitting the gas on hydrogen tech for commercial trucks, sae, 2022-05-03 MATT WOLFE
Investigation of An Ammonia Diesel DualFuel Combustion Process on a Heavy-Duty Single Cylinder Research Engine for the Development of Suitable Simulation Tools for Maritime Applications Till Mante1(*), Sascha Prehn1, Martin Theile2, Lars Seidel3, Laura Mestre3, Bert Buchholz1, and Fabian Mauss4 1 LKV—University of Rostock, Rostock, Germany {till.mante,sascha.prehn, bert.buchholz}@uni-rostock.de 2 FVTR GmbH, Rostock, Germany martin.theile@fvtr.de 3 LOGE Deutschland GmbH, Cottbus, Germany {lars.seidel,laura.mestre}@logesoft.com 4 BTU Cottbus-Senftenberg, Cottbus, Germany fmauss@b-tu.de Abstract.  This paper discusses the adaption of a single cylinder research engine for a retrofit application with an ammonia diesel dual-fuel combustion process and the build of an ammonia fuel system. The gaseous ammonia will be injected in the air intake pipe and the premixed ammonia air mixture will enter the combustion chamber. The diesel injection is carried out via a highpressure common rail system. All relevant parameters can be freely adjusted via a freely programmable control unit. With the help of experimental data from a single cylinder research engine at the chair of piston machines and internal combustion engines of the University of Rostock (LKV), a dualfuel combustion model based on detailed chemistry will be developed and optimized. This model will be integrated in a full research engine model, which ensures the best possible representation of the real engine. The combustion model is being developed by LOGE Deutschland GmbH. The full research engine model is developed by FVTR GmbH. The analysis of the combustion process starts with pure diesel operating points and is successively substituted by ammonia in the course of the measurement campaigns. Both the combustion characteristics are relevant, as they significantly influence the resulting performance and engine operation, as well as the exhaust emissions, as the carbon emissions can be reduced, but the nitrogen oxides and ammonia slip increase significantly in relevance due to the ammonia. The results obtained will be used to derive initial recommendations for action and to estimate the potential for application in the inland waterway shipping. In addition, the d­ evelopment © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 24–39, 2023. https://doi.org/10.1007/978-3-658-41477-1_3
Investigation of An Ammonia Diesel Dual-Fuel …    25 of the systematic simulation tools covers a broad spectrum of research questions and aims to increase the efficiency of the necessary R&D. Keywords:  Combustion engines with alternative fuels · Combustion processes · Fuel and air systems · Engine and system optimization 1 Introduction Ammonia is considered one of the best-known chemical substances. To use this knowledge and make a positive contribution to the goal of climate neutrality, ammonia can also be considered as a fuel. Looking at the sum formula NH3, it quickly becomes clear that this potential fuel does not contain any carbon atoms and therefore does not form any carbon emissions during combustion. In general, the use of regeneratively produced carbon-containing fuels (e.g. synthetic methane, e-methanol, synthetic paraffinic fuels, synthetic OME, etc.) can achieve complete climate neutrality, since a closed CO2 cycle exists during the production of the fuel. With a time perspective beyond 2030, however, the availability of CO2 for the synthesis of the above-mentioned fuels could become problematic, especially since the separation of CO2 from the atmospheric air is energetically costly. Here, ammonia as a nitrogen-based hydrogen carrier offers a potential solution. By switching from carbon-based fuels to the nitrogen-based fuel ammonia, emissions of unburned hydrocarbons (including methane slip) and particulates can assumedly be reduced to virtually zero. Thus, the potential of a “zero carbon emissions” ship exists, whereby local as well as global (e.g. CO2 emissions) environmentally harmful effects are reduced or completely prevented. Furthermore, the production and infrastructure is already available for a century (Haber-Bosch), e.g. in the agricultural use as fertilizer[1]. It is not only these properties that make the substance attractive as a power-to-X fuel. In addition to alternative combustion processes such as spark ignition or diffusive processes, there is still the potential for application as a dualfuel combustion process in combination with conventional fuels and thus a possible retrofit perspective for shipping. Figure 1 shows all possible combustion processes with ammonia. The challenges in handling and using ammonia should not be underestimated. The main problems are the high toxicity, the challenging combustion properties and the resulting nitrogen compounds in the exhaust gas. Fig. 1.  Combustion processes with ammonia
26    T. Mante et al. As a retrofit variant in shipping, the combination with diesel fuel (e.g. NH3-PFI with pilot diesel injection) offers itself. In order to fundamentally investigate such a combustion process, the project “AmmoniakMotor”, which is funded by the BMWK (Federal Ministry for Economic Affairs and Climate Action)/PTJ and carried out by the project partners FVTR GmbH (process simulation), LOGE Deutschland GmbH (reaction kinetics in cylinder combustion model) and LKV—University of Rostock (NH3 research engine/test bench measurements), exists. The collaboration is displayed in Fig. 2. In the selected combustion process, the ammonia is injected in gaseous form into the intake air and brought into the combustion chamber as an ammonia-air mixture. For ignition & combustion support, diesel fuel is injected into the combustion chamber at high pressure via a common rail system. The LKV is converting an existing diesel single-cylinder research engine (SCE) to dual-fuel operation with ammonia. The FVTR is focused on the thermodynamic analysis of the incylinder process by using one the one hand sophisticated pressure trace analysis tools, which are capable of handling different ammonia-diesel ratios. On the other hand, a GT-Power model of the research engine will be created and combined with a stochastic reactor combustion model from LOGE. Within the project LOGE developed a detailed chemistry model for the combustion of diesel fuel and ammonia including the formation and reduction of emissions such as soot and nitrous species. The detailed model was reduced to lower computational time. The combustion developed model is used to model the incylinder combustion using LOGE’s stochastic reactor model (SRM). In a later phase of the project also a tabulated combustion modelling approach will be applied to reach even faster CPU times. Test bench data from LKV, in particular measured emissions, will be used in later phase of the project to improve the chemistry model. Fig. 2.  AmmoniakMotor—workflow
Investigation of An Ammonia Diesel Dual-Fuel …    27 2 Ammonia as an Alternative Fuel The major challenge in the use of ammonia as a fuel is its high toxicity and the associated safety requirements. Another characteristic is the pungent odor, which can be perceived from approx. 5 ppm in the air. Further contamination should be prevented as far as possible by early detection but should be avoided altogether due to the high toxicity. This requires sensitive and accurate safety technology. Affected rooms should be equipped with gas detectors and a gas warning system and should be permanently in operation if ammonia is present in said room. Persons should enter this room only with a suitable gas mask and under the supervision of another colleague, and all pipes should be free of ammonia during work. In the event of an emergency, sufficient ventilation should be provided to ensure that the entire amount of ammonia can be removed fast from the room. All these points make it challenging to use the fuel on ships and require trained personnel and maximum focus [2]. Furthermore, ammonia shows disadvantages in its combustion behavior compared to conventional fuels and thus cannot be replaced 1:1. The auto-ignition temperature of 630 °C is significantly higher than that of diesel with values between 180– 320 °C [3], which means that a diesel-like combustion process with auto-ignition and diffusion-controlled combustion is classified as technically complex to implement and would require very high compression ratios. The laminar flame velocity, which is relevant as an essential parameter for premixed combustion processes, is with 0.07 m/s [4] at standard conditions significantly lower than gasoline (approx. 0.4 m/s) or methane (approx. 0.37 m/s). This creates challenges in achieving complete conversion of the ammonia in the combustion chamber. Although the adiabatic flame temperature at stoichiometric conditions of approx. 1800 °C is lower than for many other fuels (comparison diesel: 2327 °C, gasoline: 2307, methane: 1950 °C), it is highly unlikely that global lean burn of the order of e.g. today’s natural gas engines (lambda significantly higher than 2) can occur in premixed combustion, which means that the flame temperature is expected to be higher in comparison. This may have a negative impact on the generation of thermal nitrogen oxides. Even though ammonia has the potential to be a CO2 free fuel, new challenges in exhaust gas aftertreatment arise with nitrous oxide (N2O) and the resulting ammonia slip. With a significantly higher greenhouse gas factor than carbon dioxide, nitrous oxide must be viewed very critically. Initial measurements show that nitrous oxide emissions from ammonia combustion increase simultaneously with the ammonia slip. Another important aspect is corrosion and the interaction with other materials (for e.g. pipes, valves, measurement systems, injectors). There are not that many possible combinations with either liquid and gaseous ammonia and to avoid leaks after a short time, the systems have to be thoroughly planned. Ammonia and its corrosion behavior on different materials is not widely researched yet.
28    T. Mante et al. 3 Test Bench Setup, Fuel System & Simulation Model Due to its high toxicity, the safe handling of ammonia is a decisive criterion for its use as a fuel. Especially in the process of basic research, the fuel system must be designed carefully along with sufficient the safety technology. 3.1 Test Bench Setup At the LKV in Rostock, a SCE is being converted to dual-fuel operation with ammonia and diesel. Figure 3 shows the test bench in its current state. A validated diesel operation forms the basis for the investigation of the dual-fuel concept. The test bench has a fully conditionable air system to best simulate the use of a turbocharger, diesel fuel system (free variation of injection pressures, times, temperatures & durations, common rail), cooling water & oil system as well as an open access research engine control unit with all possible degrees of freedom. The recently built ammonia fuel system is also variable in injection pressure & quantity. 1 cylinder, 4 stroke diesel External intake air conditioning Nominal speed Nominal power Bore Stroke Cylinder volume Compression ratio 2300 rpm 45 kW 110 mm 136 mm 1,29l 18:1 Fig. 3.  Test bench setup The ammonia used is stored in a gas bottle. To ensure safety when the gas bottle is open, it is located in a permanently vented gas bottle cabinet in the test bench room. The entire fuel system was also installed in this safety storage cabinet so that possible leaks do not contaminate the test bench room. A gas sensor in the exhaust air of the cabinet detects possible ammonia leaks. The safety technology also includes a sufficient powerful exhaust air system, additional gas sensors, a gas warning control unit, gas masks, an emergency shower and an oxygen respirator for emergencies. The procedures for changing the gas bottle, opening and closing the bottle or shutting down the test bench at the end of the working day are firmly regulated.
Investigation of An Ammonia Diesel Dual-Fuel …    29 3.2 Fuel System The fuel system is shown schematically in Fig. 4. The ammonia is taken in liquid form, processed and evaporated after measuring the mass flow with a Coriolis measurement system. At this point, the ammonia is still liquid and can, if necessary, be transported into the engine in this state. A pressure reducer regulates the evaporated gaseous ammonia to the desired pressure and a proportional valve/ special gas injectors control the mass of ammonia introduced into the engine intake pipe. Furthermore, there are several ball valves closed in the normal state, a safety valve, several purge ports for nitrogen and a throttle for safety empty of pipes with almost odorless release in the ambient air. The introduction of the gaseous ammonia into the engine intake is controlled by a proportional valve. This is to be replaced in the further course of the project by gas injectors, which realize a more realistic application. Fig. 4.  Ammonia fuel system Following successful setup and commissioning, the aim in the current stage of the project is to promote detailed knowledge about the combustion process with successively increase of the diesel substitution rates. In addition to the internal combustion processes, there is a focus on exhaust gas emissions, wear and lubricant effects as well. The latter is investigated in the associated lubricant laboratory of the LKV, which analyzes and evaluates oil samples using modern equipment and can very quickly detect signs of wear and change of lubrication characteristics.
30    T. Mante et al. For the further investigation, the simulation model of the project partner LOGE Deutschland GmbH will be validated with the measurement data from the SCE. This model is described below. First modelling results are discussed in the next section. 3.3 Simulation Model Stochastic Reactor Model The SRM is used in this study to model the combustion process. The SRM accounts for turbulence and inhomogeneity effects during the combustion. In the calculation, the combustion chamber homogeneity is represented by a statistical homogeneity and the physical quantities are described by a probability density function (pdf) [5–9]. In the SRM the mass in the reactor is divided stochastically into virtual packages called particles. Each particle has its own chemical composition, temperature, and mass, and can mix with other particles and exchange heat with the walls [7]. The transport Eq. 1 of the pdf contains on the left side the accumulation term and various source terms Qi (ψ). In the source terms, the piston work, convective heat transfer, chemical reactions, direct injection and vaporization are included. Therein, φ is a vector of random variables, ψ is its realization in the sample ψ -space and t is the time. The term on the right side P2 describes the molecular mixing due to turbulence and is in a non-closed form. A modified Euclidean Minimum Spanning Tree (EMST) mixing model is used to close the P2 term [10, 11], which accounts for locality in the particle mixing process for mixture fraction. As a result, only neighboring particles in the mixture fraction space can mix with each other.  ∂  ∂ Fφ (ψ, t) + Qi (ψ)Fφ (ψ, t) = P2 Fφ (ψ, t) ∂t ∂ψi (1) The SRM incorporates a phenomenological turbulence model to calculate the scalar mixing time τφ [10, 12]. The change of turbulent kinetic energy k in Eq. (2) is calculated including on the right side, the first term for density changes, the second term for dissipation ε, the third term for squish flow, the fourth term for direct injection and the last term for swirl flow.   2  3 dV k k 2 dk sq  cyl  = − · − ε + Csq · · dϕ 3 Vcyl dt dt TDC<ϕ<EVO dkinj + Csw · + Cinj · dt  3 cm  1 · l 6·n (2) In that equation, ϕ is the crank angle, Vcyl is the instantaneous cylinder volume, t is the time in seconds, ksq is the turbulent kinetic energy from the squish flow, kinj is the turbulent kinetic energy from the direct injection, cm is the mean piston speed, l is the integral length scale and n is the engine speed. The dissipation in Eq. (3) is derived from the turbulent kinetic energy and length scale l , which is based on the instantaneous cylinder volume. k 3/2 l Finally, the scalar mixing time is calculated by Eq. (4): ε = Cdiss · (3)
Investigation of An Ammonia Diesel Dual-Fuel …    31 τφ = Cτ · k ε (4) The factors Cdiss, Csq, Cinj, Csw and Cτ need to be calibrated for the respective engine. The calibration was done using LOGEengine expert system with the experimental pressure trace of the operating point with pure diesel as target. As good match between experimental pressure trace and model prediction was reached (Fig. 8). Major parameters for the SRM modelling are listed in the table below (Table 1): Table 1.  SRM modelling parameters Parameters Number of particles Time step size [°CA] Number of cycles Mixing time coefficient CΦ Dissipation factor Cε Particle mixing model Heat transfer model Turbulence model Start of simulation End of simulation Value 200 0.5 5 14.29 1 Enthalpy conditioned EMST [6] Woschni K–ε model [6] Intake valve closing (IVC) Exhaust valve opening (EVO) Chemistry model The commercial diesel used in the experiment was modelled by a 3 component surrogate composed of 17.2 vol% 1-Methylnapathalene to represent the aromatic fraction, 76.1% n-Decane to represent to n-alkane fraction and 6.7 vol% methyl decanoate to model the FAME content. A comparison of the properties of the commercial diesel and the surrogate is shown in the table below: Table 2.  Comparison of commercial diesel & surrogate Property Density at 20 °C [kg/m3] Lower heating value [MJ/kg] Lower heating value [MJ/l] Mean molecular weight [g/Mol] C/H/O ratio (atomic) Mass% C/H/O Cetane number FAME % (v/v) Commercial EN 590 835.7 42.71 38.08 192 13.7/22.3/0.09 85.94/13.33/0.74 52.9 6.7 Surrogate 786.1 42.53 33.5 140 10.26/19.32/0.12 85.35/13.37/1.28 52.9 6.7
32    T. Mante et al. The chemistry model for the fuel oxidation and emission formation is based on the current LOGEfuel reaction model. The model for methane and methyl decanoate was adapted from [15, 16] and updated for better match with experiments for ignition delay time and emission formation. A comparison of predicted and measured ignition delay time for n-Decane is shown in Fig. 5. The sub-models for ammonia oxidation and NOx chemistry are adapted from [14]. The detailed reaction mechanism consisted of 1307 species and was than reduced to 491 species using the technique described in [16, 17] to reduce computation time. Fig. 5.  Comparison of predicted and measured ignition delay times of n-Decane/air mixtures in shock tubes at different pressures 4 First Simulation & Measurement Results In the course of the project, as said, the project partner LOGE will develop a combustion model for dual-fuel combustion, based on a stochastic reactor model, with diesel and ammonia and validate it on the basis of the measured data from the LKV test engine in addition to published experiments for ignition delay time, flame speed and speciation. In the following, both initial simulation and measurement results and thus detailed validation data will be evaluated. In contrast to the simulation, there are limits to the test bench and measurement operation, e.g. due to emission values or cylinder peak pressures.
Investigation of An Ammonia Diesel Dual-Fuel …    33 4.1 Adding Gaseous Ammonia & Investigations on the Influence of Early Diesel Pilot Injection on Ammonia Combustion The first aspect to be investigated is the addition of ammonia to a diesel-only operating point. For the analysis, a medium load engine operating point was selected, which is shown below in Table 3. These parameters are constant during the measurement. Table 3.  Reference operating point “diesel only” (PI… pilot injection, MI… main injection) Engine speed 1500 rpm Intake air pressure 1.91 bar λ = 2.0 Diesel rail pressure 900 bar PI 1 20°CA BTD 0.2 ms MI 1 14°CA BTD 1.6 ms Figure 6 shows the cylinder pressure and heat release rate for this operating point in pure diesel mode. Based from this, gaseous ammonia is added to the intake air (approx. 3.7 kg/h, which corresponds to an energy share of the total combustion of approx. 25%). This results in an increase of engine torque from 115 Nm to 145 Nm. The increased amount of fuel can also be seen in the cylinder pressure & heat release rate. Due to ammonia slip caused by valve overlap and incomplete ammonia combustion, NH3 emissions of 3270 ppm can be detected in the exhaust gas. To reduce the ammonia emission, another diesel pilot injection is added at 60°CA BTD (0.2 ms, yellow graph). This operating point is shown in Table 4. Table 4.   Operating point with early diesel pilot injection (also for comparison to the simulation later on) Engine speed 1500 rpm Intake air pressure 1.91 bar Diesel rail pressure 900 bar Early PI PI 1 MI 1 60°CA BTD 20°CA BTD 14°CA BTD 0.2 ms 0.2 ms 1.6 ms The injection duration is very short to inject only a small amount of diesel within the combustion chamber in order to get a high premixed diesel share that initialize the ignition of the homogeneous ammonia/air mixture in the combustion chamber. Due to the very early diesel pilot injection a higher volume of the combustion chamber is captured with diesel ignition energy which results in a more efficient ignition and combustion behavior of the ammonia. Compared to the engine operation without the early pilot injection the ammonia concentration in the exhaust is significantly reduced to 2500 ppm (−23%). For the further series of measurements, the early pilot injection is consequently used to reduce the ammonia slip. Furthermore, a slight increase of the diesel amount in the early pre-injection also has a positive effect on reducing NH3 emissions and is going to be investigated in the near future.
34    T. Mante et al. Fig. 6.  Addition of ammonia and impact of an early diesel pilot The operating point with the early diesel pilot injection and the additional ammonia (yellow graph in Fig. 6) has been chosen for the first comparison of model prediction with experiments. The second point used here is the same point without the addition of ammonia (Table 4). Therefore, they only differ in the amount of premixed NH3. The base line case fueled only by diesel injection was used for training of the turbulence model. The second point was used to test the model prediction for addition of premixed ammonia. The ammonia was assumed to be perfectly premixed with the air after intake valve closes. For both cases no EGR (there is probably a small amount of internal EGR) and dry air was assumed. Table 5 compares the measured peak pressure, max. rate of heat release and raw emissions with the model prediction. No tuning of the combustion model was performed to match the emissions. For both operating points the peak pressure is well matched (see Fig. 7). Also, the trend that additional ammonia increases the peak ROHR is matched, though a difference in absolute numbers is seen due to discretization in the model of 0.5 °CA. It was found that the model predicts a complete consumption of the ammonia while in the experiments an ammonia slip of 2457 ppm was observed (about 5% of ammonia trapped at intake valve closes). For major emissions such as O2 and H2O the trends are also well kept while absolute numbers differ from the experiment which will be discussed at the end of this section. The predicted formation of NO and NO2 are remarkable close to the measured values considering the NO model tuning was done. Model and experiment predict a reduction of NOX emissions for the operating point with additional NH3, even though the mean in cylinder temperature is much higher (about 200 K at exhaust valve opening). Like the experiment the model predicts a significant amount of N2O at exhaust valve opens. It can be seen in Fig. 7 that engine out emissions of N2O are a result of formation and reduction process. Formation is dominant until the peak pressure is reached, and all fuel is consumed, followed by a rapid consumption to about 20% of its peak value. The underlying chemistry will be studied in a later publication.
Investigation of An Ammonia Diesel Dual-Fuel …    35 Fig. 7.  Comparison in pressure curve and N2O emissions for simulation and experiment (experimental N2O represented as dot) As mentioned before these are the first modelling attempts for diesel/ammonia dual-fuel combustion in this project and there is a discrepancy for the major species which is higher than the expected experimental uncertainty of the measurement equipment. We expect that the model assumption of dry air as well as no EGR play an important role for underestimation of major species. In addition, the complete consumption of ammonia directly leads to a higher water content. The reason for the complete NH3 consumption in the model is currently under investigation. Based on the now available experiments the combustion chemistry—in particular the ammonia/ hydrocarbon interaction—will be revised. We also will study in which extend the crevice volume needs to be considered to capture the ammonia emissions (see discussions in [13]). Table 5.  Comparison of experimental & simulation results pmax ROHR O2 NH3 NO NO2 N2O CO H2O bar J/°CA ppm ppm ppm ppm ppm ppm ppm Diesel only + early pilot Exp 149,91 136,46 106,088 0 1985 86 0 125 76,891 Sim 150,94 165,26 102,187 0 2504 74 0 13 64,266 Diesel only + early pilot + ammonia Exp Sim 165,54 167,82 190,71 234,61 60,250 57,409 2457 0 1757 2449 37 46 60 40 235 1 131,940 131,633
36    T. Mante et al. 4.2 Investigation of Substitution Potential To give an outlook to the substitution potential, a new operating point is defined. This differs by reducing to one early pilot-injection and one main injection of diesel. The injection durations have also been adjusted to the operation point before. The injection and engine parameters are listed in Table 6. Table 6.  Starting operating point for substitution investigation Engine speed 1500 rpm Intake air pressure 1.91 bar Diesel rail pressure 900 bar Early PI 60 °CA BTD 0.4 ms MI 1 10 °CA BTD 1.2 ms Starting from pure diesel operation, ammonia is now injected to the intake air. With increasing amount of ammonia, the diesel amount is being reduced for constant total fuel energy in the combustion chamber. Figure 8 shows the burning duration and NH3 concentration in the exhaust gas over the substitution rate of diesel. It can be derived that an increase of ammonia amount in the combustion chamber results in an increased ammonia slip. At the same time, the burning duration is decreasing, which indicates an increased burning speed for higher ammonia mass in the combustion chamber. Fig. 8.  Diesel substitution and the effects on torque and ammonia slip Figure 9 shows the cylinder pressure curves and corresponding rate of heat release calculated by an in-house thermodynamic analysis tool. Compared to the pure diesel mode a substitution rate of 10% leads to an increased ignition delay with lower heat release rates before the main injection event. These effects are even stronger at 30% substitution rate. This leads to the assumption, that the lower reactivity and lower oxygen partial pressure has negative effect on the pilot injection combustion, which should be considered when dealing with higher substitution rates by adjusting pilot injection duration and timing.
Investigation of An Ammonia Diesel Dual-Fuel …    37 After the first pilot injection combustion, there is a second event of moderate heat release rate right before the main injection event. This event is still under investigation and is believed to result from unburned fuel from the pilot injection, which undergoes a different evaporation process (maybe interaction with the piston or liner). The influence of the ammonia on the main combustion event is rather complex. There is a slight increase in ignition delay with increasing substitution rate, which can be explained due to the different in-cylinder conditions due to the pilot injection combustion. There is a slight increase in the maximum heat release rate at 30% substitution rate. This behavior shows the complex nature of ammonia-diesel dualfuel combustion modes and underlines the need for further investigations. The effect of the increased burning speed can also be seen in the sum heat release in Fig. 9, where the increase of the heat release at 30% substitution rate starts the latest, but increases faster than the points with less ammonia. Fig. 9.  Effect of increasing substitution rates on cylinder pressure, rate of heat release and cumulated heat release
38    T. Mante et al. From this point with 30% energetic ammonia in the combustion, different parameters (e.g. share of diesel amount, diesel injection timing, and lambda) will be variated to reduce ammonia slip and improve the combustion process. Then, the energetic ammonia amount can be increased further and the potential of the dual-fuel combustion process can be clearly seen. 5 Summary To meet the challenge of climate change, the use of alternative fuels is essential. This also includes existing fleets of ship with operating lives of more than 25 years. Here, retrofit concepts can make a significant contribution to achieve the climate targets. Using ammonia, a carbon-free energy source, requires well-designed safety technology, a reliable fuel system, and efficient combustion. These challenges are high, but if successfully implemented, a large part of the maritime industry can thus capitalize on them and paves the way for carbon-free shipping. The installation of the ammonia fuel system at LKV and the initial investigations of a dual-fuel concept on a SCE have shown that the challenges can be met and that ammonia is a viable candidate as a future fuel. Furthermore, the combustion modelling of LOGE Deutschland GmbH allows this novel combustion process to be investigated and developed beyond the limits of experimental possibilities. The greatest challenges in the use of ammonia as fuel are N2O formation, ammonia slip and new challenges in the areas of exhaust gas aftertreatment due to very different gas composition as well as durability & corrosion. References 1. Grindberg et al.: Stickstoffbasierte Kraftstoffe: eine „Power-to-Fuel-to-Power“-Analyse, vol. 128. https://onlinelibrary.wiley.com/doi/10.1002/ange.201510618 (2016) 2. AirLiquide: Sicherheitsdatenblatt Ammoniak (2019) 3. Gupta B. R.: Hydrogen Fuel Production, Transport and Storage. CRC Press, Boca Raton (2008) 4. Theile, M., Drescher, M., Reska, M., Dahms, F., Swiderski, E.: Development of a GHGneutral combustion concept exemplified by methanol. In: 7th Rostock Large Engine Symposium, Rostock, Germany (2022) 5. Pasternak, M.: Simulation of the diesel engine combustion process using the stochastic reactor model. BTU Cottbus, Senftenberg PhD Thesis (2016) 6. Kraft, M.: Stochastic modeling of turbulent reacting flow in chemical engineering. VDI Verlag, Düsseldorf (1998) 7. Tuner, M.: Stochastic reactor models for engine simulations. Lund: PhD Thesis (2008) 8. Pope, S.B.: Pdf methods for turbulent reactive flows. Prog. Energy Combust. Sci. 11(2), 119–192 (1985) 9. Harworth, D.: Progress in probability density function methods for turbulent reacting flows. Prog. Energy Combust. Sci. 36(2), 168–259 (2010) 10. Franken, T., Sommerhoff, A., Willems, W., Matrisciano, A., et al.: Advanced predictive diesel combustion simulation using turbulence model and stochastic reactor model. SAE Technical Paper 2017-01-0516. https://doi.org/10.4271/2017-01-0516 (2017)
Investigation of An Ammonia Diesel Dual-Fuel …    39 11. Bernard, G., Scaife, M., Bhave, A., Ooi, D., et al.: Application of the SRM engine suite over the entire load speedoperation of a U.S. EPA tier 4 capable IC engine. SAE Technical Paper 2016-01-0571. https://doi.org/10.4271/2016-01-0571 (2016) 12. Kozuch, P.: Phenomenological model for a combined nitric oxide and soot emission calculation in DI diesel engines. PhD Thesis, Stuttgart (2004) 13. Franken, T., Matrisciano, A., Sari, R., Fogué Robles, Á., et al.: Modeling of reactivity controlled compression ignition combustion using a stochastic reactor model coupled with detailed chemistry. SAE Technical Paper 2021-24-0014. https://doi.org/10.4271/2021-240014 (2021) 14. Shrestha, K.P., Giri, B.R., Elbaz, A.M., Issayev, G., Roberts, W.L., Seidel, L., Maus, F.: A detailed chemical insights into the kinetics of diethyl ether enhancing ammonia combustion and the importance of NOx recycling mechanism. A Farooq Fuel Communications (2022) 15. Wang, X.: Kinetic mechanism of surrogates for biodiesel. Ph.D. Thesis Cottbus (2018) 16. Matrisciano, A., Seidel, L., Mauss, F.: An a priori thermodynamic data analysis based chemical lumping method for the reduction of large and multi-component chemical kinetic mechanisms. Int. J. Chem. Kinet. 54, 523–540 (2022) 17. Seidel, L., Netzer, C., Hilbig, M., Mauss, F., Klauer, C., Pasternak, M., Matrisciano, A.: Systematic reduction of detailed chemical reaction mechanisms for engine applications. J. Eng. Gas Turbines Power 139(9), 091701 (2017)
H2 ICE DI Multicylinder Engine Tests for Thermodynamics and Component Development Simon Schneider1(*), Christian Trabold2, Thomas Friedrich1, Florian Mayer1, Fabian Weller1, and Roman Stiehl1 1 MAHLE International GmbH, Stuttgart, Germany {simon.schneider,thomas.friedrich,florian.b.mayer, fabian.weller,roman.stiehl}@mahle.com 2 MAHLE GmbH, Stuttgart, Germany christian.trabold@mahle.com Abstract.  For commercial vehicles, the hydrogen internal combustion engine (H2 ICE) is a propulsion variant that enables fast defossilisation in the HD vehicle segment. MAHLE is intensively investigating this kind of engines and develops components for this application. A research engine was built and operated with a combustion system with direct injection of hydrogen (H2 ICE DI) whereas experience is used from operating the same aggregate in port fuel injection configuration (H2 ICE PFI) in the preceding project. The results demonstrate the potentials of the DI combustion system in terms of engine load and efficiency. Furthermore, a direct comparison to the PFI combustion system is done. Boundary condition is the realization on a typical commercial vehicle engine and the use of components that were developed for a future series use of H2 ICE engines. MAHLE deducts important insight related to requirements for the components from these investigations and uses the opportunity to test further subsystems for this application, e.g. in the field of crank case ventilation. Keywords:  Hydrogen combustion engine · Hydrogen direct injection · CO2 neutral truck 1 Hydrogen Combustion Systems for Trucks and Configuration of the Research Engine In order to achieve climate neutral transportation, fossil fuels have to be replaced by renewable energy carriers. Hydrogen is a very promising candidate for applications in which high energy density and fast refueling is required. Onboard the vehicle, it can be used in a hydrogen fuel cell or in an internal combustion engine. Both technologies are currently investigated and developed by many companies. DAF [1], MAN [2] and Cummins [3] are developing ICE engines and vehicles for on- and offroad © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 40–52, 2023. https://doi.org/10.1007/978-3-658-41477-1_4
H2 ICE DI multicylinder engine tests …    41 applications. DEUTZ has announced the SOP of their H2 ICE focused on electricity generation in 2024 [4]. In parallel, suppliers like BOSCH are investigating the technology to understand the system and its impact on their components [5]. With the same motivation, MAHLE has converted a 13l HD Diesel engine to be operated on hydrogen in our in-house test facilities. For this engine, a dedicated Power Cell Unit (PCU) was developed [6] and the engine was successfully operated with Port Fuel Injection (PFI) [7]. As a next development stage, the engine was further adapted to be operated with Direct Injection (DI). This mitigates the risk of backfire and provides higher air flow rates, giving the potential for higher BMEP and efficiency. However, due to the shorter time between injection and combustion, proper mixture formation is crucial [8]. The setup and the results of the engine test at MAHLE are presented in this paper. 2 Design of DI Research Engine and Comparison to PFI Setup 2.1 DI Configuration and Conceptual Design Choices The existing MAHLE H2 ICE research engine was adapted to enable DI combustion. The cylinder head now contains an insert with central injector position and near central spark plug position at a slight angle and a distance of approx. 15 mm to the center. This promises a maximum of symmetry for mixture preparation and combustion. CFD simulations for several operating points were performed to ensure sufficient mixture quality. Spark plugs identical to those from the PFI testing were used with cold rating and a J electrode. The configuration of the gas path was kept identical to the PFI setup. Single runners for each cylinder are connected to a plenum. The charge motion of the Fig. 1.  MAHLE H2 ICE research engine – view from exhaust side on valvetrain cover
42    S. Schneider et al. engine is very low – there is no swirl and no tumble, identical to the Diesel baseline engine. Some charge motion is generated from the fuel injection itself, depending on injection timing. An impression of the engine is given in Fig. 1. 2.2 MAHLE Hydrogen Optimized Piston and Ring Set The piston bowl shape was kept from the PFI testing. The top land was modified to reduce gap volumes in this region. Low blow-by and low lube oil consumption are main challenges for the power cell unit of hydrogen combustion engines. Thus, the piston ring set is further improved compared to the setup presented in [7]. An optimization loop was performed with data from the previous run and the measures were integrated to the design. The DI ring set proved to enable even lower blow-by flows. The configuration of the combustion chamber is shown in Fig. 2. Fig. 2.  Combustion chamber configuration: DI with central injector position 2.3 Scavenged Crank Case Ventilation The scavenging crank case ventilation with the MAHLE high pressure impactor system was applied in an identical way as described in [7]. Besides keeping hydrogen concentrations under control, the scavenging ventilation also lowers the moisture content within the crank case. This is important to avoid oil dilution and corrosion, especially at engine operation at low loads and low ambient temperatures. The dew point temperature at which condensation starts is shifted by 20 °C if scavenging is applied.
H2 ICE DI multicylinder engine tests …    43 3 Testing Results and Potential of H2 ICE DI Combustion 3.1 Engine Power Compared: DI Setup vs. PFI Setup of 2021 With the research engine, extensive testing was performed. The main targets were verification and validation of the components applied as well as the investigation of the potential of DI combustion especially in comparison to the PFI baseline. When operating the H2 ICE DI research test engine, two main modes of the combustion systems can be distinguished by the choice of the injection timing (Fig. 3). Pressure trace / bar Injection PFI mode 0 180 Injection DI mode 360 540 Crank angle / deg a TDCF Valve lift, Injection / - • Injection during the intake stroke, so called “PFI Mode” • Injection during the compression stroke, so called “DI Mode” 720 Fig. 3.  PFI mode and DI mode injection timing schematic The PFI mode has as an advantageous longer time for mixture preparation. The DI mode on the other hand enables higher volumetric efficiency, as the fuel is injected into the cylinder after intake valve closing (IVC). This enables higher air-fuel ratios with benefits for raw NOX emissions. A prerequisite for this mode is a sufficiently high injection flow rate and resulting short injection duration, to complete injection before the cylinder pressure is too high and to leave sufficient time for mixture preparation. The engine load achieved with DI in an initial power curve is shown in Fig. 4. With the DI setup, a slightly lower power curve was achieved, ranging from 15.5 bar BMEP at 1800 rpm to 18 bar BMEP at 1166 rpm. The difference to the PFI setup was in the range of 1.0 to 2.5 bar BMEP. Limiting factors towards higher load were different depending on the combustion phasing. Knocking prohibited higher loads at early combustion phasing. For late combustion phasing misfires and combustion instabilities were the limiting factors. Similar results have also been shown by Bunce et al. [9].
44    S. Schneider et al. 25 20.5 bar 18.0 bar 20 BMEP / bar PFI setup (2021) 18.5 bar 17.0 bar Injectors in intake port 16.5 bar 15.5 bar Intake stroke injection With HP EGR A85 15 A75 B75 C75 A50 B50 C50 DI setup (2022) 10 Injectors in DI position Intake stroke injection & compression stroke injection 5 A25 0 1000 B25 1200 C25 1400 1600 Speed / rpm With HP EGR or wastegate 1800 2000 Fig. 4.  Power curve in previous project and initial power curve in current setup The engine was operated across the map and the performance of the thermodynamics was studied in detail. Fig. 5 shows a map of the selected results in PFI mode. It can be seen that efficiency values >44% can be achieved with well controlled NOX emissions. Effective efficiency etae / % 20 NOX spec. / g/kWh 43 20 1.5 15 41 43 10 42 40 41 40 39 39 36 5 1200 1400 1600 Speed / rpm 36 1800 BMEP / bar BMEP / bar 42 15 10 1.1 1.50 0.7 1.10 0.70 0.30 0.3 0.04 0.04 5 1200 1400 1600 Speed / rpm 1800 Fig. 5.  Engine maps for efficiency and NOX emissions in PFI mode of the DI engine 3.2 Analysis of PFI and DI Mode Fig. 6 shows a comparison of the two modes at 1166 rpm and 10 bar BMEP. The airfuel ratio is 2.38 for the PFI mode and 2.81 for the DI mode, each being the maximum
H2 ICE DI multicylinder engine tests …    45 air mass flow of this operating point. The air-fuel ratio benefit of DI mode comes with the disadvantage of increased pumping work (not shown in the diagram). The test was chosen to understand the potential of each mode without controlling the air mass flow by throttle, wastegate, or EGR. Therefore the different air-fuel ratios as results of the different operation modes were accepted. A discussion of the advantages of throttle, wastegate and EGR can be found in Sect. 3.3. A50 Var MFB50 Lambda const PFI Mode A50 Var MFB50 Lambda const DI Mode burn duration 10-90 % (INDI) covariance pmi avr. (INDI) etae opt. COV PMI - avr / % BD1090 / °KW 34 30 26 22 18 NOX spec / g/kWh 46 etai,HD / % 3.0 misfire 1.5 0.0 indicated efficiency high press. cycle 44 42 40 misfire 4.5 0 5 10 15 MFB50 / °CA 20 25 1.2 NOX emissions engine out 0.9 0.6 0.3 0.0 0 5 10 15 20 25 MFB50 / °CA Fig. 6.  A50 ignition timing variation at constant air-fuel ratio: DI mode (Lambda 2.81) vs. PFI mode (Lambda 2.38). The range of optimum effective efficiency is marked Both modes reach best efficiency at early MFB 50 timings of 4–5 °CA aTDCf. Indicated efficiency of the DI mode with max. 46% is slightly above those of PFI mode (45.5%) despite of the big difference in air-fuel ratio. NOX emissions are acceptable for both modes, but better for DI mode with 0.2 g/kWh at optimum efficiency compared to 0.75 g/kWh for PFI mode at same timing. This is mainly caused by the leaner operation of the DI mode, which reduces NOX emissions. In
46    S. Schneider et al. contrast, the PFI mode has shorter burn duration of approx. 20 °CA compared to DI mode with 23 °CA which is a result of lower air-fuel ratio. When phasing combustion towards late, combustion duration increases and efficiency drops as expected for both modes. However, the late limit for MFB50 is later for the DI mode. The reason for this couldn’t be perfectly clarified. Instability increases, which is expressed in terms of the covariance of IMEP in our data, until cyclic variations increase so that the operating point isn’t stable anymore. The early MFB50 limit is defined by a steep increase in knock tendency for each mode. Tests show that the knock limit of the DI mode is at a higher Lambda value than that of PFI mode. This comes from a higher amount of inhomogeneities coming from shorter mixing time. Burn rates and split of losses From Fig. 6, the two points with optimum efficiency are investigated via thermodynamic analysis. Both are at MFB of 5° aTDCf and have an effective efficiency from measured data of 42.3% each. Comparison of burn rates (Fig. 7) shows typical curves with fast burn-off matching the duration known from the Indiset. Normalized Burn Rate / 1/°CA 0.05 PFI mode, λ = 2.38, BD1090 = 19.7°CA DI mode, λ = 2.81, BD1090 = 23.0°CA 0.04 N = 1166 rpm BMEP = 10 bar MFB50 = 5°CA 0.03 0.02 0.01 0.00 -30 0 30 60 90 Crank Angle / °CA Fig. 7.  Burn rates from optimum points of A50 ignition timing variation For closer comparison of the operating points, a split of losses within the pressure trace analysis is performed (Fig. 8). DI mode has a slight advantage for real gas composition as only air is inducted. PFI mode has an advantage from the shorter burn duration from lower lambda. In contrast, DI mode has a similarly big advantage from
H2 ICE DI multicylinder engine tests …    47 better fluid properties of the leaner gas. Finally, PFI mode has an advantage as its gas exchange work is lower due to the turbocharger configuration. In sum, the split of losses confirms that both operating points have identical efficiency. DIFF of losses / % DI mode benefit Lambda difference: higher 1.0% 0.5% Sum Real Gas Exchange Ideal Gas Exchange Compression Expansion Heat Transfer Real Fluid Properties Friction Overall εeff diff. -0.16% Gas exchange work: impact of lower air mass Real Burn Rate Incomplete Combustion Real Composition -1.0% Lambda impact: burn duration 3 CA shorter Combustion Phasing -0.5% PFI mode benefit 0.0% Fig. 8.  Split of losses difference of optimum points of A50 ignition timing variation Comparison of the advantages of the two modes To better demonstrate the effects of both combustion modes, Fig. 9 shows a variation of start of injection (SOI) for typical timings of PFI mode and DI mode at operating point 1166 rpm, 15 bar BMEP at const MFB50 of 11 °CA. The COV PMI plot shows that both modes can be calibrated for stable operation. In PFI mode, SOI can be chosen rather soon after intake valve opening. Best performance for this mode is reached with SOI in first third of the intake stroke. Injecting later, with SOI later than 300 °CA bTDCf, leads to stratification effects indicated by a strong NOX emission increase. Possible injections timings in DI mode start with intake valve closing and can be retarded until the cylinder pressure increases too much to inject properly. With the switch to DI mode Lambda increases by around 0.4 points (not shown). For DI mode with early SOI, the combustion is slowed down due to the higher Lambda compared to PFI mode. The later the injection is done, the more the combustion is sped up, until the burn duration reaches levels below those of the PFI mode. This can be explained with turbulence from the injection. The later it takes place, the more turbulence is being preserved until the combustion starts and is able to support the flame propagation.
48    S. Schneider et al. A75 SOI Var PFI mode A75 SOI Var DI mode burn duration 10-90 % (INDI) 3.0 COV PMI - avr / % BD1090 / °KW 22 20 18 covariance pmi avr. (INDI) 2.5 2.0 1.5 1.0 NOX spec / g/kWh etai,HD / % indicated efficiency high pressure cycle 45 44 360 300 180 120 Start of inj. / °CA bTDCf NOX emissions engine out 5 4 3 2 1 0 360 300 180 120 Start of inj. / °CA bTDCf Fig. 9.  A75 SOI var at const. MFB50 DI mode vs. PFI mode This effect can also be seen in the combustion efficiency of DI mode. It starts at an identical level as in PFI mode despite higher Lambda and rises by 1% point (etai,HD = 45.5% compared to 44.5%) with phasing SOI late. This sort of directly influencing combustion via the injection is only applicable in DI mode. DI mode improves NOX emissions down to levels of 0.4–0.5 g/kWh at the same time in this test. Both modes have strengths that can be summed up as shown in Fig. 10. PFI mode DI mode Better homogenization from longer mixing time Higher volumetric efficiency enables leaner lambda Charge motion benefit from fuel injection Option for combustion improvement at perfect choice of timing and pressure Lower gas exchange work Robust calibration - wide range of timings and injection pressures Fig. 10.  Benefits of each mode of the DI combustion system
H2 ICE DI multicylinder engine tests …    49 Comparison of DI operation to PFI Setup performance Compared to PFI operation, the DI operation in PFI mode is rather similar in terms of characteristics and performance. This is confirmed at an EGR sweep at operating point A75, Fig. 11. The Covariance of PMI is lowest for PFI as it is the benchmark for perfect mixing of the cylinder charge and slightly higher for DI setup in PFI mode. Boost pressure and exhaust gas pressure are very similar but slightly higher for DI setup in PFI mode. Flow losses at the intake valves are a little lower as only air is transported and so the pressure ratio of the EGR shifts – and the EGR flow slightly increases as well. Burn duration is identical at low EGR and follows the same trend, with slightly longer duration for DI setup PFI mode at high EGR as the EGR rates are slightly higher as described before. Overall, the DI setup in PFI mode is very similar in characteristics of the combustion compared to the PFI setup. PFI Setup A75 HP EGR var. DI Setup PFI mode A75 HP EGR var. 3 COV PMI - avr / % BD1090 / °KW burn duration 10-90 % (INDI) 22 20 18 Increasing EGR rate 1 1300 P31 / mbar P_LL_5 / mbar 1800 1700 1600 2.2 air-fuel ratio / - 2 0 air pressure upstream cyl. 5 (rel.) 2.0 covariance pmi avr. (INDI) 2.4 exhaust gas pressure upstream turbine cyl. 4-6 (rel.) 1200 1100 1000 2.0 2.2 air-fuel ratio / - Fig. 11.  A75 EGR variation PFI setup compared to DI setup in PFI mode 2.4
50    S. Schneider et al. 3.3 Lambda Control As described before, a measure is needed to control the air-fuel ratio to a certain value across the engine map. At the research engine, three of those were investigated: cooled high pressure exhaust gas recirculation (HP EGR), turbocharger wastegate (WG) and use of a throttle flap. Below, the comparison of HP EGR and wastegate as the two most favorable options is discussed in detail. HP EGR vs. wastegate air-fuel ratio control In Fig. 12, testing results are shown for a test comparing HP EGR and wastegate operation at the 1166 rpm, 10 bar BMEP operating point discussed before. Both methods of air-fuel ratio control are operated in DI mode at start of injection of 180 °CA bTDCf and a const. MFB50 timing of 8 °CA aTDCf. As can be seen, combustion efficiency is best without wastegate or EGR. However, both measures reduce pumping work with increasing setting, which leads to best overall efficiency at mid setting of EGR and at moderate settings of the wastegate. The DI mode wastegate variation reaches knock limit at approx. Lambda 2.2. Near this limit, there is a steep increase in NOX emissions, so that only a small application window can be utilized. The DI mode high pressure EGR variation expands lambda range down to Lambda <1.7. The EGR operation shows 1 to 5 °CA slower burn duration compared to WG but nevertheless has higher combustion efficiency etai,HD. In numbers, this is 44.8% compared to 44.1% at Lambda 2.35. The NOX emissions are well controlled for the HP EGR variant and stay near 1 g/kWh even at the most extreme EGR setting. This results in a wider calibration window for the EGR variant at Lambda 2.0–2.4 with NOX values of 0.55–0.2 g/kWh. Stability is good for both variants over the sweep. Summing up, HP EGR shows clear advantages over wastegate as means of airfuel ratio control. It allows for a wider applicable Lambda range at lower NOX levels, while even providing a small fuel consumption advantage. Influence of wall heat loss in DI combustion The data in Fig. 12 shows a trend which appears counter-intuitive at first sight: As expected, the burn duration decreased with the air-fuel ratio. However, this is not translated into a benefit in efficiency. In contrast, the EGR operating points that burn slower have better efficiency. This can be explained by two effects. Indicators like energy balance and component temperatures show that an increase in wall heat loss could occur under these conditions. This would reduce the benefit of the faster combustion. However, a more detailed analysis is necessary to confirm this effect. Another additional explanation is the influence of the EGR. It keeps the gas mass flow high, even at low Lambdas, due to the recirculation of inert exhaust gas. This keeps exhaust gas temperatures moderate and avoids high component temperatures at low air mass flow conditions as with the wastegate. This classical EGR effect is an important benefit for this combustion system at high engine loads. It makes EGR the preferred method to control the air-fuel ratio, in interaction with the turbocharger.
H2 ICE DI multicylinder engine tests …    51 A50 Var WG DI Mode A50 Var EGR DI Mode covariance pmi avr. (INDI) COV PMI - avr / % burn duration 10-90 % (INDI) BD1090 / °KW 24 21 18 etai,HD / % 46 1.5 1.2 indicated efficiency high pressure cycle NOX emissions engine out NOX spec / g/kWh 15 1.8 45 44 43 3 2 1 0 etae / % 43 pmi LW avr. (INDI) Baseline 42 41 40 1.7 Increasing EGR and WG 2.1 2.5 air-fuel ratio / - 2.9 pmi LW - avr / bar brake efficiency -0.1 -0.2 -0.3 1.7 2.1 2.5 air-fuel ratio / - 2.9 Fig. 12.  A50 wastegate var DI mode vs. EGR var DI mode at const. MFB50 timing 4 Summary and Conclusion The H2 DI combustion engine shows comparable performance to the PFI engine. Both modes of the DI combustion system – “PFI mode” and “DI mode” – reach similar performance in terms of efficiency and emissions in the stationary testing of this project. The combustion system is sensitive on proper adjustment of the preferred Lambda range, raising the requirement of a variable element at the turbocharger. The second critical item for the combustion is quality of homogenization that has to be ensured in each mode.
52    S. Schneider et al. In order to achieve good dynamics in transient operation, the higher Lambda of the DI mode and the ability to use and switch between both modes seem essential, as explained e.g. in [2]. Limiting to reaching higher load is combustion anomalies and increase of covariance which narrows the application window of calibration parameters. On the lower limit of Lambda, knocking is the limit. HP EGR showed to be stabilizing here and helps to widen the range. On the lean side, inhomogeneity leads to limited range compared to perfectly mixed cylinder charge as seen in PFI setup operation. To overcome this, a certain amount of charge motion is beneficial to enable more stable operation. As the engine investigated in this work does not have any significant charge motion, it is expected that higher loads can be reached with other engines. An additional enabler for better homogenization in DI mode is the optimization of the injection flow pattern, which promises advances in terms of efficiency and load. Optimizations on the ignition side, e.g. pre-chamber ignition like MAHLE Jet Ignition, widen the lean burn area to enable a good calibration over the whole engine map. As demonstrated by MAHLE Powertrain, this is a strong measure to increase the combustion stability in a lean-burn H2 ICE [9]. Acknowledgements. We would like to thank Robert BOSCH GmbH for providing the injectors for this testing campaign. References 1. DAF Trucks N. V.: Hydrogen. DAF Trucks. (n. d.). https://www.daf.com/en/about-daf/ sustainability/alternative-fuels-and-drivelines/hydrogen. Accessed 5 Oct 2022. 2. Walter, L., Sommermann, A., Hyna, D., et al.: The H2 combustion engine – the forerunner of a zero emissions future. In: 42nd International Vienna Motor Symposium, Vienna (2021) 3. Cummins Inc.: Cummins to reveal zero-carbon H2-ICE concept truck at IAA expo powered by the B6.7H hydrogen engine. [press release]. https://www.cummins.com/news/ releases/2022/09/13/cummins-reveal-zero-carbon-h2-ice-concept-truck-iaa-expo-poweredb67h (2022, 13. September) 4. DEUTZ AG.: Der Wasserstoffmotor von DEUTZ ist reif für den Markt. [Press release]. https://www.deutz.com/media/pressemitteilungen/der-wasserstoffmotor-von-deutz-ist-reiffuer-den-markt (2021, August 21) 5. Kufferath, A., Schünemann, E., Krüger, M., et al.: H2 ICE powertrains for future on-road mobility. In: 42nd International Vienna Motor Symposium, Vienna (2021) 6. Marlok, H., Trabold, C., Puck, A.: Engine Component Development for H2 Combustion Engines, Heavy-Duty, On- and Off-Highway Engines. Rostock (2021) 7. Rieger, D., Mayer, F., Weller, F., Schneider, S., Stiehl, R.: Experimental investigation of a hydrogen powered heavy-duty truck engine. In: Internationaler Motorenkongress, BadenBaden (2022) 8. Kapus, P., Raser, B., Arnberger, A., et al.: High efficiency hydrogen internal combustion engine – carbon free powertrain for passenger car hybrids and commercial vehicle. In: 43rd International Vienna Motor Symposium, Vienna (2022) 9. Bunce, M., Peters, N., et al.: Jet ignition as an enabling technology for stable, highly dilute hydrogen combustion in off-road and heavy duty engines. In: Internationaler Motorenkongress, Springer (2021)
Assessment of a Direct-Injection, Spark-Ignited, Hydrogen-Fuelled Heavy-Duty Engine John Hughes1(*), David Bennet1, Angela Loiudice1, Nicholas Coles1, Trevor Downes1, Agam Saroop1, Richard Penning1, Lukáš Valenta1, Peter Rabanser1, Jonathan Davis1, Jackson Harvey-Bush1, Alvaro Concepcion Calero1, Richard Osborne1, Penny Atkins2, Roger Allcorn2, and Nigel Fox2 1 Ricardo Shoreham Technical Centre, Ricardo UK Ltd, Shoreham by Sea, UK {John.Hughes,David.Bennet,Angela.Loiudice, Nicholas.Coles,Trevor.Downes, Agam.Saroop,Richard.Penning, Lukas.Valenta,Peter.Rabanser, Jon.Davis,Jackson.Harvey-Bush}@ricardo.com 2 Advanced Engineering Centre, University of Brighton, Brighton, UK P.A.Atkins@brighton.ac.uk Abstract.  Hydrogen-fuelled internal combustion engines (ICE) offer a zerocarbon fuel option for many ICE applications. As part of a global interest to characterise and study the behavior of hydrogen fuel in existing ICE applications Ricardo is collaborating with the University of Brighton to test hydrogen fuel in a Ricardo designed Proteus single cylinder engine. The engine is representative of a 13 litre Euro VI heavy duty (HD) production application converted to run on hydrogen fuel with minimal changes. The engine is fitted with a 35-bar direct injection (DI), hydrogen injector which gives improved flexibility for injection strategies and greatly reduces the presence of hydrogen in the intake system compared to a PFI system. Steady-state testing was carried out at an array of speed load points covering a large part of a typical heavy duty (HD) drive cycle area. An extract of the test results are shared and discussed in this paper. Lambda (λ) sweeps show the system is capable of running out to values exceeding λ = 5.0, exhaust gas recirculation (EGR) sweeps show over 40% EGR can be tolerated at given lambda conditions. Abnormal combustion events present sizeable challenges at lower lambdas due to very large knocking pressures and pre ignition risks. The lambda-threshold where the majority of these events are observed increases with speed and load thus narrowing the initial operating range of the engine prior to introducing mitigating measures like cooled EGR. The basic impact of lambda, EGR, injection and ignition timing sweeps are presented in this paper and show how © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 53–75, 2023. https://doi.org/10.1007/978-3-658-41477-1_5
54    J. Hughes et al. the system responds to the corresponding changes in specific heat capacity, mixture preparation, and combustion phasing. Keywords:  Hydrogen Engine · Hydrogen Combustion · Hydrogen Emissions · EGR · Proteus · ICE 1 Introduction Ricardo and the University of Brighton are collaborating to study the effects of running a typical mainstream HD engine on pure hydrogen. Hydrogen is increasingly envisaged as a future energy carrier in the transition to a net zero carbon economy. While using fuel cells to extract energy from hydrogen is seen by some as a long-term goal, hydrogen fueled combustion engines provide definite advantages in the short to medium term, as they offer lower cost solutions building on robust and proven technologies. They are also tolerant to fuel contamination and small particles, as well as being easier to manage thermally. In this research work Ricardo decided to investigate a Direct Injection (DI) hydrogen system. This approach provides greater flexibility in injection strategies, improves volumetric efficiency, allows lower boost pressures to be used, and reduces the presence of hydrogen in the intake manifold, minimising the risk of backfire compared to port fuelled injection (PFI) system. The work was started in a single cylinder Proteus research engine, before being moved to a multi-cylinder engine. This paper will focus on the results from the Proteus single cylinder engine. Ricardo has a long history of designing state of the art single cylinder engines (SCE) for research and development purposes and these are in use across the globe both for commercial and academic research alike. Ricardo’s SCEs are available in four families, namely: “Hydra” for light duty applications, “Proteus” for heavy duty applications, “Atlas” for large engine applications and the largest called “Prometheus” for power generation applications etc. A Proteus SCE was used for this study and the chosen engine configuration has a modified Scania OC13 unit head and a Volvo D13 bottom end, making the engine representative of a typical Euro VI production application. 2 Key Engine Features and Test Facility Overview As mentioned earlier testing was carried out on a Ricardo Proteus single cylinder research engine at the University of Brighton. Table 1 gives an overview of how the engine incorporates components representative of a Euro VI heavy-duty engine and the conversion to run on hydrogen. A Scania unit head was modified to incorporate a side DI H2 injector and a Kistler pressure transducer as per Fig. 1.
Assessment of a Direct-Injection, Spark-Ignited …    55 Table 1.  Engine Specification and Instrumentation Item Piston and Bottom End Cylinder Head Ignition System Fuel Injection System EGR High-Speed Measurement Equipment Low-Speed Measurement Equipment Hydrogen Proteus • Volvo D13 piston with modified bowl to reduce compression ratio to 12.6:1 • Scania OC13 CNG unit head • Modified for direct injection, in cylinder pressure measurement and metal temperatures • Custom spark-ignition system using AEM smart coil • BorgWarner prototype H2 injector (35 bar injection pressure) • Cooled EGR • A&D Combustion Analysis Software (CAS) data acquisition system • I ntake and exhaust manifold and in-cylinder dynamic pressure measurements using Kistler 6025 pressure transducers • Ignition and fuel injection timing via current clamps •E  ngine and test cell system temperatures and pressures •F  uel mass flow rate using a Bronkhorst F-113AC mass flow meter • Air mass flow via a T Mass sensor and critical flow nozzles • I njection and spark timing, throttle and EGR valve position data from National instruments control system • HORIBA HyEVO H2 analyser • Two HORIBA MEXA 7000 exhaust gas analysers monitoring intake and exhaust composition Fig. 1.  Instrumented Scania unit head with H2 DI injector fitted
56    J. Hughes et al. A CFD study was carried out to assess the impact on the unit head cooling circuit to help define the optimal positioning of the DI injector as indicated in Fig. 2. Further instrumentation was added to the cylinder head to measure an array of temperatures at key locations close to the flame face and known critical locations close to the valve bridges, spark plug and the injector itself. Inlet – Inlet bridge Inlet – Exhaust bridge Injector EX2 EX1 IN2 Sparkplug – Exhaust bridge IN1 Injector drilling Exhaust – Exhaust bridge Outer bore Fig. 2.  Coolant analysis of OC13 head water jacket to assess cooling risk due to injector installation. Head instrumented with thermocouples to log the thermal loads during testing, shown on the right Further CFD studies were carried out to assess the injector location in relation to mixture preparation and homogeneity across the intake and compression strokes. Various combustion chamber configurations as well as injector locations were compared to assess the impact on mixture preparation prior to initial hardware selection. Figure 3 shows some of the analysis carried out to optimise the final hydrogen injector location for the Scania unit head. Fig. 3.  3D Computational fluid dynamics of direct hydrogen injection carried out with VECTIS software to optimize mixture preparation and homogeneity
Assessment of a Direct-Injection, Spark-Ignited …    57 A Volvo D13 production piston was modified to reduce the compression ratio from 16.2:1 to 12.6:1 as per Fig. 4. Fig. 4.  Original Volvo D13 piston on the left and modified D13 piston for H2 Proteus SCE test application is shown on the right The engine was installed in the Sir Harry Ricardo Laboratories at the University of Brighton as per Fig. 5 and additional instrumentation as per Table 1. Fig. 5.  University of brighton single cylinder hydrogen engine test cell
58    J. Hughes et al. 3 Test Results The initial test programme covered a range of steady-state speed and load operating conditions representative of the expected operating range for HD applications as per Fig. 6. Testing included lambda, EGR, injection and ignition timing sweeps at these key points. Initial boundary conditions including fixed gross indicated mean effective pressure (GIMEP) and an initial target 50% mass fraction burned (MFB) angle of 8º crank angle after top dead center firing (ºCA ATDCF). An extract of some of the results of the testing is present-ed here. Fig. 6.  Initial target steady state key points to characterize hydrogen combustion over an array of boundary conditions including lambda, EGR, ignition and injection timing 3.1 Impact of Lambda on Engine-Out Emissions To determine the sensitivity of the system to air/fuel ratio, lambda sweeps were carried out at an array of key points. Data shown in Fig. 7 is for 900 rpm, 0% EGR, over four loads: 1) 3.5 bar 2) 9.0 bar 3) 12.0 bar and 4) 14.0 bar GIMEP. A lean lambda limit of λ = 5.5 was observed at 3.5 bar GIMEP and data at λ = 1.0 was possible to log at both 3.5 bar GIMEP and 9 bar GIMEP. The NOx trend shows a progressive increase in NOx with load as in-cylinder temperature increases. The values at very low lambdas are also influenced by retarding of the ignition timing to help with abnormal combustion.
Assessment of a Direct-Injection, Spark-Ignited …    59 Peak NOx emissions of 6600 ppm and 7000 ppm were observed at 3.5 bar GIMEP λ = 1.3 and 9.0 bar GIMEP λ = 1.4 respectively. NOx values then drop rapidly as lambda is in-creased and combustion temperatures cool to give NOx values below 25 ppm at all conditions above λ = 2.5. Further testing at higher speeds showed NOx formation to be more dominated by load than speed and, as expected, was also influenced by EGR and relative combustion phasing as ignition timing was optimised further. The presence of hydrocarbons (HC), carbon monoxide (CO) and carbon dioxide (CO2) in the exhaust emissions are due to the presence of oil in the system. The absolute values of each are unique to this experimental system at that time. The increases at lower lambdas and lower loads are due to the increased throttling of the system which increases the propensity of ingress of the oil into the combustion chamber. This highlights an additional benefit of maximising the lean combustion potential of hydrogen by limiting the intake throttling amount required. This reduces the risk of oil entering the combustion chamber via rings, stem seals etc. Fig. 7.  Lambda sweep engine out emissions at 900 rpm, 0% EGR, 3.5 bar, 9.0 bar, 12.0 bar and 14.0 bar GIMEP
60    J. Hughes et al. 3.2 Impact of Lambda on Combustion Figure 8 shows, similar dataset to Fig. 7 and expands on the impact load and lambda have on combustion. For all the datasets the 50% MFB angle was held at 8 ºCA ATDCF except for the lambdas where knock was preset. Combustion stability is relatively good throughout the majority of the lambda sweeps with coefficient of variance of GIMEP (CoV of GIMEP) <3% throughout the test suite. At lower lambdas the COV of GIMEP starts to rise as abnormal combustion starts to influence the system. However, even out to very lean values of λ = 4.5, the combustion stability is good and hence COV of GIMEP is still very low (e.g. <3) with lower normalized value of GIMEP (LNV GIMEP) only dropping below 90% at λ > 4.5. From λ = 1.5 to λ = 4.0 for any given lambda as load increases there is only a small change in combustion duration, even from very low load. This will potentially help allow for a wide lambda range to be more easily calibrated for in vehicle applications and help with maintaining correct combustion phasing during transient fluctuation in lambda. As lambda exceeds λ = 4.0 there is a progressive slowing of combustion relative to load and from then on an increased spread in ignition delay and 10–90% MFB is observed. Fig. 8.  Lambda sweep combustion and pressure characteristics comparison: 900 rpm, 0% EGR, 3.5 bar, 9.0 bar, 12.0 bar and 14.0 bar GIMEP. Angle of 50% MFB is constant at 8 ºCA ATDCF
Assessment of a Direct-Injection, Spark-Ignited …    61 The relationship between knock/abnormal combustion events with load and lambda is very evident in the dataset presented. As load increases the lambda limit that can be achieved before knock is observed increases. At 3.5 bar GIMEP λ < 2.0 resulted in abnormal combustion, whereas at 14 bar GIMEP lambda values λ < 3.0 resulted in knock and abnormal combustion events occurring. Thermal efficiency can be observed in terms of gross indicated thermal efficiency (GITE). GIMEP in bar is converted to power and compared to fuel power. Typically, the peak GITE was observed at increasing lambdas with increasing load. This however is not the final optimal thermal efficiency as the ignition timing is not fully optimised at this point. As expected, peak cylinder pressure (Pmax) increases with increasing lambda as well as load. The slope of increased Pmax with lambda rises with increasing load. The aver-age rate of pressure rise over 300 cycles increases with load and increases further at lower lambdas as the burn rate accelerates. Overall, as load increases there is a narrowing of the lambda range that can be utilized. At lower lambdas knock and abnormal combustion are the limitation. At the lean end there is a deterioration in combustion stability which is part of an ongoing study. 3.3 Impact of EGR on Combustion and Emissions Figure 9 gives an example of the impact EGR has on combustion and emissions at the same load and lambda condition across three speeds (900 rpm, 1400 rpm, 1800 rpm). Across the three sweeps a large EGR rate (>45%) was tolerated without misfire. This high EGR rate considerably increases the specific heat capacity of the system hence lowering combustion temperatures and reducing the rate of NOx formation. The added EGR also allows for the engine to be de-throttled as intake manifold pressure crosses barometric pressure at approximately 40% EGR. Hydrogen’s ability to tolerate a large amount of EGR presents more options to help reduce pumping losses or even remove the need for a throttle in the first place. Adding EGR as expected slows combustion and rate of pressure rise but leads to increased cylinder pressures due to the increased trapped mass in the system. At high-er loads the ability to tolerate lean combustion or large amounts of EGR may be superseded by cylinder pressure limitations especially in retrofit applications. The downside to tolerating large quantities of EGR is there is however a noticeable increase in hydrogen slip once the EGR rate exceeds 25%. This is believed to be due to the expected increasing flame quench distances from the walls due to the lower combustion temperatures. This increase in the unburned boundary layer, despite it getting progressively more dilute with EGR, leaves increasingly more unburned hydrogen in the combustion chamber at the end of combustion.
62    J. Hughes et al. Fig. 9.  EGR sweep λ = 2.0 3.5 bar GIMEP, 900 rpm, 1400 rpm and 1800 rpm comparison 3.4 Ignition Timing Optimisation The ability to optimise the ignition timing for fuel economy is limited by the sensitivity of the system to abnormal combustion and the necessary trade-off with NOx formation rate. Figure 10 shows the benefits of leaner lambdas both in maximizing gross indicated specific fuel consumption (GISFC) and reducing NOx. At λ = 2.0 as ignition timing is advanced the presence of abnormal combustion prevented the system reaching the optimal GISFC. NOx formation increases as ignition timing is advanced due to higher in-cylinder temperatures; hence advancing ignition timing at λ = 2.0 also has a much greater impact on increasing NOx emission than at the leaner conditions. At λ = 2.5 and λ = 3.0 the slower 10–90% MFB also means the rate of pressure rise progressively reduces resulting in a much cooler combustion system and hence a lower NOx formation rate. As Ignition timing is advanced at λ = 2.5 and λ = 3.0, although combustion gets faster and rate of pressure rise increases, the rate of NOx increase is much lower.
Assessment of a Direct-Injection, Spark-Ignited …    63 Fig. 10.  Ignition timing sweep at 1400 rpm 3.5 bar GIMEP, λ = 2.0, 2.5 and 3.0 The optimum GISFC for these sweeps is found between 2 ºCA and 5.5°CA ATDCF which is relatively advanced compared to traditional spark ignited fuels like gasoline etc. Other sweeps show similar tendencies and were also influenced by relative speed, load, EGR rate, etc. Figure 11 demonstrates that at higher speeds and loads (1800 rpm 14 bar GIMEP) relatively advanced ignition timing can be tolerated com-pared to traditional λ = 1.0 gasoline systems, which have more retarded combustion phasing due to knock. Figure 11 also shows how the system can be progressively further optimised by in-creasing lambda. As lambda is increased combustion phasing can be advanced further before abnormal combustion occurs. At the lean condition of λ = 3.0 the optimum fuel economy potenzial of the system can potentially be reached; however large knock events are present.
64    J. Hughes et al. Fig. 11.  Ignition timing sweep 1800 rpm 14 bar GIMEP 0% EGR λ = 2.5, 3.0 and 3.5. Example of abnormal combustion preventing optimal ignition timing even at very lean conditions Figure 12 shows ignition timing optimisation with and without EGR. The addition of EGR delays the onset of knock and once knock is encountered the amplitude of knock is suppressed. EGR is very powerful at reducing the rate of NOx formation but there is a trade-off with fuel economy if ignition timing cannot be fully optimised. Fig. 12.  Ignition timing sweep showing 900 rpm 9 bar GIMEP. As EGR is added NOx emissions are greatly reduced and knock is suppressed to the point where ignition timing can be optimised to clearly define minimum GISFC 3.5 Injection Timing Optimisation A range of injection timing sweeps or start of injection sweeps (SOI sweeps) were carried out to study how hydrogen-air mixture homogeneity is influenced by injection timing and the effect this would have on combustion and emissions. Four sweeps were
Assessment of a Direct-Injection, Spark-Ignited …    65 selected from the Ricardo and University of Brighton investigation to show in this paper to demonstrate some of the impacts captured during this study. The optimising range for the SOI study is initially bookended by requirement to start injection after the exhaust valve is closed to prevent hydrogen slip, and to end injection before cylinder pressure reaches approximately 20 bar compression pressure to avoid any risk of damaging the 35-bar injector from intake pressure waves. For each data point a constant GIMEP was held and the 50% MFB angle of 8 ºCA ATDCF was maintained. Figure 13 outlines some of the findings. As the injection timing is swept from the most advanced setting of 300 ºCA BTDCF to 180 ºCA BTDCF a progressive increase in NOx formation is observed. This would indicate increased temperatures within the combustion chamber and is further backed-up by a reduction in 10–90% MFB angles, indicating faster combustion as well as increases in rate of pressure rise and maxi-mum cylinder pressure. Combustion stability is also influenced by the injection timing. As SOI is retarded to <240 ºCA the COV GIMEP starts to increase and the LNV GIMEP decreases. Also of note is the fact that at 1800 rpm 9 bar GIMEP λ = 2.5 the system is very close to its knock threshold. As injection timing is retarded this becomes more evident and increasing knocking pressures were logged. Overall, the data suggests mixture homogeneity has not fully stabilized even at very advanced injection timings and feeds directly into further studies by the Ricardo CFD team. Fig. 13.  Injection timing sweeps at 900 rpm and 1800 rpm, λ = 2.5, λ = 3.0
66    J. Hughes et al. 3.6 Thermal Impacts Previously a Ricardo CFD study was referenced which assessed the impact of retro fitting an injector into the Scania unit head. To allow for further development of Ricardo hydrogen CFD capability with hydrogen an array of thermocouples were fitted to the cylinder head. The thermocouples were positioned to provide a detailed overview of the temperature profile during all the various sweeps. This data can help build a picture of the boundary conditions to be expected from hydrogen combustion for further modeling by the Ricardo design and analysis teams. Figure 14 shows an example of maps at λ = 2.5 with 0% EGR showing the temperature profiles over an array of steady-state speed and load points. This data helps in highlighting for example how successfully the area near the injector has been cooled. It also is combined with other datasets to understand the thermal impacts of burning hydrogen in an ICE application. Fig. 14.  Cylinder head thermocouple data at λ = 2.5 with 0% EGR. Data can be mapped to show temperature profile in the unit head across all speed and load points for given lambdas, EGR levels etc. In addition to metal temperatures, the exhaust gas temperature data provides a vital overview what the boost and aftertreatment systems can expect to experience on a hydrogen engine. The absolute temperature of the engine out exhaust gas from single cylinder engines is not fully representative of the absolute temperatures that
Assessment of a Direct-Injection, Spark-Ignited …    67 would be obtained on multi cylinder engine. The long delay between each exhaust gas stroke, different heat transfer pathways and exhaust gas pulsations etc. greatly influence the temperate measurement. However, the relative trends and sensitivities to different boundary conditions (lambda, EGR, ignition timing etc.) can be captured and used as inputs to models. The data also gives an overview of conditions best suited to enhancing transient behavior or maintaining required aftertreatment temperatures. Figure 15 gives a small overview of how the exhaust gas temperatures change in relation to lambda, speed and load. These can be cross referenced with the NOx emissions maps also generated to help understand the challenges facing boosting and aftertreatment systems (ATS). As can be seen from the data there is a noticeable drop in exhaust gas temperature as lambda is increased. This provides challenges for transient strategies and can be cross referenced with compressor and turbine options to better understand the tradeoffs to be expected with keeping NOx emissions low while maintaining transient expectations. Fig. 15.  Example of engine-out exhaust gas temperature data mapped against speed and load at different boundary conditions. An array of sensitivity studies provide reference data for 1-D, CFD, FE, 0-D etc. studies. The thermal data shows the impact numerous boundary conditions have on the relative engine out exhaust gas temperature
68    J. Hughes et al. 3.7 Abnormal Combustion The ignition timing sweeps seen earlier show that end-gas knock can be observed when advancing ignition and hence by retarding ignition timing avoided. Also, the lambda sweeps showed that at a fixed combustion phasing, as lambda is reduced an asymptote is reached where end-gas knock occurs; this asymptote getting leaner as load is increased. However, in addition to these system characteristics where abnormal combustion occurrence is relatively predictable there are also occurrences of extreme abnormal combustion events that are much more stochastic. Figure 16 on the left shows an example of a single large knock event of 145 bar peak-to-peak (pk-to-pk) followed by a single preignition (PI) event after which the system returned to normal combustion cycles. This is one example of a large number of similar events seen at many different test conditions. On the right is example of multiple events of PI over 100 consecutive cycles. Similarly, very high pk-to-pk knock pressures of 210 bar were logged and again the engine had relatively normal combustion before and after. Fig. 16.  Examples of the stochastic nature of more extreme abnormal combustion events are shown above. Left shows large single knock event followed by single PI event before system returns to normal combustion. Right shows PI with large knock event followed by multiple lesser PI events before system recovers to normal combustion Figure 17 on the left shows an example where multiple knocking PI events get progressively more advanced before a single very early PI event occurred. The following cycles returned to the previous PI combustion characteristics. In this case
Assessment of a Direct-Injection, Spark-Ignited …    69 the engine showed no signs of returning to normal combustion and was manually shut down to prevent damage. To the right in Fig. 17 is an example of a very early PI event which occurs during the intake stroke. As the intake valve is open the pressure wave registered on the intake Kistler transducer and is shown below. The following cycle then misfired believed to be due to excessive amount of residuals then present in the intake system. Fig. 17.  On the left is a condition where PI progressively advanced with each cycle, followed by a very early PI event. On the right (top plot) is an example of single PI during intake stroke with pressure wave registering on the intake Kistler (below plot). The following cycle misfired Only a small number of events are discussed in this paper out of a very substantial number that were captured during testing. The root cause of for all events is not necessarily the same and are part of an ongoing investigation at Ricardo. The presence of hot spots could explain some occurrences where PI gets progressively worse however the more random stochastic events are more difficult to explain as the hot spot would need to appear and then disappear over a very small number of cycles. Further investigation into the impact the ingress of oil, abnormalities in the ignition system, compression temperatures etc. have on combustion is ongoing at Ricardo. 4 Ricardo Simulation The empirical data gathered is used initially to validate Ricardo models, from 1-D to 3-D CFD, of the Proteus combustion system in order to close the loop on analysing the findings and to help ensure valid conclusions are drawn. These models then allow Ricardo to adjust the boundary conditions to explore new scenarios in parallel with the test programme. 4.1 1-D Performance Simulation A single cylinder 1-D performance model of the tested engine was built in the 1-D software WAVE and validated against all the gathered test data as indicated in Fig. 18.
Fig. 18.  Ricardo 1-D WAVE model of Proteus SCE H2 engine 70    J. Hughes et al.
Assessment of a Direct-Injection, Spark-Ignited …    71 This 1-D model is used for the development of a predictive Hydrogen Combustion Duration Sub-model (HCDS). HCDS is a semi empirical sub-model based on the com-bination of laminar and turbulent flame speed calculation and empirical test data. HCDS reflects in-cylinder conditions such as lambda, pressure, amount of internal and external residuals etc. The sub-model also reacts to the change of bore, stroke and intake port design. HCDS is under continuous development following the progress of the presented testbed programme to support the future development of engines with hydrogen combustion system. 4.2 3D CFD Simulation The data from the Ricardo H2 SCE also provides an opportunity to validate the updated combustion models for lean hydrogen combustion in VECTIS CFD code includes the thermodiffusive instability effects and the general methodology for the prediction of hydrogen combustion. As such, the initial concept level in-cylinder CFD simulations of the Ricardo H2 SCE test engine, shown previously, were revisited and refined to correspond to the acquired test data. Two main enhancements were made to the modelling; the H2 injection was validated for the final injector configuration and the combustion simulations employed the aforementioned enhanced models for lean hydrogen combustion. A 3-point lambda swing was considered at 1400 rpm and 9 bar GIMEP with nominal lambdas of λ = 2.5, λ = 3 and λ = 3.5. A relatively early start of injection timing was used during testing to try an ensure as close to a homogeneous mixture as possible at spark timing. Figure 19 shows an example of the spray match for the H2 injector used in the SCE along with the evolution of mass weighted H2 distribution probability during compression for the lambda 2.5 keypoint (EQR 0.4)
Fig. 19.  Example spray match for BW CNG/CHG 6.2 injector used in Ricardo H2 SCE and mixture uniformity at TDC from updated in-cylinder injection simulation 72    J. Hughes et al.
Assessment of a Direct-Injection, Spark-Ignited …    73 With trapped conditions at spark timing now matched to the measured test points the combustion prediction can now be more fairly assessed. Both the standard combustion approach and the enhanced lean hydrogen combustion model were evaluated. The two models were tuned to match the test data at the mid, λ = 3.0, test point of the three-point test swing before being run at the two other test points without further tuning. Figure 20 shows the response of the models to a change in lambda. The match achieved when tuning the models at the mid-point is very good, with both models lying on the test pressure curve. As the operating lambda is changed the standard model tends to undershoot the measured pressure at the richer condition and overshoot at the leaner condition. With the new thermodiffusive model, the response is significantly improved. Fig. 20.  Predicted in-cylinder pressure compared to test for 3-point lambda sweep With additional data from the SCE the combustion models are being validated across a wider range of operating conditions, with and without EGR, and for abnormal combustion events such as pre-ignition and knock. 5 Conclusions The internal combustion engine will remain relevant as a chemical-to-kinetic energy converter in heavy-duty, off-highway machines and in marine applications for some time to come. This paper gives a small overview of some of the characteristics of hydrogen combustion captured by Ricardo and the University of Brighton. The hydrogen combustion lean limit extending to >λ = 4.0 in some conditions allows the engine out NOx emissions to be reduced to <10 ppm. Similarly, the engine has a high tolerance for EGR with levels of >40% possible without misfire, giving alternate combinations to keep engine-out emissions low, reducing the compromise with specific power, exhaust gas temperatures, aftertreatment specifications etc. However, the potential for extreme abnormal combustion events to occur needs to be better understood when optimising the combustion parameters. Retrofitting an existing combustion system with hydrogen fuel injection equipment (FIE) presents additional challenges as there are restrictions on where the
74    J. Hughes et al. injector can be positioned etc. The use of CFD tools are essential to understand the trade-offs available. Specific empirical tests including injection timing sweeps etc. help show how the homogeneity can be further improved and further iterations of CFD can help fine-tune the combustion system. Ricardo validated 1-D models help better understand the combustion process and the thermodynamics behind the sensitivity studies carried out. Further structural analysis, cooling circuit analysis etc. is then possible by combining empirical data and model outputs to maximize the understanding of burning hydrogen in an internal combustion engine. The Ricardo Proteus SCE has shown there are very robust ways to study the impact of running an engine configuration on hydrogen fuel prior to further studies on multicylinder applications. This study shows the possibility of combining direct injection technology with existing swirling combustion chambers. This aligns well with the expected desired strategy to create direct-injection hydrogen fuelled heavyduty engines via minimum modification to existing diesel and CNG products. The learning from this study is also being transferred to 13l multi cylinder engine currently installed in Ricardo Shoreham Technical Centre in UK. Acknowledgements. The authors would like to thank the University of Brighton for the use of their facilities and equipment as well as their collaboration and support in carrying out this extensive study. Finally, the authors would like to thank the Ricardo UK Test Operations team for their support and the wider Ricardo technical teams for their input and expertise in assisting with this study and paper. Glossary ATDCF After top dead centre firing GISFC Gross indicated fuel consumption ATS Aftertreatment systems GITE Gross indicated thermal efficiency CA Crank angle HC Hydrocarbon CFD Computational fluid dynamics HCD Hydrogen Combustion Duration Sub-model CHG Compressed hydrogen gas ICE Internal Combustion Engine CNG Compressed natural gas LNV Lower normalised value CO Carbon Monoxide MFB Mass fraction burned CO2 Carbon dioxide NOx Nitrogen oxides COL Carbon monoxide low range PI Preignition COV Coefficient of variation PPM parts per million EGR Exhaust Gas Recirculation SCE Single cylinder engine EQR Equivalence ratio TDC Top dead centre GIMEP Gross indicated mean effective pressure
Assessment of a Direct-Injection, Spark-Ignited …    75 References 1. Walter, L., et al.: The H2 Combustion Engine – The Forerunner of a Zero Emissions Future, Vienna Motor Symposium 2. Boberic, A., M. Sc., et al.: Measures to achieve high specific power with a heavy-duty Ha internal combustion engine: A numerical and experimental analysis. 31st Aachen Colloquium Sustainable Mobility 2022. Aachen, October 10th to 12th (2022) 3. Maio, G., et al.: Retrofitting a diesel baseline to a fully Ha spark ignition engine by combining experiments, OD/1D, and 3D CFD simulations: 31st Aachen Colloquium Sustainable Mobility 2022. Aachen, October 10th to 12th (2022) 4. Chi, Y., Dr., et al.: Hydrogen Internal Combustion Engine: Zero- Impact Emission Technology for Sustainable Mobility: 31st Aachen Colloquium Sustainable Mobility 2022. Aachen, October 10th to 12th (2022) 5. Lazzaro, M., Catapano, F., Sementa, P.: Experimental characterization of methane direct injection from an outward-opening poppet-valve injector. SAE Technical Paper 2019-240135 (2019). https://doi.org/10.4271/2019-24-0135 6. Atkins, P. A., Dr., et al.: Examining trade-offs between NOx emissions and hydrogen slip for hydrogen combustion engines, THIESEL 2022 Conference on Thermo- and Fluid Dynamics of Clean Propulsion Powerplants. 13th–16th Sept 2022
The Compact Catalytical Heater (CCH): Thermal Management for HD EU-VII/ EPA-27 with Low Impact on Existing EATS Architectures Manuel Presti1(*), Oswald Holz1, Mathias Keck2, and Dennis Sailer2 1 2 Vitesco Technologies Emitec GmbH, Lohmar, Germany manuel.presti@vitesco.com BIN Boysen Innovationszentrum Nagold GmbH & Co. KG, Nagold, Germany mathias.keck@bin.boysen-online.de Abstract.  Currently the OEMs of commercial vehicles (using an internal combustion engine) are preparing for the new emission legislation EU-VII und EPA-27. The challenge is an improved NOx-reduction at cold-start and low load conditions as well as reduced CO2. In the meantime, also in the Off-Road sector (NRMM) the first discussions started on next steps. The existing exhaust aftertreatment systems are typically showing very high NOx-conversion rates when operated at the appropriate temperature. OEMs are investigating a variety of possible solutions to increase the temperature level of the SCR catalysts for the critical operation points: cold start and low load. “Pure” electrical heating has quite a high CO2-disadvantage in the case that the electrical power is coming from alternator and battery. The high power-demand for higher exhaust mass-flow is another challenge for the electrical system. Fuel dosing into the exhaust system is a state-of-the-art process for DPF regeneration and shows a high efficiency in energy release. Combining electrical heating with fuel dosing results in an efficient heating with moderate electrical power demand. “Engine-independent” heating of the exhaust system allows in turn the engine to operate in the “CO2-bestpoint” and thus reduce the fuel consumption. The innovative compact catalytical heater as an add-on component upstream of a well proven CV-muffler allows to begin fuel dosing very early in the coldstart phase, generating high amount of energy for the fast heat-up of all components (including catalysts) within the muffler. It is also intended to operate for keeping the exhaust system warm in low load operation. The goal is to continue using already existing and well-established exhaust components (muffler) to reduce R&D efforts & tooling costs. This paper describes the development of the system including simulation as well as test results on a dynamic heavy-duty engine test bench resulting an improvement of 11%-points in the FTP cold start and in the Low Load Cycle (LLC) a NOx conversion of 99% with active heating. © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 76–94, 2023. https://doi.org/10.1007/978-3-658-41477-1_6
The Compact Catalytical Heater (CCH): Thermal Management …    77 Keywords:  Low NOx · Exhaust thermal management · Electrically heated catalyst · Catalytical heater 1 Introduction In order to comply with the coming reduced emission limits (USA & Europe) combined with reduced fuel consumption, the exhaust aftertreatment system (EATS) needs to be “fully operational all the time” when the engine is running. Engines with improved fuel efficiency tend to have lower exhaust temperatures, which further complicates catalyst operation in low load condition. Cold start of the engine is expected to become a major challenge and will require a fast heat-up of all components in the EATS. Typical EU-VI trucks have the most tailpipe nitrogen oxides (NOx) emissions in the first 10% of the engine-work [g/kWh], while Stage V non-road mobile machinery (NRMM) operate in some RDE cases within extended idle mode. The tailpipe NOx-concentration has peaks at a power lower than 10% or higher than 75% of the nominal power [1, 2]. Several studies have been conducted on thermal management of heavy-duty exhaust systems in order to get the catalyst-temperature into the window of best performance [3–7]. The current paper describes the development of an advanced catalytical heater capable to provide a high amount of heat-energy during cold start and low load operation utilizing only a limited electrical energy (max 4.3 kW). The compact catalytical heater (CCH) can provide the heat-energy mostly independent from the engine operation point allowing the engine to be driven in a fuel-efficient (or hybrid supported) mode. The goal is to continue using already existing and well-established exhaust components (muffler) to reduce R&D efforts & tooling costs. 2 Current State of Technology Engine developers are continuously increasing the efficiency of combustion engines and thus reducing fuel consumption and CO2 emissions. This improvement leads to lower exhaust gas temperatures and in some cases decreases the efficiency of exhaust aftertreatment systems. “Passive” measures – such as a close coupled position of the catalysts or insulation of the tubing – can support. In our investigations with a close coupled SCR-catalyst (including a second, “main” SCR -system: dual SCR) an “active” heating was still necessary [3]. The prevalent active heating is currently done with engine measures. For DPF regeneration in addition fuel is injected into the exhaust and combusted on the oxidation catalyst (DOC: Diesel Oxidation Catalyst). Electrical heating and external burners are being investigated as “additional active heating”.
78    M. Presti et al. By using engine-based measures to raise the temperature in the exhaust system, one part of the introduced energy is dissipated via the engine cooling system and does not contribute to the heating of the exhaust system components. External burners have the disadvantage that, in addition to the exhaust gas, the combustion air has also to be heated, which increases the overall fuel consumption. Efficiency of “pure” electrical heating is in the range of ~40–60% when the energy is used directly from alternator and battery. Total electrical heating power is limited by the installed electrical configuration on board. Combining of electrical heating with fuel injection promises an improved overall heating efficiency and having a fast-acting controllability. For this the electrical power is used only to ensure the oxidation catalyst light-off for the catalytic “combustion” of fuel. Heat release of the fuel is expected to have an efficiency close to 100% – directly in the exhaust system. With an appropriate configuration and actual operation up to 40–50 kW heat energy can be provided for the heat-up of the exhaust system. In previous studies at an engine test bench [4] the hydrocarbon (HC) conversion with additional limited electrical heating power and fuel injection has been analyzed. For a critically low load point the heat release of the injected HC on the DOC is 50% higher than the reference without additional heating. The small full flow EHC (Fig. 1, conf. A, before decoupling element) in position 1 has higher thermal loss along the exhaust path than small EHC (same type, conf. B) in position 3 and EHC (conf. C) in front of the DOC. The configuration A and B can be beneficial in comparison to configuration C as a possible slip of the injected fuel is neglected, based on the mixing and evaporation length. Figure 2 shows an example of HC conversion for configuration C with varying temperature upstream the DOC. The given electrical power (4 kW) can not generate same conversion levels at a higher mass flow compared to the lower flow rates. Fig. 1.  Modular test build-up without bypass design to validate the HC-conversion with electrical heating catalyst EHC in configuration A, B or C [4]. (©Boysen)
The Compact Catalytical Heater (CCH): Thermal Management …    79 Fig. 2.  HC-conversion map for electrical heating catalyst EHC in front of DOC (at position C, s. build-up) at modular test build-up. (©Boysen) An increasing exhaust gas temperature is beneficial for the urea preparation as limitation towards the reduction of NOx. Alternate options to enhance the urea preparation are the integration of active heating measures in the urea mixing path (EHC, heating pipe) or using passive measures like mixing elements, Hydrolysis wash-coat on the evaporation surface and pipe in pipe configuration. Especially passive measures enhance the generation and distribution of Ammonia (NH3) for the SCR-catalyst, but do not affect the SCR-Light-Off significantly (Fig. 3). Fig. 3.  Measures for enhancing urea preparation as limitation of the SCR-catalyst function. (©Boysen)
80    M. Presti et al. 3 Development and Validation of a Compact Catalytical Heater (CCH) For regeneration of particulate filters – in the heavy-duty sector – is common to inject fuel directly into the exhaust system and convert it into heat at the oxidation catalyst. To do this, the catalyst must have reached its operating temperature, which is not ensured in all engine operating points, so that heating measures are required to “support”. With electrical energy, the temperature of the oxidation catalyst can be raised by means of an EHC (EHC = Electrically Heated Catalyst) to a level that the introduced fuel is completely converted. The required electrical energy depends on the exhaust-gas mass flow and its temperature [4]. During the cold start, a fast heatup of the exhaust system is required: i.e. to supply as much heat energy as quickly as possible into the exhaust system. In this case the advantage of fuel dosing is evident: with the (limited) electrical power only the HC-Light-Off of the DOC is ensured – the dosed fuel then provides the high heat-energy input. For cold start operation and system configurations in which a high electrical power is not feasible or desired, it is possible to bring a partial gas flow with a lower electrical power faster to the “ignition temperature” of the oxidation catalyst. With the addition of fuel, a large amount of energy can be introduced not only to heat the partial flow to an elevated temperature level (e.g. 600 °C) but also the entire system much faster to the desired level (e.g. 220 °C of the SCR-catalyst). Initial results of a first-generation heating module with partial flow EHC & fuel dosing, employing an EHC with a volume of only 1.65 l (Ø 174.6 mm) and a maximum electrical power of 4.3 kW, were described in [3]. Based on the findings of the first PoC (Proof of Concept) configuration, a new compact system has been developed with reduced heat capacity: CCH (Compact Catalytical Heater). This paper describes the development and validation of the new system with 50% reduced length, weight hence heat capacity in a close to industrialization status. 3.1 Concept The task of the new system is to improve NOx-emission-reduction in the cold start or low-load range without causing disadvantageous back pressure in the nominal load case.
The Compact Catalytical Heater (CCH): Thermal Management …    81 This is achieved by means of controllable mass flow management through a flap. Electrical heating power and flap position are adjusted to each other based on the operation condition. The Boysen-2/2 way-flap is controlled by a brushless direct current motor of a Sonceboz actuator with a very short closing time <150 ms and high precision in closing position and torque control. Injection of hydrocarbons takes place as a function of the exhaust gas mass flow, -temperature, surface temperature of the EHC and the desired temperature level. It is essential to obtain a high mixing quality of the injected HC onto the EHC within one universal module/component. It is important to have an evenly distributed ratio between heat flow through the EHC, exhaust gas (oxygen) and the concentration of the fluid being metered in. This can be achieved by a uniform local “lambda”. Bypassing the EHC (the first DOC) also reduces aging effects on it. Fig. 4.  Design of the compact catalytical heater (CCH) With the compact design of the arrangement (Fig. 4), installation space, (thermal) mass, and surface area can be reduced to achieve a fast light-off characteristic of the first DOC included in CCH and the second (main) DOC in the muffler box. By a large cross-section of the main path inlet towards the merging chamber, the overall pressure drop can be decreased (Fig. 5).
82    M. Presti et al. Fig. 5.  Compact catalytical heater (CCH) basic design. (©Boysen) 3.2 Operating Conditions The simulation load points are related to the engine load points of the Vitesco Technologies Emitec test engine (Table 1). Within the nominal load point (NLP) the back pressure increase of the CCH-system should be about 15 mbar. As typical load point in the FTP cycle of the reference heating system [3] TLP1 indicate the susceptibility to spray drift and asymmetric flow. For the idle phase TLP2 indicate a boundary case without the susceptibilities of TLP1. Table 1.  Load points for simulation designing Load Point NLP TLP1 TLP2 Massflow in kg/h 2100 800 120 Inlet Temperature in °C 500 220 120 Flap Variation Open 45°/Closed Closed HC-Dosing in g/s – 0.75 0.12 Measurements of the hot gas test rig include a mapping with steady load points and tests on engine dyno beyond TLP1 transient cycles.
The Compact Catalytical Heater (CCH): Thermal Management …    83 3.3 General Model Features and Simulation Procedure Fig. 6.  Conceptional design of elements in the mixing chamber. (©Boysen) Pre-analysis on a hot-gas test rig and a verification via CFD has shown that through the perforated structure PE-Design® of the EMICAT® a recirculation of gas via an inlet swirl structure can appear, when the swirl-number is very high. The flow simulation of the heating disc and support catalyst have specific linear axial viscous –, quadratically axial, linear viscous and quadratic radial internal resistance. The radial heat and mass transfer are supported through the perforated structure of the EHC and the swirl flow of the concept (Fig. 6). The development of the CCH-design is based on the tool Star-CCM+ from Siemens (Version: 14.04.013). • Meshing settings: – Prism layer (PL) Thickness: 5 mm/PL Stretch: 1.3/PL Quantity: 10 • Per simulation (load case) 2.7 million cells • Physics: – Realizable K-Epsilon Two-Layer (Turbulence Model). – All y+ Walltreatment (near wall consideration) – Ideal gas • Thermal boundary conditions: – Interior component walls adiabatic – Exterior walls T = 25 °C/alpha = 20 W/(m2K) – No radiation model The simulation results in Fig. 7 indicate the function of the mixing chamber elements as the flow is stabilized to avoid spray deflection. The swirl is homogenized through the resistance of the decreasing cross section, the deflection losses of the swirl cone, throttle sleeve, perforated sleeve and the relative velocity between the injection hydrocarbon droplets towards the gas flow.
84    M. Presti et al. The axial velocity profile based on typical mono-swirl flow has a minimum in the center, which characteristic is more pronounced with higher mass flow through the bypass path. The comparison of a closed flap to a 45° opened flap for TLP1 indicates the effect (Fig. 7). The mass flow percentage of the bypass within opening of the flap can decrease to about half for TLP1 and about one quarter for the nominal load point (NLP). Fig. 7.  Analysis of the mass flow, velocity and static pressure of compact catalytical heater (CCH) #510 model for partial load points. (©Boysen) Fig. 8.  Analysis of the mass flow, velocity and static pressure of compact catalytical heater (CCH) model #510 for nominal load point. (©Boysen)
The Compact Catalytical Heater (CCH): Thermal Management …    85 At the nominal load point the flow acceleration from the outlet chamber downstream to the pipe can cause a pressure loss (Fig. 8). For further reduction of the back pressure the flow axis of the downstream path of the CCH-system is lower positioned in the height (Fig. 9). A much higher back pressure for bypass-path as for the main path is advancing high HC-conversion within low exhaust mass flow through the EHC (s. chapter “Current state of technology”, Sect. 2). The total back pressure at TLP1 with a closed flap of the prototype is 57 mbar (Fig. 10). Fig. 9.  Design of the compact catalytical heater (CCH) model #510 compared to model #511 (concept for prototype) with two different outlet cones. (©Boysen) Fig. 10.  Analysis of the flow characteristic both concept for the prototype and the modular ready for production prototype of the compact catalytical heater (CCH) with TLP1 and closed flap. (©Boysen)
86    M. Presti et al. For developing a control strategy, the modular design of the prototype for the hot gas test rig is analyzed via CFD. Through small angle of cone downstream of the hotgas burner and perforated plates the inlet flow in the cross-section towards CCH is homogenous. 3.4 Control Strategy Within the total mass flow ṁtot , and the flap position ϕ the partial mass flow ṁBypass,% towards the EHC can be determined. ṁBypass,% = f(ṁtot , ϕ) (1) Based on the hot gas test rig measurements a control loop, which is implemented in MATLAB Simulink, is developed for OEM-applications. The model includes the electrical heat-up phase and the chemical heat-up phase. The chemical heat-up phase is based on a full conversion of HC. For development of a model the conversion rate of the EHC has to be experimentally determined. The possible dosing amount is depending on the ratio of the converted HC between the EHC and the second main DOC. 3.5 Validation on the Hot Gas Test Rig The same insulated CCH-prototype is used for the validation on the hot gas test rig and the engine dyno. For analysis of the pressure drop, temperature distribution, -boost and the mass flow distribution, additional elements upstream and downstream were used for solid comparison between testing and simulation. To compare back pressure with directed flow, two perforated plates are used: configuration 1. The comparison between simulation and measured pressure shows a very low difference (total backpressure = dptot; static backpressure = dps), Fig. 11. It has to be considered that the flap has an internal and an external leakage, which can reduce the back pressure slightly.
The Compact Catalytical Heater (CCH): Thermal Management …    87 Fig. 11.  Configuration 1 of the modular test-up of the compact catalytical heater (CCH) on the hot-gas test-rig without electrical heating. (©Boysen) In order to analyze the the influence of a certain swirl of the inlet flow a configuration 2 has been installed with a 107 mm outer diameter mixing element with 16 blades and specific outlet angles of 45°. The flow characteristic and mass distribution of the CCH towards the two paths depend on the swirl flow characteristic of the exhaust gas downstream of the turbocharger. The inlet flow influences the kind of swirl in the HC-mixing path. Within TLP1 and 4 kW electrical power, the temperature distribution in the cross-section at position 2 (Fig. 13) of EHC differs between configuration 1 and 2. A 100% closed flap (= “flap position 100%”) affects for configuration 1 a higher flow velocity for negative y-coordinates and lower temperatures in the measurement than for configuration 2 (Fig. 12). Fig. 12.  Temperature distribution at position 2 at TLP1 at the modular hot-gas test-up
88    M. Presti et al. Differences of the surface- and gas-temperatures for configurations 1 and 2 indicate an influence of the inlet swirl, which can be based on a different mass flow distribution between both CCH-paths and inside the EHC-path (s. Figs. 14 and 15). Generally, the correlation of temperature increase through EHC is similar. If the flap is closed, an increase of the mass flow and, as a consequence, lower temperatures are measured. Fig. 13.  Modular test-up of the compact catalytical heater (CCH) for the hot-gas test-rig. (©Boysen) As forecast to the ideal starting time of HC-injection it has to be considered that for the light-off the surface temperatures should be higher than 270 °C, but to avoid aging stay below 600 °C (including the exothermal reaction by the injected fuel). The isolines of the transition between the green and yellow in Fig. 14 for position 1 indicates the opening angle of the flap at a specific total mass flow as a good condition for start of HC-injection. Fig. 14.  Mean surface-temperatures at pos. 1 for configuration 1 (left, rectified CCH inlet flow) and configuration 2 (right, swirl flow at CCH inlet) with ambient inlet temperature and 4 kW heating power of EHC. (©Boysen)
The Compact Catalytical Heater (CCH): Thermal Management …    89 Within warm exhaust gas and especially within additional HC-injection the isolines would be drifting to higher mass flow. Downstream of the bypass-path the gas temperatures the temperatures have a similar tendency of the relation to the mass flow and the flap position (Fig. 15). Fig. 15.  Mean gas-temperatures at pos. 2 for configuration 1 (left, rectified CCH inlet flow) and configuration 2 (right, swirl flow at CCH inlet) with ambient inlet temperature and 4 kW heating power of EHC Within the CCH the total heat flux impact to the exhaust gas is almost independent of the partial bypass-mass flow based on the conservation of energy (Fig. 16). Fig. 16.  Mean gas-temperatures at pos. 4 for configuration 1 (left, rectified CCH inlet flow) and configuration 2 (right, swirl flow at CCH inlet) with ambient inlet temperature and 4 kW heating power of EHC. (©Boysen) Based on thermodynamic principles and simplifications (cp = const.) it is possible to determine the bypass mass flow through temperature increase in dependency of the total mass flow and the flap position on the hot gas test bench (s. Fig. 17). Q̇ = ṁ ˆ T2 cp (T)dT T1 (2)
90    M. Presti et al. ṁ = Pel (T2 − T1 ) · cp (3) Fig. 17.  Calculated bypass mass flow based on measurements with configuration 2 (swirl flow at CCH inlet), ambient inlet temperature and 4 kW heating power of EHC. (©Boysen) To gain a desired temperature of the EHC it is necessary for a feed forward control strategy of electrical heating and dosing HC to consider the current bypass-mass flow. 3.6 Validation on Engine Dyno The CCH-system is validated in combination with a modified exhaust aftertreatment system of an EU-VI truck: an EHC with hydrolysis coating (H-EHC) is installed in the AdBlue® mixing path upstream of the SCR catalysts (Fig. 18). The inlet of the muffler includes a perforated baffle, which enhances the temperature homogenization and the HC-uniformity. The urea fluid is injected inside the center of a swirl flow for an optimized urea mixing. The integrated EHC has a 9 mm heating disc and 165x40 mm support catalyst with 300/600 LS-PE® structure, which enhance the mixing of generated urea (CH4N2O, liquid/gas), Isocyanic acid (HNCO, gas) and ammonia (NH3, gas).
The Compact Catalytical Heater (CCH): Thermal Management …    91 Fig. 18.   Modified exhaust aftertreatment system of an EU-VI truck with an integrated electrically heated catalyst (EHC) downstream of the urea injection module combined with CCH. (©Boysen) Tests are conducted on a 15 l – US-2010 engine. Among others the following three configurations are examined: 1. the modified EU-VI system without active heating as a reference (not shown on Fig. 18), 2. the modified EU-VI system with heating of the “internal” Hydrolysis-EHC (Fig. 18 – upper config.), 3. the modified EU-VI system with heating of the upstream CCH (Fig. 18 – lower config.). For configuration 1 & 2 the flap of CCH is all the time fully open to reduce the impact on backpressure and temperature loss. When the Hydrolysis-EHC is heated inside the exhaust-box, the urea release temperature in the control module is lowered, as the temperature sensor is located upstream the heating device. The maximum electrical energy for configuration 2 and 3 is 4.3 kW. This allows to compare the impact of heating downstream the DOC+DPF heat capacity, to the temperature increase in front of the muffler by CCH combined with exothermal HC conversion in the DOC. Figure 19 shows the temperature profile of an FTP cold start, upstream and downstream the SCR catalysts and the urea dosing. With active heating the urea dosing can be released earlier in the cycle, resulting in an improved NOx conversion (Fig. 20). Electrical heating of the hydrolysis EHC with 4.3 kW (downstream the DPF) causes a fast temperature-increase in front of the SCR catalysts – while heating with CCH (upstream of the main DOC) shows a delayed heat-up in the first 220 seconds due to the heat capacity of the DOC and DPF. Nevertheless, urea dosing can start earlier for the heated CCH as the temperature at the dosing position (upstream the hydrolysis catalyst) is higher. With CCH the electrical energy [in kWh] could be reduced by 12% compared to the heating of the hydrolysis-EHC.
92    M. Presti et al. Fig. 19.  Temperature up- and down-stream of the SCR catalysts & urea dosing in FTP cold start. (© Vitesco Technologies GmbH) Even a larger improvement by active heating can be seen in the Low Load Cycle (LLC). The electrical energy for CCH to keep the SCR system within the optimal temperature window is in this cycle also reduced by 12% compared to hydrolysisEHC, while the NOx-conversion improved from 92.8 to 99.3% (Fig. 20). Fig. 20.  NOx conversion rates in FTP and low load cycle. (© Vitesco Technologies GmbH) Here it is evident, that 4.3 kW max power is not sufficient for the engine/massflow combination if used at the hydrolysis-EHC position. Conversely with CCH (using the same electrical power) a higher temperature level can be maintained in the SCR catalysts (Fig. 21) resulting in lower NOx tailpipe emissions. (Fig. 20).
The Compact Catalytical Heater (CCH): Thermal Management …    93 Fig. 21.  Temperature up- and down-stream of the SCR catalysts & urea dosing in low load cycle. (© Vitesco Technologies GmbH) 4 Summary Based on the results presented and information from literature, it will be essential to provide CO2-optimized heating measures for the exhaust system to reach the future limit values as well on-road as also off-road in Europe and in the USA. One possibility is to run the engine in a “fuel consumption optimized map”. The required heating measures are implemented directly in the exhaust system with high efficiency and low heat losses – largely independent of engine operation. This also allows a higher flexibility for hybrid operation. Electrical energy for exhaust heating on board is limited. A significant increase in heat-energy output can be achieved by catalytic conversion of fuel on the electrically heated oxidation catalyst directly in the exhaust system. The electrical energy is used “only” to ensure the “ignition” of the catalyst. A bypass allows to reduce the electrical power demand for the light-off. Electricity from recuperation reduces the add-on fuel consumption. The presented compact catalytical heater is intended to be installed upstream of today’s muffler boxes within the typically long inlet tubing. The additional backpressure of the system can be considered small, as the system is only operated when heating is required. During high load operation – the exhaust aftertreatment components are typically within their operation window – no heating is required, and the flap is open creating almost no additional flow restriction and means no additional fuel consumption.
94    M. Presti et al. Thus, already proven exhaust systems or components can be reused. This reduces development and testing effort as well as tooling costs for new configurations and opens some flexibility for different markets. In addition, the CCH enables a great degree of flexibility for the integration of the system in various powertrain configurations (hybrid) and vehicle architectures (On-, Off-Road). Decisive for future solutions will be the overall system and operating costs (“total cost of ownership”; TCO). References 1. Rodríguez, F., Badshah, H.: Real world NOx performance of Euro VI-D trucks and recommendations for Euro VII. International council on clean transportation (2021) 2. Desouza, C.D., Marsh, D.J., Beevers, S.D., Molden, N., Green, D.C.: Real-world emissions from non-road mobile machinery in London. Atmospheric Environment (2020) 3. Holz, O., Presti, M.: Thermal Management for Low NOx Applications in Heavy Duty Vehicles, ATZ heavyduty worldwide 02/2021 (pages 36 ... 39) 4. Brück, R., Presti, M., Keck, M., Dengler, J., Faiß, M.: Thermal Management on Demand; the Exhaust Aftertreatment Solution for Future Heavy Duty Application, ATZ Live international 8th engine congress (2021) 5. Holz, O., Presti, M., Mosch, T., Dachsel, J., Rodatz, P., Fink, F., Nienhoff, M.: Heavy Duty Exhaust Systems for Low NOx Application: Thermal Management and Control, ATZ Live Heavy-Duty-, On- und Off-Highway-Motoren (2020) 6. Brück, R., Presti, M., Holz, O., Geisselmann, A., Scheuer, A.: Der Weg zur Erreichung der “CARB post 2023” Emissionsgesetzgebung für Nutzfahrzeuge. 38th International Vienna Motor Symposium, Vienna (2017) 7. Presti, M., Scheeder, A., Holz, O., Brück, R.: Motornahe Abgasnachbehandlung im Nutzfahrzeug: eine Lösung für CARB 2020 NOx? 8th Emission Control Conference, Dresden (2016)
Liebherr’s Approach to Hydrogen Fuel Injection Systems Richard Pirkl1, Mario D’Onofrio2(*), Lydia Kapusta1, and Dennis Herrmann1 1 Liebherr-Components Deggendorf GmbH, Deggendorf, Germany {richard.pirkl,Lydia.Kapusta, dennis.herrmann}@liebherr.com 2 Liebherr Machines Bulle SA, Bulle, Switzerland Mario.Donofrio@liebherr.com Abstract.  Liebherr develops hydrogen fuel injection system solutions to be used in on- and off-highway hydrogen combustions engines. Heavy-duty off-highway applications have partly different requirements compared to onhighway applications. Robustness against dust, dirt & vibrations and other harsh environmental conditions must be given. Additionally higher peak power demand and more dynamic load cycles increase the requirements on the transient performance of the engine. To meet these requirements, Liebherr has developed a complete hydrogen injection system that includes all the components needed for pressure regulation and fuel dosing. Throughout the development, real load cycles of heavy-duty mobile machinery have been considered to properly design the system and its components. This paper will provide detailed insights on the layout, design and functionality of the hydrogen injection system. In particular, the dynamic pressure regulation by means of a gas metering valve is shown and how this approach enables diesel-like transient engine behavior. Furthermore, first test results on the system performance are provided. Additionally an overview on the common platform approach to the Liebherr portfolio of hydrogen fuel injectors for port fuel injection (PFI) and direct injection (DI) incl. actual test results will be given. Liebherr’s approach to hydrogen fuel injection systems are not only limited to heavy duty commercial engines. Also components for large engines are considered in the overall platform approach. Keywords:  Hydrogen combustion engine · Hydrogen injection system · Low pressure direct injection · Port fuel injection · Alternative fuels 1 Introduction Reducing greenhouse gas emissions and thus limiting global warming below the 2 °C target is one of the key challenges of the 21st century. The importance of this goal is also reflected by the high amount of programs and regulations towards greenhouse © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 95–111, 2023. https://doi.org/10.1007/978-3-658-41477-1_7
96    R. Pirkl et al. gas reductions that are currently proposed or becoming effective. The European “Fit for 55”, the “European Green Deal” & the Californian “Advanced Clean Truck” are mentioned here as representative for the ongoing global activities. The ongoing political activities influence the development activities of OEMs all other the world. Development activities are shifted more and more towards alternative powertrains and alternative fuels like hydrogen, methanol & ammonia for example. Currently many public announcements on all kind of a zero CO2 powertrain solutions from the hydrogen fuel cell to the hydrogen combustion engine can be found. Especially in an environment that is shaped by a dynamic change process regarding today’s powertrain concepts the hydrogen combustion engine can offer some advantages over the fuel cell. Existing production facilities and basic engine components can further be used. Packaging on existing equipment is relatively easy possible and the hydrogen combustion engine allows for lower requirements on the H2 purity and air cleanliness. Mobile construction equipment and other off-highway vehicles and machinery in particular can profit from these advantages of the hydrogen combustion engine. Taking additionally into account the high variety of different off-highway machines it becomes obviously that an integration of fuel cells will not be possible in the short to mid-term into all of these machines. Thus the hydrogen combustion engine cannot only be seen substitutional to the fuel cell but complementary in a technology open approach [1]. The hydrogen injection system is one of the performance determining and at the same time most challenging component for a hydrogen combustion engine. Liebherr develops different hydrogen fuel injection systems and components for port fuel and direct injection for commercial heavy-duty and large engines. 2 Hydrogen Fuel Injection System 2.1 Concepts for Hydrogen Fuel Injection Main fuel injection concepts for hydrogen are multi or single point port fuel injection (PFI) or direct injection (DI). Below Table 1 summarizes some key characteristics for the main combustion concepts in combination with hydrogen. The theoretical specific power level of the H2 internal combustion engine (ICE) should be comparable high, based on the high mixture calorific values. Nevertheless, all the hydrogen engine concepts that have been published during the last years could not fulfill the theoretical expectations. One major reason for this is that all these concepts where based on PFI due to a lack of components for DI [2]. In the meantime PFI concepts have improved in terms of performance, but there is still a significant gap to the level of a diesel engine [3]. As shown in Table 1 recently published engine tests lead to the result that the efficiency level of a spark ignited engine with pre-mixed combustion is for both injection concepts (PFI and DI) on the same level [4]. Intuitive one would expect that the DI injection lead to a higher efficiency level compared to the PFI, thanks to a better cylinder filling combined with optimized combustion timing. These benefits are again compensated by higher wall heat losses and gas ex-change work. Finally,
Liebherr’s Approach to Hydrogen Fuel Injection Systems    97 measured efficiency levels for PFI and DI are today on the same level, but the DI injectors used for the published test results have not been fully optimized in respect of spray and mixture formation [2, 4]. It still can be expected to achieve an efficiency benefit for DI in comparison to PFI. Even so, the results on the efficiency with H2 DI today have not revealed their full potenzial, one major benefit of DI over PFI is out of discussion. The maximum achievable specific power density of H2 DI engines is higher than for H2 PFI engines applying the same charge air pressure level, since air displacement effects by the hydrogen injected into the intake air manifold lead to a lower mixture calorific heating value for PFI. Table 1.  Hydrogen combustion key characteristics (hydrogen values based on [5]) Positive/spark ignited pre-mixed combustion H2 injection pressure Mixture calorific heating value Powerdensity Efficiency Risk of backfire H2 storage and tank utilization Efforts for fuel injection system PFI ≤15 bar 3–3.2 MJ/m3 Low pressure DI ≤60 bar 4.2–4.5 MJ/m3 −20–−30% compared to diesel ~42% high All gaseous H2 storage tanks (350–700 bar) Thanks to low injection pressures good usage of the tank volume But injection pressure levels may be too high for liquid H2 (LH2) tanks −10–0% compared to diesel ~42% low All gaseous H2 storage tanks (350–700 bar) Higher injection pressure levels lead to less efficient usage of the tank volume Lower driving/ working range possible compared to PFI Use of LH2 tanks only with cryogenic pump Low (based on existing natural PFI technology) Compression ignited diffusive combustion High pressure DI 250–350 bar > 4.5 MJ/m3 Comparable to diesel > 45% No risk of backfire Gaseous storage is possible, but compression will be required very early. Due to this gaseous storage might be inefficient for high pressure DI LH2 storage will require a cryogenic pump, but offers the possibility for more efficient compression Highest demand on H2 storage Medium High (new injector concepts (new injector concept and multi-level H2 and H2 compression pressure control) required) Highest efficiency levels and best transient performance can be enabled by means of high pressure DI in combination with a diesel-like diffusive combustion concept. For high pressure hydrogen fuel injection one major additional challenge arises. This is the supply of hydrogen at comparable high pressure levels up to 350 bar. In case of
98    R. Pirkl et al. compressed gaseous hydrogen storage (even at 700 bar tank pressure), a compressor is required to use a reasonable part of the hydrogen tank capacity. It is common knowledge that gaseous compression is very inefficient requiring large compressors and thus from today’s point of view no option for mobile applications. Liquid hydrogen storage and compression with a cryogenic pump will be favorable in terms of compression efficiency but cost and availability of the required tank system and pump is likely to be an issue in the near future. Due to the complexity of hydrogen storage and compression high pressure DI is not the primarily focus of Liebherr. Liebherr is developing components and system solutions for PFI and DI. The system approach shown in the following is valid for PFI and DI systems although the following pictures and graphics will mainly show the DI system as example. 2.2 Introduction: Main Requirements on the Hydrogen Fuel Injection System The overarching goal for the H2 ICE is to offer the same performance and driving characteristics as a diesel engine, at the same displacement. The typical rated output of a 13-litre 6-cylinder engine is 400 kW (on-highway) and can be up to 450 kW (off-highway). A static flow of 11–12 g/s is required to achieve the specific output of 75 kW/cyl. Injection quantities ranging from approx. 2.5 mg during idling up to at least 110 mg under full load must be possible. These basic requirements are valid for both injection concepts, PFI and DI. In light of these very basic requirements, it becomes clear that injection pressure modulation will be required to fulfill the minimum and maximum injection quantity requirements. Depending on the application profile, demanding transient requirements must also be met. The transient behavior is important for both on- and off-highway applications. Off-highway applications such as wheel loaders have a more dynamic load profile than heavy trucks, for example. This is reflected in more frequent changes between low/noload and full-load operation. Lower injection pressures (at ~10 bar for DI and ~4 bar for PFI) are required to achieve the minimum injection quantities for engine idling, while full load operation requires higher injection pressures (up to 30 or even 60 bar for DI and max 15 bar for PFI). Highly dynamic pressure control is required to meet the transient requirements and to achieve a load assumption comparable to that of diesel solutions. Table 2 summarizes the main performance requirements on the hydrogen injection system. Table 2.  Hydrogen injection system: comparison in term of flow and pressure requirements System type Injection pressure Static flow rate Injection duration Max. quantity range Min. quantity range Pressure control DI PFI 10–30/60 bar 3–15bar min. 11 g/s up to 15g/s up to 12 g/s ≤7.5ms ≤10ms ~100–110 mg/stroke ~2.5 mg/stroke highly dynamic, enabling fast pressure reduction in foot-off mode
Liebherr’s Approach to Hydrogen Fuel Injection Systems    99 Especially in DI applications relatively short injection duration is crucial in order to achieve the required performance levels. So, it is important to understand how flow conditions, cylinder backpressure and injected quantity are linked to each other and why supersonic or supercritical flow conditions help to achieve the injection quantity targets. The relationship between the state of the system that is expressed by pressure (Pup) and temperature (Tup) and quantity introduced into the combustion chamber can be expressed via Eq. 1, which gives the mass flow rate of a compressible ideal gas through an orifice: Pup dm = ACq Cm  Tup (1) where Pup, Tup are temperature and pressure upstream the injector metering area A (for sake of simplicity assumed corresponding to the value sensed inside the hydrogen system rail), Cq the flow coefficient, Cm the flow parameter. The flow coefficient Cq is less than one and is used to include friction losses and a phenomenon known as vena contracta. Flow condition and gas type are accounted in Eq. 1 via the flow parameter Cm. The goal of bringing the performance provided by an H2 DI engine up to those typical for a Diesel engine requires that the system is capable of guaranteeing high flow rates. The higher the injection pressure, the higher is the quantity of hydrogen which is possible to inject in a given time as the flow increases proportionally to the upstream pressure. If the hydrogen flow reaches supersonic (speed of sound) velocity at the metering valve it is in so called choked condition. This means the gas velocity is from now on limited to speed of sound and the injected mass will not decrease in case of downstream pressure variation (cylinder pressure) for a fixed upstream pressure. To ensure a sonic flow condition at injector nozzle the ratio between downstream pressure and the injection pressure must smaller than the critical pressure (Eq. 2). Pcombustion chamber = pinjection  2 γ +1  γ γ −1 (2) For hydrogen with a heat capacity ratio γ in the range of [1.406 @ 20 °C ÷ 1.399 @ 100 °C] critical pressure ratio varies around ~0.52. This means that the injection pressure must be about twice the backpressure in the cylinder. Based on this physical requirement, Fig. 1 shows an example of the possible DI injection windows under sonic flow conditions for 30 and 60 bar rail pressure from inlet valve closure. At 60 bar rail pressure injection the maximum cylinder pressure within the barriers for sonic flow conditions is 30 bar. At 30 bar rail pressure the maximum cylinder pressure to stay within sonic flow conditions is 15 bar. Higher rail pressure thus enables a significantly longer injection window and thus potentially higher power per cylinder.
100    R. Pirkl et al. Fig. 1.  Example of injection windows at different injection pressure levels 2.3 Real-World Off-Road Engine Transient Requirements The application load profile is determined directly from measurements on real machines and converted into the H2 fuel requirement. Since the wheel loader has one of the most dynamic load profiles of mobile construction machinery, it was chosen as the reference. Fig. 2.  Mission profile measurements for a Liebherr wheel loader
Liebherr’s Approach to Hydrogen Fuel Injection Systems    101 The mission load profile is derived from measurements on today’s diesel powered machines. Relevant parameters are recorded at high sampling rate and later on converted in H2 system fueling requirements. Figure 2 shows mission profile information recorded for a wheel loader. Figure 3 shows how the machine mission profile has been converted in H2 fueling quantity requirements. In order to achieve the same level of drivability for the H2 system as for diesel systems, the dynamic levels in terms of torque and power must be equivalent. In terms of the demands on the H2 system, this leads to high gradients for the regulation of fuel quantities, especially during the transition from idling to full load, and thus also to very dynamic, transient demands on the system pressure. Fig. 3.  Mission profile conversion into hydrogen fueling requirements The wheel loader is run in full load for only ~5% of its operating time. Most of the time it runs at low load or idles. Another major challenge is the very frequent load jumps between full load and idling and the associated reduction in system pressure. These operating conditions differ greatly from a railway application profile (high load without frequent load changes), for example. 2.4 System Design & Layout The structure of the H2 system is determined by the vehicle layout and installation space. The goal of the Liebherr H2 system is to allow for fast and accurate pressure and flow control, regardless of the position of the fuel tank, engine, vehicle size and layout. The Liebherr design is compatible with two-stage pressure control as shown in Fig. 4 which, based on simulations and experimental results, offers clear advantages in terms of dynamic pressure control.
102    R. Pirkl et al. Fig. 4.  Proposed system layout: 2 stages regulation In stage 1 by means of a pressure regulator (LPR), the filling level dependent tank pressure is controlled to a variable or fixed predefined set point. In stage 2 by means of a gas metering valve (LGV), the rail pressure is controlled to a set point that is dependent on the operating conditions. The value of the rail pressure which feeds the injectors is the results of the mass flow balance between the mass flow entering the system and the mass flow which leaves the system (flow injected by each injector according to the engine power demand). This process is described by the following differential equation   Ninjectors dm  � = −ṁout i  + ṁin dt (3) i=0 here m is the mass of the gas within the control volume . m = ρcontrol volume Vcontrol volume The injection pressure is regulated by operating the GMV via the electronic unit control (ECU). The ECU uses the information provided by the pressure and temperature sensors installed on the rail in combination with the required injection quantities as per engine map to calculate the amount of gas to be delivered via the GMV and controls thus the rail pressure. A key component of this system layout is the GMV that serves two functions. First the control of gas mass flow in proportional operation and second the shut-off function between pressure control valve and rail. The Liebherr H2 system is conceived for operating without any electronic pressure relief valve. The idea is to keep the system layout as simple as possible as well as not releasing any hydrogen gas in atmosphere during operation (which may be critical due to safety restrictions or special application requirements).
Liebherr’s Approach to Hydrogen Fuel Injection Systems    103 In order to be used in many different applications, regardless of whether DI or PFI engine are considered, a common system layout is proposed. Therefore, the design of the system entails the same pressure regulation concept and the use of a single rail for PFI and DI as can be seen in Fig. 5 (the shown layout of rail and injectors refers to the DI system, for PFI the interface between rail and injectors can be different). Fig. 5.  Liebherr H2 fuel injection system: in evidence the use of a common rail configured as typical diesel like injection system The development work to ensure that a single layout can be adapted to the needs of different applications and engine configurations must be a tradeoff over the following requirements, which sometime are in contradiction: • System pressure gradient up & down from IDLE – full load (bar/s) and vice versa • Pressure stability @ different engine operating points (IDLE, full load, torque point) • Hydrogen volume discharge at engine stop (mainly driven by safety requirements) 2.5 Experimental Results on the Hydrogen System Liebherr has developed a system test bench with the aim of having a tool for research and development activities at system level. The bench (shown in the Fig. 6) can be used to test the complete system or the performances of the individual components (through independent control of the injectors and GMV). The bench is also equipped with a high speed data acquisition (DAQ) and is designed in such a way that the pressure and temperature are continuously monitored and feed backed to the ECU to enable the pressure and injection control functions. The bench is also equipped with a back pressure system connected either to the tip of the injectors or to the outlets of the other components to evaluate their performances under variable and controlled pressure drop.
104    R. Pirkl et al. Fig. 6.  On the left an overview of the H2 system bench, on the right the whole Liebherr H2 system installed including the MPRV up to the injectors Additionally the system test bench permits also the full simulation of a machine profile. In the Fig. 7 a typical case of a 4 cylinder engine running at a constant speed of 2000 rpm at variable load is shown. This case is chosen to demonstrate the typical performances and limitations, our system layout can achieve. In light blue the rail pressure is plotted whereas in red the corresponding injected quantity is plotted. Three relevant cases can be differentiated 1. Engine load increases. In this case the injected quantity is suddenly increased to simulate the transient from IDLE condition to full load. The pressure set point also is suddenly increased and the system pressure follows the set point with a response time < 1ms. An overshoot of the system pressure is also visible, which is not linked to the system layout, but determined mainly by the actual status of the calibration and which is under further optimization. 2. Foot-off operation. in this phase (in the below graph, this event happens two times @ 2a,2b) the engine load is decreased and the injected quantity is also suddenly decreased to simulate the transient from a partial load or full load (2a and 2b) to idle. In the plot it can be seen that the gradients of pressure decreasing are different. In case 2a the idle pressure is reached in 2 seconds while in case 2b in about 5 seconds. This is essentially linked to two factors: the intrinsic characteristics of the injection system and the absolute value of the injected quantity (mg/shot), in case 2b the pressure drops more slowly to the idle value because the injection quantity is one third compared to case 2a and therefore the system depressurizes naturally at a slower speed. 3. The last case illustrated is the case of cut-off or coasting. At this time of the machine cycle the injected quantity required is zero. This typically happens when the vehicle is descending along the slope and the engine is used only as an inertial brake. It can be observed how the rail pressure remains constant at the set point value the system is gas tight as the GMV is completely closed to stop the flow of gas. This behavior is linked to the system layout which, as previously explained, does not use a pressure relief valve. Focusing further on the foot-off operation (case 2), in the lower picture of Fig. 7 the performances of the Liebherr system is compared to the performances of a typical hydrogen PFI system.
Liebherr’s Approach to Hydrogen Fuel Injection Systems    105 Fig. 7.  Simulated machine operation, variable load & constant speed (see above); foot-off benchmark results (see below) In order to compare the two systems, under the same conditions and in a fair manner a benchmark test has been performed. The benchmark is made: at constant engine speed, requesting a reduction of system pressure of 12 bar, and imposing the same amount of quantity injected. Therefore the pressure gradient is purely linked to the physical characteristics of the system and independent of the pressure controller. From the image, it can be observed that the proposed layout is in the order of magnitude, seven times faster than a typical PFI system. Design a system capable of fast transient operation appears contradictory to the requirements of having a system which maximizes the stability of the rail pressure at the different engine operating points. Due to this trade-off between dynamic behavior and pressure stability these two aspects have been carefully evaluated during the system concept phase. The outcome of the benchmark is showed in the Fig. 8 where, for the sake of brevity, only the constant full load operation is analyzed. In a gas injection system, at sonic or choked condition the injected quantity is directly proportional to the injection pressure (see also equation number (1). Thus any deviation of the controlled pressure from the desired set point will generate a fueling deviation. The gas injection system is (similar to the Diesel system) a dynamic system in which the pressure waves into the rail are a result of the external perturbations (injection and feeding events) as well as the natural response of the system (determined by its Eigen-values). It is physically impossible to reach the ideal conditions in which the system pressure is perfectly constant. Therefore the target becomes the minimization of the pressure oscillations.
106    R. Pirkl et al. Looking at the pressure traces shown in Fig. 8 it is possible to observe that the performance of Liebherr solution is very close to the performance of a typical PFI system but at the first glance inferior in term of absolute delta pressure (peak – valley) value observed in the considered measuring window. In reality, unlike Diesel systems in which a significant part of the rail pressure perturbations are generated by the high pressure pump; in hydrogen injection systems the gas is fed by the pressure regulator which has the primary purpose of generating a constant outlet pressure, by acting in response to the pressure variation generated in the rail itself. The system turns out to be self-phased. Therefore the variation of absolute pressure observable over time is not as important as the pressure drop happening during the injection events. Therefore the two systems are equivalent since pressure variation is limited within a band of 0.2bar for both. Fig. 8.  Evaluation of the pressure traces measured Summarizing because of the benchmark results, it is possible to state that the system layout proposed by Liebherr guarantees an excellent dynamic response, superior to typical PFI systems, and an equivalent performance in terms of pressure stability. Furthermore, since the system is designed in such a way that the hydrogen volume discharged at engine stop is minimized; it is possible to affirm without a doubt that the Liebherr system has all the options to become attractive solution for the market. 2.6 Hydrogen Injector Platform Like most hydrogen (and other gas) injector concepts that can be found in literature, the Liebherr hydrogen injectors for PFI and DI, unlike a hydraulically actuated diesel injector, a direct actuated injector. Hydraulically actuated concepts for H2 injectors
Liebherr’s Approach to Hydrogen Fuel Injection Systems    107 also have been shown, but they will require a working fluid in order to open and close the valve and thus lead to a much more complex system structure [6]. Liebherr’s directly actuated H2 low-pressure DI (LDI injectors) and PFI injectors (LPI injectors) are designed to meet the necessary flow rate requirements of heavy-duty engines. The outer dimensions of the LDI injector are close to those of corresponding diesel injectors, particularly with regard to the critical maximum outer diameter. Both injector platforms (PFI and DI) are based on the same technical design platform regarding, actuation, sealing and valve guidance. Injector overview. Main features and design characteristics of the Liebherr H2 injectors are shown Fig. 9. Fig. 9.  Liebherr injector overview Actuator. The injector is directly actuated to open and close the needle. The magnet is thoroughly dimensioned to enable precise actuation (opening and closing) and being at the same time small enough to stay within the requirement limits for the injector outer dimension in the magnet area. From the beginning on, this process has been accompanied by magnet simulations for different magnet concepts and materials. In addition, different magnet materials and installation situations have been simulated to adjust the magnet force to enable on the one hand a proper opening of the injector and on the other hand to reduce the closing delay to a minimum. The magnet is hermetically insulated from the hydrogen to prevent any hydrogen embrittlement risk for the magnet materials Injector nozzle. The injector nozzle of the LDI injector is equipped with a diffusor cap to enable spray formation and bending. In the current sample stage this diffusor cap is exchangeable. This enables cost effective testing cold chamber or single cylinder engine testing of different variants in order to define the best fitting solution. A screw on solution as shown in Fig. 10 realizes the exchangeability of the diffusor cap.
108    R. Pirkl et al. Fig. 10.  Exchangeable diffusor cap Valve design. Liebherr developed a two-valve concept for the DI injector in which an active cold valve controls the hydrogen flow and a passive hot valve decouples the cold valve from the combustion heat and combustion pressure. For the PFI injector only the cold valve is required thanks to the lower temperatures and pressures in the intake manifold. The cold valve is defining the injector flow rate by its flow cross section. The flow cross section is opened and closed by means of the inward opening needle. The guidance concept and material combination is optimized for dry running conditions. The good wear behavior of this concept has already been shown in multiple endurance tests on the hydraulic test bench and also in currently running engine tests. To achieve an effective sealing against hydrogen the valve plate is additionally equipped with an elastomer sealing element. The hot valve is integrated in the nozzle of the injector. The hot valve is an outward opening passive safety valve that is sealing against the engine cylinder. The combustion chamber pressure hereby supports the sealing function. Injector test results. One major development target is the achievement of very low leakage rates. Testing with forming gas consisting of 95% nitrogen and 5% hydrogen on a vacuum leak test bench shows very good results for the Liebherr injector concept. The overall external leakage rate is 1*10–6 mbar*l/s. This means that the injector is considered as gas tight. Reason for the very good leakage test results is the new developed Liebherr twovalve injector concept. The injection rates were measured on a function test bench using an injection analyzer. The test medium was nitrogen and the measured values were subsequently converted into hydrogen values. The backpressure on the injection analyzer test bench is always set to 5 bar. Below described test results refer to the LDI injector. The measured injection rate of the current sample stage show a good stability as well as a good opening and closure behavior (see Fig. 11). A multiple step optimization of the current profile also helped to achieve these results. The linear injection quantity curve allows a precise quantity control at different pressure levels (see Fig. 12).
Liebherr’s Approach to Hydrogen Fuel Injection Systems    109 The required maximum amount of 110 mg is reached at a rail pressure of 30 bar. Injection rates are up to 15 g/s @ 40 bar rail pressure. The minimum quantity targets of ~2.5 mg per stroke are achieved at a rail pressure of 10 bar. All tests were performed with a dry running injector, without the addition of lubricating oil. Several variants of the needle guide were tested in advance in order Fig. 11.  Injection rate curve Fig. 12.  Injection quantity curve (30 bar configuration) to find a solution with good dry-running properties that did not show any significant wear in endurance tests. 3 Summary and Outlook From today’s perspective the hydrogen combustion engine will definitely be one of the powertrain solutions to enable the transition to zero CO2. There are different
110    R. Pirkl et al. hydrogen injection solutions in evaluation. PFI is definitely the fastest and less complex way, but transient performance and power density will show a gap to more demanding requirements. This gap is especially evident for the applications where a hydrogen combustion engine will have the most benefits compared to a fuel cell like non-road mobile machinery and special purpose vehicles. In order to provide solutions for different requirements Liebherr develops components and system for direct and port fuel hydrogen injection. Beside the hydrogen system solutions for heavy duty engines, Liebherr also develops a system with higher flow rates for large engines. Below Fig. 13 shows the future Liebherr hydrogen product portfolio. In addition to H2 applications, the products currently in the development pipeline also have the potenzial to be used with other alternative fuels such as ammonia and methanol, which are already being evaluated in preliminary tests. Fig. 13.  Liebherr injector portfolio
Liebherr’s Approach to Hydrogen Fuel Injection Systems    111 References 1. Weiss, U.: The off-highway sector in the field of tension of future power train concepts – Which chances has the internal combustion engine (ICE) in this industry?, International engine congress Baden-Baden 2022 (2022) 2. Dreisbach, R., Arnberger, A., et al.: The heavy-duty hydrogen engine and its realization until 2025, 42nd International Vienna Motor Symposium (2021) 3. Korn, T.: The new highly efficient hydrogen internal combustion engine as ideal powertrain for the heavy-duty sector, International engine congress Baden-Baden (2019) 4. Lejsek, D., et.al.: Thermodynamic analysis of hydrogen engines with port fuel- and direct injection, 18th Symposi-um “Sustainable Mobility, Transport and Power generation” Graz (2021) 5. Eichlseder, H., Klell, M.: Wasserstofff in der Fahrzeugtechnik, 4. Aufl. Springer Verlag GmbH, ISBN 978-3-658-20446-4 (2018) 6. Nogami, M., et. al.: Development of a Common-rail Type High Pressure Hydrogen Injector with a Large Injection Rate and an Ability of Multiple Stage Injection, 18th World Hydrogen Energy Conference (2010)
Hydrogen Dosing Systems for Large Engines: Challenges and Potentials of Three Different Approaches Enrico Bärow(*), Michael Willmann, Andreas Kühner, and Rick Boom Woodward L’Orange GmbH, Porschestraße 8, 70435 Stuttgart, Germany {enrico.baerow,michael.willmann, andreas.kuehner,rick.boom}@woodward.com Abstract.  Hydrogen dosing systems for large engines are available as low pressure gas admission valves in the intake manifold, as mid pressure port fuel or direct injection systems and high pressure dual fuel systems. Here the first three options are used to operate the engine in an Otto-cycle mode, where the last injection system allows a Diesel-like combustion process. All four engine concepts have their validity in their individual application. Key aspects for choosing one of the combustion technologies are system and operating costs – strongly related to the tank and periphery technologies needed to provide a certain system pressure for the dosing system. The pressure and power range as well as the functionality of all systems, operating conditions and limitations will be discussed. Main challenges in the development and the practical application on an engine are shown as well as the corresponding technical solutions. Where available, combustion results will be shared to support the working hypothesis for the selection of individual concepts / systems. A final conclusion will indicate individual benefits and will give an outlook, which system has to be expected on which engine application in the field. Keywords:  Hydrogen injection · High pressure Dual Fuel · Direct injection · Port fuel injection 1 Introduction The costs for electric power generation from renewable energy sources have been plummeting for years. Today, they are cost competitive even without subsidies in most regions of the world. Political instabilities in the world seem to accelerate the trend towards non-fossil fuels – the price gap between fossil and non-fossil fuels is narrowing [1]. © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 112–122, 2023. https://doi.org/10.1007/978-3-658-41477-1_8
Hydrogen Dosing Systems for Large Engines …    113 It can be expected, that over the next years Power-to-X (P2X) technologies will follow a similar cost decline as they scale up rapidly [2]. Legislative initiatives mainly in Europe and the USA are also targeting a massive acceleration of market maturation for renewables and especially green Hydrogen. On the basis of green hydrogen, it will be possible to create cost competitive synthetic fuels with a zero carbon footprint. These synthetic fuels easily can be used to achieve a dramatic reduction of greenhouse gas emissions, especially in applications, where a direct electrification and battery electric drives are not feasible. From today’s perspective each of the P2X fuels will have favorable applications where its fuel characteristics offer advantages over the competing P2X fuels. 2 Applications for Hydrogen Use The fuels shown in Fig. 1 are the most widely discussed P2X fuels. From the perspective of being GHG neutral they all have one commonality: they need to be produced from green hydrogen. The conversion of hydrogen to more complex chemicals improves the ease of storage but also increases the total costs and energy demand of production, especially if carbon capture is needed to generate hydrocarbon fuels. It is shown in Fig. 1, how much fuel volume is necessary to store a certain amount of energy. It can be seen, that for LNG, Methanol and Ammonia, the volume is almost two to three times as large as for Diesel or heavy fuel oil (HFO). For hydrogen, both liquid and compressed, the required volume is much larger. The increased efforts for the insulation of cryogenic or a pressure vessel for the compressed hydrogen worsens this ratio. The storage of hydrogen in a liquid organic hydrogen carrier (LOHC) seems to require less volume than for the storage of pure hydrogen. But there are still some challenges left: e.g. the storage of the discharged oil, the reconversion yield, the necessary additional infrastructure (e.g. a hydrogen buffer tank) and the high energetic efforts to release the hydrogen. Fig. 1.  Required volume in liter of P2X fuel for storage of 10kWh (without storage tank)
114    E. Bärow et al. Due to the high efforts for the storage of pure hydrogen, this fuel can preferably be used in short to intermediate range applications (see Fig. 2). The maps show a systematic approach to identify the best P2X technologies for different applications, divided in mobile (top) and stationary applications (without grid connection; bottom). Grid based power generation does not apply to this categorization methodology because they offer “unlimited” range. For short range and especially highly utilized applications direct electrification or fuel cells might be the best solution because the high system efficiency outweighs the higher investment costs for fuel cells or battery energy storage. Internal combustion engines, on the other hand, offer a higher power density and higher efficiency at high loads – and are available at lower investment costs. Fig. 2.  Schematic segmentation for choice of P2X technology, top: for mobile applications, bottom: for (off-grid) stationary applications
Hydrogen Dosing Systems for Large Engines …    115 3 Injection Technologies Fig. 3.  Product portfolio of WLO injection technologies for different injection pressures and fuels Woodward offers a broad range of injection technologies that are designed or adapted to inject synthetic fuels, either gaseous or liquid. Figure 3 gives an overview of injectors and valves for different pressures and different fuels. Basically, these are differentiated into: – Low pressure gas admission systems including SOGAV gas valves and EPRS pressure regulation valves, – low pressure atomizers for liquid fuels, – medium pressure injectors for gaseous fuels (plate valve) or liquid fuels, – high pressure dual fuel injectors The whole injector portfolio not only covers different fuels but also different injection arrangements either as port fuel injection (PFI) or direct injection (DI) into the cylinder head. All injectors either were developed in the past years or are currently under development in different projects. This publication focuses on the injection systems for hydrogen for internal combustion engines (see Fig. 3, bottom line). As mentioned before, each application brings its own requirements regarding the fuel, the fuel injection system and hence the combustion process. The main aspects to take into account are threefold:
116    E. Bärow et al. – the source of hydrogen (defining e.g. pressure, temperature, phase state) – requirements regarding injection system (retro fit vs. new-built, simplicity with respect to actuation) – engine requirements (power density, efficiency, transient operation requirements) Figure 4 illustrates schematically the recommended correlation between available infrastructure, engine requirements and the most feasible injection systems. Other combinations would also be possible and mainly depend on specific boundary conditions. On the next chapters the different hydrogen injection systems will be explained. 3.1 High Pressure – DI Fig. 4.  Correlation between hydrogen infrastructure, expected engine efficiencies/break mean effective pressures (BMEP) and recommended injection system For high pressure dual fuel applications Woodward L’Orange introduced the new high-pressure dual fuel (HPDF) injector family [3, 4]. It allows the injection of both, diesel fuel at up to 2200 bar and a second (carbon neutral) fuel at 600 bar directly into the cylinder. Although the injector was designed for the injection of natural gas as well as liquid fuels, with modifications it can be adapted for the injection of hydrogen. The diagram in Fig. 5 (right) shows the differences in the energy injection rate. For the same injection pressure, operation conditions and spray configuration the diagram compares the amount of energy that is injected for a certain injection duration – basically taking into account the different velocities inside the spray holes, the different state of the fuel (gaseous vs. liquid) and the different energy densities of the fuel. Although of these differences it can be seen, that for 500 bar the injected amount of energy with hydrogen is of the same order as for Methanol for the same spray configuration.
Hydrogen Dosing Systems for Large Engines …    117 Fig. 5.  HPDF injector with 3-1-needle arrangement (left). Comparison of achievable engine powers only with respect to chemical and physical properties of the fuels (right) The high-pressure direct injection of hydrogen allows a diesel like combustion process. On one hand this would allow highest efficiencies, best transient behavior and high power densities. But this might also lead to one of two major drawbacks: 1. the inhomogeneous mixture would lead to a combustion close to stoichiometric conditions. As a result, this would lead to high flame temperatures and hence to a strong formation of NOx. With those emissions to be limited, this might have a negative effect on cylinder power and efficiency. Fig. 6.  Comparison of required power for compressing different fuels to high pressure 2. The compression of hydrogen to very high pressures is very energy demanding. Figure 6 illustrates the theoretical power for different fuels to be compressed to a certain pressure. The compression power is normalized by the mechanical engine power output. It can be seen, that due to the lower energy content of the P2X fuels the compression power is higher than for diesel fuel, even at lower end pressures. It can also be seen, that for hydrogen there is a big difference, if hydrogen is either cryogenic/liquid or gaseous at high pressure. Assuming a tank filling of 20% of a 700 bar storage tank, which equals roughly 100 bar remaining tank pressure, a compression to 600 bar injection pressure would be about three times as power consuming as for liquid hydrogen. Higher tank fillings (tank pressures) would reduce the required power/energy, whereas lower tank pressures would increase it even further. In [8] it is shown, that the actual compression energy for hydrogen is mostly twice as much as the theoretical.
118    E. Bärow et al. Due to these two reasons a critical view on the field of high power density application should be made when choosing a hydrogen HPDF concept. The right infrastructure (availability of high pressure Hydrogen or liquid Hydrogen and Cryogenic pumps) and a well-tuned combustion process (i.e. including exhaust aftertreatment) are inherent for the use of HPDF with hydrogen. Fig. 7.  Medium pressure injector for hydrogen injection (plate valve design) 3.2 Medium Pressure – DI & PFI Woodward L’Orange has designed a new injector, especially made for the injection of hydrogen (see Fig. 7). It features a direct electric actuation and can be operated with system pressures of 15–60 bar. Due to the low density of hydrogen, a large cross section in the needle seat needs to be opened. Therefore, the injector is designed with a plate valve nozzle. It can be applied in two different ways: either for port fuel injection (PFI) or direct injection (DI) in the cylinder head (see Fig. 8). Both arrangements have their benefits and disadvantages. Arranged for port fuel injection, it allows a good mixing of the injected hydrogen with the air to achieve a homogeneous mixture. This can be achieved by placing the injector close to the engine’s inlet valves and by optimizing the injection timing towards mixing. This results in a low knock-tendency and can help to minimize the risk of back fire. Also, with a homogeneous and lean mixture, the engine can be operated at very high efficiencies and with almost no formation of nitric oxides. Besides, as it does not require any space in the cylinder head, the mixture can be ignited by a central ignition source (e.g. spark plug). This concept would be perfect for the retrofit of an engine because the cylinder head does not need to be modified. The downside of the PFI arrangement is a reduced cylinder filling with air – and so a lower power density.
Hydrogen Dosing Systems for Large Engines …    119 On the other hand, the injector can be used for direct injection. In this configuration, the injector is integrated into the cylinder head and the injection timing is limited to a smaller time frame. There is less time for mixture formation until top dead center, which will result in a more inhomogeneous mixture, higher NOx and slightly higher risk of knocking. But this more extensive arrangement leads to some other benefits. The injection timing and cylinder pressure conditions during injection allow a higher filling rate (air+fuel) in the cylinder – and so a higher power density. Due to the shorter delay between injection and ignition, the danger of pre-combustion due to oil leakage in the cylinder is reduced. Last, but not least, this arrangement is not sensitive to back firing and can perform faster load transitions (Fig. 9). Fig. 8.  Arrangement of medium pressure injector for PFI or DI 3.3 Low Pressure – PFI Fig. 9.   Solenoid operated gas admission valve (SOGAV), left, and electronic pressure regulation system (EPRS), right
120    E. Bärow et al. For many years the SOGAVTM (Solenoid Operated Gas Admission Valve) port fuel gas admission valves have been used for applications where gaseous fuels need to be injected at low pressure upstream of the cylinder intake valves. The pressure range typically is from 5 to 10 bar. It offers a direct actuation and so it is an easy to use and well proven robust design gas admission valve. In combination with the ECU (Woodward LECM) it is possible to detect open and closed position with a so called virtual sensing capability. This virtual sensing makes it possible to monitor in real time the position of the valve position. This makes it a good solution for pure gas or dual fuel engines. Such low pressure dual fuel engines rely on Woodward L’Orange’s diesel injectors as ignition source. These are able to inject smallest quantities of fuel with extreme precision while also being able to run at full power in diesel-mode. SOGAV has been designed to be used in a natural gas and LNG environment. With hydrogen and also ammonia port fuel gas admission systems, the SOGAV fuel gas specification has been expanded into the hydrogen and ammonia applications. The so- called hydrogen and ammonia hardened SOGAV are available for alternative fuel applications. The SOGAV operating principle is based on a differential pressure across the valve. With load changes of the engine the charge air pressure of the inlet manifold is varying. In order to control the differential pressure this requires active pressure control of the fuel gas pressure. The differential pressure across the SOGAV is also used as a control parameter to control the opening duration and optimize the opening duration depending on actual load conditions. I.e. at idle conditions the SOGAV opening would be very short when the nominal differential pressure is maintained and could cause combustion stability issues. Since the introduction of SOGAV these pressure regulators have been based on the mechanical design diaphragm zeropressure regulators with a manipulated back pressure. Modern engines require improved dynamic behavior, which drives more accurate and faster pressure regulation. Alternative fuels, like hydrogen, require even more accurate and fast pressure control. Woodward introduced an Electronic Pressure Regulation System (EPRS) that meets the increased pressure control accuracies. It has a model based control that includes the volume of the gas manifold, in order to optimize the gas pressure response without over- or undershooting the pressure. The EPRS is called a system as it interacts with the SOGAV command signal as a feedforward parameter. A mechanical zero pressure regulator can only act upon a pressure change, while the EPRS already acts on the SOGAV command signal change. This is especially important for the hydrogen low pressure port fuel (i.e. SOGAV) application. 4 Summary The introduction of green hydrogen as an energy carrier for mobile and stationary large engine applications is one of the major steps in the next years. Depending on the specific application a broad range of combustion concepts are feasible due to the
Hydrogen Dosing Systems for Large Engines …    121 favorable fuel properties of hydrogen. Woodward L’Orange provides a broad range of injection systems for those combustion concepts from highspeed engines with ≈100 kW/cylinder up to >1000 kW/cylinder. A platform family concept with broad customization options allows efficient development for each injection systems while also fully meeting the specific needs of each individual engine concept. Acknowledgements. The authors would like to thank all the Woodward members who closely collaborate in the development of the future P2X injector families. We especially appreciate the support we receive from Woodward’s Technology group (know-how and guidance in combustion technology, simulation and design) and Woodward’s rapid prototype network, especially: Greg Hampson, Domenico Chiera, Jessica Deblois, James Wood, John Karspeck and Chuck Brennecke. Abbreviations DI Direct injection EPRS Electronic pressure regulation system HPDF High pressure dual fuel HPDI High pressure direct injection LNG Liquefied natural gas LH2 Liquefied hydrogen LOHC Liquid organic hydrogen carrier MPI Medium pressure injection PC Pre-combustion chamber PFI Port fuel injection SOGAV Solenoid operated gas admission valve References 1. https://www.handelsblatt.com/unternehmen/erneuerbare-energien-gruener-wasserstoff-istzum-ersten-mal-guenstiger-als-wasserstoff-aus-erdgas/28251636.html. Accessed 27 April 2022 2. Zhao, Y., Setzler, B., Wang, J., Nash, J., Wang, T., Xu, B., Yan, Y.: An Efficient Direct Ammonia Fuel Cell for Affordable Carbon-Neutral Transportation. Joule (2019). https://doi. org/10.1016/j.joule.2019.07.005 3. Senghaas, C., Willmann, M., Berger, I.: New injector family for high pressure gas and low caloric liquid fuels. 29th CIMAC Congress Vancouver (2019) 4. Bärow, E., Willmann, M., Aßmus, K., Redtenbacher, C., Wimmer, A.: Operating Experience with a Combined High-Pressure Gas-Diesel Platform Injector. In Eichlseder, H. (ed.), 17. Tagung Der Arbeitsprozess des Verbrennungsmotors: 17th Symposium The Working Process of the Internal Combusition Engine, vol. 103, pp. 141–153. Verlag der Technischen Universität Graz (2019) (IVT-Mitteilungen)
122    E. Bärow et al. 5. Senghaas, C., Bärow, E.: Woodward L’Orange’s New Injector Generation – An Adaptable Injector Family for Future Fuels. 9th AVL Large Engines TechDays, April 21–22, 2021 (2021) 6. Gleis, S., Frankl, S., Prager, M., Wachtmeister, G.: Optical analysis of the combustion of potential future E-Fuels with a high pressure dual fuel injection system. June 23rd/24th, 2020, Kurhaus Baden-Baden (2020) 7. Frankl, S., Gelner, A., Gleis, S., Härtl, M., Wachtmeister, G.: Numerical Study on Renewable and Sustainable Fuels for HPDF Engines, Proceedings of the 2020 28th Conference on Nuclear Engineering, ICONE28-POWER2020–16438 (2020) 8. Gardiner, M.: Energy requirements for hydrogen gas compression and liquefication as related to vehicle storage needs. DOE Hydrogen and Fuel Cells Program Record #9013. Department of Energy, USA (2009)
Hydrogen Storage Technologies Mathias Keck(*), Dirk Bessey, Frank Buehler, and Manuel Eugen Faiß BIN Boysen Innovationszentrum Nagold GmbH & Co. KG, Nagold, Germany {mathias.keck,dirk.bessey, frank.buehler,manuel.faiss}@bin.boysen-online.de Abstract.  In order to achieve the globally agreed carbon dioxide reductions for a heavy-duty vehicle (HDV) several technologies are currently pursued, battery electrical vehicles (BEV), fuel cell electrical vehicles (FCEV), hydrogen-internal combustion engines (H2-ICE) and e-fuels. The total cost of ownership (TCO) is a very important aspect in the transportation sector. The fuel cell electrical vehicle (FCEV) is a very interesting alternative powertrain technology especially for long haul applications. The hydrogen storage technology is a key success factor to achieve the overall TCO requirements. The paper describes the specific requirements and challenges for a hydrogen storage system in a HDV application and compares the three different hydrogen storage technologies, such as compressed gaseous hydrogen (CGH2), liquid hydrogen (LH2) and cryo-compressed hydrogen (CcH2). Keywords:  Hydrogen · Heavy duty hydrogen storage tank system · Fuel cell electrical vehicle 1 Introduction The global reduction of carbon dioxide emissions is a great challenge in the next decade. In [1] the breakdown of the carbon dioxide emissions by countries is shown. Carbon dioxide emissions from Russia, Japan, EU27, USA, China and India have remained at very high level over the last 20 years and have to be reduced. The European Union has committed itself to reduce carbon dioxide emissions until 2050 to be climate-neutral [2]. The decarbonization of the transportation sector is an important part of the solution. Currently most heavy-duty vehicles (HDV) are powered by a diesel combustion engine and thus emit exhaust gas. To reduce the carbon dioxide emissions the diesel combustion engine has to be replaced by an alternative powertrain. There are different technical approaches for alternative powertrains pursued. First of all, internal combustion engines (ICE) could be powered in future with e-fuels or hydrogen. Specially e-fuels could be an interesting solution for the existing fleet using the existing infrastructure. However, also the use of hydrogen for ICE’s is an interesting solution, while only some adaptions on the current combustion technology is necessary. Battery electrical vehicles (BEV) and fuel cell electrical © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 123–130, 2023. https://doi.org/10.1007/978-3-658-41477-1_9
124    M. Keck et al. vehicles (FCEV) are currently more or less equally discussed for future alternative powertrains. Both solutions have their advantages and disadvantages. For electrical powered HDV’s also catenary systems are under investigation for some niche applications. Besides the range, usage and the infrastructure, the total cost of ownership (TCO) plays a very import factor for the owner. Furthermore, it is imperative that whatever powertrain solution is considered that the energy carrier (battery, hydrogen, e-fuel) is produced by a renewable source, such as photovoltaic and/or wind power. Green hydrogen provides an enormous potential to become the energy carrier for the future. Therefore, the appropriate storage technology for hydrogen is keen to achieve the overall requirements. The three most commonly discussed hydrogen storage technologies will be presented and their advantages and disadvantages will be discussed 2 Hydrogen Storage Technologies 2.1 Hydrogen Hydrogen is the smallest atom in the periodic system and one of the smallest molecules. At ambient pressure of 1 bara and ambient temperature of 293 K hydrogen has a gaseous state with a very low density of about 0.082 kg/m3. Accordingly, to this property hydrogen has to be stored at high pressure and / or at low temperature. For low temperatures in cryogenic area, it is also important to differentiate between orthoand parahydrogen because of the different material properties. The critical point of normal hydrogen is at a temperature of about 33 K and a pressure of about 13 bara. Figure 1 shows the phase diagram of normal hydrogen [3] and the application area in the different storage technologies of subcooled/liquid hydrogen (sLH2/LH2) [4], cryocompressed hydrogen (CcH2) [5, 6] and compressed gaseous hydrogen (CGH2). Fig. 1.  Phase diagram of normal hydrogen [3]
Hydrogen Storage Technologies     125 In [7], a comparison of different technologies for energy storage is shown. An important difference between the individual storage technologies is the specific energy, the energy density of the system and the storage medium. In general, the specific energy density of batteries for automotive applications is very low. In comparison gasoline has a very high energy density and specific energy. The highest specific energy can be achieved with hydrogen. Whereas gasoline storage systems have a low system mass, hydrogen storage systems have a heavy composite pressure vessel or a vacuum insulated pressure vessel made of stainless steel. But because of the high specific energy of hydrogen the hydrogen storage tank system has a higher specific energy. According to the state of the art technology battery storage systems are not suitable for long haul trucks which have to cover long distances of up to 800 km per day without a stop for refueling. In the following the different hydrogen storage technologies for commercial vehicles will be presented. 2.2 Liquid Hydrogen Storage System State of the art for cryogenic hydrogen storage systems is the liquid storage technology. Liquid hydrogen at ambient pressure of 1 bara and a temperature of 20 K has a very high density of over 70 kg/m3. But liquid hydrogen storage systems (LH2) have the disadvantage of two receptacles at each vessel because the gaseous hydrogen must be returned to the fueling station. The subcooled hydrogen storage tank (sLH2) has only one receptacle at each vessel and it is possible to refuel both vessels through one receptacle, because there is no necessity to return the gaseous hydrogen. The particular challenge at liquid hydrogen or subcooled liquid hydrogen storage systems is the low storage temperature through a passive cooling technology. The storage systems consist of two vessels, an inner and an outer vessel which are made of stainless steel. Between the inner and the outer vessel is a vacuum gap which is filled with a multi-layer insulation (MLI) to minimize the heat input into the inner tank. Also, the bearing and the piping in the vacuum gap needs to be optimized for low heat input. The lower the heat input, the longer is the so-called hold time of the tank, which is the time until the boil-off of the tank starts. When the temperature of liquid hydrogen increases through the heat input as described above, it results also in a pressure increase within the inner vessel. If the pressure reaches a critical level, the hydrogen is released through a pressure relieve valve (PRV) out of the tank into the boil-off management system (BOMS). The boil-off management system converts the hydrogen into water. Additional challenges are the cryogenic components like the receptacles, cryogenic valves, pressure relief valves or heat exchangers. Figure 2 shows a tank assembly of a sLH2 storage tank and the BOMS from BOYSEN. The diameter of the outer vessel is about 710 mm, the length is about 2500 mm and the inner vessel has a net volume of about 750 l.
126    M. Keck et al. Fig. 2.  Subcooled liquid hydrogen storage system (front) and boil-off management system (top) This configuration enables a usable storage capacity of over 40 kg for each storage tank depending of the operation strategy. The cryogenic connecting pipe, which is also vacuum insulated, allows a refueling of both storage tanks via one receptacle. The vacuum piping and the vessels have not only to be designed for the maximum allowable working pressure, both of them have to be designed for the mechanical stress through excitation caused by the road load. Figure 3 shows a test rig which is simulating a dynamic road load and the test rig for the boil-off management system. The dynamic road load test rig consists of seven hydraulic cylinders which are fixed at a frame of a heavy-duty truck. By means of this test rig it is possible to simulate a real dynamic road load which is measured on the road and adapted to the test rig. The boil-off management test rig enables to simulate the boil-off event without a storage tank system. Furthermore, it is possible to measure the tail pipe emissions, the mixture of hydrogen and the air in front of the catalyst in every condition of the boil-off management system. The pressure loss and temperature, including the investigations of the light-off behavior of the catalyst, are important metrics for the design of the boil-off management system. Fig. 3.  LH2 storage system on test rig (left) and boil-off management test rig (right)
Hydrogen Storage Technologies     127 2.3 Compressed Gaseous Hydrogen Storage Technology State of the art for compressed hydrogen storage systems (CGH2) in heavy-duty trucks is a pressure of 350 bar. Currently refueling procedures for this pressure level are existing. At 350 bar and a temperature of 288 K the density of normal hydrogen increases to 24 kg/m3. Most pressure vessels for this application are type IV vessels. The basic design concept of a type IV pressure vessel is shown in Fig. 4. The inner liner is made of plastic to secure the gas tightness, while the outer skin is made of a carbon fiber to build the load bearing structure. Fig. 4.  Compressed gaseous hydrogen vessel type IV Refueling procedures for 700 bar storage tank systems for heavy duty trucks above 10 kg hydrogen are in discussion. To increase the usable hydrogen mass BOYSEN is developing a compressed hydrogen storage tank system including the vessel for an application with 700 bar for heavy duty trucks. By increasing the pressure from 350 to 700 bar the density of hydrogen increases by 67%. Particular challenges include the development of an on-tank valve (OTV) and a high-pressure regulator (HPR) for a 700 bar application with high mass flow rates. Also, the sealing design between the on-tank valve and the boss is an important part of the development. Furthermore, the high control accuracy at low pressure and high mass flow rate is key to achieve. Compared to the liquid hydrogen storage system the energy density is much lower. Therefore, a frame for up to three or four vessels behind the driver’s cabin is needed to guarantee an appropriate range of the vehicle. Figure 5 shows an example of a concept with six vessels.
128    M. Keck et al. Fig. 5.  Compressed gaseous tank system (CGH2) 2.4 Cryo-compressed Hydrogen Storage System Cryo-compressed hydrogen storage systems (CcH2) for automotive applications became famous with the investigations of BMW [6]. BMW has developed a storage tank system with an operating pressure below 350 bar. The lowest temperature which could be achieved was 33 K. Today the cryo-compressed hydrogen storage technology is still under development. New investigations [5] show that the pressure can be increased to 450 bar. A particular challenge is the combination of high pressure and low temperature. The system needs an inner high-pressure vessel and an outer vessel to build a gap which is filled with a multi-layer insulation in vacuum ambient. Because of the high-pressure level, the boil-off event is much lower prioritized as by the liquid hydrogen storage system. BOYSEN is following the interesting development but there are only activities in preparation to investigate a proof of concept.
Hydrogen Storage Technologies     129 3 Comparison Between the Different Storage Technologies As described in Sect. 2.1 every storage technology has its advantages and disadvantages. Following in Fig. 6 the three hydrogen storage technologies will be compared. Purely looking at the density, the CcH2 tank system seems to be the most favorable one. Furthermore, a boil-off management system is currently not needed. However, it is also the most complex and expensive system. Besides the density the net volume carrying hydrogen is also very important. The huge advantage of the CGH2 technology is that the infrastructure is already existing. Meaning hydrogen refueling stations (HRS) for passenger cars (700 bar) and commercial vehicles (350 bar) are available and even further developed. To be an adequate solution for applications which require a medium range, definitely 700 bar tanks and the appropriate filling protocol for commercial vehicles needs to be established. Furthermore, the design of OTV must be more robust against leakage as a result of wear and tear. Nevertheless, to carry a higher amount of hydrogen per vehicle, there are multiple numbers of tanks necessary in comparison to the sLH2 or CcH2 technology. The sLH2 technology offers from BOYSEN’s point of view the highest potential for long-haul applications and/or applications with a high-power demand. The TCO is superior against the CGH2 and CcH2 technology looking at the total vehicle architecture and system cost. From a technical standpoint the heat loss needs to be absolutely minimized by an extraordinary vacuum insulation in combination with MLI. Furthermore, the bearing concept between the inner and outer tank needs to be designed to carry the load on one hand and to minimize the heat transfer from the outer into the inner tank. These measures sum up in a long hold time of the system. However, a boil-off management system as a safety device is still required. Fig. 6.  Comparison between the three common storage systems
130    M. Keck et al. 4 Conclusions + Outlook Green hydrogen is one of the key elements for carbon dioxide-free road transport. The development of suitable components for hydrogen application is one of the biggest challenge which requires a high competence of the individual supplier. Components such as cryogenic valves or high-pressure valves face automotive suppliers with new challenges, but also offer them opportunities. Another challenge is the certification of the hydrogen storage systems. In addition to hydrogen compatible of the sensor, a safety system such as a BOMS are very important developments in the future. One of the most important advantages of hydrogen storage systems is the short refueling process. The hydrogen storage system enables to cover long distances without long refueling stops. When refueling is required, the sLH2 and CGH2 storage systems should be refueled in the same timely matter like a diesel heavy-duty vehicle. For the use of hydrogen in the future, it is important that a corresponding infrastructure is quickly established. A standardized refueling process and components such as the receptacle for refueling hydrogen storage systems are also very important for rapid acceptance of the technology. Both the CGH2 700 bar technology and the sLH2 technology reduces the packaging problem in vehicles for long ranges and offer a zero-emission strategy for long haul use. There are several ways to achieve the zero-emission goal for commercial vehicles. Hydrogen has a very high potential to become the future energy storage. But hydrogen needs to be produced from renewal energy such as photovoltaic and wind power. Furthermore, the appropriate infrastructure needs to be established fast. Given these premises and a technology open competition, BOYSEN strongly believes that we will see CHG2 and sLH2 technologies in the market based upon the individual application of the commercial vehicle. Therefore, BOYSEN develops intensively the 700 bar CGH2 technology and the sLH2 technology further to achieve market readiness within this decade. References 1. Crippa, M. et al.: GHG emissions of all world countries, JRC SCIENCE FOR POLICY REPORT, 2021 Report (2021) 2. The European Parliament and Council of the European Union.: Regulation (EU) 2021/1119 of the European Parliament and of the Council of 30 June 2021 establishing the framework for achieving climate neutrality and amending Regulations (EC) No 401/2009 and (EU) 2018/1999 (‘European Climate Law’), Brussel (2021) 3. Lemmon, E.W., Huber, M.L., McLinden, M.O.: NIST REFPROP, Reference Fluid Thermodynamic and Transport Properties, NIST Standard Reference Database 23, Version 9.1 (2013) 4. Maus, S., Stanzel, N., Schäfer, S.: Clean Energy Partnership (CEP), Whitepaper process sLH2 (2021) 5. Brunner, T., Forstner, C., Cardella, U.: Clean Energy Partnership (CEP), Whitepaper process CcH2 (2021) 6. Kunze, K., Kircher, O.: Cryo-Compressed Hydrogen Storage. Cryogenic Cluster Day, Oxford (2012) 7. Wunderlich, P.: Electrodes for Lithium-Oxygen Batteries, Dissertation, RWTH Aachen, (2019)
Well-to-Wheel CO2-Analysis of Different Powertrain Systems on Representative Heavy-Duty Mission Profiles Nicolas Hummel(*), Tim Herold, and Christian Beidl Institut für Verbrennungskraftmaschinen und Fahrzeugantriebe, Technische Universität Darmstadt, Darmstadt, Deutschland {hummel,beidl}@vkm.tu-darmstadt.de Abstract.  Im Zusammenhang mit dem Ziel der Europäischen Kommission bis 2030 die CO2-Emissionen um 55 % zu senken, ist besonders der Verkehrssektor gefordert alternative Antriebsysteme für unterschiedlichste Anwendungen zu entwickeln. Der Fokus dieser Arbeit liegt dabei auf der Untersuchung unterschiedlicher Antriebssysteme in der Nutzfahrzeuganwendung. Neben dem Standard Dieselantrieb werden die Well-to-Wheel CO2-Emissionen eines Erdgasfahrzeugs, eines batterieelektrischen Fahrzeugs und eines Wasserstoffverbrenners in verschiedenen Anwendungsfällen untersucht. Die Lastprofile erstrecken sich von dem hochspezifischen Müllsammelbetrieb bis hin zur Warenlieferung auf der Langstrecke. Dabei spielen die Zuladung und die Topographie ebenfalls eine wichtige Rolle. Methodologisch erfolgen die Untersuchungen aller Fahrszenarien nach folgendem Schema. Eine im realen Fahrzeug aufgenommene Strecke wird in die Virtuelle IPG-Truckmaker Umgebung überführt. Anschließend wird das Modell des realen Referenzfahrzeugs erstellt und die erzeugte Simulationsumgebung wird anhand des Vergleichs von realen und simulierten Kraftstoffverbräuchen validiert. Das validierte Referenzfahrzeug dient von nun an als Basis für den Aufbau der Nutzfahrzeuge mit alternativen Antrieben. In diesem Zusammenhang können die Verbräuche der unterschiedlichen Antriebssysteme in den ausgewählten Anwendungen verglichen werden. Zusammen mit den ermittelten Well-to-Wheel Emissionen der betrachteten Energiespeicher erfolgt schließlich die Bewertung des Anwendungsspezifischen CO2-Impakts der einzelnen Antriebssysteme. Das Ergebnis dieses Vergleichs ist neben der variierbaren Simulation durch veränderte Randbedingungen oder Streckenprofile auch die Beantwortung der für Logistikunternehmen aller Art relevanten Frage des ökologischen Optimums. Sie dient im hierbei spezifischen Fall als Orientierungshilfe, um bei einer möglichen Flottenanpassung den ökologischen Aspekt stärker zu berücksichtigen. Keywords:  Alternative powertrains · Well-to-Wheel · CO2 · Simulation © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 131–142, 2023. https://doi.org/10.1007/978-3-658-41477-1_10
132    N. Hummel et al. 1 Motivation The mandatory goals set by the European Commission in the context of the “Green deal” [1] requires a minimum reduction of the greenhouse gas emissions (GHG) by 55% until 2030 in comparison to 1990 and climate-neutrality until 2050. These goals apply to all sectors and especially in the mobility sector, new technologies and methodologies to asses and rate energy paths are required to reach those goals. In Europe, the transport sector causes about 25% of the GHG-emissions. Figure 1 displays the repartition in Germany: Heavy-duty emissions represented 8% of the GHG-emissions in 2020. In this context a reduction of 42% has to be achieved in the transportation section until 2030 while the prognosed heavy-duty traffic volume is supposed to increase by 16.8% from 2020 to 2030 [2]. Those contradictory goals underline the necessity to develop new energy concepts for the heavy-duty sector. Fig. 1.  Greenhouse gas emissions in Germany 2020 [3] In the current rating procedure of the CO2-impact of a powertrain system, only the vehicle use is considered. In this context, 2019 a part of the heavy-duty trucks fleet, representing about 65–70% of the sectors CO2-emissions, where monitored and embedded in the VECTO simulation tool. This procedure is used as a benchmark for
Well-to-Wheel CO2-Analysis of Different Powertrain …    133 the future evaluation of Tank-to-Wheel CO2-emission reduction [4]. Nevertheless, in order to evaluate and compare the climate-impact of different powertrain systems, a comprehensive, system-embracing analysis has to be carried out. In this context the production of the energy carrier plays a major role, as some propulsion systems such as battery electric or hydrogen driven vehicles have zero Tank-to-Wheel CO2emission as the energy carrier does not contain any carbon atom. Nevertheless, depending on the production path, the production of electricity and hydrogen can have a significant CO2-emission factor. In the scope of this work, the production path of every energy carrier is considered in order to compare the powertrains on a Well-toWheel basis and therefore allow a systematic rating of the CO2-impact of a powertrain system. Furthermore, different assumptions for future energy production and CO2impact are made and applied to three different heavy-duty mission profiles. 2 Methodology The reference vehicle, in this case a conventional EURO VI Diesel truck, is monitored during real-life use on typical mission profiles using a data-logger with GPS-antenna and CAN-communication to ECU-datasets. The GPS signal is then used to build a digital copy of the route in IPG-Truckmaker. Depending on the GPS signal quality, the altitude profile has to be smoothed or complemented with accurate datasets (i.e. DGM) in order to obtain a continuous, drivable digital route. The recorded speed profile of the real truck is then implemented on the digital track in form of speed limitation. This v/s-approach secures the correlation of desired vehicle speed and altitude profile regardless of the powertrain and actual speed. In this context different powertrains can evolve at different velocities over the same routes according to their power reserve. In the next step, a digital model of the truck is embedded in IPG-Truckmaker. In this context the vehicle data and the engine maps are implemented. In the following simulation validation step, real and simulated fuel consumptions are compared and if necessary the simulation parameters corrected. At this point the validated vehicle parameters allow to replace the standard Diesel engine with other powertrain configurations and simulate them on the same route. The different driving resistances and consumption values represent the output values of simulation environment and are checked regarding their plausibility on the basis of the simulated vehicle weights and expected powertrain efficiencies. The multiplication with the Well-to-Wheel values of the different powertrains and the assumed productions scenarios enable a comparison of powertrains systems on different missions according to their CO2-impact (Fig. 2).
134    N. Hummel et al. Fig. 2.  Methodological approach The described methodology allows a comparison of energy systems without having the real hardware onsite for real-life testing. In this context it is possible to choose the most ecological powertrain according to specific mission requirements. 3 Simulation Environment The simulation of the reference vehicle requires basic information’s about weight, powertrain topology, gear ratio and engine data. Once the parametrization of the hardware is complete, the shifting strategy is also embedded in the IPG-Truckmaker environment and the comparison of real and virtual datasets allow to trim the vehicle simulation parameters in several iteration steps. In the case of special applications such as city buses or refuse collection vehicles, the weight variations and auxiliary power demand during stops must be implemented via maneuver parametrization. The comparison of the fuel consumptions in reality and in the simulation is used to validate the reference vehicle model. Figure 3 displays the real and the simulated Diesel consumption on a refuse collection route. The cumulated real and simulated fuel consumptions match in the driving parts of the route as well as in the refuse collection parts. In this context it can be assumed, that the assumptions made for the vehicle and powertrain parametrization, the auxiliaries and the driving maneuvers reflect real driving behavior.
Well-to-Wheel CO2-Analysis of Different Powertrain …    135 Fig. 3.  Real and simulated fuel consumptions on a refuse collection route Based on the validated reference Diesel truck, further powertrain topologies are implemented and parametrized in IPG-Truckmaker. According to the adapted weight a plausibility check based on the cumulated motion energy is executed: the motion energies of all powertrains should be in the same range but differ slightly according to the vehicle weights. The powertrain efficiencies define the consumption on each vehicle type on the considered route. Figure 4 displays the consumptions of alternative powertrains on three different heavy-duty mission profiles. Fig. 4.  Consumption of different powertrain type on typical heavy-duty mission profiles • In the waste collection route all three internal combustion engines have similar consumptions (Diesel ~ 510 kWhDiesel) about twice as high as the battery electric truck (BEV ~ 250 kWhElectric). On this mission type, with a mean velocity of 9.8 km/h and a standstill timeshare of 60% over the 60 km route, the combustion
136    N. Hummel et al. engine vehicles are mainly operated in engine map areas with poor efficiencies. On the other hand, the BEV is benefiting from a clutch free starting, a higher powertrain efficiency at low power/torque output and regenerative braking. • On the delivery route with a mean velocity of 37 km/h, a positive elevation of 18 m/km and v*apos about 1 m/s2 the advantage of the BEV is still significant in terms of efficiency due to the challenging altitude profile of this route. Nevertheless, the flatter the elevation profile gets, the lower the difference with be. • The simulated long-haul route has very little elevation and a mean speed of 61 km/h over 90 km. In this type of use-case the Diesel truck consumes about 1/3 more than the BEV (~275 kWhDiesel vs. ~185 kWhElectric). The BEV still benefits from lower powertrain losses but due to the constant speed travelling, only little energy can be recuperated during braking. 4 Emission Factor of Different Energy Carrier The equivalent CO2-emissions of an energy carrier can be divided into two main phases: • Well-to-Tank for the production path (WtT) • Tank-to-Wheel for the usage of the energy carrier in the vehicle (TtW) The sum of both terms results in the Well-to-Wheel (WtW) emission factor. In order to compare energy systems in a systemic way, the WtW approach is the one to use as the allocation of CO2-emissions is not equally distributed on WtT and TtW and differs depending on the energy carrier. 4.1 Well-To-Tank The Well-to-Tank part includes the extraction at the source, the transport, the manufacturing and the distribution of the energy carrier. The values for the fossil sources diesel and gas are taken from the JEC Well-to-Tank report v5 and are respectively 62 g CO2,eq/kWhDiesel and 59 g CO2,eq/kWhCNG [5]. They are no major technological improvement expected in the Well-to-Tank path for fossil sources. Only the share of the transport to the marker could be reduces in the future if regenerative fuels are used in the tanker ships which carry crude-oil to Europe. Electricity is required for the production of all other energy carrier. In this context, the emission factor of the energy sector is a major lever for CO2-neutral mobility. In the scope of the European Green-deal and the “Fit for 55” announcement from July 2021 [6], a CO2-emission reduction of 55% on the basis of the 1990 value (764 g CO2,eq/kWhElectric) should lead to a maximum emission factor for the German electricity mix of 343 g CO2,eq/kWhElectric in 2030 [7]. The scenarios for 2050 are based on the goals of the European commission with 95% emission reduction compared to 1990 and would lead to an emission factor of 23 g CO2,eq/kWhElectric. This value is also used for the emission factor of local renewable source such as wind or solar energy even before 2050 [8, 9].
Well-to-Wheel CO2-Analysis of Different Powertrain …    137 For the production of hydrogen, the energy required for the electrolysis and its origin is the main contributor to the emission factor. The low temperature electrolyzer efficiency is expected to reach 71% by 2030, which would lead to an emission factor of 483 g CO2,eq/kWhH2 when using German 2030 electricity-mix or 32 g CO2,eq/ kWhH2 is only renewable energy source are used. In order to be used in a vehicle the produced Hydrogen has to be transported and compressed. Those steps lead to total Well-to-Tank emission factors of 579 g CO2,eq/kWhH2 and 47 g CO2,eq/kWhH2. In order to obtain carbonated synthetic fuels, carbon atoms have to be separated from a CO2 source and synthetized with hydrogen in a second process step. In this work, only Direct Air Capture is treated as CO2 neutrality has to be reached in all process steps. With future expected process efficiencies, renewable methane (eCH4) can be produced with an emission factor of 611 g CO2,eq/kWhCH4 with the 2030 German electricity mix or 40 g CO2,eq/kWhCH4 with renewable sources [10, 11]. With similar assumptions for the Fischer-Tropsch synthesis process, emission factors of respectively 615 g CO2,eq/kWhFT-Di and 49 g CO2,eq/kWhFT-Di are reachable [11]. Hydrated vegetable oils (HVO) are biogenic fuels from the second generation which only use waste oils (i.e. from the food industry) and therefore do not compete with food production. The Well-to-Tank emission factor for HVO is taken from the JEC Well-to-Tank reprt V5 and reaches 43 g CO2,eq/kWhHVO [5, S. 201]. Figure 5 summarizes the Well-to-Tank CO2,eq-emission factors for the considered energy carrier. g CO2,eq/kWh Well-to-Tank 1400 1200 1000 800 600 400 200 0 1130 1146 994 611 579 615 343 485 65 59 43 2017 Diesel CNG Strom 65 59 43 65 59 23 47 40 49 43 2030-55% reducon vs.1990 2050-Ambioniert-95 H2-VKM 700bar eCH4 FT-Diesel HVO100 Fig. 5.  Well-to-Tank CO2,eq-emission factors for the considered energy carrier From Fig. 5 it becomes clear, that as soon as a sufficient amount or renewable energy is used for the production, the type of energy carrier used will mainly depend on the requirements during usage and not on the climate impact.
138    N. Hummel et al. 4.2 Tank-To-Wheel For the calculation of the Tank-to-Wheel (TtW) CO2,eq emissions different aspects have to be considered. The combustion of an energy carrier with carbon chain releases CO2. Nevertheless, the carbon mass share is decisive regarding the amount of CO2 emitted during the combustion: therefore Diesel releases 264 g CO2,eq/kWhDiesel [12] whereas CNG emits 202 g CO2,eq/kWhCNG [12]. In the case of electric or hydrogen powered vehicles the Tank-to-Wheel CO2emissions are Zero as no carbon-based combustion takes place in the vehicle. Synthetic and biogenic fuels have a similar molecular structure as their fossil counterparts therefore the combustion itself has a similar CO2 footprint than the fossil fuel. In addition to the CO2-emission due to the combustion of the energy carrier, the usage of urea in the exhaust-aftertreatment system also has a CO2-impact. In this context the SCR of a Diesel engine has further 2 g CO2,eq/kWhDiesel emission while the SCR of a Hydrogen combustion engines emits about 4 g CO2,eq/kWhH2 (Table 1). Table 1.  Tank-to-Wheel emissions Tank-to-Wheel g CO2,eq/kWh Energy carrier Urea Total Diesel CNG Strom H2-VKM eCH4 FT-Diesel HVO100 264 2 266 202 0 202 0 0 0 0 4 4 202 0 202 255 1 256 255 1 256 4.3 Well-to-Wheel The calculation of the Tank-to-Wheel CO2-emissions of synthetic and biogenic fuels considers the combustion of the fuel, the so-called CO2-credits reflecting the CO2 absorbed by the plant during its growth and the CO2 efficiency of the whole production process. In this context HVO100 reaches a CO2-efficiency of 100% and has a calculated Tank-to-Wheel emission factor of 0 g CO2,ep/kWhHVO [13] whereas the CO2-footprint of Fischer-Tropsch-Diesel and e-Methane depends on the efficiency of the CO2-capture process. The Well-to-Wheel CO2-emission of the considered energy carrier depends on the energy demand and the energy source used for the production and on the energy conversion in the vehicle. The evolution of the emission factors according to the origin of the electric energy used for production shows that e-fuels such as e-Methane of Fischer-Tropsch-Diesel have no positive environmental impact if not produced with at least 75% renewable electricity [14]. On the other hand, biogenic fuels such as HVO100 have a high potential already today even though they probably will be used as blends instead of pure fuels because of their limited capacity. From Fig. 6 it can be taken, that from shortly after 2030 regenerative fuels are going to break even with fossil diesel and gas if energy mixes evolve as expected and planed from the European governments. Nevertheless sweet spot productions allow the production of Fischer-Tropsch-Diesel and e-Methane with Well-to-Wheel
Well-to-Wheel CO2-Analysis of Different Powertrain …    139 emission factors in the range of 50 g CO2,eq/kWh in short future. The low emission factor of HVO underlines the necessity to use all available stocks as blends in fossil Diesel to reduce its emission factor. g CO2,eq/kWh Well-to-Wheel emission factors 1400 1200 1000 800 600 400 200 0 1146 1130 994 836 764 485 65 59 65 59 1990 Diesel CNG Strom 625 593 629 497 343 65 59 2017 H2-Elektrolyse 59 32 40 65 23 47 49 2030-55% 2050-95% reducon vs.1990 reducon vs. 1990 H2-VKM 700bar eCH4 FT-Diesel Fig. 6.  Well-to-Wheel CO2,eq-emission factors for the considered energy carrier 5 Comparison of the CO2,eq-Emissions of Different Powertrains The multiplication of vehicle consumption from the IPG-Truckmaker simulation and the emission factor of the energy carrier displays the CO2,eq-emission of a powertrain system according to a production path and a mission profile. Figure 7 displays the CO2,eq-emissions of long-haul trucks with different powertrain systems in three energy system scenarios: • A status quo situation in 2020 with an emission factor of 485 g CO2,eq/kWh for the German electricity mix. The efficiency of the electrolysis process is assumed to be at 64% and the Direct-Air-Capture has a CO2-extraction efficiency of 81%. • In 2030, the assumed reduction of the GHG-emissions by 55% compared to 1990 would lead to an emission factor for the German electricity mix of 343 g CO2,eq/ kWh. Furthermore the efficiency of the hydrogen production and Direct-AirCapture are supposed to reach respectively 69% and 91%. • 2050, all energy carrier are expected to have a low CO2-footprint due to the high share of renewable electricity in the German and European mix. In this context a reduction of 81% to 96% compared to a conventional Diesel powertrain is achieved. Nevertheless, the values for Hydrogen, e-Methane and Fischer-Tropsch Diesel can be reached already today if renewable energy from sweet spots is used for the energy carrier production.
140    N. Hummel et al. Diesel 400% 372% 361% CNG 350% HVO100 314% German E-mix 2020 300% H2-VKM 700bar eCH4 WtW CO2,eq in % 250% FT-Diesel 200% 193% 183% 200% German E-mix 2030 H2-VKM 700bar German E-mix 2030 150% 100% eCH4 German E-mix 2030 FT-Diesel German E-mix 2030 100% 83% German E-mix 2050 59% 50% 13% 0% 66% 19% 16% 15% 4% H2-VKM 700bar from renewable sources eCH4 from renewable sources FT-Diesel from renewable sources Fig. 7.  CO2,eq-emissions of different powertrain systems according to the energy carrier used The CO2-saving potential of battery electric trucks over conventional Diesel trucks varies according to the share of regenerative braking and stating operation of the mission profile and directly translates into the powertrain efficiency. In a high transient operation such as waste collection or city-bus applications the electric powertrain reaches about 67% powertrain efficiency while a Diesel combustion engine only reaches about 22%. With the German electricity mix of 2020, a CO2emission reduction of about 35% can be achieved with battery electric trucks in a city environment and even 63% in a hilly delivery mission profile. The electric powertrain matches all requirements of those kind of mission profiles while the drawbacks of combustion engines are maximized: driving in poor powertrain efficiency areas and local emissions due to cold exhaust aftertreatment systems. On the energetical side, the electric powertrain is therefore first choice if the range requirements can be reached.
Well-to-Wheel CO2-Analysis of Different Powertrain …    141 On the other hand, in a nearly stationary driving context of a long-haul truck a Diesel engine has efficiency values of about 40% and with the lower regenerative braking share the electric powertrain efficiency lays in the lower 60% which leads to a reduction of about 30% when using the German electricity mix 2020. Nevertheless, the importance of the requirements regarding the range of the vehicle could easily be matched when using Fischer-Tropsch Diesel or HVO in a pure form or as blending in Diesel combustion engines in long-haul applications. The CO2-impact can be minimized to 13 to 19% of a conventional Diesel truck when using pure HVO or Fischer-Tropsch Diesel. Furthermore, the local emissions of the truck are not an issue due to operation temperatures of the exhaust aftertreatment system in which conversion efficiencies are close to 100%. 6 Summary and Outlook This study displays the importance of a diversification of powertrains to meet the requirements of different heavy-duty applications. Furthermore, it becomes clear that the energy form used in the vehicle is not a criterion for the climate impact of a powertrain. Instead, the production path for the energy carrier and even more the usage of every sustainable energy source is the key for a climate neutral mobility. In this context the advantages of each energy carrier and the related powertrain must be used efficiently: in urban applications electromobility with zero local emissions and a high powertrain efficiency in all driving situations is without alternative. In longhaul missions, molecular renewable energy carrier have great potential due to their high energy density, the already existing infrastructure und the scalable ramp up with blending. The future mobility must be prepared and solutions addressed today. Even more, in order to reach climate neutrality by 2050, the energy system must be renewed and build on all climate neutral energy types available. References 1. European Commission: European Green Deal. Europäischer Grüner Deal, (2022) 2. Bundesministerium für Digitales und Verkehr: Verkehrsverflechtungsprognose 2030, https:// www.bmvi.de/SharedDocs/DE/Artikel/G/verkehrsverflechtungsprognose-2030.html. (2022) Zugegriffen: 29. Juni 2022 3. Bundesministerium für Umwelt, Naturschutz und Nukleare Sicherheit und WWW.BMU. DE. Klimaschutz in Zahlen – Fakten, Trends und Impulse deutscher Klimapolitik, Ausgabe (2021) 4. European Commission: Verordnung (EU) 2019/1242 Des Europäischen Parlaments und des Rates vom 20. Juni 2019 zur Festlegung von CO2-Emissionsnormen für neue schwere Nutzfahrzeuge und zur Änderung der Verordnungen (EG) Nr. 595/2009 und (EU) 2018/956 des Europäischen Parlaments und des Rates sowie der Richtlinie 96/53/EG des Rates, 25. Juli 2019
142    N. Hummel et al. 5. European Commission. Joint Research Centre: JEC well-to-tank report V5: JEC well to wheels analysis : well to wheels analysis of future automotive fuels and powertrains in the European context: Publications Office, (2020) 6. 'Fit for 55': delivering the EU's 2030 Climate Target on the way to climate neutrality. In: COM(2021) 550 final, 14. Juli 2021 7. Umweltbundesamt: Klimaschutz im Stromsektor 2030 – Vergleich von Instrumenten zur Emissionsminderung. Endbericht, (2017) 8. Öko-Institut E. V. und Fraunhofer ISI. Klimaschutzszenario 2050 – Zusammenfassung des 2. Endberichts, (2. Endbericht), (2015) 9. Bundesregierung Deutschland: Klimaschutzgesetz 2021. Generationenvertrag für das Klima, (2021) 10. Umweltbundesamt: System comparison of storable energy carriers from renewable energies. Final report, (2019) 11. Forschungsvereinigung Verbrennungskraftmaschinen E. V. Zukünftige Kraftstoffe: FVVKraftstoffstudie IV [online]. Transformation der Mobilität im klimaneutralen und postfossilen Zeitalter. FINAL REPORT 1269 | 2021 – Frankfurt am Main, www.fvv-net.de. (2021) 12. Umweltbundesamt: CO2-Emissionsfaktoren für fossile Brennstoffe, (2016) 13. European Commission: Richtlinie (EU) 2018/ 2001 des Europäischen Parlaments und des Rates – vom 11. Dezember 2018 – zur Förderung der Nutzung von Energie aus erneuerbaren Quellen, 21. Dezember 2018 14. Öko-Institut E. V.: Strombasierte Kraftstoffe: die Zukunft von PtX
Hydrogen in the Gas Network – Challenges and Solutions for High Performance Engines for Power Generation Clément Leroux(*), Robert Böwing, Bernadet Hochfilzer, Alexander Zuschnig, and Manuel Behr INNIO Jenbacher GmbH & Co. OG, Jenbach, Austria {clement.leroux,Robert.Boewing, Bernadet.Hochfilzer,Alexander.Zuschnig, Manuel.Behr}@innio.com Abstract.  The global drive to increase the use of renewable energy requires new approaches for energy storage and transportation to be developed. Blending hydrogen into the existing natural gas pipeline network is one strategy to store surplus electric energy in the form of green hydrogen. This strategy is currently being seriously considered in both the US and Europe. The INNIO approach is to enable INNIO’s entire Jenbacher product line for power generation to run on pipeline gas – hydrogen mixtures, with the permitted hydrogen content allowed to fluctuate between 0 and 25% vol. The challenges for engine development are as follows: The solution must enable operation with varying hydrogen contents and be applicable to the entire pipeline gas product program. Engine parameters like NOx, peak firing pressure, power control reserve, combustion knock margin, and turbocharger surge margin must stay within defined limits. Critical events like mega knock at high BMEP (engine damage) and autoignition during fault ride though events (grid code non-compliance) must be avoided. The selected strategy involves the measurement of the hydrogen content in natural gas and the pre-definition of various engine operating parameters. The final concept consists of a hardware/software package that includes additional sensors as well as hydrogen compensation software. Gas train size/version and fuel metering size/version must be checked and adapted to each individual engine if required. The development project ran over two years and included hydrogen sensor selection and validation, component certification, controls strategy development, and single and multi-cylinder engine testing. The testing was carried out with defined mixtures of natural gas, propane, and hydrogen on various Jenbacher engines from INNIO platforms and included steady-state and transient operation. The final solution is retrofittable. © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings S. 143–157, 2023. https://doi.org/10.1007/978-3-658-41477-1_11
144    C. Leroux et al. INNIO’s Jenbacher engines are now ready for hydrogen ad-mixed in the gas pipeline. The applied technical concept offers robust power plant operation at best performance. Any potenzial customer demands with hydrogen in natural gas contents above 25% (up to 100%) also can be handled but will require further engine hardware and software packages affecting pure natural gas operation. Keywords:  Hydrogen · Natural Gas · Renewable Energy · Power Generation 1 Introduction Increasing the use of renewable energy requires new approaches to energy storage and transport. Blending hydrogen into the existing gas pipe-line network is a strategy for storing and supplying renewable energy to customers in the short-term. This strategy is seriously being considered in both the US and Europe. The resulting engineering task is thus to enable INNIO’s entire Jenbacher product line to operate on natural gas – hydrogen mixtures, with the hydrogen content fluctuating between 0 and 25%. The challenges for engine development are as follows: • The solution needs to enable operation with varying hydrogen contents and be applicable to the entire Jenbacher product portfolio, • Disadvantages for standard gas operation must be avoided • Engine parameters like NOx, peak firing pressure, control reserve, knock margin and turbocharger surge margin must stay within defined limits • Critical events like mega knock at high BMEP (engine damage) and autoignition during fault ride though (grid code non-compliance) must be avoided This challenge differs somewhat from past developments, where engines for special gas applications have been designed specifically for the unique, specific gas characteristics without the need to consider unchanged engine performance with natural gas. Some challenges like varying gas quality or potenzial uncontrolled combustion events are similar, so the INNIO’s broad Jenbacher experience and knowledge in special gases are key to development of a hydrogen energy solution for the entire product portfolio in a fast and efficient manner. The development activities described in this paper are thus not only based on INNIO’s Jenbacher experiences in engine operation with pure hydrogen or add-mixed hydrogen as covered in [1–4] but also on expertise in special gas engine design as illustrated in [5–12]. The last-mentioned papers covering engine development activities and operating experiences with various special gases containing hydrogen, such as gases from steel production like coke gas, blast furnace gas and converter gas (with hydrogen contents up to 65% vol.); from gasification processes such as wood gas (with hydrogen contents up to 45% vol.); and from chemical industry processes (with hydrogen contents up to 25%). The knowledge gained by developing customer
Hydrogen in the Gas Network …    145 solutions for these special gases includes multi-gas operation (switching between different gases) and mixed-gas operation (e.g., add-mixing a high-calorific gas to a low-calorific gas). These experiences have been key concerning the new challenge of hydrogen in the gas pipeline, especially considering the long-term operating behavior in the field. Nevertheless, it shall be pointed out again, that the boundary condition to not compromise the given engine performance in pure natural gas operation mode (which is assumed to remain the dominant customer operation mode) excludes major hardware adaptation measures (compression ratio, Miller cam timing, combustion system, port injection etc.) and makes other adaptation measures rather unattractive (turbocharger modification, mixture temperature reduction, special oil formulations, etc.). Figure 1 shows some examples of already existing hydrogen in natural gas customer applications. Please note that more than 200 MW of INNIO’s installed fleet are running on syn gases with up to 70% hydrogen. Fig. 1.  Examples of INNIO’s Hydrogen Admixing Customer Projects 2 Challenges of Hydrogen Admixing on Engine Operation 2.1 Introduction Admixing hydrogen to the natural gas in the pipeline affects the engine operation if no counter measures are taken. Table 1 shows the qualitative impact of 25% hydrogen in natural gas with no engine-setting adaptations are done.
146    C. Leroux et al. Table 1.  Impact of H2 in NG on Engine Operation (Qualitative Change vs. pure NG Operation) Parameter NOx emissions HC emissions Peak firing pressure Control reserve Knock margin Surge margin 25% H2 Delta vs. NG No Adaptation ↑↑ – ↑ ↓↓ ↓↓ ↓↓ 2.2 Engine Operating Window INNIO’s Jenbacher engines are characterized by a lean-burn combustion system developed for high efficiency and low NOx emissions. A typical operating window of a lean-burn engine is shown in Fig. 2. This operating window is restricted by four limits: • • • • Knocking Misfiring Minimum compressor bypass (CBP) reserve Maximum exhaust gas temperature Fig. 2.  Operating Window of a Lean-Burn Engine
Hydrogen in the Gas Network …    147 The admixing of hydrogen to the natural gas affects the limits of the operating window. This will be discussed further in the following section. 2.3 Effects of Hydrogen Admixing on Combustion Hydrogen admixing results in significant changes of the air-fuel mixture properties affecting the engine operation. Table 2 shows a comparison of selected methane and hydrogen characteristics. Hydrogen admixing thus leads to a reduction in the methane number, hence in the knock resistance. The lower minimum ignition energy of hydrogen makes the mixture more prone, for instance, to pre-ignition. The higher laminar flame speed accelerates the combustion process and the wider ignition limits improve the lean limit. Table 2.  Comparison of the Properties of Methane and Hydrogen Parameter Unit – kg/Nm3 MJ/kg ms Methane CH4 100 0.66 50 1.33 Hydrogen H2 0 0.09 120 0.11 Methane number Density Heating value Ignition delay (λ = 1, T = 1200 K, p = 30 bar) Laminar flame speed (λ = 1, T = 300 K, p = 1 bar) Minimum ignition energy (At stoichiometric conditions) Self-ignition temperature Ignition limits (λ) m/s 0.37 2.1 mJ 0.28 0.016 K – 859 0.7–2.1 780 0.5–10.5 Hydrogen admixing to natural gas reduces the methane number of the fuel mixture as shown in Fig. 3. This must be considered for any compensation actions.
148    C. Leroux et al. 95 NG Base - MN92 Methane Number [-] 90 NG Base - MN82 85 NG Base - MN72 80 NG Base - MN65 75 70 65 60 55 50 0 5 10 15 20 25 30 H2 Content [%Vol.] Fig. 3.  Methane Number of Natural Gas – Hydrogen Mixtures Hydrogen admixing also leads to an increase in the laminar flame speed of the fuel mixture as shown in Fig. 4. At constant boundary conditions, the higher laminar flame speed results in a faster and earlier positioned combustion process characterized by higher peak firing pressure, higher NOx emissions, and lower exhaust gas enthalpy for the turbine of the turbocharger. 18 Laminar flame speed Relave change 17 16 14 16.5 12 16 10 8 15.5 6 15 4 14.5 Relave Change [%] Laminar Flame Speed [cm/s] 17.5 2 14 0 0 5 10 15 20 25 30 H2 Content [%Vol.] Fig. 4.  Laminar Flame Speed of Natural Gas – Hydrogen Mixtures The low minimum ignition energy of hydrogen improves the lean air-fuel ratio limit of the engine, but also increases the risk of auto-ignition (pre-ignition, backfiring, mega-knock, etc.). This must be considered when selecting spark timing, airfuel ratio, and maximum power output.
Hydrogen in the Gas Network …    149 Considering the main effects of hydrogen admixing on combustion described above, a strategy to compensate the impact of hydrogen in natural gas thus could be to operate the engine with a higher air-fuel ratio and a later spark timing. This will have a positive effect on NOx-emissions, peak-firing pressure, power control reserve, knock margin and turbocharger surge margin. Figure 5 shows the impact of 25% hydrogen in natural gas on combustion with constant boundary conditions and with adapted air-fuel ratio and spark timing. Burn Rate [kJ/m³.°CA] NG NG + 25% H2 no adaptaon NG + 25% H2 with adaptaon Crank Angle [°CA] Fig. 5.  Combustion Process – Impact of Hydrogen and Engine Settings 3 Development of a Hardware & Software Solution The focus of the engineering activities was to develop and validate a hardware and software solution for reliable engine operation with best performance at fluctuating hydrogen contents in the natural gas grid. Therefore, a hydrogen and multi-gas mixing infrastructure was added to the testing facilities enabling an extensive testing campaign, including both single cylinder engine (SCE) and multi-cylinder engine (MCE) tests, to cover the INNIO’s entire Jenbacher product portfolio. The engine tests were performed with up to 30% vol. hydrogen in the gas on various engine types. To cover the full range of gas qualities including the most critical cases with low base gas methane number, the base gas used during the testing campaign was a mixture of natural gas and propane, to which hydrogen was admixed (Fig. 6).
150    C. Leroux et al. Fig. 6.  Hydrogen Admixing Test at INNIO in Jenbach (H2 Trailer, J612 Engine, Gas Mixing Unit) For thorough validation, the testing campaign included multiple types of investigations, some of which are listed below: Steady-state investigations: • • • • knock and misfire border energy balance and emissions cylinder pressures and component temperatures power control reserve and turbocharger layout Transient investigations: • • • • engine start capability and emergency stop island mode (load acceptance and load rejection) static and dynamic grid code hydrogen content change rates System tests: • provoke intake backfire to measure flame and pressure waves • provoke exhaust deflagration to understand risks for aftertreatment systems All components of the engine and the balance of plant were checked, validated, and released for hydrogen readiness in close cooperation with involved suppliers. The parts included gas train, gas dosing valve, port injection valve (when applicable), prechamber gas compressor, compressor bypass valve, throttle valve, and turbocharger. Although a universal, standardized hardware and software solution for hydrogen in natural gas has been developed, some individual engine checks are still required depending on the customer application. For example, the gas train layout must be
Hydrogen in the Gas Network …    151 checked for its sizing considering up to 20% higher gas flow rate required when operating the engine with hydrogen in natural gas. The extensive validation also included artificially provoked intake backfire and exhaust deflagration tests to ensure system robustness in the field in case of unexpected events such as engine operation outside of specification. INNIO’s experience with special gases and field engines was very beneficial in developing and validating a robust technical solution. As explained in Sect. 2.3, the low minimum ignition energy of hydrogen makes the air-fuel mixture more prone to auto-ignition. Depending on the hydrogen content, the air-fuel ratio and the engine load, early combustion resulting in heavy knocking can suddenly occur in principle. Figure 7 shows the cylinder pressure trace during an uncontrolled combustion event when running without the developed compensation software. The final engine operating conditions were defined to stay away from any uncontrolled combustion events and ensure reliable operation by adapting air-fuel ratio, spark timing, or engine load. Several hardware configurations were tested, including variation of the compression ratio, adaptation of the turbocharger, and usage of aged components to cover all engine versions and engine aging effects in the field. Aged components included, for example, pistons with 30,000 operating hours and heavy deposit build up. Cylinder Pressure [bar] Normal Combuson Uncontrolled Combuson Carnk Angle [°CA] Fig. 7.  Uncontrolled Combustion Event when Running without Compensation Software Operating the engine with hydrogen in natural gas mixture and an increased airfuel ratio improves the combustion stability, both in transient and steady state mode. Depending on the engine type and version, the turbocharger can be adapted to provide sufficient power control reserve for the increased air-fuel ratio, if desired.
152    C. Leroux et al. 4 INNIO’s Jenbacher Solution for Hydrogen Admixing Operation 4.1 Hydrogen Sensor A core feature of the solution is to measure the fluctuating hydrogen content in the natural gas and to predefine spark timing, air-fuel ratio and power (if required) as function of the hydrogen content. To determine the hydrogen content in the gas supply, a sensor is implemented upstream of the engine. Important selection criteria for the hydrogen sensor are its response time, measurement range, accuracy, and potential cross dependencies. The sensor cost and its lifetime and maintenance interval are the main drivers to the lifecycle cost of this component. After performing market research, only a few manufacturers could be identified that already have an available product. A lot of supplier development is being done in the field of sensing hydrogen, especially optimizing costs and reducing cross dependence, by applying different physical principles. The measurement principle of the chosen sensors is based on a determination of the thermal conductivity. Since hydrogen has a much larger thermal conductivity than natural gas as shown in Fig. 8, any positive change of this value corresponds to a change of the hydrogen content. For this measurement principle, the knowledge of the thermal conductivity of the base gas is key information. This, however, cannot always be ensured since the gas quality and, hence, the thermal conductivity of the base gas, is changing. Therefore, the hydrogen sensor was optimized by having a calibration on a base gas that has an average value of the field gas quality. An improvement of this approach could be having an additional sensor for the natural gas quality on site that can handle hydrogen content. Thermal Conducvity [mW/m.K] 180 160 140 120 100 80 60 40 20 0 H2 N2 O2 Air CO2 CH4 C2H6 C3H8 C4H10 C5H12 C6H14 H2 Content [%Vol.] Fig. 8.  Thermal Conductivity of Different Gases at 0 °C [14]
Hydrogen in the Gas Network …    153 During the engine test, the measurement values of the sensors were always averaged over a certain amount of time during steady-state engine operation. Via a gas flow meter in the hydrogen admixing pipe, the reference hydrogen content was determined. The methane number was calculated using the gas composition with a gas chromatograph and varied by admixing propane. The test plan included a variation of the hydrogen content, the methane number, as well as dynamic responses of the admixed hydrogen content. The results and the already explained cross dependency of the base gas quality can be seen in Fig. 9, where the hydrogen content was kept constant and a methane number variation of the base gas was made. Supplier A H2 Sensor Deviaon [%] Lower / upper specififcaon limit 70 75 80 85 90 95 Base Gas Methane Number [-] Fig. 9.  H2 Sensor Deviation to Test Bench Gas Meter vs. Gas Base Methane Number at 16% Vol. H2 Content 4.2 Hydrogen Compensation Software To compensate for the impact of hydrogen in the natural gas on engine operation, different approaches were defined and implemented. The defined controls strategy resulted in new software to meet the requirements. The three major points of the hydrogen compensation software are as follows: • Ignition timing point change • Boost pressure change (i.e., air-fuel ratio change) • Power reduction (if required)
154    C. Leroux et al. For the hydrogen compensation software, the H2-signal, either from the H2-sensor or provided as a customer signal in vol% is used. If the signal is not valid, an internal default value of the H2 content is used to run the engine in stable and safe operation conditions and prevent unstable combustion events until valid H2 content again can be provided. Ignition Timing Change The nominal ignition timing in degrees crank angle depends on the fuel gas, compression ratio and other factors. To counter the exhaust gas temperature decrease with rising hydrogen content, the ignition timing is retarded. This also increases the distance to the knocking border and, therefore, counteracts the higher possibility of knock events due to the decrease of the methane number. An example of ignition timing retardation depending on hydrogen content is shown in Fig. 10. Ignition Timning [°CAbTDC] Standard setting H2 compensation Switching point H2 Content [%Vol.] Fig. 10.  Ignition Timing Adaptation vs. H2 Content The starting point to adapt the ignition timing can be set to a value higher than 0% vol. H2 to account for sensor accuracy. The ignition timing is retarded with increasing hydrogen content. The slope can vary depending on engine type and version. A switching point of the ignition timing slope can be set to adapt the characteristic if needed. This functionality is used on some engine versions. Air-Fuel Ratio Adaptation As explained above, combustion stability generally is improved when admixing hydrogen to the base gas, enabling engine operation at higher air-fuel ratio. Moreover, operation at higher air-fuel ratio allows safe operation in regard to uncontrolled combustion events. The air-fuel ratio is increased, depending on the measured hydrogen content. Figure 11 illustrates a possible adaptation of the air-fuel ratio based on the hydrogen content and engine load.
Hydrogen in the Gas Network …    155 The software allows for the adjustment of the air-fuel ratio with a certain slope to counteract the impact of hydrogen. The starting point to adapt the air-fuel ratio can be set to a value higher than 0% vol. to account for sensor accuracy. After a defined switching point, it is possible to overcompensate the hydrogen impact by further leaning out the engine. The necessary increase in air-fuel ratio also depends on the engine load. If the engine load is lower, the needed air-fuel ratio increase is lower. Therefore, the air-fuel ratio increase is interpolated, depending on the engine load. Standard seng - 100% load H2 compensa on - 100% load Air Fuel Rao [-] Switching point H2 Content [%Vol.] Fig. 11.   Air-Fuel Ratio Adaptation vs. H2 Content Power Reduction (only in Case of Excessive H2 Content) The target engine power is set with the engine control HMI (human machine interface) or is provided as an external signal from the customer system. The nominal engine power that can be achieved depends on the engine type and engine version, as well as the cylinder number of the engine. With a power reduction, the maximum allowed engine power can be reduced to prevent a potential engine trip and keep the engine operational until the boundary conditions change, and the power reduction is not needed any more. The reason for an active power reduction can vary. Possible reductions of engine power can include oil or water temperatures and high or low grid frequency among other factors. For hydrogen admixing, an additional power reduction is introduced that depends on the actual hydrogen content in the fuel gas. Depending on the specific engine type and version, it may be necessary to limit the maximum power output to ensure
156    C. Leroux et al. stable engine operation and decrease the occurrence of unstable combustion events by decreasing the cylinder peak pressure. Additionally, the software can protect the engine when the hydrogen admixing exceeds the upper limit (H2 > 25% vol.) by first applying a power reduction and then shutting down the engine. 4.3 Engine Operation Results with Hydrogen Compensation Software The developed solution covers INNIO’ entire Jenbacher engine product portfolio with Type 2, 3, 4, 6, and 9 engines, including 50 Hz and 60 Hz applications. Subject to engine version, base gas quality (MN), and site conditions, the engine power output will stay unchanged up to 25% hydrogen in natural gas respectively will be slightly adjusted according to the hydrogen signal. A potenzial version-specific power adjustment at very high hydrogen contents can be compensated with a turbocharger adaptation if desired. Table 3 shows an example of a successful application of INNIO’s Jenbacher solution for hydrogen admixing. The developed solution ensures safe and reliable operation conditions for all engine components. It brings a slight reduction in peak firing pressure and a moderate gain in knock margin. The control reserve can be fully recovered, and the compressor surge margin stays unchanged. The NOx emissions are kept unchanged while the HC emissions are reduced. An adaptation of the engine datasheet is not required when changing from natural gas to 25% hydrogen in natural gas operation, as engine efficiency and heat balance do not change with the applied hydrogen compensation software. Table 3.  Engine Operation with and without Hydrogen Compensation Software Parameter Unit NOx emissions HC emissions Peak firing pressure Control reserve Knock margin Surge margin % % % % % % 25% H2 in NG 25% H2 in NG No Adaptation λ Adaptation only +60 ±0 −20 −10 +10 +10 −25 −50 −85 −50 −20 −15 25% H2 in NG H2 Compensation Software ±0 −25 −5 ±0 +25 ±0 5 Summary Targeted activities of controls, performance, and testing engineers resulted in a robust technical solution for INNIO’s Jenbacher engines that enables operation with fluctuating hydrogen content up to 25% in the pipeline gas. A new engine controls logic was developed, including a closed loop control using fuel gas and emissions
Hydrogen in the Gas Network …    157 sensors. The new logic adapts the operating settings to enable engine operation at maximum performance while avoiding abnormal combustion events and ensuring exhaust emissions and grid code compliance. During the application and validation process, steady-state and transient engine testing with gas mixtures of natural gas, propane, and hydrogen were carried out, including back-fire investigations. The realized increase of the allowed hydrogen content in natural gas up to 25% for the INNIO’s entire Jenbacher engine portfolio supports our continuous efforts to build a more secure, affordable, and clean energy value chain – harnessing the power of engineering, technology, digitization, and green fuels. References 1. Baumann, Z.: Machen Sie sich bereit für eine Zukunft mit Wasserstoff, Dessau Gas Engine Conference, Mai (2022) 2. Kunz, A.: Gas Engines: Renewable Power with Operational Flexibility, Key-Note, 9th AVL Large Engines TechDays, Fully Digital, April (2021) 3. Hochfilzer, B.: Decarbonization of Europe’s Power Generation – ready for Hydrogen Engine Power Plants for 25% Hydrogen in Natural Gas, CIMAC Cascades in Graz, September (2021) 4. Laiminger, S., et al.: Hydrogen as Future Fuel for Gas Engines, CIMAC Vancouver (2019) 5. Böwing, R.: Use of Special Gases in Power Plant Engines” in chapter “Off-HighwayGas Engines in Natural Gas and Renewable Methane for Powertrains, ISBN: 978-3-31923225-6 (2016) 6. Prankl, S. et al.: Fortschritte bei Sondergasen – GE Gasmotoren mit hoher Leistung für wasserstoff- und kohlenmonoxidreiche Gase, 4. Rostocker Großmotorentagung, September (2016) 7. Zauner, S. et al.: Nutzung von Gichtgas im Großmotor mit Hilfe eines auf Zweigasbetrieb angepassten Regelungskonzeptes; 3. Rostocker Großmotorentagung, September (2014) 8. Chmela, F. et al.: Simulation of the combustion rate trend during operation with special gases; 8th Dessau Gas Engines Conference, Germany, March (2013) 9. Amplatz, E. et al.: Utilization of special gases in stationary gas engines – A manufacturer’s experience , MTZ heavy duty conference, Hamburg, November (2011) 10. Amplatz, E. et al.: Sondergase aus Industrieprozessen – neue Ressourcen für Energieerzeugung mit Verbrennungsmotoren; Tagung Gasfahrzeuge Stuttgart (2009) 11. Schneßl, E. et al.: Großgasmotorenkonzepte für Gase mit extrem niedrigem Heizwert; 6. Dessauer Gasmotoren-Konferenz, März (2009) 12. Schneßl, E. et al.: „Optimierung von Brennverfahren für Sondergasanwendungen auf Basis Simulation und Versuch am Einzylinder-Forschungsmotor“; Heavy-Duty, On-and Off-Highway Engines, MTZ Konferenz in Friedrichshafen, Nov. (2009) 13. Lopez, F., Vogl, L., Spyra, N., Böwing, R., Krainz, G.: New requirements for dynamic Grid Code regulations and the impact on turbocharging concepts, 21. Aufladetechnische Konferenz (2016) 14. Ingenieur Buch Website: https://www.ingenieur-buch.de/media/blfa_files/9783658106867Leseprobe.pdf. Accessed: 24. Sept. 2022
Safe and Sustainable Testing of Hydrogen Powertrains Nicolas Weyland(*) KST-Motorenversuch GmbH & Co. KG, Bad Dürkheim, Germany nicolas.weyland@kst-motorenversuch.de Abstract.  Hydrogen-based powertrains are hopeful prospects in the development of climate-friendly transport systems of the future. Testing in a safe way is absolutely essential for the development and testing of hydrogen-based powertrains. Our attention is to ensure sustainable testing. Green hydrogen and green electricity, as well as feeding them back into the power grid, are important elements in the issue of sustainability. The production of green hydrogen through electrolysis is a goal we will achieve in 2024. Safety is a priority issue, when testing with hydrogen. This is in our interest, but also in the interest of all our customers. A comprehensive safety package for the operation of hydrogen powertrains serves as a basis for this. This includes hazard assessment, fire and explosion protection documents, as well as a safety strategy. The results of the risk assessment are the cornerstone for the safety concept. The risk assessment reveals the hazards that can occur during hydrogen testing. With the help of various countermeasures, the probability of occurrence or risks of these events can be reduced. These countermeasures have been worked out for a wide range of scenarios and include requirements for sensors, redundancies, as well as room air exchange rates and line evacuations. The entire spectrum was then summarized in the safety strategy and is being implemented for all hydrogen test benches. This strategy relates to the test bench side. Special walls, explosion protection documents and ram protection are also installed for trailer stations in order to the safety of the hydrogen suplly process. Keywords:  Hydrogen · Testing · Sustainability 1 Preface Current trends such as emission‐free vehicles or CO2‐neutral development and production demonstrate the growing importance of sustainability in the automotive © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 158–166, 2023. https://doi.org/10.1007/978-3-658-41477-1_12
Safe and Sustainable Testing of Hydrogen Powertrains    159 industry. This industry segment is going through a significant phase of change. Key elements of this transformation are electromobility, autonomous driving and connected vehicles. The growing demand for electric cars and innovative mobility concepts shows how important sustainability has become. The transformation focuses on climate change and CO2 emissions as well as the sustainability of the value chain. Climate change and its effects have long been part of a broad social debate. As a result of this, the legislature has significantly tightened the requirements for CO2 emissions in recent years. Automotive manufacturers need to reduce CO2 emissions both in vehicle production and for the vehicle fleet. In this context, the use of alternative drive trains such as fuel cells play an important role. As natural resources are becoming increasingly scarce, sustainable material chains are becoming increasingly important to the automotive industry. These are based on the principle of reusing and recycling resources. Automotive manufacturers count on biodegradable components and sustainable processes in research, development, and production. A sustainable supply chain and environmentally friendly transport are essential in order to fully live up to the responsibility of human rights and environmental protection. We support the system change to e‐mobility, combustion engines with hydrogen and fuel cell technology based on hydrogen to deliver innovative solutions to protect the environment and safeguarding the climate. With our motto “Testing Powertrains to Move the Future”, we see ourselves as a partner in innovation together with our national and international customers – mainly manufacturers and suppliers from the automotive industry – to shape the future. We continuously analyse the market developments to identify trends at an early stage and support our partners with innovations in the field of testing. • • • • • • How will drive the car of the future? How efficient and environmentally friendly are electric cars? What are the alternatives? How powerful are hydrogen engines? What is the lifetime of a gearbox? How quickly do the engines wear off? These are the type of questions we work on to find answers for. Sustainable actions are one of the greatest challenges of our time. 2 Our Strategy to Sustainability At KST, sustainability is based on three structural pillars: economically successful development & testing, environmental protection and social responsibility. As a responsible and successful company, we are equally committed to each.
160     N. Weyland 2.1 Certifications In accordance with the related regulations, we are accredited with various certifications, which are regularly checked and audited. This includes a quality management system certified according to ISO 9001: 2015 by TÜV SÜD. KST is TISAX certified. This is an information protection standard defined by the automotive industry. The Deutsche Akkreditierungsstelle GmbH confirms our competence according to DINEN ISO/IEC 17025:2018 to perform motor CEC test procedures. On April 29th, 2020, KST received the certification of the French rating “accredited R&D service provider”, issued by the French Ministry of Education and Research. With this accreditation for the years 2020, 2021 and 2022, KST is recognized as an innovative research service provider for companies in France. KST as a accredited service provider must annually demonstrate its active work on innovative R&D projects in order to receive this government certification. 2.2 Service Portfolio By creating an environmentally friendly identity for our company, we are strengthening our customers’ trust in our performance and capabilities for innovation and wish to further encourage customer and supplier groups to an environmentally conscious behaviour. KST operates a test facility in Bad Dürkheim with state-of-the-art test benches for passenger cars, commercial vehicles and large engines as well as for the development and testing of fuel cells and motor vehicle powertrains. The range of services includes functional and development work as well as endurance testing for the following areas: • • • • • • • • • • internal combustion engines till 4 MW electric and hybrid drives from 48 V to 1200 V powertrains till 4-wheels configuration (BEV/Hybrid/Conventional) inverters and electronic components hydrogen drives, H2 engines, H2 fuel cell systems, stacks and H2 components large engines – industry/railway/marine turbochargers exhaust systems transmissions driving tests and fleet aging 2.3 Sustainability Against the background of volatile markets and the political requirement to promote alternative drive concepts, KST is intensifying its research and development activities. As a result, not only test capacities for power electronics were developed and made available, but also test capacities for hydrogen capability increased and the development of system efficiency test benches are driven forward.
Safe and Sustainable Testing of Hydrogen Powertrains    161 Fuel, electricity and hydrogen are key to operating the range of test benches successfully. Fuels for the internal combustion engines are stored in tanks. Operating supplies such as AdBlue, Glysantin etc. as well as oils are obtained through thoroughly monitored channels and stored in appropriate containers. Hazardous substances are stored in type-approved tanks which comply with the corresponding regulations and are subject to regular monitoring. We have been purchasing 100% green electricity from a regional supplier since 2022. Hydrogen is supplied daily by trailer deliveries. KST has a trailer station on the plant’s premises since May 2021. Another trailer station was going into operation in October 2022. A hydrogen storage tank farm is also being planned. 2.3.1 • • • • How Do We Understand Ecology? protection and efficient use of natural resources controlled CO2 emissions with the aim of reducing them controlled fuel consumption controlled energy consumption with the aim of purchasing 100% green electricity and natural gas to achieve CO2 neutrality 2.3.2 Which are the Measured Environmental Impacts of Our Activities? • • • • • • controlled emissions controlled fuel consumption controlled power consumption pre-sorted waste controlled discharge of odour and noise use of soil, energy, water and other resources 2.3.3 What Measures Have We Taken? • in 2015, an energy management system was introduced to record every major source of power consumption at the test benches, refrigeration systems and cooling water reservoirs in order to measure and control the energy consumption • partial renovation of the company buildings to reduce energy consumption • conversion of the heating systems from night storage heaters and fuel combustion systems to natural gas central heating • conversion of all light sources to energy-efficient technology, mostly LEDs • conversion of the fuel farm’s fire extinguishing system to use environmentally friendly extinguishing agents (as a measure for calamity control) • refurbishment of the fuel farm to guarantee optimal and permanent sealing to prevent leakage • retrofitting of ventilation/exhaust systems and refrigeration units of test benches with frequency converters to achieve significant energy savings • conversion of all refrigeration systems to environmentally friendly coolants • conversion of the forklift fleet from diesel to electric and retrofitting of the remaining diesel forklifts with diesel particulate filters; in 2021, 70% of fork lifts are already electric forklifts
162     N. Weyland • • • • 2 photovoltaic systems with approx. 90 kWp output renewal of the exhaust silencer for noise reduction consolidation of process cooling recirculation to increase efficiency in 2020, starting of modernizing and retrofitting five hydrogen-based test benches which were completed in the first quarter of 2021; seven more hydrogen test benches are completed since the quarter of 2022, hydrogen tests in conjunction with fuel cells and combustion engines are already possible since the second quarter of 2021 • for the operation of hydrogen systems, specific safety measures were implemented in order to continue to guarantee the present high safety standard • completion of a hydrogen trailer station in Q2 2021 -> conversion from H2 cylinder bundles to H2 trailer station for increased efficiency • conversion of the previous purchase plan from conventional natural gas to natural gas with CO2 neutralization in 2021 -> natural gas purchase with CO2 neutralization from 2022 2.3.4 What are the Future Measures? • energy-related optimization of systems; replacement of old machines with more energyefficient machines; optimization of measurement- control- and regulation technology • maintaining our high standards of safety through training at all times • to further increase efficiency and save energy the centralization of compressed air production and retrofitting the circuit with frequency converters is planned for 2023 • the centralization of a modern heat recovery system and retrofitting frequency converters in the circuit is planned for 2023 to further increase efficiency and save energy • an hydrogen storage tank solution is planned for 2023 to reach a more efficient use of the H2 resources • a common project with the local electric supplier Pfalz-Werke is planned for 2024 to supply KST with green hydrogen from an electrolyser which will be installed in the near of the KST test facility and connected with a pipeline; this will increase the efficienty of delivering of H2 • reducing the company’s CO2 footprint by the use of 50% electric mobility vehicles by 2025; in 2020, 20% of our fleet already consisted of e-models 2.3.5 Recovery of Electrical Current on the Test Bench In combustion engines, the energy is chemically bound in the fuel (petrol, diesel, gas, hydrogen) and is converted into kinetic energy by combustion in the engine. The kinetic energy is converted into a speed-dependent alternating current by the test bench loading machine (generator). The frequency converter from the generator adapts this current to the house network or public network and feeds it in. Depending
Safe and Sustainable Testing of Hydrogen Powertrains    163 on the test operation, stationary or dynamic, up to 85% of the energy can be recovered. The fuel cell system in the test stand is supplied with hydrogen. The reaction of oxygen and hydrogen produces electricity directly. The direct current is then converted into alternating current by the battery simulator and made it available again to the home network. Depending on the test operation, stationary or dynamic, up to 90% of the energy can be recovered. 2.3.6 From the Bottle Bundle of Grey Hydrogen to the Green Hydrogen Electrolyzer Hydrogen is still mostly produced from steam reforming and this production causes a large amount of CO2 (approx. 9 tons of CO2 per ton of hydrogen); this is considered as grey hydrogen. With electricity from renewable sources, however, hydrogen can also be produced CO2-free through the electrolysis of water. Only this green hydrogen can become an energy carrier of the future. We started to operate our first hydrogen test benches at the beginning of 2021 and used the hydrogen that could be supplied to us at that time. First small quantities in cylinder bundles (a cylinder bundle has a content of 12 kg of hydrogen which is enough for a maximum of one day of tests on a small fuel cell). The first trailer station was put into operation in May 2021; this was urgently needed due to the increasing demand for hydrogen. In the first 18 months, we were operating our hydrogen test facility from 100% grey hydrogen. In order to meet the increasing demand for hydrogen and to obtain more delivery reliability, we took a second hydrogen supplier on board in September 2022, this time with hydrogen coming from an electrolyzer produced partly with electricity from renewable sources. As we aim to use CO2-free hydrogen supply, it is obvious that a nearly hydrogen production plant is an important option. Now a regional energy supplier is investing in an electrolyser plant next to our test facility. KST is pursuing this forward-looking project as a future customer that will be directly supplied with green hydrogen. In favor of meeting the planned demand for hydrogen, an on-site electrolyzer with a capacity of 6 to 10 MW is needed. To cope with fluctuations in the availability of green electricity, a large storage facility with a capacity of several tons is required. This is the only way to ensure a continuous hydrogen supply for our test field. In order to optimize the use of the electrolyzer, the heat generated will also be used as process heat.
164     N. Weyland 3 Testing 3.1 H2 Engines When developing hydrogen engines, existing diesel or gas engines are often used as a basis, on which both the engine software (control unit or data statuses) and the hardware are then adapted for operation with hydrogen. As for the hardware, there is a variety of components to test. Some components are validated directly on the engines: • newly designed piston head shape for an optimized combustion chamber and optimal air turbulence; an optimized hydrogen engine can achieve an efficiency of around 45% • new intake valves (tightness not yet guaranteed) • special spark plugs for hydrogen combustion • cylinder head with modified valve train, adapted to avoid dry running • new blow-by separation system to reduce the oil content in the combustion air • larger exhaust gas turbochargers (single-stage or double-stage charging) to achieve a better filling of the engine • exhaust after-treatment systems for NOx reduction and to catch the soot from the oil Other components are mostly tested separately on component test benches before they are used in the engines and further validated: • the injection systems: there are also two options available, Direct Injection (DI) and Port Injection (PFI) • hydrogen pressure regulator: optimising it enables better regulation of the rail pressure and thus more accurate injection • the compatibility of exhaust gas probes and engine sensors fuel-carrying parts with hydrogen have to be tested; fuel filters for hydrogen have to be tested over the long term, as well 3.2 Fuel Cells In the development of fuel cell systems, both, the software (control unit) and the hardware have to go into endurance testing for operation with hydrogen. As far as the hardware is concerned, a variety of components have to be tested. Some components are validated directly on the fuel cell system: • material properties (hydrogen embrittlement) and/or coatings • tests on admixtures of gases • dynamics tests of different humidification units
Safe and Sustainable Testing of Hydrogen Powertrains    165 • emergency stop procedures • humidifier • climate driving tests (freeze-start properties): – freezing and warm-up – freezing and heating via cooling medium – H2 admixture in cathode air • condensate separator • testing of various purging strategies Other tests on the fuel cell: • testing of different hydrogen qualities • harmful gases in the air • particles in air and H2 Other components are usually tested separately on component test benches before being used and further validated in the fuel cell system: • • • • • • stack or short stack compressor recirculation pumps condensate valves testing of various pressure maintenance valves testing of cathode air filter systems 4 Safety Safety for the protection of the staff, the company infrastructure and the safety of the specimen are topics that we have developed responsibly. 4.1 Safety from a Test Bench Perspective The preparation of safety documents is a very important process: • explosion protection and fire protection documents have been prepared in cooperation with TÜV with safety testing of the test bench and specimen during commissioning (incl. leakage test of all H2-carrying components) • risk assessment was developed independently • safety concept was also developed independently The reason for the high safety requirements becomes apparent when one takes a closer look at the properties of hydrogen and their effects. If hydrogen is dispersed in the ambient air, it already forms an explosive mixture at a hydrogen content of 4% by volume. Since hydrogen is odourless and colourless, the gas warning system is a central element within the safety concept.
166     N. Weyland The test bench ventilation increases the room air exchange rate, when gas is detected. In combination with an explosion-proof ceiling fume hood, the hydrogen can thus be diluted or evacuated. In addition, hydrogen can also ignite directly at the point of leakage (e.g. pipe or fitting), generating an extremely hot flame (2500 °C). For example, the spark of a dropped tool is sufficient as ignition energy. Compared to a fossil fuel fire, the hydrogen flame contains no carbon atoms. Therefore, in addition to the high temperature, the flame is not visible to the human eye. Accordingly, the infrared spectrum is not or only barely present. The IR flame detectors from the test bench are therefore supported by UV flame detectors, which detect hydrogen fires. These and many other topics were summarized in the selfdeveloped safety strategy and serve as an internal guideline for the retrofitting of hydrogen test benches. In addition to the test benches, however, safety must also be taken into account in the delivery of hydrogen. For this purpose, several trailer stations have now been built under strict conditions. This included structural measures such as protective walls, explosion protection zones, special parking spaces, lightning arrester and much more. 4.2 Safety Measures to Protect the Test Parts • pop-up valves or bursting discs in the intake air system or in the charge air duct protect internal combustion engines in the event of backfiring • installation of hydrogen sensors in the exhaust system for combustion engines and fuel cells and in the blowby system for combustion engines; measurements show up to 6% hydrogen content • in the case of combustion engine applications, knock monitoring is realised via installed indexing measurement systems and an immediate automatic shutdown of the H2 supply to the test specimen is initiated in the event of knock events • possibility of manual shutdown of the H2 supply to the test specimen by means of a button on the test stand console in case of undesired events that are not automatically monitored
Hybrid PEM Fuel Cell Systems Sönke Gößling(*), Matthias Bahr, and Felix Smyrek ZBT – Zentrum für Brennstoffzellen-Technik GmbH, Duisburg, Germany {S.Goessling,M.Bahr,F.Smyrek}@zbt.de Abstract.  PEM fuel cell drivetrains in heavy duty applications are mostly implemented using multiple fuel cell systems and as battery hybrid systems. The complex architecture of those hybrid system results in various degrees of freedom in the operating strategy. Those have a major influence on aspects such as dynamics, efficiency and lifetime of the entire system. In order to be able to analyze and evaluate the capability of an efficiency optimized operating strategies, the ZBT fuel cell model is integrated into a fuel cell system and a full vehicle simulation. The dimensioning and also the load profiles are inspired by the Hyundai XCIENT Fuel Cell with 20 t total permitted mass. Starting from a rudimentary and purely functional operating strategy, an efficiency optimized operating strategy is presented. A mere optimization of the fuel cell system operation is not sufficient, since the losses in the battery system must also be considered. The numerous effects of the operating strategy are described. Keywords:  PEM fuel cell model · Fuel cell system simulation · Fuel cell vehicle simulation · Hybrid control strategy 1 Introduction The development of electrified and CO2-free heavy-duty vehicles shows a rapid change process. Even if optimal long-term solutions still require a considerable amount of development, solutions must be made available in the short and medium term. In order to put heavy-duty vehicles on the road nowadays, for example several fuel cell systems are now used in current vehicles with dimensions essentially comparable to those of passenger cars. The reason for this is the availability of the system components as well as the fuel cells itself in this performance class. The batteries in the vehicles are dimensioned relatively large, which allows the fuel cells to be operated carefully and thus with a low degradation to enable the increased lifetime requirements compared to passenger cars. As a result of this configuration, several energy sources are available to cover the power requirements of the electric drive. A significant part of the operating strategy is to choose the power distribution between the battery and fuel cell that the most dynamic coverage possible is ensured with the simultaneous highest possible efficiency and the lowest possible degradation © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 167–171, 2023. https://doi.org/10.1007/978-3-658-41477-1_13
168    S. Gößling et al. of the entire system. To demonstrate the potential offered by this flexibility in energy distribution, the configuration of the Hyundai XCIENT Fuel Cell with a total mass of 20 t is replicated in a simulation model and examined in detail on the basis of publicly available data [1]. 2 Simulation Setup The simulation is organized on three levels. On top level, the entire vehicle is connected together with the two separate fuel cell systems with 95 kW each and the 73 kWh battery system. The systems are connected together via their respective DC/ DC converter to a 650 V high-voltage bus. This high-voltage bus supplies the 190 kW electric motor, which in turn is connected to a 2-speed transmission. The vehicle is operated via a distance and speed profile including idle times and altitude profile. A general overview of the top level is shown in Fig. 1. Fig. 1.  Screenshot of the AVL Cruise™ M top level vehicle simulation On second level, the fuel cell media systems are simulated. Active recirculation takes place at the anode by using a recirculation blower [2]. A Celeroton-2212000-GB compressor is used on the cathode side, the system is pressurized by means of a throttle and a controllable bypass is also implemented for partial load operation. There is no humidifier installed in the cathode system. The cooling system consists of a small and large circuit and controls the temperature at the inlet as well as the temperature rise across the fuel cell stack. The top level simulation of the vehicle as well as the simulation of the media systems is done using the software AVL Cruise™. The fuel cell system is generally not limited in operation at low power requirements. However, if the power requirement approaches zero, the efficiency will also approach zero (Fig. 2). The part-load range in the region of 10% of the possible maximum system power achieves the highest efficiency of approx. 60%. As the system power increases further, the efficiency decreases.
Hybrid PEM Fuel Cell Systems    169 On the third level, the simulation of the transport processes within the fuel cell and the power of the fuel cell is carried out. At this level, a model developed by ZBT in MATLAB/Simulink is used, which is integrated into the CruiseM environment via functional mock-up interface (FMI) to enable a co-simulation. The model provides a local resolution of the internal electrochemical and transport processes while still being able to provide 1 ms real-time capability. It is based on the model published in [3], but it has been extended to include various physical correlations and, in particular, dynamic components [4, 5]. The presented fuel cell stack has an active area of 300 cm2 and consists of 400 cells. Fig. 2.  Efficiency of the fuel cell system The vehicle is operated with different VECTO load cycles [6] to be able to analyze the distinction of different operating strategies. 3 Results The reference operating strategy is mainly designed as a load-following strategy for the fuel cell systems; the output of the fuel cell systems has the objective of providing the required propulsion power. The battery is controlled in order to stabilize the highvoltage bus. If deviations occur in load-following operation due to limited maximum power and dynamic boundary conditions of the fuel cell system, the difference is automatically covered by the battery through the control concept. As a result, the state of charge (SoC) of the battery changes. In this case, the reference operating strategy adapts the load-following operation of the fuel cells to provide a surplus or less power to control the SoC to the target of 65%. In Fig. 3, the resulting SoC of this strategy is shown. This strategy enables to fully match the performance requirements and keep the SoC within a relatively small operating range. The reference operating strategy is not affected by the efficiency of the fuel cell systems, which can vary considerably over the operating range. This influence is additionally taken into account in the following efficiency-optimized operating strategy. The new operating strategy now attempts to keep the SoC within the
170    S. Gößling et al. specified operating range while operating the fuel cell systems at high efficiency. The SoC as a result of the efficiency-optimized operating strategy is shown in Fig. 4. The average power demand of the load profile is higher than the power supply of the fuel cell systems when they are operated at optimum efficiency. As a result of the operation of the fuel cell systems with priority on efficiency and consequently lower power supply compared to the average demand, the SoC of the battery, which compensates for the deviation, drops to a lower level. It can also be observed that the SoC of the battery is subject to higher dynamics. Fig. 3.  SoC for an operation with the reference operating strategy Fig. 4.  SoC of the operating strategy, which focuses on prioritized operation of the fuel cells in higher efficiency range In order to compare and evaluate the results, the hydrogen consumption of the vehicle is calculated. In addition, however, the SoC at the start and end of the cycle must also be considered, which has a significant influence due to the large installed capacity of the battery. In order to ensure that the SoC is properly taken into account and that no simplifying assumptions have to be made here, the cycle is run through several times in sequence. One cycle contains of a distance of 100 km and a total of five of these cycles are carried out. In Figs. 3 and 4, it can be seen that the absolute
Hybrid PEM Fuel Cell Systems    171 level of SoC changes significantly in the first cycle, but a comparable pattern appears for each cycle thereafter. Comparing the consumption of the overall system for the two shown operating strategies, no clear increase in efficiency can be seen here. Although the fuel cell systems can be operated more efficiently, they are not solely responsible for the losses in efficiency. All DC/DC and also the battery itself operate with specific power losses. The new operation management has an impact on all these electrical systems. In order to achieve an increase in efficiency, these must also be taken into account in the operating strategy. Acknowledgements. The research project was carried out in the framework of the industrial collective research program (IGF no. 61 EWN). It was supported by the Federal Ministry for Economic Affairs and Climate Action (BMWK) through the AiF (German Federation of Industrial Research Associations eV) based on a decision taken by the German Bundestag. References 1. Hyundai Motor Company (8. July. 2020): Erste Brennstoffzellen-Lkw Hyundai Xcient Fuel Cell kommen nach Europa., [online] https://www.hyundai.news/de/articles/press-releases/ erste-brennstoffzellen-lkw-hyundai-xcient-fuel-cell-kommen-nach-europa.html. Accessed: 13. Oct. 2022 2. Klunker, C., Nachtigal, P.: REZEBT: Rezirkulationsgebläse-Entwicklung für die Brennstoffzellen-Technologie, FC3 Fuel Cell Conference Chemnitz (2022) 3. Gößling, S.: 2-D + 1-D ortsaufgelöste Modellierung von PEM-Brennstoffzellen. Dissertation, Universität Duisburg-Essen (2019) 4. Gößling, S., Nickig, N., Bahr, M.: 2-D + 1-D PEM fuel cell model for fuel cell system simulations. Int. J. Hydrogen Energy 46(70), 34874–34882 (2021). https://doi.org/10.1016/j. ijhydene.2021.08.044 5. Tinz, S.; Wick, M.; Gößling, S.; Bahr, M.: Modulare Simulationsumgebung für Brennstoffzellensysteme mit Fokus auf den Membranwasserhaushalt, MTZ83. 11, 52–65 (2022) 6. European Commission: Vehicle Energy Consumption calculation TOol – VECTO, https:// climate.ec.europa.eu/eu-action/transport-emissions/road-transport-reducing-co2-emissionsvehicles/vehicle-energy-consumption-calculation-tool-vecto_en. Accessed: 14. Oct. 2022
Fuel Cell System Development for Heavy Duty Application Stephan Schnorpfeil(*), Arne Kotowski, Hauke Sötje, and Guido Hartmann SEGULA Technologies GmbH, Rüsselsheim am Main, Germany {stephanjohannes.schnorpfeil,arne.kotowski, hauke.soetje,guido.hartmann}@segulagrp.de Abstract.  Fuel Cell propulsion systems offer high energy density and short refueling times. These are the key facts for their application to heavy-duty vehicles. In the fuel cell propulsion system the layout of the fuel cell system itself is crucial. Based on the requirements like lifetime – and efficiency targets as well as package boundary conditions the components in the fuel cell system like stack and the so called BoP (Balance of plant) components such as compressor, hydrogen gas injector and humidifier are defined. Besides this the high temperature – and low temperature circuits and the high voltage system with DCDC’s and bleeding resistor are specified. The paper describes the fundamental aspects and processes for defining the layout of a fuel cell system with all its subcomponents. Starting with 1D simulation the BoP components and their interactions are optimized for overall high system efficiency and performances. The system packaging ensures the integration in the heavy-duty vehicle and the connection to the vehicle air intake – and hydrogen storage system, high voltage architecture and thermal management. The software of the fuel cell system adjusts the system actuators based on the targeted fuel cell system state like idle, nominal power, peak power and transient operation. Finally, the system is tested on the fuel cell test bench. Keywords:  Fuel Cell · Balance of Plant · Simulation 1 Motivation Fuel cell systems are more and more entering the market in different sectors. For example developments are announced e.g. for marine – [1] and aviation applications [2]. However, mainly in the heavy-duty sector the technology gets more and more momentum. Major suppliers and OEM’s have started or even accomplished projects for fuel cell vehicle and/or fuel cell system production [3, 4]. These heavy-duty applications need a fuel cell system that is dedicated development to their requirements especially concerning durability, total costs of ownership © Der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022 , Proceedings, S. 172–183, 2023. https://doi.org/10.1007/978-3-658-41477-1_14
Fuel Cell System Development for Heavy Duty Application    173 and efficiency. Besides this, certification and safety regulations need to be fulfilled. The realization of such a heavy-duty fuel cell system is described in this paper. 2 Basic Fuel Cell System Layout The fuel cell system is the new heart of future powertrain for heavy-duty fuel cell trucks (compare Fig. 1). (a) (c) (e) (b) (d) Fig. 1.  HyBatt truck component arrangement: a Hydrogen storage system (HSS) b Fuel cell systems c Traction battery d E-Axle e HV Electronics [5] The main task of the fuel cell system is to convert the hydrogen coming from the HSS (hydrogen storage system) into electrical energy for the electrical powertrain. Therefore, a well-specified setup of the fuel cell system is required (illustrated in Fig. 2). Fig. 2.  Simplified fuel cell system layout [6]
174    S. Schnorpfeil et al. The fuel cell system consists of hydrogen supply (anode), air supply (cathode), exhaust system, low temperature and high temperature coolant circuit as well as the high voltage and low voltage system. Here, each component in the periphery of the stack that is necessary to run the reaction in the stack is called a Balance of Plant (BoP) component. In the anode path the main components are hydrogen injector, jet pump and recirculation pump. The hydrogen injector introduces the hydrogen into the hydrogen recirculation. This injection provokes the motion of the hydrogen towards the stack where it is converted into current based on the inner stack reaction. However, not the complete hydrogen can be transformed. The rest is coming towards the stack anode outlet and is back fed to the hydrogen circulation mainly by the jet pump which is basically working after the ejector principle. Only in conditions where the hydrogen flow is stalling the recirculation pump will support the back flow to the jet pump. The cathode path consists mainly of the components air filter, compressor, heat exchanger and humidifier. The air filter is extremely important in order to sort out NOX, NH3 and SO2 since the stack will be contaminated with these pollutants. The compressor supplies necessary air to the stack. This is on the one hand essential to get in the start-up phase the reaction in the stack running. Here the compressor needs to be supplied from a battery until the stack produces its own current. On the other hand the compressor is the enabler to increase the power density of the fuel cell system. A high boosting power in combination with a high conversion density rate in the stack can lead to a potential for reducing stack size. Consequently, the compressed air need to be cooled in the intercooler. Beyond the mentioned tasks of the compressor in the shut-down phase the afterun of the compressor is necessary to dry the stack. However, in normal operation it is necessary to humidify the stack. This is carried out by the humidifier in case the stack has no internal humidification. Therefore, the exhaust gas of the stack can be fed back to the humidifier. For the operation of the fuel cell system a dedicated thermal management is necessary. This normally includes a low temperature – and high temperature coolant cycle. Whereas the high temperature coolant cycle is necessary to cool the stack with a supply temperature of around 70 °C, the low temperature coolant cycle provides the coolant for the intercooler and the high voltage electronics with a supply temperature of around 40 °C. The high voltage circuit layout is also dedicated for the application. One example is shown in Fig. 3.
Fuel Cell System Development for Heavy Duty Application    175 Fig. 3.  Exemplary principle of high voltage system for a fuel cell system In the start up phase the pre charge resistor relay is closed in order to limit current. In normal system operation the pre charge resistor relay is open and main relay is closed so that fuel cell system can feed the high voltage battery and/or the electric engine. In system shut down the main relay and pre charge relay is opened and the relay at the depolarization resistor is closed. This enables the depolarization resistor to discharge the stack which is reacting the residuals of hydrogen and air. 3 Fuel Cell System Specification 3.1 Fuel Cell System Simulation The fuel cell system development and specification is essentially following a V-cycle approach, as it is known from other developments (Fig. 4).
176    S. Schnorpfeil et al. Fig. 4.  Fuel Cell System development V-cycle For the system simulation and especially for the BoP (Balance of plant) component definition a system model is set up (Fig. 5). The model reflects the main components of the BoP but besides this in the sub models also all throttles and valves that are relevant for the system operation. Fig. 5.  BoP (Balance of Plant) simulation model overview [6]
Fuel Cell System Development for Heavy Duty Application    177 The driving parameter of the fuel cell system simulation model is the electrical load. The electrical load is determined in the superordinated fuel cell vehicle model based on the driving cycle and vehicle operation strategy (Fig. 6). Fig. 6.  Superordinated fuel cell vehicle model [7] In terms of heavy duty application this leads to a configuration with approximately 210 kW continuous power from the fuel cell system and a 50 kWh – 70 kWh battery capacity, as presented in [5]. This enables the constant highway driving to be covered by the fuel cell system only (Fig. 7). Fig. 7.  Simulated drive cycle for Heavy duty truck tractor [5]
178    S. Schnorpfeil et al. In order to archive the electrical load target the necessary air – and hydrogen flow needs to be established in the stack. This drives the layout of anode and cathode path with all subcomponents. For example the layout of the passive humidifier is one of the most complicated parts in the fuel cell system development process and is a challenge for multiphysical simulation. Passive means, that water from the cathode return line will be used to humidify the air from the cathode feedline. In general, a high humidification level is required for a high stack efficiency. In the simulation of the passive humidifier points like water transportation from wet to dry side as well as the thermal coupling between both sides need to be taken into account. Target is to size the passive bypass throttle in order to maintain a specific mass flow through the humidifier in all operating conditions. Figure 8 shows the humidifier flow chart. Fig. 8.  Passive humidifier flow chart [6] Besides the dimension, also special requirements for the components need to be taken into account. NOX, NH3 and SO2 as well as oil droplets would contaminate the stack. Therefore, air filter needs to be installed which can reduces NOX, NH3 and SO2 to an acceptable minimum. Besides that the compressor needs to run oil free. Thus, often compressors with air bearings are installed. Figure 9 shows the assembly of a fuel cell compressor [8].
Fuel Cell System Development for Heavy Duty Application    179 Air bearing Aerodynamics Motor Motor winding Fig. 9.  Fuel cell compressor assembly with air bearings [8] Important is to ensure the system function and do a validation of the simulation model as shown in the development V-cycle (Fig. 4). Therefore the subcomponents are tested by the supplier and the characteristic curves and/or maps are implemented in the model. Often it is recommended to test the stack directly and/or do a stack drive-in before it is implemented into the system. Furthermore, the interaction of the components needs to be taken care of. This point can be determined on the fuel cell system test bench where the complete fuel cell system is tested. Figure 10 shows a stack testing – and fuel cell system testing setup. Stack testing Fuel Cell System testing Fig. 10.  Stack and fuel cell system testing setup
180    S. Schnorpfeil et al. Besides the already mentioned points, the fuel cell system simulation is an important engineering tool for setting up the software & controls environment. Coupling the fuel cell system model with the operation software modules the software modules are tested and calibrated in the simulation environment (model in the loop). 3.2 Total Costs of Ownership Besides the purely dimensioning of the components other factors in the layout of a fuel cell system need to be taken into account. One critical point is the total cost of ownership (TCO) of the fuel cell vehicle and therewith of the fuel cell system. Typically, a holistic approach for the complete fuel cell system is applied. This means that the same stack platform is used for different applications – the stack is only multiplied. Thus, the production number of stack units increases and this drives lower production costs per unit. Besides, in some applications the whole fuel cell system is used multiple times – e.g. for reaching a power output of 200 kW two fuel cell systems with 100 kW power output each is applied. Both approaches are exemplarily shown in Fig. 11. Fig. 11.  Fuel Cell Stack and – System multiplication Both approaches have their advantages and disadvantages, e.g. multiplying the stack reduces the amount of BoP components significantly. On the other side the development of application-dedicated BoP components like humidifier and particularly compressor may be necessary. In addition, hybrid forms between both approaches are in development. Here a standardization of the fuel cell system can help amongst others to lower TCO for end user. One example is StasHH – Standard Sized FC module for Heavy Duty applications [9] (Fig. 12).
Fuel Cell System Development for Heavy Duty Application    181 Fig. 12.  StasHH Key Terminology and system definition [10] There amongst others, the size of the package box for a dedicated fuel cell system power output range as well as interfaces to application and the content of the package box is defined (Fig. 13). Fig. 13.  Dimension table based on StasHH [10] Also for the BoP components a modularity approach can be followed. Thereby, it is important that the components can be applied for more than one fuel cell application with a high same-part ratio. For example, this can be demonstrated on the fuel cell compressor. While the compressor wheel and volute is changed in order to achieve a higher mass flow, the rest of the compressor parts such as air bearings and E-motor are equal. Thus, a same part of ratio of up to 80% can be achieved [8]. This is shown in Fig. 14 for three different compressor types.
182    S. Schnorpfeil et al. Fig. 14.  3 different fuel cell compressor types with different air mass flow [8] 3.3 Safety and Certification During the development it is important to take safety and certification requirements into account from the beginning. Standard requirements come from the ISO 26262. This particularly means that the functional safety process needs to be realized. Starting with the DIA (Development Interface Agreement) between the projects partners, steps like HARA (Hazard Analysis and Risk Assessment), Functional- and Technical Safety Concept as well as Technical Hardware – and Technical Software Safety need to be passed. Up to now, the consolidation for an applicable standard regarding fuel cell systems in vehicles is ongoing. Guidance can be given by standards that are existing from other areas like ECE R134, ECE R100, ECE R10, regulation (EC) 79/2009 and regulation (EU) 2021/535. However, safety and certification requirements can have significant influence especially on the design of the system and therefore need to be carefully reviewed before starting the conception phase. Some guidance is given e.g. by white paper from TÜV Süd [11]. 3.4 Additional Requirements Furthermore, development also needs to take serviceability -, durability – and crash requirements into consideration. Regarding serviceability, it is important upfront to define components that need to be exchanged in service. One example is the ion exchanger. Accessibility needs to be ensured for exchanging in service. The durability target for heavy duty applications is a lifetime of more than 30,000 hours. The requirements for every BoP component can be estimated with the help of the simulation model. Based on driving cycle it can be estimated how often and in which modulation a component is actuated. This can help the supplier to represent the lifetime driving on a dedicated test bench for the component.
Fuel Cell System Development for Heavy Duty Application    183 4 Summary The paper demonstrates how in fuel cell system development the upfront simulation of the system is a crucial step. Here, the basic components are defined. From the vehicle data and drive cycle the requirements for each component can be derived. Also, all operating modes of the fuel cell system can be simulated and the component’s functionality can be checked. Besides, also the modulation of each component can be estimated based on the driving cycle over lifetime. MiL simulation helps to identify gaps in fuel cell system controls and software. Next to operational aspects there are other boundary conditions like package space-, certification-, safety- and total costs of ownership requirements. They also need to be validated in the beginning of the development phase. Moreover, special requirements like oil-free bearings in the compressor need to be recognized. Overall, the above mentioned items need a careful review from the beginning of the development phase onwards. Finally, the fuel cell system performance is tested on the fuel cell system test bench. Here the interaction of the components can be validated. In order to be able to check all operating modes a fuel cell system test bench with battery simulator is recommended. References 1. About Travel: https://abouttravel.ch/reisebranche/kreuzfahrtschiffe-und-die-klimafrageerste-brennstoffzellen-tests-kommen/. Accessed: 5. Oct. 2022 2. Airbus: https://www.airbus.com/en/newsroom/news/2020-10-hydrogen-fuel-cells-explained. Accessed: 5. Oct. 2022 3. Daimler Truck: https://media.daimlertruck.com/marsMediaSite/en/instance/ko/Developmentmilestone-Daimler-Truck-tests-fuel-cell-truck-with-liquid-hydrogen.xhtml?oid=51975637. Accessed: 5. Oct. 2022 4. Freudenberg: https://www.fst.com/de/fuel-cell/. Accessed: 5. Oct. 2022 5. Weiss, E., Schnorpfeil, S., Nickel, D.: Fuel Cell System Integration for Heavy-Duty Applications. In: ATZ Heavy Duty Conference, Rostock (2021) 6. Hartmann, E., Rohde, N., Muthusamy, V., Schnorpfeil, S.: Fuel Cell Systems – A Challenge of Multiphysical Simulations. Matlab Expo (2022), 2022/05/17 7. Schnorpfeil, S., Hartmann, E., Kotowski, A., Kapadia, B., Sötje, H.: Fuel Cell Propulsion System Layout. In: ATZ Conference – Der Antrieb von morgen (2021) 8. Schnorpfeil, S., Glahn, C., Zwyssig, C., Fröhlich, P.: Standardized compressors for fuel cell applications. In: 26. Aufladetechnische Konferenz, Dresden (2022) 9. Stashh: https://www.stashh.eu/. Accessed: 15. Sept. 2022 10. Stashh: https://www.stashh.eu/sites/default/files/StasHH%20standard%20%28part%20 1%29%20-%20Size%20definition.pdf. Accessed: 15. Sept. 2022 11. Tüv Süd: https://www.tuvsud.com/en-us/resource-centre/white-papers/eu-type-approval-ofhydrogen-powered-vehicles. Accessed: 15. Sept. 2022
Autorenverzeichnis A Allcorn, Roger, 53 Atkins, Penny, 53 B Bahr, Matthias, 167 Bärow, Enrico, 112 Behr, Manuel, 143 Beidl, Christian, 131 Bennet, David, 53 Bessey, Dirk, 123 Boom, Rick, 112 Böwing, Robert, 143 Buchholz, Bert, 24 Buehler, Frank, 123 Bülte, Heiner, 1 C Calero, Alvaro Concepcion, 53 Coles, Nicholas, 53 D D’Onofrio, Mario, 95 Davis, Jonathan, 53 Downes, Trevor, 53 F Faiß, Manuel Eugen, 123 Fox, Nigel, 53 Friedrich, Thomas, 40 Funke, Carsten, 1 G Gößling, Sönke, 167 H Hartmann, Guido, 172 Harvey-Bush, Jackson, 53 Herold, Tim, 131 Herrmann, Dennis, 95 Hochfilzer, Bernadet, 143 Holz, Oswald, 76 Hughes, John, 53 Hummel, Nicolas, 131 K Kapusta, Lydia, 95 Keck, Mathias, 76, 123 Kotowski, Arne, 172 Kühner, Andreas, 112 L Leroux, Clément, 143 Loiudice, Angela, 53 M Mante, Till, 24 Mauss, Fabian, 24 Mayer, Florian, 40 Mestre, Laura, 24 N Nork, Benedikt, 1 O Osborne, Richard, 53 P Penning, Richard, 53 Pirkl, Richard, 95 Prehn, Sascha, 24 Presti, Manuel, 76 R Rabanser, Peter, 53 © Der/die Herausgeber bzw. der/die Autor(en), exklusiv lizenziert an Springer Fachmedien Wiesbaden GmbH, ein Teil von Springer Nature 2023 A. Heintzel (Hrsg.): HDENGI 2022, Proceedings, S. 185–186, 2023. https://doi.org/10.1007/978-3-658-41477-1
Autorenverzeichnis 186 S Sailer, Dennis, 76 Saroop, Agam, 53 Schneider, Simon, 40 Schnorpfeil, Stephan, 172 Seba, Bouzid, 13 Seidel, Lars, 24 Smyrek, Felix, 167 Sötje, Hauke, 172 Stiehl, Roman, 40 T Theile, Martin, 24 Töpfer, Georg, 1 Trabold, Christian, 40 V Valenta, Lukáš, 53 W Weiss, Ulrich, 13 Weller, Fabian, 40 Weyland, Nicolas, 158 Willmann, Michael, 112 Z Zuschnig, Alexander, 143