Термодинамические свойства индивидуальных веществ. Том 1. Книга 2 - Гурвич Л.В., Вейц И.В., Медведев В.А.

Автор: Гурвич Л.В. Вейц И.В. Медведев В.А.
Теги: тепло термодинамика химия химическая термодинамика
Год: 1978
Похожие
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Текст
                    АКАДЕМИЯ НАУК СССР
ИНСТИТУТ ВЫСОКИХ ТЕМПЕРАТУР
ГОСУДАРСТВЕННЫЙ ИНСТИТУТ ПРИКЛАДНОЙ ХИМИИ

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
СПРАВОЧНОЕ ИЗДАНИЕ
В ЧЕТЫРЕХ ТОМАХ
Издание третье, переработанное и расширенное
Согласовано с Государственной службой
стандартных справочных данных
РЕДАКЦИОННАЯ КОЛЛЕГИЯ
В. П. ГЛУШКО (ответственный редактор),
Л. В. ГУРВИЧ (зам. ответственного редактора),
Г.А.БЕРГМАН, И. В. ВЕЙЦ, В.А.МЕДВЕДЕВ,
Г. А. ХАЧКУРУЗОВ, В. С. ЮНГМАН
ИЗДАТЕЛЬСТВО «НАУКА» МОСКВА 1978

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
Том I
ЭЛЕМЕНТЫ
О, H(D,T), F, C1, Вг, I, He, Ne, Ar,
Кг, Хе, Rn, S, N, Р
И ИХ СОЕДИНЕНИЯ
Книга 2
ТАБЛИЦЫ
ТЕРМОДИНАМИЧЕСКИХ СВОЙСТВ
ИЗДАТЕЛЬСТВО «НАУКА» МОСКВА 1978

УДК 536+ 541.1
Термодинамические свойства индивидуальных веществ. Справочное издание: В 4-х т./Л.В. Гурвич, И.В. Вейц,
В.А. Медведев и др. - 3-е изд., перераб. и расширен. - Т. I. Кн. 2. - М.: Наука, 1978. - 328 с.
Издание состоит из четырех томов, каждый том - из двух книг: в первой описаны методы расчета, во
второй книге помещены таблицы термодинамических свойств.
Во второй книге I тома в 237 основных и 26 дополнительных таблицах представлены
термодинамические свойства веществ, рассчитанные авторами на основании данных, принятых в первой книге. Таблицы
рассчитаны в интервале температур от 100 до 6000 К; для 15 газов - до 10 000 К, для 47 газов - до
20 000 К; для некоторых веществ (преимущественно кристаллических) таблицы даны от 5 К. Для 50
веществ приведены второй вириальный коэффициент и критические постоянные.
Л.В. ГУРВИЧ
И.В. ВЕЙЦ
В.А. МЕДВЕДЕВ
Г.А. ХАЧКУРУЗОВ
B.C. ЮНГМАН
Г.А. БЕРГМАН
В.Ф. БАЙБУЗ
АВТОРЫ
B.C. ИОРИШ
Г.Н. ЮРКОВ
СИ. ГОРБОВ
Л.Ф. КУРАТОВА
Н.П. РТИЩЕВА
И.Н. ПРЖЕВАЛЬСКИЙ
В.Ю. ЗИЦЕРМАН
В.Я. ЛЕОНИДОВ
Ю.С. ЕЖОВ
С.Э. ТОМБЕРГ
И.И. НАЗАРЕНКО
А.Л. РОГАЦКИЙ
О.В. ДОРОФЕЕВА
М.С.ДЕМИДОВА
20502-459
Т Подписное издание
055 @2)-78
© Издательство "Наука", 1978г.
Эта книга не может быть полностью или частично
воспроизведена или размножена, введена в
информационно-поисковую систему или передана по линиям
связи в любой форме или любыми средствами (в том
числе электронными устройствами и на магнитных
носителях информации) без письменного
разрешения издательства "Наука".

ВВЕДЕНИЕ
Основное содержание второй книги I тома
настоящего справочного издания составляют 237 таблиц
термодинамических свойств веществ, образованных
15 химическими элементами (О, Н, F, C1, Вг, I, Не,
Ne, Ar? Кг, Хе, Rn, S, N, Р) и изотопами водорода. В
235 таблицах представлены свойства газообразных
веществ, в 2 — свойства веществ в
конденсированном состоянии (S и Pi^Oio)* Для 47 заряженных
газов, включая электронный газ, таблицы даны
начиная с температуры 298,15 К; в остальных случаях
минимальная температура равна 100 К. Таблицы для
45газов (e,O,O+,CT5O2,O^Cq Л,Н*,НГ,Н2,Н$ ,Hj,
ОН, ОН+, Н2О, Н2О+, Н3СГ, D, D2, HD? T, T2,HT, DT,
Не, Не+,Ne,Ne+S Ar, Ar+,Kr,Kr+,Xe,Xe+,Rn,Rn+,N,N+,
N2, N$, NO, NO+, NH, NH+) рассчитаны до 20 000 К,
для 16 газов (ОН", F, F", F2, HF, DF, TF, C1, СГ,
Вг, ВГ, I, Г, S, S", Р) - до 10000 К и для остальных
174 газов - до 6000 К. Шаг по температуре
составляет 100 до 6000 К, 200 от 6000 К до 10 000 К и 500 от
10 000 К до 20 000 К. Все таблицы содержат данные
для Т = 298,15 К; кроме того, для веществ в
конденсированном состоянии приведены свойства для
температур фазовых переходов и полиморфных
превращений (выделены курсивом).
В кавдой таблице приводятся значения
теплоемкости при постоянном давлении Ср(Г),приведенной
энергии Гиббса Ф° (Г), энтропии 5° (Г) и изменения
энтальпии Н° (Г) - Н ° @), а также логарифма
константы равновесия lg К ° (Г) для газов (кроме
нейтральных одноатомных газов) и логарифма
давления пара lgp (Г) для конденсированных веществ.
Соответствующее выражение для К° (Г) через
парциальные давления атомов (и электрона) приведены
в таблицах иод названием вещества наряду с
величиной энтальпии реакцию А/.Я°@), для которой
рассчитывались значения igK °(Г) или lgp (Г) =
На правом поле таблицы по вертикали напечатаны
аппроксимирующие уравнения для Ф° (Т) с
указанием пределов применимости по Г и принятые значения
энтальпии образования А *Н ° (Г) данного вещества
из элементов в стандартных состояниях при Т = 0 и
298,15 К, а также молекулярный вес М и ядерная
составляющая 5яд,равная Фяд-
^ Для характеристики достоверности
табулированных величин в левом верхнем углу каждой таблицы
указан ее класс точности. Класс точности таблицы
выражается числом, характеризующим класс точности
величин Ф°(Г), и буквой, соответствующей классу
точности величины АгН°@) для данного вещества.
Классы точности ф°G) и Д^0 @) связаны с
погрешностями соответствующих величин следующим
образом:
Класс
точности
Ф° СП
1
II
III
IV
V
VI
VII
Погрешность
Ф° C000 К)
Дж- К •
• моль"
<0,03
<0Д
<0,3
< 1
<3
^10
>10
Класс точ-
ности
А
В
С
D
Е
F
G
Погрешность
АГН° @)
кДж * моль
<0,1
«3,3
<1
<3
<10
<30
>30
В дополнении к книге даны таблицы
термодинамических функций (их нумерации предшествует
буква Д), несколько отличающиеся по форме
представления от остальных таблиц тома.
Прежде всего, это таблицы для ряда
легколетучих веществ в конденсированном состоянии (Н2 О,
Н2О2, Br2, I2, XeF2) XeF4, XeF6> NH4NO3, NH4F,
P), начиная с 5 К и далее с шагом 5 до 50 К, с шагом
10 от 50 до 300К (включая 298,15 К) и с шагом 20 от
300 К и выше. Из газообразных веществ даны а-Н2
и«-Н2 (соответственно D2 иТ2) от 10 до 200 К с
шагом 10, далее 250, 298,15, 300 и до 1000 К с
шагом 100. Кроме того, в дополнение включены
полимеры RnVn (и = 2-7) от 100 до 3000 К, Хе2 и
XeF от 100 до 2000 К. В таблицах, помещенных в
дополнении, не приведены величины \gK° (T) или
lgp (Г), а также аппроксимирующие формулы для
Ф°(Г). Кроме того, на этих таблицах не указан
к ларе точности. В соответствующих разделах
первой книги можной найти сведения о
погрешностях термодинамической функций этих веществ
и данные, необходимые для расчета lgX° (Г)
В двух таблицах, замыкающих дополнение к этой
книге, даны константы аппроксимационного
уравнения для второго вириального коэффициента (табл.
Д. 25) и критические постоянные (табл. Д. 26) для
тех веществ I тома, для которых имеются
соответствующие данные (см. раздел П 3.7 первой книги).

УКАЗАТЕЛЬ ТАБЛИЦ
Номер
таблицы
Вещество
Стр.
Номер
таблицы
Вещество
Стр.
1 Электрон е 10
2 Кислород О (г) 12
3 Положительный ион кислорода О+ (г). . . Н
4 Отрицательный ион кислорода О" (г) . . 16
5 ДикислородО2 (г) 18
6 Положительный ион дикислррода О* (г) 20
7 Отрицательный ион дикислорода О" (г) . 22
8 Озон О3 (г) 24
9 Водород Н (г) 25
10 Положительный ион водорода Н+ (г) ... 27
11 Отрицательный ион водорода Н" (г) ... 29
12 ДиводородН2 (г) 31
13 Положительный ион диводородаН* (г) . . 33
14 Положительный ион триводородаН* (г) . 35
15 ГидроксилОН (г) 37
16 Положительный ион гидроксила ОН + (г) 39
17 Отрицательный ион гидроксила ОН ~ (г) . . 41
18 Диоксид водорода НО2 (г) 43
19 Отрицательный ион диоксида водорЪда
НО" (г) 44
20 Вода Н2О (г) 45
21 Положительный ион оксида диводорода
Н2О+ (г) 47
22 Перекись водорода Н2О2 (г) 49
23 Положительный ион . оксида триводорода
Н3О+ (г) 50
24 Дейтерий D (г) 52
25 Дидейтерий D2 (г) 54
26 Оксид дейтерия DO (г) 56
27 Отрицательный ион оксида дейтерия DCT(r) 57
28 Диоксид дейтерия DO2 (г) 58
29 Отрицательный ион диоксида дейтерия
DO" (г) 59
30 Оксид дидейтерия D2O (г) 60
31 Диоксид дидейтерия D2O2 (г) 61
32 Протодейтерий HD (г) 62
33 Оксид протодейтерия HDO (г) 64
34 Диоксид протодейтерия HDO2 (г) ..... 65
35 Тритий Т (г) 66
36 ДитритийТ2 (г) 68
37 Оксид трития ТО (г) 70
38 ОксиддитритияТ2О (г) 71
39 Поототритий НТ (г) 72
40 Оксид прототрития НТО (г) 74
41 Дейтеротритий DT (г) 75
42 Оксид дейтеротрития DTO (г) 77
43 Фтор F (г) 78
44 Отрицательный ион фтора F ~ (г) 80
45 ДифторР2 (г) 82
46 Фторид кислорода F О (г) 84
47 Дифторид кислорода F2O (г) 85
48 Фторид водорода HF (г) 86
49 Фторид гидроксила HOF (г) 88
50 Фторид дейтерия DF (г) 89
51 Фторид трития TF (г) 91
52 ХлорС1 "(г) 93
53 Отрицательный ион хлора С1~ (г) 95
54 ДихлорС12 (г) 97
55 Оксид хлора СЮ (г) 99
56 Диоксид хлора СЮ2 (г) 100
57 ОксиддихлораС12О (г) 101
58 Хлорид водорода НС1 (г) 102
59 Гидроксид хлора НОС1 (г) . . 103
60 Хлорид дейтерия DC1 (г) 104
61 Хлорид трития ТС1 (г) 105
62 Фторид хлора C1F (г) 106
63 Трифторид хлора C1F3 (г) 107
64 Пентафторид хлора C1F5 (г) 108
65 Бром Вг (г) 109
66 Отрицательный ион брома Вг" (г) 111
67 ДибромВг2 (г) 113
68 Оксид брома ВгО (г) 114-
69 Бромид водорода НВг (г) 115
70 Бромид дейтерия DBr (г) 116
71 Бромид трития ТВг(г) 117
72 Фторид брома BrF (г) 118
73 Трифторид брома BrF 3 (г) 119
74 Пентафторид брома BrF 5 (г) 120
75 Хлорид брома ВКЛ (г) 121
76 Иод I (г) 122
77 Отрицательный ион иода I" (г) 124
78 Дииод12 (г) 126
79 Оксид иода 10 (г) 127
80 Иодид водорода HI (г) 128
81 Иодид дейтерия DI (г) . 129
82 Иодид трития TI (г) 130
6

Номер
таблицы
Вещество
Стр.
Номер
таблицы
Вещество
Стр.
83 Фторид иода [IF (г) 131
84 Пентафторид иода IF5 (г) 132
85 Гептафторид иода IF? (г) 133
86 Хлорид иода IC1 (г) 134
87 Бромид иода IBr (г) 135
88 Гелий Не (г) 136
89 Положительный ион гелия Не+ (г) 138
90 Неон Ne (г) 140
91 Положительный ион неона Ne+ (г) .... 142
92 Аргон Аг (г) 144
93 Положительный ион аргона Аг * (г) . . . . 146
94 Криптон Кг (г) 148
95 Положительный ион криптона Кг+ (г) . . 150
96 Дифторид криптона КгF2 (г) 152
97 Ксенон Хе (г) 153
98 Положительный ион ксенона Хе+ (г) ... 155
99 Триоксид ксенона ХеО3 (г) 157
100 Тетроксид ксенона ХеО4 (г) 158
101 Дифторид ксенона XeF2 (г) 159
102 Тетрафторид ксенона XeF4 (г) 160
103 Гексафторид ксенона XeFg (г) 161
104 Диоксид-дифторид ксенона XeO2F2 (г) 162
105 Триоксид-дифторид ксенона XeO3F2 (г) 163
106 Оксид-тетрафторид ксенона XeOF4 (г) 164
107 Радон Rn (г) 165
108 Положительный ион радона Rn+ (г) . . . 167
109 CepaS (к, ж) 169
110 CepaS (г) 170
111 Отрицательный ион серы S ~ (г) 172
112 Дисера52 (г) J74
113 Отрицательный ион дисеры S ~ (г) .... 175
114 TpncepaS3 (г) 176
115 TeTpacepaS4 (г) 177
116 Пентасера85 (г) 178
117 TeKcacepaS6 (г) , 179
118 TenTacepaS7 (г) . 180
119 OKTacepaS8 (г) 181
120 Оксид серы. SO (г) 182
121 Отрицательный ион оксида серы SO" (г) 183
122 Диоксид серы SO2 (г) 184
123 Отрицательный ион диоксида серы
SO" (г) • 185
124 Триоксид серы SO3 (г) 186
125 ' Оксид дисеры S2O (г) 187
126 Гидрид серы SH^(r) 188
127 Отрицательный ион гидрида серы SH ~ (г) 189
128 Сероводород H2S (г) 190
129 Серная кислота H2SO4 (г) 191
130 Фторид серы SF (г) 192
131 Отрицательный ион фторида серы SF ~ (г) 193
132 Дифторид серы SF2 (г) 194
133 Трифгоридсеры SF3 (г) 195
134 Отрицательный ион трифторида серы
SFJ (г) 196
135 Тетрафторид серы SF4 (г) 197
136
137
138
139
140
141
142
143
144
14*
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
Пентафторид серы SF5 (г) 198
Отрицательный ион пентафторида серы
SFJ (г) 199
Гексафторид серы SFg (г) 200
Оксид-дифторид серы SOF2 (г) 201
Диоксид-дифторид серы SO2F (г) .... 202
Азот N (г) 203
Положительный ион азота N+ (г) 205
Диазот N 2 (г) 207
Положительный ион диазота N^ (г) .... 209
Tpna3OTN3 (г) 211
Оксид азота NO (г) 212
Положительный ион оксида азота
NO+ (г) 214
Диоксид азота NO 2 (г) 216
Отрицательный ион диоксида азота
NO" (г) 217
Отрицательный ион триоксида азота
NO" (г) 218
Оксид диазота N2O (г) - . . 219
Триоксид диазота N2O (г) 220
Тетроксид диазота N 2О4 (г) 221
Пентоксид диазота N2О (г) 222
Гидрид азота NH (г) 223
Положительный ион гидрида азота
NH+ (г) 225
Дигидрид азота NH (г) 227
Аммиак NH3 (г) 228
Аммоний ион NH 4 (г) 229
Дигидрид диазота N2H2 (г) 230
транс-Дигидрид диазота транс-Ы2Н2 (г) 231
цис-Дигидрид диазота цис-N Н (г) . . • 232
1,1-дигидриддиазота 1,1-N2H2 (г) .... 233
Гидразин N2H4 (г) 234
Гидрид триазота HN3 (г) 235
Оксид-гидрид азота НNO (г) 236
Азотистая кислота HNO2 (г) 237
транс-Азотистая кислота zpawc-HNO^ (г) 238
цис-Азотистая кислота цис- HNO2 (г) 239
Азотная кислота HNO3 (г) \ 240
Гидроксиламин NH2OH (г) 241
Аминил-нитрит NH2NO2 (г) 242
Фторид азота NF (г) 243
Дифторид азота NF2 (г) 244
Три фторид азота NF3 (г) 245
Дифторид диазота N2F2 (г) 246
цыс-Дифторид диазота цис-^F 2 (г) .... 247
транс-Дифторид диазота транс-N^ 2 (г) 248
Тетрафторид диазота N2F4 (г) ....... 249
трдкс-Тетрафторид диазота транс-N^л (г) 250
гош-Тетрафторид диазота 2OM/-N2F4 (r) 251
Оксид-фторид азота FNO (г) 252
Диоксид-фторид азота FNO2 (г)» . , . , . 253
Триоксид-фторид азота FNO3 (г) 254

Номер
таблицы
Вещество
Стр.
Номер
таблицы
Вещество
Стр
185 Оксид-трифторид азота F3NO (г) 255
186 Гидрид-фторид азота NHF (г) 256
187 Дигидрид-фторид азота NH2F (г) 257
188 Гид рид-дифторид азота NHF2 (г) 258
189 Оксид-хлорид азота C1NO (г) 259
190 Диоксид-хлорид азота C1NO2 (г) 260
191 Сульфид азота NS (г) 261
192 Фосфор Р (г) ; . . 262
193 Дифосфор Р2 (г) 264
194 ТрифосфорР3 (г) 265
195 Тетрафосфор Р4 (г) 266
196 Оксид фосфора РО (г) 267
197 Отрицательный ион оксида фосфора
РО" (г) 268
198 Диоксид фосфора РО2 (г) 269
199 Отрицательный ион диоксида фосфора
РО2 (г) 270
200 ТриоксиддифосфораР2О3 (г) 271
201 ТетроксиддифосфораР204 (г) 272
202 ПентоксиддифосфораР2О5 273
203 ГексоксидтрифосфораР3О6 (г) 274
204 Гексоксид тетрафосфора Р4О6 (г) .... 275
205 Гептоксид тетрафосфора Р4О? (г) 276
206 Октоксид тетрафосфора Р4О (г) 277
207 Ноноксид тетрафосфора Р4О9 (г) 278
208 Декоксид тетрафосфора P4OJ0 (к, ж) . . . 279
209 Декоксид тетрафосфора Р4О10 (г) .... 280
210 Гидрид фосфора РН (г) 281
211 Дигидрид фосфора РН2 (г) 282
212 Отрицательный ион дигидрида фосфора
РН2 (г) 283
213 Оксид-гидрид фосфора НРО (г) 284
214 Фторид фосфора PF (г) 285
215 Дифторид фосфора PF2 (г) 286
216 Отрицательный ион дифторида фосфора
PF" (г) 287
217 Трифторид фосфора PF3 (г) 288
218 Пентафторид фосфора PFg (г) 289
219 Оксид-трифторид фосфора POF3 (г) .... 290
220 Хлорид фосфора РС1 (г) 291
221 Дихлорид фосфора РС1 2 (г) 292
222 Отрицательный ион дихлорида фосфора
РС1 2 (г) 293
223 Трихлорид фосфора РС13 (г) 294
224 Пентахлорид фосфора PCI s (г) 295
225 Оксид-трихлорид фосфора РОС1 3 (г) . . . 296
226 Фторид-хлорид фосфора PFC1 (г) .... 297
227 Отрицательный ион фторид-хлорида фосфо
pa PFC1" (г) 298
228 Дифторид-хлорид фосфора PF2Q (г) . . 299
229 Тетрафторид-хлорид фосфора PF4C1 (г) 300
230 Фторид-дихлорид фосфора PFC1 2 (г) ... 301
231 Трифторид-дихлорид фосфора PF3Q2 (г) 302
232 Дифторид-трихлорид фосфора PF2 Cl 3 (г) 303
233 Фторид-тетрахлорид фосфора PFC14 (г) 304
234 Оксид-дифторид-хлорид фосфора
POF2C1 (г) 305
235 Оксид-фторид-дихлорид фосфора
POFC12 (г) 306
236 Сульфид фосфора PS (г) 307
237 Нитрид фосфора PN (г) 308
Д. 1 , Ортоводород о-Н2 (г) 309
Д. 2 Параводород л-Н2 (г) 309
Д. 3 ВодаН2О (к, ж) 310
Д. 4 Перекись водорода Н2О2 (к, ж) 311
Д. 5 Ортодейтерий o-D 2 (г) 312
Д. 6 Парадейтерий «-D2 (r) 312
Д. 7 Ортотритий о-Т2 (г) 313
Д. 8 " Паратритий и-Т2 (г) 313
Д. 9 Дифторид диводородаН^ (г) 314
Д. 10 Трифторид триводородаН3Р3 (г) .... 314
Д. 11 ТетрафторидтетраводородаН^ (г) . . 315
Д. 12 Пентафторид пентаводорода Н$ F g (г) . . 315
Д. 13 ГексафторидгексаводородаН F6 (г) . . 316
Д. 14 Гептафторид гептаводородаН,^ (г) . . 316
Д. 15 ДибромВг2 (к, ж) 317
Д. 16 Дииод 12 (к, ж) '. . . . 317
Д. 17 ДиксенонХе2 (г) 318
Д. 18 Фторид ксенона XeF (г) 319
Д. 19 Дифторид ксенона XeF2 (к, ж). 319
Д. 20 Тетрафторид ксенона XeF4 (к, ж) .... 320
Д. 21 Гексафторид ксенона XeF (к, ж) .... 320
Д. 22 Нитрат аммония NH4NO3 (к, ж) 321
Д. 23 Фторид аммония NH4F (к, ж) 322
Д. 24 Фосфор Р (к, белый; ж) 323
Д. 25 Константы аппроксимирующего уравнения
для вириальных коэффициентов ..... 324
Д. 26. Критические постоянные 326

ТАБЛИЦЫ
ТЕРМОДИНАМИЧЕСКИХ
СВОЙСТВ

Класс точности
I
ЭЛЕКТРОН е (г)
Таблица 1
с;т
Ф°(Т)
S°(T)
Дж • К • моль"
кДж * моль
-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400 .
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.7$6
20.786
.081
.210
6.190
10.828
14.618
17.822
20.597
23.046
25.236
27.217
29.025
30.689
32.230
33.664
35.005
36.265
37.453
38.577
39.643
40.658
41.625
42.548
43.433
44.282
45.097
45.881
46.637
47.367
48.071
48.753
49.413
50.053
50.673
51.276
51.861
52.431
52.985
53.525
54.051
54.564
55.065
55.554
56.032
56.499
56.956
57.403
57.841
58.270
58.689
59.101
59.505
59.901
60.289
60.671
61.045
61.413
61.774
62.130
62.479
20.867
20.996
26.976
31.614
35.404
38.608
41.383
43.832
46.022
48.003
49.8! 1
51.475
53.016
54.450
55.791
57.051
58.239
59.363
60.429
61.444
62.411
63.335
64.219
65.068
65.883
66.667
67.423
68.153
68.857
69.539
70.199
70.839
71.459
72.062
72.647
73.217
73.771
74.311
74.837
75.350
75.851
76.340
76.818
77.285
77.742
78.189
78.627
79.056
79.475
79.887
80.291
80.687
81.07Г
81.45?
81.831
82.199
82.561
82.916
83.265
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18J07
20.786
22.865
24.943
2/.092
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930'
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
и
3
f—I
00
©
о
V
«о
00
R
к
II
н
10

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000*
17500
18000
18500
19000
19500
20000
С°ЛТ)
у
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ЭЛЕКТРОН е (г)
Ф°(Г)
Дж К • моль*
63.161
63.821
64.460
65.081
65.683
66.269
66.838
67.393
67.933
68.459
68.972
69.473
69.962
70.440
70.907
71.364
71.811
72.249
72.677
73.097
74.111
75.078
76.002
76.887
77.735
78.551
79.335
80.091
80.821
81.525
82.207
82.867
83.506
84.127
84.729
85.315
85.884
86.439
86.979
87.505
S°(T)
#°(Г)-#°@)
кДж * моль
83.947 128.873 -
84.607 133.031 -
85.246 137.188 -
85.867 141.345 —
86.469 145.502 -
87.055 149.659 -
87.624 153.817 -
88.179 157.974 —
88.719 162.131 -
89.245 166.288 -
89.758 170.445 -
90.259 174.603 -
90.748 178.760 -
91.226 182.917
91.693 187.074 -
92.150 191.231 -
92.597 195.388 -
93.035 199.546 —
93.463 203.703 -
93.883 207.860 -
94.89% 218.253 —
95.864 228.646 -
96.788 239.039 -
97.673 249.432 —
98.521 259.825 —
99.337 270.218 —
100.121 280.611 —
100.877 291.004 —
101 607 **П1 4Q7
102.311 311.790 -
102.993 322.183 —
103.653 332.576 -
104.292 342.969 —
104.913 353.362 —
105,515 363.755 —
106.101 374.148 —
106.671 384.541 —
107.225 394.934 —
107.765 405.327 —
108.291 415.720 —
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 А^ОП
I tOK/yj
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 1
(окончание)
11

Класс точности
I
КИСЛОРОД 0 (г)
L
Таблица 2
К
crm
Ф°(Т)
S°{T)
Дж К - моль
кДж • моль
-1
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
23.703
22.734
21.911
21.901
21.482
21.257
21.124
21.040
20.984
20.944
10.915
20.893
20.877
20.864
20.853
20.845
20.838
20.833
20.830
20.827
20.826
20.827
20.830
20.835
20.841
20.851
20.862
20.877
20.894
20.914
20.937
20.963
20.991
21.022
21.056
21.092
21.130
21.170
21.213
21.257
21.302
21.349
21.397
21.445
21.495
21.545
21.596
21.647
21.697
21.748
21.799
21.849
21.899
21.949
21.997
22.045
22.093
22.139
22.184
22.229
22.273
113.767
129.348
138.391
138.531
144.988
149.950
153.972
157.350
160.260
162.816
165.094
167.149
169.019
170.736
172.322
173.796
175.173
176.464
177.680
178.829
179.918
180.953
181.939
182.880
183.780
184.644
185.473
186.270
187.038
187.779
188.494
189.186
189.856
190.505
191.134
191.746
192.340
192.917
193.480
194.028
194.562
195.083
195.592
196.088
196.574
197.049
197.514
197.968
198.414
198.851
199.279
199.698
200.110
200.514
200.911
201.301
201.684
202.061
202.431
202.795
203.154
135.837
152.043
160.946
161.084
167.320
172.087
175.950
179.200
182.005
184.474
186.679
108.672
190.489
192.160
193.705
195.144
196.489
197.752
198.943
200.069
201.137
202.153
203.122
204.048
204.935
205.786
206.604
207.392
208.151
208.885
209.594
210.281
210.947
211.593
212.221
212.832
213.427
214.007
214.572
215.123
215.662
216.189
216.70*
217.208
217.701
218.185
218.659
219.124
219.580
220.028
220.468
220.900
221.325
221.743
222.153
222.557
222.955
223.346
223.732
224.112
224.485
2.207
4.539
6.728
6.766
8.933
11.069
13.187
15.295
17.396
19.492
21.585
23.676
25.764
27.851
29.937
32.022
34.106
36.190
38.273
40.356
42.438
44.521
46.604
48.687.
50.771
52.855
54.941
57.028
59.116
61.207
63.299
65.394
67.492
69.593
71.1697
73.804
75.915
78.030
80.149
82.273
84.401
86.533
88.670
90.812
92.959
95.111
97.268
99.431
101.598
103.770
105.947
108.130
110.317
112.510
114.707
116.909
119.116
121.328
123.544
125.764
127.990
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
ON
¦o
С
6
On
? *
2 3
2 6
О Os
CO
X
о
©
X
fi
00
+
.796
«N
II
О
i
+
.501
1
V
V
о
о
<t
1
2
0
?*,
II
12

КИСЛОРОД О (г)
Таблица 2
(окончание)
С°р (Т)
Ф°G)
Дж К -моль
Н°{Т)-Н°@)
кДж • моль
"
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
22.356
22.436
22.510
22.581
22.646
22.707
22.763
22.814
22.861
22.904
22.943
22.978
23.009
23.036
23.061
23.082
23.100
23.115
23.127
23.137
23.153
23.156
23.148
23.133
23.110
23.082
23.049
23.013
22.974
22.933
22.891
22.847
22.803
22.759
22.715
22.671
22.627
22.584
22.541
22.500
203.854
204.533
205.192
205.832
206.454
207.060
207.650
208.226
208.787
209.335
209.870
210.393
210.904
211.405
211.894
212.374
212.844
213.304
213.756
214.198
215.27С
216.294
217.275
218.216
219.121
219.991
220.830
221.640
222.422
223.178
223.910
224.620
225.308
225.976
226.624
227.255
227.869
228.467
229.049
229.616
225.217
225.928
226.620
227.293
227.948
228.587
229.210
229.818
230.411
230.990
231.556
232.110
232.651
233.180
233.698
234.205
234.702
235.188
235.665
236.132
237.261
238.339
239.368
240.353
241.297
242.203
243.073
243.911
244.717
245.496
246.247
246.973
247.675
248.356
249.015
249.654
250.274
250.877
251.463
252.033
132.452
136.932
141.426
145.936
150.458
154.994
159.541
164.098
168.666
173.243
177.827
182.419
187.018
191.623
196.232
200.847
205.465
210.086
214.711
219.337
230.910
242.488
254.064
265.635
277.196
288.744
300.277
311.792
323.289
334.766
346.222
357.656
369.069
380.459
391.828
403.174
414.498
425.801
437.082
448.343
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
3 .
г- i
Ч |
I
? '
1-й
s Ъ
о 3t
+ S
о
V
V
? *$ 1
^ 3- S
II
р
т
о
13

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ПОЛОЖИТЕЛЬНЫЙ ИОН КИСЛОРОДА 0 +
К°(Т)= р(О) .
с°7т
Ф°(П
Дж • К~ • моль"
20.786 134.062
20.786 134.191
20.786 140.171
20.786 144.809
20.786 148.599
20.786 151.803
20.786 154.578
20.786 157.027
20.786 159.217
20.786 161.198
20.786 163.006
20.786 164.670
20.786 166.211
20.786 167.645
20.786 168.986
20.786 170.246
20.786 171.434
120.786 172.558
20.786 173.624
20.786 174.639
20.786 175.606
20.786 176.530
20.787 177.414
20.787 178.263
20.788 179.078
20.789 179.862
20.790 180.618
20.792 181.348
20.795 182.052
20.799 1&2.734
20.804 183.394
20.810 184.034
20.818 184.654
20.827 185.257
20.839 185.843
20.853 186.412
20.870 , 186.967
20.890 187.507
20.912 188.034
20.938 188.547
20.968 189.048
21.001 189.538
21.038 190.017
21.079 190.484
21.125 190.942
21.175 191.390
21.229 191.829
21.288 192.259
21.351 192.680
21.419 193.093
21.491 193.498
21.568 193.896
21.650 194.287
21.736 194.671
21.826 195.048
21.921 195.418
22.020 195.783
22.124 196.141
22.231 196.494
-1
154.848
154.977
160.957
165.595
169.385
172.589
175.364
177.813
180.003
181.984
183.792
185.456
186.997
188.431
189.772
191.032
192.220
193.344
194.410
195.425*
196.392
197.316
198.200
199.049
199.864
200.649
201.405
202.134
202.839
203.521
204.182
204.822
205.443
206.047
206.634
207.205
207.761
208.304
208.833
209.349
209.854
210.348
210.831
211.304
211.768
212.223
212.669
213.108
213.538
213.962
214.379
214.789
215.192
215.591
215.983
216.370
216.752
217.130
217.502
е) АгН
//°(Л-//°@)
кДж • моль
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
43 887
51.965
54.044
56.123
58.202
60.281
62.360
64.440
66.520
68.601
70.682
72.764
74.848
76.932
79.018
81.106
83.196
85.289
87.384
89.483
91.584
93.690
95.800
97.915
100.036
102.161
104.293
106.432
108.577
110.730
112.891
115.060
117.238
119.425
121.623
123.830
126.047
(г)
Таблица 3
э@) = -1313.943 кДж • моль
lgK°(T)
230.4162
228.9904
171.5093
136.9678
113.9045
97.4052
85.0114
75.3569
67.6213
61.2823
55.9916
51.5080
47.6589
44.3179
41.3900
38.8025
36.4990
34.4348
32.5742
30.8882
29.3531
27.9494
26.6607
25.4733
24.3755
23.3575
22.4109
•21.5281
20.7030
19.9299
19.2041
18.5213
17.8776
17.2699
16.6950
16.1504
15.6337
15.1428
14.6758
14.2309
13.8066
13.4014
13.0140
12.6434
12.2883
11.9479
11.6211
11.3073
11.0056
10.7153
10.4357
10.1664
9.9066
9.6559
9.4138
9.1799
8.9537
8.7349
8.5231
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800 '
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
~ о
§ м т
L. * о
ОО чО Гл
8 Р ? *
3 © 7 к
'-н U-) /-ч Й
II '"~| ^ lo
о об о
+ С . п
^ о
+
1
ЧО ~
00 1
о |
V Т
? * Я
Ю211
Дж •
6000
Я пн V
О со
s 5 l
On ^
Ч чо «•"
^ со* 2
* L ?
со Н ^
2 ? »
• On ^
II +
14

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
i9000
19500
20000
С°р G)
22.457
22.698
22.951
23.216
23.490
23.773
24.062
24.357
24.654
24.954
25.254
25.552
25.848
26.141
26.428
26.709
26.983
27.249
27.507
27.755
28.331
28.838
29.274
29.637
29.929
30.154
30.315
30.418
30.469
30.472
30.435
' 30.362
30.259
30.131
29.981
29.814
29.634
29.442
29.243
29.039
ПОЛОЖИТЕЛЬНЫЙ ИОН
ф°G)
Дж К~ -моль"
197.184
197.853
198.503
199.135
199.751
200.351
200.936
201.508
202.067
202.614
203.149
203.674
204.188
204.692
205.188
205.674
206.152
206.623
207.085
207.541
208.649
209.718
21^.751
211.751
212.721
213.661
214.576
215.464
216.330
217.172
217.993
218.793
219.574
220.335
221.079
221.804
222.513
223.206
223.883
224.545
-1
218.235
218.952
219.654
220.343
221.020
221.686
222.341
222.986
223.623
224.251
224.871
225.483
226.088
226.685
227.276
227.860
228.437
229.008
229.573
230.131
231.499
232.829
234.121
235.375
236.591
237.769
238.911
240.015
241.084
242.117
243.115
244.080
245.013
245.915
246.786
247.628
248.443
249.231
249.993
250.731
КИСЛОРОДА О+ (г)
#°(Г)-#°@)
кДж * моль"*
130.516
135.031
139.596
144.212
148.883
153.609
158.392
163.234
168.135
173.096
178.117
183.197
188.338
193.536
198.793
204.107
209.476
214.900
220.376
225.902
239.926
254.222
268.753
283.484
298.378
-313.402
328.521
343.707
358.931
374.168
389.396
404.597
419.754
434.852
449.881
464.831
479.693
494.462
509.134
523.705
lgK°(T)
8.1190
7.7391
" 7.3812
7.0434
6.7239
6.4212
6.1341
5.8613
5.6016
5.3542
5.1182
4.8926
4.6769
4.4704
4.2724
4.0824
3.8999
3.7244
3.5555
3.3928
3.0111
2.6612
2.3389
2.0410
1.7645
1.5070
1.2666
1.0414
.8299
.6308
.4430
.2654
.0972
-.0625
-.2142
-.3587
-.•4965
-.6280
-.7538
-.8839
Т
К
6&0
6400
6600
6800 ,
7000
7200
7400
7600
7800
8000
8200
8400
• 8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 3
. (окончание)
•"*
о
О\ ~
Г""* 1
о 9
+ ?
CN „ц
VO « V
\О j. О
о ^ о
© « гм
° Я v
со V
О г
•§ ? v
* ' v
S Й §
" а 2
i + т
Г» <N
00 Г-ч
2 ^ „
7 7 з
О

Класс точности
Ш-С
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
«АЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
21.685
21.677
21.359
21.180
21.073
21.003
20.956
20.923
20.898
20.880
20.865
20.854
20.845
20.838
20.832
20.827
20.822
20.819
20.816
20.813
20.811
20.809
20.807
20.805
20.804
20.802
9ft ftfti
Xv.Ov/ 1
20.800
20.799
20.799
20.798
20.797
20.796
20.796
20.795
20.795
20.794
20.794
20.794
20.793
20.793
20.793
20.792
20.792
20.792
20.792
20.791
20.791
20.791
20.791
20.791
20.790
20.790
20.790
20.790
20.790
20.790
20.790
20.789
ОТРИЦАТЕЛЬНЫЙ
К°(Т)= р@) •
Ф°(Т)
Дж • К • моль
135.646
135.783
142.104
146.977
150.937
154.270
157.146
159.675
161.931
163.967
165.822
167.526
169.101
170.565
171.933
173.217
174.426
175.569
176.653
177.683
178.664
179.601
180.498
181.357
182.183
182.977
1 оо 719
1 Од. / 1«
184.480
185.192
185.881
186.548
187.194
187.820
188.428
189.020
189.594
190.153
190.698
191.228
191.746
192.251
192.744
193.225
193.696
194.156
194.606
195.047
195.479
195.901
196.316
196.722
197.120
197.511
197.895
198.272
198.642
199.005
199.363
199.714
р (е) • р~1 (СГ)
S°(T)
-1
157.685
157.819
164.007
168.752
172.603
175.846
178.647
181.113
183.316
185.307
187.124
188.793
190.338
191.776
193.121
194.384
195.574
196.700
197.767
198.783
199.751
200.676
201.562
202.411
203.227
204.012
ОПА 7ftft
iUt. / UO
205.498
206.204
206.886
207.546
208.186
208.807
209.410
209.995
210.565
211.120
211.660
212.186
212.700
213.201
213.690
214.168
214.635
215.092
215.540
215.977
216.406
216.826
217.238
217.641
218.037
218.426
218.808
219.182
219.550
219.912
220.267
220.616
ИОН КИСЛОРОДА 0" (г)
V
/7°СЛ-//О«»
кДж • моль
6.571
6.611
8.761
10.887
12.999
15.103
17.201
19.295
21.386
23.474
25.562
27.648
29.733
31.817
33.900
35.983
38.065
40.148
42,229
44.311
46.392
48.473
50.554
52.634
54.715
56.795
58.875
60.955
63.035
65.115
67.195
69.275
71.354
73.434
75.513
77.593
79.672
81.752
83.831
85.911
87.990
90.069
92.148
94.228
96.307
98.386
100.465
102.544
104.623
106.702
108.781
110.861
112.940
115.019
117.098
U&I77
121.255
123.334
125.413
э@) = 141.200 кДж-моль
lgK°(T)
-24.5897
-24.4303
-17.9646
-14.0300
-11.3704
-9.4446
-7.9808
-6.8271
-5.8920
-5.1171
-4.4631
-3.9027
-3.4164
-2.9898
-2.6120
-2.2746
-1.9712
-1.6965
-1.4464
-1.2176
-1.0072
-.8130
-.6329
-.4655
-.3093
-.1631
-.0258
Л 032
.2250
.3400
.4490
.5524
.6507
.7443
.8336
.9189
1.0005
1.0786
1.1536
1.2255
1.2947
1.3613
1.4255
1.4873
1.5471
1.6048
1.6606
1.7146
1.7669
1.8176
1.8668
1.9145
1.9609
2.0060
2.0498
2.0925
2.1340
2.1745
2.2140
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
On
ON
On
On
II
I
X
v©
О
d
i
i
*•*
r-
s
s
X
?
SO
00
•
о
I***
«o
d
vH
II
с
T а б л и
T
«g
k
f
00
8
I
о
С
i *
w
О
'й
I
•
X
V)
JO
о
1
oS
d
+ '
00
d
1
T
§
I
so
«—i
О
1—t
II
я
Ю
00
i *
Q,
о
ц а 4
i
л
о
1
k
и
о 5
Я
о
8
«о
V
к
V
§
о
.г.
о
0
II
16

г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р(Т)
20.789
20.789
20.789
20.789
20.789
20.788
20.788
20.788
20.788
20.788
20.788
20.788
20.788
20.788
20.788
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.787
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ОТРИЦАТЕЛЬНЫЙ ИОН
1 Ф°G)
Дж К*" • моль
200.400
201.063
201.706
202.330
202.935
203.523
204.096
204.652
205.195
205.723
206.239
206.741
207.232
207.712
208.181
208.640
209.088
209.528
209.958
210.379
211.396
212.367
213.293
214.180
215.031
215.849
216.635
217.393
218.124
218.831
219.514
220.175
220.816
221.438
222.042
222.628
223.199
223.754
224.295
224.822
| S°(T)
-1
221.298
221.958
222.598
223.218
223.821
224.407
224.976
225.531
226.071
226.597
227.110
227.611
228.100
228.578
229.045
229.502
229.949
230.387
230.816
231.236
232.250
233.217
234.141
235.025
235.874
236.689
237.474
238.230
238.959
239.664
240.345
241.005
241.645
242.266
242.868
243.454
244.023
244.578
245.118
245.644
КИСЛОРОДА 0"
Я°(Л-#°@)
кДж • моль*
1
;
129.571
133.729
137.887
142.045
146.202
150.360
154.518
158.675
162.833
166.991
171.148
175.306
179.463
183.621
187.778
191.936
196.093
200.251
204.408
208.566
218.959
229.353.
239.746
250.140
260.533
270.926
281.320
291.713
302.106
312.500
322.893
333.286
343.679
354.0J3
364.466
374.859
385.252
395.645
40/6.039
416.432
(г)
2.2900
2.3624
2.4316
2.4977
2.5611
2.6219
2.6802
2.7364
2.7905
2.8426
2.8929
2.9416
2.9886
3.0341
3.0782
3.1210
3.1625
3.2028
3.2420
3.2801
3.3710
3.4563
3.5366
3.6123
3.6840
3.7521
3.8168
3.8785
3.9374
3.9938
4.0478
4.0996
4.1495
4.1974
4.2437
4.2883
4.3314
4.3730
4.4133
4.4620
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
1
<Й
о
О
о
1
»о
о
§
S3
оо
00
00
г~
о
+
СО
о
II
о
Т а бл
и ца 4
(окончание)
i
§
i
к
с*
Н
О
о
о
ё
3
о
о
1
V
[ оооог
V
V
о
8
1-4
1
О
1-Н
Ь,
II
872
17

Класс точности
I-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
230Q
2400
2500
2600
2700
2800
2900
3000
3100
320.0
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'Р
ДИКИСЛОРОД О2
К°(Т) - р2 @) • р (О2)
Ф°(Т)
S°iT)
Дж • К • моль
29.112
29.127
29.378
29.387
30.108
31.093
32.093
32.986
33.739
34.363
34,8$0
35.312
35.681
36.005
36.296
36.566
36.822
37.069
37.310
37.547
37.783
38.016
38.248
38.478
38.705
38.929
39.150
39.366
39.578
39.784
39.986
40.181
40.371
40.555
40.734
40.906
41.074
41.236
41.393
41.546
41.695
41.840
41.981
42.119
42.253
42.385
42.515
42.642
42.767
42.889
43.009
43.127
43.243
43.356
43.467
43.575
43.680
43.782
43.881
43.976
44.067
144.182 173.192
164.310 193.372
175.921 205.035
176.101 205.217
184.495 213.760
191.052 220.582
196.465 226.340
201.099 231.356
205.165 235.811
208.796 239.822
212.084 243.471
215.092 246.816
217.866 249.904
220.442 252.774
222.848 255.453
225.106 257.966
227.235 260.334
229.248 262.574
231.159 264.700
232.978 266.723
234.714 268.655
236.375 270.504
237.967 272.278
239.496 273.983
240.967 275.626
242.385 277.210
243.754 278.741
245.078 280.223
246.359 281.659
247.600 283.051
248.804 284.403
249.974 285.717
251.111 286.996
252.218 288.241
253.295 289.455
254.345 290.638
255.369 291.793
256.369 292.920
257.345 294.022
258.300 295.099
259.233 296.153
260.146 297.184
261.040 298.194
261.916 299.183-
262.774 300.153
263.615 301.104
264.440 302.036
265.250 302.952
266.044 303.850
266.825 304.733
267.592 305.600
268.345 306.452
269.086 307.290
269.815 308.114
270.532 308.924
271.237 309.722
271.931 310.506
272.615 311.279
273.2S8 312.039
273.951 312.788
274.604 313.526
\"
Н°(Т)-Н°@)
кДж • моль
2.901
5.812
8.680
8.735
11.706
14.765
17.925
21.180
24.517
27.923
31.386
34.897
38.447
42.031
45.646
49.290
52.959
56.654
60.373
64.116
67.882
71.672
75.486
79.322
83.181
87.063
90.967
94.893
98.840
102.808
106.797
110.805
11 4.833
118.879
122.943
127.025
131.i124
135.240
139.371
143.51.8
147.680>
151.856
156.047
160.251
164.469
168.700
172.943
177.200
181.468
185.748
190.040
194.344
198.658
202.983
207.319
211.664
216.020
220.384
224.757
229.139
233.529
(г)
"@) =493.566
-253.4552
-123.9743
-81.2012
-80.6628
-58.9425
-45.8762
-37.1452
-30.8961
-26.2006
-22.5426
-19.6118
-17.2106
-15.207Q
-13.5096
-12.0531
-10.7894
-9.6825
-8.7049
-7.8352
-7.0564
-6.3548
-5.7196
-5.1418
-4.6138
-4.1295
-3.6837
-3.2720
-2.8906
-2.5363
-2.2062
-1.8981
-1.6097
-1.3392
-1.0851
-.8458
-.6202
-.4070
-.2053
-.0142
.1672
.3395
.5034
.6596
.8085
.9507
.0866
.2165
.3410
.4603
*5748
.6846
.7902
.8918
.9895
2.0836
2.1743
2.2618
2.3462
2.4277
2.5064
2.5826
Таблица 5
> кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
00 1
00 V
о .
°^ ?
со II Й
" ° Я ^
^ 1 2 2
V, - =*
<Ч г. О ос!
* §
О
1 Ы Ъ* /—
о • *
СО «й О
*-¦ Д о
—4 R. О
о "Ц V
О 00
к я »
•о Я Т
Я © 2
СО 00 ||
со jo "
00 *-< w
II +
18

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С; (Г)
ДИКИСЛОРОД О2 (г)
Ф°(Г)
S°(T)
Дж К~ -моль"
44.236
44.386
44.514
44.620
44.702
44.758
44.788
44.792
44.769
44.721
44.647
44.549
44.428
44.286
44.124
43.944
43.747
43.536
43.311
43.075
42.447
41.782
41.099
40.416
39.744
39.092
38.467
37.873
37.312
36.785
36.292
35.832
35.404
35.006
34.638
34.296
33.980
33.687
33.415
33.164
275.883 314.969
277.127 316.370
278.336 317.730
279.51? 319.053
280.663 320.338
281.782 321.588
282.874 322.802
283:941 323.983
284.982 325.132
286.000 326.248
286.995 327.334
287.968 328.389
288.920 329.415
289.851 330.412
290.763 331.381
291.656 332.323
292.531 333.239
.293.389 334.130
294.229 334.995
295.052 335.836
297.042 337.838
298.939 339.705
300.749 341.447
302.479 343.076
304.133 344.600
305.716 346.029
307.234 347.371
308.690 348.635
310.087 349.826
311.430 350.951
312.721 352.016
313.965 353.027
315.162 353.988
316.317 354.902
317.431 355.775"
318.508 356.608
319.547 357.406
320.553 358.171
321.526 358.905
322.469 359.611
Я°(Г)-Я°@)
кДж * моль
242.329
251.155
260.000
268.860
277.728
286.599
295.466'
304.324
313.166
321.987
330.779
339.538
348.258
356.935
365.562
374.137
382.655
391.113
399.508
407.836
428.356
448.424
468.028
' 487.164
505.839
524.064
541.855
559/230
576.211
592.819
609.075
625.001
040.618
655.947
671.005
685.812
700.384
714.736
728.884
742.841
2.7275
2.8634
2.9911
3.1113
3.2247
3.3319
3.4333
3.5293
3.6206
3.7073
3.7898
3.8685
3.9435
4.0153
4.0839
4.1496
4.2126
4.2731
4.3312
4.3870
4.5178
4.6373
4.7472
4.8486
4.9426
5.0301
5.1119
5.1887
5.2609
5.3290
5.3934
5.4546
5.5127
5.5682
5.6211
5.6717
5.7202
5.7668
5.8116
5.8547
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000 .
Таблица 5
(окончание)
'х
со 1
2 |
? 7 §
1 к
2 ^ V
о тн
О СМ **"
+ 1^ V
J5 '"н о
я «С §
+ 1 ~
,- X *ч
ГО Г- ||
г-- оо
II
^ +
к,
о

Класс точности
I-C
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИКИСЛОРОДА О; (г)
Таблица 6
К°.(Т)= р2(О) •
г//°@) = - 671.434 кДж-моль
-1
Ф°(Т)
SO(T)
Дж • к" * • моль"J
кДж • моль
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.670
30.660
30.474
30.854
31.508
32.238
32.938
33.565
34.112
34.581
34.982
35.325
35.620
35.875
36.097
36.291
36.463
36.617
36.754
36.878
36.991
37.094
37.189
37.278
37.360
37.438
37.511
37.581
37.648
37.713
37.775
37.837
37.897
37.957
38.018
38.079
38.142
38.207
38.275
38.346
38.422
38.503
38.590
38.684
38.785
38.895
39.015
39.145
39.286
39.440
39.606
39.785
39.979
40.187
40.410
40.649
40.904
41.175
41.462
174.052
174.245
183.203
190.119
195.766
200.552
204.720
208.419
211.752
214.790
217.584
220.172
222.585
224.845
226.973
228.984
230.889
232.701
234.427
236.077
237.657
239.173
240.629
242.031
243.382
244.687
245.948
247.168
'248.350
249.496
250.609
251.690
252.741
253.764
254.760
255.731
256.678
257.602
258.504
259.386
260.248
261.091
261.916
262.724
263.516
264.292
265.052
265.799
266.531
267.250
267.956
268.651
269.333
270.004
270.664
271.313
271.952
272.582
273.202
205.281
205.471
214.249
221.082
226.763
231.674
236.025
239.942
243.507
246.781
249.808
252.622
255.251
257.717
260.040
262.234
264.313
266.289
268.171
2^9.967
271.685
273.332
274.912
276.432
277.896
279.307
280.670
281.988
283.263
284.498
285.697
286.860
287.991
289.090
290.160
291.203
292:219
293.211
294.179
295.125
296.050
296.955
297.841
298.709
299.560
300.396
301.216
302.022
302.814
303.593
304.361
305.117
305.862
306.598
307.324
308.041
308.750
309.452
310.146
9.311
9.368
12.418
15.481
18.598
21.785
25.045
28.370
31.755
35.190
38.669
42.185
45.732
49.307
52.906
56.526
60.164
63.818
67.486
71.168
74.862
78.566
82.280
86.003
89.735
93.475
97.223
100.978
104.739
108.507
112.281
116.062
119.849
123.641
127.440
131.245
135.056
138.874
142.698
146.529
150.367
154.213
158.068
161.931
165.805
169.689
173.584
177.492
181.414
185.350
189.302
193.271
197.260
201.268
205.297
209.350
213.428
217.532
221.663
122.9926
122.2650
92.9330
75.3120
63.5487
55.1338
48.8124
43.8872
39.9399
36.7040
34.0021
31.7111
29.7433
28.0342
26.5355
25.2102
24,0295
22.9707
22.0157
21.1496
20.3604
19.6382
18.9747
18.3628
17.7966
17.2712
16.7822
16.3258
15.8989
15.4986
15.1224
14.7682
14.4341
14.1183
13.8194
13.5360
13.2669
13.0110
12.7674
12.5351
12.3134
12.1015
11.8.988
11.7047
11.5186
11.3400
11.1685
11.0036
10.8450
10.6922
10.5450
10.4031
10.2661
10.1337
10.0059
9.8822
9.7625
9.6466
9.5344
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
«о
<ч
00
3
со
о
о «
со
S §
8
00
.003
о
1
|
*>
со
00
т—<
00
г*-
CN
II
С-
со
а
со
с»
X
со
1
X
г-
•о
Щ
с*
+
VO
V
V
20

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИКИСЛОРОДА
С°р (Г)
Дж К • моль*
42.083 274.416
42.768 275.597
43.511 276.746
44.308 277.867
45.152 278.961
46.035 280.029
46.947 281.075
4.7.878 282.099
48.818 283.103
49.754 284.088
50.676 285.055
51.572 286.006
52.433 286.941
53.248 287.861
54.009 288.767 .
54.708 289.660
55.339 2&0.540
55.896 291.408
56.377 292.264
56.778 293.109
57.427 295.175
57.584 297.177
57.293 299.119
56.618 301.003
55.634 302.830
54.418 304.602
53.039 306.321
51.559 307.987
50.029 309.602
48.490 311.166
46.971 312.682
45.496 314.151
44.078 315.573
42.729 316.951
41.453 318.287
40.252 319.580
39.128 320.835
38.077 322.051
37.097 323.230
36.185 324.374
-1
#°(Л-#°@)
кДж * моль""
311.516 230.017
312.862 238.501
314.190 247.128
315.500 255.909
316.797 264.854
318.081 273.972
319.355 283.269
320.619 292.752
321.875 302.421
323.123 312.278
324.362 322.321
325.594 332.547
326.818 342.947
328.033 353.516
329.238 364.242
330.433 375.115
331.616 386.120
332.787 397.244
333.945 408.473
335.088 419.789
337.876 448.359
340.552 477.130
343.107 505.865
345.532 534.355
347.824 562.427
349.983 589.945
352.011 616.812
353.913 642.962
355.696 668.358
357.365 692.985
358.930 716.846
360.398 739.958
361.776 762.347
363.072 784.043
364.291 805.083
365.442 825.503
366.529 845.343
367.558 864.639
368.534 883.427
369.462 901.742
О2+ (г)
9.3199
9.1179
8.9272
8.7469
8.5760
8.4137
8.2593
8.1123
7.9719
7.8378
7.7095
7.5865
7.4684
7.3550
7.2458
7.1407
7.0393
6.9415
6.8470
6.7556
6.5397
6.3398
6.1539
5.9806
5.8184
5.6662
5.5232
5.3885
5.2613
5.1412
5.0275
4.9197
4.8175
4.7203
4.6280
4.5400
4.4562
4.3763
4.3000
4.2174
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 6
(окончание)
т* т
И
Т
¦к ™ х
СО ^ °
S ©
s mx s
§ 3 V
^ к.
1 ' "
j X
а ? §
оо *О о
S 2 -
¦ + ?
8 2 2
™ 2 ^
<N'7 х
i
g
>е
21

Класс точности
IV-C
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
31.418
31.433
32.453
33.531
34.423
35.119
35.656
36.077
36.412
36.685
36.913
37.107
37.275
37.424
37.558
37.680
37.794
37.901
38.003
38.101
38.195
38.288
38.380
38.471
38.561
38.652
38.743
38*836
38.929
39.024
39.120
39.218
39.316
39.416
39.516
39.617
39.718
39.818
39.918
40.015
40.11
40.203
40.292
40.376
40.455
40.529
^0.597
40.658
40.71
40.756
40.794
40.822
40.842
40.852
40.853
40.844
40.825
40.797
40.759
ОТРИЦАТЕЛЬНЫЙ
К°(Т)= р2(О)
Ф°(П
Дж • К • моль
177.953
178.146
187.160
194.207
200.028
205.008
209.373
213.263
216.777
219.984
222.934
225.668
228.214
230.599
232.842
234.959
236.965
238.869
240.683
242.415
244.072
245.660
247.185
248.652
250.066
251.430
252.747
254.022
255.256
256.452
257.613
258.740
259.837
260.903
261.942
262.954
263.941
264.904
265.845
266.764
267.663
268.542
269.402
270.244
271.069
271.878
272.672
273.450
274.213
274.963
275.699
276.422
277.132
277.831
278.517
279.193
279.858
280.512
281.155
Р (<?) • Р~Х (О2)
'1
209.227
209.421
218.596
225.956
232.151
237.512
242.238
246.463
250.282
253.766
256.968
259.930
262.686
265.263
267.683
269.964
272.120
274.167
276.113
277.970
279.745
281.445
283.076
284.645
286.155
287.612
9«Q 020
ллУЭ U»\J ?*\J
290.381
291.699
292.977
294.217
295.423
296.595
297.736
298.848
299.932
300.990
302.023
303.032
304.019
304.984
305.929
306.855
307.761
308.649
309.520
310.374
311.212
312.034
312.840
313.632
314.410
315.173
315.923
316.659
317.381
318.092
318.789
319.475
ИОН ДИКИСЛОРОДА 0" (г)
я°(Л-//°@)
кДж • моль
9.324
9.383
12.574
15.874
19.274
22.752
26/292
29.880
33.505
37.160
40.840
44.542
48.261
51.996
55.745
59.507
63.281
67.066
70.861
74.666
78.481
82.305
86.139
89.981
93.833
97.693
101 S63
1 \J I m*J\J%J
105.442
109.330
113.228
117.135
121.052
124.979
128.915
132.862
136.819
140.786
144.762
148.749
152.746
156.752
160.768
164.793
168.826
172.868
176.917
180.973
185.036
189.104
193.178
197.256
201.336
205.420
209.504
213.590
217.675
221.758
225.839
229.917
Таблица 7
э@) = 536.066 кДж- моль 1
\gK°{T)
Т
К
-88.7488 298.15
-88.1584 300
-64.3083 400
-49.9153 500
-40.2677 600
-33.3407 700
-28.1195 800
-24.0388 900
-20.7588 1000
-18.0626 1100
-15.8056 1200
-13.8872 1300
-12.2356 .1400
-10.7979 1500
-9.5344 1600
-8.4148 1700
-7.4154 1800
-6.5174 1900
-5.7059 2000
-4.9686 2100
-4.2955 2200
-3.6785 2300
-3.1106 2400
-2.5861 2500
-2.0999 2600
-1.6480 2700
-1 2267 2800
1 • 4* Л* \J I ^\J\J\J
-.8330 2900
-.4641 3000
..1176 3100
.2085 3200
.5159 3300
.8064 3400
1.0813 3500
1.3420 3600
1.5894 3700
1.8247 3800
2.0488 3900
2.2624 4000
2.4664 4100
2.6614 4200
2.8480 4300
3.0267 4400
3.1981 4500
3.3627 4600
3.5208 4700
3.6729 4800
3.8193 4900
3.9604- 5000
4.0964 5100
4.2276 5200
4.3544 5300
4.4769 5400
4.5953 5500
4.7099 5600
4.8209 5700
4.9285 5800
5.0328 5900
5.1339 6000
7
7 §
л • 7
s§ i 1
*О С{ о Т
го ' 2? ,-J^
* § 1 *
ON *—' Jg
-< 12 " t§
ГО fN R.
и i 2 ^
V? II io ^
^ 1-H О
О oo
ON II
U <N
• « с о 5
S i « со*
s
*^ о
+
7^
H
^ 'g
6 1
+ s
v 7 /—»
Os >* *
i * I
si °
§ "к v
x *¦ V
- 7 о
го ' о
00 OJ «О
го ^i о
^ rN ~-«
^Г ,. с**
чо ^
го го "
^ О н
ON . ч"^
fN rN
II -
о
22

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
ОТРИЦАТЕЛЬНЫЙ ИОН ДИКИСЛОРОДА
С°р (Г)
Ф°G)
Дж К~ -моль"
40.655 282.413
40.514 283.633
40.337 284.818
40.127 285.969
39.887 287.087
39.619 288.176
39.327 289.235
39.014 290.267
38.683 291.271
38.336 292.251
37.978 293.206
37.609 294.137
37.233 295.047
36.853 295.934
36.470 296.801
36.085 297.647
35.702 298.475
35.320 299.283
34.942 300.074
34.569 300.847
33.660 302.708
32.795 304.473
31.981 306.149
31.219 307.743
30.511 309.262
29.855 310.712
29.249 312.096
28.691 313.420
28.177 314.688
27.704 315.904
27.269 317.072
26.868 318.193
26.499 319.273
26.160 320.312
25.846 321.314
25.557 322.281
25.290 323.215
25.043 324.118
24.815 324.991
24.603 325.837
S°(T)
-1
кДж * моль""
320.810 238.059
322.098 246.177
323.342 254.262
324.544 262.309
325.703 270.311
326.823 278.262
327.905 286.157
328.950 293.992
329.959 301.762
330.934 309.464
331.876 ' 317.096
332.787 324.654
333.667 332.139
334.519 339.547
335 343 346.880
336.140 354.135
336.912 361.314
337.660 368.416
338.384 375.442
339.086 382.393
340.751 399.449
342.296 416.060
343.736 432.252
345.081 448.050
346.341 463.480
347.525 478.569
348.640 493.344
349.693 5Q7.827
350.691 522.042
351.638 536.010
352.540 549.752
353.399 563.285
354.220 576.626
355.006 589.789
355.760 602.790
356.484 615.640
357.180 628.351
357.851 640.933
358.499 653 397
359.124 665.751 .
о; (г)
5.3275
5.5103
5.6832
5.8472
6.0029
6.1511
6.2923
6.4270
6.5558
6.6791
6.7973
6.9108
7 0198
7.1246
7.2256
7.3230
7.4170
7.5078
7.5956
7.6805
7.8816
8.0681
8.2420
8.4047
8.5575
8.7015
8.8375
8.9665
9.0890
9.2057
9.3170
9.4234
9.5254
9.6232
9.7172
9.8076
9.8947
9.9788
10.0600
10.1481
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 7
(окончание)
+
^ ё
i
iC l> о
^ ^ о
S m S
+ 1 v
S 7 ^
00 ^
00 ? <=> '
?S О О
• On О
04 2 ~
+ 'V
- ? '2
ЧО Tf
vd ^ к
00 ГО ||
II Т *—'
Б

Класс точности
IV-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
гаоо
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
33.313
35.128
39.374
39.461
43.964
47.588
50.301
52.317
53.83.9
55.017
55.959
56.745
57.444
58.121
58.843
59.681
60.703
61.979
63.570
65.521
67.862
70.600
73.713
77.153
80.845
84.693
88.580
92.387
95.992
99.286
102.177
104.598
106.510
107.900
108.779
109.179
Г09.147
108.741
108.019
107.046
105.879
104.572
103.175
101.726
100.260
98.806
97.385
96.013
94.702
93.461
92.295
91.207
90.197
89,267
88.415
87.638
86.932
86.296
85.727
85.221
84.774
К°(Т)= р3(О) -р~
Ф°G)
Дж • К • моль"
167.405
190.520
204.128
204.343
214.585
222.939
230.099
236.414
242.086
247.246
251.987
256.375
260.462
264.288
267.888
271.288
274.512
277.580
280.510
283.318
286.017
288.621
291.141
293.588
295.970
298.297
300.575
302.810
305.008
307.173
309.308
311.414
313.494
315.549
317.580
319.585
321.566
323.521
325.452
327.356
329.233
33L083
332.906
334.702
336.469
338.209
339.921
341.605
343.261
344.890
346.492
348.067
349.617
351.140
352.638
354.112
355.561
356.987
358.389
359.769
361.128
1'<Р9>
S°{T)
200.660
224.120
238.896
239.139
251.124
261.341
270.270
278.183
285.273
291.685
297.532
302.903
307.871
312.496
316.828
320.915
324.799
328.516
332.102
335.590
339.008
342.384
345.739
349.091
352.450
355.829
359.227
362.642
366.067
369.494
372.910
376.301
379.654
382.954
386.190
389.349
392.426
395.411
398.302
401.096
403.792
406.391
408.894
411.305
413.627
415.864
418.019
420.099
422.106
424.046
425.923
427.739
429.501
431.210
432.870
434.485
436.058
437.591
439.087
440.548
441.976
ОЗОН О3 (г)
М
//°(/')—//°@)
кДж • моль
3.326
6.720
10.366
10.439
14.616
19.201
24.103
29.238
34.550
39.995
45.545
51.181
56.891
62.669
68.517
74.442
80.459
86.591
92.866
99.317
105.983
112.903
120.115
127.656
135.554
143.830
152.494
161.544
170.965
180.732
190.809
201.151
211.711
222.436
233.274
244.176
255.096
265.992
276.833
287.588
298.236
308.760
319.147
329.392
339.492
349.445
359.254
368.924
378.459
387.866
397.154
406.327
415.398
424.370
433,254
442.056
450.783
459.444
468.045
476.592
485.091
э@) =595.892
lgK°(T)
-302.1746
-145.3115
-93.3727
-92.7182
-66.3031
-50.3991
-39.7677
-32.1573
-26.4393
-21.9852
-18.4175
-15.4952
-13.0575
-10.9931
-9.2224
.-7.6868
-6.3426
-5.1562
-4.1015
-3.1580
-2.3092
-1.5420
-.8454
-.2106
.3700
.9025
1.3923
1.8438
2.2611
2.6474
3.0058
3.3389
3.6489
3.9380
4.2080
4.4606
4.6973
4.9193
5.1280
5.3245
5.5096
5.6844
5.8497
6.0061
6.1544
6.2951
6.4289
6.5562
6.6774
6.7931
6.9035
7.0091
7.1100
7.2067
7.2995
7.3884
7.4738
7.5558
7.6347
7.7107
7.7838
. кДж • моль 1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400 ¦
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
ON
ON
*t
II
00
VO
о
г*
1
г-
со
о
о
со
t
со
«о
со
II
г
Таблица 8
а
§
1 2
1 * 'е
2 б о
1 § т
? 2 к
i !L *
~* Ь4 ^
о оо
ON II
S « V
о S
<з ^^
т
А
1
а я
Ъ 1
«о vo
Й V
00
"Н fc-ч
1 w
V
CN СЭ
( со
со 1
JsJ О
г—1
?? и
г*-
VO ъ
«о w
CN
|
24

Класс точности
I
ВОДОРОД Н (г)
Таблица 9
сп(Т)
Ф°(Л
S°iT)
ДжК
//°GW/ «О
кДж • моль"
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
26.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
71.114
85.521
93.821
93.949
99.929
104.567
108.357
111.561
114.337
116.785
118.975
120.956
122.765
124.429
125.969
127.403
128.745
130.005
131.193
132.317
133.383
134.397
135.364
136.288
137.173
138.021
138.837
139.621
140.377
141.106
141.811
142.493
143.153
143.792
144.413
145.015
145.601
. 146.170
146.725
147.265
147.791
148.304
148.805
149.294
149.772
150.239
150.696
151.143
151.581
152.009
152.429
152.841
153.244
153.640
154.029
154.410
154.785
155.153
155.514
155.869
156.219
91.900
106.307
114.604
114.735
120.715
125.353
129.143
132.347
135.123
137.571
139.761
141.742
143.551
145.215
146.755
148.189
149.531
150.791
151.979
153.103
154.169
155.183
156.150
157.074
157.959
158.807
159.623
160.407
161.163
161.892
162.597
163.279
163.939
164.578
165.199
165.801
166.387
166.956
167.511
168.050
168.577
169.090
169.591
170.080
170.558
171.025
171.482
171.929
172.366
172.795
173.215
173.627
174.030
174.426
174.815
175.196
175.571
175.939
176.300
176.655
177.005
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
О ^"
5 ©¦
О
С
X
г-
On
I
г*
о о;
I
§
v
.786:
+
го
00
VO
vo
V
100
т"
о
II
н
ь
25

ВОДОРОД Н (г)
Таблица 9
(окончание)
С°р(Т)
Ф°G)
к
Дж К"" • моль""!
Я°(Г)-Я°@)
кДж • моль"
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
1.7000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.7?6
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20:786
20.786
156.900
157.560
158.200
158.820
159.423
160.009
160.578
161.132
161.672
162.199
162.712
163.213
163.702
164.180
164.647
165.104
165,551
165.988
166.417
166.837
167.851
168.818
169.742
170.626
171.475
172.290
173.075
173.831
174.560
175.265
175.946
176.606
177.246
177.866
178.469
179.055
179.624
180.178
180.718
181.244
177.686
178.346
178.986
179.606
180.209
180.794
181.364
181.918
182.458
182.984
183.498
183.999
184.488
184.966
185.433
185.890
186.337
186.774
187.203
187.623
188.637
1 $9.604
190.528
191.412
192.261
193.076
193.861
194.617
195.346
196.051
196.732
197.392
198.032
198.652
199.255
199.840
200.410
200.964
201.504
202.031
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
26

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ПОЛОЖИТЕЛЬНЫЙ ИОН ВОДОРОДА Н+ (г]
А' °(Т) = р (Н) • р'1 (Н+ ) • р'1 (е) Ar H
Ф°(Т)
Дж • К • моль
//°(Г)_//°@)
кДж • моль
88.052 108.838 6.197
88.180 108.966 6.236
94.160 114.946 8.314
98.798 119.584 10.393
102.588 123.374 12.472
105.792 126.578 14.550
108.568 129.354 16.629
111.016 131.802 18.707
113.206 133.992 20.786
115.187 135.973 22.865
116.996 137.782 24.943
118.659 139.445 27.022
120.200 140.986 29.100
121.634 142.420 31.179
122.975 143.761 33.258
124.236 145.022 35.336
125.424 146.210 37.415
126.548 147.334 39.493
127.614 148.400 41.572
128.628 149.414 43.651
129.595 150.381 45.729
130.519 151.305 47.808
131.403 152.189 49.886
132.252 153.038 51.965
133.067 153.853 54.044
133.852 154.638 56.122
134.608 155.394 58.201
135.337 156.123 60.279
136.042 156.828 62.358
136.723 157.509 64.437
137.383 158.169 66.515
138.023 158.809 68.594
138.643 159.429 70.672
139.246 160.032 72.751
139.831 160.617 74.830
140.401 161.187 76.908
140.955 161.741 78.987
141.495 162.281 81.065
142.021 162.808 83.144
142.535 163.321 85.223
143.036 163.822 87.301
143.525 164.311 89.380
144.003 164.789 91.458
144.470 165.256 93.537
144.927 165.713 95.616
145.374 166.160 97.694
145.811 166.597 99.773
146.240 167.026 101.852
146.660 167.446 103.930
147.071 167.857 106.009
147.475 168.261 108.087
147.871 168.657 110.166
148.259 169.045 112.245
148.641 169.427 114.323
149.015 169.801 116.402
149.383 170.169 118.480
149.745 170.531 120.559
150.100 170.886 122.638
150.449 171.235 124.716
э@) = -1312.
lgK°(T)
230.1595
228.7354
171.3117
136.8028
113.7603
97.2755
84.8923
75.2459
67.5167
61.1829
55.8965
51.4164
47.5704
44.2320
41.3063
38.7209
36.4192
34.3566
32.4974
30.8126
29.2787
25.8761
26.5883
25.4017
- 24.3048
23.2876
22.3416
21.4594
20.6349
19.8624
19.1370
18.4546
17.8114
17.2040
16.6295
16.0853
15.5689
15.0782
14.6114
14.1667
13.7426
13.3375
12.9504
12.5798
12.2249
11.8845
11.5579
11.2441
10.9425
10.6522
10.3727
10.1034
9.8436
9.5929
9.3509
9.1169
8.8907
8.6719
8.4601
Таблица 10
049 кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
хл 7
о X 7
S? ГО *?
§ § ?
«О го VO V
В 8 2 *
О . '~н
т*н lO s~* t-5
II '"н ^ VO
^11 ю f*
о °о ""*
+ * ^ с*
т * о в;
Б
^ о
2 §
о
т о
1 CN
• v
v
t—i «О
VO 00
Г- СЧ
о
+ о
г-
уд -
О "
т-Н И
VO ><
II
с.
Ь
27

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°ЛТ)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°G)
Дж К" -моль"
151.131
151.791
152.431
153.051
153.654
154.239
154.809
155.363
155.903
156.429
156.943
157.443
157.933
158.410
158.878
159.334
159.781
160.219
160.648
161.068
162.082
163.049
163.973
164.857
165.706
166.521
167.306
168.061
168.791
169.496
170.177
170.837
171.477
172.097
172.700
173.285
173.855
174.409
174.949
175.475
5° G)
-1
171.917
172.577
173.216
173.837
174.440
175.025
175.595
176.149
176.689
177.215
177.728
178.229
178.718
179.196
179.664
180.120
180.567
181.005
181.434
181.853
182.868
183.835
184.759
185.643
186.492
187.307
188.092
188.847
189.577
190.281
190.963
191.623
192.263
192.883
193.486
194.071
194.641
195.195
195.735
196.261
ВОДОРОДА Н
к Дж • моль"
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
+ (г)
8.0560
7.6761
7.3182
6.9804
6.6610
6.3584
6.0714
5.7987
5.5393
5.2922
5.0564
4.8312
4.6160
4.4099
4.2124
4.0230
3.8412
3.6664
3.4983
3.3365
2.9572
2.6100
2.2909
1.9964
1.7236
1.4701
1.2339
1.0131
.8062
.6119
.4289
.2562
.0930
-.0615
-.2082
-.3476
-.4802
-.6067
-.7274
-.8523
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 10
(окончание)
-
28

Класс точности
I-A
ОТРИЦАТЕЛЬНЫЙ ИОН ВОДОРОДА Н" (г)
Д,.//о@) = 72.770 кДж • моль
Таблица 11
К°(Т)= р(Н) р(е) р1(Ю
Ф°(Т)
s°m
Дж * К ¦ моль
кДж • моль"
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20,786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20 786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
88.066
88.194
94.174
98.813
102.602
105.806
108.582
111.030
113.220
115.201
117.010
118.674
120.214
121.648
122.990
124.250
125.438
126.562
127.628
128.642
129.609
130.533
131.418
132.266
133.082
133.866
134.622
135.351
136.056
136.738
137.398
138.037
138.658
139.260
139.846
140.415
140.970
141.510
142.036
142.549
143.050
143.539
144.017
144.484
144.941
145.388
145.826
146.254
146.674
147.086
147.489
147.885
148.274
148.655
149.030
149.398
149.759
150.115
150.464
108.852
108.981
114.960
119.599
123.388
126.592
129.368
131.816
134.006
135.987
137.796
139.460
141.000
142.434
143.776
145.036
146.224
147.348
148.414
149.428
150.395
151.319
152.204
153.052
153.868
154.652
155.408
156.137
156.842
157.524
158.184
158.823
159.444
160.046
160.632
161.201
161.756
162.296
162.822
163.335
163.836
164.325
164.803
165.270
165.727
166.174
166.612
167.040
167.460
167.872
168.275
168.671
169.060
169.441
169.816
170.184
170.545
170.900
171.250
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
-12.4459
-12.3605
-8.8786
-6.7358
-5.2709
-4 «085
-3.3747
-2.7189
-2.1822
-1.7332
-1.3507
-1.0202
-.7309
-.4750
-.2465
-.0409
.1453
.3152
.4709
.6144
.7472
.8705
.9856
1.0933
1.1943
1.2895
1.3792
1.4641
1.5446
1.6211
1.6939
1.7633
1.8296
1.8930
1.9538
2.0121
х 2.0680
2.1219
2.1737
2.2237
2.3730
2.4173
2.2626
2.3085
2.4494
2.4904
2.5301
2.5686
2.6061
2.6425
2.6779
2.7124
2.7459
2.7787
2.8106
2.8417
2.8721
2.9017
2.9307
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
V
I v
«-« «о
ое оо
о <^
II
29

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р G)
г
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
0.786
20.786
ОТРИЦАТЕЛЬНЫЙ ИОН
Ф°G)
Дж К • моль"
151.145
151.805
152.445
153.066
153.668
154.254
154.823
155.377
155.917
156.444
156.957
157.458
157.947
158.425
158.892
159.349
159.796
160.233
160.662
161.082
162.096
163.063
163.987
164.872
165.720
166.535
167.320
168.076
168.805
169.510
170.191
170.851
171.491
172.112
172.714
173.300
173.869
174.423
174.963
175.490
S°(T>
-1
171.931
172.591
173.231
173.852
174.454
175.040
175.609
176.163
176.703
177.230
177.743
178.244
Л 78.733
179.211
179.678
180.135
180.582
181.019
181.448
181.868
182.882
183.849
184.773
185.658
186.506
187.321
188.106
188.862
189.591
190.296
190.977
191.637
192.277
192.897
193.500
194.086
194.655
195.209
195.749
196.276
ВОДОРОДА Н
Я°(Г)-Я°@)
кДж' моль
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.919
187.076
191.233
195.391
199.548
203.705
207.862
218.255
228.648
239.041
249.434
259.827
270.220
280.613
291.006
301.399
311.792
322.185
332.578
342.971
353.364
363.757
374.150
384.543
394.936
405.329
415.722
"(г)
\%К°{Т)
2.9868
3.0404
3.0918
3.1412
3.1886
3.2343
3.2783
3.3208
3.3618
3.4015
3.4399
3.4771
3.5131
3.5481
3.5821
3.6152
3.6473
3.6786
3.7091
3.7388
3.8098
3.8768
3.9401
4.0001
4.0571
4.1113
4.1631
4.2127
4.2601
4.3057
4.3495
4.3916
4.4322
4.4714
4.5093
4.5459
4.5813
4.6157
4.6490
4.6910
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13506
14000
14500
15000 .
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 11
(окончание)
30

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
28.155
27.447
28.836
28.849
29.181
29.260
29.327
29.440
29.623
29.880
30.204
30.580
30.991
31.422
31.860
32.296
32.724
33.138
33.535
33.915
34.277
34.622
34.949
35.259
35.555
35.837
36.106
36.363
36.610
36.847
37.076
37.298
37.513
37.723
37.928
38.129
38.326
38.520
38.711
38.899
39.085
39.269
39.450
39.629
39.806
39.980
40.151
40.318
40.482
40.641
40.796
40.945
41.088
41.226
41.357
41.480
41.596
41.703
41.803
41.893
41.974
к'°(Т)= р2(Н)
Ф°(Т)
Дж • К • моль
70.624
90.836
102.169
102.345
110.538
116.927
122.169
126.614
130.476
133.892
136.957
139.740
142.292
144.649
146.843
148.896
150.827
152.651
154.381
156.027
157.597
159.100
160.541
161.926
163.259
164.545
165.787
166.988
168.152
169.281
170.376
171.441
172.477
173.486
174.469
175.428
176.363
177.277
178.170
179.044
179.899
180.736
181.556
182.359
183.147
183.920
184.679
185.424
186.156
186.875
187.582
188.278
188.962
189.635
190.297
190.950
191.592
192.225
192.849
193.464
194.071
ДИВОДОРОД Н2 (г)
s°m
100.616
119.301
130.570
130.747
139.104
145.626
150.966
155.494
159.437
162.940
166.104
169.000
171.678
174.176 ,
176.520
178.734
180.832
182.828
184.733
186.557
188.306 .
189.987
191.605
193.165
194.672
196.129
197.540
198.908
200.235
201.524
202.776
203.996
205.183
206.341
207.470
208.573
209.649
210.702
211.732
212.740
213.727
214.695
215.643
216.573
217.486
218.383
219.264
220.129
220.979
221.816
222.638
223.448
224.244
•-. 225.028
225.800
226.560
227.308
228.046
228.772
229.487
230.192
ArH°@) - 432.068 кДж • моль
Н°(Т)-Н°@)
кДж • моль" К1
igA'V)
V
2.999 -221.9461
5.693 -108.6536
8.468 -71.2309
8.521 -70.7599
11.426 -51.7560
14.349 -40.3209
17.278 -32.6759
20.216 -27.1998
23.169 -23.0815
26.143 -19.8696
29.147 -17.2933
32.186 -15.1801
35.264 -13.4146
38.385 -11.9173
41.549 -10.6309
44.757 -9.5136
48.008 -8.5340
51.301 -7.6679
54.635 -6.8966
58.007 -6.2053
61.417 -5.5820
64.862 -5.0172
68.341 -4.5029
71.851 -4.0327
75.392 -3.6011
78.962 -3.2035
82.559 -2.8360
86.183 -2.4953
89 831 -2 1786
93.504 - .8834
97.201 -1.6076
100.919 -1.3494
104.660 -1.1070
108.422 -.8792
112.204 -.6645
116.007 -.4620
119.830 -.2706
123.672 -.0894
127.534 .0824
131.414 .2454
135.314 .4004
139.231 .5479
143.167 .6885
147.121 .8226
151.093 .9506
155.082
159.089
163.112
167.152
171.208
175.280
179.368
183.469
187.585
191.714
.0730
.1901
.3023
.4098
.5130
.6121
.7072
.7988
.8869
.9717
195.856 2.0535
200.010 2.1323
204.175 2.2084
208.350 2.2818
212.535 2.3528
216.728 2.4213
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 12
i
§
z
oo *7
S о ^
• и EJ
^ o ,~, <N
11 л *Я
"^ "-» *-? "ИЗ
о oo
С ?} "
т1 #> о ое
зГ °°
о w
^ о
'к -
о л
ч© с;
г- о
1
1 -^ /-"»
5 « °
8 | V
i °p v
JS с* О
го ^J "^
о °5
Я Я 2
00 >< Ь-«
т-Ч ON ||
2 " х
go
II +
t
С**»

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
42.107
42.200
42.252
42.263
42.233
42.164
42.055
41.910
41.731
41.520
41.280
41.014
40.724
40.415
40.088
39.745
39.391
39.027
38.655
38.277
37.321
36.367
35.432
34.530
33.669
32.855
32.089
31.373
30.706
30.085
29.510
28.976
28.483
28.025
27.602
27.211
26.848
26.511
26.200
25.910
ДИВОДОРОД
Ф°(Т)
Дж К"" • моль"
195.258
196.414
197.540
198.637
199.707
200.751
201.770
202.765
203.738
204.689
205.619
206.528
207.418
208.289
209.142
209.977
210.795
211.596
212.381
213.151
215.009
216.779
218.468
220.079
221.620
223.093
224.505
225.858
227.156
228.403
229.602
230.756
231.868
232.939
233.973
234.971
235.936
236.869
237.772
238.647
-1
231.571
232.909
234.208
235.470
236.695
237.884
239.038
240.157
241.244
242.298
243.320
244.312
245.273
246.206
247.111
247.988
248.839
249.664
250.465
251.242
253.087
254.801
256.397
257.886
259.277
260.582
261.808
262.961
264.050
265.081
266.058
266.986
267.870
268.714
269.520
270.292
271.032
271.744
272.428
273.088
Н2 (г)
я°(Л-я>)
кДж • моль"
225.137
233.569
242.015
250.467
258.917
267.357
275.780
284.177
292.542
300.867
309.148
317.377
325.552
333.666
341.716
349-.700
357.614
365.456
373.224
380.917
399.818
418.239
436.188
453.676
470.724
487.353
503.587
519.451
534.969
550.164
565.061
579.681
594.044
608.170
622.076
635.777
•649.291
662.630.
67&.807
688.833
2.551В
2.6742
2.7890
2.8971
2.9990
3.0952
3.1862
3.2724
3.3541
3.4317
3.5056
3.5759
3.6430
3.7071
3.7684
3.8270
3.8832
3.9370
3.9888
4.0385
4.1549
4.2611
4.3587
4.4487
4.5321
4.6097
4.6822
4.7502
4.8142
4.8746
4.9317
4.9858
5.0373
5.0864
5.1333
5.1782
5.2212
5.2624
5.3021
5.3404
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 12
(окончание)
т .
2 Й
v2 I
О
i
U * 2
о р; <N
? 2 v
8 + *^
\/
jS m ^
JO g §
3 d 2
2 ? " •
2 ^ ^
C7N ***> II
т"н **"* X
II + ^
g I
О
32

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.289
29.292
29.525
30.016
30.719
31.529
32.358
33.153
33.889
34.561
35.171
35.725
36.231
36.697
37.130
37.539
37.927
38.301
38.664
39.021
39.374
39.724
40.072
40.417
40.759
41.095
41.423
41.739
42.040
42.323
42.583
42.819
43.026
43.202
43.345
43.454
43.527
43.564
43.565
43.530
43.461
43.357
43.222
43.057
42.863
42.644
42.400
42.135
41.851
41.549
41.233
40.904
40.563
40.215
39.859
39.497
39.132
38.764
38.395
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИВОДОРОДА Н2+
К°(Т)= р2(Н)
Ф°(Л
Дж • К • моль
113.471
113.649
121.952
128.427
133.751
138.288
142.255
145.792
148.989
151.914
154.614
157.124
159.471
161.678
163.763
165.738
167.617
169.409
171.123
172.766
174.343
175.862
177.326
178.739
180.106
181.430
182.713
183^960
185.171
186.349
187.496
188.614
189.704
190.768
191.808
192.823
193.816
194.788
195.739
196.670
197.582
198.476
199.352
200.211
201.053
201.880
202.690
203.486
204.267
205.034
205.787
206.527
207.253
207.967
208.668
209.358
210.035
210.701
211.356
-1
Н°(Т)-Н°@)
кДж • моль
142.259 8.583
142.440 8.638
150.894 11.576
157.530 14.551
163.062 17.587
167.857 20.699
172.122 23.893
175.979 27.169
179.511 30.522
182.773 33.945
185.807 37.432
188.644 40.977
191.311 44.575
193.826 48.222
196.209 51.913
198.472 55.647
200.629 59.420
202.689 63.232
204.663 67.080
206.558 70.965
208.382 74.884
210.140 78.839
211.838 82.829
213.480 86.854
215.072 90.912
216.617 95.005
218.117 99.131
219.577 103.289
220.997 107.478
222.380 111.697
223.728 115.942
225.042 120.212
226.323 124.505
227.573 128.817
228.792 133.144
229.981 137.484
231.141 141.834
232.272 146.189
233.375 150.545
234.451 154.900
235.499 159.250
236.520 163.591
237.516 167.921
238.485 172.235
239.430 176.531
240.349 180.807
241.244 185.059
242.116 189.286
242.964 193.485
243.790 197.656
244.594 201.795
245.376 205.902
246.138 209.975
246.679 214.014
247.600 218.018
248.303 221.986
248.986 225.917
249.652 229.812
250.300 233.670
Э@) - -1056.
\ВК°(Т)
188.9254
187.7818
141.6818
113.9987
95.5271
82.3208
72.4060
64.6861
58.5029
53.4378
49.2114
45.6304
42.5567
39.8889
37.5512
35.4854
33.6462
31.9980
30.5122
29.1657
27.9396
26.8181
25.7883
24.8392
23.9616
23.1475
22.3901
2L6836
21.0230
20.4038
19.8221
19.2747
18.7584
18.2706
17.8090
17.3715
16.9561
16.5613
16.1854
15.8272
15.4853
15.1587
14.8462
14.5471
14.2604
13.9854
13.7214
13.4676
13.2235
12.9886
12.7623
12.5442
12.3337
12.1306
11.9344
11.7447
11.5614
11.3839
11.2121
(г)
Таблица 13
292 кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ё * Т
(Ч О ^"' Ь^
ю чо $?
*—< СО ^" у.
я оо 7 n
II •"¦< & «О
О об -*
с-Г ^ "
а: о
^ 1
О л
2 5
со о
о 2
со ^ ?
S k |
S Г* ^
9 * V
О <N '
Н cs V
Ja ""* о
я „' °
чо "Н *"
о S • '
со со 2
OS t С
I 3
оо ^
II *"*
о
3 872
33

т
к
6200
6400
6600
6800 '
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Г)
37.658
36.928
36.213
35.516
34.842
34.192
33.569
32.973
32.404
31.864
31.350
30.863
30.401
29.964
29.550
29.159
28.789
28.439
28.109
27.796
27.087
26.470
25.931
25.459
25.045
24.679
24.356
24.070
23.814
23.586
23.382
23.199
23.033
22.883
22.748
22.624
22.512
22.409
22.315
22.229
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°G)
Дж К~ • моль"
212.632
213.867
215.062
216.219
217.339
218.425
219.478
220.500
221.491
222.454
223.389
224.298
225.181
226.040
226.877
227.691
228.484
229.257
230.011
230.745
232.506
234.164
235.731
237.214
238.621
239.959
241.232
242.447
244 fiO8
244.719
245.783
246.804
247.786
248.730
249.640
250.517
251.363
252.182
252.973
253.739
-l
251.547
252.732
253.857
254.928
255.947
256.919
257.848
258.735
259.584
260.398
261.178
261.928
262.648
263.342
264.011
264.656
265.279
265.881
266.464
267.029
268.368
269.613
270.778
271.871
272.902
273.877
274.802
275.683
276.523
277.326
278.096
278.836
279.547
280.232
280.894
281.533
282.151
282.750
283.331
283.895
ДИВОДОРОДА
Я°(Л-Я°@)
кДж * моль
241.275
248.733
256.047
263.220
270.255
277.158
283.934
290.588
297.125
303.551
309.872
316.093
322.219
328.255
334.206
340.076
345.871
351.593
357.248
362.838
376.555
389.941
403.038
415.883
428.507
440.936
453.193
465.298
477.268
489.117
500.859
512.503
524.060
535.539
546.946
558.288
569.572
580.802
591.983
603.118
Н2+ (г)
10.8844
10.5763
10.2860
10.0121
9.7532
9.5081
9.2758
9.0552
8.8454
8.6458
8.4556
8.2741
8.1007
7.9350
7.7763
7.6244
7.4787
7.3389
7.2047
7.0756
6.7739
6.4989
6.2473
6.0161
5.8030
5.6060
5.4232
5.2533
с OQAQ
4.9468
4.8082
4.6781
4.5557
4.4404
4.3317
4.2289
4.1316
4.0393
3.9517
3.8588
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
«600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 4ЛЛП
1 *гОии
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 13
(окончание)
+
о Т
5> й
1 §
+ f
2 * *
о • о
о * о
<* А о
00 ^ О
От <Ч
о х ч .
a v
| + V
§ ™н о
s § §
<ч гч ^
+ °i -r"
S и °
S -2 -
? ? ^
сч • N
04 <* ><
II + w
g
34

Класс точности
IV-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
ПОЛОЖИТЕЛЬНЫЙ
к°(Т)= р3(Н) -р'Чнр р
Ф°(Т)
S°(T)
Дж • К~1 • моль"!
33.262
33.262
33.336
33.650
34.344
35.416
36.768
38.272
39.820
41.335
42.771
44.102
45.320
46.423
47.417
48.311
49.113
49.833
50.479
51.060
51.583
52.054
52.480
52.866
53.216
53.535
53.825
54^090
54.333
54.555
54.760
54.948
55.122
55.282
55.431
55.569
55.697
55.816
55.927
56.030
56.127
56.218
56.302
56.382
56.457
56.527
56.593
56.656
56.715
56.770
56.823
56,873
56.920
56.965
57.007
57.047
57.086
57.122
57.157
114.009 147.267
114.215 147.473
123.783 157.048
131.209 164.515
137.290 170.705
142.455 176.075
146.963 180.890
150.982 185.307
154.622 189.419
157.963 193.286
161.060 196.945
163.955 200.422
166.679 203.735
169.256 206.900
171.704 209.929
174.039 212.831
176.272 215.615
178.413 218.290
180.472 220.863
182.454 223.340
184.368 225.728
186.216 228.031
188.005 230.256
189.738 232.406
191.420 234.487
193.052- 236.501
1<7*г.ООа Л/OO.tOO
196.183 240.347
197.686 242.185
199.150 243.970
200.578 245.705
201.971 247.393
203.331 249.036
204.660 250.636
205.959 252.196
207.229 253.71b
208.472 255.200
209.689 256.648
210.881 258.063
212.048 259.445
213.193 260.796
214.316 262.118
215.417 263.412
216.497 264.678
217.558 265.918
218.600 267.133
219.624 268.324
220.630 269.491
221.618 270.636
222.591 271.760
223.547 272.863
224.487 273.946
225.413 275.009
226.324 276.054
227.222 277.081
228.105 278.090
228.976 279.083
229.833 280.059
230.678 281.019
1 ИОН ТРИВОДОРОДА Н+
(е) АгН
//°(Г)-//°@)
кДж • моль"
9.916
9.977
13.306
16.653
20.049
23.534 '
27.142
30.893
34.797
38.856
43.062
47.406
51.878
56.467
61.159
65.947
70.819,
75.767
80.783
85.860
90.993
96.175
101.402
106.670
111.974
117.312
1 99 fiftO
128.076
133.497
138.942
144.408
149.893
155.397
160.917
166.453
172.003
177.566
183.142
188.729
194.327
199.935
205.552
211.178
216.812
222.454
228.104
233.760
239.422
245.091
250.765
256.444
262.129
267.819
273.513
279.212
284.914
290.621
296.332
302.046
(г)
Таблица 14
°@) = -455.898 кДж-моль 1
\%К°{Т)
88.6129
88.1230
68.4035
56.5935
48.7340
43.1291
38.9312
35.6696
33.0623
30.9299
29.1530
27.6491
26.3593
25.2406
24.2606
23.3949
22.6241
21.9334
21.3105
20.7459
20.2316
19.7609
19.3285
18.9297
18.5607
18.2182
1 7 ftQ<№
1 / .ОЭЭО
17.6016
17.3230
17.0616
16.8159
16.5845
16.3660
16.1594
15.9638
15.7781
15.6017
15.4339
15.2740
15.1214
14.9757
14.8363
14.7028
14.5749
14.4522
14.3343
14.2210
14.1120
14.0070
13.9058
13.8083
13.7141
13.6231
13.5352
13.4501
13.3678
13.2881
13.2108
13.1359
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
Oftflfl
ZO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700 .
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
1
й * «
1 5 й
* S? О
i * 3
а ? •-•
1Г> о о 2э4
»-н о 1-*
СО X —1
,02
L.(
«"* *-н Q со
ъ*. и *° ^
^ Д -! о
о g ^
Е-Г й
+ со •> о 05
В + *о со
о, ^
+
й i
Й |
о Т
1 у,
а * ?
§ пх 1
8 | °
§ 2 v
* « V
- ё §
si °
г- °°.
ON »О -."
О °^ 1
<N | О
+ X *^
Й о ?
|| 4-
С
О
35

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
. 9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
57.221
57.280
57.334
57.383
57.428
57.470
57.508
57.544
57.576
57.607
57.635
57.661
57.686
57.709
57.730
57.750
57.769
57.786
57.803
57.819
57.854
57.884
57.911
57.935
57.955
57.974
57.990
58.005
58.018
58.030
58.041
58.051
58.060
58.068
58.075
58.082
58.088
58.094
58.100
58.105
ПОЛОЖИТЕЛЬНЫЙ ИОН ТРИВОДОРОДА Н3+
Ф°(Г)
Дж < К"** • моль"
232.333
233.941
235.507
237.031
238.517
239.965
241.379
242.759
244.106
245.424
246.712
247.973
249.207
250.415
251.599
252.759
253.896
255.012
256.106
257.181
259.783
262.275
264.664
266.959
269.166
271.294
273.346
275.328
277.246
279.102
280.900
282.645
284.339
285.985
287.586
289.144
290.662
292.140
293.583
294.990
¦1
H°(T)-H°@)
кДж • моль"
282.894 313.484
284.712 324.934
286.476 336.395
288.188 347.867
289.852 359.348
291.470 370.838
293.046 382.336
294.580 393.841
296.075 405.353
297.533 416.872
298.956 428.396
300.345 439.926
301.702 451.461
303.028 463.000
304.326 474.544
305.595 486.092
306.837 497.644
308.053 509.199
309.245 520.758
310.413 532.320
313.235 561.239
315.927 590.173
318.500 619.123
320.965 648.084
323.331 677.057
325.604 706.039
327.793 735.030
329.902 764.029
331 938 793 035
333.905 822.047
335.808 851.065
337.651 880.088
339.437 909.115
341.171 938.147
342.854 967.183
344.490 996.223
346.081 1025.265
347.631 1054.311
349.140 1083.359
350.611 1112.411
12.9926
12.8575
12.7298
12.6089
12.4942
12.3852
12.2815
12.1826
12.0883
11.9981
11.9119
11.8292
11.7499
11.6738
1 Г.6006
11.5302
11.4625
11.3971
11.3341
11.2732
11.1298
10.9976
10.8753
10.7615
10.6555
10.5562
10.4632
10.3756
10.2930
10.2149
10.1409
10.0707
10.0040
9.9404
9.8797
9.8217
9.7661
9.7129
9.6619
9.6031
(г)
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 14
(окончание)
+
СМ
оо «-
? т
•л ..о
? ё
с* _
'ч Т ,-ч
8 * *
8 i I
? * §
О го СМ
=> & \/
VO
ГО ?
1 ь Г/
5 + v
§ "к §
3 S §
« 2 Г.
+ 7 т
S 2
г « 2
5 = ^
СМ 00 w
„ ¦ о
II "Т
g
36

Класс точности
I-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
C°iT)
г
31.628
30.515
29.886
29.879
29.604
29.495
29.513
29.655
29.914
30.265
30.682
31.135
31.603
32.069
32.522
32.956
33.367
33.753
34.114
34.451
34.766
35.059
35.334
35.591
35.833
36.060
36.275
36.479
36.673
36.858
37.036
37.206
37.371
37.530
37.685
37.835
37.982
38.125
38.265
38.402
38.535
38.666
38.793
38.917
39.038
39.155
39.269
39.378
39.482
39.582
39.677
39.766
39.850
39.927
39.999
40.063
40.121
40.172
40.216
40.252
40.280
К°(Т) = р(О) •
Ф°(Л
Дж • К • моль
122.539
142.312
154.068
154.251
162.764
169.368
174.761
179.320
183.270
186.759
189.887
192.726
195.328
197.732
199.969
202.063
204.032
205.893
207.657
209.335
210.936
212.468
213.936
215.346
216.704
218.012
219.275
220.497
221.679
222^25
223.937
225.017
226.067
227.089
228.084
229.054
230.000
230.924
231.826
232.707
233.569
234.413
235.239
236.048
236.840.
237.618
238.380
239.128
239.862
240.584
241.292
241.988
242.673
243.346
244.008
244.659
245.301
245.932
246.554
247.166
247.769
ГИДРОКСИЛ ОН (г)
р(Н>.р-«Ж)
S°(T)
149.978
171.579
183.628
183.813
192.365
198.957
204.334
208.893
212.868
216.411
219.621
222.566
225.296
227.844
230.237
232.496
234.636
236.670
238.610
240.464
242.239
243.942
245.580
247.156
248.676
250.143
251.562
252.935
254.265
255.555
256.808
258.025
259.209
60.361
261.484
262.578
263.646
264.689
265.707
266.703
267.677
268.630
269.563
270.478
271.374
272.252
273.114
273.960
274.790
275.605
276.406
277.192
277.965
278.725
279.472
280.207
280.929
281.640
282.339
283.027
283.704
Таблица 15
ArH°@) = 423.720 кДж • моль
Н°(Т)-Но@)
кДж * моль
\%К°{Т)
2.744 -218.0693
5.853 -106.8729
8.813 -70.1512
8.868 -69.6890
11.841 -51.0402
14.795 -39.8174
17.744 -32.3136
20.701 -26.9382
23.679 -22.8953
26.687 -19.7422
29.734 -17.2130
32.825 -15.1385
35.961 -13.4055
39.145 -11.9358
42.375 -10.6732
45.649 -9.5768
48.965 -8.6155
52.322 -7.7657
55.715 -7.0090
59.144 -6.3308
62.605 -5.7194
66.096 -5.1654
69.616 -4.6610
73.162 -4.1999
76.734 -3.7765
80.328 -3.3866
83.945 -3.0262
87.583 -2.6921
q 1 941 -2 ЧЯ1 *»
94.917 -2.0920
98.612 -1.8215
102.324 -1.5682
106.053 -1.3305
109.798 -1.1069
113.559 -.8964
117.335 -.6976
121.126 -.5098
124.931 -.3319
128.751 -.1633
132.584 -.0032
136.431 .1490
140.291 .2940
144.164 .4321
148.050 .5639
151.948 .6898
155.857 .8102
159.778 .9254
163.711 1.0358
167.654 1.1417
171.607 1.2433
175.570 1.3409
179.542 1.4348
183.523 1.5251
187.512 1.6120
191.508 1.6958
195.512 1.7765
199.521 1.8545
203.536 1.9298
207.555 2.0025
211.578 2.0727
215.605 2.1407
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
А
А
S * л
1 ! •
со ^t го '
° . ? S *
" 7 * д|
^ *-* "? «о
О 00
О д со
О w
+
т ~
х i
со ^
VO О
со **
о ^*
с* ¦*«
I й |
+ 2 *-
? 7 V
с *
""* п О
00 X °
го «? Т-,
^ <Ч О
, 1 *""*
т 1 »
i I ^
?j о н
чЗ- со w
II 4-
с
о
37

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
* 8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
40.315
40.319
40.292
40.234
40.148
40.033
39.892
39.727
39.538
39.329
39.101
38.857
38.598
38.326
38.044
37.752
37.454
37.150
36.842
36.531
35.749
34.973
34.215
33.483
32.782
32.116
31.487
30.894
30.338
29.817
29.330
28.874
28.449
28.053
27.683
27.337
27.014
26.713
26.431
26.167
ГИДРОКСИЛ ОН (г)
Ф°G)
Дж К • моль
248.950
250.097
251.214
252.300
253.358
254.389
255.395
256.375
257.333
258.268
259.181
260.074
260.946
261.800
262.634
263.451
264.250
265.033
265.800
266.551
268.363
270.088
271.733
273.302
274.801
276.236
277.610
278.928
280.192
281.408
282.577
283.703
284.787
285.833
286.843
287.820
288.763
289.676
290.561
291.418
S°(T)
-1
Я°(Г)-Я°@)
кДж * моль
285.025 223.665
286.305 231.729
287.545 239.791
288.748 247.844
289.912 255.882
291.042 263.901
292.137 271.894
293.199 279:856
294.228 287.783
295.227 295.670
296.195 303.513
297.134 311.309
298.046 319.055
298.930 326.748
299.788 334.385
300.621 341.964
301.430 349.485
302.215 356.946
302.978 364.345
303.719 371.682
305.483 389.752
307.128 407.432
308.665 424.728
310.106 441.652
311.459 458.217
312.731 474.440
313.931 490.339
315.066 505.933
316 140 S21 94Q
317.160 536.276
318.129 551.062
319.053 565.612
319.935 579.941
320.779 594.066
321.586 607.998
322.361 . 621.752
323.106 635.339
323.822 648.770
324.512 662.055
325.178 675.204
2.2702
2.3917
2.5061
2.6138
2.7155
2.8117
2.9029
2.9893
3.0715
3.1497
3.2243
3.2954
3.3633
3.4283
3.4906
3.5503
3.6076
3.6627
3.7157
3.7667
3.8864
3.9961
4.0972
4.1908
4.2778
4.3590
4.4351
4.5066
л К7АС1
4.6377
4.6981
4.7554
4.8100
4.8621
4.9119
4.9596
5.0054
5.0493
5.0916
5.1323
Т
К
' 6200
6400
6600
6800
7000
7200
. 7400
7600
7800
8000
8200
8400
8600
•8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 4.^00
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 15
(окончание)
+
8 §
о 1
1
"н ?v -
8 х §
^ п о
О
§ | V
X 1-4
В J V
ч© °- *"*
+ 1 ^
око
г-н Г- 1—i
00 Ч©
• ?¦»» С*"<
II + W
g
о
38

Класс точности
1-Е
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.196
29.196
29.218
29.329
29.580
29.972
30.470
31.030
31.61
32.187
32.739
33.259
33.742
34.189
34.600
34.979
35.329
35.653
35.954
36.235
36.499
36.749
36.987
37.215
37.436
37.650
37.861
38.068
38.273
38.479
38.685
38.892
39.103
39.317
39.535
39.758
39.986
40.220
40.460
40.706
40.958
41.217
41.482
41.752
42.028
42.308
42.593
42.881
43.171
43.463
43.756
44.048
44.339
44.628
44.912
45.192
45.466
45.733
45.992
ПОЛОЖИТЕЛЬНЫЙ ИОН ГИДРОКСИЛА ОН* (г)
К°(Т)= р(О) •
Ф°(Т)
Дж • К • моль
153.780
153.959
162.273
168.738
174.033
178.522
182.426
185.887
189.001
191.837
194.444
196.860
199.114
201.228
203.220
205.105
206.895
208.600
210.229
211.788
213.283
214.721
216.105
217.441
218.731
219.978
221.187
222.359
223.496
224.601
225.676
226.722
227.742
228.736
229.706
230.653
231.579
232.484
233.370
234.237
235.087
235.920
236.736
237.538
238.324
239.097
239.856
240.602
241.336
242.058
242.769
243.469
244.158
244.837
245.507
246.167
246.818
247.460
248.093
р(Н).р-'<ОН<
S°(T)
-1
182.634
182.814
191.215
197.744
203.112
207.699
211.733
215.354
218.653
221.693
224.518
227.159
229.642
231.985
234.205
236.314
238.323
240.242
242.079
243.840
245.532
247.160
248.729
250.243
251.707
253.124
254.497
255.829
257.123
258.382
259.607
260.800
261.964
263.101
264.212
265.298
266.361
267.403
268.424
269.426
270.410
271.377
272.327
273.263
274.183
275.090
275.984
276.865
277.734
278.592
279.439
280.275
281.101
281.917
282.724
283.521
284.310
285.089
285.860
Wo v
н°(Т)-н°(о)
кДж • моль"*
8.603
8.657
11.577
14.503
17.447
20.424
23.445
26.520
29.652
32.842
36.088
39.389
42.739
46.136
49.576
53.055
56.571
60.120
63.700
67.310
70.947
74.609
78.296
82.006
85.739
89.493
Qo OfiQ
97.065
100.883
104.720
108.578
112.457
116.357
120.278
124.220
128.185
132.172
136.182
140.216
^ 144.274
148.358
152.466
156.601
160.763
164.952
169.168
173.414
177.687
181.990
186.321
190.682
195.073
199.492
203.940
208.417
212.923
217.456
222.016
226.602
Таблица 16
°@) = -820.280 кДж . моль г
147.8003
146.9121
111.1097
89.6079
75.2593
64.9997
57.2966
51.2985
46.4941
42.5582
39.2737 .
36.4906
34.1016
32.0278
30.2104
28.6041
27.1740
25.8921
24.7364
23.6888
22.7348
21.8621
21.0606
20.3219
19.6386
19.0047
18 4150
17.8648
17.3503
16.8680
16.4149
15.9884
15.5861
15.2061
14.8464
14.5054
14.1817
13.8739
13.5809
13.3016
13.0349
12.7801
12.5364
12.3029
12.0791
11.8644
11.6581
11.4597
11.2688
11.0850
10.9078
10.7369
10.5720
10.4126
10.2585
10.1095
9.9652
9.8255
9.6901
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
^оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i **
о &
s 1=1 7
k ^ к
9 " я §
Д СО «?
Ю О\ 00 in
С*"» О <*^ '
^> ~ ^ Ъ?
о 52 и
О 00 И
|| II 1О ,—<
^ О 00 °)
On io
+ ~ ^
*Е + " о S
о S
о
Т
'* к 2
S ^ о
, го О
о * vo
§f v
t 7 V
Р + v
оо ? ^
г-- *-? <э-
Я Я 2
+ i
оо К {**¦
00 ЧО '
со ^-< II
<N v^
СО ^ ^'
"Э- СО ^
CNJ ^f
II +
39

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
46.481
46.926
47.321
47.660
47.939
48.156
48.309
48.398
48.424
48.388
48.294
48.144
47.943
47.694
47.403
47.072
46.708
46.313
45.893
45.452
44.279
43.046
41.795
40.558
39.355
38.203
37.111
36.083
35.120
34.223
33.390
32.618
31.902
31.240
30.628
30.062
29.-538
29.054
28.605
28.188
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°(Г)
Дж К"" • моль"
249.336
250.548
251.731
252.887
254.016
255.121
256.202
257.261
258.298
259.315
260.311
261.288
262.246
263.186
264.108
265.013
265.901
266.773
267.629
268.470
270.506
272.452
274.315
276.098
277.806
279.443
281.014
282.521
283.969
285.361
286.699
287.988
289.230
290.427
291.582
292.697
293.774
294.816
2У5.823
296.799
-1
287.376
288.859
290.309
291.727
293.113
294.466
295.788
297.078
298.335
299.561
300.755
301.917
303.048
304.147
305.216
306.254
307.262
308.242
309.192
310.115
312.305
314.336
316.222
317.975
319.606
321.127
322.548
323.879
325.128
326.303
327.412
328.459
329.452
330.394
331.291
332.146
332.962
333.744
334.492
335.211
ГИДРОКСИЛА
Н°(Т)-Н°@)
кДж • моль""
235.850
245.191
254.617
264.116
273.677
283.288
292.935
302.607
312.290
321.972
331.64!
341.286
350.896
360.460
369.970
379.419
388.797
398.100
407.321
416.456
438:892
460.724
481.935
502.522
522.498
541.886
560.712
579.007
596.805
614.138
631.039
647.539
663.666
679.450
694.915
710.086
724.984
739.631
754.044
768.241
ОН+ (г)
9.4314
9.1876
8.9573
8.7395
8.5330
8.3369
8.1504
7.9728
7.8034
7.6416
7.4868
7.3387
7.1968
7.0606
6.9298
6.8041
6.6831
6.5667
6.4544
6.3462
6.0918
5.8582
5.6428
5.4436
5.2588
5.0869
4.9266
4.7768
4.6365
4.5048
4.3809
4.2643
4.1542
4.0502
3.9518
3.8585
3.7699
3.685а
3.6057
3.5198
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
5600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
со
»—i
г-
ё
СО
со
+
g
с
со
о
со
о
со
со
<ч
II
g
Таблица 16
(окончание)
Т
А
§
1
к ^
Ъ i
со V
+
i s
00 §
гН i-Ч
1 т
х о
00 Т*
КГ) г
О Ьч
т-Н II
+ w
40

Класс точности
IV-B
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
aouu
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г
29.141
29.141
29.156
29.194
29.290
29.473
29.752
30.114
30.535
30.990
31.460
31.928
32.383
32.820
33.233
33.623
33.987
34.328
34.645
34.942
35.220
35.480
35.724
35.954
36.171
36.377
ос 47°.
O\)JD 1 О
36.761
36.942
37.117
37.287
37.453
37.617
37.779
37.941
38.103
38.265
38.429
38.596
38.766
38.939
39.116
39.297
39.482
39.673
39.868
40.068
40.272
40.481
40.695
40.912
41.134
41.359
41.587
41.818
42.051
42.286
42.523
42.760
ОТРИЦАТЕЛЬНЫЙ
К°(Т) = р(О) ч
Ф°(Т)
Дж • К - моль"
143.455
143.634
151.949
158.411
163.699
168.177
172.064
175.501
178.586
181.388
183.958
186.335
188.547
190.619
192.569
194.412
196.159
197.823
199.410
200.928
202.385
203.784
205.131
206.430
207.684
208.896
91 Л П71
ZlxJ.XJ/ 1
211.209
212.314
213.387
214.430
215.446
216.435
217.400
218.340
219.259
220.156
221.033
221.890
222.730
223.552
224.357
225.147
225.921
226.680
227.426
228.158
228.877
229.584
230.280
230.963
231.636
232.298
232.950
233.593
234.226
234.849
235.464
236.071
7(Н) -р(е) -р~]
S°iT)
172.320
172.500
180.885
187.395
192.725
197.252
201.205
204.729
207.924
210.855
213.572
216.108
218.491
220.740
222.872
224.899
226.831
228.678
230.447
232.144
233.776
235.348
236.863
238.326
239.740
241.109
949 44fi
243.722
244.972
246.186
247.367
248.517
249.637
250.730
251.797
252.839
253.857
254.853
255.828
256.783
257.719
258.637
259.539
260.424
261.294
252.149
262.991
263.819
264.634
265.438
. 266.231
267.012
267.783
268.544
269.295
270.037
270.771
271.496
272.213
ИОН ГИДРОКСИЛА ОН~
(ОН) SrH
H°(T)-H°i0)
кДж • моль
8.606
8.660
11.575
14.492
17.415
20.353
23.313
26.306
29.338
32.414
35.536
38.706
41.922
45.182
48.485
51.828
55.209
58.624
62.073
65.553
69.061
72.596
76.157
79.740
83.347
86.974
QO A99
94.289
97.974
101 677
105*397
109.134
112.888
116.658
120.444
124.246
128.064
131.899
135.750
139.618
143.503
147.406
151.327
155.266
159.223
163.200
167.197
171.214
175.252
179.310
183.391
187.493
191.617
195.765
199.935
204.128
208.345
212.586
216.850
(г)
1 а б л и u a 17
°@) = 599.850 кДж • моль
lgK°(T)
-100.4495
-99.7900
-73.1519
-57.0795
-46.3055
-38.5681
-32.7340
-28.1726
-24.5045
-21.4882
-18.9622
-16.8143
-14.9646
-13.3539
-11.9382
-10.6834
-9.5631
-8.5564
-7.6466
-6.8199
-6.0652
-5.3734
-4.7367
-4.1486
-3.6036
-3.0970
.9 fi94ft
-2.1835
-1.7701
-1.3819
-1.0166
-.6722
-.3469
-.0391
.2526
.5296
.7928
1.0435
1.2824
1.5104
1.7284
1.9368
2.1365
2.3279
2.5116
2.6880
2.8577
3.0209
3.1781
3.3295
3.4756
3.6167
3.7529
3.8845
4.0118
4.1350
4.2543
4.3699
4.4820
/'
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙПЛ
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
л
7 о
jQ S
с
i S "
A OV О
3 2 s
ю со со ~*
оо со ^i
f- О ~н «V
© г-' 1
52 ' «
- 1 2 ч
11 " * s
*S ¦""^ «-и On
° 00 UO
1 * и
S . - о 5
*? x ^
о о
* о
< X
<J
+
§ В
оо 2
«о 2
О *N
8 2 V
© IO К
? + v
% - §
^ eg S
СО *; V
rs ^ 'л
<N ** 2
+ 1 a
SO X S-
vo со И
S ч *
II +
41

ОТРИЦАТЕЛЬНЫЙ ИОН ГИДРОКСИЛА ОН" (г)
Таблица 17
(окончание)
с; (
Ф°(Г)
Дж'К -моль
Н°{Т)-Н°@)
кДж' моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
43.236
43.709
44.176
44.632
45.075
45.501
45.907
46.291
46.650
46.983
47.287
47.562
47.806
48.020
48.202
48.352
48.470
48.558
48.614
48.641
237.260
238.418
239.547
240.649
241.726
242.778
243.808
244.816
245.804
246.773
247.723
248.655
249.570
250.468
251.351
252.219
253.072
253.912
254.737
255.550
273.622
275.003
276.355
277.680
278.980
280.256
281.508
282.738
283.945
285.131
286.294
287.437
288.559
289.661
290.742
291.803
292.844
293.866
294.868
295.850
225.449
234.144
242.933
251.814
260.785
269.842
278.984
288.204
297.498
306.862
316.290
325.775
335.312
344.896
354.518
364.174
373.857
383.560
393.278
403.004
К
4.6961
4.8979
5.0886
5.2689
5.4398
5.6019
5.7561
5.9028
6.0426
6.1761
6.3035
6.4255
6.5422
6.6542
6.7615
6.8647
6.9638
7.0592
7.1510
7.2395
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
s.
о
о
о
об
8
00
II
о
I
о
о
о
о
V
V
42

Класс точности
IV-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.258
33.491
34.905
34.944
37.296
39.687
41.781
43.558
45.084
46.419
47.604
48.672
49.644
50.535
51.360
52.128
52.845
53.518
54.149
54.742
55.299
55.820
56.308
56.763
57.186
57.578
57.940
58.274
СО СОЛ
DO.OOyj
58.860
59.115
59.347
59.557
59.745
59.915
60.066
60.200
60.319
60.423
60.513
60.592
60.659
60.716
60.764
60.803
60.834
60.858
60.876
60.888
60.895
60.897
60.894
60.888
60.879
60.866
60.851
60.834
60.814
60.792
60.769
60.745
К°(Т)=р(Я) •/
Ф°(П
Дж • К~ • моль"
159.061
182.117
195.445
195.653
205.386
213.106
219.580
225.203
230.199
234.712
238.839
242.649
246.192
249.510
252.631
255.580
258.379
261.042
263.584
266.017
268.352
270.595
272.755
274.839
276.852
278.800
280.685
282.514
OQA ООП
Z.O't.ZxJV)
286.015
287.692
289.326
290.916
292.467
293.980
295.457
296.899
298.309
299.687
301.036
302.356
303.648
304.914
306.155
307.371
308.564
309.735
310.884
312.012
313.120
314.209
315.279
316.330
317.364
318.381
319.381
320.366
321.335
322.289
323.228
324.153
ДИОКСИД
?2(О) р~1{ПО
S°(T)
-1
192.319
215.404
228.995
229.211
239.577
248.160
255.586
262.164
268.082
273.471
278.424
283.012
287.290
291.299
295.075
298.644
302.032
305.256
308.333
311.277
314.099
316.810
319.418
321.931
324.356
326.698
328.964
331.157
qqo Oft9
335.342
337.342
339.284
341.172
343.008
344.794
346.533
348.227
349.878
351.488
353.059
354.592
356.088
357.551
358.980
360.378
361.744
363.082
364.391
365.672
366.928
368.158
369.364
370.547
• 371.706
372.844
373.961
375.057
376.134
377.191
378.230
379.252
ВОДОРОДА НО2 (г)
2) АгН°@) = 704.600 кДж • моль
Я°(Г)-//°@)
кДж • моль
lgtfV)
3.326 -360.7491
6.657 -175.5530
* 10.003 -114.2922
10.068 -113.5205
13.676 -82.3719
17.527 -63.6125
21.603 -51.0646
25.873 -42.0751
30.307 -35.3149
34.883 -30.0441
39.586 -25.8179
44.400 -22.3530
49.317 -19.4601
54.326 -17.0079
59.422 -14.9025
64.596 -13.0751
69.845 -11.4739
75.164 -10.0592
80.548 -8.8002
85.992 -7.6724
91.495 -6.6563
97.051 -5.7361
102.658 -4.8988
108.312 -4.1337
114.009 -3.4319
119.748 -2.7857
125.524 -2.1888
131.335 -1.6358
1 17 1 7fl 1 1 ООП
lo/.i/o -l.i zzu
143.050 -.6433
148.949 -.1964
154.872 .2219
160.817 .6143
166.783 .9830
172.766 1.3302
178.765 1.6576
184.778 1.9670
190.804 2.2598
196.842 2.5373
202.888 2.8007
208.944 3.0509
215.007 3.2891
221.075 3.5160
227.149 3.7324
233.228 3.9391
239.310 4.1367
245.395 4.3257
251.481 4.5068
257.569 4.6804
263.659 4.8470
269.748 5.0070
275.838 5.1608
281.927 5.3088
288.015 5.4512
294.103 5.5885
300.188 5.7208
306.273 5.8484
312.355 5.9717
318.436 6.0907
324.514 6.2058
330.589 6.3172
Г*
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 18
-1
i
А
- i '
I А I
г- Й 2S» '
1 ! з *
п -* я 2
11 II Ю ОО
^ ^ *-*. я
О ОО ЧО
С* U
2 * о 5
В о ъ
о В
* о
+
1 '"Ч
Н 1
ЧО Л
оо а
ч? О
ч s
+ и
ю ^ о
СО СО о
О ЧО ^°
§ я v
? 2 t-
а + V
- « о
" 1 °
со ^ О
+ • ~*
5 5 ^<
СО ЧО
II 4-
С
о
•е-
43

Класс точности
V-G
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯП0
AOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.110
35.151
37.590
39.989
42.046
43.770
45.236
46.510
47.632
48.628
49.515
50.305
51.010
51.638
52.198
52.698
53.145
53.545
53.903
54.224
54.514
54.775
55.011
55.224
55.418
55.595
55.756
55.903
56.038
56.162
56.275
56.380
56.477
56.566
56.649
56.726
56.797
56.864
56.926
56.983
57.038
57.088
57.136
57.180
57.222
57.261
57.298
57.333
57.366
57.397
57.427
57.455
57.481
57.506
57.530
57.553
57.574
57.595
57-614
ОТРИЦАТЕЛЬНЫЙ ИОН
К°(Л = р(П) •
Ф°(Л
Дж • К • моль
190.396
190.604
200.358
208.105
214.608
220.257
225.277
229.811
233.955
237.779
241.335
244.661
247.789
250.743
253.543
256.205
258.744
261.171
263.496
265.728
267.875
269.943
271.937
273.864
275.728
277.532
279.282
280.979
282.627
284.229
285.788*
287.306
288.784
290.226
291.632
293.005
294.346
295.656
296.938
298.192
299.419
300.620
301.797
302.951
304.032
305.192
306.280
307.349
308.398
309.429
310.441
311.436
312.415
313.377
314.323
315.255
316.171
317.074
317.962
р2(О) .р(е) -р~
S°(T)
223.995
224.212
234.651
243.302
250.780
257.395
263.338
268.741
273.701
278.288
282.558
286.553
290.307
293.848
297.199
300.379
303.404
306.288
309.044
311.682
314.211
316.640
318.977
321.227
323.397
325.491
327.516
329.476
331.373
333.213
334.997
336.731
338.415
340.054
341.648
343.202
344.715
346.192
347.632
349.038
350.412
351.755
353.068
354.352
355.610
356.840
358.047
359.228
360.387
361.523
362.638
363.732
364.806
365.861
366.898
367.916
368.917
369.902
370.870
ДИОКСИДА
1(НО? АГИ
Н°(Г)-Но@)
кДж • моль"*
10.018
10.083
13.717
17.598
21.703
25.997
30.449
35.037
39.746
44.560
49.467
54.459
59.526
64.659
69.851
75.096
80.389
85.724
91.096
' 96.503
101.940
107.405
112.894
118.406
123.939
129.489
135.057
140.640
146.237
151.847
157.469
163.102
168.745
174.397
180.058
185.727
191.403
197.086
202.776
208.471
214.172
219.879
225.590
231.306
237.026
242.750
248.478
254.209
259.944
265.683
271.424
277.168
2*2.915
288.664
294.416
300.170
305.926
311.685
317.445
ВОДОРОДА
НО2" (г)
э@) = 832.505 кДж-моль
-136.4323
-135.5157
-98.4884
-76.1477
-61.1763
-50.4302
-42.3332
-36.0076
-30.9257
-26.7507
-23.2577
-20.2908
-17.7383
-15.5181
-13.5684
-11.8422
-10.3026
-8.9205
-7.6724
-6.5396
-5.5065
-4.5603
-3.6902
-2.8873
-2.1438
-1.4534
-.8104
-.2099
.3522
.8795
1.3754
1.8425
2.2834
2.7004
3.0953
3.4699
3.8258
4.1644
4.4870
4.7947
5.0886
5.3696
5.6386
5.8964
6.1436
6.3810
6.6092
6.8286
7.0399
7.2435
7.4397
7.6291
7.8120
7.9887
8.1596
8.3250
8.4851
8.6402
8.7906
Т
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200 ,
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г-
8
со
со
II
«о
8
+
1
о
О
1
?
О
00
со
00
$
со
*н
II
о
•6*
Т а б л и
Т
Т. §
?> о
й о
s й
CN '
ГЧ ||
1 Q
II *
О QQ*
1 "м -
о ,и.
lC i с
<=• О
о 5
^ 0
1
I
т
к
со
г-
т
«О
^:
1
ON
s
ца 19
§
к
V©
00
о
ЧО
о «
' со
о
S
V
V
8
«о
1
о
II
44

Класс точности
I-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.310
33.354
33.609
33.618
34.146
35.071
36.289
37.606
38.942
40.261
41.544
42.782
43.969
45.105
46.186
47.215
48.191
49.117
49.992
50.819
51.600
52.336
53.030
53.682
54.296
54.873
55.415
55.924
56.402
56.851
57.274
57.671
58.046
58.399
58.732
59.049
59.349
59.635
59.909
60.172
60.427
60.673
60.914
61.150
61.384
61.617
61.849
62.084
62.322
62.566
62.816
63.074
63.343
63.623
63.893
64.143
64.365
64.549
64.721
64.882
65.030
К°(Т)= р2(Н)
Ф°(Л
Дж • К • моль
119.379
142.260
155.501
155.706
165.279
172.763
178.928
184.199
188.826
192.966
196.727
200.181
203.385
206.377
209.190
211.848
214.371
216.774
219.070
221.271
223.386
225.422
227.387
229.285
231.123
232.904
234.632
236.311
237.945
239.535
241.084
242.596
244.070
245.511
246.918
248.295
249.642
250.961
252.253
253.519
254.760
255.978
257.172
258.345
259.497
260.629
261.741
262.835
263.911
264.969
266.010
267.035
268.045
269.040
270.016
270.978
271.927
272.865
273.790
274.703
275.604
•Р(О) -р~1
S°iT)
152.271
175.370
188.724
188.930
198.715
206.425
212.924
218.617
223.726
228.389
232.697
236.716
240.489
244.054
247.436
250.658
253.737
256.686
259.519
262.244
264.871
267.406
269.857
272.229
274.527
276.755
278.918
281.019
283 062
285.049
286.983
288.868
290.705
292.496
294.245
295.952
297.620
299.250
300.844
302.403
303.930
305.425
306.890
308.326
309.735
311.117
312.474
313.806
315.116
316.403
317.670
318.916
320.144
321.353
322.528
323.682
324.823
325.964
327.088
328.196
329.288
ВОДА Н20 (г)
(Н2О) ЛгН
н°т-н°«))
кДж • моль
3.289
6.622
9.908
9.967 ,
13.374
16.831
20.398
24.092
27.920
31.880
35.971
40.187
44.525
48.980
53.545
58.215
62.986
67.852
72.807
77.848
82.970
88.167
93.436
98.772
104.171
109.629
115.144
120.711
126.328
131.991
137.697
143.445
149.231
155.053
160.910
166.799
172.719
178.668
184.646
190.650
196.680
202.735
208.814
214.917
221.044
227.194
233.368
239.564
245.784
252.029
258.298
264.592
270.913
277.261
283.565
289.868
296.217
302.663
309.127
315.607
322.103
э@) = 917.764 кДж • моль
\%К°(Т)
-472.2482
-231.4323
-151.8788
-150.8772
-110.4666
-86.1445
-69.8811
-58.2314
-49.4706
-42.639$
-37.1616
-32.6698
-28.9188
-25.7386
-23.0078
-20.6370
-18.5593
-16.7233
-15.0890
-13.6248
-12.3055
-11.1105
-10.0229
-9.0290
-8.1171
-7.2774
-6.5017
-5.7829
-5.1150
-4.4928
-3.9118
-3.3679
-2.8578
-2.3783
-1.9269
-1.5011
-1.0988
-.7181
-.3573
-.0149
.3104
.6199
.9148
1.1960
1.4645
1.7211
1.9666
2.2017
2.4270
2.6431
2.8506
3.0500
3.2417
3.4261
3.6039
3.7753
3.9405
4.0998
4.2536
4.4022
4.5458
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000 *
©
00
II
+
©
со
00
сч
00
©
о
©
1
со
©
со
а
щ
С
о
Та
Т
с;
1
со
О)
со
II
о
С»
я
о
т
л
1
i
го
*
©
со
со
+
Н
со
©
ЧО
1
00
со
00
+
б л и
т
1
о
00
?
1
II
Q
ю
00
ON
с
я
о
<1
ца 20
_
i
О
i
•
<^>
о ос
2
©
§
ЧО
V
ь.
V
о
©
? •
о
II
45

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°ЛТ)
и
65.290
65.499
65.658
65.767
65.826
65.838
65.804
65.726
65.608
65.452
65.263
65.044
64.799
64.533
64.249
63.951
63.644
63.332
63.017
62.705
61.954
61.276
60.701
60.243
59.903
59.668
59.517
59.419
59.338
59.237
59.074
58.812
58.410
57.832
57.044
56.014
54.711
53.109
51.183
48.908
Ф°(Г)
Дж К~ -моль"
277.370
279.092
280.771
282.411
284.011
285.576
287.104
288.600
290.063
291.495
292.897
294.270
295.615
296.933
298.226
299.493
300.736
301.955
303.152
304.326
307.169
309.888
312.492
314.989
317.Э87
319.692
321.912
324.051
326.117
328.112
330.043
331.913
333.725
335.483
337.189
338.845
340.454
342.016
343.535
345.011
ВОДА Н2О
S\T)
-1
331.424
333.501
335.519
337.481
339.388
341.243
343.046
344.800
346.506
348.165
349.779
351.349
352.877
354.364
355.810
357.219
358.592
359.928
361.231
362.501
365.542
368.408
371.119
373.692
376.144
378.488
380.737
382.900
384.984
386.994
388.933
390.805
392.609
394.345
396.010
397.603
399.121
400.560
401.915
403.183
(г)
#°(Л-я°@)
кДж • моль
335.136
348.216
361.332
374.476
387.636
400.803
413.968
427.121
440.255
453.362
466.434
479.465
492.450
505.384
518.262
531.082
543.842
556.539
569.174
581.746
612.909
643.712
674.202
704.433
734.465
764.353
794.147
823.879
qco CAQ
ОЭО.ЭОО
883.214
912.795
942.271
971.584
1000.652
1029.381
1057.656
1085.350
1112.318
1138.405
1163.443
\%К°(Т)
4.8190
5.0751
5.3156
5.5418
5.7551
5.9565
6.1469
6.3272
6.4983
6.6607
6.8152
6.9623
7.1026
7.2364
7.3644
7.4867
7.6039
7.7163
7.8240
7.9275
8.1692
8.3892
8.5905
8.7753
8.9458
9.1035
9.2499
9.3862
л с 1 Qi
У.51о4
9.6325
9.7442
9.8492
Q.9481
10.0414
10.1297
10.2134
10.2929
10.3686
10.4408
10.5098
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 Л ?ЛЛ
145UU
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 20
(окончание)
+
'а т
? к
со о
ЧО >5
т
'* ^ Q
а ¦=* §
00 ГО о
сг\ 1«» Г";
-о.о:
1.707;
00 «N О
о ^ 2
^ 1-4 .л
+ 1 Т
to V4 О
ЧО ~н
rf  ^
t*- 00
гм со v
II + w
?
о
ф
46

Класс точности
IV-С
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
OQflft
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.683
33.696
34.622
35.789
37.026
38.300
39.606
40.923
42.223
43.482
44.679
45.808
46.866
47.857
48.790
49.671
50.508
51.309
52.079
52.823
53.543
54.242
54.920
55.577
56.214
56.830
57 423
57^92
58.538
59.057
59.551
60.018
60.458
60.870
61.255
61.613
61.944
62.248
62.527
62.780
63.010
63.217
63.401
63.564
63.708
63.832
63.939
64.030
64.104
64.165
64.212
64.246
64.269
64.281
64.284
64.278
64.264
64.243
64.214
ПОЛОЖИТЕЛЬНЫЙ ИОН
*em = p<p).|
Ф°(Т)
Дж • К • моль
161.945
162.151
171.761
179.275
185.485
190.805
195.481
199.669
203.474
206.972
210.217
213.249
216.100
218.794
221.351
223.786
226.113
228.343
230.485
232.547
234.536
23i, 08
238.318
240.121
241.870
243.570
гуле 004
246.834
248.404
249.936
251.431
252.892
254.320
255.718
257.087
258.427
259.741
261.029
262.292
263.533
264.750
265.946
267.121
268.276
269.411
270.527
271.625
272.705
273.769
274.816
275.847
276.862
277.862
278.847
279.818
280.775
281.719
282.649
283.566
?2(Н) р'Чн^О
S°(T)
-1
195.265
195.473
205.284
213.133
219.767
225.569
230.768
235.509
239.889
243.972
247.808
251.429
254.863
258.130
261.249
264.234
267.097
269.849
272.500
275.060
277.534
279.929
282.252
284.507
286.700
288.833
ООП Q1 П
zyu.y 1 и
292.935
294.911
296.839
298.721
300.561
302.360
304.118
305.838
307.521
309.169
310.782
312.361
313.909
315.424
316.910
318.365
319.792
321.190
322.562
323.907
325.226
326.520
327.791
329.037
330.260
331.462
332.641
333.799
334.937
336.055
337.153
338.233
ОКСИДА
¦>-p*w
//V)-//°
ДИВОДОРОДА
Н2О+ (г)
Л. #°@)= -299.449 кДж • моль
@)
кДж • моль
9.934
9.997
13.409
16.929
20.569
24:335
28.230
32.257
36.414
40.700
45.109
49.633
54.268
59.004
63.837
68.761
73.770
78.861
84.031
89.276
94.594
99.984
105.442
110.967
116.557
122.209
1 97 Q99
1 л 1 . aZZ
133.693
139.520
145.400
151.330
157.309
163.333
169.400
175.606
181.650
187.828
194.037
200.276
206.542
212.832
219.143
225.474
231.823
238.186
244.564
250.952
257.351
263.757
270.171
276.590
283.013
289.439
295.866
302.295
308.723
315.150
321.576
327.998
igtfV)
61.0283
6G 7080
47.8212
40.1094
34.9793
31.3210
28.5807
26.4509
24.7476
23.3537
22.1914
21.2070
20.3620
19.6283
18.9850
18.4160
17.9089
17.4538
17.0429
16.6698
16.3293
16.0173
15.7300
15.4646
15.2184
14.9895
14 7758
14.5758
14.3882
14.2118
14.0454
13.8883
13.7396
13.5985
13.4645
13.3370
13.2155
13.0995
12.9886
12.8825
12.7808
12.6832
12.5895
12.4994
12.4127
12.3291
12.2486
12.1708
12.0957
12.0231
11.9529
11.8849
11.8190
11.7552
11.6933
11.6332
11:5748
11.5181
11.4629
т
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
лоии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
ю
о
00
II
¦<;
+
ё
со
8
О
+
ь ON
о
О
О
|
й
«О
О\
ON
<N
4"
со
«О
VO
VO
||
о
ф
Таб л и
i
л
о
О
со
00
II
о
о
о
т
л
е;
О
i
*
го
X
сЗ
+
С»
00
со
1
VO
+
т
1
•
с*
X
00
II
я
00
Си
Q
с
?
о
<\
ца 21
i
§
1
i
с-
о
с-
о 5
о
§
V
V
о
о
т
—«
II
47

г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200.
9400
9600
9800
10000
10500
11000
11500
1Я000
12500
13000
13500
14000
1 AK(\f\
145UU
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
ПОЛОЖИТЕЛЬНЫЙ 1
С°р (Т)
64.141
64.048
63.940
63.820
63.691
63.556
63.416
63.274
63.131
62.987
62.845
62.704
62.566
62.431
62.298
62.169
62.044
61.923
61.805
61.691
61.423
61.179
60.956
60.753
60.569
60.402
60.250
60.112
эУ.УоО
59.871
59.766
59.670
59.582
59.501
59.427
59.359
59.296
59.237
59.183
59.133
Ф°G)
Дж К • моль"
285.364
287.114
288.818
290.479
292.100
293.680
295.223
296.729
298.202
299.640
301.048
302.424
303.772
305.091
306.383
307.649
308.890
310.107
311.300
312.471
315.305
318.014
320.609
323.098
325.488
327.789
330.005
332.142
334.206
336.202
338.133
340.003
341.817
343.577
345.287
346.949
348.565
350.139
351.672
353.166
ИОН ОКСИДА
S°(T)
-1
340.337
342.372
344.341
346.248
348.097
349.889
351.628
353.318
354.959
356.556
358.110
359.622
361.096
362.533
363.934
365.302
366.638
367.943
369.218
370.466
373.469
376.321
379.035
381.625
384.102
386.474
388.751
390.939
395.078
397.040
398.936
400.770
402.548
404.271
405.944
407.570
409.151
410.689
412.186
ДИВОДОРОДА
Я°(Г)-Я°@)
кДж • моль"*
340.834
353.653
366.452
379.229
391.980
404.705
417.402
430.071
442.711
455.323
467.906
480.461
492.988
505.488
517.961
530.407
542.829
555.225
567.598
579.948
610.725
641.375
671.907
702.334
732.664
762.906
793.068
823.158
ОС О 1 ОО
оЭо. loz
883.146
913.055
942.914
972.727
1002.497
1032.229
1061.925
1091.588
1121.222
1150.827
1180.405
Н2О+ (г)
0
11.35П,
11.2568
11.1615
11.0709
10.9846
10.9022
10.8235
10.7482
10.6760
10.6068
10.5404
10.4765
10.4151
10.3560
10.2989
Ю.2439
10.1908
10.1395
10.0899
10.0419
9.9283
9.8231
9.7253
9.6340
9.5485
9.4683
9.3928
9.3215
9.1902
9.1296
9.0719
9.0169
8.9643
8.9141
8.8660
8.8199
8.7756
8.7331
8.6824
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 А КПП
14&UU
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
о
о
+
с*
'if
00
г»
р
о
1
со
00
чо
+
<—1
ON
Я
00
II
р
о
Таблица 21
(окончание)
Т
л
Е-
О
7
Т
к ^
l=t о
2 v
+ Еч
U ©
1 I
со °
^ Е^
СО II
48

Класс точности
IV-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.445
38.966
42.395
42.467
46.481
50.267
53.524
56.284
58.662
60.753
62.619
64.300
65.819
67.195
68.442
69.574
70.602
71.537
72.390
73.168
73.882
74.537
75.141
75.699
76.216
76.697
77.146
77.566
77.961
78.332
78.683
79.016
79.332
79.633
79.920
80.195
80.459
80.712
80.957
81.193
81.422
81.644
81.859
82.068
82.272
82.471
82.666
82.856
83.042
83.225
83.405
83.581
83.755
83.926
84.094
84.260
84.425
84.587
84.747
84.906
85.063
*V)=V(h>
Ф°(Л
Дж • К~1 • моль"
158.108
182.376
196.982
197.213
208.225
217.171
224.817
231.556
237.616
243.146
248.246
252.988
257.427
261.606
265.557
269.307
272.879
276.290
279.556
282.690
285.703
288.605
291.404
294.109
296.726
299.260
301.717
304.102
306.420
308.673
310.867
313.004
315.086
317.118
319.101
321.038
322.931
324.782
326.593
328.366
330.102
331.803
333.471
335.106
336.71 Г
338.285
339.831
341.350
342.842
344.308
345.750
347.167
348.562
349.935
351.286
352.616
353.926
355.217
356.488
357.742
358.977
ПЕРЕКИСЬ
• р2 <О) • р (Н
S°(T)
-1
192.502
218.236
234.407
234.669
247.433
258.220
267.681
276.145
283.820
290.852
297.352
303.400
309.061
314.385
319.411
324.172
328.696
333.004
337.118
341.053
344.824
348.445
351.927
355.279
358.512
361.633
364.650
367.569
370.398
373.140
375.802
378.387
380.901
383.347
385.728
388.049
390.312
392.520
394.676
396.781
398.840
400.853
402.823
404.752
406.641
408.492
410.307
412.087
413.833
415.547
417.230
418.884
420.508
422.105
423.676
425.220
426.740
428.236
429.708
431.158
432.587
ВОДОРОДА
а> v
Н°(Т)-Н°@)
кДж • моль
3.439
7.172
11.158
11.237
15.683
20.525
25.719
31,213
36.963
42.936
49.106
55.453
61.961
68.612
75.395
82.297
89.307
96.414
103.611
110.890
118.243
125.664
133.149
140.691
148.287
155.933
163.625
171.361
179.138
186.952
194.804
202.689
210.606
218.554
22G.532
234.538
242.571
250.629
258.713
266.820
274.951
283.105
291.280
299.476
307.693
315.930
324.187
332.463
340.758
349.072
357.403
365.753
374.119
382.503
390.904
399.322
407.756
416.207
424.674
433.156
441.655
Н2О2 (г)
Ч°@) = 1055.522
-540.2851
-262.7494
-170.9509
-169.7947
-123.1256
-95.0230
-76.2283
-62.7655
-52.6426
-44.7512
-38.4248
-33.2387
-28.9095
-25.2403
-22.0907
-19.3574
-16.9627
-14.8474
-12.9650
-11.2792
-9.7605
-8.3854
-7.1342
-5.9910
-4.9424
-3.9770
-3.0854
-2.2593
-1.4919
-.7770
-.1095
.5152
1.1011
1.6517
2.1701
2.6590
3.1209
3.5580
3.9722
4.3653
4.7388
5.0942
5.4327
5.7556
6.0638
6.3585
6.6403
6.9102
7.1690
7.4172
7.6555
7.8845
8.1047
8.3166
8.5208
8.7175
8.9072
9.0903
9.2671
9.4379
9.6031
кДж • моль 1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
со
II
+
ё
со
«о
о
+
V
ON
ON
СО
О
1
о
1О
со
VO
ч—1
00
со
II
Таблица 22
Т
I
. о
Т 2
о % ^
^ ° о
? ^ ?
оо со т
00 _< 1
00 | ^
as
ГА II sg
II </"> чо
О 00 ^
_ ON i-h
°« 1ч "а
д4 О ° «
О w<s со
о Е
^ о
i
«? 1
| v
+ V
«н g
о То
1 7
ON ^
§ II
об Ч""'
49

Класс точности
V-F
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;,л
35.484
35.530
38.411
41.574
44.635
47.514
50.230
52.801
55.227
57.499
59.608
61.549
63.323
64.937
66.400
67.724
68.919
69.998
70.973
71.855
72.653
73.376
74.032
74.629
75.173
75.669
76.123
76.539
76.921
77.271
77.595
77.893
78.168
78.424
78.660
78.880
79.085
79.275
79.453
79.619
79.774
79.920
80.056
80.184
80.305
80.418
80.525
80.626
80.721
80.81
80.896
80.977
81.053
81.126
81.195
81.260
81.322
81.382
81.438
ПОЛОЖИТЕЛЬНЫЙ ИОН
К°(Т) = р3(Н)
Ф°(Т)
Дж • К • моль
159.330
159.538
169.336
177.150
183.751
189.532
194.717
199.448
203.820
207.900
211.736
215.364
218.812
222.102
225.251
228.274
231.182
233.986
236.694
239.313
241.849
244.308
246.696
249.016
251.272
253.468
255.607
257.693
259.727
261.713
263.653
265.549
267.403
269.216
270.991
272.729
274.432
276.100
277.736
279.341
280.916
282.461
283.979
285.469
286.933
288.373
289.788
291.179
292.548
293.894
295.220
296.525
297.809
299.074
300.321
301.549
302.759
303.952
305.129
¦P(O)V(H3,
-i
193.025
193.244
203.846
212.756
220.610
227.709
234.232
240.298
245.988
251.360
256.455
261.303
265.931
270.355
274.594
278.660
282.565
286.321
289.936
293.421
296.782
300.028
303.165
306.199
309.137
311.984
314.744
317.423
320.024
322.552
325.010
327.403
329.732
332.002
334.215
336.373
338.479
340.536
342.545
344.509
346.430
348.308
350.147
351.948
353.712
355.440
357.134
358.796
360.425
362.025
363.595
365.136
366.651
368.139
369,601
371.039
372.452
373.843
375.212
ОКСИДА ТРИВОДОРОДА
Н3О+ (г)
Т а б л и ц а -23
Э+ ) • р'1 (е) Д.//°@)= 296.085 кДж • моль
//?Г/')~//°@)
кДж • моль
¦„•<л
10.046 -38.2682
10.112 -37.9385
13.804 -24.6002
17.803 -16.5318
22.115 - 1.1154
26.724 -7.2239
31.613 -4.2910
36.765 -2.0008
42.168 -.1630
47.806 1.3441
53.662 2.6020
59.721 3.6674
65.966 4.5808
72.381 5.3723
78.949 6.0642
- 85.656 6.6740
92.489 7.2152
99.436 7.6983
106.485 8,1322
113.628 8.5236
120.854 8.8784
128.156 9.2013
135.527 9.4962
142.960 9.7665
150.451 10.0151
157.993 10.2443
165.583 10.4562
173.216 10.6526
180.890 10.8351
188.600 11.0050
196.343 11.1635
204.118 11.3116
211.921 11.4503
219.751 11.5805
227.605 11.7027
235.482 11.8177
243.380 11.9261
251.299 12.0283
259.235 12.1248
267.189 12.2161
275.158 12.3026
283.143 12.3846
291.142 12.4623
299.154 12.5362
307.179 12.6064
315.215 12.6732
323.262 12.7369
331.320 12.7975
339.387 12.8554
347.464 12.9106
355.549 12.9634
363.643 13.0138
371.744 13.0621
379.854 13.1083
387.970 13.1525
396.092 13.1949
404.222 13.2356
412.357 13.2746
420.498 13.3121
т
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
i
7 s
• ^ 8 §
>** 00 ,_
JJ О ^ '
О 00 f~s Ъ?
II **2 го
11 - « 3
* ° а ?
^ и
О + d
го О о не
|_Н **»
Ж го Со
О w
* о
+
*О О
? д
а * s
5 Л g
S й §
О V}
Я об V
О ^"
i i i
^- ON О
CN ГО
^О OI г}-
*-i *Ч 1
ГО | О
S & ^
S г^ "
11
о
ь
50

ПОЛОЖИТЕЛЬНЫЙ ИОН ОКСИДА ТРИВОДОРОДА Н3О+ (г)
Таблица 23
(окончание)
&
S°(T)
Дж К • моль
кДж * моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
81.543
81.639
81.726
81.806
81.880
81.948
82.010
82.068
82.121
82.171
82.217
82.260
82.300
82.337
82.372
82.405
82.436
82.464
82.492
82.517
82.575
82.625
82.669
82.707'
82.741
82.771
82.798
82.822
82.844
82.864
82.881
82.897
82.912
82.925
82.938
82.949
82.959
82.969
82.978
82.986
307.432
309.675
311.859
313.987
316.062
318.087
320.064
321.995
323.883
325.729
327.535
329.302
331.034
332.729
334.392
336.021
337.620
339.188
340.727
342.239
345.902
349.411
352.777
356.014
359.129
362.132
365.030
367.832
370.541
373.166
375.710
378.179
380.576
382.907
385.174
387.380
389.530
391.626
393.671
395.666
3/7.884
380.474
382.988
385.429
387.801
390.109
392.355
394.543
396.675
398.755
400.784
402.766
404.702
406.595
408.445
410.256
412.020
413.765
415.465
417.132
421.160
425.002
428.676
432.195
435.572
438.818
44.1.942
444.954
447.860
450.669
453.387
456.018
458.569
461.045
463.449
465.786
468.058
470.271
472.426
474.527
436.796
453.114
469.451
485.804
502.173
518.556
534.952
551.360
567.779
584.208
600.647
617.095
633.550
650.014
666.485
682.963
699.447
715.937
732.433
748.934
790.207
831.507
872.831
914.175
955.537
996.916
1038.308
1079.714
1121.130
1162.557
1203.994
1245.438
1286.891
1328.350
1369.816
1411.288
1452.765
1494.247
1535.734
1577.225
13.3826
13.4479
13.5083
13.5643
13.6163
13.6648
13.7099
13.7520
13.7913
13.8280
13.8624
13.8946
13.9248
13.9532
13.9798
14.0048
14.0283
14.0504
14.0712
14.0909
14.1351
14.1733
14.2063
14.2349
14.2596
14.2810
14.2994
14.3153
14.3288
14.3404
14.3502
14.3585
14.3653
14.3708
14.3753
14.3787
14.3811
14.3828
14.3837
14.3743
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
? V
V
о
о
о
Т
о
51

Класс точности
I
ДЕЙТЕРИЙ D (г)
Таблица 24
с;,л
Ф°(Т)
S°(T)
Дж • К • моль
кДж • моль
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
79.746
94.154
102.454
102.582
108.562
113.200
116.990
120.194
122.970
125.418
127.608
129.589
131.398
133.062
134.602
136.036
137.378
138.638
139.826
140.950
142.016
143.030
143.997
144.921
145.806
146.654
147.469
Г48.254
149.010
149.739
150.444
151.125
151.785
152.425
153.045
153.648
154.234
154.803
155.357
155.897
156.424
156.937
157.438
157.927
158.405
158.872
159.329
159.776
160.213
160.642
161.062
161.473
161.877
162.273
162.662
163.043
163.417
163.78$
164.147
164.502
164.852
100.532
114.940
123.240
123.368
129.348
133.986
137.776
140.980
143.756
146.204
148.394
150.375
152.184
153.848
155.388
156.822
158.164
159.424
160.612
161.736
162.802
163.816
164.783
165.707
166.592
167.440
168.255
169.040
169.796
170.525
171.230
171.911
172.571
173.211
173.831
174.434
175.020
175.589
176.143
176.683
177.209
177.723
178.224
178.713
179.191
179.658
180.115
180.562
180.999
181.428
181.848
182.259
182.663
183.059
183.448
183.829
184.203
184.571
184.933
185.288
185.637
2.079
4.157
6 Л 97
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
«-и
О
с-
О
00
ON
<N
II
О
Г-
II
я
а и
w a
О w
On
II
о вс
со
§
V
V
о
о
?
°*
52

ДЕЙТЕРИЙ D (г)
Таблица 24
(окончание)
со
К
Дж К • моль"
И°(Т)-И°@)
кДж * моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
2*0.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
165.533
166.193
166.833
167.453
168.056
168.641
169.211
169.765
170.305
170.831
171.344
171.845
172.335
172.812
173.280
ф.736
174.183
174.621
175.050
175.469
176.484
177.451
178.375
179.259
180.108
180.923
181.708
182.463
183.193
183.897
184.579
185.239
185.879
186.499
187.102
187.687
188.257
188.811
189.351
189.877
186.319
186.979
187.619
188.239
188.842
189.427
189.997
190.551
191.091
191.617
192.131
192.631
193.120
193.598
194.065
194.522
194.969
195.407
195.836
196.256
197.270
198.237
199.161
200.045
200.894
201.709
202.493
203.249
203.979
204.684
205.365
206.025
206.665
207.285
207.888
208.473
209.043
209.597
210.137
210.663
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
53

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Й.00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.318
29.205
29.195
29.196
29.244
29.368
29.622
30.011
30.505
31.061
31.641
32.216
32.768
33.289
33.773
34.221
34.634
35.014
35.364
35.688
35.987
36.265
36.525
36.769
36.999
37.216
37.423
37.620
37.810
37*993
38.171
38.344
38.513
38.679
38.843
39.005
39.165
39.324
39.481
39.639
39.795
39.950
40.105
40.258
40.410
40.560
40.709
40.854
40.997
41.135
41.270
41.400
41.525
41.645
41.757
41.863
41.962
42.053
42.136
42.210
42.275
А-(Г)=Р'Ш).р-
Ф°(Г)
Дж • К~1 • моль
85.172
104.674
116.108
116.286
124.572
131.022
136.308
140.792
144.693
148.151
151.264
154.099
156.705
159.121
161.375
163.489
165.482
167.367
169.158
170.863
172.492
174.052
175.548
176.986
178.371
179.707
180.997
182.246
183.454
184^626
185.764
186.869
187.944
188.990
190.009
191.003
191.972
192.918
193.842
194.746
195.630
196.495
197.342
198.172
198.985
199.783
200.566
201.334
202.088
202.829
203.557
204.272
204.976
205.668
206.350
207.020
207.680
208.330
208.971
209.602
210.224
ДИДЕЙТЕРИЙ
S°(T)
112.676
133.194
144.849
145.029
153.434
159.971
165.346
169.939
173.978
177.603
180.905
183.948
186.775
189.419
191.904
194.249
196.471
198.583
200.594
202.515
204.353
206.116
207.809
209.438
211.008
212.522
213.986
215.402
216.774
218Л04
219.395
220.649
221.869
223.057
224.214
225.342
226.444
227.519
228.569
229.597
230.603
231.587
232.552
233.497
234.424
235.334
236.227
237.104
237.966
238.813
239.645
240.464
241.269
242.061
242.840
243.608
244.363
245.106
245.839
246.560
247.269
П°(Г)-П
D2 (г)
Дг//°@) = 439.614 кДж-моль
'@)
кДж * моль
2.750
5.704
8.569
8.623
11.545
14.474
17.423
50.403
23.428
26.506
29.641
32.834
36.084
39.387
42.740
46.140
49.583
53.066
56.585
60.138
63.722
67.335
70.974
74.639
78.328
82.039
85.771
89.523
97Л85
100.893
104.719
108.562
112.421
116.297
120.190
124.098
128.023
131.963
135.919
139.891
143.878
147.881
151.899
155.932
159.981
164.044
168.122
172.215
176.321
180.442
184.575
188.722
192.880
197.050
201.232
205.423
209.624
213.833
218.051
222.275
-225.7456
-110.4453
-72.3792
-71.9001
-52.5726
-40.9436
-33.1695
-27.6017
-23.4149
-20.1506
. -17.5329
-15.3865
-13.5941
-12.0745
-10.7697
-9.6368
-8.6440
-7.7666
-6.9856
-6.2858
-5.6552
-5.0840
-4.5641
-4.0889
-3.6529
-3.2513
-2.8802
-2.5364
О О1 Aft
-1.9190
-1.6409
-1.3805
-1.1362
-.9066
-.6903
-.4863
-.2935
-.1111
.0619
.2260
.3820
.5305
.6719
.8068
.9356
1.0587
1.1765
1.2893
1.3974
1.5011
1.6007
1.6963
1.7883
1.8768
1.9621
2.0442
2.1234
2.1998
2.2736
2.3449
2.4138
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
«оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
550D
5600
5700
5800
5900
6000
S
00
О
II
+
го
On
о
1
ON
8
О
о
о
VO
r-i
00
1Л
205.:
С
о
Табли
о
^^
о »
II jo
О 00
ON
ГЧ U
О
<Г S
^ о
Т
А
О
?
1
V»
5
СП
«о
+
X
00
ON
7
+
ца 25
Т
1
о
Т
д
ON
чО
ГЦ
об
о S
S
V
к.
V
о"
о
1
II
54

ДИДЕЙТЕРИЙ D_ (г)
Таблица 25
(окончание)
С°р (Т)
s°m
Дж К" -моль
"
Н°{Т)-Н°@)
к Дж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
42.378
42.442
42.466
42.449
42.394
42.299
42.167
42.000
41.800
41.570
41.312
41.029
40.725
40.401
40.061
39.708
39.343
38.969
38.589
38.204
37.234
36.270
35.329
34.424
33.562
32.748
31.985
31.272
30.608
29.991
29.420
28.890
28.401
27.947
27.528
27.140
26.781
26.448
26.140
25.853
211.441
212.625
213.778
214.900
215.995
217.062
218.103
219.119
220.112
221.081
222.029
222.956
223.862
224.748
225.616
226.465
227.297
228.111
228.908
229.690
231.576
233.371
235.082
236.714
238.273
239.764
241.191
242.559
243.871
245.130
246.340
247.505
248.626
249.707
250.749
251.756
252.728
253.668
254.578
255.459
248.657
250.004
251.311
252.578
253.808
255.001
256.158
257.280
258.369
259.424
260.448
261.440
262.402
263.334
264.238
265.115
265.965
266.790
267.589
268.365
270.205
271.915
273.507
274.991
276.379
277.679
278.900
280.050
281.136
282.163
283.137
284.063
284.944
285.785
286.589
287.359
288.098
288.808
289.491
290.149
230.741
239.224
247.715
256.207
264.692
273.162
281.609
290.026
298.407
306.744
315.033
323.268
331.444
339.556
347.603
355.580
363.485
371.316
379.072
386.752
405.612
423.987
441.885
459.322
476.316
492.892
509.073
524.885
540.353
555.501
570.352
584.927
599.248
613.334
627.201
640.867
654.346
667.653
680.799
693.796
2.5448
2.6676
2.7830
2.8915
2.9938
3.0903
3.1816
3.2681
3.3502
3.4281
3.5022
3.5728
3.6401
3.7044
3.7659
3.8247
3.8811
3.9352
3.9871
4.0370
4.1538
4.2605
4.3584
4.44*88
4.5325
4.6104
4.6833
4.7516
4.8158
4.8764
4.9338
4.9882
5.0399
5.0892
5.1363
5.1814
5.2246
5.2660
5.3059
5.3443
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
<=> 7
I
? 3
1
00
ЧО
оо
ЧО
i
II
+
»О
ЧО
о
1
н
т
9.9:
+
**•
V
о
100
т
о
1-4
II
^>
>-*
ф
55

Класс точности
I-B
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
32.156
30.644
29.939
29.931
29.682
29.728
30.021
30.490
31.059
31.664
32.263
32.831
33.357
33.838
34.273
34.666
35.021
35.342
35.633
35.898
36.141
36.365
36.572
36.764
36.944
37.113
37.273
37.425
37.570
37J09
37.844
37.975
38.102
38.227
38.349
38.468
38.587
38.703
38.818
38.932
39.044
39.154
39.263
39.370
39.474
39.577
39.676
39.772
39.865
39.955
40.040
40.120
40.195
40.266
40.330
40.389
40.442
40.488
40.527
40.560
40.585
К°(Т)= p(D) •
Ф°(Т)
Дж • К • моль
126.723
147.318
159.374
159.561
168.230
174.933
180.400
185.023
189.036
192.590
195.786
198.694
201.367
203.842
206.150
208.314
210.351
212.278
214.106
215.846
217.506
219.094
220.617
222.080
223.487
224.843
226.152
227.418
99Я (\А0
229.828
230.979
232.096
233.181
234.237
235.264
236.266
237.242
238.194
239.124
240.032
240.920
241.788
242.638
243.470
244.285
245.083
245.866
246.635
247.388
248.128
248.855
249.568
250.270
250.960
251.638
252.305
252.961
253.607
254.243
254.869
255.486
ОКСИД
р(О) p~l(DO)
S°(T)
-1
155.670
177.474
189.557
189.742
198.311
204.934
210.377
215.038
219.146
222.839
226.206
229.308
232.188
234.877
237.401
239.779
242.028
244.161
246.189
248.123
249.971
251.740
253.436
255.066
256.634
258.146
259.605
261.014
АЛЛ »>П
26з!б99
264.979
266.223
267.430
268.605
269.748
270.861
271.946
273.005
274.039
275.048
276.036
277.001
277.946
278.871
279.777
280.666
281.536
282.391
283.229
284.052
284.860
285.654
286.434
287.200
287.953
288.694
289.422
290.138
290.843
291.536
292.218
ДЕЙТЕРИЯ DO (г)
Н°(Т)-Н°@)
кДж • моль
2.895
6.031
8.999
9.054
12.032
15.001
17.986
21.011
24.088
27.224
30.420
33.675
36.985
40.345
43.751
47.198
50.683
54.201
57.750
61.327
64.929
68.555
72.202
75.869
79.554
83.257
86.976
90.711
98*225
102.003
105.794
109.598
113.414
117.243
121.084
124.936
128.801
132.677
136.564
140.463
144.373
148.294
152.226
156.168
160.120
164.083
168.055
172.037
176.028
180Л28
184.036
188.052
192.075
196.105
200.141
204.183
208.229
212.280
216.334
220.392
Таблица 26
э@) = 429.750 кДж • моль
-220.9866
-108.2583
-71.0339
-70.5653
-51.6622
-40.2871
-32.6822
-27.2352
•23.1393
-19.9459
-17.3852
-15.2857
-13.5325
-12.0463
-10.7702
-9.6623
-8.6915
-7.8335
-7.0699
-6.3857
-5.7691
-5.2106
-4.7022
-4.2376
-3.8112
-3.4185
-3.0556
-2.7193
9 А(\(\7
-2. Г155
-1.8434
-1.5886
-1.3496
-1.1248
-.91.31
-.7134
-.5246
-.3459
-.1765
-.0156
.1373
.2828
.4215
.5539
.6803
.8011
.9168
1.0276
1.1339
1.2359
1.3338
1.4280
1.5186
1.6058
1.6899
1.7709
1.8491
1.9245
1.9974
2.0679
2.1361
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
§
Л 1
о * g
i •
О pj »-н -ч
2 о ? ^
о ^j. ^
«5 оо и *
^ ? Q П
II п * О
"^ /-S '"I ^
О 00 &
С <N "
о с о 5
S О оз
о В
^ О
^^
+
7 *
й '-
Я §
о 2
d J"
•
с* ^
«> * 2
so t=t о
¦¦н о
со ^ о
О J* ^°
§ 2 V
g + V
х §
со ^ О
оо *2
^ 1 7
!n го
II +
с
о
56

Класс точности
V-D
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200,
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200.
5300
5400
5500
5600
5700
5800
5900
6000
29.140
29.141
29.204
29.397
29.760
30.267
30.857
31.477
32.088
32.667
33.203
33.693
34.136
34.537
34.899
35.227
35.524
35.795
36.042
36.270
36.480
36.675
36.858
37.029
37.191
37.345
37.492
37!б34
37.772
37.906
38.037
38.167
38.296
38.426
38.555
38.686
38.819
38.953
39.091
39.231
39.374
39.521
39.671
39.825
39.983
40.144
40.308
40.476
40.647
40.821
40.998
41.176
41.357
41.540
41.724
41.909
42.095
42.281
42.467
ОТРИЦАТЕЛЬНЫЙ
К°(Т)= рф) •
Ф°(Т)
Дж • К • моль
149.746
149.923
158.161
164.579
169.845
174.319
178.216
181.677
184.796
187.639
190.257
192.685
194.951
197.078
199.083
200.981
202.782
204.498
206.137
207.706
209.210
210.656
212.047
213.389
214,685
215.937
217.150
21в!з25
219.465
220.572
221.648
222.695
223.714
224.707
225.676
226.621
227.544
228.446
229.328
230.190
231.035
231.861
232.671
233.465
234.244
235.008
235.759
236.495
237.219
237.930
238.630
239.317
239.994
240.660
241.316
241.962
242.598
243.225
243.843
р(О) • р(е) •
S°(T)
-1
178.300
178.480
186.870
193.404
198.794
203.418
207.497
211.167
214.516
217.601
220.467
223.144
225.658
228.027
230.268
232.394
234.416
236.344
238.186
239.950
241.642
243.268
244.833
246.341
247.797
249.203
250 564
251.882
253.160
254.401
255.607
256.779
257.920
259.032
260.117
261.175
262.208
263.218
264.206
265.173
266.120
267.048
267.959
268.852
269.729
270.591
271.437
272.270
273.089
273.896
274.691
275.473
276.244
277.005
277.755
278.495
279.225
279.946
280.658
ИОН ОКСИДА
р'1 (OD~) Д И
Н°(Т)-Н°@)
кДж • моль
8.513
8.567
11.484
14.412
17.369
20.369
23.425
26.542
29.720
32.958
36.252
39.597
42.989
46.423
49.895
53.402
56.940
60.506
64.098
67.714
71.351
75.009
78.686
82.381
86.092
89.818
93.560
97.317
101.087
104.871
108.668
112.478
116.302
120.138
123.987
127.849
131.724
135.613
139.515
143.431
147.361
151.306
155.265
159.240
163.230
167.236
171.259
175.298
179.354
183.427
187.517
191.626
195.752
199.896
204.059
208.240
212.440
216.658
220.895
ДЕЙТЕРИЯ
°@) = 605.800
„on
-101.3695
-100.7036
-73.8024
-57.5723
-46.6936
-38.8820
-32.9930
-28.3896
-24.6888
-21.6464
-19.0992
-16.9342
-15.0701
-13.4476
-12.0218
-10.7584
-9.6308
-8.6178
-7.7024
-6.8709
-6.1121
-5.4165
-4.7765
-4.1855
-3.6379
-3.1289
-2.6546
-2^2114
-1.7963
-1.4065
-1.0398
-.6941
-.3676
-.0587
.2340
.5119
.7760
1.0275
1.2671
1.4959
1.7144
1.9235
2.1237
2.3157
2.4998
2.6767
2.8468
3.0105
3.1680
3.3199
3.4664
3.6077
3.7443
3.8762
4.0039
4.1274
4.2470
4.3628
4.4752
DO"
кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
S
о
ос
II
+
7
,$
сч
г-
8
О
с*
СЧ
§
о
о
CD
00
-«•
сч
о
оо
00
00
о
сч
1
о
Т а б
1
•
о
сч
го
i
II
о
1
о
о
1
л
§
2
1
1—Г
М.
го
«О
г-
го
го
1
го
го
лица 27
7
«3
§
¦
? 7
" -С
* §
О 2
гч ^
7
и &
2
«о о>
ОО ON
ON
СЧ ||
с
.\ eg
о
О
Я
о
S
V
к,
V
§
1
о
II
57

Класс точности
IV-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.259
33.718
35.844
35.896
38.816
41.523
43.832
45.781
47.431
48.833
50.031
51.065
51.968
52.768
53.487
54.142
54.745
55.305
55.828
56.317
56.776
57.206
57.608
57.984
58.333
58.657
58.956
59.232
59.484
59.714
59.923
60.112
60.282
60.433
60.568
60.687
60.792
60.882
60.960
61.027
61.083
61.129
61.165
61.194
61.215
61.230
61.238
61.241
61.239
61.233
61.222
61.208
61.191
61.171
61.148
61.123
61.097
61.068
61.039
61.008
60.976
*V> = P(D)V
Ф°(Г)
Дж • К~1 • моль"**
162.584
185.644
199.013
199.222
209.052
216.904
223.529
229.307
234.460
239.127
243.404
247.359
251.042
254.492
257.738
260.807
263.718
266.488
269.131
271.659
274.083
276.411
278.651
280.810
282.894
284.909
286.859
288.749
290 582
292,362
294.092
295.775
297.413
299.009
300.565
302.083
303.564
305.012
306.426
307.809
309.162
310.487
311.783
313.054
314.299
315.519
316.716
317.891
3,19.043
320.175
321.286
322.378
323.451
324.505
325.542
326.562
327.565
328.552
329.524
330.480
331.422
ДИОКСИД
(О) -рфО2)
S°(T)
195.841
218.962
232.772
232.994
243.718
252.678
260.458
267.366
273.589
279.259
284.^68
289.286
293.769
297.961
301.898
305.611
309.125
312.461
315.637
318.669
321.569
324.350
327.020
329.589
332.065
334.452
336.759
338.989
341.148
343.240
345.268
347.236
349.147
351.004
352.810
354.568
356.279
357.946
359.570
361.155
362.701
364.209
365.683
367.122
368.530
369.905
371.251
372.568
373.858
375.120
376.357
377.570
378.758
379.924
381.067
382.188
383.289
384.371
385.432
386.476
387.501
ДЕЙТЕРИЯ
V
кДж • моль
3.326
6.664
10.065
10.132
13.867
17.887
2*2.15$
26.641
31.304
36.119
41.064
46.120
51.273
56.510
61.823
67.205
72.650
78.153
83.710
89.318
94.972
100.672
106.413
112.193
118.009
123.858
129.739
135.649
141.585
147.545
153.527
159.529
165.549
171.585
177.635
183.698
189.772
195.856
201.948
208.047
214.153
220.263
226.378
232.496
238.617
244.739
250.863
256.987
263.111
269.234
275.357
281.478
287.599
293.716
299.832
305.946
312.057
318.165
324.271
330.373
336.472
DO2 (г)
э@) = 712.000 кДж-моль
-364.3474
-177.2189
-115.3240
-114.5444
-83.0788
-64.1331
-51.4641
-42.3908
-35.5697
-30.2533
-25.9920
-22.4995
-19.5846
-17.1145
-14.9945
-13.1549
-11.5435
-10.1201
-8.8537
-7.7196
-6.6980
-5.7730
-4.9316
-4.1628
-3.4576
-2.8085
-2.2090
-1.6537
-1.1378
-!б572
-.2086
.2113
.6051
.9751
1.3235
1.6520
1.9624
2.2562
2.5345
2.7987
3.0497
3.2885
3.5161
3.7331
3.9403
4.1384
4.3280
4.5095
4.6836
4.8506
5.0110
5.1651
5.3134
5.4562
5.5937
5.7263
5.8543
5.9778
6.0971
6.2124
6.3240
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200 .
5300
5*00
5500
5600
5700
5800
5900
6000
о
ON
о
П-*
со
II
+
Л
00
•о
(Ч
00
о
г»
*$
со
о
о
о
jg
VO
<ч
00
со
*?
On
CS
со
1
Г
Таблица 28
i
§
§
v;
/S
X,
373
_;
и
о
о
О
Q
о
<
т
1
1
1
Й
со
+
X
12
•о
со
1
г-
«о
Tt
•о
т
А
5
о
' Т
ё
On
•о Т4
II ^
«о ^
00 ON
ON
о 5
о
<J
Я
О
о
о
NO
V
\у
V
8
«О
1
О
II
58

Класс точности
V-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
36.040
36.094
39.072
41.756
44.007
45.895
47.491
48.845
49.996
50.974
51.808
52.520
53.129
53.653
54.105
54.497
54.839
55.137
55.400
55.631
55.836
56.018
56.180
56.326
56.456
56.574
56.681
56.778
56.865
56.946
57.019
57.086
57.148
57.204
57.257
57.305
57.350
57.392
57.430
57.466
57.500
57.531
57.560
57.588
57.613
57.637
57.660
57.682
57.702
57.721
57.739
57.756
57.772
57.787
57.801
57.815
57.828
57.840
57.852
ОТРИЦАТЕЛЬНЫЙ ИОН
*V) = p(D).p
Ф°(Т)
Дж • К*~ * • моль"
193.940
194.149
204.000
211.878
218.527
224.327
229.498
234.181
238.470
242.435
246.125
249.580
252.830
255.900
258.810
261.576
264.214
266.734
269.147
271.462
273.687
275.830
277.895
279.889
281.815
283.680
285.487
287.238
288.938
290.589
292.195
293.758
295.279
296.762
298.207
299.617
300.994
302.339
303.654
304.939
306.197
307.428
308.633
309.814
310.972
312.106
313.219
314.312
315.384
316.436
317.470
318.486
319.484
320.466
321.431
322.380
323.315
324.234
325.139
2 (О) -р(е) р1
S°(T)
-1
227.748
227.971
238.763
247.778
• 255.597
262.526
268.762
274.436
279.644
284.456
288.928
293.103
297.018
300.702
304.180
307.472
310.597
313.570
316.405
319.113
321.706
324.192
326.580
328.876
331.088
333.221
335.280
337.271
339.198
341.063
342.873
344.628
346.333
347.991
349.603
351.172
352.701
354.192
355.645
357.064
358.449
359.802
361.125
362.419
363.685
364.924
366.138
367.327
368.493
369.635
370.756
371.856
372.936
373.996
375.038
376.061
377.067
378.055
379.028
ДИОКСИДА
(DO2") Aru
//VW/°@)
кДж • моль
10.080
10.147
13.905
17.950
22.242
26.740
31.411
36.230
41.173
46.223
51.363
56.581
61.864
67.204
72.592
78.023
83.490
88.989
94.516
100.068
105.641
111.234
116.844
122.470
128.109
133.761
139.424
145.097
150.779
156.469
162.168
167.873
173.585
179.302
185.025
190.753
196.486
202.223
207.964
213.709
219.458
225.209
230.964
236.721
242.481
248.244
254.009
259.776
265.545
271.316
277.089
282.864
288.640
294.418
300.197
305.978
311.760
317.544
323.328
ДЕЙТЕРИЯ
ро; (г)
э@) = 840.290 кДж- моль
-137.5304
-136.6055
-99.2444
-76.7071
-61.6078
-50.7728
-42.6111
-36.2368
-31.1172
-26.9126
-23.3959
-20.4096
-17.8411
-15.6076
-13.6468
-11.9111
-10.3633
-8.9741
-7.7200
-6.5819
-5.5440
-4.5937
-3.7199
-2.9137
-2.1673
-1.4742
-.8288
-.2261
.3379
.8671
1.3646
1.8332
2.2755
2.6937
3.0898
3.4655
3.8224
4.1620
4.4854
4.7940
5.0886
5.3704
5.6401
5.8985
6.1463
6.3843
6.6129
6.8329
7.0446
7.2486
7.4453
7.6351
7.8184
7.9954
8.1667
8.3324
8.4928
8.6482
8.7988
г
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
СО
+
1
н
•о
гч
+
,2
О
ОС
о
о
1О
On
КГ)
v©
00
as
СЧ
со
о
ь
Табли
Т
§
1 5
X О
ЁГ о
X О
^ со
5 ~
СЧ II
^ я
" 2
о 2
• с* и
? I
\ °w
§
к
го
СЧ
с*
н
ЧО
г»
VO
со
1
К
?
ца 29
т
ё
о
т
к
•о
и
о 5
СП
2
о
8
о
V
к.
V
8
1
о
К.
и
н
59

Класс точности
И-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.300
33.456
34.265
34.287
35.647
37.198
38.853
40.569
42.283
43.933
45.477
46.893
48.173
49.324
50.352
51.271
52.093
52.830
53.492
54.089
54.630
55.122
55.572
55.984
56.365
56.717
57.044
57.350
57.636
57.906
58.1*60
58.402
58.631
58.850
59.060
59.261
59.455
59.642
59.823
59.999
60.170
60.336
60.498
60.657
60.812
60.965
61.114
61.261
61.406
61.549
61.690
61.830
61.968
62.104
62.239
62.373
62.506
62.638
?2.770
62.900
63.030
К°(Т)= P2(D).
Ф°(Л
Дж • К • моль
128.555
151.530
164.822
165.028
174.688
182.283
188.593
194.029
198.832
203.156
207.104
210.748
214.140
217.319
220.315
223.151
225.847
228.417
230.874
233.229
235.491
237.668
239.766
241.792
243.750
245.645
247.482
249.264
250 995
252.677
254.314
255.908
257.461
258.975
260.453
261.896
263.306
264.684
266.032
2671352
268.643
269.909
271.149
272.365
273.558
274.729
275.878
277.007
278.115
279.205
280.276
281.329
282.365
283.385
284.388
285.376
286.349
287.307
288.251
289.182
290.099
ОКСИД ДИДЕЙТЕРИЯ D2O (г)
S°iT)
-1
161.635
184.743
198.227
198.439
208.482
216.601
223.528
229.645
235.175
240.251
244.961
249.363
253.499
257.401
261.095
264.601
267.936
271.117
274.156
277.064
279.853
282.530
285.105
287.585
289.975
292.283
294.514
296.673
298.764
300.791
302.759
304.670
306.528
308.335
310.095
311.810
313.482
315.114
316.707
318.263
319.784
321.272
322.728
324.153
325.549
326.918
328.260
329.575
330.867
332.134
333.379
334.602
335.804
336.986
338.148
339.291
340.416
341.524
342.614
343.688
344.747
1 а б л и ца 30
)) Д,#°@) = 932.647 кДж • моль 1
Н°{Т)-Н°@)
кДж • моль
lgK°(T)
3.308 -479.5998
6.643 -234.9016
9.960 -154.0712
10.023 -153.0536
13.517 -111.9997
17.159 -87.2948
20.961 -70.7798
24.931 -58.9535
29.074 -50.0632
33.386 -43.1337
37.857 -37.5792
42.477 -33.0266
47.231 -29.2265
52.107 -26.0063
57.092 -23.2423
62.174 -20.8439
67.343 -18.7428
72.590 -16.8869
77.907 -15.2356
83.286 -13.7568
88.723 -12.4246
94.211 -11.2184
99.746 -10.1211
105.324 -9.1184
110.942 -8.1987
116.596 -7.3520
122.284 -6.5700
128.004 -5.8456
133 753 -5 1725
139.531 -4.5455
145.334 -3.9601
151.162 -3.4122
157.014 -2.8983
162.888 -2.4153
168.784 -1.9606
174.700 -1.5318
180.636 -1.1266
186.591 -.7431
192.5$4 -.3798
198.555 -.0350
204.564 .2927
210.589 .6045
216.631 .9015
222.688 1.1848
228.762 1.4552
234.851 1.7137
240.955 1.9610
247.073 2.1979
253.207 2.4249
259.355 2.6427
265.516 2.8518
271.692 3.0528
277.883 3.2466
284.086 3.4320
290.303 3.6111
296.534 3.7838
302.778 3.9503
309.035 4.1109
315.306 4.2661
321.589 4.4160
327.885 4.5609
т
к
' 100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
А
^ о
| 2
л
§ а ^
• а? ё
^ о 2
ЁГ С5
о о ? Т
JS я 7 *
о :§ II *
S 7 2 5
» II «О ^
^ ?^ пг 00
1
f-Г <N ||
л4 г*4
Я. « «
е °« V
е
^ о
1н Т
*о л
О ,_|
+ 1
I© k 2
° «г я
оо *ъ ^
о *о
о «о V
d J3 ^
н + V
X + V
Д с* О
С^ ^ Т-ч
СО ^* _|
•4- 1 о
? ? "
S оо w
О4 00
II ¦+¦
60

Кла^ч: точности
IV С
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
Z,O\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
CpiT)
36.995
40.814
45.247
45.339
50.101
54.190
57.651
60.639
63.241
65.507
67.473
69.173
70.641
71.913
73.016
73.978
74.822
75.566
76.227
76.817
77.348
77.829
78.266
78.668
79.038
79.381
79.702
80.002
80.284
80.552
80.806
81.048
81.280
81.503
81.718
81.925
82.126
82.322
82.512
82.698
82.879
83.057
83.232
83.403
83.572
83.738
83.902
84.064
84.224
84.382
84.539
84.694
84.848
85.001
85.153
85.303
85.453
85.602
85.750
85.898
86.045
А-(Л=р'в».
Ф°G)
_ i
Дж • К • моль
163.527
188.147
203.193
203.433
214.905
224.308
232.389
239.537
245.983
251.876
257.319
262.387
267.134
271.604
275.831
279.842
283.660
287.304
290.790
294.132
297.343
300.431
303.408
306.280
309.056
311.741
314.342
316.864
319.311
321*688
324.000
326.249
328.440
330.575
332.657
334.688
336.672
338.610
340.505
342.358
344.172
345.947
347.687
349.391
351.062
352.701
354.309
355.888
357.438
358.961
ЗбЬ.457
361.928
363.374
364.796
366.196
367.573
368.928
370.263
371.578
372.873
374.149
ДИОКСИД
Р2(О) Vac
-1
197.976
224.892
241.975
242.255
255.963
267.595
277.789
286.906
295.177
302.760
309.766
316.278
322.361
328.067
333.438
338.509
343.311
347.870
352.208
356.346
360.300
364.085
367.716
371.204
374.560
377.794
380.913
383.927
386 841
389.664
392,399
395.052
397.629
400.134
402.570
404.942
407.253
409.505
411.703
413.849
415.945
417.994
419.997
421.958
423.877
425.757
427.599
429.405
431.177
432.915
434.621
436.297
437.943
439.561
441.151
442.715
444.254
445.767
447.257
448.724
450.169
ДИДЕЙТЕРИЯ
2°2> V
//Yn-//°«o)
кДж • моль
3.445
7.349
11.563
11.647
16.423
21.643
27.240
33.158
39.355
45.795
52.446
59.281
66.273
73.402
80.650
88.001
95.442
} 02.962
110.552
118.205
125.914
133.673
141.478
149.325
157.211
165.132
173.086
181.071
189.086
197.128
205.196
213.288
221.405
229.544
237.705
245.887
254.090
262.312
270.554
278.815
287.093
295.390
303.705
312.036
320.385
328.751
337.133
345.531
353.945
362.376
370.822
379.284
387.761
396.253
404.761
413.284
421.821
430.374
438.942
447.524
456.121
D2O2 (г)
"@) = 1071
о
-548.1650
-266.3984
-173.2240
-172.0506
-124.6973
-96.1936
-77.1384
-63.4946
-53.2401
-45.2496
-38.8467
-33.6004
-29.2228
-25.5145
-22.3326
-19.5724
-17.1552
-15.0207
-13.1221
-11.4223
-9.8916
-8.5059
-7.2456
-6.0944
-5.0387
-4.0670
-3.1698
-2.3388
. 1.5669
-!в481
-.1770
.4510
1.0398
1.5931
2.1139
2.6050
3.0690
3.5079
3.9238
4.3184
4.6933
5.0500
5.3897
5.7136
6.0229
6.3184
6.6012
6.8719
7.1313
7.3802
7.6191
7.8487
8.0694
8.2819
8.4864
8.6836
8.8737
9.0571
9.2343
9.4054
9.5708
.792 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
9G0
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
§
сч
о
VO
го
II
+
1
OS
V©
с*
VO
+
©1
00
о
1
S
i
00
•о
00
•о
«о
«¦н
о
с*
го
II
с
о
Таблица 31
i
Й
т 1
А
о X ^
s 9 '
Дж-
300]
М0Л1
00 |,
2 Л X
II 1Л» &*
" v> i—
° Os °°'
О w Й
N О ° «
Q с» СО
о" &
, О
А
§
т
* 2
* §
| V
? V
м о
х о
V© «О
S
<N |
^ 2
^г II
О) *
г»
61

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
АЛЛА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.286
29.186
29.200
29.201
29.230
29.282
29.393
29.592
29.887
30.266
30.705
31.179
31.669
32.159
32.636
33.095
33.532
33.944
34.333
34.697
35.040
35.362
35.664
35.950
36.219
36.475
36.718
36.951
37.173
37.388
37.594
37.795
37.990
38.180
38.367
38.550
38.730
38.908
39.084
39.258
39.430
39.600
39.769
39.936
40.100
40.262
40.421
40.577
40.730
40.878
41.021
41.160
41.293
41.419
41.539
41.652
41.757
41.854
41.942
42.022
42.092
Л'°(Г) = р(Н),
Ф°(Т)
Дж • К • моль
84.558
103.817
115.152
115.329
123.565
129.984
135.246
139.707
143.584
147.015
150.097
152.898
155.469
157.848
160.063
162.139
164.093
165.941
167.694
169.363
170.957
172.482
173.945
175.352
176.706
178.012
179.274
180.495
101 ATft
1 01 «Of О
182.824
183.938
185.020
186.072
187.097
188.095
189.069
190.019
190.947
191.853
192.740
193.607
194.456
195.288
196.103
196.902
197.686
198.455
199.210
199.952
200.680
201.396
202.101
202.793
203.475
204.146
204.806
205.456
206.097
206.728
207.350
207.963
ПРОТОДЕЙТЕРИЙ HD (г)
о (D) • р'1 (HD)
S°(T)
-1
111.786
132.035
143.690
143.871
152.275
158.802
164.150
168.694
172.664
176.205
179.416
182.365
185.099
187.653
190.054
192.321
194.471
196.517
198.468
200.334
202.123
203.840
205.492
207.084
208.620
210.104
211.539
212.929
214.277
215.585
216.856
218.092
219.295
220.467
221.610
222.724
223.813
224.877
225.917
226.934
227.930
228.906
229.862
230.800
231.720
232.623
233.510
234.381
235.236
236.078
236.905
237.719
238.519
239.307
240.082
240.846
241.597
242.337
243.066
243.784
244.490
Ar//°@) = 435.510 кДж • моль
//°(П-//°«»
кДж • моль
2.723 -224.0208
5.644 -109.7796
8.509 -72.0612
8.563 -71.5865
11.484 -52.4350
14.409 -40.9115
17.342 -33.2076
20.291 -27.6897
23.264 -23.5400
26.271 -20.3040
29.319 -17.7086
32.413 -15.5799
35.556 -13.8019
38.747 -12.2941
41.987 -10.9989
45;274 -9.8743
48.605 -8.8884
51.979 -8.0169
55.393 -7.2409
58.845 -6.5456
62.332 -5.9188
65.852 -5.3509
69.404 -4.8339
72.985 -4.3613
76.593 -3.9275
80.228 -3.5279
83.888 -3.1587
87.571 -2.8165
At сто о AQP.4.
95.006 -2.2019
98.755 -1.9250
102.524 -1.6657
106.314 -1.4224
110.122 -1.1937
113.950 -.9783
117.796 -.7750
121.660 -.5829
125.542 -.4011
129.441 -.2287
133.358 -.0651
137.293 .0904
141.244 .2383
145.213 .3793
149.198 .5138
153.200 .6422
157.218 .7650
161.252 .8824
165.302 .9949
169.367
173.448
177.543
181.652
185.775
189.910
194.058
198.218
202.388
206.569
210.759
.1027
.2061
.3054
.4009
1.4926
1.5809
.6660
.7479
.8269
.9032
.9768
214.957 2.0479
219.163 2.1166
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
OfiAA
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 32
Т
л • о
. § * *
• 1
i i § ?
s а ? 5
^ Я ^ о
1| о & ?
^ II *^ Tt
s 2 ^
* и: о?
S3 Q Ьо
+
оо к
г*** о
о S
со
т
I й *
q R v
° 6 к
g 7 v
2 5
+ ' Т
гч <^"> и
^ о ъ
о ^ w
<Ч
Till +
о
62

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р{Т)
ПРОТОДЕЙТЕРИЙ HD (г)
Ф°G)
S°(T)
Дж К-моль
42.204
42.277
42.309
42.300
4^.251
42.163
42.037
41.876
41.681
41.456
41.203
40.924
40.624
40.305
39.969
39.619
39.258
38.888
38.511
38.129
37.166
36.208
35.273
34.373
33.516
32.707
31.947
31.237
30.576
29.963
29.393
28.866
28.378
27.927
27.509
27.123
26.765
26.433
26.125
25.840
209.164 245.872
210.332 247.214
211.470 248.515
212.578 249.778
213.658 251.004
214.712 252.193
215.741 253.347
216.745 254.465
217.726 255.551
218.685 256.603
219.623 257.624
220.539 258.613
221.436 259.573
222.313 260.503
223.172 261.405
224.013 262.280
224.836 263.128
225.642 263.951
226.432 264.749
227.207 265.523
229.075 267.360
230.855 269.067
232.551 ' 270.655
234.170 272.138
235.717 273.523
237.196 274.822
238.612 276.042
239.970 277.191
241.272 278.275
242.523 279.301
243.725 280.274
244.882 281.199
245.996 282.080
247.070 282.920
248.106 283.724
249.106 284.493
250.072 285.231
251.007 285.941
251.911 286.623
252.787 287.281
Я*(Л-Я*@)
кДж * моль
227.593
236.042
244.501
252.963
261.419
269.861
278.281
286.673
295.029
303.344
311.610
319.823
327.978
336.071
344.099
352.058
359.945
367.760
375.500
383.164
401.988
420.331
438.200
455.611
472.581
489.135*
505.296
521.091
536.542
551.675
566.512
581.075
595.385
609.460
623.317
636.974
650.445
663.743
676.882
689.872
2.2474
2.3700
2.4851
2.5934
2.6955
2.7919
2.8831
2.9694
3.0513
3.1291
3.2031
3.2736
3.3409
3.4051
3.4665
3.5252
3.5815
3.6355
3.6874
3.7373
3.8539
3.9605
4.0583
4.1486
4.2323
4.3102
4.3829
4.4512
4.5154
4.5760
4.6333
4.6877
4.7394
4.7887
4.8358
4,8808
4.9240
4.9654
5.0053
5.0437
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
О
Таблица 32
(окончание)
! т-
t 5
о
г
«с
V?
1
i й s
2 пн §
О ^О CN
>
. ^ v
5 + *•"
3 ™» V
i я 1
со *""! —I
с
О\ <—> ^
О> го
^ О\
ю «г ^
О -ч II
<N ГО
1
Р
О
и
63

Класс точности
Н-В
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯОО
4,O\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.302
33.370
33.798
33.811
34.788
36.068
37.482
38,959
40.45$
41.933
43.360
44.714
45.980
47.152
48.230
49.217
50.119
50.942
51.694
52.381
53.010
53.587
54.118
54.607
55.061
55.481
55.873
56.238
56.581
56^903
57.206
57.493
57.765
58.023
58.269
58.505
58.730
58.947
59.155
59.356
59.551
59.739
59.922
60.099
60.273
60.441
60.606
60.768
60.926
61.081
61.234
61.384
61.532
61.677
61.821
61.963
62.103
62.242
62.379
62.515
62.650
Л'°(Г) = р(Н) -i
Ф°G)
Дж • К • моль
129.907
152.848
166.113
166.318
175.926
183;448
189.671
195.012
199.716
203.937
207.780
211.320
214.608
217.685
220.582
223.322
225.925
228.407
230.779
233.052
235.236
237.338
239.365
241.323
243.217
245.051
246.829
248.555
250.232
251.864
253.452
254.999
256.507
257.978
259.415
260.819
262.191
263.533
264.846
266.132
267.392
268.626
269.836
271.024
272.189
273.332
274.456
275.559
276.644
277.710
278.758
279.789
280.804
281.803
282.786
283.754
284.708
285.648
286.574
287.488
288.388
ОКСИД ПРОТОДЕЙТЕРИЯ
o(D) p(O) •
S°(T)
-1
162.921
186.018
199.403
199.612
209.463
217.359
224.059
229.947
235.247
240.098
244.590
248.787
252.732
256.460
259.994
263.356
266.561
269.625
272.558
275.372
278.075
280.676
283.181
285.597
287.931
290.187
292.371
294.487
296 538
ш0 ч/ V» l/l/V/
298.529
300.464
302.344
304.174
305.955
307.691
309.384
311.035
312.647
314.222
315.761
317.266
318.739
320.181
321.593
322.976
324.333
325.663
326.968
328.249
329.507
330.743
331.957
333.150
334.324
335.478
336.613
337.731
338.832
339.916
340.983
342.035
р'1 (HDO) АгН
И°(Т)-Н°@)
кДж • моль
3.301
6.634
9.926
9.988
13.415
16.956
20.632
24.454
28.425
32.545
36.810
41.214
45.750
50.407
55.177
60.050
65.018
70.071
75.204
, 80.408
85.678
91.008
96.394
101.830
107.314
112.841
118.409
124.015
129.656
135.330
141.036
146.771
152.534
158.323
164.138
169.977
175.839
181.723
187.628
193.553
199.499
205.463
211.446
217.447
223.466
229.502
235.554
241.623
247.708
253.808
259.924
266.055
272.200
278.361
284.536
290.725
296.928
303.146
309.377
315.621
321.880
HDO (г)
°@) = 924.960 кДж-моль
-476.1059 *
-233.4138
-153.2428
-152.2336
-111.5115
-87.0035
-70.6178
-58.8822
-50.0583
-43.1792
-37.6640
-33.1423
-29.3673
-26.1675
-23.4204
-21.0360
-18.9469
-17.1011
-15.4585
-13.9871
-12.6615
-11.4609
-10.3686
-9.3703
-8.4545
-7.6113
-6.8324
-6.1108
-5.4402
-4.8155
-4.2321
-3.6861
-3.1739
-2.6925
-2.2393
-1.8117
^1.4077
-1.0254
-.6631
-.3192
.0076
.3185
.6148
.8973
1.1671
1.4250
1.6717
1.9080
2.1345
2.3518
2.5605
2.7610
2.9539
3.1395
3.3182
3.4905
3.6567
3.8171
3.9720
4.1216
4.2663
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
<ч
о
ON
и
'^
CN
«О
00
о
о
4-
м
'К
<N
8
О
1
JS
со
00
+
г»
•е-
Та б
i
л
о
.
VO
СО
со
CS
II
с
в
?
о
<
т
А
2
Т
к
со
Н
ю
об
+
X
со
1
«о
со
чо
V©
л и
1
к
•-Ч
О
<N
«О
II
Я
ю
об
8
?
о
ца 33
i
Т
*?
»о
о
О 05!
2
о
о
S
V
V
о
о
1
о
II
н
64

Класс точности
IV-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1 1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛП
лоии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
36.047
39.824
43.790
43.872
48.273
52.221
55.587
58.462
60.950
63.124
65.034
66.717
68.206
69.525
70.696
71.740
72.673
73.511
74.266
74.949
75.569
76.136
76.656
пли
77.576
77.987
78.370
78.728
79.065
79.382
79.683
79.968
80.239
80.498
80.747
80.985
81.215
81.437
81.651
81.859
82.060
82.257
82.448
82.635
82.81V
82.996
83.171
83.343
83.512
83.678
83.842
84.003
84.162
84.319
84.475
84.628
84.780
84.931
85.080
85.228
85.374
ДИОКСИД ПГОТОДЕЙТЕРИЯ HDO2 (г)
К°(Т)= р(Н) •
Ф°(Т)
Дж • К • моль
166.299
190.658
205.443
205.678
216.896
226.056
233.909
240.844
247.092
252.799
258.067
262.969
267.559
271.881
275.968
279.846
283.539
287.065
290.439
293.676
296.786
299.779
302.666
305.453
308.147
310.756
313.283
315.735
О 1 О 1 1 А
О 1 О. I 1 U
320.431
322.682
324.873
327.009
329.091
331.122
333.105
335.042
336.935
338.787
340.599
342.372
344.110
345.812
347.481
349.117
350.723
352.299
353.846
355.366
356.859
358.327
359.770
361.189
362.685
363^959
365.312
366.643
367.955
369.247
370.520
371.774
p(D) -р2 (О) ч
S°(T)
-1
200.606
226.846
243.455
243.726
256.955
268.161
277.988
286.779
294.751
302.059
308.810
315.089
320.960
326.472
331.668
336.582
341.242
345.673
349.897
353.931
357.791
361.492
365.047
368.464
371.757
374.932
377.998
380.963
386.612
389.308
391.926
394.469
396.942
399.349
401.693
403.978
406.206
408.381
410.504
412.579
414.608
416.592
418.535
420.437
422.300
424.126
425.916
427.673
429.396
431.089
432.751
434.383
435.988
437.566
439.117
440.643
442.145
443.624
445.079
446.513
0-X(HDO2) Arl/
#°G')_tf°@)
кДж • моль
3.431
7.238
11.333
11.414
16.023
21.053
26.448
32.154
38.127
44.334
50.743
57.333
64.080
70.968
77.980
85.103
92.325
99.635
107.024
114.485
122.012
129.598
137.237
144.927
152.663
160.441
168.259
176.114
I Ot.Uut
191.927
199.880
207.863
215.873
223.910
231.972
240.059
248.169
256.302
264.456
272.632
280.828
289.044
297.279
305.533
313.806
322.096
330.405
338.730
347.073
355.433
363.809
372.201
380.609
389.033
397.473
405.928
414.399
422.884
431.385
439.900
448.430
Т j-k C^ TY (Ж VI f\ ^ Jk
1 аолица 34
э@) = 1063.800 кДж • моль 1
lgK°(T)
-544.5861
-264.8933
-172.3923
-171.2272
-124.2086
-95.9009
-76.9729
-63.4174
-53.2272
-45.2849
-38.9193
-33.7022
-29.3481
-25.6587
-22.4925
-19.7452
-17.3389
-15.2136
-13.3228
-11.6297
-10.1047
-8.7240
-7.4680
-6.3206
-5.2682
-4.2995
-3.4049
-2.5762
-1.8064
-L0893
-.4199
.2066
.7941
1.3462
1.8659
2.3561
2.8191
3.2573
3.6724
4.0664
4.4407
4.7968
5.1361
5.4596
5.7685
6.0636
6.3460
6.6164
6.8756
7.1242
7.3629
7.5923
7.8129
8.0252
8.2296
8.4267
8.6167
8.8000
8.9771
9.1481
9.3135
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
т 1
* * i
^ О
О о> ^ |
оо со *~* Ь?
8 5 ' •
•—n СО 11 1x2
О ^ " Я
^ 1 О ^
СО ' Л
11 1/1 CN
11 ^ 2 Я
^ ° об in
с й *~*
о" Ч "
S о" »«
5 а *
X
* о
< ->
+
X 1
5? §
V ' ^^
О ^ V
о н i;
° п 2
<N " о
н + V
« д §
КГ) чо О
+ ' ^
^ * к.
оч СО ^*"
оо «п "
^ °°. н
со оо
о
65

Класс точности
I
ТРИТИЙ Т (г)
Таблица 35
Ф°(Л
S°{T)
Дж К
кДж * моль
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400"
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600*
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786.
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
84.782
99.190
107.489
107.618
113.598
118.236
122.026
125.230
128.005
130.454
132.644
134.625
136.433
138.097
139.638
141.072
142.413
143.673
144.861
145.985
147.051
148.066
149.033
149.957
150.841
151.690
152.505
153.289
154.045
154.775
155.480
156.161
156.821
157.461
158.081
158.684
159.269
159.839
160.393
160.933
161.459
161.973
162.473
162.963
163.440
163.908
164.364
164.811
165.249
165.678
166.098
166.509
166.913
167.309
167.697
168.079
168.453
168.821
169.183
169.538
169.887
105.568
119.976
128.275
128.404
134.384
139.022
142.812
146.016
148.791
151.240
153.430
155.411
157.219
158.883
160.424
161.858
163.199
164.459
165.647
166.771
167.837
168.852
169.819
170.743
171.627
172.476
173.291
174.075
174.831
175.561
176.265
176.947
177.607
178.247
178.867
179.470
180.055
180.625
181.179
181.719
182.245
182.759
183.259
183.748
184.226
184.693
185.150
185.597
186.035
186.464
186.884
187.295
187.699
188.095
188.483
188.865
189,239
189.607
189.968
190.324
190.673
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
8
ЧО
О
со
II
I
-ц II
О
Ь
о
00
сч
и
ь
п
о *
со
I
V
V
¦8
о
00
66

ТРИТИЙ Т (г)
Таблица 35
(окончание)
С°р (Г)
S° (Г)
К"
Дж К" -моль

Яо(Г)-Я°@)
кДж * моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
. 13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
170.569
171.229
171.868
172.489
173.091
173.677
174.246
174.801
175.341
175.867
176.380
176.881
177.370
177.848
178.315
178.772
179.219
179.657
180.085
180.505
181.519
182.486
183.410
184.295
185.144
185.959
186.743
187.499
188.228
188.933
189.615
190.275
190.914
191.535
192.137
192.723
193.292
193.847
194.387
194.913
191.355
192.015
192.654
193.275
193.877
194.463
195.032
195.587
196.127
196.653
197.166
197.667
198.156
198.634
199.101
199.558
200.005
200.443
200.871
201.291
202.305
203.272
204.196
205.081
205.929
206.745
207.529
208.285
209.015
209.719
210.401
211.061
211.700
212.321
212.924
213.509
214.079
214.633
215.173
215.699
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
67

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800.
4900
5000.
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°}(Т)
28.762
29.164
29.199
29.200
29.316
29.610
30.098
30.721
31.404
32.089
32.742
33.346
33.895
34.391
34.837
35.237
35.599
35.926
36.225
36.497
36.749
36.981
37.198
37.402
37.594
37.777
37.952
38.119
OQ ООО
38.439
38.593
38.744
38.892
39.039
39.185
39.330
39.475
39.619
39.764
39.909
40.053
40.198
40.342
40.487
40.630
40.772
40.9 U
41.051
41.188
41.321
41.450
41.575
41.696
41.811
41.920
42.022
42.118
42.206
42.286
42.358
42.421'
К°(Т)=р2(Т) •
Ф°(Л
Дж • К • моль
93.052
112.840
124.341
124.520
132.840
139.315
144.625
149.137
153.072
156.570
159.725
162.604
165.257
167.718
170.018
172.176
174.212
176.139
177.970
179.713
181.379
182.973
184.503
185.973
187.388
188.753
190.071
191.345
1Q2 S7Q
I 9a<wi 9
193.775
194.935
196.062
197.158
198.224
199.262
200.273
201.260
202.223
203.164
204.083
204.981
2О5.?61
206.722
207.565
208.391
209.201
209.995
210.775
211.540
212.292
213.030
213.756
214.469
215.171
215.861
216.541
217.209
217.868
218.516
219.155
219.785
дитритий т2
р'1 (т2)
121.416
141.566
153.217
153.397
161.810
168.380
173.819
178.504
182.650
186.389
189.804
192.953
195.879
198.612
201.177
203.594
205.880
208.048
210.111
212.077
213.955
215.754
217.479
219.137
220.733
222.272
223.757
225.192
226.581
227.928
229.233
230.501
231.734
232.933
234.100
235.238
236.348
237.432
238.490
239.525
240.537
241.528
242.498
243.449
244.382
245.296
246.194
247.076
247.941
248.792
249.628
250.450
251.259
252.054
252.836
253.607
254.365
255.111
255.846
256.569
257.281
Д
//°(Л-//°<(
кДж • моль
2.836
5.745
8.609
8.663
11.588
14.533
17.516
20.557
23.663
26.837
30.079
33.384
36.747
40.161
43.623
47.127
50.669
54.246
57.854
61.490
65.152
68.839
72.548
76.278
80.028
83.797
87.583
91.387
95.207
99.043
102.895
106.762
110.643
114.540
118.451
122.377
126.317
130.272
134.241
138.225
142.223
146.236
150.263
154.304
158.360
162.430
166.514
170.612
174.724
178.850
182.988
187.140
191.303
195.479
199.665
203.862
208.069
212.286
216.510
220.743
224.982
(г)
г//°@) = 442.958
))
1
\о К°(Т\
1К ль. \ 1 )
-227.3778
-111.2191
-72.8690
-72.3864
-52.9151
-41.2000
-33.3690
-27.7610
-23.5449
-20.2583
-17.6235
-15.4635
-13.6603
•12.1319
-10.8198
. -9.6809
-8.6831
-7.8015
-7.0168
-6.3140
-5.6807
-5.1071
-4.5852
-* Ю82
-3.6706
-3.2676
-2.6953
-2.5503
-2.2297
-1.9311
-1.6521
-1.3910
-1.1460
-.9158
-.6990
-.4944
-.3012
-.1183
.0551
.2196
.3760
.5247
.6664
.8016
.9307
1.0540
J.1720
1.2850
1.3933
1.4972
1.5970
1.6928
1.7849
1.8736
1.9590
2.0412
2.1206
2.1971
2.2710
2.3423
2.4113
кДж • моль
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
9'rt)
2200
2300
2400
2500
2600
2700
2800
2900
30Q0
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
s
II
+
Т
х
r—i
VD
т—1
О
+
о
8
о
1
1
а
го
г-
VO
<ч
чо
о
<ч
О\
*—1
о
ь
Таблица 36
Т
§
i
и ^-
° 2 К
° об """'
ON "
о tT о 05
Н со
ч^ о
т
О
1
« 1
§ V
+ V
N о
•о ?
|
X ^
со
»-¦ II
щ ^<
68

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р(Т)
42.520
42.581
42.603
42.585
42.527
42.431
42.297
42.129
41.927
41.696
41.436
41.152
40.845
40.519
40.177
39.822
39.455
39.079
38.696
38.309
37.332
36.361
35.413
34.532
33.654
32.814
32.045
31.327
30.658
30.038
29.462
28.929
28.436
27.980
27.558
27.168
26.806
26.471
26.161
25.873
Ф°G)
Дж К • моль
221.017
222.215
223.380
224.516
225.622
226.700
227.752
228.779
229.781
230.760
231.717
232.652
233.567
234.462
235.337
236.194
237.032
237.854
238.658
239.446
241.347
243.157
244.881
246.525
248.096
249.597
251.034
252.411
253.732
254.999
256.217
257.389
258.517
259.604
260.653
261.665
262.643
263.588
264.503
265.389
ДИТРИТИЙ
5° G)
-1
258.674
260.025
261.336
262.608
263.841
265.038
266.199
267.325
268.416
269.475
270.502
271.497
272.461
273.397
274.304
275.183
276.035
276.862
277.664
278.442
280.287
282.001
283.597
285.084
286.475
287.778
289.002
290.154
291.242
292.270
293.246
294.173
295.055
295.897
296.702
297.473
298.213
298.923
299.606
300.265
Т2(г)
Я°(Л-Я°@)
кДж * моль
233.477
241.987
250.507
259.026
267.537
276.034
284.508
292.951
301.357
309.719
318.033
326.292
334.492
342.629
350.699
358.699
366.627
374.480
382.258
389.958
408.869
427.291
445.234
462.711
479.743
496.353
512.566
528.407
543.901
559.073
573.946
588.542
602.882
616.985
630.868
644.548
658.040
671.359
684.516
697.523
ig*°m
2.5425
2.6655
2.7810
2.8896
2.9920
3.0887
3.1801
3.2667
3.3488
3.4268
3.5009
3.5716
3.6390
3.7033
3.7648
3.8237
3.8801
3.9342
3.9861
4.0361
4.1529
4.2595
4.3575
4.4478
4.5315
4.6095
4.6823
4.7505
4.8148
4.8754
4.9327
4.9871
5.0388
5.0881
5.1351
5.1802
5.2233
5.2648
5.3046
5.3430
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 36
(окончание)
+
on ?
г- °
о
1, Т
X /-~"
я « §
1 ° w
О го \у
X + **•
Я | о
2 8 8
чб О г-,
<*^ '""' .л
+ 1 f
^ н о
^ 1О гН
Г- Г-
О ОО г
о ^
<N 00 И
II + w
g
О
69

Класс точности
I-B
Т
К
100
200
29$. 1$
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
32.304
30.683
29.970
29.963
29.813
30.063
30.588
31.251
31.949
32.622
33.241
33.798
34.291
34.727
35.112
35.452
35.754
36.025
36.268
36.488
36.688
36.872
37.042
37.200
37.348
37.488
37.620
37.746
37.868
37.985
38.098
38.208
38.316
38.422
38.526
38.628
38.730
38.830
38.929
39.027
39.124
39.219
39.313
39.405
39.495
39.582
39.667
39.749
39.828
39.903
39.973
40.040
40.101
40.158
40.209
40.254
40.293
40.326
40.353
40.373
40.386
К°(Т)- р(Т) •
Ф°(Л
Дж • К« • моль
129.635
150.538
162.703
162.891
171.620
178.364
183.870
188.535
192.593
196.194
199.437
202.394
205.114
207.636
209.988
212.194
214.272
216.237
218.101
219.876
221.569
223.188
224.740
226.230
227.663
229.044
230.376
231.663
232 909
4M^4f* w ^/ %0
234.115
235.284
236.419
237.521
238.593
239.636
240.652
241.642
242.608
243.550
244.470
245.370
246.249
247.109
247.952
248.776
249.584
250.376
251.152
251.914
252.662
253.396
254.117
254.825
255.521
256.205
256.878
257.540
258.192
258.833
259.464
260.086
ОКСИД
р(О) р^СТО)
s°m
-х
Г59.157
181.021
193.115
193.300
201.889
208.562
214.086
218.850
223.069
226.871
230.341
233.536
236.498
239.260
241.848
244.283
246.580
248.756
250.822
252.789
254.666
256.460
258.180
259.830
261.416
262.944
264.417
265.839
267.214
268.545
269.834
271.085
272.300
273.481
274.629
275.748
276.837
277.900
278.936
279.949
280.938
281.905
282.852
283.778
284.685
285.573
286.444
287.298
288.136
288.958
289.765
290.557
291.335
292.100
292.851
293.589
294.315
295.028
295.730
296.420
297.098
ТРИТИЯ ТО
V
//Vb*/e<o>
кДж * моль
2.952
6.097
9.067
9.123
12.108
15.099
18.130
21.221
24.381
27.610
30.903
34.256
37.661
41.112
44.605
48.133
51.694
55.283
58.898
62.536
66.195
69.873
73.569
77.281
81.008
84.750
88.506
92.274
96.055
99.847
103.652
107.467
111.293
115.130
118.977
122.835
126.703
130.581
134.469
138.367
142.274
146.191
150.118
154.054
157.999
161 953
165.915
169.886
173.865
177.852
181.845
185.846
189.853
193.866
197.884
201.908
205.935
209.966
214.000
218.036
222.075
(г)
°@) = 432.320кДж- моль"*1
-222.2181 <
-108.8346
-71.3950
-70.9237
-51.9118
-40.4718
-32.8241
-27.3474
-23.2298
-20.0202
-17.4471
-15.3379
-13.5771
-12.0847
-10.8035
-9.6915
-8.7171
-7.8563
-7.0901
-6.4038
-5.7854
-5.2253
-4.7155
-4.2497
-3.8222
-3.4285
-3.0648
-2.7278
•2.4145
-2.1226
-1.8500
-1.5947
-1.3552
-1.1300
-.9179
-.7178
-.5287
-.3497
-.1800
-.0189
.1343
.2801
.4190
.5516
.6782
.7993
.9151
1.0261
1.1325
1.2347
1.3328
1.4271
1.5179
1.6053
1.6894
1.7706
1.8489
1.9245
1.9976
2.0682
2.1365
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5600
5600
5700
5800
5900
6000
«о
rf
«о
т—1
•О
ON
*"¦'
II
ЧО
ЧС
О
сч
ЧО
го
8
О
го
,•4
го
ON
<N
О
О
On
ЧО
СЧ
II
Ь
Т а б л и
i
А
2
Й
X
О)
го
о
С
О
Ь
о
<**
1
А
С!
d
о
ЧО
ON
Г*
Н
О
чо
|
О

ON
сч
т
А
§
•
X
ЧО
го
ЧО
го
II
Я
«о
об
ON
сч
и
о
ь
о
ца37
А
§
i
00
ON
•о
II
о 5
«о
о
о
о
чО
V
v
8
</*)
1
о
э
II
70

Класс точности
Ш-В
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
,3700
3800
3900
4000
4100 ф
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-
33.298
33.656
34.958
34.988
36.77р
38.716
40.746
42.758
44.656
46.385
47.923
49.276
50.458
51.490
52.391
53.182
53.878
54.495
55.044
55.536
55.980
56.382
56.749
57.086
57.397
57.685
57.953
58.204
58.441
58.664
58.876
59.078
59.271
59.457
59.635
59.807
59.973
60.135
60.292
60.445
60.594
60.741
60.884
61.025
61.164
61.300
61.435
61.568
61.699
61.829
61.958
62.085
62.212
62.338
62.462
62.587
62.710
62.833
62.955
63.077
63.199
К°(Т) = р2(Т)
Ф°(Л
Дж • К*" * • моль"
134.193
157.203
170.539
170.747
180.486
188.184
194.614
200.180
205.119
209.582
213.669
217.448
220.971
224.276
227.391
230.341
233.144
235.815
238.368
240.813
243.159
245.416
247.589
249.685
251.711
253.670
255.567
257.406
259.190
260.924
262.610
264.250
265.847
267.403
268.921
270.402
271.849
273.262
274.644
275.995
277.318
278.613
279.882
281.125
282.344
283.540
284.714
285.866
286.997
288.109
289.201
290.274
291.330
292.368
293.390
294.396
295.386
296.361
297.321
298.267
299.200
ОКСИД ДИТРИТИЯ
р(О) •p^CTjO)
-1
li
А
'°<У')-//°«
кДж - моль
167.334
190.476
204.132
204.348
214.652
223.064
230.302
236.735
242.570
247.931
252.900
257.532
261.871
265.952
269.801
273.443
276.898
280.184
283.314
286.304
289.164
291.905
294.536
297.067
299.503
301.852
304.120
306.312
308.432
310.487
312.480
314.413
316.292
318.119
319.897
321.628
323.315
324.960
326.566
328 Л 34
329.666
331.164
332.630
334.064
335.469
336.845
338.194
339.516
340.814
342.087
343.338
344.566
345.773
346.959
348.125
349.273
350.402
351.512
352606
353.684
354.745
3.314
6.655
10.016
10.080
13.666
17.440
21.413
25.588'
29.960
34.514
39.231
44.092
49.080
54.179
59.374
64.653
70.007
75.426
80.904.
86.433
92.009
97.628
103.285
108.977
114.701
120.455
126.237
132.045
137.878
143.733
149.610
155.508
161.426
167.362
173.317
179.289
185.278
191.283
197.305
203.341
209.393
215.460
221.542
227.637
233.747
239.870
246.007
252.157
258.320
264.496
270.686
276.888
283.103
289.330
295.570
30 i.823
308.088
314.365
320.654
326.956
333.269
Т2О (г)
г//°@) - 939
))
¦1
\оК°(Т\
-482.7440
-236.3598
-154.9760
-153.95 Щ
-112.6204
-87.7521
-71.1308
-59.2310
-50.2875
-43.3184
-37.7336
-33.1574
-29.3386
•26.1033
-23.3270
-20.9184
-18.8089
-16.9458
-15.2885
^ -13.8045
9 -12.4679
-11.2578
-10 1571
-9.1514
-8.229.1
•7.3802
•6.5961
-5.8698
-5.1951
-4.5666
-3.9799
-3.4307
-2.9157
-2.4318
-1.9762
-1.5465
-1.1405
-.7564
-.3924
-.0470
.2813
.5936
.8911
1.1748
1.4456
1.7045
1.9522
2.1894
2.4167
2.6348
2.8442
3.0454
3.2389
3.4251
3.6045
3.7773
3.9440
4.1049
4.2602
4.4103
4.5553
ЛЮкДж* мол!
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
>
о
•о
f—«
со
О
<N
1!
»/*>
rf
ON
О
00
о
+
'*
СО
ЧО
00
о
©
о
1
а
ЧО
*3"
00
'"¦?
On
со
+
ЧО
Tf
со
со
О
о.
CNJ
II
Ьч
%
Таблица 38
i
л
г*
т I
А 7
о * Т
s 1 §
X <г, I
3 Щ „•
5 « &
7 о -
¦I * S
О 00 •-«
ON
о * п
Н О со
о Н
^ С
Т
о
* §
S v
со ^
j. \/
т V
<ч О
х о
о «о
о
»О 1
ю о
1 
г-*
ЧО »%
о ~
71

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯП0
*оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.240
29.180
29.198
29.198
29.231
29.297
29.439
29.686
30.035
30.467
30.951
31.461
31.976
32.480
32.966
33.426
33.860
34.266
34.646
35.001
35.332
35.642
35.933
36.206
36.464
36.709
36.942
37.164
37.376
37.581
37.779
37.971
38.158
38.341
38.521
38.697
38.871
39.043
39.213
39.381
39.548
39.714
39.878
40.040
40.200
40.358
40.513
40.666
40.814
40.959
41.099
41.235
41.364
41.488
41.604
41.714
41.816
41.910
41.996
42.073
42Л40
К°(Т)= р(Т) -рО
Ф°(Т)
Дж • К • моль
88.889
108.254
119.623
119.799
128.052
134.481
139.751
144.219
148.102
151.540
154.630
157.440
160.020
162.408
164.634
166.720
168.684
170.543
172.306
173.986
175.589
177.124
178.597
180.012
181.376
182.690
183.961
185.189
186.380
187^534
188.654
189.743
190.802
191.833
192.838
193.817
194.773
195.706
196.618
197.510
198.382
199.236
200.072
200.892
201.695
202.483
203.256
204.015
204.761
205.493
206.213
206.920
207.616
208.301
208.975
209.639
210.292
210.935
211.569
212.194
212.810
ПРОТОТРИТИЙ НТ {
S°(T)
116.339
136.574
148.228
148.409
156.813
163.341
168 694
173.249
177.235
180.797
184.032
187.005
189.765
192.344
194.769
197.060
199.231
201.296
203.265
205.148
206.952
208.683
210.348
211.952
213.498
214.992
216.436
217.834
219.190
220.505
221.782
223.024
224.233
225 410
226.557
227.676
228.769
229.836
230.880
231.900
232.900
233.878
234.837
235.777
236.700
237.605
238.494
239.367
240.224
241.067
241.896
242.711
243.513
244.302
245.079
245.844
246.596
247.337
248.067
248.785
249.493
V
//V)-//°«»
кДж • моль
2.745
5.664
8.529
8.583
11.504
14.430
17.366
20.321
23.307
26.331
29.402
32.522
35.694
38.917
42.189
45.509
48.874
52.280
55.726
59.209
62.726
66.274
69.853
73.460
77.094
80.753
84.436
88.141
91.868
95.616
99.384
103.172
106.978
110.803
114.646
118.507
122.385
126.281
130.194
134.124
138.070
142.033
146.013
150.009
154.021
158.049
162.092
166.151
170.225
174.314
178.417
182.534
186.664
190.806
194.961
199.127
203.304
207.490
211.685
215.889
220.100
[г)
э@) = 436
о
-224.6474
-110.0801
-72.2542
-71.7781
-52.5722
-41.0161
-33.2905
-27.7570
-23.5959
-20.3510
-17.7486
-15.6144
-13.8318
-12.3203
-11.0220
-9.8948
-8.9066
-8.0333
-7.2557
-6.5589
-5.9309
-5.3619
-4.8440
-4.3705
-3.9360
-3.5358
-3.1660
-2.8232
-2.5046
-2.2078
-1.9304
-1.6708
-1.4272
-1.1981
-.9824
-.7789
-.5866
-.4046
-.2320
-.0683
.0874
.2355
.3767
.5113
.6398
.7627
.8802
.9928
.1007
.2042
.3036
.3991
.4910
.5794
.6645
.7465
.8256
1.9019
1.9755
2.0467
2.1155
.780 кДж • моль *
г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
180Q
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
со
СЧ
о
II
\
СЧ
СЧ
о
1
'к
СЧ
«о
СЧ
СЧ
о
о
о
3
со
о
со
VO
о
СЧ
с
о
ь
1 а б
1
1
со
о
II
о
я
о
<!
т
2
т
к
с*
тн
S
1—1
г»
н
о
on
1
й
ON
со
4-
л и
1
л
1
СЧ
о
II
я
оо
ON
СЧ
н
в
о
ц а 39
т
А
I
1
со
«¦н
II
с к
со
2
о
о
о
V
V
о
о
• •
1
о
II
><
72

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
42.247
42.314
42.341
42.327
42.273
42.181
42.050
41.885
41.686
41.457
41.200
40.919
40.616
40.294
39.955
39.603
39.240
38.868
38.489
38.106
37.141
36.181
35.245
34.345
33.488
32.679
31.920
31.211
30.551
29.938
29.370
28.843
28.357
27.906
27.490
27.104
26.747
26.416
26.110
25.825
ПРОТОТРИТИЙ НТ (г)
Ф°G)
Дж К~ • моль"
214.015
215.188
216.330
217.443
218.527
219.585
220.618
221.625
222.610
223.572
224.512
225.432
226.331
227.211
228.072
228.915
229.741
230.549
231.341
232.117
233.991
235.774
237.474
239.097
240.646
242.128
243.547
244.907
246.211
247.464
248.668
249.826
250.942
252.017
253.054
254.056
255.023
. 255.959
256.864
257.741
-1
#°(Г)-#°@)
кДж моль
250.876 228.539
252.219 236.996
253.522 245.462
254.785 253.929
256.012 262.390
257.201 270.836
258.355 279.260
259.475 287.654
260.560 296.011
261.613 304.326
262.633 312.592
263.623 320.805
264.582 328.959
265.512 337.050
266.414 345.075
267.288 353.031
268.136 360.916
268.958 368.726
269.756 376.462
270.529 384.122
272.365 402.933
274.071 42К263
275.659 439.119
277.139 456.514
278.524 473.470
279.821 490.010
281.040 506.157
282.188 521.938
283.272 537.376
284.297 552.496
285.269 567.321
286.193 581.873
287.073 596.171
287.913 610.236
288.716 624.083
289.485 637.730
290.223 651.192
290.931 664.482
291.613 677.612
292.271 690.595
2.2463
2.3690
2.4842
2.5926
2.6947
2.7912
2.8824
2.9688
3.0508
3.1286
3.2027
3.2732
3.3405
3.4047
3.4662
3.5250
3.5813
3,6354
3.6873
3.7372
3.8539
3.9605
4.0584
4.1488
4.2325
4.3105
4.3833
4.4516
4.5159
4.5765
4.6339
4.6883
4.7401
4.7894
4.8365
4.8816
4.9248
4.9663
5.0062
5.0446
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 39
(окончание)
+
^ .7
г*- е:
о
7
й к 2
<N ^ О
= "
° 2 v
S S 8
+ 1 ^
г- X 'о
00 СО _ч
V) On
00 1О г"
сч го ^
II + w
g
0
73

Класс точности
II-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.297
33.382
33.918
33.934
35.108
36.630
38.279
39.940
41.553
43.086
44.521
45.850
47.071
48.186
49.202
50.126
50.965
51.728
52.423
53.057
53.636
54.167
54.656
55.106
55.523
55.910
56.271
56.608
56.924
57.221
57.501
57.767
58.018
58.258
58.487
58.706
58.916
59.118
59.312
59.501
59.683
59.859
60.031
60.198
60.361
60.520
60.676
60.828
60.978
61.125
61.270
61.412
61.553
61.691
61.828
61.963
62.097
62.229
62.360
62.490
62.619
А'°(Л= р(Н) •
Ф°(Т)
Дж • К • моль
132.979
155.948
169.224
169.431
179.055
186.602
192.861
198.247
203.001
207.276
211.176
214.772
218.116
221.248
224.197
226.988
229.638
232.164
234.579
236.892
239.114
241.252
243.313
245.303
247.227
249.090
250.895
252.647
254.348
256.002
257.612
259.180
260.708
262.198
263.653
265.073
266.462
267.819
269.147
270.447
271.720
272.968
274.191
275.390
276.566
277.721
278.855
279.968
281.062
282.138
283.195
284.235
285.258
286.265
287.256
288.232
289.193
290.140
291.073
291.992
292.899
ОКСИД
р (Т) • р @)
S°(T)
-1
166.051
189.146
202.553
202.763
212.674
220.667
227.491
233.517
238.956
243.940
248.554
252.861
256.903
260.716
264.324
267.751
271.013
274.126
277.103
279.955
282.691
285,^21
287.852
290.292
292.646
294.921
297.120
299.251
301.315
303.318
305.263
307.152
308.990
310.780
312.522
314.221
315.877
317.494
319.073
320.617
322.125
323.601
325.046
326.460
327.846
329.204.
330.536
331.843
333.125
334.384
335.620
336.835
338.029
339.203
340.357
341.493
342.610
343.711
344.794
345.861
346.912
ПРОТОТРИТИЯ
V(hto) V/
//°(П-//°«))
кДж * моль
3.307
6.640
9.937
10.000
13.448
17.033
20.778
24.689
58.764
32.997
37.378
41.897
46.544
51.308
56.178
61.146
66.201
71.336
76.544
81.819
87.154
92.544
97.986
103.474
109.006
114.578
120.187
125.831
131.508
137.215
142.952
148.715
154.504
160.318
166.156
172.015
177.896
183.798
189.720
195.660
201.620
207.597
213.591
219.603
225.631
231.675
237.735
243.810
249.900
256.005
262.125
268.259
274.407
280.570
286.746
292.935
299.138
305.354
311.584
317.826
324.082
НТО (г)
°@) = 928.050 кДж- моль
IgAfV)
-477.6173
-234.1197
-153.6837
-152.6711
-111.8154
-87.2280
-70.7904
-59.0187
-50.1687
-43.2700
-37.7397
-33.2064
-29.4220
-26.2147
-23.4615
-21.0720
-18.9786
-17.1293
-15.4836
-14.0096
-12.6817
-11.4792
-10.3851
-9.3853
-8.4682
-7.6238
-6.8438
-6.1212
-5.4498
-4.8243
-4.2402
-3.6935
-3.1807
-2.6988
-2.2450
-1.8170
-1.4126
-1.0299
-.6672
-.3230
.0041
.3154
.6119
.8947
1.1648
1.4229
1.6699
1.9064
2.1331
2.3506
2.5595
2.7602
2.9532
3.1390
3.3179
3.4904
3.6567
3.8172
3.9722
4.1220
4.2668
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ю
со
СО
о
СЧ
II
+
¦к
О\
SO
ON
о
'к
SO
1—<
СЧ
1
О
8
rj-
со
+
00
со
сч
II
g
Т а б л и
7
л
а
о
X
•/¦>
Г-
со
7
и
о
*!
О
К
о
С!
§
7
00
СЧ
+
с*
X
со
so
1
со
SO
00
+
1
7
с;
О
д
ON
so
1
и
Я
00
ON
°1
8
X
0
ца 40
7
§
7
к
r-f
*—ч.
On
*"•
II
о et
со
S
V
V
§
Т.
i
о
0
II
74

Класс точности
1-Л
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.163
29.167
29.195
29.196
29.265
29.451
29.800
30.294
30.878
31.502
32.124
32.721
33.280
33.795
34.267
34.697
35.089
35.447
35.774
36.075
36.353
36.610
36.851
37.076
37.288
37.489
37.680
37.864
38.041
38.212
38.378
38.540
38.699
38.856
39.011
39.165
39.317
39.469
39.621
39.772
39.922
40.073
40.222
40.371
40.519
40.665
40.810
40.952
41.091
41.227
41.359
41.487
41.610
41.727
41.838
41.943
42.040
42.129
42.211
42.284
42.348
Ф°(Т)
Дж • К • моль
94.927
114.604
126.072
126.251
134.554
141.015
146.311
150.807
154.721
158.196
161.326
164.179
166.805
169.241
171.514
173.648
175.659
177.563
179.372
181.094
182.740
184.315
185.826
187.279
188.677
190.026
191.329
192.589
193.810
194.993
196.141
197.256
198.340
199.396
200.423
201.425
202.403
. 203.357
204.288
205.199
206.090
206.962
207.815
208.651
209.471
210.274
211.062
211.836
212.595
213.341
214.074
214.794
215.502
216.199
216.884
217.559
218.223
218.877
219.521
220.156
220.781
ДЕЙТЕРОТРИТИЙ DT
VP-'(DT)
S°iT)
123.018
143.230
154.880
155.061
163.468
170.015
175.413
180.042
184.125
187.798
191.149
194.239
197.111
199.795
202.317
204.696
206.948
209.086
211.122
213.064
214.922
216.702
218.410
220.054
221.636
223.162
224.636
226.062
227.442
228.780
230.078
231.339
232.565
233.759
234.921
236.054*
237.160
238.239
239.293
240.325
241.333
242.321
243.288
244.237
245.167
246.079
246.974
247.853
248.717
249.566
250.400
251.220
252.027
252.821
253.602
254.370
255.127
255.872
256.605
257.327
258.039
V
/Лл-/Ло)
кДж * моль
2.809
5.725
8.589
8.643
11.566
14.500
17.461
20.465
23.523
26.642
29.823
33.066
36.366
39.720
43.124
46.572
50.062
53.589
57.150
60.743
64.365
68.013
71.686
75.383
79.101
82.840
86.598
90.376
94.171
97.984
101.813
105.659
109.521
113.399
117.292
121.201
125.125
129.064
133.019
136.989
140.973
144.973
148.988
153.017
157.062
161.121
165.195
169.283
173.385
177.501
181.631
185.773
189.928
194.095
198.273
202.462
206.661
210.870
215.087
219.312
223.543
(г)
э@) = 441.197 кДж- моль
•226.8190
-111.1144
-72.9140
-72.4332
-53.0377
-41.3679
-33.5668
-27.9799
-23.7791
-20.5041
-17.8782
-15.7252
-13.9276
-12.4037
-11.0953
-9.9595
-8.9642
-8.0848
-7.3020
-6.6007
-5.9688
-5.3964
-4.8755
-4.3995
-3.9626
-3.5603
-3.1887
-2.8443
-2.5242
-2.2260
-1.9474
-1.6867
-1.4421
-1.2121
-.9956
-.7913
-.5983
-.4156
-.2425
-.0782
.0780
.2266
.3682
.5032
.6322
.7554
.8733
.9862
1.0944
1.1982
1.2978
1.3936
1.4856
1.5742
1.6595
1.7417
1.8210
1.8975
1.9713
2.0426
2.1115
/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
.03
II
+
1
X
«о
со
«-ч
о
м
г!
г-
I.001C
го
го
г**
«¦ч
II
Ь
Г а б л и
i
л
§
к
п
ON
00
о
о
и
о
С
о
о
<
т
§
т
к
ъ
ON
*"*
м
со
00
1
1
ON
00
ON
ON
ГО
"*"
1
§
к
V
ON
Я
о
II
2
V)
об
ON
U
г;
О
о
^\
<4
ца 41
л
§. •
•
т
*
ON
ОО
1—4
II
п
о к
Я
2
V
\/
500«
о
и
н
75

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р(Т)
42.449
42.511
42.534
42.517
42.460
42.365
42.232
42.064
41.864
41.633
41.374
41.090
40.785
40.460
40.119
39.764
39.399
39.024
38.643
38.257
37.283
36.315
35.371
34.463
33.598
32.782
32.016
31.300
30.634
30.Q15
29.441
28.910
28.419
27.964
27.544
27.155
26,794
26.461
26.151
25.864
ДЕЙТЕРОТРИТИЙ DT (г)
Ф°(Т)
Дж К • моль"
222.006
223.196
224.355
225.484
226.584
227.656
228.702
229.723
230.720
231.695
232.647
233.577
234.488
235.378
236.249
237.102
237.937
238.754
239.555
240.340
242.233
244.035
245.752
247.390
248.955
250.450
251.882
253.254
254.570
255.8<3
257.047
258.215
259.340
260.424
261.469
262.478
263.453
264.396
265.308
266.191
-1
Я°(Г)-Я°@)
к Дж • моль
259.429 232.024
260.778 240.520
262.086 249.025
263.356 257.531
264.588 266.029
265.782 274.513
266.942 282.973
268.066 291.403
269.156 299.796
270.213 308.146
271.238 316.447
272.231 324.694
273.195 332.882
274.129 341.007
275.034 349.065
275.912 357.054
276.763 364.970
277.589 372.812
278.390 380.579
279.166 388.269
281.009 407.154
282.721 425.553
284.315 443.474
285.801 460.931
287.190 477.944
288.492 494.537
289.714 510.734
290.865 526.561
291.952 542.042
292.980 557.202
293.955 572.065
294.881 586.651
295.763 600.982
296.605 615.076
297.409 628.952
298.179 642.625
298.918 656.111
299.629 669.424
300.312 682.576
300.970 695.579
2.2427
2.3656
2.4810
2.5896
2.6919
2.7885
2.8799
2.9664
3.0485
3.1264
3.2006
3.2712
3.3385
3.4029
3.4644
3.5232
3.5796
3.6337
3.6856
3.7355
3.8523
3.9590
4.0569
4.1473
4.2310
4.3089
4.3818
4.4500
4^749
4.6322
4.6866
4.7383
4.7876
4.8347
4.8798
4.9229
4.9644
5.0042
5.0426
Т
К
\ 6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
3200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 4 («ПО
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 41
(окончание)
+
г^ 7
Й g
со о
о
Т
JJ ц О
о 2 ™
? 2 v
1 -С v
Я ^ §
^ б 2
Т
со Н О
v© УП ,-н
00 00
6 ^ ^
CN О\ И
<Ч CN >^
II + w
о
76

Класс точности
III-И
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ГСП
33.298
33.529
34.560
34.586
36.165
37.928
39.783
41.С55
43.466
45.159
46.702
48.087
49.319
50.409
51.374
52.228
52.987
53.662
54.267
54.811
55.302
55.748
56.155
56.528
56.872
57.190
57.486
57.763
58.023
58.268
58.499
58.719
58.928
59.128
59.320
59.505
59.683
59.855
60.022
60.184
60.342
60.496
60.646
60.793
60.938
61.080
61.219
61.357
61.492
61.626
61.758
61.889
62.019
62.147
62.274
62.401
62.526
62.651
62.775
62.898
63.021
К°(Т)= рф) •
<\Лт)
Дж • К • моль
137.196
160.190
173.500
173.708
183.401
191.042
197.407
202.904
207.772
212.163
216.178
219.888
223.345
226.585
229.640
232.533
235.281
237.901
240.406
242.805
245.109
247.325
249.461
251.521
253 513
255.440
257.306
259.116
260.874
262.581
264.242
265.859
267.433
268.969
270.466
271.928
273.356
274.751
276Л16
277.451
278.758
280.038
281.292
282.521
283.727
284.910
286.071
287.211
288.330
289.430
290.511
291.574
292.620
293.648
294.660
295.657
296.638
297.604
298.556
299.493
300.418
ОКСИД ДЕЙТЕРОТРИТИЯ
р(Т) р(О) -р~
-1
170.311
193.430
206.984
207.198
217.357
225.614
232.692
238.966
244.647
249.866
254.705
259.222
263.460
267.452
271.224
274.798
278.193
281.426
284.511
287.460
290.284
292.993
295.596
298.100
300.513
302.841
305.091
307.265
309.371
311.411
313.390
315.312
317.180
318.996
320.764
322.487
324.165
325.803
327.401
328.963
330.488
331.980
333.440
334.869
336.268
337.639
338.983
340.301
341.594
342.864
344.110
345.334
346.537
347.720
348.883
350.026
351.152
352.260
353.350
354.424
355.483
'(DTO) V,
//°( /)—//°@)
кДж • моль
3.312
6.648
9.983
10.047
13.582
17.286
21.171
25.243
29.500
33.932
38.527
43.267
48.139
53.126
58.216
63.397
68.659
73.992
79.389
84.843
90.349
95.902
101.498
107.132
112.802
118.505
124.239
130.002
135.792
141.606
147.445
153.306
159.188
165.091
171.013
176.955
182.914
188.891
194.885
200.895
206.921
212.963
219.020
225.092
231.179
237.280
243.395
249.524
255.666
261.822
267.991
274.174
280.369
286.578
292.799
299.032
305.279
311.537
317.809
324.092
330.388
DTO (г)
"@) = 935.770
-481.4194
-235.9066
-154.8086
-153.7877
-112.5996
-87.8155
-71.2490
-59.3871
-50.4710
-43.5224
-37.9533
-33.3893
-29.5802
-26.3528
-23.5829
-21.1796
-19.0745
-17.2152
-15.5611
-14.0798
-12.7455
-11.5375
-10.4386
-9.4345
-8.5136
-7.6658
-6.8829
-6.1576
-5.4837
-4.8561
-4.2700
-3.7215
-3.2071
-2.7237
-2.2686
-1.8394
-1.4338
-1.0501
-.6864
-.3413
-.0134
.2987
.5959
.8794
1.1500
1.4087
1.6562
1.8932
2.1204
2.3383
2.5476
2.7487
2.9420
3.1281
3.3074
3.4801
3.6467
3.8075
3.9627
4.1127
4.2578
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
24Q0
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ю
CN
О
<Ч
II
'к
О
00
чо
О
с*
'х
00
00
о
о
г-•
00
"¦?
со
г»
00
00
о
ь
Т а б
.
о
1
!!
е
о
1
.
i
*
со
+
vo
1
к
со
V©
ON
л и
т
ё
о
к
00
о
1
II
*""?
00
сч
о
ца 42
i
ё
§
Т
со
2
«о
II
о 5
->
?
о
о
о
V
V
8
1
о
II
н
—
77

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
OfiAA
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100 ,
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
21.205
22.605
22.746
22.742
22.432
22.100
21.832
21.628
21.474
21.357
21.266
21.194
21.137
21.091
21.053
21.022
20.996
20.974
20.955
20.939
20.925
20.913
20.902
20.893
20.885
20.877
20.87]
20.865
20.860
20!в55
20.851
20.847
20.843
20.840
20.837
20.834
20.831
20.829
20.827
20.825
20.823
20.821
20.820
20.818
20.817
20.815
20.814
20.813
20.812
20.811
20.810
20.809
20.808
20.807
20.807
20.806
20.805
20.805
20.804
20.803
20.803
Ф°<Л
*~ 1
Дж - К • моль
113.510
128.130
136.777
136.912
143.233
148.160
152.186
155.585
158.522
161.105
163.410
165.489
167.382
169.120
170.725
172.217
173.610
174.916
176.146
177.308
178.408
179.454
180.450
181.400
182.310
183.181
184.017
184.822
1 ft1* SQfi
186.343
187.064
187.760
188.434
189.088
189.721
190.336
190.932
191.513
192.077
192.627
193.163
193.685
194.194
194.692
195.177
195.652
196.116
196.570
197.014
197.449
197.875
198.292
198.701
199.103
199.497
199.883
200.262
200.635
201.001
201.361
201.714
ФТОР F (г)
134.369
149.559
158.640
158.780
165.284
170.252
174.257
177.606
180.484
183.006
185.252
187.275
189.116
190.806
192.368
193.820
195.175
196.448
197.646
198.778
199.852
200.873
201.845
202.774
203.663
204.516
205.334
206.122
206.881
207.613
208.320
209.003
209.665
210.306
210.928
211.532
212.119
212.690
213.245
213.786
214.313
214.828
215.329
215.819
216.298
216.766
217.223
217.671
218.109
218.538
218.959
219.371
219.775
220.171
220.560
220.942
221.317
221.685
222.047
222.402
222.752
//V>-//°«»
кДж ¦ моль
¦/'
К.
2.086 — ' 100
4.286 — 200
6.518 — 298.15
6.561 — 300
8.820 — 400
11.046 — 500
13.242 — 600
15.415 — 700
17.570 — 800
19.711 — 900
21.842 — 1000
23.965 — 1100
26.081 — 1200
28.193 — 1300
30.300 —• 1400
32.404 — 1500
34.505 — 1600
36.603 — 1700
38.699 — 1800
40.794 — 1900
42.887 - 2000
44.979 — 2100
47.070 — 2200
49.160 — 2300
51.249 — 2400
53.337 — 2500
55.424 — 2600
57.511 — 2700
ВД ВД7 9R00
v9«Uvi *Ovv
61.683 — 2900
63.768 — 3000
65.853 — 3100
67.937 — 3200
70.022 — 3300
72.105 — 3400
74.189 — 3500
76.272 - 3600
78.355 — 3700
80.438 — 3800
82.521 — 3900
84.603 — 4000
86.685 — 4100
88.767 - 4200
90.849 — 4300
92.931 — 4400
95.012 — 4500
97.094 — 4600
99.175 — 4700
101.257 — 4800
103.338 - 4900
105.419 — 5000
107.500 — 5100
109.581 — 5200
111.661 — 5300
113.742 - 5400
115.823 — 5500
117.903 — 5600
119.984 — 5700
122.064 — 5800
124.145 — 5900
126.225 — 6000
Таблица 43
т 1 \.
§ * |
О X ^
О? ^ Ц *
00 1/"> (С 5*5
*"" К II ^
ЕГ О ^
^ г- ЪС г-
о оо »
•> * О К
0 ,
^ °-
*Н
О
—и 7
О J9
t О
1 ,
с* —
S |
8 «% v
1*5 V
;8 In;
2-0
500'
%П 1
? ^ S
+ 7 ^
§5 ?
с
о
ь
78

ФТОР F (г)
Таблица 43
(окончание)
S°(T)

Дж К 'моль"
"
кДж' моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.802
20.801
20.800
20.799
20.798
20.798
20.797
20.797
20.796
20.796
20.795
20.795
20.794
20.794
20.794
20.793
20.793
20.793
20.792
20.792
202.404
203.072
203.718
204.346
204.955
205.546
206.122
206.681
207 226
207.758
208.276
208.781
209.274
209.756
210.227
210.688
211.138
211.579
212.011
212.434
223.434
224.094
224.734
225.355
225.958
226.544
227.114
227.669
228.209
228.73J
229.249
229.750
230.239
230.717
231.185
231.642
232.089
232.527
232.955
233.375
130.385
134.546
138.706
142.866
147.025
151.185
155.344
159.504
163.663
167.822
171.981
176.140
180.299
184.458
188.616
192.775
196.934
201.092
205.251
209.409
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
1—1
©
I
ъ
00
б
о
о
V
V
S
о
79

Класс точности
I-B
ОТРИЦАТЕЛЬНЫЙ ИОН ФТОРА F" (г)
-р(е)
1 а б л и ц а 44
//°@) = 328.010 кДж-моль
-1
С°(Т)
Ф°(Т)
кДж • моль
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
460Q
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
124.679
124.808
130,788
135.426
139.216
142.420
145.196
147.644
149.834
151.815
153.624
155.287
156.828
158.262
159.603
160.863
162.052
163.175
164.242
165.256
166.223
167.147
168.031
168.880
169.695
170.480
171.235
i 71.965
172.669
173.351
174.011
174.651
175.271
175.874
176.459
177.029
177.583
178.123
178.649
179.163
179.663
180.152
180.630
181.097
181.554
182.001
182.439
182.868
183.288
183.699
184.103
184.499
184.887
185.269
185.643
186.011
186.373
186.728
187.077
145.465
145.594
151.574
156.212
160.002
163.206
165.982
168.430
170.620
172.601
174.409
176.073
177.614
179.048
180.389
181.649
182.837
183.961
185.028
186.042
187.009
187.933
188.817
189.666
190.481
191.265
192.021
192.751
193.456
194.137
194.797
195.437
196.057
196.660
197.245
197.815
198.369
198.909
199.435
199.948
200.449
200.939
201.416
201.884
202.340
202.787
203.225
203.654
204.074
204.485
204.889
205.285
205.673
206.055
206.429
206.797
207.159
207.514
207.863
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
1 Г2.245
114.323
116.402
118.480
120.559
122.638
124.716
-56.8291
-56.4677
-41.8598
-33.0358
-27.1144
-22.8575
-19.6446
-17.1301
-15.1060
-13.4398
-12.0429
-10.8539
-9.8286
-8.9348
-8.1482
-7.4501
-6.8259
-6.2643
-5.7559
-5.2934
-4.8705
-4.4822
-4.1244
-3.7933
3.4860
-3.1999
-2.9329
-2.6829
-2.4483
-2.2276
-2.0197
-1.8234
-1.6376
-1.4615
-1.2943
-1.1354
-.9840
-.8397
-.7019
-.5702
-.4441
-.3232
-.2073
-.0960
.0110
.1140
.2131
.3087
.4009
.4899
.5759
.6590
.7394
.8173
.8927
.9659
1.0368
1.1057
1.1725
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
Tf
On
00
ON
ON
00
о
к
00
ю
1
л
о
т
00
ON
о
о
I
О R
За
+ О
О
О
о
V
к.
V
80

ОТРИЦАТЕЛЬНЫЙ ИОН ФТОРА F " (г)
Таблица 44
(окончание)
К
с;
Ф°G)
Дж К моль"
Н°(Т)-Н°@)
кДж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
187.759
188.419
189.058
189.679
190.281
190.867
191.436
191.991
192.531
193.057
193.570
194.071
194.560
195.038
195.505
195.962
196.409
196.847
197.275
197.695
208.545
209.205
209.844
210.465
211.068
211.653
212.223
212.777
213.317
213.843
214.356
214.857
215.346
215.824
216.291
216.748
217.195
217.633
218.061
218.481
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
G)
К
1.3007
1.4219
! 5368
1.6459
1.7497
1.8486
1.9430
2.0332
2.1194
2.2021
2.2814
2.3575
2.4307
2.5012
2.5691
2.6345
2.6977
2.7587
2.8176
2.8747
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
н
S
о
о
о
о
о
о
о 7
I ?
1- I
о
. о
г- о
°^ о
II I
?
S
V
V
б 872
81

Класс точности
И-С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°рт
29.114
29.685
31.303
31.336
32.993
34.257
35.169
35.835
36.339
36.734
37.057
37.333
37.577
37.800
38.007
38.204
38.388
38.560
38.715
38.850
38.960
39.041
39.089
39.101
39.076
39.014
38.913
38.777
38.606
38.403
38.170
37.912
37.631
37.330
37.012
36.682
36.341
35.992
35.637
35.280
34.921
34.563
34.206
33.853
33.505
33.162
32.825
32.494
32.171
31.855
31.548
31.248
30.956
30.673
30.398
30.131
29.873
29.622
29.380
29.145
28.917
К°(Т)=р2(Г) •
Ф°(Л
Дж • К • моль
141.190
161.362
173.080
173.263
181.867
188.692
194.389
199.299
203.623
207.492
210.996
214.200
217.153
219.893
222.450
224.847
227.103
229.236
231.257
233.179
235.011
236.761
238.437
240.044
241.588
243.074
244.505
245.886
947 220
*** 1 •ллЛЗ
248.509
249.756
250.964
252.135
253.270
254.372
255.442
256.482
257.493
258.476
259.432
260.364
261.271
262.156
263.018
263.859
264.679
265.480
266.262
267.025
267.771
268.501
269.214
269.911
270.594
271.262
271.915
272.556
273.183
273.797
274.399
274.990
ДИФТОР F2 (г)
p"!(F2) LrH
S°(T)
-1
кДж ¦ моль
170.260 2.907
190.542 5.836
202.685 8.825
202.873 8.883
212.123 12.102
219.628 15.468
225.959 18.942
231.433 22.494
236.252 26.103
240.556 29.758
244.444 33.448
247.989 37.168
251.248 40.913
254.264 44.682
257.073 48.473
259.702 52.283
262.174 56.113
264.506 59.961
266.715 63.825
268.812 67.703
270.808 71.594
272.П0 75.494
274.528 79.401
276.266 83.311
277.930 87.220
279.524 91.125
281.052 95.021
282.518 98.906
283 925 1П9 77fi
285.276 106.626
286.575^ 110.455
287.822 114.260
289.021 118.037
290.175 121.785
291.285 125.502
292.353 129.187
293.381 132.838
294.372 136.455
295.327 140.036
296.248 143.582
297.137 147.092
297.995 150.566
298.824 154.005
299.624 157.408
300.399 160.776
301.148 164.109
301.873 167.408
302.575 170.674
303.256 173.907
303.916 177.108
304.557 180.279
305.178 183.418
305.782 186.528
306.369 189.610
306.940 192.663
307.495 195.690
308.036 198.690
308.562 201.665
309.075 204.615
309.576 207.541
310.064 210.444
Таблица 45
\0) = 154.550кДж- моль 1
\gK°(T)
-76.2443
-35.4068
-21.8280
-21.6565
-14.7183
-10.5237
-7.7097
-5.6890
-4.1665
-2.9775
-2.0229
-1.2391
-.5840
-.0281
.4496
.8647
1.2287
1.5506
1.8373
2.0943
2.3260
2.5361
2.7273
2.9022
3.0628
3.2107
3.3475
3.4744
3.5924
3J025
3.8055
3.9019
3.9926
4.0780
4.1585
4.2347
4.3068
4.3753
4.4403
4.5022
4.5613
4.6177
4.6716
4.7232
4.7727
4.8201
4.8658
4.9097
4.9520
4.9928
?0321
5.0702
5.1069
5.1425
5.1770
5.2104
5.2428
5.2742
5.3048
5.3345
5.3634
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
4O\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
§
' о Т
s *
о>
О) О *
Г* и Еч
11 о & й
^ " 2 ~
О 00
ON "
U fN
Й
f4» U Or*
о Ъ
т* т
СО А
VO К
00 О
со 5
Р 7
О ^ч
1 1
J *
5 5 §
* о о
00 ^ ^
Ш! On
§ 1 v
О об Ь,
t 7 v
- « я
Я "> 2
* н С
о ^
г- г- п
<N
ft
82

ДИФТОР F. (г)
Таблица 45
(окончание)
с°рт
Ф°G)
S°(T)
Дж'К"*1 -моль"
Н°(Т)-Н°@)
кДж * моль
\%К°{Т)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
28.485
28.080
27.702
27.349
27.018
26.710
26.421
26.151
25.898
25.662
25.440
25.231
25.036
24.852
24.680
24.517
24.364
24.220
24.084
23.955
276.136
277.240
278.304
279.329
280.319
281.276
282.200
283.095
283.962
284.802
285.617
286.407
287.175
287.921
288.647
289.353
290.040
290.709
291.362
291.998
311.004
311.903
312.761
313.582
314.370
315.127
315.855
316.556
317.232
317.885
318.516
319.126
319.717
320.291
320.847
321.388
321.914
322.425
322.923
323.408
216.184
221.840
227.417
232.922
238.358
243.731
249.044
254.301
259.505
264.661
269.771
274.838.
279.864
284.853
289.806
294.725
299.613
304.472
309.302
314.105
5.4190
5.4718
5.5220
5.5699
5.6158
5.6596
5.7017
5.7422
5.7811
5.8186
5.8547
5.8897
5.9235
5.9562
5.9879
6.0186
6.0484
6.0774
6.1057
6.1331
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
•о
со
s к *
9 й I
Т J v
^ "н V
S g о
РО О
о
ON
и
СП ^Э
83

Класс точности
1V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ФТОРИД
Л'°(П = p(F) -p(O) .p"!(FO)
Ф°(Л
Дж • К • моль
32.700 150.735
31.704 172.204
31.873 184.732
31.888 184.927
32.919 193.999
33.963 201.104
34.813 206.979
35.472 212.007
35.982 216.413
36.386 220.340
36.712 223.888
36.984 227.124
37.216 230.102
37.420 232.860
37.604 235.430
37.773 237.837
37.932 240.100
38.083 242.236
38.229 244.260
38.371 246.183
38.508 248.014
38.641 249.762
38.767 251.436
38.886 253.040
38.996 254.581
39.093 256.064
39.176 257.493
39.243 258.872
39.292 260.204
39.321 261.493
39.329 262.741
39.314 263.951
39.277 265.125
39.217 266.265
39.135 267.373
39.030 268.451
38.904 269.499
38.757 270.520
38.591 271.515
38.408 272.485
38.507 273.431
37.992 274.354
37.763 275.256
37.523 276.136
37.272 276.996
37.012 277.837
36.744 278.659
36.471 279.463
36.193 280.250
35.910 281.020
35.626 281.774
35.340 282.512
35.053 283.235
34.766 283.944
34.481 284.639
34.197 285.320
33.915 285.987
33.636 286.642
33.361 287.285
33.089 287.915
32.821 288.534
S°(T)
-1
181.115
203.527
216.168
216.365
225.673
233.134
239.404
244.823
249.594
253.856
257.707
261.219
264.447
267.435
270.215
272.815
275.258
277.562
279.743
281.814
283.785
285.667
287.468
289.194
290.851
292.445
293.980
295.460
296.888
298.267
299.600
300.890
302.138
303.345
304.515
305.648
306.746
307.810
308.841
309.841
310.811
311.752
312.665
313.550
314.410
315.245
316.056
316.843
317.608
318.351
319.074
319.776
320.460
321.125
321.772
322.402
323.016
323.614
324.196
324.764
325.318
КИСЛОРОДА
\
кДж • моль"
3.038
6.265
9.373
9.431
12.670
16.015
19.456
22.971
26.545
30.164
33.820
37.505
41.215
44.947
48.698
52.467
56.253
60.053
63.869
67.699
71.543
75.401
79.271
83.154
87.048
90.953
94.866
98.787
102.714
106.645
110.578
114.510
118.440
122.365
126.283
130.191
134.088
137.971
141.839
145.689
149.520
153.330
157.118
160.882
164.622
168.336
172.024
175.685
179.318
182.923
186.500
190.048
193.568
197.059
200.521
203.955
207.360
210.738
214.088
217.410
220.706
FO (г)
Н°@) = 215.677
-108.6580 Ч
-51.8738
-33.0612
-32.8240
-23.2424
-17.4642
-13.5955
-10.8219
-8.7349
-7.1069
-5.8011
-4.7301
-3.8356
-3.0771
-2.4256
-1.8599
-1.3641
-.9258
-.5356
-.1859
.1293
.4148
.6748
.9124
1.1306
1.3315
1.5171
1.6892
1.8492
L9983
2.1376
2.2681
2.3906
2.5057
2.6142
2.7166
2.8135
2.9052
2.9922
3.0749
3.1536
3.2286
3.3001
3.3684
3.4337
3.4963
3.5563
3.6139
3.6692
3.7224
3.7736
3.8229
3.8705
3.9165
3.9609
4.0038
4.0453
4.0855
4.1245
4.1623
4.1990
кДж • моль *
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
00
г-
О\
со
II
+
1
X
Tf
00
О
V
00
<ч
00
О
О
I
1
Г-
о
СО
см
со
00
об
СМ
о
Таблица 46
—
Гл |
§ т
2 * ё
% V %
^ и5 «
3 § -/
О 1
00 О** ь*ч
00 *~* %
О II ё^
п 2 2
/~ч 1^ О)
об
U On II
<^
о с о g
~ О со
о fe,
1
2
v; О
со ^О
? v
О -
7 v
«V §
о
°> т
1 *^
чо ^
о "
00 Н
84

Класс точности
IV-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1008
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЯАА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°(Т)= p2(V)
Ф°(Т)
Дж • К~' • моль
33.772 173.259
38.124 196.644
43.493 210.796
43.587 211.023
47.960 221.882
51.037 230.807
53.176 238.464
54.702 245.204
55!832 251.237
56.700 256.706
57.391 261.713
57.960 266.332
58.443 270.620
58.862 274.624
59.235 278.380
59.572 281.917
59.884 285.260
60.174 288.430
60.448 291.445
60.710 294.319
60.962 297.066
61.206 299.696
61.443 302.220
61.676 304.645
61.904 306.981
62.130 309.232
62.353 311.406
62.574 313.508
62 793 315 5ДЗ
63.012 317.515
63.230 319.427
63.447 321.284
63.665 323.089
63.882 324.845
64.100 326.555
64.318 328.221
64.536 329.845
64.756 331.430
64.976 332.978
65.196 334.490
65.418 335.968
65.641 337.414
65.865 338.829
66.090 340.215
66.316 341.573
66.543 342.904
66.772 344.210
67.002 345.490
67.234 346.747
67.466 347.982
67.701 349.194
67.937 350.385
68.174 351.557
68.413 352.708
68.654 353.841
68.896 354.956
69.140 356.054
69.385 357.135
69.632 358.199
69.881 359.248
70.132 360.281
ДИФТОРИД
Р(О) V(F2
S°[T)
-1
206.589
231.155
247.392
247.662
260.833
271.887
281.393
289.711
297.092
303.721
309.732
315.229
320.293
324.988
329.364
333.463
337.318
340.957
344.404
347.679
350.800
353.780
356.633
359.369
361.999
364.531
366.972
369.329
371.609
373.816
375.956
378.033
380.051
382.013
383.924
385.785
387.600
389.371
391.101
392.791
394.445 .
396.063
397.647
399.200
400.722
402.215
403.680
405.118
406.531
407.920
409.285
410.628
411.950
413.250
414.531
415.793
417.037
418.263
419.472
420.664
421.841
КИСЛОРОДА
0) ЛгН
НО(Т)-Н°(())
кДж ' моль
3.333
6.902
10.911
10.992
15.581
20.540
25.757
31.155
36.684
42.313
48.018
53.787
59.608
65.473
71.378
77.319
83.292
89.295
95.326
101.384
107.468
113.576
119.709
125.865
132.044
138.246
144.470
150.716
1 КА QQR
163.275
169.587
175.921
182.276
188.654
195.053
201.474
207.916
214.381
220.868
227.376
233.907
24Q.460
247.035
253,633
260.253
266.896
273.562
280.250
286.962
293.697
300.456
307.237
314.043
320.872
327.725
334.603
341.505
348.431
355.382
362.358
369.358
F2O (г)
°@) = 374.578
-186.9061
-87.9581
-55.1168
-54.7026
-37.9674
-27.8769
-21.1243
-16.2863
-12.6488
-9.8136
-7.5414
-5.6795
-4.1257
-2.8095
-1.6800
-.7002
.1578
.9155
1.5894
2.1927
2.7360
3.2278
3.6750
4.0834
4.4579
4.8025
5.1206
5.4152
5.6888
5*9434
6.1811
6.4034
6.6118
6.8075
6.9916
7.1651
7.3289
7.4839
7.6305
7.7696
7.9017
8.0272
8.1467
8.2605
8.3691
8.4728
8.5719
8.6667
8.7574
8.8444
8.9277
9.0078
9.0846
9.1585
9.2296
9.2979
9.3638
9.4272
9.4884
9.5474
9.6044
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
ZOV/VI
2900
3000
3100
3200
33D0
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
VO
On
О)
ГО
«О
II
Т
ГО
ON
ОО
00
+
го
г-
<ч
8
о
о
1
S
00
so
+
О
SO
<N
о
00
с
о
ь
Т а б л и
,_,
i
§
к
«о
«о
г-
II
о
и
6
о
а:
т
л
»-«
i
к
R
го
00
+
гч
V»
00
с-*
го
1
X
ГО
1
i
к
о
о
*о
fS
II
ь2
»о
00
О\
О
0
а;
<1
ца 47
i
Т
к
М.
ОО
SO
f—4
II
О о?
->
2
О
о
о
sO
V
v
о
о
«Л
О
II
85

Класс точности
I-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.133
29.128
29.137
29.137
29.149
29.172
29.230
29.350
29.549
29.827
30.169
30.558
30.974
31.403
31.831
32.250
32.654
33.039
33.404
33.747
34.070
34.373
34.657
34.923
35.173
35.407
35.628
35.836
36.032
36.218
36.394
36.562
36.722
36.876
37Л23
37.164
37.300
37.432
37.560
37.684
37.805
37.923
38.039
38.152
38.263
38.372
38.480
38.586
38.691
38.794
38.896
38.997
39.096
39.194
39.291
39.386
39.480
39.572
39.662
39.750
39.836
ФТОРИД
К°(Т)= р(Н) p(F) ^(HF)
Ф°(Л
Дж * К - моль
113.576
133.336
144.825
145.003
153.312
159.770
165.055
169.529
173.410
176.841
179.917
182.709
185.267
187.631
189.829
191.886
193.820
195.647
197.379
199.027
200.598
202.101
203.542
204.926
206.257
207.541
208.781
209.986
211.140
212.265
213.356
214.416
215.447
216.450
217.427
218.379
219.308
220.215
221.100
221.966
222.812
223.640
224.451
225.245
226.023
226.786
227.534
228.268
228.989
229.697
230.392
231.075
231.747
232.408
233.057
233.697
234.326
234.946
235.556
236.157
236.749
S°(T)
141.844.
162.034
173.666
173.846
182.230
188.736
194.060
198.573
202.504
206.000
209.160
212.053
214.730
217.226
219.569
221.780
223.874
225.865
227.764
229.579
231.319
232.988
234.594
236.140
237.632
239.073
240.466
241.814
243.121
244.389
245.620
246.816
247.979
249.112
250.215
251.290
252.339
253.362
254.362
255.340
256.295
257.230
258.145
259.042
259.920
260.781
261.626
262.455
263.268
264.067
264.852
265.623
266.381
267.127
267.860
268.582
269.293
269.992
270.681
271.360
272.029
ВОДОРОДА
Я°(Г)-Я°@)
кДж • моль
2.827
5.740
8.599
8.653
11.567
14.483
17.403
20.331
23.275
26.243
29.243
32.279
35.355
38.474
41.636
44.840
48.085
51.370
54.692
58.050
61.441
64.863
68.315
71.794
75.299
78.828
82.380
85.953
89.547
93.159
96.790
100.438
104.102
107.782
111.477
115.187
118.910
122.647
126.396
130.158
133.933
137.719
141.517
145.327
149.148
152.980
156.822
160.676
164.539
168.414
172.298
176.193
180.098
184.012
187.936
191.870
195.814
199.766
203.728
207.699
211.678
HF (г)
Н°@) = 566.562 кДж-моль
-292.2266
-143.7737
-94.7777
-94.1612
-69.2912
-54.3320
-44.3352
-37.1779
-31.7976
-27.6038
-24.2415
-21.4849
-19.1832
-17.2319
-15.5564
-14.1018
-12.8269
-11.7003
-10.6973
-9.7987
-8.9888
-8.2551
-7.5873
-6.9768
-6.4165
-5.9006
-5.4237
-4.9818
-4.5710
-4.1882
-3.8306
-3.4958
-3.1816
-2.8862
-2.6080
-2.3455
-2.0974
-1.8625
-1.6398
-1.4284
-1.2274
-1.0362
-.8539
-.6800
-.5139
-.3551
-.2031
-.0575
.0821
.2160
.3447
.4684
.5873 •
.7019
.8122
.9185
1.0211
1.1202
1.2158
1.3082
1.3976
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5.000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
го
о.ооб:
см
II
+
-
v2
см
О\
со
о
'к
S
О
о
+
г-
On
СМ
со
см
S
00
со
II
Табли
1
А
г*
т °
а .
о Д
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X о
5 8
со ?)
см <]*
•S •
см ._
1 Q
II ю
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OS
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А
о
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т
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1
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О
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с*
5?
об
см
1
$
см
СО
+
ца 48
i
А
Т
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-н
II
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S
V
V
о
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1
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II
86

ФТОРИД ВОДОРОДА HF (г)
Таблица 48
(окончание)
S\T)
К
ДжК -моль
"
кДж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
40.002
40.156
40.299
40.428
40.543
40.642
40.723
40.786
40.831
40.856
40.861
40.846
40.812
40.757
40.684
40.592
40.481
40.354
40.211
40.052
237.908
239.036
240.132
241.201
242.242
2*3.257
244.249
245.217
246.162
247.087
247.992
248.877
249.744
250.592
251.424
252.239
253.038
253.822
254.591
255.346
273.338
274.610
275.848
277.053
278.227
279.370
280.485
281.572
282.632
283.666
284.675
285.660
286.620
287.558
288.473
289.366
290.238
291.089
291.920
292.730
219.662
227.678
235.724
243.797
251.894
260.013
268.149
276.301
284.463
292.632
300.804
308.975
317.141
325.298
333.443
341.570
349.678
357.762
365.819
373.845
1.5678
1.7274
1.8775
2.0187
2.1519
2.2778
2.3969
2.5098
2.6169
2.7187
2.8156
2.9078
2.9958
3.0798
3.1601
3.2369
3.3105
3.3810
3.4487
3.5137
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
+
* ^
8738
о
о
о
1
1
!8.73
+
С*
X
<ч
О
X
1641
1
со
О
00
so
S
S
V
V
1000
ь
1-Н
II
X
87

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9R00
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.259
33.878
35.937
35.983
38.573
40.907
42.832
44.422
45.765
46.937
47.978
48.907
49.740
50.489
51.163
51.761
52.301
52.786
53.217
53.606
53.953
54.267
54.552
54.807
55.037
55.250
55.439
55.614
55.773
55.916
56.049
56.171
56.284
56.388
56.485
56.572
56.656
56.731
56.803
56.870
56.928
56.987
57.041
57.091
57.137
57.183
57.225
57.263
57.300
57.334
57.367
57.397
57.426
57.455
57.480
57.506
57.531
57.552
57.572
57.593
57.614
К°(Т) = р(Й) •
Ф°(Л
Дж • К • моль"
156.349
179.416
192.809
193.018
202.868
210.717
217.323
223.064
228.164
232.767
236.972
240.850
244.453
247.817
250.980
253.967
256.796
259.482
262.042
264.490
266.837
269.084
271.247
273.331
275.339
277.276
279.151
280.967
9Я9 794
284.431
286.088
287.699
289.264
290.791
292.276
293.724
295.134
296.515
297.862
299.176
300,464
301.720
302.954
304.159
305.339
306.498
307.632
308.745
309.837
310.908
311.962
312.996
314.008
315.008
315.987
316.954
317.904
318.837
319.753
320.661
321.548
ФТОРИД
Р(О) -p(F)
-i
189.604
212.767
226.645
226.867
237.574
246.440
254.076
260.800
266.825
272.281
277.285
281.900
286.193
290.205
293.971
297.523
300.879
304.067
307.096
309.983
312.740
315.385
317.916
320.343
322.682
324.933
327.104
329.201
331.225
333.184
335.083
336.924
338.707
340.443
342.125
343.765
345.359
346.916
348.426
349.903
351.347
352.753
354.125
355.468
356.782
358.066
359.321
360.556
361.761
362.941
364.100
365.238
366.351
367.447
368.522
369.577
370.610
371.631
372.631
373.614
374.585
ГИДРОКСИЛА HOF (г)
•p~l(HOF) ArH
H°(T)-H°@)
кДж • моль
3.322
6.669
10.088
10.150
13.883
17.862
22.050
26.414
30.928
35.560
40.309
45.154
50.087
55.104
60.183
65.330
70.530
75.794
81.095
86.434
91.802
97.229
102.668
108.124
113.618
119.141
124.676
130.228
t <*«\ ЯП 9
ioo.ova
141.379
146.981
152.596
158.215
163.851
169.483
175.144
180.809
186.483
192.144
197.834
203.524
209.232
214.918
220.625
226.348
232.056
237.771
243.511
249.235
254.959
260.683
266.432
272.176
277.921
283 686
289.423
295.155
300.925
306.690
312.423
318.222
°@) = 634.092
lgtfV)
-323.7917
-157.0610
-101.8862
-101.1911
-73.1248
-56.2154
-44.9018
-36.7943
-30.6958
-25.9397
-22.1255
-18.9977
-16.3856
-14.1708
-12.2690
-10.6181
-9.1710
-7.8921
-6.7537
-5.7337
-4.8146
-3.9817
-3.2238
-2.5310
-1.8951
-1.3094
-.7681
-.2665
IQQft
. I iJ&O
.6343
1.0403
1.4205
1.7773
2.1126
2.4286
2.7268
3.0088
3.2756
3.5286
3.7690
3.9974
4.2151
4.4223
4.6202
4.8093
4.9900
5.1632
5.32-91
5.4882
5.6410
5.7876
5.9287
6.0647
6.1954
6.S216
6.4431
6.5604
6.6738
6.7835
6.8892
6.9919
кДж • моль
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
ZO\t\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
J5800
5900
6000
о
t-»
ю
о
о
VO
со
1!
+
VO
г-
VO
«о
о
+
X
ON
Г—
ON
00
VO
О
о
1
1
со
00
о
+
р
<ч
со
II
с
Т а б л и
Т
ё
о
к
X
О
8
On
1
II
О
и
iC
о.
ни
О
<1
т
т
к
f-^
VO
ч—i
J.
X
со
rf
1
X
СЯ
r»
i-H
ON
+
|
IS
к
о
о
On
vo
ON
1
II
Я
*o
00
On
CN
НЧ
О
3
о
•«с;
^\
ца 49
i
л
мол
• T
<§
ON
VO
»-4
og
to
2
о
о
о
vO
V
v
V
§
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1
о
{»!,
II
><

Класс точности
I-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.117
29.125
29.137
29.137
29.174
29.298
29.562
29.964
30.466
31.022
31.592
32.149
32.677
33.169
33.620
34.033
34.408
34.750
35.060
35.343
35.602
35.839
36.057
36.258
36.445
36.619
36.781
36.934
37.078
37.214
37.343
37.467
37.585
37.699
37.809
37.915
38.018
38.119
38.217
38.313
38.408
38.501
38.593
38.684
38.774
38.864
38.952
39.041
39.128
39.215
39.302
39.388
39.473
39.558
39.641
39.724
39.806
39.887
39.966
40.044
40.120
A'°G) = p(D) •/
Ф°(Л
Дж • К • моль
119.108
139.066
150.620
150.799
159.140
165.620
170.923
175.418
179.326
182.790
185.906
188.744
191.352
193.769
196.022
198.136
200.127
202.011
203.798
205.500
207.125
208.680
210.172
211.605
212.984
214.313
215.597
216.838
218.039
219.203
220.332
221.429
222.495
223.531
224.541
225.524
226.483
227.419
228.332
229.225
230.097
230.950
231.785
232.603
233.404
234.189
234.958
235.713
236.453
237.180
237.894
238.596
239.285
239.962
240.629
241.284
241.929
242.564
243.189
243.804
244.410
ФТОРИД
>(F) ^(DF)
S°(T)
-l
147.777
167.961
179.592
179.772
188.158
194.679
200.042
204.628
208.661
212.281
215.579
218.616
221.436
224.072
226.547
228.880
231.089
233.185
235.181
237.084
238.903
240.646
242.319
243.926
245.473
246.964
248.404
249.795
251.141
252.444
253.708
254.934
256.126
257.284
258.411
259.509
260.578
261.621
262.639
263.633
264.604
265.554
266.483
267.392
268.282
269.155
270.010
270.848
271.671
272.479
273.272
274.051
274.817
275.569
276.310
277.038
277.754
278.460
279.154
279.838
280.512
ДЕЙТЕРИЯ
\
Н°{Т)-Н°(()
кДж • моль
2.867
5.779
8.638
8.692
11.607
14.530
17.471
20.447
23.468
26.542
29.673
32.860
36.101
39.394
42.734
46.117
49.539
52.997
56.488
60.008
63.556
67.128
70.723
74.339
77.974
81.627
85.298
88.983
92.684
96.399
100.127
103.867
107.620
111.384
115.159
118.946
122.742
126.549
1 .'10.366
134.193
138.029
141.874
145.729
149.593
153.466
157.348
161.238
165.138
169.046
172.964
176.889
180.824
184.767
188.718
192.678
196.647
200.623
204.608
208.600
212.601
216.609
DF (г)
Н°@) = 573.
)
\а кг°(Т\
lgA {1 )
-295.5578
-145.3688
-95.8012
-95.1775
-70.0181
-54.8853
-44.7730
-37.5336
-32.0924
-27.8517
-24.4527
-21.6668
-19.3412
-17.3703
-15.6785
-14.2102
-12.9238
-11.7872
-10.7758
-9.8698
-9.0535
-8.3142
-7.6415
-7.0266
-6.4625
-5.9431
-5.4632
-5.0185
-4.6052
-4^2202
-3.8605
-3.5238
-3.2080
-2.9111
-2.6314
-2.3676
-2.1183
-1.8823
-1.6586
-1.4462
-1.2444
-1.0523
-.8693
-.6946
-.5279
-.3685
-.2159
-.0698
.0703
.2048
.3339
.4580
.5774
.6923
.8029
.9096
1.0125
1.1119
1.2078
1.3005
1.3902
250 кДж • моль *
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
О
1—4
гч
II
+
т—1
о
1
с*-
О
ON
о
§
о
о
+
J3
О
On
4j»
+
ГО
ГО
II
с
%
Т п Л
1 а о л и
i
а
ъ
2
*
X
оо
V©
vd
Г"*-
1
о
и
tu
Q
о
<
1
А
g
S
^*
i
v>
к
1=1
ё
СО
+
гч
VO
04
с4
го
1
X
On
vo
+
А
§
к
п
X
г»
vd
I
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/—«ч
«О
00
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(н
fcu
О
о
ца 50
i
А
Т
к
г—
On
00
II
п
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со
я
о
о
о
VO
V
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V
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н
89

ФТОРИД ДЕЙТЕРИЯ DF (г)
Таблица 50
(окончание)
с°рт
Ф"G)
Дж К" -моль"
кДж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
40.266
40.403
40.529
40.643
40.743
40.827
40.896
40.946
40.978
40.992
40.986
40.960
40.916
40.852
40.769
40.668
40.549
40.414
40.262
40.096
245.596
246.748
247.869
248.960
250.023
251.059
252.070
253.057
254.020
254.962
255.883
256.784
257.665
258.528
259.374
260.202
261.014
261.810
262.591
263.357
281.829
283.110
284.355
285.567
286.747
287.896
289.015
290.107
291.171
292.208
293.220
294.208
295Л71
296.111
297.028
297.923
298.796
299.649
300.481
301.292
224.648
232.715
240.808
248.926
257.065
265.222
273.394
281.579
289.772
297.969
306.167
314.362
322.550
330.727
338.890
347.034
355.155
363.252
371.320
379.356
1.5608
1.7209
1.8713
2.0129
2.1465
2.2727
2.3921
2.5052
2.6126
2.7146
2.8117
2.9041
2.9923
3.0765
3.156&
3.2339
3.3076
3.3783
3.4461
3.5113
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
+
7х
О
+
о
о
о
1
1
i
со
ЧО
го
X
312
о
X
со
1
i
X
чо
о
V
V
о
§
7!
'о
II
g
90

Класс точности
I-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000*
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.114
29.124
29.144
29.145
29.247
29.531
30.009
30.619
31.285
31.948
32.575
33.151
33.671
34.135
34.549
34.917
35.245
35.538
35.802
36.040
36.256
36.452
36.633
36.799
36.954
37.097
37.232
37.359
37.479
37.593
37.702
37.806
37.907
38.004
38.099
38.191
38.281
38.369
38.456
38.541
38.626
38.710
38.793
38.875
38.958
39.040
39.121
39.203
39.284
39.365
39.446
39.527
39.608
39.688
39.767
39.846
39.924
40.001
40.076
40.151
40.223
*°(Л = р(Т) •
Ф°(Л
Дж • К • моль
122.510
142.534
154.109
154.288
162.642
169.132
174.450
178.966
182.902
186.399
189.552
192.428
195.076
197.532
199.826
201.978
204.007
205.927
207.749
209.485
211.142
212.727
214.247
215.708
217.113
218.468
219.775
221.039
222.262
223.446
224.595
225.711
226.794
227.848
228.874
229.873
230.847
231.797
232.725
233.631
234.516
235.382
236.228
237.057
237.869
238.664
239.444
240.209
240.959
241.695
242.418
243.128
243.826
244.511
245.185
245.848
246.500
247.142
247.774
248.396
249.009
ФТОРИД
p(F) p'^TF)
S°iT)
-l
i
151.310
171.494
183.125
183.305
191.701
198.253
203.677
208.348
212.480
216.203
219.602
222.734
225.641
228.355
230.900
233.297
235.561
237.707
239.745
241.688
243.542
245.316
247.016
248.648
250.217
251.729
253.186
254.594
255.955
257.272
258.548
259.786
260.988
262.156
263.292
264.397
265.475
266.525
267.549
268.549
269.526
270.481
271.414
272.328
273.223
274.099
274.958
275.800
276.627
277.438
278.234
279.016
279.784
280.539
281.282
282.012
282.731
283.438
284.134
284.820
285.496
ТРИТИЯ
Н°(Т)-Н°(
кДж • моль"
2.880
5.792
8.651
8.705
11.624
14.561
17.536
20.567
23.662
26.824
30.050
33.337
36.679
40.069
43.504
46.978
50.486
54.025
57.593
61.185
64.800
68.435
72.090
75.762
79.449
83.152
86.868
90.598
94.340
98.094
101.858
105.634
109.420
113.215
117.020
120.835
124.658
128.491
132.332
136.182
140.040
143.907
147.782
151.666
155.557
159.457
163.365
167.281
171.206
175.138
179.079
183.027
186.984
190.949
194.922
198.902
202.891
206.887
210.891
214.902
218.921
TF (г)
г#°@) = 576.150 кДж- моль
))
-1
lgATV)
-296.9872
-146.0443
-96.2285
-95.6016
-70.3166
-55.1087
-44.9467
-37.6723
-32.2055
-27.9455
-24.5316
-21.7339
-19.3989
-17.4204
-15.7224
-14.2489
-12.9581
-11.8179
-10.8033
-9.8946
-9.0760
-8.3347
-7.6602
-7.0438
-6.4783
-5.9576
-5.4767
-5.0310
-4.6169
-4.2310
-3.8707
-3.5333
-3.2169
-2.9194
-2.6393
-2.3750
-2.1253
-1.8889
-1.6648
-1.4522
-1.2500
-1.0577
-.8744
-.6995
-.5325
-.3729
-.2201
-.0738
.0665
.2011
.3303
.4546
.5741
.6891
.7999
.9067
1.0097
1.1092
1.2052
1.2980
1.3877
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
ю
о
If
+
v©
ON
On
О
О
+
?*
го
ГГ
<N
О
©
1
g
о
»о
+
3
о
оо
об
^>
f>J
II
К,
Табли
i
л
§
§ к
§ 5
2 ,!
" Я
II JO
О об
ON
'JU ?
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о Ь
* о
<
i
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о
1
к
го
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00
t
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1
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00
ON
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го
+
ца 51
Т
л
i
к
чо
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II
о 5
о о;
со
я
о
чо
V
V /
V
§
«о
о
г
к»
II
91

ФТОРИД ТРИТИЯ TF (г)
Таблица 51
(окончание)
С°р(Т)
Ф°G)
S G)
Дж К -моль
Я°(Г)-Я°@)
кДж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
40.364
40.495
40.617
40.726
40.822
40.903
40.968
41.016
41.045
41.056
41.048
41.021
40.974
40.908
40.824
40.722
40.602
40.465
40.312
40.145
250.207
251.372
252.504
253.605
254.678
255.724
256.744
257.739
258.711
259.661
260.589
261.497
262.385
263.255
264.107
264.941
265.759
266.561
267.347
268.118
286.817
288.100
289.348
290.563
291.744
292.896
294.017
295.111
296.176
297.216
298.229
299.218
300.183
301.124
302.043
302.939
303.813
304.667
305.500
306.312
226.980
235:066
243.177
251.312
259.467
267.640
275.827
284.026
292.232
300.442
308.653
316.860
325.060
333.249
341.422
349.577
357.710
365.817
373.895
381.941
1.5586
1.7188
1.8693
2.0111
2.1448
2.2711
2.3906
2.5038
2.6112
2.7133
2.8104
2.9029
2.9912
3.0754
3.1559
3.2329
3.3067
3.3774
3.4453
3.5104
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
'X
©
+
'*
О
VO
со
00
со
§
о
1
.9636 hue
со
со
сч
«о
со
об
«о
сч
т
со
X
VO
сч
о
сч
X
ON
VO
со
со
1
I
X
«¦н
VO
00
8
о
о
V
2 > 000
..
II
X
92

Класс точности
I
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.788
21.079
21.838
21.852
22.467
22.744
22.781
22.692
22.549
22.389
22.233
22.089
21.959
21.843
21.742
21.652
21.573
21.504
21.443
21.389
21.341
21.298
21.260
21.226
21.195
21.167
21.142
21.119
21.099
21.080
21.063
21.047
21.032
21.019
21.007
20.995
20.985
20.975
20.966
20.958
20.950
20.943
20.936
20.929
20.923
20.918
20.912
20.907
20.903
20.898
20.894
20.890
20.886
20.883
20.879
20.876
20.873
20.870
20.867
20.865
20.862
Ф°(Т)
*~ 1
Дж • К • моль
121.279
135.694
144.044
144.174
150.266
155.054
159.009
162.378
165.311
167.907
170.233
172.338
174.261
176.028
177.663
179.184
180.605
181.938
183.193
184.379
185.502
186.570
187.586
188.557
189.484
190.373
191.226
192.046
192.836
193.597
194.331
195.041
195.727
196.392
197.037
197.662
198.269
198,860
199.434
199.992
200.537
201.067
201.585
202.089
202.583
203.064
203.535
203.996
204.446
204.887
205.319
205.742
206.157
206.564
206.963
207.354
207.739
208.116
208.487
# 208.851
209.209
-1
142.065
156.526
165.076
165.214
171.593
176.642
180.794
184.301
187.322
189.968
192.319
194.431
196.348
198.101
199.716
201.212
202.607
203.913
205.140
206.298
207.394
208.434
209.424
210.368
211.271
212.136
212.966
213.763
214.531
215.271
215.985
216.676
217.344
217.991
218.618
219.227
219.818
220.393
220.952
221.496
222.027
222.544
223.049
223.541
224.022
224.493
224.952
225.402
225.842
226.2/3
226.695
227.109
227.515
227.912
228.303
228.686
229.062
229.431
229.794
230.151
230.502
ХЛОР С1 (г)
кДж • моль
/•
К
2.079 — 100
4.166 — 200
6.272 — 298.15
6.312 — 300
8.531 — 400
10.794 — 500
13.072 — 600
15.346 — 700
17.608 — 800
19.855 — 900
22.086 - 1000
24.302 — 1100
26.504 — 1200
28.694 — 1300
30.874 — 1400
33.043 — 1500
35.204 — 1600
37.358 — 1700
39.506 — 1800
41.647 — 1900
43.783 — 2000
45.915 — 2100
48.043 - 2200
50.168 — 2300
52.289 — 2400
54.407 — 2500
56.522 — 2600
58.635 — 2700
60.746 — 2800
62.855 — 2900
64.962 — 3000
67.068 — 3100
69.172 — 3200
71.274 - 3300
73.375 — 3400
75.475 — 3500
77.574 — 3600
79.673 - 3700
81.770 — 3800
83.866 — 3900
85.961 — 4000
88.056 - 4100
90.150 — 4200
92.243 — 4300
94.336 — 4400
96.428 — 4500
98.519 — 4600
100.610 — 4700
102.701 — 4800
104.791 - 4900
106.880 — 5000
108.969 — 5100
111.058 — 5200
113.147 — 5300
115.235 — 5400
117.323 — 5500
119.410 — 5600
121.497 — 5700
123.584 — 5800
125.671 — 5900
127.757 — 6000
Таблица 52
„_,
i
§
Т 2 Т
g м §
* о Т
«*> . а ^ *?
^ о Г^1 &
• сч *"• J2-
•О \© || 1—Ч
*° eC ^ О
и 2 ? §
¦^ 1Г *° ЧО
/'~s 00
* и" о S
0 со
U Т
с й
о о
о* ?
+ ^.
со * О
«о ^ о
N Ц О
о тх V
О *О ?*,
к го V
i J §
<N X *°
СЧ •-•
Г*; ^t <*
JT{ -у! О
СЧ ОО ^н
vo г-
СЧ СО II
О со
«о -! ?
сч с?
и 1
С
%
93

ХЛОР С1 (г)
Таблица 52
(окончание)
С°р (Т)
Ф°G)
к
Дж К -моль
Я°(Г)-Я°@)
кДж • моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.858
20.853
. 20.850
20.846
20.843
20.840
20.837
20.834
20.832
20.830
20.828
20.826
20.824
20.822
20.821
20.819
20.818
20.817
20.816
20.814
209.907
210.582
211.236
211.871
212.486
213.084
213.665
214.231
214.781
215.318
215.840
216.351
216.848
217.335
217.810
218.275
218.729
219.174
219.609
220.036
231.186
231.848
232.489
233.112
233.716
234.303
234.874
235.430
235.971
236.498
237.012
237.514
238.004
238.483
238.951
239.409
239.856
240.295
240.724
241.144
131.929
136.100
140.270
144.440
148.609
152.777
156.945
161.112
165.279
169.445
173.611
177.776
181.941
186.106
190.270
194.434
198.598
202.761
206.924
211.088
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
I
o
<^
s
о
I ^
о
о
0.02
V
V
со
VO
<N
VO
d
S §
ON t'
00 bi
4 II
о ^
94

Класс точности
I-B
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ОТРИЦАТЕЛЬНЫЙ ИОН
К°(Т)=р(С\)'р{е)
Ф°(Т)
Дж • К~ * • моль
20.786 132.460
20.786 132.588
20.786 138.568
20.786 143.206
20.786 146.996
20.786 150.200
20.786 152.976
20.786 155.424
20.786 157.614
20.786 159.595
20.786 161.404
20.786 163.068
20.786 164.608
20.786 166.042
20.786 167.384
20.786 168.64?
20.786 169.832
20.786 170.956
20.786 172.022
20.786 173.036
20.786 174.003
20.786 174.927
20.786 175.812
20.786 176.660
20.786 177.475
20.786 178.260
20.786 179.016
20.786 179.745
20.786 180.450
20.786 181.131
20.786 181.791
20.786 182.431
20.786 183.051
20.786 183.654
20.786 184.240
20.786 184.809
20.786 185.363
20.786 185.903
20.786 186.430
20.786 186.943
20.786 187.444
20.786 187.933
20.786 188.411
20.786 188.878
20.786 189.335
20.786 189.782
20.786 190.219
20.786 190.648
20.786 191.068
20.786 191.480
20.786 191.883
20.786 192.279
20.786 192.668
20.786 193.049
20.786 193.424
20.786 193.791
20.786 194.153
20.786 194.508
20.786 194.858
•Р-'(СГ)
S°(T)
153.246
153.374
159.354
163.992
167.782
170.986
173.762
176.210
178.400
180.381
182.190
183.854
185.394
186.828
188.170
189.430
190.618
191.742
192.808
193.822
194.789
195.713
196.598
197.446
198.261
199.046
199.802
200.531
201.236
201.917
202.577
203.217
203.837
204.440
205.026
205.595
206.149
206.689
207.216
207.729
208.230
208.719
209.197
209.664
210.121
210.568
211.005
211.434
211.854
212.265
212.669
213.065
213.454
213.835
214.209
214.577
214.939
215.294
215.644
н°т-н'
ХЛОРА С1 " (г)
АгН°@) = 348,700
кДж • моль
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
-60.4806
-60.0971
-44.6006
-35.2435
-28.9656
-24.4530
-21.0472
-18.3819
-16.2367
-14.4709
-12.9906
-11.7308
-10.6446
-9.6978
-8.8647
-8.1254
-7.4646
-6.8701
-6.3321
-5.8427
-5.3953
-4.9847
-4.6063
-4.2563
-3.9315
-3.6292
-3.3471
-3.0830
-2.8353
-2.6024
-2.3829
-2.1757
-1.9797
-1.7940
-1.6177
-1.4501
-1.2906
-1.1385
-.9933
-.8545
-.7217
-.5945
-.4725
-.3554
-.2428
-.1345
-.0302
.0703
.1672
.2607
.3511
.4384
.5229
.6047
.6839
.7606
.8351
.9073
.9775
кДж • моль
Г
К
298.15
300
400
500
6QU "
~~700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
•
•о
СО
II
~Х
сч
§
р
о
+
™х
со
§
о
р
о
g
со
ЧО
00
Г-;
О
сч
сч
г-
»о
о
сч
II
Т а б
i
§
д
о
оо
р
ON
сч
сч
1
и
|
0
о
<г
т
о
Т
X
1
о
1
с* •
X
О
р
о
X
со
о
р
о
1
л и ц а 53
-
2
Ъ? 1
S g
X О
о *
со '
сч .
и JS
С О
л со
*""? чо
00 —<
сч «
с о 9
о о?
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G
о
о
о
ЧО
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V
V
§
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^."
1
о
II
X
95

ОТРИЦАТЕЛЬНЫЙ ИОН ХЛОРА С1 " (г)
Таблица 53
(окончание)
С°р (Т)
Ф°(Г)
ДжК моль"
Я°(Г)-Я°@)
кДж * моль
-1
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
195.539
196.199
196.839
197.459
198,062
198.647
199.217
199.771
200.311
200.837
201.351
201.852
202.341
202.818
203.286
203.742
204.189
204.627
205.056
205.476
216.325
216.985
217.625
218.245
218.848
219.433
220.003
220.557
221.097
221.623
222.137
222.637
223.127
223.604
224.072
224.528
224.976
225.413
225.842
226.262
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
1.1119
1.2390
1.3594
1.4737
1.5823
1.6859
1.7846
1.8789
1.9691
2.0555
2.1383
2.2179
2.2943
2.3678
2.4387
2.5069
2.5728
2.6364
2.6978
2.7573
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
8
О
+
О
О
О
2
§
о
о
V
V
О
I «
96

Класс точности
I-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
38G0
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ДИХЛОРС12 (г)
K°m = P2(ci)-pml(ci2) zw/
Ф°(Т)
Дж • К • моль
29.299
31.720
33.949
33.981
35.296
36.060
36.525
36.814
36.992
37.103
37.181
37.248
37.318
37.399
37.494
37.604
37.728
37.865
38.016
38.182
38.364
38.564
38.785
39.030
39.300
39.596
39.917
40.263
40.631
41.017
41.417
41.823
42.232
42.636
43.028
43.404
43.756
44.079
44.369
44.622
44.835
45.006
45.132
45.214
45.251
45.243
45.193
45.102
44.971
44.803
44.600
44.366
44.103
43.814
43.502
43.169
42.818
42.452
42.074
41.685
41.288
f#V)-//°«)>
кДж • моль
159.778 188.897 2.912
180.106 209.854 5.950
192.176 222.965 9.180
192.367 223.179 9.244
201.368 233.153 12.714
208.549 241.118 16.285
214.544 247.737 19.916
219.700 253.391 23.584
224.226 258.319 27.275
228.261 262.683 30.980
231.902 266.597 34.695
235.220 270.144 38.416
2313.267 273.388 42.144
24?.085 276.378 45.880
243.707 279.152 49.624
246.157 281.743 53.379 .
248.458 284.174 57.146
250.627 286.465 60.925
252.679 288.634 64.719
254.626 290.694 68.529
256.478 292.656 72.356
258.246 294.533 76.202
259.937 296.332 80.070
261.557 298.061 83.960
263.113 299.728 87.877
264.610 301.338 91.821
266.053 302.897 95.797
267.445 304.410 99.805
268.792 305.881 103.850
270.096 307.314 107.932
271.360 308.711 112.054
272.587 310.076 116.216
273.779 311.410 120.419
274.939 312.716 124.662
276.069 313.994 128.945
277.171 315.247 133.267
278.246 316.475 137.625
279.295 317.678 142.017
280.321 318.858 146.440
281.324 320.013 150.890
282.305 321.146 155.363
283.266 322.255 159.855
284.207 323.341 164.363
285.130 324.404 168.880
286.034 325.444 173.404
286.922 326.461 177.929
287.792 327.455 182.451
288.646 328.426 186.966
289.485 329.374 191.470
290.308 330.300 195.959
291.117 331.203 200.429
291.912 332.084 204.877
292.693 332.943 209.301
293.460 3:33.780 213.697
294.214 334.596 218.063
294.956 335.392 222.396
295.685 336.166 226.696
296.402 336.921 230.960
297.107 337.656 235.186
297.800 338.372 239.374
298.482 339.069 243.522
э@) =239.240
-120.6406
-57.7142
-36.9034
-36.6413
-26.0614
-19.6880
-15.4226
-12.3646
-10.0630
-8.2670
-6.8257
-5.6430
-4.6547
-3.8162
-3.0957
-2.4697
-1.9208
-1.4354
-1.0031
-.6155
-.2660
.0507
.3391
.6027
.8448
1.0677
1.2737
1.4647
1.6421
1.8074
1.9617
2.1061
2.2415
2.3687
2.4884
2.6012
2.7077
2.8084
2.9036
2.9939
3.0796
3.1611
3.2385
3.3123
3.3826
3.4497
3.5138
3.5751
3.6337
3.6899
3.7438
3.7955
3.8452
3.8929
3.9389
3.9831
4.0257
4.0669
4.1066
4.1449
4.1820
кДж-моль""
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
17КШ__.
Т800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 54
1
•2
о
?
т.
1 о i
о " ^~^
«> /-> О
II V vo
^ О кг) •
~ Z ^
О оо н
с>< г о л
° и
^ о
1
v i
,7Ш
•мол
о **
J. 1
! %
Я п Я
f- О
»О го о
о н о
ЧО <*} чо
2 g V,
О ON \/
& ОО
^ й к
н ' V
J5 ^ о
о S ">
Ov Tf ^. -
со ^ О
+ Д ?
I ц ¦
§ т
СО 1
II
о""'
ф
7 872
97

ДИХЛОР С12 (г)
Таблица 54
(окончание)
С°р(Т)
Дж К -моль""
#°(Г)~#°@)
к Дж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
40.477
39.655
38.833
38.021
37.226
36.454
35.708
34.992
34.306
33.652
33.029
32.439
31.879
31.349
30.849
30.376
29.930
29.509
29.111
28.737
299.813
301.102
302.350
303.559
304.732
305.868
306.971
308.041
309.079
310.088
311.068
312.021
312.947
313.848
314.725
315.578
316.410
317.219
318.009
318.779
340.410
341.682
342.890
344.036
345.127
346.165
347.153
348.096
348.996
349.856
350.680
351.468
352.225
352.952
353.651
354.323
354.972
355.597
356.202
356.786
251.699
259.712
267.560
275.246
282.770
290.137
297.353
304.422
311.351
318.146
324.814
331.360
337.791
344.113
350.332
356.454
362.484
368.427
374.289
380.073
К
4.2525
4.318»
4.381 J
4.4399
4.4954
4.5481
4.5982
4.6458
4.6912
4.7346
4.7761
4.8159
4.8542
4.8909
4.9263
4.9605
4.9934
5.0253
5.0561
5.0860
6200
6400
6600
6800
7000_
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9400
9600
9800
10000
го
00
го
00
о
о
о
о
о
о
- V
V
00
ON
сч
О
о
о
о
II
р
98

Класс точности
Ш-А
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
160D
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г; (л
30.879
33.492
34.47 i
34.488
35.298
35.927
36.395
36.745
37.015
37.231
37.410
37.564
37.700
37.824
37.939
38.049
38.154
38.257
38.360
38.462
38.564
38.668
38.772
3&.878
38.984
39.090
39.195
39.297
39.397
39.492
39.581
39.662
39.735
39.798
39.850
39.890
39.916
39.929
39.928
39.913
39.883
39.838
39.779
39.707
39.620
39.521
39.410
39.287
39.154
39.011
38.859
38.698
38.531
38.357
38.178
37.995
37.808
37.618
37.425
37.231
37.037
A'V)=p(Cl)'p
Ф°(Т)
Дж • К • моль
159.658
180.507
193.056
193.254
202.551
209.911
216.022
221.258
225.842
229.924
233.603
236.954
240.031
242.877
245.525
248.000
250.324
252.516
254.589
256.556
258.427
260.212
261.919
263.554
265.123
266.631
268.084
269.485
270.838
272.146
273.412
274.639
275.829
276.985
278.109
279.201
280.265
281.301
282.311
283.296
284.258
285.196
286.114
287.010
287.887
288.745
289.585
290.407
291.213
292.002
292.775
293.534
294.277
295.007
295.723
296.426
297.116
297.794
298.460
299.114
299.757
ОКСИД ХЛОРА СЮ
[о^тГЧао) д //
s°xn
-1
H°{T)-H°(i))
кДж * моль
189.020 2.936
211.426 6.184
224.992 9.522
225.205 9.585
235.241 13.076
243.189 16.639
249.783 20.256
255.421 .23.914
260.345 27.603
264.718 31.315
268.650 35.048
272.223 38.796
275.498 42.560
278.520 46.336
281.328 50.124
283.949 53.924
286.406 57.734
288.724 61.555
290.914 65.385
292.991 69.227
294.966 73.078
296.850 76.939
298.651 80.812
300.377 84.694
302.034 88.587
303.628 92.491
305.163 96.405
306.644 100.330
308.075 104.264
309.459 108.209
310.800 112.163
312.099 116.125
313.359 120.095
314.583 124.072
315.772 128.054
316.927 132.041
318.051 136.031
319.145 140.024
320.210 144.017
321.247 148.009
322.257 151.999
323.242 155.985
324.201 159.965
325.136 163.940
326.048 167.906
326.937 171.863
327.804 175.809
328.651 179.744
329.476 183.666
330.282 187.574
331.069 191.467
331.837 195.345
332.586 199.206
333.319 203.050
334.034 206.876
334.733 210.685
335.416 214.475
336.083 218.245
336.735 221.997
337.373 225.729
337.997 229.442
(г)
\()) -265.38С
lgA'V)
-134.6806
-64.8936
-41.8242
-41.5337
-29.8123
-22.7566
-18.0386
-14.6592
-12.1180
-10.1369
-8.5484
-7.2460
-6.1585
-5.2366
-4.4449
-3.7577
-3.1554
-2.6232
-2.1494
-1.7248
-1.3422
-.9956
-.6801
-.3917
-.1271
.1167
.3419
.5507
.7447
.9256
1.0945
1.2527
1.4011
1.5406
1.6720
1.7960
1.9132
2.0242
2.1294
2.2292
2.3242
2.4146
2.5008
2.5830
2.6616
2.7368
2.8088
2.8777
2.9439
3.0075
3.0686
3.1273
3.1839
3.2385
3.2911
3.3418
3.3909
3.4383
3.4842
3.5285
3.5715
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
¦200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 55
-1
^_
_ о
§ к х*
§ 1=1 с:
т *; о
& 5>
Р$: "Z -<'
™ ел Л Ы
4 3 2 А
- S 1 *
" V a jo
О 2 7
с S "
^ г| а
О Сой
С к °°
^ о
о Г
^ о~
!
>^
з ^
<N 3
О 2
+ ^*
'* г* ^
2 i *
*-< Д °
g ro S
Я Д v
о о v
+ ^ К
О О
*О 00 '*
• . 1
? °" о
4- •—'
оо ? К.
С4 -~ II
г: d *
ГО 1
„
С
Ф
99

Класс точности
Ш-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
33.829
37.620
42.000
42.081
46.072
49.142
51.386
53.024
54.239
55.163
55.882
56.457
56.927
57.319
57.654
57.944
58.199
58.429
58.637
58.828
59.006
59.173
59.332
59.486
59.635
59.781
59.926
60.071
60.218
60.368
60.523
60.682
60.847
61.020
61.201
61.390
61.589
61.798
62.017
62.246
62.486
62.736
62.997
63.268
63.550
63.840
64.141
64.450
64.767
65.092
65.424
65.762
66.106
66.455
66.809
67.166
67.525
67.887
68.251
68.615
68.979
К°(Т)=р(С1)
Ф°(Т)
ДИОКСИД ХЛОРА С1О2 (г)
•р^-р'1 (СЮ2) Дг//
Дж • К • моль
183.075
206.468
220.545
220.770
231.471
240.208
247.676
254.238
260.108
265.428
270.298
274.791
278.963
282.859
286.513
289.956
293.209
296.293
299.226
302.022
304.693
307.250
309.703
312.060
314.328
316.515
318.624
320.664
322.637
324.548
326.401
328.199
329.947
331.646
333.299
334.910
336.479
338.011
339.505
340.964
342.392
343.786
345.152
346.488
347.797
349.080
350.339
351.573
352.785
353.974
355.143
356.291
357.420
358.530
359.623
360.698
36L757
362.800
363.827
364.839
365.837
216.418
240.933
256.769
257.029
269.702
280.329
289.498
297.549
304.713
311.157
317.008
322.361
327.295
331.867
336.126
340.114
343.863
347.398
350.743
353.920
356.941
359.825
362.581
365.221
367.757
370.194
372.542
374.805
376.994
379.109
381.158
383.144
385.075
386.950
388.774
390.551
392.283
393.973
395.624
397.238
398.817
400.362
401.878
403.363
404.821
406.252
407.659
409.041
410.402
411.741
413.059
414.358
415.638
416.900
418.145
419.375
420.588
421.787
422.970
424.140
425.297
//°G')-//°@)
кДж • моль
3.334
6.893
10.800
10.878
15.293
20.061
25.093
30.318
35.684
41.156
46.710
52.328
57.998
63.711
69.459
75.240
81.047
86.879
92.732
98.606
104.497
110.406
116.332
122.273
128.229
134.200
140.185
146.185
152.199
158.228
164.273
170.333
176.410
182.503
188.614
194.743
200.892
207.061
213.252
219.465
225.702
231.963
238.250
244.562
250.904
257.272
263.672
270.101
276.562
283.055
289.581
296.140
302.733
309.361
316.024
322.723
329.457
336.228
343.035
349.879
356.757
э@) = 505.714 кДж-моль
\gK°(T)
-255.4971
-122.2613
-78.1363
-77.5803
-55.1336
-41.6138
-32.5721
-26.0965
-21.2288
-17.4353
-14.3952
-11.9039
-9.8248
-8.0634
-6.5518
-5.2402
-4.0915
-3.0769
-2.1743
-1.3659
-.6378
.0214
.6211
1.1690
1.6717
2.1343
2.5617
2.9576
3.3254
3.6680
3.9880
4.2874
4.5682
4.8321
5.0806
5.3150
5.5365
5.7460
5.9445
6.1330
6.3120
6.4823
«.6446
6.7993
6.947Q
7.0882
7.2232
7.3525
7.4764
7.5952
7.7092
7.8188
7.9241
8.0255
8.1230
8.2169
8.3075
8.3949
8.4792
8.5606
8.6392
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
Г^
V©
II
+•
'«8
«о
со
<Ч
+
00
оо
о
t—4
О
1
а
в
ЧО
а
•
«о
•о
J.
00
00
Tf
^«
VO
00
со
. и
с
ол
Т а б л и
1А
ГА 1
1 А
1 5
П о
* о
«*- О
Ч ~*
г- II
о ^
7 *
«о
О лл
? с.
U, о
° S
<J
7
А
т
к
ООбх'
00
+
н
со
о
1
а
00
«S
со
со*
»—t
+
ца 56
1
1А
О
т
т
i
vO
II
Et
о at;
со
->
я
о
у /
V
V
g
•o
II
100

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
«OUV
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.493
42.250
47.807
47.891
51.376
53.455
54.748
55.589
56.162
56.568
56.865
57.087
57.259
57.397
57.506
57.593
57.665
57.723
57.773
57.819
57.853
57.886
57.916
57.936
57.957
57.978
57.995
58.008
58.024
58.033
58.045
58.054
58.062
58.070
58.079
58.087
58.091
58.095
58.104
58.108
58.112
58.116
58.121
58.125
58.129
58.129
58.133
58.137
58.137
58.141
58.141
58.146
58.146
58.150
58.150
58.154
58.154
58.154
58.158
58.158
58.158
А'°(Л=р2(С1)-/?(С
Ф°(Л
Дж • К • моль
189.466
213.570
228.612
228.855
240.524
250.114
258.293
265.448
271.808
277.536
282.745
287.528
291.946
296.055
299.887
303.485
306.874
310.075
313.109
315.996
318.744
321.368
323.878
о26.284
328.598
330.820
332.962
335.029
337.020
33&949
340.815
342.627
344.380
346.083
347.736
349.347
350.912
352.435
353.920
355.372
356.782
358.163
359.510
360.828
362.116
363.376
364.610
365.819
367.003
368.162
369.300
370.418
371.510
372.585
373.639
374.677
375.694
376.694
377.677
378.644
379.597
ОКСИД ДИХЛОРА
«•рТЧс^о)
223.223
249.854
267.837
268.134
282.431
294.138
304.008
312.515
319.979
326.619
332.594
338.025
342.999
347.589
351.849
355.820
359.539
363.037
366.334
369.459
372.426
375.250
377.945
380.522
382.987
385.355
387.627
389.815
391.928
393.961
395.932
397.836
399.677
401.463
403.200
404.881
406.517
408.112
409.660
411.170
412.639
414.074
415.476
416.844
418.178
419.484
420.764
422.015
423.237
424.438
425.613
426.764
427.894
428.998
430.086
431.153
432.203
433.233
434.241
435.237
436.216
Н°(Г)-Н°(()
кДж * моль
3.372
7.255
11.694
11.782
16.761
22.012
27.426
32.945
38.535
44.171
49.849
55.543
61.263
66.995
72.744
78.497
84.262
90.032
95.802
101.580
107.363
113.149
118.944
124.743
130.530
136.337
142.124
147.919
153.739
159.533
165.349
171.144
176.947
182.751
188.575
194.370
200,177
206.001
211.809
217.612
223.424
229.235
235.055
240.867
246.670
252.486
258.306
264.118
269.917
275.745
281.561
287.364
293. Г97
298.988
304.812
310.615
316.452
322.272
328.071
333.899
339.707
С12О(Г)
Я°@) =405.196
)
1
lgtfV)
-202.9341
-96.0486
-60.6523
-60.2063
-42.2047
-31.3637
-24.1128
-18.9188
-15.0131
-11.9680
-9.5265
-7.5249
-5.8538
-4.4374
-3.2210
-2.1652
-1.2400
-.4224
.3055
.9575
1.5451
2.0776
2.5623
3.0054
3.4119
3.7866
4.1327
4.4536
4.7521
5.0302
5.2901
5.5333
5.7618
5.9766
6.1791
6.3701
6.5508
6.7220
6.8843
7.0383
7.1850
7.3246
7.4578
7.5848
7.7062
7.8225
7.9337
8.0403
8.1426
8.2409
8.3354
8.4261
8.5138
8.5980
8.6793
8.7576
8.8334
8.9065
8.9773
9.0457
9.1118
кДж-моль
Г
К
100
200
298.15
30Q
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3580
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
8
ON
VO
00
II
+
т
?
00
00
On
О
+
1
&
ON
с~-
ю
О
О
О
1
х
<N
ON
rt
t-^
О*
+
сч
rf
ON
II
о
•е-
Т а б л и
'-а
~, О
1* ?
о J5
2 ^
Д о
3 §
.82
§ Я
II «о
'—'
О ОО
On
<э с
G d
О pi
> &
<i
f
1
к
ГО
VO
О
+
|
н
ю
00
t--
+
ца 57
§
2
—
к
R.
^
ГО
II
d
о о?
со
?
О
О
о
V
V
500'
i
II
X
101

Класс точное i и
IB
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ХЛОРИД ВОДОРОДА НС1 (г)
К°(Т) = р<П)-р
Ф°G)
Дж К моль
29.116 126.290
29.124 146.257
29.136 157.813
29.136 157.992
29.175 166.335
29.304 172.815
29.575 178.119
29.987 182.615
30.498 186.524
31.061 189.989
31.637 193.107
32.199 195.946
32.731 198.556
33.225 200.974
33.680 203.230
34.095 205.345
34.474 207.338
34.818 209.224
35.132 211.013
35.418 212.717
35.681 214.344
35.922 215.901
36.145 217.395
36.351 218.829
36.544 220.210
36.723 221.542
36.892 222.828
37.052 224.071
37.203 2*>5 274
37.347 226.440
37.485 227.571
37.617 228.670
37.743 229.737
37.866 230.776
37.984 231.788
38.099 232.773
38.209 233.734
38.317 234.672
38.421 235.588
38.521 236.483
38.617 237.357
38.710 238.213
38.799 239.050
38.883 239.870
38.963 240.673
39.038 241.460
39.108 242.232
39.172 242.989
39.230 243.732
39.282 244.461
39.328 245.177
39.366 245.880
39.398 246.572
39.423 247.251
39.440 247.919
39.450 248.576
39.452 249.222
39.446 249.858
39.432 250.484
39.411 251.101
39.382 251.708
(( 1).р-|A1П)
- \
154.976
175.160
186.786
186.971
195.357
201.878
207.243
211.831
215.868
219.492
222.794
225.836
228.661
231.301
233.780
236.118
238.331
240.431
242.430
244.337
246.161
247.906
249.584
251.195
252.747
254.242
255.686
257.081
258.431
259.739
261.008
262.239
263.435
264.599
265.731
266.833
267.908
268.957
269.980
270.979
271.956
272.910
273.844
274.758
275.653
276.529
277.388
278.230
279.055
279.865
280.659
281.438
282.203
282.954
283.691
284.414
285.125
285.823
286.509
287.183
287.845
То Г) л ы и а ^8
Д //"<Ш 427.780 кДж-моль
Н \Т)-Н'\0)
кДж • моль
2.869 -219.9936
5.781 -107.8078
8.640 -70.7628
8.693 -70.2965
11.609 -51.4812
14.531 -40.1550
17.474 -32.5793
20.451 -27.1507
23.475 -23.0665
26.552 -19.8806
29.687 -17.3249
32.879 -15.2284
36.126 -13.4771
39.424 -119918
42.770 -10.7160
46.159 -9.6082
49.588 -8.6369
53.052 -7.7785
56.550 -7.0141
60.078 -6.3291
63.633 -5.7117
67.213 -5.1523
70.817 -4.6430
74.442 -4.1774
78.087 • -3.7501
81.750 -3.3565
85.431 -2.9928
89.128 -2.6556
Q9 Я41 -9 4491
С/^.Отг 1 Z.O4Z 1
96.569 -2.0500
100.310 -1.7771
104.066 -1.5215
107.834 -1.2817
111.614 -1.0563
115.407 -.8439
119.211 -.6435
123.026 -.4540
126.853 -.2747
130.689 -.1046
134.537 .0568
138.393 .2103
142.260 .3563
146.135 .4955
150.020 .6284
153.912 .7552
157.812 .8765
161.719 .9926
165.633
169.553
173.479
177.410
181.344
185.283
189.224
193.167
197.112
201.057
.1038
.2105
.3128
.4111
.5056
.5965
.6840
.7683
.8496
.9281
205.002 2.0038
208.946 2.0769
212.888 2.1476
216.827 2.2159
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
. 1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
oftfiO
*OUu
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4iOO
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5&00
5600
5700
5800
5900
6000
!
_ О
Л
5 =* '-
7*5
J5 о ^
^ С. —
S >о S! '*
3 - ' й
^ II иг; ;>
-^ ОС ^
, Cn !!
_' ' Ч
S -г ъ
о ZZ
>, -~
^- о
4
1
ОС —
" ¦
тг ^
о о
^С Л V
О =3 g
5 и ^
2 5 v
>. + V
.. о
?, й s
1/-, Q\
S ^ ^
о г- и
ОС -"N *"'
102

Класс точности
>V-1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.284
34.585
37.284
37.334
40.071
42.301
44.041
45.435
46.602
47.623
48.535
49,363
50.116
50.798
51.418
51.974
52.480
52.932
53.342
53.715
54.045
54.347
54.619
54.865
55.091
55.296
55.480
55.648
55.803
55.945
56.075
56.196
56.305
56.409
56.501
56.589
56.669
56.744
56.815
56.878
56.941
56.995
57.049
57.100
57.146
57.188
57-229
57.271
57.305
57.338
57.372
57.405
57,430
57.459
57.485
57.510
57.535
57.556
57.577
57.598
57.618
ГИДРОКСИД
К°(Т)=р(Н)-1
Ф°(Л
Дж К • моль
165.575
188.675
202.181
202.395
212.416
220.440
227.210
233.097
238.323
1 243.039
247.340
251.302
254.980
258.411
261.628
264.666
267.540
270.268
272.867
275.348
277.720
280.000
282.184
284.293
286.318
288.280
290.172
292.004
293.779
295.498
297.172
298.795
300.372
301.908
303.406
304.862
306.285
307.673
309.025
310.352
311.644
312.912
314.151
315.360
316.548
317.711
318.853
319.971
321.071
322.146
323.205
324.242
325.263
326.263
327.251
328.217
329.171
330.109
331.033
331.941
332.832
э(О)-р(С1)-рв1<
.У"</)
-1
198.834
222.177
236.474
236.704
247.829
257.022
264.896
271.791
277.938
283.485
288.552
293.218
297.548
301.586
305.372
308.941
312.309
315.506
318.544
321.439
324.201
326.845
329.380
331.816
334.154
336.410
338.581
340.677
342.707
344.665
346.564
348.405
350.192
351.924
353.610
355.250
356.844
358.401
359.911
361.388
362.832
364.238
365.610
366.953
368.267
369.551
370.811
372.041
373.246
374.430
375.589
376.727
377.840
378.936
380.008
381.066
382.099
383.120
384.120
385.103
386.074
ХЛОРА НОС1
J1OC1) Д^//
Н'\Г)-Н°Ц))
кДж • моль
3.322
6.699
10.222
10.293
14.163
18.288
22.611
27.083
31.690
36.401
41.209
46.104
51.079
56.125
61.238
66.409
71.627
76.903
82.216
87.572
92.957
98.371
103.827
109.300
114.806
120.321
125.864
131.417
136.998
142^580
148.174
153.789
159.421
165.052
170.692
176.357
182.014
187.688
193.366
199.043
204.750
210.432
216.127
221.851
227.562
233.277
239.001
244.729
250.440
256.189
261.921
267.670
273.398
279.164
284.883
290.665
296.398
302.167
307.904
313.657
319.447
(г)
э@) -=669.49^
-342.3598
-166.3955
-108.1984
-107.4654
-77.8791
-60.0616
-48.1438
-39.6053
-33.1833
-28.1756
-24.1598
-20.8669
-18.1172
-15.7858
-13.7837
-12.0458
-10.5226
-9.1765
-7.9783
-6.9047
-5.9371
-5.0608
-4.2628
-3.5338
-2.8643
-2.2481
-1.6785
-1.1506
-.6598
-!2025
.2246
.6247
1.0001
1.3531
1.6855
1.9994
2.2959
2.5767
2.8431
3.0958
3.3363
3.5650
3.7832
3.9915
4.1904
4.3806
4.5626
4.7372
4.9043
5.0651
5.2194
5.3679
5.5107
5.6483
5.7808
5.9088
6.0322
6.1514
6.2665
6.3778
6.4857
Таблица 59
кДж-моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
oftOO
AOvv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
540С
5500
5600
5700
5800
5900
6000
о § -
? . '.д
? S ?
о <- S 7
1 8. ? *
N °° ^ Д
К 1 g EJ
II !1 «О \О
и см „
—г
о п ° *
Е о *°
о X
\ г
<
+
1
& т
1 i
ю §
о ?
+ -«
-, 1
7 5<
5 * Я
о Н g
Ьг Н О
Я о so
О ГО
• V
| «О V
* 7 к
Г- ? О
? 2 S
+ I s
ON ON Ь-
О rf И
ГО r"H ^
ГО v> ^^
ro 4.
о
ь
103

Класс точности
I-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
' 3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<;,л
29.113
29.124
29.170
29.172
29.406
29.912
30.612
31.386
32.148
32.852
33.480
34.032
34.514
34.934
35.301
35.623
35.907
36.160
36.387
36.591
36.777
36.946
37.103
37.249
37.385
37.513
37.634
37.750
37.861
37.968
38.071
38.171
38.268
38.363
38.456
38.547
38.636
38.723
38.808
38.891
38.971
39.049
39.123
39.194
39.262
39.325
39.384
39.437
39.486
39.529
39.566
39.597
39.622
39.640
39.650
39.654
39.650
39.639
39.620
39.594
39.560
К°(Т)= рФ)'р{С\)
Дж • К • моль
131.923
151.991
163.581
163.760
172.124
178,628
183.968
188.515
192.486
196.023
199.218
202.136
204.827
207.324
209.657
211.848
213.913
215.867
217.722
219.488
221.174
222.787
224.334
225.819
227.248
228.625
229.954
231.238
232.480
233.683
234.850
235.982
237!082
238.152
239.193
240.206
241.194
242.158
243.098
244.017
244.914
245.792
246.650
247.490
248.312
249.118
249.908
250.683
251.442
252.188
252.919
253.638
254.344
255.037
255.719
256.389
257.048
257.697
258.335
258.963
259.582
ХЛОРИД
¦р-ОХЛ)
s°m
160.813
180.995
192.629
192.810
201.228
207.839
213.352-
248.129
222.370
226.198
229.693
232.910
235.892
238.672
241.275
243.721
246.030
248.214
250.288
252.261
254.142
255.941
257.663
259.316
260.904
262.432
263.906
265.329
266.704
268.034
269.323
270.573
271.787
272.965
274.112
275.228
276.315
277.375
278.409
279.418
280.404
281.367
282.309 .
283.230
284.132
285.015
285.880
286.728
287.559
288.373
289.172
289.956
290.725
291.480
292.221
292.949
293.663
294.365
295.054
295.731
296.396
ДЕЙТЕРИЯ
\
Н\Т)-Н°М
кДж • моль
2.889
5.801
8.661
8.715
11.641
14.605
17.630
20.730
23.907
27.158
30.475
33.851
37.279
40.752
44.264
47.811
51.387
54.991
58.619
62.268
65.936
69.622
73.325
77.043
80.775
84.519
88.277
92.046
95.827
99.618
103.420
107.232
111.054
114.886
118.727
122.577
126.436
130.304
134.181
138.066
141.959
145.860
149.769
153.685
157.607
161.537
165.472
169.413
173.359
177.310
181.265
185.223
189.184
193.148
197.112
201.077
205.043
209.007
212.970
216.931
220.888
DC1 (г)
Н°(()) =432.760 кДж-моль
)
-222.4381
-108.9571
-71.4856
-71.0140
-51.9830
-40.5280
-32.8675
-27.3795
-23.2522
-20.0339
-17.4533
-15.3373
-13.5705
-12.0727
-10.7867
-9.6703
-8.6920
-7.8276
-7.0581
-6.3688
-5.7476
-5.1849
-4.6728
-4.2047
-3.7752
-3.3796
-3.0141
-2.6754
-2.3605
-2.0671
-1.7931
-1.5365
-1.2958
-1.0694
-.8562
-.6551
-.4650
-.2851
-.1145
.0475
.2014
.3480
.4876
.6208
.7480
.8696
.9860
1.0976
1.2045
1.3071
1.4056
1.5003
1.5914
1.6792
.7637
.8451
.9237
.9996
2.0729
2.1437
2.2122
¦/•
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
4900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
?
со
и
¦5
О
s
со
о
г*
1
г-
о
О
.1
g
О
со
•
О
со
ft
,
ф
Т а б л и
в;
*н О
1
§ *
к
_^ СО
Я <f
СО i
со II
On ^^
!! ю
^ —<
° 00*
S
7 О
1
ё
00
О
&
00
1
«о
.56
ца 60
7
•
•
El
Tt
<N
•О
п
о в*
со
я
о
8
\ /
V
V
g
«о
«г
1
о
к.
II
104

Класс точности
1-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
J500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.112
29.128
29.26"
29.275
29.785
30.602
31.527
32.415
33.205
33.684
34.459
34.944
35.355
35.705
36.007
36.269
36.498
36.702
36.884
37.048
37.198
37.336
37.463
37.583
37.696
37.802
37.905
38.003
38.098
38.190
38.280
38.368
38.454
38.539
38.623
38.705
38.786
38.866
38.944
39.020
39.094
39.166
39.236
39.302
39.365
39.425
39.480
39.530
39.576
39.616
39.650
39.679
39.701
39.717
39.725
39.727
39.721
39.709
39.688
39.661
39.626
к°<т)= Ра)р(с
Ф°СЛ
Дж К. - моль" *
135.307
155.409
167.012
167.192
175.571
182.103
187.484
192.082
196.110
199.705
202.958
205.934
208.678
211.227
213.608
215.844
217.951
219.944
221.836
223.637
225.355
226.998
228.572
230.084
231.538
232.938
234.289
235.594
236 856
238.078
239.262
240.411
241.527
242.611
243.667
244.694
245.695
246.671
247.623
248.553
249.461
250.349
251.217
252.067
252.899
253.713
254.512
255.294
256.062
256.815
257.554
258.280
258.992
259.692
260.380
261.057
261.722
262.377
263.020
263.654
264.278
ХЛОРИД
)р(ТС1)
S°(T)
164.265
184.447
196.095
196.276
204.758
211.489
217.150
222.077
226.458
230.410
234.010
237.318
240.376
243.221
245.878
248.371
250.720
252.939
255.042
257.040
258.944
260.763
262.502
264.170
265.772
267.313
268.798
270.230
271.614
272.952
274.249
275.506
276.725
277.910
279.061
280.182
281.274
282.337
283.375
284.387
285.376
286.342
287.287
288.211
289.115
290.001
290.868
291.717
292.550
293.367
294.167
294.953
295.724
296.480
297.222
297.951
298.667
299.370
300.060
300.739
301.405
ТРИТИЯ ТС1
V
п°(Т)-н°@)
кДж • моль*
2.896
5.808
8.671
8.725
11.675
14.693
17.799
20.997
24.279
27.634
31.052
34.523
38.038
41.592
45.178
48.792
52.430
56.091
59.770
63.467
67.179
70.906
74.646
78.398
82.162
85.937
89.723
93.518
ОТ ^9^
101.138
104.961
108.793
112.635
116.484
120.342
124.209
128.083
131.966
135.856
139.755
143.660
147.573
151.493
155.420
159.354
163.293
167.239
171.189
175.144
179.104
183.067
187.034
19.1.003
194.974
198.946
202.919
206.891
210.863
214.833
218.800
222.764
(г)
-/о@) ¦= 434.940
\gK°(T)
-223.4906
-109.4419
-71.7837
-71.3097
-52.1847
-40.6742
-32.9779
-27.4655
-23.3208
-20.0897
-17.4995
-15.3761
-13.6035
•12.1011
-10.8113
-9.6919
-8.7111
-7.8445
-7.0732
-6.3824
-5.7599
-5.1960
-4.6829
-4.2140
-3.7837
-3.3874
-3.0213
-2.6821
9 4fifi7
"Z.OOO/
-2.0729
-1.7985
-1.5415
-1.3005
-1.0738
-.8604
-.6590
-.4687
-.2885
-.1177
.0444
.1985
.3452
.4849
.6183
.7456
.8673
.9839
1.0955
1.2025
1.3052
1.4038
1.4986
1.5898
1.6775
1.7621
1.8436
1.9223
1.9982
2.0716
2.1424
2.2110
кДж'моль*
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛА
ZOKJyJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
ю
^t
00
со
II
1
со
<N
«О
^
О
+
С4
Ю
гч
ON
о
<^>
О
g
00
ЧО
<N
ON
с4
со
+
со
(««.
II
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е
Т а б л и
Та
с;
Та Р
§ *
X о
i f
00 '
СП 1!
I» ^
'О 00
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U <N
г . —*
Ё с
о ё
^ °>
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I
А
К
О
1
k
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с»
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1
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ца 61
§
t
а
k
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ON
00
Г4!
II
п
о в;
со
я
о
§
V
V
о
о
«о
1
II
><
105

Класс точности
III-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
340*)
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;<п
29.124
30.129
32.086
32.122
33.753
34.866
35.618
36.143
36.524
36.814
37.043
37.231
.37.390
37.529
37.654
37.770
37.879
37.985
38.090
38.197
38.307
38.424
38.550
38.684
38.830
38.986
39.154
39.332
39.518
39.712
39.910
40.109
40.308
40.502
40.688
40.865
41.027
41.175
41.304
41.413
41.501
41.565
41.607
41.624
41.616
41.585
41.530
41.452
41.351
41.230
41.088
40.927
40.749
40.554
40.345
40.122
39.887
39.641
39.386
39.123
38.853
К°(Т)= /?(Cl)-p(F
ф°G)
Дж • К" 1 • моль" 1
155.961
176.159
187.951
188.136
196.841
203.764
209.548
214.531
218.915
222.833
226.377
229.614
232.594
235.356
237.929
240.339
242.605
244.744
246.769
248.693
250.524
252.273
253.946
255.549
257.089
258.571
259.998
261.376
осо 707
A,\J?t. 1 \3 1
263.995
265.243
266.454
267.629
268.771
269.882
270.963
272.017
273.045
274.048
275.028
275.985
276.921
277.836
278.732
279.609
280.468
281.309
282.135
282.944
283.737
284.516
285.281
286.031
286.768
287.492
288.203
288.901
289.588
290.263
290.927
291.579
ФТОРИД ХЛОРА
)-p"!(ClF)
S°(T)
185.047
205.438
217.831
218.030
227.508
235.167
241.595
247.127
251.979
256.298
260.189
263.729
266.976
269.974
272.760
275.362
277.803
280.102
282.276
284.339
286.301
288.172
289.963
291.680
293.329
294.917
296.449
297.931
OQQ ^fi4
300.754
302.104
303.416
304.692
305.936
307.148
308.330
309.483
310.609
311.709
312.783
313.833
314.859
315.861
316.840
317.797
318.732
319.645
320.537
321.409
322.261
323.092
323.904
324.697
325.472
326.228
326.966
327.687 '
328.391
329.078
329.749
330.404
11°(T)-H°((
кДж • моль
2.909
5.856
8.909
8.968
12.267
15.701
19.228
22.817
26.452
30.119
33.812
37.526
41.258
45.004
48.763
52.534
56,317
60.110
63.914
67.728
71.553
75.390
79.238
83.100
86.976
90.866
94.773
98.697
1 ПО ААП
1UZ.04U
106.601
110.582
114.583
118.604
122.645
126.704
130.782
134.877
138.987
143.111
147.247
151.393
155.546
159.705
163.867
168.029
172.189
176.345
180.494
184.634
188.763
192.879
196.980
201.064
205.129
209.174
213.197
217.197
221.174
225.125
229.050
232.949
C1F (г)
№(()) - 252.500 кДж'моль*
))
-1
\&К°(Т)
-127.7732
-61.3663
-39.3854
-39.1084
-27.9238
-21.18*35
-16.6724
-13.4388
-11.0060
-9.1083
-7.5862
-6.3377
-5.2949
-4.4106
-3.6510
-2.9915
-2.4133
-1.9023
-1.4473
-1.0395
-.6719
-.3388
-.0356
.2416
.4961
.7304
.9470
1.1478
1 4^44
1.5083
1.6707
1.8228
1.9654
2.0995
2.2258
2.3449
2.4574
2.5639
2.6647
2.7605
2.8514
2.9380
3.0204
3.0990
3.1740
3.2457
3.3143
3.3799
3.4429
3.5032
3.5612
3.6169
3.6705
3.7221
3.7717
3.8196
3.8659
3.9105
3.9536
3.9953
4.0356
Г
• К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
^t
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^j.
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^ 1
!
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чО
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106

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.497
53.003
64.058
64.217
70.735
74.551
76.899
78.426
79.463
80.196
80.735
81.137
81.451
81.693
81.890
82.049
82.179
82.288
82.380
82.455
82.522
82.581
82.627
82.673
82.710
82.744
82.773
82.798
82.823
82.844
82.865
82.882
82.898
82.911
82.928
82.936
82.949
82.961
82.970
82.978
82.986
82.995
82.999
83.007
83.011
83.020
83.024
83.028
83.032
83.037
83.041
83.045
83.049
83.053
83.057
83.057
83.062
83.066
83.066
83.070
83.074
К°(Т)= р(С1Ьр
Ф°(Г)
— i
Дж • К • моль
193.759
218.926
235.976
236.265
250.310
262.293
272.775
282.097
290.494
298.134
305.134
311.598
317.602
323.201
328.452
333.393
338.058
342.476
346.673
350.669
354.485
358.129
361.627
364.978
368.204
371.309
374.300
377.187
379.982
382.681
385.300
387.836
390.296
392.689
395.011
397.275
399.476
401.622
403.710
405.752
407.743
409.689
411.588
413.446
415.262
417.040
418.781
420.488
422.157
423.798
425.404
426.977
428.526
430.044
431.534
433.003
434.442
435.856
437.249
438.618
439.961
ТРИФТОРИД ХЛОРА
3(V).p~l(CW3)
~ s°m
227.851
258.616
282.021
282.419
301.870
318.104
331.920
343.895
354.443
363.844
372.325
380.041
387.112
393.643
399.706
405.359
410.660
415.647
420.350
424.806
429.040
433.065
436.910
440.584
444.103
447.479
450.726
453.852
456.864
459.768
462.580
465.295
467.927
470.479
472.952
475.358
477.696
479.968
482.182
484.337
486.437
488.487
490.487
492.437
494.349
496.211
498.039
499.822
501.571
503.282
504.960
506.604
508.219
509.801
511.353
512.876
514.374
515.842
517.290
518.708
520.106
V
Н°(Т)-Н°@)
кДж • моль"'
3.406
7.937
13.728
13.845
20.623
27.903
35.485
43.255
51.158
59.137
67.192
75.284
83.409
91.572
99.752
107.944
116.162
124.387
132.618
140.860
149.111
157.366
165.621
173.893
182.156
190.424
198.704
206.993
215.269
223.549
231.838
240.122
248.415
256.704
264.996
273.289
281.594
289.879
298.192
306.477
314.774
323.071
^31.372
339.656
347.978
356.267
364.585
372.865
381.183
389.472
397.777
406.095
414.404
422.705
431.019
439.304
447.617
455.919
464.232
472.533
480.868
C1F3 (г)
Ч°@) =511.946 кДж'МОЛь""
igA:°(r>
-253.4082
-117.9741
. -73.0584
-72.4924
-49.6332
-35.8666
-26.6628
-20.0743
-15.1243
-11.2690
-8.1808
-5.6517
-3.5424
-1.7560
-.2240
1.1045
2.2675
3.2942
4.2071
5.0243
5.7599
6.4258
7.0310
7.5841
8.0910
8.5575
8.9882
9.3872
9.7575
10.1026
10.4245
10.7258
11.0084
11.2737
11.5236
11.7591
11.9816
12.1921
12.3917
12.5808
12.7605
12.9315
13.0944
13.2497
13.3981
13.5398
13.6753
13.8050
13.9295
14.0487
14.1632
14.2735
14.3792
14.4811
14.5792
14.6736
14.7647
14.8527
14.9376
15.0196
15.0991
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
CN
00
Tt
rf,
га
On
II
00
О
00
TJ-
г—
+
с*
1
Н
г-
О
со
о
о
1
1
CN
Tf
СО
CN
00
+
со
о
§
оо*
rf
II
g
о
в
Т а б
о
о
>©
1
II
г^
о
го
О
_
1
§
I
к
ъ
*
+
О
CN
1
н
оо
со
со"
+
лица 63
i
9 Т
8 |
«? .
rj* «ч
Г ?
* OS
• со
? «*>
CN II
п
" о я
го ^
S
0
О
О
о
V
к.
V
о
о
1
о
К.
II
107

Класс точности
VI-1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
и
42.204
75.003
97.162
97.472
110.015
117.203
121.580
124.400
126.308
127.655
128.638
129.379
129.948
130.392
130.747
131.036
131.274
131.471
131.638
131.781
131.902
132.002
132.094
132.174
132.241
132.304
132.358
132.408
132.450
132.488
132.525
132.555
132.584
132.613
132.634
132.659
132.676
132.697
132.714
132.730
132.743
132.760
132.772
132.781
132.793
132.806
132.814
132.823
132.831
132.839
132.848
132.852
132.860
132.869
132.873
132.877
132.885
132.889
132.894
132.898
132.902
К°(Г)= р(С\)-р5(Ь
Ф°(Т)
Дж • К~ • моль"
201.219
228.754
250.005
250.377
269.314
286.193
301.364
315.104
327.636
339.142
349.765
359.631
368.832
377.451
385.555
393.204
400.442
407.312
413.848
420.082
426.040
431.743
437.212
442.471
447.529
452.400
457.103
461.646
466.040
470.295
474.416
478.416
482.299
486.069
489.738
493.312
496.788
5Q0.177
503.483
506.709
509.859
512.935
515.943
518.884
521.759
524.579
527.336
530.039
532.687
535.286
537.829
540.332
542.783
545.194
547.562
549.884
552.168
554.415
556.624
558.800
560.938
ПЕНТАФТОРИД ХЛОРА
>7f'(ClF5)
sV>
236.248
275.657
310.142
310.745
340.677
366.070
387.857
406.823
423.568
438.526
452.032
464.328
475.609
486.031
495.709
504.738
513.202
521.169
528.687
535.809
542.570
549.009
555.152
561.026
566.653
572.055
577.243
582.239
587.055
591.703
596.197
600.544
604.753
608.833
612.791
616.636
620.372
624.008
627.548
630.996
634.356
637.636
640.832
643.958
647.012
649.996
652.916
655.769
658.568
661.305
663.991
666.623
669.200
671.732
674.217
676.652
679.049
681.401
683.711
685.982
688.217
//°G)-Я°@)
кДж • моль
3.502
9.376
17.929
18.109
28.544
39.937
51.895
64.200
76.744
89.442
102.266
115.166
128.128
141.153
154.211
167.299
180.412
193.554
206.708
219.880
233.060
246.256
259.465
272.674
285.896
299.138
312.364
325.598
338.840
352.083
365.342
378.593
• 391.852
405.120
418.375
431.634
444.902
458.174
471.445
484.717
497.985
511.273
524.533
537.8-13
551.114
564.373
577.666
590.929
604.226
617.494
630.803
644.083
657.364
670.648
683.936
697.225
710.534
723.819
737.099
750.375
763.672
C1F5 (г)
^@) = 735.271 кДж-моль
lgK°(T)
-358.5910
-163.4278
-98.6275
-97.8105
-64.8255
-44.9673
-31.6995
-22.2093
-15.0854
-9.5419
-5.1062
-1.4771
1.5468
4.1047
6.2963
8.1947
9.8549
11.3189
12.6193
13.7820
14.8276
15.7730
16.6318
17.4151
18.1325
18.7922
19.4005
19.9631
20.4851
20.9706
21.4234
21.8464
22.2427
22.6148
?2.9645
23.2938
23.6046
23.8983
24.1763
24.4397
24.6896
24.9273
25.1532
25.3685
25.5739
25.7697
25.9570
26.1360
26.3075
26.4716
26.6294
26.7804
26.9257
27.0652
27.1994
27.3288
27.4534
27.5733
27.6891
27.8006
27.9085
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
СО
II
о
СО
г-
со
со
со
ON
о
о
1
1
г-
со
г*-
оо
в
о
VO
II
(^
о
Г а б л и
7
R
1 2
§ ^
я о
W о
х °.
оо
ЧО СО
V я
II m
о *"•
^ 00
U ON
[JU* ^
о U
1
А
о
?
т
к
го
00
1—1
+
г-
1
X
г-
ON
+
ел
и а 64
1
А
а
•
к
On
II
о 5
со*
я
V
V
8
•о
1
о
II
108

Класс точности
J
БРОМ Вг (г)
Таблица 65
К
Ф°(Л
S°(T)
Дж • К • моль
кДж - моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.787
20.798
20.833
20.908
21.027
21.184
21.365
21.559
21.752
21.937
22.107
22.258
22.388
22.497
22.586
22.657
22.710
22.748
22.772
22.785
22.788
22.782
22.769
22.750
22.727
22.699
22.669
22.635
22.600
22.564
22.527
22.489
22.450
22.412
22.374
22.336
22.298
22.261
22.225
22.189
22.154
22.120
22.087
22.055
22.023
21.992
21.962
21.933
21.905
21.878
21.851
21.825
21.800
21.776
2L753
21.730
21.708
131.413
145.821
154.120
154.249
160.229
164.867
168.657
171.863
174.642
177.096
179.295
181.289
183.114
184.798
186.362
187.823
189.194
190.486
191.708
192.868
193.971
195.023
196.029
196.992
197.916
198.805
199.660
200.484
201.280
202.048
202.792
203.512
204.209
204.886
205.543
206.182
206.803
207.407
207.995
208.568
209.127
209.672
210.205
210.724
211.232
211.729
212.214
212.689
213.155
213.610
214.056
214.494
214.922
215.343
215.756
216.161
216.558
216.949
217.332
217.709
218.080
152.199
166.607
174.904
175.035
181.015
185.654
189.449
192.665
195.464
197.950
200.191
202.236
204.120
205.869
207.501
209.032
210.472
211.833
213.121
214.344
215.508
216.617
217.676
218.688
219.658
220.588
221.482
222.341
223.168
223.965
224.734
225.476
226.195
226.889
227.563
228.215
228.848
229.463
230.060
230.640
231.205
231.756
232.292
232.814
233.324
233.821
234.307
234.782
235.246
235.700
236.144
236.578
237.004
237.421
237.830
238.230
238.623
239.009
239.388
239.759
240.124
2.079
4.157
6.197
6.236
8.314
10.394
12.475
14.562
16.658
18.768
20.896
23.042
25.207
27.392
29.594
31.813
34.045
36.289
38.544
40.806
43.075
45.348
47.624
49.902
52.180
54.459
56.736
59.012
61.286
63.558
65.826
68.091
70.353
72.611
74.866
77.117
79.364
81.607
83.846
86.081
88.313
90.541
92.765
94.986
97.203
99.417
101.627
103.834
106.038
108.239
110.437
112.632
114.824
117.013
119.199
121.383
123.564
125.743
127.919
130.094
132.265
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
I
3
и
о
о
VO
оо
553
со
О
1
с5
«о
о
.001
о
i
ON
ON
+
1—<
со
ON
II
С
Ь
i
ё
о
2
i
ё
со
ON
^ц
со
°°.
|
ON
VO
+
Я
g
VO
V
V
g
«о
.,
1
о
л
II
109

БРОМ Вг (г)
Т а б л и ц а 65
(окончание)
С, in
СП
кДж' моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
21.665
21.626
21.588
21.553
21.520
21.489
21.459
21.432
21 406
21 38!
21.358
21.336
21.315
21.295
21.277
21 259
21.242
21.226
21.211
21.197
218 803
219.502
220.179
220.836
221.473
222.092
222.694
223.280
223.849
224.404
224 945
225.473
225.988
226 491
226 982
227.462
227.931
228.391
228.840
229.281
240.835
241.522
242.187
242.831
243.456
244.061
244.650
245.222
245.778
246.320
246.847
247.362
247.864
248.353
248.832
249.299
249.756
?50.203
250.641
251.063
136.603
140 932
145.253
149.567
153.874
158.175
162.470
166.759
171.043
175.321
179.595
183.865
188 130
192.391
196 648
200.901
205 152
209.398
213.642
217.883
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
820ь
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
+
р
о ^1
о
о
О'
о
V
V
о
о
110

Класс точности
1 В
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ОТРИЦАТЕЛЬНЫЙ ИОН
К°(Т)= р(Вг)-р(е) -pV'Br")
<I>Vn
Дж • К ' моль
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
•20.786
20.780
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
142.594
142.723
148.703
153.341
157.131
160.335
163.110
165.559
167.749
169.730
171.538
173.202
174.743
176.177
177.518
178.778
179.966
181.090
182.156
183.171
184.137
185.061
185.946
186.795
187.610
188.394
189.150
189.880
190.584
191.266
191.926
192.565
193.186
193.788
194.374
194.944
195.498
196.038
196.564
197.077
197.578
198.067
198.545
199.012
199.469
199.916
200.354
200.782
201.202
201.614
202.018
202.414
202.802
203.184
203.558
203.926
204.288
204.643
204.992
163.380
163.509
169.488
174.127
177.917
181.121
183.896
186.345
138.535
190.516
192.324
193.988
195.528
196.963
198.304
199.564
200.752
201.876
202.942
203.956
204.924
205.848
206.732
207.581
208.396
209.180
209.936
210.666
211.370
212.052
212.712
213.352
213.972
214.575
215.160
215.730
216.284
216.824
217 350
217.863
218.364
218.853
219.331
219.798
220.255
220.702
221.140
221.568
221.988
222.400
222.804
223.200
223.588
223.970
224.344
224.712
225.073
225.429
225.778
Б?ОМА Вг (г)
lW/°@> 324.700
кДж • моль
6.197
6 236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
. 27.022
29г: 100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
-56.2790
-55.9215
-41.4755
-32.7531
-26.9016
-22.6960
-19.5222
-17.0384
-15.0391
-13.3931
-12.0129
-10.8377
-9.8241
-8.9402
-8.1619
-7.4709
-6.8528
-6.2963
-5.7923
-5.3336
-4.9139
-4.5284
-4.1729
-3.8438
-3.5382
-3.2535
-2.9877
-2.7386
-2.5049
-2.2849
-2.0775
-1.8815
-1.6960
-1.5201
-1.3531
-1.1942
-1.0429
-.8985
-.7606
-.6287
-.5024
-.3813
-.2652
-.1536
-.0463
.0570
.1565
.2524
.3449
.4343
.5206
.6041
.6849
.7632
.8390
.9126
.9839
.0532
1.1204
кДж • моль 1
"/¦
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
ON
ON
с-.
4-
о
о
о
р
о
1
ъ
о
о
о
о
о
о
+
1
00
о
+
о
!2
ь
ь
Таблица 66
Т
J3
О
Т ^
? * 7
° й л
^ * о
с[ р ^
г- ^
° ^ С=^
7 и 8
о со ""
1 С ^1
1- 0 (?
о ^*
1
о
О
, о
«ч v
ГО у
О V /
о V
о о
+ й
§ 2
О
н и
О W
О W
о
+
111

ОТРИЦАТЕЛЬНЫЙ ИОН БРОМА Вг " (г)
Таблица 66
(окончание)
К
С°р (Т)
Ф°G)
Дж К~* • моль""
кДж • моль
-1
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
Л.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
205.674
206.334
206.973
207.594
208.196
208.782
209.351
209.906
210.446
210.972
211.485
211.986
212.475
212.953
213.420
213.877
214.324
214.762
215.190
215.610
226.460
227.120
227.759
228.380
228.982
229.568
230.137
230.692
231.232
231.758
232.271
232.772
233.261
233.739
234.206
234.663
235.110
235.548
235?976
236.396
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
• 162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
1.2494
1.3714
1.4871
1.5970
1.7015
1.8012
1.8962
1.9871
2.0741
2.1575
2.2374
2.3142
2.3881
2.4592
2.5277
2.5937
2.6575
2.7190
2.7786
2.8362
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
о
о
о
V
V
о
о
о
го
О
К -н
Si1:
7 ? а
112

Класс точности
II-А
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
поб
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
А'°(Л = р2(Вг)-/Г
с;<т)
Ф°(Т)
Дж • К • моль
30.900 179.024
34.597 199.989
36.057 212.737
36.074 212.938
36.728 222.467
37.080 230.038
37.303 236.330
37.462 241.715
37.587 246.426
37.693 250.613
37.789 254.382
37.879 257.810
37.967 260.954
38.059 263.858
38.160 266.557
38.277 269.077
38.417 271.442
38.588 273.670
38.798 275.777
39.053 277.776
39.356 279.677
39.706 281.491
40.102 283.227
40.536 284.890
41.001 286.488
41.485 288.027
41.977 289.512
42.465 290.946
42 936 292 334
43.378 293.679
43.780 294.984
44.135 296.252
44.435 297.486
44.674 298.686
44.849 299.856
44.958 300.997
45.001 302.110
44.980 303.197
44.896 304.258
44.754 305.296
44.557 306.310
44.310 307.302
44.018 308.272
43.686 309.222
43.318 310.151
42.921 311.061
42.499 311.952
42.056 312.825
41.598 313.681
41.126 314.519
40.646 315.340
40.161 316.145
39.673 316.934
39.184 317.708
38.698 318.467
38.216 319.211
37.740 319.941
37.272 320.658
36.811 321.361
36.360 322.050
35.919 322.728
'(В,,)
s°m
208.509
231.228
245.350
245.580
256.058
264.295
271.076
276.839
281.850
286.283
290.260
293.865
297.165
300.208
303.032
305.668
308.143
310.477
312.688
314.793
316.803
318.732
320.588
322.380
324.115
325.799
327.435
329.028
330.5811
332.096
333.573
335.015
336.421
337.792
339.129
340.430
341.698
342.931
344.129
345.294
346.424
347.522
348.586
349.618
350.618
351.587
352.526
353.435
354.316
355.169
355.995
356.795
357.570
358.321
359.049
359.755
360.439
361.103
361.747
362.372
362.980
ДИБРОМ Вг2
н°(г)-н4
кДж • моль"
2.948
6.248
9.724
9.792
13.436
17.128
20.848
24.587
28.339
32.103
35.878
39.661
43.453
47.255
51.065
54.887
58.722
62.571
66.440
70.333
74.253
78.205
82.195
86.227
90.304
94.428
98.601
102.823
107.093
111.409
115.768
120.164
124.593
129.049
133.525
138.-016
142.515
147.014
151.509
155.992
160.458
164.902
169.318
173.704
178.054
182.366
186.638
190.866
195.048
199.185
203.273
207.314
211.305
215.248
219.142
222.988
226.786
230.536
234.240
237.899
241.513
(г)
//°@) = 190.140
))
•1
-94.9403
-44.8714
-28.3227
-28.1144
-19.7110
-14.6560
-11.2781
-8.8598
-7.0420
-5.6249
-4.4885
-3.5564
-2.7775
-2.1167
-1.5485
-1.0546
-.6211
-.2374
.1048
.4119
.6892
.9408
1.1703
1.3803
1.5733
1.7512
1.9158
2.0685
2.2105
2^3428
2.4665
2.5822
2.6908
2.7928
2.8889
2.9795
3.0650
3.1459
3.2226
3.2953
3.3644
3.4301
3.4927
3.5524
3.6094
3.6639
3.7160
3.7660
3.8139
3.8600
3.9042
3.9468
3.9878
4.0274
4.0656
4.1024
4.1381
4.1726
4.2060
4.2383
4.2697
кДж-моль
/
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 6 7
i
о
7 ? 7
й к 5
6 сЗ о
V Г
* 2 7
00 P"f '
о Ъ °^ *
со О •
<* чо <*> *
1О О II Е?
" * S 5
о оо «
s *** ^
о CQ
^ С
Os q
СО О
-: -*
О 1
CN * С
g ' ос ^
О чО V
О го **"
+ 1 V
S « о
—• Н О
у^ CN ir>
О ^ rt."
СО 1^ |
00 ^ С!
со + *~*
+ X ?
? s w
ГО 1
II
?
О |
8 872
113

Класс точности
II-D
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;т
29.125
30.515
33.746
33.808
36.672
38.425
39.319
39.702
39.817
39.801
39.732
39.647
39.566
39.497
39.444
39.409
39.392
39.390
.39.405
39.433
39.474
39.526
39.586
39.652
39.721
39.791
39.858
39.921
39.975
40.020
40.052
40.070
40.072
40.057
40.024
39.974
39.904
39.817
39.712
39.590
39.452
39.298
39.131
38.950
38.758
38.556
38.344
38.124
37.897
37.664
37.427
37.186
36.943
36.697
36.451
36.204
35.958
35.712
35.468
35.226
34.986
ОКСИД БРОМА ВгО (г)
К°(Т)= р(ВгO>@)тГ!(Вг0) Л И
Ф°(Т)
Дж • К • моль
170.364
190.532
202.383
202.570
211.441
218.607
224.670
229.940
234.603
238.784
242.572
246.034
249.219
252.168
254.913
257.480
259.890
262.162
264.310
266.347
268.285
270.132
271.896
273.586
275.206
276.763
278.262
279.706
281.100
282.447
283.751
285.013
286.236
287.424
288.578
289.699
290.789
291.851
292.885
293.893
294.875
295.834
296.770
297.685
298.578
299.451
300.305
301.140
301.957
302.757
303.541
304.308
305.060
305.797
306.520
307.228
307.923
308.605
309.274
309.930
310.575
~1
Н°(Т)-Н°@)
кДж * моль
199.376 2.901
219.832 5.860
232.600 9.009
232.809 9.072
242.952 12.605
251.343 16.368
258.438 20.261
264.532 24.215
269.843 '28.192
274.533 32.174
278.723 36.151
282.506 40.120
285.952 44.080
289.117 48.034
292.042 51.980
294.762 55.923
297.304 59.863
299.692 63.802
301.944 67.741
304.075 71.683.
306.099 75.629
308.026' 79.578
309.866 83.534
311.627 87.496
313.316 91.464
314.939 95.440
316.501 99.422
318.007 103.411
319.460 107.406
320.863 111.406
322.220 115.410
323.534 119.416
324.806 123.423
326.039 127.430
327.235 131.434
328.394 135.434
329.520 139.428
330.612 143.415
331.672 147.391
332.702 151.356
333.703 155.309
334.675 159.246
335.620 163.168
336.539 167.072
337.432 170.957
338.301 174.823
339.146 178.668
339.968 182.492
340.768 186.293
341.547 190.071
342.306 193.826
343.045 197.556
343.765 201.263
344.466 204.945
345.150 208.602
345.816 212.235
346.466 215.843
347.100 219.427
347.719 222.986
348.324 226.520
348.914 230.031
°@) =231.300 кДж'моль
\gK°(T)
-116.9091
-55.9876
-35.8145
-35.5603
-25.3060
-19.1380
-15.0194
-12.0742
-9.8631
-8.1418
-6.7634
-5.6344
•t *>924
-3.8x.44
-3.209ч
-2.6149
-2.0938
-1.6334
-1.2234
-.8560
-.5247
.2245
.0488
.2988
.5284
.7399
.9355
1.1168
1.2855
1.4428
1.5898
1.7275
1.8568
1.9784
. 2.0930
2.2013
2.3037
2.4007
2.4927
2.5801
2.6633
2.7426
2.8183
2.8905
2.9596
3.0257
3.0891
3.1500
3.2084
3.2646
3.3-186
3.3707
3.4209
3.4693
3.5161
3.5613
3.6050
3.6473
3.6883
3.7280
3.7665
/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 68
•
7
-
I
"° *? 7
1 5 1
2 * о
1—г «—• _
. ^ °q i
S S 2 *
ON ^ ~
со Q rt
¦^ ^ ~" ^
О об "•
U* CN
О " о *
да о ъ
<Г да
<г ^
Й '=5
? ?
¦* 1 я
о
Г- Ц ^
~ гч ч -
§ ^. v
' ' v
*О 00
00 О
^ о f
fN о
+ ё ы
т!- г- и
^О ГО
^ го ^
ГО
ГО
II
о
114

Класс точности
Н-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
20G0
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.115
29.124
29.141
29.141
29.220
29.453
29.871
30.430
31.061
31.707
32.331
32.915
33.449
33.932
34.367
34.758
35.109
35.427
35.714
35.975
36.214
36.433
36.637
36.826Г
37.003
37.169
37.326
37.476
37.618
37.754
37.885
38.010
38.130
38.245
38.354
38.458
38.557
38.649
38.735
38.814
38.885
38.949
39.004
39.051
39.088
39.116
39.134
39.142
39.140
39.128
39.105
39.072
39.028
38.975
38.912
38.838
38.756
38.664
38.564
38.455
38.338
Ф°т
Дж • К • моль
138.002
158.011
169.581
169.760
178.111
184.598
189.912
194.421
198.349
201.836
204.978
207.844
210.481
212.928
215.211
217.353
219.373
221.284
223.099
224.827
226.477
228.057
229.571
231.026
232.427
233.777
235.081
236.341
237.561
238.743
239.890
241.003
242.085
243.138
244.163
245.161
246.135
247.085
248.012
248.918
249.804
250.670
251.517
252.347
253.159
253.955
254.736
255.501
256.252
256.989
257.712
258.422
259.120
259.805
260.479
261.142
261.793
262.433
263.064
263.684
264.294
БРОМИД
р(Н) -p'UWBT
S°(T)
-1
166.773
186.956
198.585
198.767
207.159
213.701
219.105
223.750
227.854
231.550
234.923
238.032
240.920
243.616
246.147
248.532
250.787
252.925
254.958
256.896
258.747
260.520
262.219
263.852
265.423
266.937
268.398.
269.809
271.175
272.497
273.780
275.024
276.233
277.408
278.551
279.664
280.749
281.807
282.839
283.846
284.829
285,790
286.730
287.648
288.546
289.425
290.285
291.127
291.951
292.757
293.548
•294.322
295.080
295.823
296.551
297.264
297.964
298.649
299.320
299.978
300.624
ВОДОРОДА НВг (г)
) АгН°@) -362.491
кДж • моль
2.877 -185.9730
5.789 -90.8413
8.648 -59.4130
8.702 -59.0173
11.619 -43.0502
14.551 -33.4373
17.516 -27.0075
20.530 -22.4001
23.604 -18.9339
26.743 -16.2302
29.945 -14.0613
33.208 -12.2820
36.526 -10.7956
39.896 -9.5348
43.311 -8.4515
46.768 -7.5106
50.261 -6.6855
53.788 -5.9559
57.346 -5.3060
60.930 -4.7234
64.540 -4.1980
68 172 -3.7217
71.826 -3.2880
75.499 -2.8912
79.191 -2.5268
82.899 -2.1911
86.624 -1.8806
90.364 -1.5927
94.119 -1.3249
97.888 -1.0752
101.670 -.8419
105.465 -.6232
109.272 -.4180
113.090 -.2249
116.920 -.0429
120.761 .1289
124.612 .2913
¦ 128.472 .4451
132.341 .5911
136.219 .7296
140.104 .8614
143.996 .9869
147.893
151.796
155.703
159.613
163.526
167.440
171.354
175.268
179.179
1.1066
.2208
.3299
.4343
.5342
.6300
.7219
.8101
.8948
183.088 1.9763
186.993 2.0547
190.894 2.1303
194.788 2.2031
198.676 2.2733
202.555 2.3411
206.426 2.4066
210.288 2.4699
214.139 2.5310
217.979 2.5903
Таблица 69
кДж • моль 1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400 *
5500
5600
5700
5800
5900
6000
л
— о
'| 1 7*
§ 1 §
| | .
—. Tf ГО ^
— гО
О ос " Й
ОС ГЧ ^~
i- ' * vO
«*- " юр
**"'• —> Т го
О ОС ГЧ
04 -1
- <N ¦'
'"-' '— Еы.
2? # 0 в;
15 2 ^
о 5
**"• о
< X
«•" *
+
-
«О j
S |
О
+ -
s * i
OS О
5 е! 8
S \ *
S й v
? °> *-
н ? V
— г» О
— X О
ON °° "Ч
чо ^
Ю ~"* г*
t^ ? Us
fs, СЧ О
ц. 1 "¦"
— н С
ЧО CN
fN ГО
!! +
ow
•е-
115

Класс точности
И -В
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
ЗШ)
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
29.112
29.126
29.228
29.232
29.645
30.367
31.234
32.101
32.895
33.592
34.192
34.705
35.143
35.520
35.846
36.131
36.381
36.604
36.805
36.986
37.152
37.305
37.448
37.582
37.708
37.829
37.944
38.055
38.163
38.267
38.368
38.466
38.561
38.652
38.741
38.825
38.905
38.980
39.051
39.115
39.173
39.224
39.267
39.302
39.329
39.347
39.356
39.356
39.345
39.325
39.295
39.255
39.205
39.145
39.076
38.997
38.909
38.812
38.707
38.593
38.472
БРОМИД
ЛГ °(П = p(Br) -p(D) -p (DBr)
Ф°(Л
Дж • К • моль
143.611
163.703
175.301
175.481
183.854
190.376
195.743
200.323
204.333
207.909
211.144
214.102
216.830
219.364
221.731
223.953
226.049
228.031
229.913
231.705
233.414
235.050
236.617
238.122
239.570
240.965
242.311
243.611
244.869
246.087
247.268
248.413
249.526
250.608
251.661
252.687
253.686
254.660
255.611
256.539
257.446
258.333
259.200
260.048
260.880
261.693
262.491
263.272
264.039
264.791
265.529
266.253
266.964
267.663
268.350
269.025
269.688
270.340
270.982
271.613
272.234
S°(T)
172.547
192.730
204.372
204.553
213.010
219.698
225.311
230.191
234.531
238.446
242.017
245.301
248.340
251.168
253.813
256.296
258.636
260.848
262.946
264.941
266.842
268.659
270.398
272.065
273.667
275.209
276.695
278.129
279.515
280.856
282.155
283.415
284.637
285.825
286.981
288.105
289.200
290.267
291.307
292.322
293.313
294.281
295.2^7
296.152
297.055
297.939
298.804
299.651
300.479
301.290
302.085
302.862
303.624
304.370
305.101
305.818
306.520
307.207
307.881
308.542
309.190
ДЕЙТЕРИЯ ]
Я°G')-Я°@)
кДж • моль"
2.894
5.805
8.668
8.722
11.662
14.661
17.741
20.908
24.158
27.484
30.874
34.319
37.812
41.346
44.914
48.51 а
52.139
55.789
59.459
63.149
66.856
70.579
74.317
78.068
81.833
85.610
89.399
93.199
97.010
100.831
104.663
108.504
112.356
116.216
120.086
123.964
127.851
131.745
135.647
139.555
143.470
147.390
151.314
155.243
159.174
163.108
167.043
170.979
174.914
178.848
182.779
186.706
190.629
194.547
198.458
202.362
206.257
210.144
214.020
217.885
221.738
DBr (г)
э@) = 367.000
lgK°(T)
-188.1702
-91.8653
-60.0508
-59.6503
-43.4881
-33.7593
-27.2537
-22.5939
-19.0900
-16.3582
•14.1680
-12.3721
-10.8725
•9.6012
-8.5094
-7.5614
-6,7304
-5.9959
-5.3419
-4.7556
-4.2272 .
-3.7482
-3.3121
-2.9133
-2.5472
-2.2098
-1.8979
-1.6088
-1.3398
-1.0891
-.8548
-.6353
-.4293
-.2355
-.0530
.1194
.2824
.4367
.5831
.7221
.8543
.9801
1.1001
1.2146
.3240
.4287
.5289
.6249
.7170
.8054
.8903
1.9720
2.0506
2.1263
2.1993
2.2697
2.3376
2.4032
2.4666
2.5279
2.5872
кДж'моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
оо
О\
т—1
00
II
+
-и
1
о
го
о
+
о»
'*
00
с-
о
§
о
1
S
сч
*п
сч
го
+
о
сч
г^
о
00
сч
!1
• S
о
Таблица 70
о
о
<Ч
О
сч
1
II
О
и
?
Q
>••
о
а:
1
•
ми
>«>
го
сч
сч
+
с*
1
1
ё
с?
+
о
00 «S
^ т
1
х «
Я го
ю 3
" г
СЧ II
? ъ
о
О
^;
Я
о
g
V
V '
g
о
«о
1
II
116

Класс точности
П-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZoxJU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
29.112
29.141
29.432
29.443
30.226
31.260
32.289
33.197
ЗЗ.Эби
34.590
35.108
35.537
35.896
36.200
36.461
36.687
36.886
37.063
37.223
37.369
37.503
37.628
37.746
37.857
37.964
38.066
38.165
38.262
ОО ОСА
оо.ооо
38.448
38.538
38.626
38.711
38.794
38.875
38.952
39.026
39.095
39.159
39.218
39.271
39.317
39.356
39.388
39.411
39.426
39.431
39.427
39.414
39.391
39.358
39.316
39.264
39.202
39.130
39.049
38.959
38.861
38.754
38.638
38.515
К°(Т)= р(Вг)-р(Т
Ф°(Т)
Дж К~1 • моль""!
146.949
167.069
178.680
178.860
187.258
193.823
199.248
203.894
207.973
211.618
214.919
217.939
220.726
223.314
225.731
228.000
230.138
232.160
234.079
235.905
237.647
239.312
240.907
242.438
243.910
245.327
246.694
248.014
ОАО 9Q1
250.527
251.724
252.886
254.014
255.110
256.177
257.215
258.227
259.213
260.175
261.113
262.031
262.927
263.804
264.662
265.501
266.323
267.128
267.918
268.692
269.451
270.196
270.926
271.644
272.349
273.042
273.722
274.391
275.048
275.695
276.331
276.957
БРОМИД
)-р(ТВг)
S°(T)
И
ТРИТИЯ ТВг (г)
М
°СП-яо@)
кДж * моль
175.940
196.124
207.799
207.981
216.549
223.403
229.195
234.242
238.726
242.764
246.436
249.803
252.911
255.796
258.488
261.012
263.386
265.628
267.751
269.768
271.688
273.520
275.274
276.954
278.568
280.119
281.614
283.057
284-450
285.797
287.102
288.367
289.595
290.788
291.947
293.075
294.173
295.243
296.287
297.305
298.298
299.269
300.217
301.143
302.049
302.935
303.801
304.649
305.479
306.292
307.087
307.866
308.629
309.376
310.109
310.826
311.529
312.217
312.892
313.554
314.202
2.899
5.811
8.682
8.736
11.716
14.790
17.968
21.244
24.603
28.031
31.517
35.050
38.622
42.227
45.860
49.518
53.197
56.895
60.609
64.339
68.082
71.839
75.608
79.388
83.179
86.981
90.792
94.614
по ЛАК
102.285
106.134
109,992
113.859
117.734
121-618
125.509
129.408
133.314
137.227
141.146
145.070
148.900
152.934
156.871
160.811
164.753
168.696
172.639
176.581
180.521
184.459
188.393
192.322
196.245
200.162
204.071
207.971
211.862
215.743
219.613
223.470
э@) = 369.000
ЧК°(Т)
-189.1262
-92.3004
-60.3147
-59.9120
-43.6640
-33.8852
-27.3478
-22.6666
-19.1477
-16.4050
-14.2066
-12.4045
-10.9001
-9.6248
-8.5299
/ -7.5794
-6.7463
-6.0100
-5.3545
-4.7670
-4.2374
-3.7576
-3.3206
-2.9211
-2.5543
-2.2164
-1.9040
-1.6144
-1 °.4.*» 1
- 1 .ОЧО 1
-1.0940
-.8594
-.6396
-.4333
-.2393
-.0565
.1161
.2792
.4337
.5802
.7194
.8517
.9777
.0978
.2124
.3219
.4267
.5270
.6230
.7152
.8037
.8887
1.9704
2.0491
2.1249
2.1979
2.2683
2.3363
2.4020
2.4654
2.5267
2.5861
кДж'моль""
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
OftOO
iCOUU
2900
3000 .
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
ON
f>J
00
li
X
*о
00
оо
со
1О
+
сч
'н
»о
*t
о
р
о
1
S
CN
с-
V)
Г-;
тГ
со
+
00
ON
CN
ON
00
CN
II
g
ф
Таблица 71
Т i
lie
г х о
с| оо '
* Ч Т
оо ? «
7 - ^
•' & ю
JL a S
О об ™
« ^ о 5
о Н
^ С
< *-.
3 1
СО VO
X V /
^ V
7 v
« §
ON
«N О
I *"'
ON *—'
111

Класс точности
И-С
/C°iT) =
ФТОРИД БРОМА BrF (г)
р'^ВгГ) А Н°@) -246.398 кДж • моль"
Таблица 72
Дж К
/г
кДж • Моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.163
30.769
32.954
32.989
34.517
35.479
36.102
36.528
36.836
37.070
37.256
37.409
37.541
37.658
37.765
37.866
37.964
38.064
38.168
38.280
38.403
38.541
38.694
38.866
39.055
39.262
39.484
39.720
39.964
40.215
40.466
40.714
40.954
41.181
41.391
41.581
41.747
41.886
41.996
42.075
42.124
42.140
42.125
42.078
42.001
41.895
41.761
41.601
41.416
41.209
40.982
40.736
40.473
40.196
39.906
39.606
39.297
38.980
38.657
38.329
37.999
166.471
186.710
198.610
198.797
207.628
214.666
220.547
225.611
230.062
234.038
237.631
240.909
243.925
246.719
249.320
251.754
254.042
256.200
258.243
260.183
262.029
263.791
265.476
267.092
268.643
270.135
271.573
272.960
274.301
275.599
276.856
278.076
279.261
280.412
281.533
282.624
283.688
284.726
285.738
286.728
287.694
288.640
289.564
290.469
291.355
292.223
293.073
293.907
294.724
295.526
296.312
297.084
297.841
298.584
299.314
300.031
300.735
301.426
302.106
302.774
303.430
195.567
216.155
228.864
229.068
238.784
246.598
253.125
258.724
263.623
267.976
^ 271.892
275.450
278.711
281.720
284.515
287.124
289.571
291.875
294.054
296.120
298.087
299.964
301.760
303.484
305.142
306.741
308.285
309.779
311.228
312.635
314.003
315.333
316.630
317.894
319.126
320.329
321.503
322.648
323.767
324.859
325.925
326.965
327.981
328.971
329.938
330.880
331.800
332.696
333.570
334.422
335.253
336.062
336.850
337.619
338.367
339.097
339.808
340.500
341.176
341.833
342.475
2.910
5.889
9.020
9.081
12.462
15.966
19.547
23.180
26.849
. 30.544
34.261
37.995
41.742
45.502
49.273
53.055
56.847
60.648
64.459
68.282
72.116
75.963
79.824
83.702
87.598
91.514
95.451
99.411
103.395
107.404
111.438
115.497
119.581
123.688
127.817
131.965
136.132
140.314
144.508
148.712
152.922
157.136
161:349
165.560
169.764
173.959
178.142
182.310
186.461
190.592
194.702
198.788
202.849
206.882
210.888
214.863
218.808
222.722
226.604
230.454
234.270
-124.6055
-59.7948
-38.3468
-38.0766
-27.1701
-20.6029
-16.2117
-13.0668
-10.7025
-8.8595
-7.3819
-6.1704
-5.1587
-4.3008
-3.5639
-2.9240
-2.3629
-1.8667
-1.4248
-1.0285
-.6711
-.3472
-.0521
.2179
.4658
.6943
.9055
.1015
.2837
.4535
.6123
.7609
.9005
2.0317
2.1552
2.2718
2.3820
2.4863
2.5852
2.6790
2.7682
2.8531
2.9339
3.0110
3.0847
3.1551
3.2224
3.2869
3.3488
3.4081
3.4652
3.5200
3.5728
3.6236
3.6725
3.7198
3.7654
3.8094
3.8520
3.8932
3.9331
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5.700
58Q0
5900
6000
2
On
00
ON
§
*
X
о
о
_:
i
и
о
*
о
58.8^
1
и
2
«о
00
р
со
<!
со
ч?>
О
«О
ON
СО
ю
р
о
1
1
,_,
On
О
Т
5.99:
I
о
со
2
о
1
V
V
о
о
«О
ЧО
|
118

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОАА
ZOVJV)
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
п
41.667
57.457
67.353
67.490
73.061
76.233
78.154
79.389
80.223
80.810
81.239
81.560
81.807
82.001
82.156
82.281
82.384
82.470
82.542
82.603
82.655
82.700
82.740
82.774
82.804
82.830
82.854
82.875
R9 RQ4
ОХ.О«7*г
82.911
82.926
82.940
82.952
82.964
82.974
82.984
82.992
83.000
83.008
83.015
83.021
83.027
83.033
83.038
83.042
83.047
83.051
83.055
83.059
83.062
83.065
83.068
83.071
83.074
83.077
83.079
83.081
83.084
83.086
83.088
83.089
К°(Т)= р(Вг)-р3
Ф°(Л
Дж • К~1 • моль
201.248
227.987
246.320
246.626
261.609
274.272
285.267
294.987
303.698
311.591
318.804
325.445
331.599
337.330
342.694
347.734
352.487
356.984
361.251
365.310
369.181
372.880
376.422
379.820
383.084
386.225
389.252
392.173
лл j ААС
397.724
, 400.367
402.929
405.413
407.827
410.172
412.452
414.672
416.834
418.942
420.997
423.003
424.961
426.875
428.746
430.575
432.365
434.117
435.833
437.515
439.163
440.779
442.365
443.920
445.447
446.947
448.420
449.868
451.290
452.689
454.065
455.418
ТРИФТОРИД БРОМА
(F)-p~1(BrF3
S°(T)
236.696
270.694
295.663
296.080
/316.336
333.011
347.094
359.240
369.899
379.384
387.922
395.680
402.788
409.344
415.427
421.099
426.413
431.410
436.126
440.591
444.829
448.863
452.711
456.390
459.913
463.294
466.543
469.670
А79 fifti
475.594
478.405
481.124
483.757
486.310
488.787
491.192
493.530
495.804
498.018
500.174
502.276
504.326
506.327
508.281
510.190
512.056
513.881
515.668
517.416
519.129
520.807
522.452
524.065
525.647
527.200
528.725,
530.222
531.692
533.137
534.558
535.954
) v
H°(T)-H°(Q)
кДж • моль"
3.545
8.541
14.711
14.836
21.891
29.369
37.096
44.978
52.961
61.014
69.118
77.258
85.427
93.618
101.826
110.048
118.282
126.524
134.775
143.032
151.295
159.563
167.835
176.111
184.390
192.672
200.956
209.242
О 1 7 К 1
225^821
234.113
242.406
250.701
258.996
267.293
275.591
283.890
292.190
300 490
308.791
317.093
325.395
333.698
342.002
350.306
358.611
366.916
375.221
383.526
391.832
400.139
408.445
416.753
425.060
433.367
441.675
449.983
458.291
466.600
474.908
483:217
BrF3 (г)
И°@) =594.56:
lgK°(T)
-296.4235
-139.4953
-87.5462
-86.8919
-60.4914
-44.6104
-34.0036
-26.4169
-20.7208
-16.2867
-12.7368
-9.8305
-7.4071
-5.3554
-3.5959
-2.0702
-.7346
.4445
1.4930
2.4317
3.2769
4.0419
4.7377
5.3733
5.9561
6.4926
6.9880
7.4469
7 Я7Ч9
/.Of Oib
8.2702
8.6410
8.9879
9.3133
9.6190
9.9069
10.1784
10.4349
10.6776
10.9076
11.1259
11.3333
11.5307
11.7187
11.8980
12.0693
12.2329
12.3895
12.5394
12.6831
12.8210
12.9535
13.0807
13.2031
13.3208
13.4343
13.5436
13.6491
13.7508
13.8491
13.9441
14.0359
1 кДж'моль
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
АОАА
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200 ,
5300
5400
5500
5600
5700
5800
5900
6000
<N
On
00
36.
II
+
1
со
со
+
*Х
со
о
S
О
О
О
js
о
VO
CN
00
+
со
со
со
с*
II
р
Табли
т I
моль
<Дж
ч 1
\> VO
т* «О
1 ы
К »о
s 2
„ ON
U CN
го L*
pQ fj^
в
^ о
А
о
ф
1
S
го
00
о
+
г»
17.
00
1
1
X
«о
о
CN
+
ца 73
г*
А
I
1
00
Г-
«о
со
II
о 5
2
о
о
о
ЧО
V
V
§
«о
^•'
1
о
II
119

Класс точности
VI- D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
47.378
80.736
101.333
101.615
112.930
119.302
123.138
125.595
127.251
128.416
129.264
129.901
130.389
130.772
131.078
131.326
131.530
131.699
131.842
131.963
132.066
132.155
132.232
132.300
132.359
132.411
132.458
132.499
132.536
132.570
132.600
132.627
132.652
132.674
132.695
132.714
132.731
132.747
132.762
132.775
132.788
132.800
132.810
132.821
132.830
132.839
132.847
132.855
132.862
132.869
132.875
132.881
132.887
132.892
132.897
132.902
132.907
132.911
132.915
132.919
132.923
ПЕНТАФТОРИД БРОМА BrFs (r)
К°(Г)=р(Вг)-р5A
Ф°(Г)
Дж • К • моль
206.488
235.961
258.828
259.227
279.348
297.088
312.906
327.145
340.073
351.900
362.790
372.877
382.268
391.051
399.299
407,071
414.419
421.387
428.012
434.324
440.353
446.122
451.653
456.964
462.073
466.994
471.739
476.322
480.753
485.042
489.197
493.227
497.138
500.938
504.633
508.228
5 И.729
515.140
518.466
521.711
524.879
527.974
530.998
533.955
536.848
539.679
542.452
545.168
547.829
550.439
552.998
555.509
557.974
560.394
562.771
565.106
567.400
569.656
, 571.875
574.057
576.203
-)-p"!(BrF?
s°m
243.107
286.661
323.139
323.767
354.712
380.660
402.777
421.957
438.843
453.902
467.478
479.829
491.154
501.607
511.309
520.361
528.844
536.823
544.355
551.487
558.258
564.704
570.853
576.733
582.365
587.769
592.963
597.963
602.782
607.434
611.929
616.277
620.488
624.570
628.532
632.378
636.117
639.754
643.295
646.743
650.105
653.384
656.584
659.709
662.763
665.748
668.668
671.525
674.322
677.062
679.746
682.378
684.958
687.489
689.973
692.412
694.807
697.159
699.471
701.743
703.977
Н°{Т)-Н°@)
кДж * моль
3.662
10.140
19.174
19.362
30.146
41.786
53.923
66.368
79.015
. 91.802
104.688
117.648
130.663
143.722
156.815
169.936
183.079
196.241
209.418
222.608
235.810
249.021
262.240
275.467
288.700
301.939
315.182
328.430
341.682
354.937
368.196
381.457
394.721
407.987
421.256
434.526
447.799
461.072
474.348
487.625
500.903
514.182
527.463
540.744
554.027
567.310
580.595
593.880
607.166
620.452
633.739
647.027
660.316
673.605
686.894
700.184
713.475
726.765
740.057
753.348
766.640
э@) = 917.950 кДж'моль
lgKq{T)
-453.7573
-210.9854
-130.5662
-129.5533
-88.6843
-64.1079
-47.7018
-35.9743
-27.1752
-20.3306
-14.8552
-10.3760
-6.6442
-3.4876
-.7829
1.5603
3.6097
5.4172
7.0232
8.4594
9.7513
10.9196
11.9812
12.9499
13.8375
14.6536
15.4064
16.1031
16.7497
17.3514
17.9126
18.4372
18.9288
19.3903
19.8243
20.2333
20.6104
20.9843
21.3298
21.6573
21.9683
22.2639
22.5452
22.8132
23.0689
23.3130
23.5464
23.7697
23.9835
24.1884
24.3850
24.5737
24.7551
24.9294
25.0972
25.2588
25.4145
25.5646
25.7094
25.8491
25.9842
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
' о
чО
ON
oq
г-
II
+
т
<ч
о
?
со
+
о
сч
с-
чо
0.0
1
X
i
о
СО
+
00
чо
со
чо
II
с
ф
Т а б л и
§
*
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ЧО
со
тГ
1 •
II
S
и*
6
о
а:
к
п
00
+
сч
$
со
1
1
00
со
+
А
Q
к
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л
О
О
°9
(N
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1
II
00
ON
(N
С
1Л
ё
0
ц а 74
л
с;
о
г
k
о
II
о 5
со
я
ЧО
V
V
§
о
1
II
120

Класс точности
II-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
C°iT)
29.721
33.012
35.012
35.037
36.050
36.609
36.956
37.193
37.369
37.509
37.627
37.732
37.828
37.920
38.010
38.101
38.197
38.299
38.410
38.533
38.668
38.815
38.974
39.142
39.318
39.497
39.676
39.850
40.015
40.168
40.303
40.419
40.511
40.578
40.618
40.629
40.612
40.566
40.492
40.391
40.263
40.110
39.935
39.738
39.522
39.288
39.038
38.775
38.501
38.216
37.923
37.623
37.318
37.009
36.698
36.385
36.071
35.759
35.447
35.138
34.832
ХЛОРИД
К°(Т)= р(Ъг)-р(С\)-р~1(ЪхС\)
Ф°(Т)
Дж • К • моль
175.526
196.049
208.385
208.580
217.808
225.162
231.293
236.556
241.169
245.278
248.982
252.355
255.453
258.316
260.979
263.468
265.805
268.008
270.091
272.067
273.947
275.740
277.454
279.096
280.672
282.188
283.647
285.056
286.416
287.732
289.006
290.241
291.440
292.605-
293.737
294.839
295.912
296.957
297.976
298.970
299.941
300.888
301.814
302.719
303.603
304.469
305.315
306.144
306.956
307.750
308.528
309.291
310.039
310.772
311.491
312.196
312.887
313.566
314.232
314.886
315.528
-1
204.721
226.336
239.936
240.153
250.387
258.496
265.204
270.919
275.898
280.308
284.266
287.857
291.144
294.176
296.989
299.615
302.077
304.395
306.588
308.668
310.648
312.538
314.347
316.083
317.753
319.361
320.914
322.414
323.867
325,274
326.638
327.961
329.246
330.494
331.706
332.884
334.028
335.140
336.221
337.271
338.292
339.285
340.249
341.187
342.098
342.984
343.844
344.681
345.495
346.286
347.055
347.803
348.530
349.238
349.927
350.598
351.250
351.886
352.505
353.109
353.696
БРОМА BrCl
\»
Н°(Т)~Н°(())
кДж * моль
2.920
6.057
9.407
9.472
13.032
16.667
20.347
24.055
27.783
31.527
35.284
39.052
42.830
46.618
50.414
54.220
58.034
61.859
65.695
69.542
73.402
77.276
81.165
85.071
88.994
92.934
96.893.
100.869
104.863
108.872
112.896
116.932
120.979
125.033
129.093
133 Л 56
137.218
141.277
145.331
149.375
153.408
157.427
161.429
165.413
169.376
173.317
177.233
181.124
184.988
188.824
192.631
196.408
200.155
203.871
207.557
211.211
214.834
218.425
221.985
225.515
229.013
(г)
э@) - 215320
ig*V)
-108.4394
-51.7708
-33.0331
-32.7971
-23.2761
-17.5444
-13.7111
-10.9647
-8.8989
-7.2876
-5.9951
-4.9347
-4.0487
-3.2970
-2.6511
-2.0898
-1.5974
-1.1618
-.7737
-.4255
-.1114
.1734
.4330
.6705
.8886
1.0897
1.2758
1.4483
1.6088
1.7585
1.8984
2.0295
2.1525
2.2683
2.3774
2.4803
2.5777
2.6699
2.7574
2.8405
2.9195
2.9948
3.0666
3.1351
3.2007
3.2633
3.3234
3.3810
3.4363
3.4895
3.5406
3.5898
3.6372
3.6830
3.7271
3.7698
3.8110
3.8509
3.8895
3.9269
3.9632
кДж'моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г-
1О
со
»о
II
1
т
н
со
г-
со
о
+
1
<2
00
о
о
о
1
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со
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II
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7
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ON
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8
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121

Класс точности
I
Г
К
100
200
298.15
300
400
500
600
700"
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.789
20.795
20.806
20.824
20.851
20.889
20.936
20.994
21.062
21.137
21.220
21.308
21.399
21.493
21.588
21.682
21.775
21.865
21.953
22.036
22.116
22.191
22.261
22.327
22.387
22.443
22.494
22.540
22.581
22.618
22.651
22.679
22.704
22.725
22.743
22.757
22.769
22.777
22.783
22.787
22.788
22.787
22.784
22.780
22.774
22.766
22.757
22.747
22.736
22.724
22.711
22.697
фО(Т-)
Дж • К • моль
137.183
151.590
159.890
160.018
165.998
170.636
174.426
177.630
180.406
182.854
185.044
187.025
188.834
190.499
192.040
193.475
194.818
196.080
197.272
198.399
199.469
200.489
201.462
202.393
203.285
204.142
204.967
205.762
206.529
207.270
207.988
208.683
209.356
210.011
210.647
211.265
211.866
212.453
213.024
213.581
214.125
214.656
215.176
215.683
216.180
216.666
217.142
217.608
218.064
218.512
218.952
219.383
219.806
220.221
220.629
221.029
221.423
221.810
222.191
222.565
222.933
S°(T)
~1
157.969
172.376
180.673
180.804
186.784
191.422
195.212
198.416
201.1J92
203.640
205.831
207.813
209.625
211.292
212.839
214:282
215.635
216.909
218.115
219.260
220.351
221.393
222.391
223.348
224.269
225.156
226.012
226.838
227.638
228.413
229.164
229.893
230.601
231.289
231.958
232.609
233.243
233.861
234.464
235.052
235.626
236.186
236.734
237.269
237.792
238.303
238.804
239.294
239.773
240.243
240.704
241.155
241.597
242.031
242.457
242.874
243.284
243.687
244.082
244.470
244.852
ЙОД I (г)
Н°(Т)-Н°@)
кДж • моль
\%К°(Т)
2.079 —
4.157 —
6.197 —
6.236 —
8.314 —
10.393 —
12.472 —
14.550 —
16J629 —
18.708 —
20.787 —
22.867 —
24.948 —
27.032 —
29.119 —
31.210 —
33.306 —
35.409 —
37.519 —
39.637 —
41.763 —
43.899 —
46.043 —
48.197 —
50.361 —
52.533 —
54.715 —
56.906 —
59.106 —
61.314 —
63.529 —
65.752 —
67.981 —
70.217 —
72.458 —
74.705 —
76.957 —
79.213 —
81.473 —
83.736 —
86.003 —
88.272 —
90.544 —
92.817 —
95.092 —
97.368 —
99.646 —
101.924 —
104.202 —
106.481 —
108.760 —
111.038 —
113.316 —
115.594 —
117.871 —
120.147 —
122.423 —
124.697 —
126.970 —
129.242 —
131.512 —
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 76
i
i
'о ^ I
*^> i о* Т
° ^ ^т .
<5 °° 2 а
** -! и г-
11 Г- _ ON
^ 2 Я °°-
с ^ о 5
*? С со
о *?
^ о
+
•р
н
Os ^
г- '
ч?> А
Р О
О 2
•
j« * §
о •=* S
°. пн V
+ о ^
2 ^ V
С * '
\О ' О
IO С4 'О
CN • —'
00 00 и
1> • ЧО "
<ч о
II +
0
•е-
122

ЙОД I (г)
Т а бл и ц а 76
(окончание)
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
с; m
22.667
22.635
22.601
22.565
22.529
22.492
22.455
22.418
22.381
22.344
22.308
22.272
22.236
22.202
22.167
22.134
22.102
22.070
22.039
22.008
Ф°G)
Дж К • моль
223.652
224.350
225.026
225.682
226.320
226.941
227.545
228.133
228.706
229.264
229..809
230.341
230.861
231.369
231.865
232.351
232.826
233.291
233.747
234.193
S°(T)
245.596
246.315
247.011
247.685
248.339
248.973
249.589
250.187
250.769
251.335
251.886
252.423
252.947
253.458
253.956
254.443
254.919
255.384
255.839
256.283
#о(Г)-"°@)
кДж * моль
136.048
140.579
145.102
149.619
154.128
158.630
163.125
167.613
172.092
176.565
181.030
185.488
189.939
194.383
198.820
203.250
207.673
212.090
216.501
220.906
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
ОС
С
О
о
о
о
о
V
V
о
2
w с

123

Класс точности
I-B
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786 •
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ОТРИЦАТЕЛЬНЫЙ ИОН ЙОДА I " (г)
К°СП = рA) • р(е) р~1A~)
Ф°(Л
Дж • К • моль
148.364
148.492
154.472
159.110
162.900
166.104
168.880
171.328
173.518
175.499
177.308
178.972
180.512
181.946
183.288
184.548
185.736
186.860
187.926
188.940
189.907
190.831
191.716
192.564
193.379
194.164
194.920
195.649
196.354
197.035
197:695
198.335
198.956
199.558
200.144
200.713
201.267
201.807
202.334
202.847
203.348
203.837
204.315
204.782
205.239
205.686
206.123
206.552
206.972
207.384
207.787
208.183
208.572
208.953
209.328
209.695
210.057
210.412
210.762
S°iT)
-1
169.150
169.278
175.258
179.896
183.686
186.890
189.666
192.114
194.304
196.285
198.094
199.758
201.298
202.732
204.074
205.334
206.522
207.646
208.712
209.726
210.693
211.617
212.502
213.350
214.165
214.950
215.706
216.435
217.140
217.821
218.481
219.121
219.741
220.344
220.930
221.499
222.053
222.593
223.120
223.633
224.134
224.623
225.101
225.568
226.025
226.472
226.909
227.338
227.758
228.169
228.573
228.969
229.358
229.739
230.113
230.481
230.843
231.198
231.548
Таблица 77
ArH°@) = 295.600 кДж- моль 1
H°iT)-H°@)
кДж ¦ моль
6.197 -51.1809
6.236 -50.8548
8.314 -37.6755
10.393 -29.7131
12.472 -24.3683
14.550 -20.5247
16.629 -17.6225
18.707 -15.3501
20.786 -13.5201
22.865 -12.0130
24.943 -10.7488
27.022 -9.6721
29.100 -8.7432
31.179 -7.9330
33.258 -7.2195
35.336 -6.5859
37.415 -6.0191
39.493 -5.5087
41.572 -5.0465
43.651 -4.6256
45.729 -4.2406
47.808 -3.8868
49.886 -3.5605
51.965 -3.2584
54.044 -2.9777
56.122 -2.7163
58.201 -2.4720
60.279 -2.2431
62.358 -2,0281
64.437
66.515
68.594
70.672
72.751
.8258
.6350
.4546
1.2838
.1217
74.830 -.9677
76.908 -.8212
78.987 -.6815
81.065 -.5482
83.144 -.4209
85.223 -.2990
87.301 -.1822
89.380 -.0702
91.458 .0374
93.537 .1407
95.616 .2402
97.694 .3360
99.773 .4283
101.852 .5173
103.930 .6033
106.009 .6863
108.087 .7666
110.166 .8444
112.245 .9196
114.323 .9925
116.402
118.480
120.559
122.638
124.716
.0632
.1318
1.1984
1.2631
1.3259
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
§
§ f I
•
§ 5 si L
о И to .
\л СО *"н Уч
fN ^ 1 EJ
^ 00 II г^
II °О /-v О*\
Т* ^ ®?>
2! 1 " _д*
II lri «—1
о °° "
с а« о 5
U С «о
s-' 1
о ~
^ О
1
7н
СО
О »Q
Р 8
о 2
о о
§ * s
2 П "°
О СП V
L °- v
1 в о '
S %
* Г- CN *
-: о i
go о
+ о э
ОО 00 II
^ 8 3
CN P
<N О
1 1
ь
124

ОТРИЦАТЕЛЬНЫЙ ИОН ЙОДА I " (г)
Таблица 77
(окончание)
с;
Ф°G)
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
«200
8400
8600
8800
9000
9200
9400
9600
9800
10000
Дж К"" * • моль~
Я°(Г)-Я°@)
кДж • моль
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
,20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
211.443
212.103
212.743
213.363
213.966
214.551
215.121
215.675
216.215
216.741
217.255
217.756
218.245
218.722
219.190
219.646
220.093
220.531
220.960
221.380
232.229
232.889
233.529
234.149
234.752
235.337
235.907
236.461
237.001
237.527
238.041
238.541
239.031
239.508
239.976
240.432
240.880
241.317
241.746
242.166
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
К
1.4465
1.5607
1.6692
1.7723
1.8705
1.9641
2.0536
2.1393
2.2213
2.3000
2.3755
2.4481
2.5180
2.5854
2.6503
2.7129
2.7735
2.8320
2.8886
2.9434
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
н
со
О
§
о
ЧО
00
г-
о
I
V
V
о
§
i
125

Класс точности
Н-А
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
4bO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.135
36.062
36.887
36.897
37.256
37.464
37.613
37.735
37.847
37.956
38.070
38.196
38.341
38.514
38.719
38.959
39.231
39.528
39.842
40.161
40.474
40.768
41.035
41.266
41.456
41.600
41.697
41.747
41.751
41.711
41.630
41.51
41.359
41.176
40.966
40.733
40.480
40.210
39.925
39.629
39.323
39.010
38.691
38.368
38.042
37.715
37.387
37.061
36.735
36.412
36.092
35.775
35.462
35.153
34.848
34.549
34.254
33.965
33.681
33.402
33.129
К°(Т)= р2(\)-р~1(
Ф°(Т)
Дж • К • моль
191.542
213.350
226.647
226.857
236.739
244.549
251.013
256.530
261.343
265.614
269.454
272.942
276.138
279.089
281.830
284.390
286.792
289.057
291.198
293.231
295.167
297.014
298.782
300.477
302.106
303.673
305.184
306.643
ОАО ЛСО
OXJO.XJOJL
309.416
310.736
312.016
313.259
314.464
315.636
316.776
317.884
318.963
320.013
321.037
322.035
323.008
323.957
324.884
325.789
326.673
327.537
328.381
329.206
330.014
330.804
331.577
332.334
333.075
333.801
334.513
335.210
335.893
336.563
337.221
337.866
ДИИОД 12 (г)
V
5°G)
221.894
245.995
260.567
260.803
271.472
279.809
286.653
292.461
297.507
301.971
305.976
309.610
312.940
316.015
318.877
321.556
324.079
326.466
328.734
330.897
332.965
334.947
336.850
338.679
340.440
342.135
343.768
345.343
Q4fi 862
348.326
349.739
351.102
352.418
353.688
354.914
356.098
357.242
358.348
359.416
360.450
361.449
3621416
363.352
364.259
365.137
365.989
366.814
367.614
368.391
369.145
369.878
370.589
371.281
371.954
372.608
373.244
373.864
374.468
375.056
375.630
376.189
Н°(Т)-Н°@)
кДж * моль
3.035
6.529
10.117
10.184
13.893
17.630
21.384
25.152
28.931
32.721
36.522
40.335
44.162
48.005
51.866
55.749'
59.659
63.596
67.565
71.565
75.597
79.659
83.750
87.865
92.002
96.155
100.320
104.493
1 fift fifift
1 UO.OQO
112.841
117.009
121.166
125.310
129.437
133.544
137.629
141.690
145.725
149.731
153.709
157.657
161.574
165.459
169.312
173.132
176.920
180.675
184.397
188.087
191.745
195.370
198.963
202.525
206.056
209.556
213.025
216.465
219.876
223.259
226.613
229.939
°@) = 148.826 кДж-моль"
igtfV)
-73.4115
-34.1766
-21.2086
-21.0454
-14.4587
-10.4953
-7.8457
-5.9483
-4.5216
-3.4092
-2.5172
-1.7857
-1.1748
-.6567
-.2118
.1746
.5134
.8128
1.0794
1.3182
1.5336
1.7286
. 1.9062
2.0686
2.2175
2.3548
2.4816
2.5992
2.7086
2*8105
2.9058
2.9951
3.0790
3.1580
3.2325
3.3029
3.3695
3.4328
3.4929
3.5501
3.6046
3.6567
3.7065
3.7542
3.7998
3.8437
3.8859
3.9264
3.9655
4.0031
4.0395
4.0746
4.1086
4.1414
4.1733
4.2042
4.2341
4.2632
4.2915
4.3190
4.3457
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
лоии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
On
О
00
со
*о
<N
II
+
>о
00
00
00
">
1
с*
t
О
Ю
g
О
+
а
о
г-
Г-»
+
СО
со
со
II
g
ол
ф
Табли
-.
§
*
§
«о
•о
VO
II
s
52,
о
с:
i
X
w>
VO
О
+
н
VO
VO
О
1
н
00
со
vo
VO
«о
+
"л
|
1
СЧ
VO
II
Я
«о
00
ON
CM
о
<J
ца 78
7
о
•
&
ON
On
II
о 5
CO
t
2
о
о
vo
V
V
о
о
1
II
126

Класс i
11
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
ZOIFU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
очности
1
29.156
30.691
32.872
32.908
34.571
35.872
37.018
38.051
38.953
39.703
40.296
40.746
41.070
41.293
41.435
41.517
41.556
41.563
41.550
41.523
41.486
41.444
41.397
41.347
41.292
41.232
41.166
41.093
41.012
40.922
40.822
40.711
40.590
40.458
40.316
40.164
40.003
39.833
39.655
39.470
39.279
39.084
38.884
38.681
38.475
38.268
38.060
37.852
37.644
37.438
37.233
37.030
36.829
36.631
36.435
36.243
36.053
35.867
35.684
35.505
35.329
К°(Т)= рA)-р(
Ф°(Т)
Дж К • моль
177.254
197.457
209.333
209.520
218.333
225.364
231.253
236.344
240.843
244.885
248.560
251.933
255.054
257.957
260.673
263.224
265.630
267.905
270.064
272.117
274.073
275.943
277.732
279.447
281.095
282.679
284.205
285.676
OQ7 ЛОТ
288.471
289.800
291.087
292.334
293.545
294.720
295.862
296.973
298.053
299.105
300.130
301.129
302.103
303.053
303.981
304.887
305.772
306.637
307.483
308.310
309.120
309.913
310.689
311.449
312.194
312.924
313.640
314.342
315.031
315.707
316.370
317.021
ОКСИД ИОДА 10
О)-р'1(Ю)
-1
206.288
226.850
239.524
239.727
249.434
257.292
263.936
269.721
274.863
279.496
283.711
287.573
291.133
294.430
297.496
300.358
303.039
305.558
307.934
310.180
312.308
314.332
316.258
318.098
319.856
321.540
323-.156
324.709
aofi 9П2
ОлЛЛ.лЛЗл
327.639
329.025
330.362
331.652
332.900
334.105
335.272
336.401
337.495
338.555
339.582
340.579
341.547
342.486
343.399
344.286
345.148
345.987
346.803
347.598
348.372
349.126
349.861
350.579
351.278
351.961
352.628
353.279
353.916
354.538
355.146
355.742
Н°(Т)-Н°@)
кДж * моль
2.903
5.879
9.001
9.062
12.440
15.964
19.610
23.364
271216
31.150
35.151
39.204
43.296
47.415
51.552
55.700
59.854
64.010
68.166
72.320
76.470
80.617
84.759
88.896
93.028
97.154
101.274
105.387
| ЛП А ЛЛ
ШУ.4Ул
113.589
117.677
121.753
125.818
129.871
133.910
137.934
141.942
145.934
149.909
153.865
157.802
161.721
165.619
169.497
173.355
177.192
181.009
184.804
188.579
192.333
196.067
199.780
203.473
207.146
210.799
214.433
218.048
221.644
225.221
228.780
232.322
(г)
э@) = 222.000
igtfocr)
-112.1099
-53.6191
-34.2469
-34.0028
-24.1502
-18.2180
-14.2523
-11.4135
-9.2808
-7.6199
-6.2901
-5.2013
-4.2936
-3.5254
-2.8668
-2.2959
-1.7963
-1.3554
-.9635
-.6127
-.2970
-.0112
.2486
.4860
.7037
;9040
.0891
.2606
A1 QQ
ЛХтзъ
.5684
.7071
.8370
.9589
2.0736
2.1816
2.2837
2.3801
2.4716
2.5583
2.6408
2.7192
2.7940
2.8654
2.9336
2.9989
3.0614
3.1214
3.1789
3.2342
3.2874
3.3387
3.3880
3.4356
3.4816
3.5260
3.5690
3.6105
3.6508
3.6898
3.7276
3.7643
кДж'моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОПА
ZO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
СО
О
On
<Ч
rf
II
+
^
О
00
о
+
•х
ON
t—
1О
оо
о
О
О
1
со
VO
CN
00
О
+
о
УГ)
•*t
со
со
II
?
о
Таб л и
-•
г;
|
1 L
« п
§ 3
« оо
X О
П о
* о
СО
2t II
ON ;I
5 ?
О 00
° ON
г ~ CN
О •->
о 13
^ °>
<
т
«=:
1
]
к
m
**>
+
«о
ON
~*
1
х
ON
ОО
VO
ON
+
ца 79
'-*
§
т
?
со
&
О
•о
II
о 5
о 05
со
я
о
g
VO
V
V
о
о
• •
1
и
><
127

Класс точности
И-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
зёоо
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(т)
29.114
29.124
29.156
29.158
29.328
29.737
30.350
31.069
31.807
32.511
33.156
33.734
34.247
34.702
35.104
35.461
35.780
36.066
36.326
36.563
36.781
36.983
37.171
37.348
37.514
37.671
37.820
37.960
38.092
38.215
38.329
38.433
38.527
38.610
38.681
38.739
38.784
38.815
38.832
38.834
38.822
38.794
38.751
38.694
38.622
38.536
38.436
38.323
38.198
38.061
37.913
37.754
37.586
37.410
37.225
37.033
36.835
36.631
36.422
36.209
35.992
к'<г>- Р(нуР
Дж * К • моль
145.814
165.862
177.445
177.624
185.983
192.481
197.811
202.343
206.299
209.819
212.996
215.898
218.572
221.054
223.372
225.548
227.601
229.543
231.388
233.144
234.821
236.426
237.966
239.444
240.868
242.240
243.564
244.844
246.083
247.284
248.448
249.578
250.677
251.745
252.785
253.799
254.786
255.749
256.689
257.608
258.505
259.382
260.240
261.079
261.901
262.705
263.494
264.267
265.024
265.767
266.495
267.210
267.911
268.600
269.276
269.941
270.593
271.234
271.864
272.484
273.093
иодид
(D-P-4HI)
S°iT)
-1
174.662
194.845
206.480
206.659
215.065
221.649
227.123
231.854
236.051
239.839
243.298
246.486
249.443
252.203
254.790
257.224
259.523
261.701
263.770
265.740
267.621
269.421
271.145
272.802
274.395
275.929
277.410
278.840
280.223
281.562
282.859
284.118
285.339
286.526
287.680
288.802
289.894
290.957
291.993
293.001
293.984
294.943
295.877
296.788
297.677
298.544
299.390
300.215
301.021
301.807
302.574
303.324
304.055
304.769
305.467
306.148
306.814
307.464
308.099
308.720
309.327
ВОДОРОДА HI (г)
АгЯ°@) =294.662
*V)V"°«o
кДж • моль""
2.885 -150.6499
5.797 -73.2351
8.657 -47.6392
8.710 -47.3168
11.633 -34.3026
14.584 -26.4617
17.587 -21.2138
20.658 -17.4512
23.802 -14.6194
27.018 -12.4098
30.302 -10.6369
33.647 -9.1822
37.046 -7.9669
40.494 -6.9361
43.985 -6.0506
47.513 -5.2814
51.076 -4.6071
54.668 -4.0109
58.288 -3.4800
61.933 -3.0042
65.600 -2.5751
69.288 -2.1863
72.996 -1.8322
76.722 -1.5084
80.465 -1.2111
84.225 -.9371
87.999 -.6838
91.788 -.4490
95.591 -.2305
99.406 -.0269
103.234 .1635
107.072 .3419
110.920 .5093
114.777 .6668
118.642 .8153
•122.513 .9555
126.389
130.269
134.152
138.035
141.918
145.799
149.676
153.549
157.415
1.0881
1.2137
1.3328
1.4460
1.5537
.6563
.7542
.8476
.9370
161.273 2.0224
165.121 . 2.1043
168.959 2.1829
172.785 2.2583
176.598 2.3307
180.397 2.4003
184.180 2.4674
187.948 2.5319
191.697 2.5942
195.429 2.6542
199.142 2.7122
202.836 2.7682
206.509 2.8224
210.162 2.8748
213.793 2.9255
217.403 2.9747
Таблица 80
кДж'моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с:
*"* ^ Т
I S 1
jg О —»
\cn t-ч со ^
СЛ *** ^ *
R сЯ II Ч
^ 2 ? со
11 8 * 5
^ и ? о
Q °°' °'
С ™ "
~ * о g
К >_Г СО
<Г ?
^ °>
i
+
чо 7
со g
2 Р
'ё к §
2 *=* §
S *<=> w
§2 V
^ CN ^
+ V
Л % g
* S 5
00 СО
<N I ~
со *° ***
On
S ? "
CN +
II
128

Класс точности
И-В
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°(Т) = рф)-р(
Ф°(Г)
Дж • К • моль
29.112 151.443
29.135 171.555
29.360 183.162
29.368 183.342
30.044 191.732
31.003 198.283
32.005 203.690
32.918 208.317
33.703 212.376
34.362 216.003
34.911 219.286
35.371 222.290
35.759 225.062
36.090 227.637
36.376 230.042
36.625 232.300
36.846 234.429
37.045 236.442
37.225 238.353
37.390 240.172
37.543 241.907
37.687 243.567
37.824 245.157
37.953 246.684
38.077 248.152
38.196 249.566
38.309 250.930
38.417 252.248
38.520 253.523
38.617 254.756
38.706 255.953
38.788 257.113
38.861 258.240
38.924 259.336
38.977 260.402
39.019 261.440
39.048 262.451
39.064 263.436
39.067 264.398
39.056 265.337
39.031 266.254
38.992 267.149
38.938 268.025
38.870 268.882
38.788 269.720
38.692 270.541
38.583 271.344
38.462 272.132
38.328 272.903
38.183 273.660
38.028 274.401
37.862 275.129
37.688 275.843
37.505 276.543
37.314 277.231
37.116 277.906
36.913 278.569
36.704 279.221
36.490 279.861
36.272 280.490
36.051 281.108
иодид
DtT^DI)
S°<7->
~l
180.419
200.603
212.265
212.447
220.978
227.782
233.524
238.528
242.976
246.985
250.635
253.984
257.079
259.955
262.640
265.158
267.529
269.769
271.892
273.909
275.831
277.666
279.422
281.107
282.724
284.281
285.781
287.229
288.628
289.982 -
291.292
292.563
293.796
294.993
296.155
297.286
298.385
299.456
300.497
301.512
302.501
303.464
304.403
305.318
306.211
307.082
307.931
308.760
309.568
310.357
311.126
311.878
312.612
313.328
314.027
314.710
315.377
316.028
316.665
317.287
317.894
ДЕЙТЕРИЯ ]
ArH
Н°(Т)-№(())
кДж • моль"
2.898
5.810
8.677
8.731
11.699
14.750
17.900
21.148
24.480
27.884
31.349
34.863
38.420
42.013
45.637
49.287
52.961
56.656
60.369
64.100
67.847
71.609
75.384
79.173
82.975
86.788
90.614
94,450
98.297
102.154
106.020
109.895
113.777
117.667
121.562
125.462
129.365
133.271
137.178
141.084
144.988
148.890
152.786
156.677
160.560
164.434
168.297
172.150
175.989
179.815
183.626
187.420
191.198
194.958
198.699
202.420
206.122
209.803
213.462
217.100
220.716
DI(r)
э@) = 298.530
\gK°(T)
-152.5134
-74.0918
-48.1646
-47.8380
-34.6570
-26.7180
-21.4067
-17.6009
-14.7385
-12.5064
-10.7165
-9.2489
-8.0234
•6.9845
-6.0924
-5.3179
-4.6391
-4.0392
-3.5052
-3.0267
-2.5953
-2.204S
-1.8487
-1.5234
-1.2248
-.9497
-.6954
-.4596
-.2,404
-.0359
.1551
.3340
.5020
.6600
.8090
.9496
1.0825
1.2085
1.3279
1.4414
1.5494
1.6523
1.7503
1.8440
1.9335
2.0192
2.1013
2.1800
2.2555
2.3281
2.3979
2.4650
2.5297
2.5921
2.6522
2.7103
2.7664
2.8207
2.8732
2.9240
2.9732
кДж'моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
ЧО
00
On
00*
гч
4—1 ¦
II
+
1
I*-
о
+
с»
1
*о
00
On
О
О
О
!
чо
©
со
+
2
*¦*
сч
On
ГЧ
II
ол
Таблица 81
§
т ? т
ё * g
о п |
? х г
Д со f
5 N. ^
* ЧО
о ^ Д
я * з
« 2 5
s °° м
On И
е ~- ^
е
\ °
1
Л °
о
™Н чо
7 v
^' О
1 -4
S н
*-<
+
872
129

Класс точности
И-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.112
29.181
29.728
29.744
30.839
32.043
33.113
33.991
34.694
35.257
35.710
36.082
36.392
36.654
36.880
37.077
37.253
37.412
37.558
37.694
37.821
37.942
38.057
38.169
38.276
38.380
38.481
38.578
38.670
38.757
38.838
38.913
38.979
39.036
39.084
39.120
39.145
39.157
39.157
39.142
39.114
39.072
39.016
38.946
38.862
38.764
38.654
38.531
38.396
38.250
38.093
37.927
37.751
37.567
37.375
37.177
36.972
36.762
36.547
36.329
36.107
К°(Т)= р(ТO>
Ф°(Т)
Дж • К • моль
154.776
174.909
186.533
186.714
195.143
201.757
207.240
211.947
216.086
219.788
223.142
226.211
229.042
231.671
234.127
236.430
238.600
240.652
242.598
244.450
246.215
247.902
249.518
251.069
252.560
253.995
255.379
256.715
95ft ПП7
259.257
260.469
261.644
262.785
263.894
264.972
266.022
267.044
268.040
269.012
269.961
270.887
271.791
272.676
273.541
274.387
275.215
276.026
276.820
277.598
278.361
279.109
279.842
280.562
281.268
281.961
282.642
283.310
283.966
284.611
285.245
285.868
ИОДИД ТРИТИЯ
183.794
203.983
215.715
215.899
224.598
231.610
237.549
242.722
247.308
251.429
255.168
258.589
261.742
264.666
267.391
.269.942
272.340
274.604
276.747
278.781
280.717
282.566
284.333
286.028
287.654
289.219
290.726
292.180
9Q4 585
294.944
296.259
297.534
298.770
299.970
301.137
302.270
303.372
304.445
305.489
306.507
307.497
308.463
309.404
310.321
311.215
312.087
312.938
313.768
314.578
315.368
316.139
316.892
317.627
318.344
319.045
319.729
320.397
321.049
321.687
322.310
322.918
Л
И°(П-И°((
кДж • моль
2.902
5.815
8.700
8.755
11.782
14.926
18.186
21.543
24.978
28.477
32.026
35.616
39.240
42.893
46.570
50.268
53.985
57.718
61.467
65.229
69.005
72.793
76.593
80.405
84.227
88.060
91.903
95.756
QQ filR
«7«7.О 1 О
103.490
107.369
111.257
115.152
119.053
122.959
126.869
130.782
134.698
138.613
142.528
146.441
150.351
154.255
158.154
162.044
165.925
169.796
173.656
177.502
181.335
185.152
188.953
192.737
196.503
200.250
203.978
207.685
211.372
215.037
218.681
222.303
Т1(г)
г№@) = 300.270
))
1
\gK°(T)
-153.3333
-74.4584
-48.3825
-48.0541
-34.7994
-26.8182
•21.4806
-L7.6573
-14.7828
-12.5421
-10.7458
-9.2733
-8.0440
-7.0021
-6.1076
-5.3312
-4.6508
-4.0496
-3 5144
-3.0349
-2.6028
-2.2112
-1.8548
-1.5290
-1.2299
-.9544
-.6997
-.4636
-.2440
-.0394
.1519
.3311
.4993
.6574
.8065
.9473
1.0804
1.2064
1.3260
1.4396
1.5477
1.6506
1.7488
1.8425
1.9321
2.0179
2.1000
2.1788
2.2544
2.3270
2.3968
2.4640
2.5288
2.5912
2.6513
2.7095
2.7656
2.8199
2.8724
2.9233
2.9725
кДж'моль""
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
»О
8
fN
°*
ON
<N
II
+
5
t-
TJ-
tO
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4-
см
'*
г-
ON
On
On
*о
о
<р
о
1
*о
со
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со
+
со
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ON
On
ON
CN
II
g
о
Табли
о
2
•
<N
f».
со
00
cn
II
о
E
о
T
л
к
1
•p
k
CN
«O
I
n
X
«o
CN
CO
+
r-
<N
CO
»o
+
I
k
g
о
CN
Ю
00
ON
CN
E
о
ца 82
M
§
•
k
чо
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о
<N
II
о .05
со
?
о
о
VO
V
V
о
о
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I
О
II
130

Класс точности
III-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.214
31.225
33.460
33.494
34.922
35.784
36.332
36.703
36.971
37.175
37.338
37.475
37.593
37.699 ,
37.799
37.896
37.995
38.102
38.222
38.360
38.523
38.715
38.943
39.209
39.516
39.865
40.255
40.683
41.1 Н\)
41.638
42.152
42.680
43.215
43.749
44.272
44.776
45.254
45.700
46.106
46.468
46.782
47.045
47.254
47.409
47.509
47.556
47.549
47.492
47.387
47.236
47.042
46.809
46.541
46.240
45.911
45.556
45.179
44.783
44.371
43.947
43.511
К°(Т)=рA) -1
Ф°(Г)
Дж • К • моль
173.296
193.573
205.553
205.741
214.655
221.764
227.702
232.812
237.302
241.309
244.928
248.229
251.264
254.074
256.689
259.136
261.436
263.604
265.656
267.604
269.458
271.227
272.919
274.541
276.099
277.598
279.044
280.439
9ft I 7ftQ
ZO1. / Оэ
283.096
284.364
285.596
286.793
287.959
289.095
290.204
291.287
292.345
293.379
294.392
295.384
296.356
297.309
298.244
299.162
300.063
300.947
301.817
302.670
303.509
304.334
305.145
305.943
306.727
307.498
308.256
309.003
309.737
310.460
311.171
311.871
ФТОРИД ЙОДА IF
*F)-p-\lF)
S°(T)
202.401
223.154
236.064
236.272
246.120
254.013
260.589
266.219
271.139
275.506
279.431
282.996
286.262
289.276
292.073
294.684
297.133
299.440
301.621
303.691
305.663
307.547
309.353
311.090
312.765
344.385
315.956
317.483
Ч1A Q71
О 1 О.«7/ I
320.423
321.843
323.234
324.598
325.936
327.249
328.540
329.808
331.054
332.279
333.481
334.662
335.820
336.956
338.070
339.161
340.230
341.275
342.297
343.296
344.271
345.224
346.153
347.060
347.943
348.804
349.644
350.461
351.257
352.033
352.788
353.523
Н\Г)-Но@)
кДж • моль
2.911
5.916
9.097
9.159
12.586
16.125
19.732
23.385
27.070
30.777
34.503
38.244
41.998
45.762
49.537
53.322
57.116
60.921
64.737
68.566
72.410
76.272
80.154
84.062
87.997
91.966
95.972
100.018
104 110
I Wr. I IU
108.249
112.438
116.679
120.974
125.322
129.724
134.176
138.678
143.226
147.817
152.446
157.109
161.800
166.516
171.249
175.996
180.749
185.505
190.258
195.002
199.733
204.448
209.141
213.808
218.448
223.056
227.029
232.166
236.664
241.122
245.538
249.911
(г)
Я°@) - 271.600
lgtfV)
-137.8247
-66.4339
-42.8233
-42.5260
-30.5268
-23.3051
-18.4781
-15.0223
-12.4251
-10.4012
-8.7792
-7.4498
-6.3402
-5.3999
-4.5926
-3.8920
-3.2780
-2.7356
-2.2527
-1.8200
-1.4301
-1.0769
-.7554
-.4615
-.1917
.0567
.2862
.4989
.6966
.8808
1.0527
.2136
.3645
1.5062
.6396
1.7653
1.8840
1.9962
2.1023
2.2030
2.2985
2.3892
2.4756
2.5578
2.6361
2.7109
2.7823
2.8506
2.9160
2.9786
3,0386
3.0962
3.1515
3.2047
3.2558
3.3051
3.3525,
3.398S'.
3.4425
3.4851
3.5263
кДж • моль *
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900 .
6000
о
а
о
О)
»о
1—4
II
1
|
1Х
со
cn
р
+
On
On
о
О
О
1
w
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CN
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+
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1 а
»? ЧО
5 ©
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CN 00
VO |
2 "
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II »O
ч-Ч
Сн CN
^ oW
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CO
X
CN
«2
$
1
<s
X
3
CO
ON
+
X
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1
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T
T
k
VO
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О
CN
||
о в}
2
§
V
{•*
v
0
0
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I
О
II
131

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙЛ.П
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
52.622
83.863
102J48
103.010
113.644
119.721
123.410
125.785
127.391
128.524
129.350
129.970
130.447
130.821
131.120
131.362
131.562
131.727
131.866
131.985
132.086
132.173
132.248
132.315
132.373
132.424
132.469
132.510
132.546
132.579
132.609
132.635
132.659
132.682
132.7.02
132.720
132.737
132.753
132.767
132.780
132.793
132.804
132.815
132.825
132.834
132.843
132.851
132.858
132.865
132.872
132.878
132.884
132.890
132.895
132.900
132.905
132.909
132.913
132.917
132.921
132.925
К°(Т)~ p(I)-pS(F
Ф°(Т)
Дж • К" * • моль" 1
211.749
243.242
267.367
267.783
288.673
306.914
323.080
337.575
350.698
362.678
373.692
383.881
393.359
402.215
410.525
418.352
425.748
432.759
439.421
445.768
451.827
457.624
463.180
468.515
473.644
478.584
483.348
487.948
*Т«7А.О«7*Т
•496.697
500.866
504.908
508.831
512.643
516.348
519.953
523.463
526.883
530.218
533.471
536.646
539.748
542.779
545.743
548.642
551.479
554.257
556.979
559.646
562.260
564.825
567.340
569.810
572.234
574.615
576.954
579.252
581.512
583.734
585.919
588.069
ПЕНТАФТОРИД ИОДА
)-p"dF5)
S°(T)
250.498
297.237
334.594
335.230
366.469
392.540
414.720
433.935
450.843
465.916
479.502
491.861
503.192
513.648
523.354
532.409
540.894
548.875
556.408
563.541
570.314
576.760
582.911
588.791
594.424
599.828
605.023
610.023
614.843
619*495
623.990
628.338
632.550
636.632
640.593
644.441
648.180
651.817
655.357
658.806
662.168
665.447
668.647
671.773
674.826
677.812
680.731
683.589
686.386
689.125
691.810
694.441
697.022
699.553
702.037
704.476
706.871
709.223
711.535
713.807
716.041
\
ЯоG')-Я°@)
кДж ¦ моль
3.875
10.799
20.044
20.234
31.118
42.813
54.984
67.452
80.116
92.915
105.810
118.778
131.800
144.864
157.961
171.086
184.232
197.397
210.577
223.770
236.973
. 250.186
263.407
276.635
289.870
303.110
316.354
329.603
одп осе
356.113
369.372
382.634
395.899
409.166
422.435
435.706
448.979
462.254
475.530
488.807
502.086
515.366
528.647
541.929
555.212
568.496
581.780
595.066
608.352
621.639
634.926
648.214
661.503
674.792
688.082
701.372
714.663
727.954
741.246
754.537
767.830
IFsfr)
Н°@) = 1325.922
lg*°G*)
-666.8307
-317.6142
•202.1848
-200.7322
-142.1451
-106.9398
•83.4486
-68.6606
-54.0666
-44.2706
-36.4343
-30.0239
-24.6831
-20.1653
-16.2941
-12.9404
-10.0070
-7.4198
-5.1211
-3.0652
-1.2158
.4567
1.9765
3.3635
4.6343
5.8029
6.8811
7.8790
о олео
O.Ovu<?
9.6671
10.47U
11.2230
11.9275
12.5890
13.2113
13.7978
14*3515-
14.8750
15.3707
15.8403
16.2872
16.7116
17.1156
17.5007
17.8681
18.2190
18.5545
18.8756
19.1832
19.4780
19.7610
20.0327
20.2939
20.5450
20.7868
21.0197
21.2441
21.4606
21.6695
21.8713
22.0662
кДж'моль*"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
QQAA
ZO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
vo
Os
00
**•
<N
||
+
|
00
<N
r-
ON
+
X
00
vo
VO
VO
о
1
н
в
со
f-
Os
СО
+
00
as
с-^
о
as
vo
II
p
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Таб
|
k
00
CO
c4
CO
00
1
II
о
С
v>
Гт
V»/
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Л
I
1
ъ
VO
1О
+
VO
VO
со
1
X
<ч
•о
о
+
л и
1
лопь
0+
л
о
о
о
00
1
1
II
00
as
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ца 84
i
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со
II
п
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п «О
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VO
V
V
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1
II
132

Класс точности
VII-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
56.210
105.724
135.649
136.060
152.684
162.157
167.906
171.608
174.113
175.880
177.169
178.137
178.881
179.466
179.932
180.311
180.622
180.880
181.098
181.283
181.440
181.577
181.695
181.798
181.889
181.969
182.040
182.104
182.160
182.211
182.257
182.299
182.337
182.372
182.403
182.432
182.458
182.483
182.505
182.526
182.545
182.563
182.580
182.595
182.610
182.623
182.636
182.648
182.659
182.669
182.679
182.688
182.697
182.705
182.713
182.720
182.727
182.734
182.740
182.746
182.752
ГЕПТАФТОРИД
К°(Т) = рA)-р1
Ф°(Т)
Дж • К • моль
210.543
243.974
272.110
272.612
298.280
321.340
342.136
361.000
378.220
394.037
408.647
422.215
434.872
446.729
457.880
468.401
478.359
487.810
496.802
505.378
513.573
521.420
528.947
536.178
543.137
549.841
656.310
562.560
568.604
574455
580.126
585.627
590.968
596.158
601.205
606.117
610.901
615.563
62С ПО
624.547
628.879
633.111
637.248
641.293
645.251
649.125
652.919
656.636
660.279
663.851
667.355
670.793
674.167
677.481
680.736
683.933
687.077
690.167
693.205
696.195
699.135
(F)-p(IF7)
s°m
-!
249.635
304.647
353.018
353.859
395.511
430.692
460.806
486.987
510.075
530.691
549.291
566.225
581.758
596.100
609.418
621.845
633.493
644.451
654.796
664.592
673.895
682.751
691.201
699.280
707.019
714.446
721.584
728.456
735.079
741.472
747.650
753.627
759.416
765.027
770.472
775.760
780.899
785.399
790.766
795.507
800.128
804.636
809.035
813.332
817.529
821.633
825.647
829.575
833.421
Ь37.187
840.878
844.496
848.043
851.523
854.938
858.291
861.583
864.818
867.996
871.120
874.191
ИОДА IF7
Н°('П-Н°(())
кДж • моль"
3.909
12.135
24,123
24.374
38.893
54.676
71.202
88.190
105.484
122.988
140.644
158.412
176.264
194.183
212.153
230.166
248.213
266.288
284.388
302.507
320.644
338.795
356.9.58
375.133
393.348
411.510
429.711
447.918
A.(\f\ 1 19
ФОО. IО л
484.350
502.574
520.801
539.033
557.269
575.508
593.74*
611.994
630.241
648.490
666.742
684.996
703.252
721.508
739.767
758.027
776.289
794.552
812.815
831.081
849.348
867.615
885.884
904.153
922.423
940.694
958.965
977.238
995.5 И
1013.785
1032.059
1050.334
(г)
Н°@) = 1596.226
-796.0998
-374.8622
-235.4994
-233.7448
-162.9812
-120.4535
-92.0771
-71.8006
-56.5926
-44.7661
-35.3082
-27.5734
•21.1313
-15.6837
-11.0174
-6.9762
-3.4428
-.3275
2.4394
4.9130
7.1374
9.1483
10.9747
12.6410
14.1670
15.5698
16.8635
18.0604
10 17П7
1 9. 1 ( VI
20.2036
21.1668
22.0671
22.9 i 03
23.7018
24.4460
25.1471
25.8086
26.4339
27.0257
27.5866
28.1191
28.6251
29.1066
29.5653
30 0027
30.4204
30.8195
31.2013
31.5668
31.9172
32.2532
32.5757
32.8856
33.1835
33.4700
33.7460
34.0118
34.2681
34.5153
34.7539
34.9843
кДж'моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
млл
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
со
со
ON
°3
О>
II
+
7
со
ЧО
ЧО
+
'н
С-
VO
ON
<ч
о
о
1
1
со
00
со
<м
1—t
00
+
а
*-ц
00
г-
II
р
<*•
0
Таб
7.
•
00
со
00
ON
1
It
е
ь
о
6
1
•
ъ
00
+
с*
со
r^
«о
1
ё
С4.
ЧО
+
Л И
Г
й
О
о
*•}
ЧО
ON
1
1
II
с
мм
•О
00*
<N
С
0
ца 85
Та
1
НИ
•
й
ON
СО
<N
«О
•О
II
СС
о о?
- со
Я
о
§
ЧО
V
V
500
i
о
и
133

Класс точности
Ш-А
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
oofjO
zouu
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.177
33.787
35.554
35.575
36.413
36.869
37.153
37.352
37.504
37.629
37.738
37.839
37.936
38.035
38.141
38.260
38.397
38.557
38.744
38.960
39.204
39.472
39.759
40.057
40.358
40.652
40.931
41.186
41.409
41.594
41.735
41.829
41.874
41.868
41.813
41.709
41.559
41.367
41.135
40.867
40.567
40.240
39.889
39.519
39.133
38.733
38.325
37.910
37.491
37.071
36.652
36.235
35.822
35.415
35.014
34.621
34.236
33.860
33.494
33.137
32.791
К°(Т)-=рA)-р(С\)
Ф°(Л
Дж • К • моль
182.190
202.891
215.412
215.611
224.980
232.439
238.648
243.972
248.633
252.781
256.518
259.920
263.041
265.926
268.608
271.114
273.466
275.683
277.780
279.769
281.662
283.468
285.195
286.851
288.441
289.972
291.447
292.871
9QA 94Я
295.581
296.873
298.126
299:344
300.527
301.678
302.798
303.889
304.953
305.990
307.001
307.988
308.952
309.893
310.812
311.711
312.589
313.448
314.288
315.110
315.914
316.702
317.472
318.227
318.966
319.691
320.400
321.096
321.778
322.446
323.102
323.746
ХЛОРИД ИОДА IC1
тГЧга)
S°(T)
211.484
233.593
247.459
247.679
258.042
266.221
272.969
278.712
283.710
288.135
292.105
295.707
299.004
302.044
304.866
307.502
309.975
312.308
314.517
316.617
318.622
320.541
322.384
324.158
325.869
327.522
329.122
330.672
332.174
333.630
335.043
336.413
337.742
339.030
340.280
341.490
342:663
343.800
344.900
345.965
346.996
347.993
348.959
349.893
350.797
351.672
352.519
353.339
354.133
354.902
355.646
356.368
357.068
357.746
358.404
359.043
359.664
360.266
360.852
361.421
361.975
АгН
Н°(Г)~Но@)
кДж • моль" *
2.929
6.140
9.555
9.621
13.225
16.891
20.593
24.319
28.062
31:818
35.587
39.366
43.155
46.953
50.762
54.582
58.414
62.262
66.127
70.012
73.920
77.853
81.815
85.805
89.826
93.877
97.956
102.062
1 UU. 1 &*•
110.343
114.510
118.688
122.874
127.061
131.246
135.422
139.586
143.733
147.858
151.958
156.030
160.07.1
164.078
168.048
171.981
175.874
179.727
183.539
187.309
191.037
194.723
198.368
201.970
205.532
209.054
212.535
215.978
219.383
222.750
226.082
229.378
(г)
э@) =207.755
lgAfV)
-104.5347
-49.8511
-31.7735
-31.5459
-22.3615
-16.8328
-13.1353
-10.4863
-8.4937
-6.9397
-5.6933
-4.6710
-3.8170
-3.0928
-2.4707
-1.9305
-1.4568
-1.0381
.6652
-.3309
-.0296
.2434
.4920
.7193
.9279
1.1200
1.2976
1.4621
1.6150
1.7575
1.8906
2.0152
2.1320
2.2419
2.3454
2.4430
2.5353
2.6227
2.7055
2.7842
2.8590
2.9303
2.9983
3.0633
3.1254
3.1849
3.2419
3.2966
3.3492
3.3997
3.4484
3.4953
3.5406
3.5843
3.6265
3.6674
3.7069
3.7452
3.7823
3.8184
3.8534 '
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
«ouv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
»о
г-
»о
со
(Ч
ЧО
'—|
II
+
«о
сч
сч
г-
о
о
1
г»
!х
г-
со
<ч
со
• о
о
о
+
so
со
со
+
со
00
со
II
g
о
•е*
Табл
g
о
.?¦
00
g
On
т—(
II
о
С
а
о
=1,«
1
1
к
го
«о
гГ
i
с*
X
со
+
со
О
О)
ON
+
и
"л
5
1
On
СО
II
/—s
'-О
00
On
CN
у
5:
^\
ца 86
о
«5
г^
<N
О
J<
со
II
«О
2
о
о
о
VD
V
V
о
о
«о
i
о
II
134

Класс точности
Ш-А
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4500
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
31.869
35.360
36.515
36.528
37.031
37.308
37.490
37.625
37.736
37.834
37.925
39.016
38.114
38.228
38.371
38.556
38.795
39.099
39.475
39.924
40.442
41.019
41.641
42.290
42.948
43.593
44.206
44.769
45.267
45.687
46.020
46.260
46.406
46.457
46.416
46.288
46.079
45.796
45.448
45.043
44.588
44.092
43.563
43.008
42.433
41.844
41.247
40.646
40.045
39.447
38.856
38.274
37.702
37.143
36.598
36.068
35.552
35.053
34.569
34.102
33.651
БРОМИД ИОДА
*-m = P(D-p0
Ф°(Л
Дж • К • моль
191.129
212.444
225.444
225.650
235.348
243.036
249.413
254.865
259.628
263.857
267.663
271.151
274.292
277.219
279.939
282.478
284.861
287.107
289.231
291.246
293.166
294.998
296.753
298.438
300.059
301.622
303.132
304.592
306.008
307.382
308.717
310.015
311.279
312.510
313.710
314.880
316.022
317.137
318.226
319.290
320.329
321.345
322.338
323.309
324,259
325.188
326.097
326.986
327.856
328.707
329.541
330.357
331.156
331.939
332.706
333.457
334.193
334.915
335.622
336.315
336.995
вотг'ово
S°[T)
1
220.929
244.311
258.681
258.907
269.493
277.788
284.607
290.397
295.429
299.879
303.870
307.489
310.801
313.856
316.694
319.347
321.843
324.204
326.449
328.595
330.655
332.643
334.565
336.430
338.244
340.010
341.732
343.411
345.048
346.644
348.199
349.712
351.184
352.613
353.999
355.343
356.644
357.903
359.120
360.295
361.430
362.525
363.581
364.600
365.582
366.529
367.442
368.323
369.172
369.992
370.783
371.547
372.284
372.997
373.686
374.353
374.998
375.623
376.228
376.815
377.385
IBr (г)
АгИ
кДж • моль
2.980
6.374
9.910
9.977
13.658
17.376
21.117
24.Й73
28.641
32.419
36.207
40.004
43.811
47.628
51.457
55.303
59.170
63.065
66,993
70.962
74.980
79.052
83.185
87.382
91.643
95.971
100.361
104.810
109.313
113.861
118.447
123.062
127.696
132.340
136.984
141.620
146.239
150.833
155.396
159.921
164.403
168.837
173.220
177.549
181.821
186.035
190.190
194.284
198.319
202.294
206.209
210.065
213.864
217.606
221.293
224.926
228.507
232.037
235.518
238.952
242.339
°@) = П5.34С
-87.5406
-41.3553
-26.0923
-25.9001
-18.1497
-13.4874
-10.3717
-8.1410
-6.4642
-5.1570
-4.1089
-3.2493
-2.5312
-1.9221
-1.3988
-.9440
-.5451
-.1923
.1221
.4041
.6584
.8889
1.0989
1.2908
14670
1.6292
1.7789
1.9177
2.0465
2.1664
2,2782
2.3828
2.4808
2.5727
2.6592
2.7407
2.8176
2.8903
2.9591
3.0244
3.0864
3.1454
3.2017
3.2553
3.3066
3.3556
3.4026
3.4477
3.4910
3.5327
3.5728
3.6114
3.6487
3.6847
3.7195
3.7532
3.7858
3.8174
3.8481
3.8779
3.9069
) кДж'моль*
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
It
4-
'ё
00
о
V
S
о
О
о
g
оо
г-
о
со
сч
«о
©
со
II
g
Т а б л и
7
7 i
i I
% 00
Ё( ON
II «о
S а>
OS
о a
^ о
<1
7
С?
О
•
7
1-4
CN
|
с*
ON
н
00
со
00
+
ца 87
о
?
\^
00
CN
СО
II
п
О 05
5
О
О
О
ЧО
V
V/
о
о
V")
1
О
II
135

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
- 20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
Ф°(Т)
Дж • К • моль
82.548
96.956
105.256
105.384
111.364
116.002
119,792
122.996
125.772
128.220
130.410
132.391
134.200
135.864
137.404
138.838
140.180
141.440
142.628
143.752
144.818
145.832
146.799
147,723
148.608
149.456
150.271
151.056
151.812
152.541
153.246
153.927
154,587
155.227
155.847
156.450
157.036
157.605
158.159
158.699
159.226
159.739
160.240
160.729
161.207
161.674
162.131
162.578
163.015
163.444
163.864
164.275
164.679
165.075
165.464
165.845
166.219
166.587
166.949
167.304
167.654
ГЕЛИЙ Не (г)
S°(T)
-1
Н°(Т)-Н°«))
кДж • моль"Х
103.334 2.079
117.742 4.157
126.039 6.197
126.170 6.236
132.150 8.314
136.788 10.393
140.578 12.472
143.782 14.550
146.558 16.629
149.006 18.707
151.196 20.786
153.177 22.865
154.986 24.943
156.650 27.022
158.190 29.100
159.624 31.179
160.966 33.258
162.226 35.336
163.414 37.415
164.538 39.493
165.604 41.572
166.618 4^.651
167.585 45.729
168.509 47.808
169.393 49.886
170.242 51.965
171.057 54.044
171.842 56.122
172.598 58.201
173.327 60.279
174.032 62.358
174.713 64.437
175.373 66.515
176.013 68.594
176.633 70.672
177.236 72.751
177.821 74.830
178.391 76.908
178.945 78.987
179.485 81.065
180.012 83.144
180.525 85.223
181.026 87.301
181.515 .89.380
181.993 91.458
182.460 93.537
182.917 95.616
183.364 97.694
183.801 99.773
184.230 101.852
184.650 103.930
185.061 106.009
185.465 108.087
185.861 110.166
186.249 112.245
186.631 114.323
187.005 116.402
187.373 118.480
187.735 120.559
188.090 122.638
188.440 124.716
igA (/)
Г
К
— 100
— 200
— 298.15
— зоо
— 400
— 500
— 600
— 700
— 800
— 900
— юоо
— поо
— 1200
— 1300
— 1400
— 1500
— 1600
— 1700
— 1800
— 1900
— 2000
~ 2100
— 2200
~ 2300
~ 2400
— 2500
— 2600
— 2700
— 2900
- зооо
— зюо
— 3200
~ 3300
~ 3400
— 35С0
— 3600
— 3700
— 3800
— 3900
— 4000
— 4100
— 4200
— 4300
— 4400
— 4500
— 4S00
— 4700
~ 4800
— 4900
— 5000
~ 5100
~ 5200
— 5300
~ 5400
— 5500
— 5600
— 5700
— 5800
~ 5900
— 6000
о
§
1!
i
*
1
Таблица 88
о
и
и *°
*™i о
о* °°
о ?
Я
о
о
о
о
[ V
V
7859
100
о ^'
+ о
с^
<^
ос
с*
! "
136

ГЕЛИЙ Не (г)
Таблица 88
(окончание)
С°р{Т)
Ф°G)
s°m
Дж К~* • моль" *
кДж * моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786.
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
168.335
168.995
169.635
170.255
170.858
171.443
172.013
172.567
173.107
173.633
174.147
174.647
175.136
175.614
176.081
176.538
176.985
177.423
177.852
178.272
179.286
180.253
181.177
182.061
182.910
183.725
184.509
185.265
185.995
186.700
187.381
188.041
188.681
189.301
189.904
190.489
191.059
191.613
192.153
192.679
189.121
189.781
190.421
191.041
191.644
192.229
192.799
193.353
193.893
194.419
194.932
195.433
195.923
196.400
196.868
197.324
197.771
198.209
198.638
199.058
200.072
201.039
201.963
202.847
203.696
204.511
205.296
206.052
206.781
207.486
208.167
208.827
209.467
210.087
210.690
211.275
211.845
212.399
212.939
213.465
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
137

Класс точности
I-A
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
210fr
2200
2300
2400
2500
2600
2700
9ЯП0
2900
3000
3100
3200
ззео
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
On
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ПОЛОЖИТЕЛЬНЫЙ ИОН
А'°(Г) = р(Не)-/
Ф°(Л
Дж • К • моль
111.017
111.146
117.126
121.764
125.554
128.758
131.533
133.982
136.172
138.153
139.961
141.625
143.165
144.600
145.941
147.201
148.389
149.513
150.579
151.594
152.560
153.484
154.369
155.218
156.033
156.817
157.573
158.303
159.007
159.689
160.349
160.988
161.609
162.212
162.797
163.367
163.921
164.461
164.987
165.500
166.001
166.490
166.968
167.435
167.892
168.339
168.777
169.205
169.625
170.037
170.440
170.836
171.225
171.606
171.981
172.349
172.710
173.066
173.415
гГ1(Не)чГ1(е)
131.803
131.932
137.912
142.550
146.340
.149.544
152.319
154.768
156.958
158.939
160.747
162.411
163.952
165.386
166.727
167.987
169.175
170.299
171.365
172.380
173.346
174.270
175.155
176.004
176.819
177.603
178.359
179.089
179.793
180.475
181.135
181.774
182.395
182.997
183.583
184.152
184.707
185.247
185.773
186.286
186.787
187.276
187.754
188.221
188.678
189.125
189.563
189.991
190.411
190.823
191.227
191.623
192.011
192.392
192.767
193.135
193.496
193.852
194.201
А
Н°(Г)-Н°((
кДж • моль"
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60^279
62.358
&4.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
. 83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
ГЕЛИЯ Не+ (г)
гН°@) - -2372.
))
1
lgK°(T)
415.3104
412.7406
309.1653
246.9651
205.4619
175.7-907
153.5180
136.1796
122.2968
110.9282
101.4462
93.4159
86.5269
80.5512
75.3180
70.6965
66.5849
62.9029
59.5862
56.5829
53.8502
51.3530
49.0620
46.9524
45.0034
43.1973
41.5187
39.9545
38.4934
37.1254
35.8417
34.6349
33.4980
32.4253
31.4112
30.4512
29.5409
28.6765
27.8547
27.0723
26.3266
25.6149
24.9350
24.2847
23.6622
23.0657
22.4936
21.9444
21.4166
20.9092
20.4209
19.9506
19.4973
19.0602
18.6383
18.2308
17.8371
17.4565
17.0882
324 кДж'моль"
/'
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
•1
7
А
О
k
8 *
ГМ CM
§ т.
• СМ
II СМ
о
С
X
о
а:
<г
1А
§
1
k
Й
со
о
см
+
о
ГО
о
со
Ь
б л и
О
к
см
со
сп
см
II
ю
со
см
и
+ ~
о
<f
ца 89
О
II
0 В{
со
о
о
о
С-1
V
Гх
V
«о
•
со
о>
С-1
"о
II
vis
138

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р{Т)
ПОЛОЖИТЕЛЬНЫЙ ИОН
S° (Г)
Дж К • моль"
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
174.097
174.756
175.396
176.017
176.619
177.205
177.774
178.329
178.868
179.395
179.908
180.409
180.898
181.376
181.843
182.300
182.747
183.184
183.613
184.033
185.047
186.014
186.938
187.823
188.671
189.487
190.271
191.027
191.756
192.461
193.143
193.803
194.442
195.063
195.665
196.251
196.820
197.375
197.915
198.441
194.883
195.543
196.182
196.803
197.405
197.991
198.560
199.115
199.655
200.181
200.694
201.195
201.684
202.162
202.629
203.086
203.533
203.971
204.399
204.819
205.833
206.800
207.724
208.609
209.457
210.273
211.057
211.813
212.542
213.247
213.929
214.589
215.228
215.849
216.451
217.037
217.606
218.161
218.701
219.227
ГЕЛИЯ Не+ (г)
#°(Г)-#о@)
кДж' моль
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
\$К°(Т)
16.3864
15.7273
15.1072
14.5226
13.9704
13.4481
12.9532
12.4836
12.0373
11.6127
11.2081
10.8221
10.4535
10.1010
9.7637
9.4405
9.1306
8.8331
8.5473
8.2725
7.6294
7.0425
6.5044
6.0093
5.5519
5.1280
4.7340
4.3667
4.0234
3.7017
3.3996
3.1153
2.8472
2.5939
2.3542
2.1269
1.9111
1.7059
1.5105
1.3145
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14^00
1 ЧО1/1/
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 89
(окончание)
N
139

Класс точности
I
НЕОН Ne (г)
Таблица 90
К
с"рт
Ф°(Т)
S°iT)
Дж • К • моль
кДж • моль
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
102.724
117.132
125.431
125.560
131.539
136.178
139.967
143.172
145.947
148.395
150.585
152.567
154.375
156.039
157.579
159.013
160.355
161.615
162.803
163.927
164.993
166.007
166.974
167.898
168.783
169.632
170.447
171.231
171.987
172.716
173.421
174.103
174.763
175.402
176.023
176.625
177.211
177.780
178.335
178.875
179.401
179.914
180.415
180.904
181.382
181.849
182.306
182.753
183.191
183.619-
184.039
184.451
184.854
185.250
185.639
186.020
186.395
186.763
187.124
187.480
187.829
123.510
137.918
146.214
146.346
152.325
156.964
160.753
163.958
166.733
169.181
171.372
173.352
175.161
176.825
178.365
179.799
181.141
182.401
183.589
184.713
185.779
186.793
187.760
188.684
189.569
190.417
191.233
192.017
192.773
194.207
194.889
195.549
196.188
196.809
197.411
197.997
198.566
199.121
199.661
200.187
200.700
201.201
201.690
202.168
202.635
203.092
203.539
203.977
204.405
204.825
205.237
205.640
206.036
206.425
206.806
207.181
207.549
207.910
208.266
208.615
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г-
о
II
О
II
О 00
ON
U (N
ЧО
00
+
00
140

НЕОН Ne (г)
Таблица 90
(окончание)
С°р(Т)
к
Дж К"*1 • моль"
кДж * моль""
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
188.511
189.170
189.810
190.431*
191.033
191.619
192.188
192.743
193.283
193,809
194.322
194.823
195.312
195.790
196.257
196.714
197.161
197.598
198.027
198.447
199.461
200.428
201.352
202.237
203.085
203.900
204.685
205.441
206.170
206.875
207.557
208.216
208.856
209.477
210.079
210.665
211.234
211.789
212.328
212.855
209.297
209.956
210.596
211.217
211.819
212.405
212.974
213.529
214.068
214.595
215.108
215.609
216.098
216.576
217.043
217.500
217.947
218.384
218.813
219.233
220.247
221.214
222.138
223.023
223.871
224.687
225.471
226.227
226.956
227.661
228.343
229.003
229.642
230.263
230.865
231.451
232.020
232.575
233.115
233.641
128.873
133.031
137.188
141.345
145.502
149.659
153.817
157.974
162.131
166.288
170.445
174.603
178.760
182.917
187.074
191.231
195.388
199.546
203.703
207.860
218.253
228.646
239.039
249.432
259.825
270.218
280.611
291.004
301.397
311.790
322.183
332.576
342.969
353.362
363.755
374.148
384.541
394.934
405.327
415.720
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
141

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАЛ
лОММ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°}(Т)
22.115
22.129
22.647
22.788
22.720
22.564
22.385
22.210
22.051
21.910
21.787
21.680
21.589
21.509
21.440
21.380
21.327
21.281
21.240
21.204
21.172
21.143
21.118
21.095
21.074
21.055
21.038
2L023
21.009
20.996
20.984
20.973
20.963
20.954
20.945
20.937
20.930
20.923
20.917
20.911
20.905
20.900
20.895
20.891
20.887
20.883
20.879
20.875
20.872
20.869
20.866
20.863
20.860
20.858
20.855
20.853
20.851
20.849
20.847
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°(Г)
Дж • К~1 • моль" 1
137.052
137.183
143.311
148.130
152.107
155.492
158.434
161.034
163.362
165.467
167.388
169.153
170.785
172.302
173.719
175.049
176.301
177.483
178.603
179.667
180.680
181.647
182.572
183.458
184.308
185.126
1 fie Q] о
1OO.91 л
186.671
187.403
188.110
188.795
189.457
190.100
190.723
191.329
191.917
192.489
193.047
193.589
194.118
194.634
195.137
195.629
196.109
196.579
197.038
197.488
197.927
198.358
198.780
199.194
199.600
199.998
200.388
200.772
201.148
201.518
201.881
202.238
(NeVp-(e)
s°m
158.194
158.331
164.779
169.853
174.004
177.495
180.496
183.123
185.454
187.549
189.450
191.190
192.793
194.280
195.665
196.963
198.184
199.336
200.426
201.462
202.447
203.388
204.287
205.149
205.976
206.771
207.536
208.274
208.986
209.675
210.341
210.987
211.613
212.220
212.811
213.384
213.943
214.486
215.016
215.532
216.036
216.528
217.008
217.478
217.937
218.386
218.826
219.256
219.678
220.091
220.497
220.894
221.284
221.667
222.042
222.412
222.774
223.131
223.481
Н°(Т)-Н°
НЕОНА Ne+ (г)
д И°@) =-2080.661 кДж-моль"
@)
кДж * моль
6.304
6.344
8.587
10.861
13.138
15.402
17.650
19.879
22.092
24.290
26.475
28.648
30.811
32.966
35.114
37.255
39.390
41.520
43.646
45.768
47.887
50.003
52.116
54.226
56.335
58.441
60.546
62.649
64.751
66.851
68.950
71.048
73.144
75.240
77.335
79.429
81.523
83.615
85.707
87.799
89.890
91.980
94.070
96.159
98.248
100.336
102.424
104.512
106.599
108.686
110.773
112.859
114.946
117.032
119.117
121.203
123.288
125.373
127.457
\%К°(Т)
363.9069
361.6523
270.7646
216.1723
179.7374
153.6844
134.1233
118.8929
106.6956
96.7056
88.3718
81.3129
75.2561
70.0016
65.3992
61.3341
57.7170
54.4775
51.5589
48.9157
46.5104
44.3120
42.2949
40.4372
38.7208
37.1299
35.6513
34^2732
32.9858
31.7802
30.6489
29.5851
28.5829
27.6370
26.7429
25.8962
25.0933
24.3309
23.6059
22.9156
'22.2575
21.6294
21.0293
20.4553
19.9057
19.3791
18.8739
18.3888
1*7.9227
17.4745
17.0430
16.6275
16.2270
15.8407
15.4678
15.1076
14.7596
14.4230
14.0973
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
«о
оо
ft
о
сч
II
1
1
00
©
О
с*
со
00
О
О
СЧ
со
со
сч
со
сч
сч
II
?
Т а б л и
§ ^
i m
3 §
оо "
О ^
п \Z
Ч »
о + *
S
^ 0
о
1
&
{Г)
Г*
00
сч
1
^>
оо
VO
ON
ON
сч
00
• 1
Ца 91
1
§
к
и
о *
•->
О
о
\ /
V
t
\ /
V
i
о
о
'о'
II
142

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
160Q0
16500
17000
17500
18000
18500
19000
19500
20000
]
С°ЛТ)
20.843
20.840
20.836
20.834
20.831
20.829
20.826
20.824
20.822
20.821
20.819
20.818
20.816
20.815
20.814
20.812
20.811
20.810
20.809
20.808
20.806
20.805
20.803
20.802
20.801
20.799
20.798
20.798
20.797
20.796
20.796
20.795
20.794
20.794
20.793
20.793
20.793
20.792
20.792
20.792
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°<7)
Дж К • моль"
202.934
203.608
204.261
204.894
205.508
206.105
206.685
207.249
207.799
208.334
208.856
209.365
209.862
210.348
210.822
211.286
211.739
212.183
212.618
213.044
214.072
215.051
215.987
216.882
217.740
218.565
219.357
220.121
220 858
221.569
222.257
222.923
223.568
224.194
224.802
225.392
225.966
226.525
227.069
227.599
S\T)
224.164
224.826
225.467
226.089
226.693
227.280
227.851
228.406
228.947
229.474'
229.988
230.490
230.980
231.458
231.926
232.384
232.831
233.269
233.698
234.119
235.134
236.102
237.027
2^7.912
238.761
239.577
240.362
241.118
241.848
242.553
243.235
243.895
244.535
245.156
245.759
246.344
246.914
247.468
248.009
248.535
НЕОНА Ne+ (г)
Я°(Г)-Я°@)
кДж • моль""
131.626
135.795
139.962
144.129
148.296
152.462
156.627
160.792
164.957
169.121
173.285
177.449
181.612
185.775
189.938
194.101
198.263
202.425
206.587
210.749
221.153
231.556
241.957
252.359
262.759
273.159
283.559
293.958
304.356
314.755
325.152
335.550
345.947
356.344
366.741
377.138
387.534
397.931
408.327
418.723
13.4767
12.8937
12.3450
11.8276
11.3389
10.8764
10.4382
10.0222
9.6268
9.2505
8.8919
8.5498
8.2229
7.9104
7.6111
7.3244
7.0494
6.7853
6.5316
6.2875
5.7163
5.1946
4.7162
4.2757
* 3.8686
3.4911
3.1401
2.8127
2.5065
2^2195
1.9498
1.6959
1.4564
1.2300
1.0156
.8122
.6191
.4353
.2602
.0835
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 91
(окончание)
i
о ч
я i
| 2
I Ij О
^ * о
^ \ /
—« V
чО го .
О Н Ьч
S - v
? ° <=>
"** О О
S 2 2
^ о ^
+ j, II
го О
г"> 1
II
с
143

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ОП 7ftfi
*U< / OU
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
АРГОН Аг (г)
Ф°(Л
Дж К • моль"*
//°G')-//°@)
кДж * моль
\gK°(T)
111.241 132.027 2.079 —
125.649 146.435 4.157 —
133.948 154.732 6.197 —
134.077 154.863 6.236 —
140.057 160.843 8.314 —
144.695 165.481 10.393 —
148.485 169.271 12.472 -
151.689 172.475 14.550 —
154.464 175.250 16.629 -
156.913 177.699 18.707 —
159.103 179.889 20.786 —
161.084 181.870 22.865 -
162.892 183.678 24.943 -
164.556 185.342 27.022 —
166.097 186.883 29.100 —
167.531 188.317 31.179 -
168.872 189.658 33.258 —
170.132 190.918 35.336 —
171.320 192.106 37.415
172.444 193.230 39.493 —
173.510 194.296 41.572 —
174.524 195.311 43.651 —
175.492 196.277 45.729 —
176.416 197.201 47.8O8 —
177.300 198.086е 49.886 —
178.149 198.935 51.965 —
178.964 199.750 54.044 —
179.748 200.534 56.122 —
180 504 201.290 58 201
181.234 202.020 60.279 —
181.938 202.724 62.358 -
182*620 203.406 64.437 —
183.280 204.066 66.515 —
183.920 204.705 68.594 —
184.540 205.326 70.672 —
185.143 205.929 72.751 —
185.728 206.514 74.830 -
186.298 207.084 76.908 —
186.852 207.638 78.987 —
187.392 208.178 81.065 —
187.918 208.704 83.1.44 —
188.43Д 209.217 85.223 —
188.932 209.718 87.301 —
189.421 210.207 89.380 —
189.899 210.685 91.458 —
190.366 211.152 93.537 —
190.823 211.609 95.616 —
191.270 212.056 97.694 —
191.708 212.494 99.773 —
192.136 212.923 101.852 —
192.556 213.342 103.930 —
192.968 213.754 106.009 —
193.372 214.158 108.087 —
193.768 214.554 110.166 —
194.156 214.942 I12.24S —
194.537 215.324 114.323 —
194.912 215.698 116.402 —
195.280 216.066 118.480 —
195.641 216.428 120.559 —
195.997 216.783 122.638 —
196.346 217.132 124.716 —
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 92
~*
i
Л
§
00 «
О) о *
й » К
11 о 5 к
^ " wo <Ч
^ — О
О сг
^л м О ОС
< J СО
о <
<
7 ' Я
л о
2 §
• а
« v
* г
Й ч/
Й V
•s §
оо -.
«^ ?
8 2
1
II
С
О
•е-
144

АРГОН Аг (г)
Таблица 92
(окончание)
G)
Ф°G)
S°(T)
к
Дж К" -моль"*1
кДж' моль
К
6200
6400
6600
6800
70С0
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.787
20.788
20.788
20.789
20.790
20.792
20.794
20.797
20.807
20.825
20.854
20.899
20.965
21.060
21.191
21.366
21.593
21.884
22.245
22.687
23.218
23.845
24.575
25.413
26.363
27.427
28.603
29.891
197.028
197.688
198.327
198.948
199.550
200.136
200.705
201.260
201.800
202.326
202.839
203.340
203.829
204.307
204.774
205.231
205.678
206.116
206.544
206.964
207.978
208.945
209.870
210.755
211.604
212.419
213.205
213.962
214.694
215.401
216.087
216.752
217.398
218.027
218.640
219.23Э
219.824
220.397
220.959
221.512
217.814
218.474
219.113
219.734
220.336
220.922
221.491
222.046
222.586
223.112
223.625
224.126
224.615
225.093
225.560
226.017
226.464
226.902
227.331
227.751
228.766
229.734
230.660
231.549
232.403
233.227
234.024
234.798
235.552
236.288
237.012
237.725
238.431
239.133
239.834
240.538
241.247
241.964
242.692
243.432
128.873
133.031
137.188
141.345
145.502
149.659
153.817
-157.974
162.131
166.288
170.445
174.603
178.760
182.918
187.075
191.233
195.391
199.549
203.708
207.867
218.267
228.675
239.094
249.532
259.997
270.502
281.063
291.700
302.437
313.304
324.333
335.562
347.035
358.796
370.897
383.390
396.329
409.772
423.775
438.394
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
10 67S
145

Класс точное ги |
1 Л
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
j
с(рт
20.984
20.990
21.421
21.913
22.318
22.587
22.734
22.786
22.773
22.719
22.639
22.547
22.449
22.351
22.255
22.163
22.076
21.995
21.920
21.850
21.785
21.725
21.670
21.619
21.572
21.528
21.488
21.451
21.416
21.384
21.354
21.326
21.300
21.276
21.253
21.232
21.213
21.194
21.177
21.160
21.145
21.131
21.117
21.104
21.092
21.081
21.070
21.060
21.050
21.041
21.032
21.024
21-016
21.008
21.001
20.994
20.988
20.981
20.976
ПОЛОЖИТЕЛЬНЫЙ ИОН АРГОНА Аг+ (г)
А°(Л = р(Ах)-р
Ф°(Л
Дж • К • моль
145.478
145.607
151.607
156.288
160.144
163.431
166.301
168.850
171.142
173.225
175.133
176.893
178.526
180.048
181.473
182.812
184.074
185.269
186.402
187.479
188.506
189.486
190.424
191.323
192.187
193.017
193.816
194.586
195.330
196.049
196.745
197.418
198.071
198.705
199.320
199.918
200.500
201.066
201.617
202.155
202.679
203.190
203.690
204.178
204.654
205.121
205.577
206.023
206.461
206.889
207.309
207.720
208.124
208.520
208.909
209.291
209.666
210.034
210.396
-1
166.293
166.423
172.516
177.350
181.383
184.845
187.872
190.553
192.954
195.122
197.096
198.904
200.572
202.117
203.556
204.903
206.167
207.359
208.485
209.553
210.568
211.535
212.458
213.342
214.189
215.002
215.784
216.538
217.264
217.966
218.644
219.301
219.937
220.554
221.153
221.735
222.301
222.852
223.388
223.911
224.421
224.918
225.404
225.878
226.342
226.796
227.239
227.674
228.099
228.516
228.924
229.325
229.718
230.103
230.482
230.853
231.218
231.577
231.930
1 а о л и и а 93
Д.Я°(()> - - 1520.572 кДж-моль"*1
кДж • моль
6.206 265.7878
6.245 264.1381
8.364 197.6370
10.531 157.6798
12.744 131.0033
14.990 И 1.9207
17.257 97.5877
19.534 86.4232
21.812 77.4785
24.087 70.1491
26.355 64.0324
28.614 58.8491
30.864 54.3998
33.104 50.5381
35.334 47.1543
37.555 44.1643
39.767 41.5027
41.971 39.1180
44.166 36.9686
46.355 35.0213
48.537 33.2485
50.712 31.6276
52.882 30.1397
55.046 28.7690
57.206 27.5020
59.361 26.3272
61.512 25.2349
63.658 24.2165
65.802 23.2647
67.942 22.3731
70.079 21.5361
72.213 20.7488
74.344 20.0068
76.473 19.3062
78.599 18.6437
80.723 18.0162
82.846 17.4209
84.966 16.8554
87.084 16.3175
89.201 15.8051
91.317 15.3165
93.430 14.8500
95.543 14.4041
97.654 13.9775
99.764 13.5689
101.872 13.1772
103.980 12.8013
106.086 12.4403
108.192 12.0932
110.296 11.7594
112.400 11.4380
114.503 11.1283
116.605 10.8297
118.706 10.5416
120.806 10.2634
122.906 9.9946
125.005 9.7348
127.104 9.4834
129.201 9.2402
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
т ®
| * 7.
«? [И] Л
* $
v Г— *
(С CN \О '.,
^- Г*- С4) н5
O^ 1Л) 1О *
со Г> II Й
|| 12 ,-s С-~
S » * 3
- S 2 с5
." ОО 1!
On
+ - CN cj
< ~~ °со*
!
1 «
1 '*•
о ~
ч< * ^
СО гп \/
§ ? ь.
^ Г"- bi
О со \ '
1 , v
2 w §
с ъ о
^ о
о ©
S © V
« ~ '2
+ х Т
СО L^
СО ON ^
00 ON II
ON 00
оо 2 w
II
с
С*"»
°^
146

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
с°рсп
20.964
20.954
20.945
20.936
20.928
20.921
20.914
20.908
20.902
20.897
20.892
20.887
20.883
20.879
20.875
20.871
20.868
20.865
20.862
20.859
20.853
20.847
20.843
20.840
20.838
20.838
20.839
20.843
20.849
20.859
20.873
20.893
20.919
20.951
20.993
21.043
21.105
21.178
21.264
21.364
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°G)
Дж К • моль"
211.102
211.785
212.446
213.087
213.709
214.313
214.900
215.471
216.027
216.569
217.097
2.17.612
218.114
218.605
219.084
219.553
220.011
220.460
220.899
221.329
222.367
223.355
224.299
225.202
226.068
226.899
227.698
228.467
229.209
229.926
230.619
231.290
231.940
232.570
233.181
233.776
234.354
234.917
235.465
235.999
-1
232.617
233.283
233.927
234.552
235.159
235.749
236.322
236.880
237.423
237.952
238.468
238.971
239.462
239.943
240.412
240.870
241.319
241.759
242.189
242.610
243.628
244.598
245.524
246.411
247.262
248.079
248.866
249.624
250.355
251.062
251.746
252.409
253.052
253.677
254.285
254.877
255.455
256.018
256.570
257.109
АРГОНА Аг+ (г)
Я°(Л-Я°@)
кДж' моль""
133.395 8.7763
137.587 8.3403
141.777 7.9297
145.965 7.5422
150.152 7.1760
154.337 6.8293
158.520 6.5005
162.702 6.1882
166.883 5.8912
171.063 5.6083
175.242 5.3386
179.420 5.0811
183.597 4.8350
187.773 4.5994
191.948 4.3738
196.123 4.1575
200.297 3.9499
204.470 3.7504
208.643 3.5586
212.815 3.3741
223.243 2.9417
233.668 2.5462
244.090 2.1830
254.511 1.8480
264.930 1.5381
275.349 1.2503
285.768 .9824
296.188 .7321
306.611 .4978
317.038 .2780
327.471 .0712
337.912 -.1237
348.365 -.3077
358.832 -.4818
369.318 -.6467
379.826 -.8032
390.363 -.9518
400.933 -1.0932
411.543 -1.2278
422.199 -1.3658
Г
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 93
(окончание)
1
i
н ^
ос j2
5 Р
\ Х §
*"" С{ о
§ ъ ^
о Я V
+ <=> о
? ! §
? ^ о
сч + ""'
+ ^ w
о °°
°! '
II
к
о
147

Класс точности
I
КРИПТОН Кг (г)
Таблица 94
Ф°(Л
S°(T)
Дж • К~1 • моль
Я°(Г)-Я°@)
кДж • моль"
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
2С.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.766
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
.20.786
20.786
120.481
134.888
143.188
143.316
149.296
153.935
157.724
160.928
163.704
166.152
168.342
170.323
172.132
173.796
175.336
176.770
178.112
179.372
180.560
181.684
182.750
183.764
184.731
185.655
186.540
187.388
188.204
188.988
189.744
190.473
191.178
191.860
192.520
193.159
193.780
194.382
194.968
195.537
196.092
196.632
197.158
197.671
198.172
198.661
199.139
199.606
200.063
200.510
200.948
201.376
201.796
202.208
202.611
203.007
203.396
203.777
204.152
204.520
204.881
205.236
205.586
141.267
155.675
163.971
164.103
170.082
174.720
178.510
181.714
184.490
186.938
189 Л 28
191.109
192.918
194.582
196.122
197.556
198.898
200.158
201.346
202.470
203.536
204.550
205.517
206.441
207.326
208.174
208.990
209.774
210.530
211.259
211.964
212.646
213.306
213.945
214.566
215.168
215.754
216.323
216.878
217.418
217.944
218.457
218.958
219.447
219.925
220.392
220.849
221.296
221.734
222.162
222.582
222.994
223.397
223.793
224.182
224.563
224.938
225.306
225.667
226.022
226.372
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
53.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
II
й
о
а:
'д -
1,
§ §
о S
о
о
о
00 ?
о о
<N +
+ Н
о о
§ о
^ О
II
Р
о
ч©
V
V
148

КРИПТОН Кг (г)
Таблица 94
(окончание)
С°р G)
Ф°G)
Дж К -моль"
кДж • моль
""*
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.786
20.786
20.786
20.786
20.786
20.787
20.787
20.788
20.788
20.790
20.792
20.794
20.798
20.802
20.809
20.817
20.827
20.841
20.858
20.879
20.955
21.078
21.263
21.534
21.912
22.424
23.096
23.955
25.027
26.335
27.897
29.726
31.829
34.204
36.841
39.720
42.810
46.072
49.459
52.914
206.267
206.927
207.567
208.187
208.790
209.376
209.945
2.10.499
211.039
211.566
212.079
212.580
213.069
213.547
214.014
214.471
214.918
215.356
215.784
216.204
217.219
218.187
219.112
219.999
220.850
221.670
222.461
223.226
223.968
224.690
225.393
226.080
226.754
227.416
228.070
228.716
229.357
229.995
230.632
231.268
227.053
227.713
228.353
228.973
229.576
230.162
230.731
231.285
231.825
232.352
232.865
233.366
233.856
234.334
234.801
235.259
235.707
236.145
236.575
236.997
238.017
238.994
239.935
240.846
241.732
242.601
243.459
244.314
245.173
240.042
246.931
247.844
248.791
249.776
250.804
251.882
253.012
254.197
255.437
256.733
128.873
133.031
137.188
141.345
145.502
149.660
153.817
157.974
162.132
166.290
170.448
174.606
178.766
182.926
187.087
191.249
195.413
199.58Q
203.750
207.924
218.380
228.887
239.469
250.164
261.020
272.098
283.471
295.225
307.462
320.292
333.839
348.233
363.610
380.107
397.858
416.989
437.613
459.828
483.706
509.298
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000*
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
794
о
1
'&
On
r-j
"л
О
Дж-К
V
**,
V
О 00
00 ON
ON V?>
О ON
я +
II
149

Класс точ
I-A
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
мости
20.786
20.786
20.786
20.786
20.788
20.794
20.811
20.843
20.895
20.968
21.061
21.170
21.291
21.421
21.554
21.688
21.819
21.944
22.062
22.171
22.271
22.361
22.441
22.512
22.573
22.625
22.669
22.705
22.734
22.756
22.771
22.782
22.787
22.788
22.785
22.778
22.768
22.755
22.740
22.723
22.705
22.684
22.662
22.640
22.616
22.591
22.566
22.541
22.515
22.489
22.463
22.436
22.410
22.384
22.358
22.332
22.306
22.280
22.255
ПОЛОЖИТЕЛЬНЫЙ ИОН
А '(/') = р(Кх)'р
Ф°(Л
Дж • К~ 1 • моль" *
154.714
154.843
160.822
165.461
169.250
172.455
175.230
177.679
179.870
181.853
183.665
185.333
186.879
188.320
189.671
190.942
192.143
193.281
194.363
195.395
196.380
197.324
198.230
199.101
199.940
200.748
201.529
202.284
203.015
203.723
204.409
205.076
205.723
206.353
206.966
207.563
208.145
208.712
209.265
209.806
210.333
210.849
211.354
211.847
212.330
212.803
213.266
213.720
214.164
214.600
215.028
215.448
215.861
216.265
216.663
217.054
217.438
217.815
218.186
175.500
175.629
181.608
186.247
190.036
193.241
196.019
198.472
200.670
202.665
204.493
206.184
207.757
209.230
210.617
211.928
213.171
214.354
215.483
216.562
217.595
218.587
219.541
220.458
221.342
222.195
223.019
223.815
224,585
225.331
226.054
226.755
227.435
228.096
228.738
229.362
229.969
230.560
231.136
231.698
232.245
232.779
233.300
233.809
234.307
234.793
235.268
235.733
236.188
236.634
237.070
237.498
237.917
238.328
238.731
239.127
239.515
239.896
240.270
Д
//V>-//°<(
кДж • моль
6.197
6.236
8.314
10.393
12.472
14.551
16.631
18.713
20.800
22.893
24.994
27.106
29.229
31.364
33.513
35.675
37.851
40.039
42.239
44.451
46.673
48.905
51.145
53.393
55.647
57.907
60.172
62.441
64.713
66.987
69.264
71.541
73.820
76.099
78.377
80.655
82.933
85.209
87.484
89.757
92.028
94.298
96.565
98.830
101.093
103.353
105.611
107.867
110.119
112.370
114.617
116.862
119.104
121.344
123.581
125.816
128.047
130.277
132.503
КРИПТОНА Кг+ (г)
г//°@) = ~
))
о
236.0374
234.5715
175.4630
139.9431
116.2267
99.2604
86.5163
76.5890
68.6351
62.1174
56.6776
52.0677
48.1103
44.6752
41.6649
39.0045
36.6361
34.5136
32.6004
30.8666
29.2879
27.8442
26.5187
25.2973
24.1681
23.1208
22.1467
21.2384
20.3892
19.5936
18.8465
18.1435
17.4809
16.8551
16.2631
15.7022
15.1700
14.6643
14.183)
13.7247
13.2874
12.8698
12.4705
12.0884
11.7223
11.3713
11.0343
10.7107
10.3994
10.1000
9.8116
9.5336
9.2656
9.0069
8.7570
8.5156
8.2821
8.0562
7,8375
1350.757 кДж*моль"
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200,
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Г а б л и
•1
1
1 5
* Z
ЕЗ «о
a s В
5 ? ~
ОО ГО Q
а ~ wo
о + -
^ °
на 95
•ч
о
?
1
Т
к
о
II
п
О о?
со
<1
+
3 ?
я ?
о
1 7*
!
чо %,
о
о *°
• чо
о ^
с н
—¦ т*
«о Ц^
t^ .
+ х
чЗ" 1/-,
о j:
li
JL
С***
ь
о
ЧО
V
V
о
о
•о
1
о
II
150

т
к
6200
6400
6600
6800
7000
7200
7400
Г600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
liOOO
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Г)
22.206
22.157
22.111
22.066
22.022
21.980
21.940
21.901
21.864
21.828
21.794
21.761
21.730
21.699
21.671
21.643
21.616
21.591
21.567
21.543
21.490
21.442
21.400
21.363
21.333
21.308
21.291
21.281
21.280
21.289
21.309
21.342
21.389
21.452
21.533
21.632
21.753
21.895
22.060
22.250
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°G)
Дж К • моль"
218.910
219.612
220.292
220.951
221.591
222.214
222.819
223.408
223.981
224.540
225.085
225.617
226.136
226.642
227.138
227.622
228.095
228.559
229.013
229.457
230.529
231.551
232.526
233.458
234.352
235.210
236.034
236.828
237.593
238.332
239.046
239.736
240.406
241.055
241.684
242.296
242.891
243.471
244.035
244.585
-1
240.999
241.703
242.384
243.044
243.683
244.302
244.904
245.489
246.057
246.610
247.149
247.674
248.185
248.684
249.172
249.648
250.113
250.568
251.013
251.448
252.498
253.496
254.449
255.359
256.230
257.066
257.870
258.644
259.391
260.112
260.811
261.488
262.145
262.785
263.407
264.016
264.610
265.192
265.762
266.323
КРИПТОНА Кг+ (г)
Н°{Т)~Н°@)
кДж • моль
136.950 7.4204
141.386 7.0281
145.813 6.6585
150.230 6.3097
154.639 5.9798
159.039 5.6673
163.431 5.3708'
167.815 5.0892
172.192 4.8212
176.561 4.5658
180.923 4.3223
185.278 4.0896
189.628 3.8672
193.970 3.6543
198.307 3.4502
202.639 3.2545
206.964 ,3.0666
211.285 2.8860
215.601 2.7123
219.912 2.5451
230.670 2.1532
241.403 1.7944
252.113 1.4647
262.803 1.1604
273.477 .8787
284.137 .6171
294.786 .3734
305.428 .1457
316.068 -.0674
326.710 -.2673
337.359 -.4552
348.021 -.6321
358.703 -.7989
369.412 -.9563
380.158 -1.1052
390.948 -1.2459
401.793 -1.3792
412.704 -1.5055
423.692 -1.6251
434.768 -1.7482
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 95
(окончание)
i
я **
VO О
о 2
+ ~ Я
с* 1 о
'* ^ 2
й * §
§ * V
3 я v
° -1 о
о о
у + О
^ 1Л ^
со ^ Z!
СО "^ О/
Р! со
Я '
g
151

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;,г)
36.811
48.269
54.198
54.275
57.301
58.946
59.917
60.531
60.942
61.230
61.439
61.595
61.715
61.808
61.883
61.944
61.993
62.035
62.069
62.099
62.124
62.145
62.1G4
62.181
62.195
62.208
62.219
62.229
fi9 93ft
62.246
62.254
62.260
62.266
62.272
62.277
62.281
62.285
62.289
62.293
62.296
62.299
62.302
62.305
62.307
62.309
62.312
62.314
62.315
62.317
62.319
62.320
62.322
62.323
62.325
62.326
62.327
62.328
62.329
62.330
62.331
62.332
i
К°(Т) = р(Кт)-р
Ф°(Т)
Дж • К • моль
172.465
195.936
211.700
211.960
224.540
234.974
243.904
251.715
258.657
264.905
270.585
275.792
280.598
285.061
289.226
293.131
296.806
300.276
303.564
306.688
309.662
312.501
315.217
317.820
320.318
322.720
325.033
327.263
OOQ 41 Р.
331.498
333.512
335.464
337.356
339.192
340.976
342.710
344.398
346.041
347.641
349.202
350.725
352.211
353.663
355.081
356.469
357.826
359.154
360.454
361.728
362.976
364.200
365.400
366.578
367.734
368.869
369.983
371.078
372.154
373.212
374.252
375.275
ЦИФТОРИД
2(F)-p~4KrF
S°{T)
203.695
233.083
253.596
253.931
270.007
282.987
293.827
303.113
311.224
318.420
324.882
330.746
336.110
341.054
345.637
349.909
353.908
357.668
361.215
364.572
367.757
370.789
373.680
376.444
379.091
381.630
384.070
386.418
OQQ СОП
OOC/tVViV
390.866
392.976
395.017
396.994
398.910
400.769
402.575
404.329
406.036
407.697
409.315
410.892
412.431
413.932
415.398
416.831
418.231
419.601
420.941
422.253
423.538
424.797
426.031
427.241
428.428
429.593
430.737
431.860
432.963
434.047
435.113
436.160
КРИПТОНА
H°(T)~H°((
кДж • моль
3.123
7.429
12.491
12.591
18.187
24.007
29.954
35.978
42,053
48.163
54.297
60.449
66.634
72.791
78.975
85.167
91.364
97.565
103.770
109.979
116.190
122.404
128.619
134.836
141.055
147.275
153.497
159.719
1 fi1^ QA9
172.167
178.392
184.617
190.844
197.070
203.298
209.526
215.754
221.983
228.212
234.441
240.671
246.901
253.132
259.362
265.593
271.824
278.055
284.287
290.518
296.750
302,982
309.214
315.446
321.679
327.911
334.144
340.377
346.610
352.842
359.076
365.309
KrF2 (r)
rH°@) = 91.819
))
•l
-38.8178
-13.7836
-5.3760
-5.2695
-.9572
1.6528
3.4036
4.6600
5.6056
6.3431
6.9344
7.4191
7.8237
8.1665
8.4606
8.7158
8.9393
9.1366
9.3121
9.4693
9.6108
9.7389
9.8554
9.9618
10.0594
10.1492
10.2321
10.3090
If) 3ftf№
10.4467
10.5088
10.5668
10.6212
10.6724
10.7205
i 0.7659
10.80S8
10.8493
10.8878
10.9242
10.9589
10.9919
11.0233
11.0532
11.0818
11.1091
11.1352
11.1603
11.1842
11.2072
11.2293
11.2506
11.2710
11,2906
11.3095
11.3277
11.3453
i 1.3623
11.3787
11.3945
11.4093
кДж'моль"
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
19Q0
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
ON
C-
On
ON
II
+
CN
VO
l>
00
+
ON
ON
c-
s
q
о
1
s
о
VO
VO
+
i—t
О
CO
8
II
g
о
Табли
A
О
1
т-Ч
ГО
VO
II
О
С
с*
и*
й
о
<г
1
А
О
•
ъ
ON
С4!
О
+
V
vo
о
1
X
7648,
о
+
1
о
о
гч
о
NO
1Г
я
00
On
Й
0
<\
ца 96
т
А
I
п
СО
ON
СО
CN
II
, о g
я
VO
V
V
о
о
«о
.'
1
о
II
152

Класс точности
I
КСЕНОН Хе (г)
Таблица 97
Ф°G)
S°(T)
Дж • К • моль
Н°(Т)-Н°@)
кДж • моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
20001
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20786
20786
20.786
20.786
20.786
20.786
20.786
20786
20.786
20.786
20.786
20.786
20786
20.786
20.786
20786
20786
20.786
20.786
20786
20.786
20.786
20.786
20786
20786
20.786
20786
20.786
20786
20.786
20786
20786
20786
20786
20.786
20.786
20786
20.786
20786
20786
20786
20786
20786
20.786
20786
20786
20.786
20.786
20786
20786
20.786
20786
20786
20786
20.786
20.786
20.786
20786
20786
20797
126.081
140.489
148788
148.917
154.897
159.535
163.325
166.529
169.304
171.753
173.943
175.924
177732
179.396
180.936
182.371
183712
184.972
186.160
187.284
188.350
189.364
190.332
191.256
192.140
192.989
193.9*04
194.588
195.344
196.074
196.778
197.460
198.120
198760
199.380
199.983
200.568
201.138
201.692
202.232
202758
203.271
203.772
204.261
204739
205.206
205.663
206:110
206.543
206.976
207.396
207.808
208.212
203.603
208.996
209.378
209.752
210.120
210.481
210.837
211.186
146.867
161.275
169.573
169703
175.683
180.321
184.111
187.315
190.090
192.539
194.729
196.710
198.518
200.182
201.723
203.157
204.498
205758
206.946
208.070
209.136
210.151
211.118
212.041
212.926
213.775
214.590
215.374
216.130
216.860
217.564
218.246
218.906
219.546
220.166
220769
221.354
221.924
222.478
223.018
223.544
224.057
224.558
225.048
225.525
225.992
226.449
226.896
227.334
227763
228.182
228.594
228.998
229.394
229782
230.164
230.538
230.906
231.268
231.623
231.972
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101.852
103.930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.63$
124.716
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
со
со
II
О
II
О
II
S
п
п
о я
со
3
g
о
о
?
i I
I
о
V©
V
V
о
о
я 3
II
153

КСЕНОН Хе (г)
Таблица 97
(окончание)
С°р{Т)
Ф°G)
S°(T)
Дж К" - моль
кДж * моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.787
20.788
20.789
20.792
20.795
20.800
20.806
20.816
20.829
20.847
20.870
20.901
20.941
20.991
21.055
21.134
21.230
21.348
21.489
21.658
22.222
23.038
24.168
25.675
27.616
30.039
32.976
36.435
40.401
44.826
49.630
54.704
59.912
65.097
70.096
74.746
78.899
82.432
85.255
87.314
211.868
212.528
213.167
213.788
214.390
214.976
215.545
216.100
216.640
217.166
217.680
218.181
218.670
219.148
219.616
220.073
220.521
220.959
221.389
221.810
222.828
223.803
224.738
225.639
226.511
227.358
228.185
228.997
229.798
230.592
231.383
232.174
232.970
233.772
234.582
235.404
236.237
237,082
237.939
238.808
232.654
233.314
233.953
234.574
235.177
235.763
236.333
236.888
237.429
237.956
238.471
238.974
239.467
239.949
240.421
240.885
241.340
241.788
242.230
242.666
243.735
244.787
245.834
246.893
247.979
249.108
250.295
251.555
252.902
254.345
255.892
257.547
259.310
261.176
263.136
265.176
267.282
269.435
271.614
273.800
128.874
133.031
137.189
141.347
145.506
149.665
153.826
157.988
162.152
166.320
170.491
174.668
178.852
183.045
187.250
191.468
195.704
199.962
204.245
208.559
219.520
230.823
242.611
255.054
268.358
282.750
298.482
315.813
335.002
356.291
379.892
405.966
434.618
465.875
499.684
535.912
574.347
614.708
656.661
699.836
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
VO
О
I
о
о
о
V
V
о
о
о
II
р
154

Класс точности
I-A
ПОЛОЖИТЕЛЬНЫЙ ИОН КСЕНОНА Хе+ (г)
Таблица 98
= -1170.355 кДж-моль""
Ф°(Т)
Дж К - моль""!
кДж • моль

298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.788
20.791
20.796
20.803
20.815
20.830
20.851
20.877
20.908
20.945
20.986
21.033
21.085
21.140
21.200
21.262
21.326
21.392
21.460
21.528
21.596
21,664
21.732
21.798
21.863
21.927
21.988
22.048
22.105
22.160
22.213
22.263
22.311
22.356
22.398
22.438
22.476
22.510
22.543
22.573
22.601
22.626
22.649
22.671
22.690
22.707
22.722
22.736
22.747
160.314
160.443
166.423
171.061
174.851
178.055
180.831
183.279
185.469
187.450
189.259
190.922
192.463
193.897
195.239
196.499
197.688
198.812
199.879
200.894
201.862
202.787
203.674
204.524
205.342
206.130
206.889
207.622
208.331
209.017
209.682
210.328
210.954
211.563
212.156
212.733
213.295
213.843
214.378
214.900
215.410
215.909
216.397
216.874
217.342
217.800
218.249
218.689
219.121
219.544
219.960
220.368
220.769
221.164
221.551
221.932
222.307
222.675
223.038
181.100
181.229
187.209
191.847
195.637
198.841
201.616
204.065
206.255
208.236
210.045
211.709
213.250
214.685
216.028
217.290
218.481
219.609
220.681
221.702
222.677
223.611
224.507
225.369
226.199
227.001
227.775
228.524
229.251
229.956
230.640
231.306
231.953
232.584
233.199
233.799
234.385
234.957
235.516
236.062
236.597
237.120
237.632
238.134
238.626
239.108
239.581
240.045
240.500
240.947
241.385
241.816
242.239
242.655
243.064
243.465
243.860
244.249
244.631
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.102
31.182
33.262
35.345
37.429
39.515
41.604
43.697
45.793
47.894
50.000
52.111
54.228
56.351
58.481
60.617
62.759
64.909
67.065
69.228
71.398
73.574
75.757
77.947
80.142
82.344
84.552
86.765
88.984
91.208
93.436
95.670
97.907
100.149
102.395
104.644
106.897
109.153
111.411
113.673
115.937
118.203
120.471
122.741
125.012
127.285
129.559
204.4323
203.1611
151.9053
121.0969
100.5215
85.7988
74.7374
66.1189
59.2121
53.5511
48.8254
44.8197
41.3804
38.3944
35.7771
33.4638
31.4039
29.5577
27.8932
26.3847
25.0109
23.7544
22.6006
21.5373
20.5541
19.6422
18.7939
18.0027
17.2630
16.5698
15.9188
15.3062
14.7287
14.1831
13.6670
13.1779
12.7138
12.2726
11.8528
11.4528
11.0711
10.7066
10.3580
10.0243
9.7045
9.3979
9.1034
8.8205
8.5485
8.2866
8.0344
7.7912
7.5567
7.3303
7.1115 ,
6.9001
6.6956
6.4977
6.3061
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1«ЙГ
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
so
го
II
5 Я
е
и
о
00
ON
3
о5
s
о
о
1
ё
661
т—1
го
.204
го
см
II
On
1
ъ
00
00*
д
>.801
1
S
V
V
о
о
«о
т-Ч
II
155

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
•8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
ПОЛОЖИТЕЛЬНЫЙ ИОН
Ф°G)
Дж К • моль
22.766
22.778
22.786
22.788
22.786
22.780
22.771
22.759
22.745
22.728
22.710
22.690
22.669
22.647
22.624
22.601
22.578
22.555
22.532
22.510
22.459
22.417
22.388
22.378
22.391
22.431
22.504
22.616
22.770
22.972
23.226
23.536
23.905
24.336
24.830
25.387
26.008
26.692
27.436
28.238
223.747
224.434
225.101
225.750
226.380
226.993
227.591
228.173
228.741
229.295
229.835
230.363
230.880
231.384
231.878
232.361
232.834
233.297
233.752
234.196
235.272
236.299
237.280
238.220
239.123
239.990
240.825
241.631
242.408
243.160
243,888
244.594
245.280
245.946
246.595
247.228
247.845
248.449
249.039
249.618
245.377
246.100
246.801
247.482
248.142
248.784
249.408
250.015
250.606
251.182
251.743
252.290
252.824
253.344
253.853
254.350
254.836
255.311
255.776
256.231
257.328
258.372
259.367
260.320
261.234
262.112
262.960
263.781
264.577
265.352
266.109
266.852
267.581
268.301
269.013
269.721
270.424
271.127
271.830
272.534
КСЕНОНА Хе+ (г)
Н°(Т)-Н°@)
кДж • моль""
м-о,
134.110 5.9404
138.665 5.5964
143.221 5.2721
147.779 4.9658
152.336 4.6760
156.893 4.4014
161.448 4.1407
166.001 3.8929
170.552 3.6570
175.099 3.4321
179.643 3.2175
184.183 3.0124
188.719 2.8162
193.250 2.6283
197.778 2.4482
202.300 2.2753
206.818 2.1093
211.331 1.9496
215.840 1.7960
220.344 1.6481
231.586 1.3010
242.804 .9831
254.005 .6908
265.195 .4211
276.386 .1714
287.591 -.0604
298.823 -.2759
310.101 -.4768
321.446 -.6642
332.879. -.8394
344.427
356.115
367.973
380.031
392.320
404.871
417.717
430.890
444.419
1.0032
1.1564
1.2999
.4342
(.5600
1:6777
1.7880
1.8913
1.9880
458.335 -2.0884
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
J1500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 98
(окончание)
+
00
ЯР -ч /~ч
'« § О
R ? §
о 7 ч/
f * g
1 Ъ §
S о io
+ <N ||
•""* СО X
S <*> ^
00
и J2
С о>
о +
ф
156

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
38.443
51.801
61.498
61.649
68.275
72.522
75.278
77.127
78.411
79.334
80.015
80.532
80.932
81.248
81.501
81.707
81.877
82.019
82.138
82.239
82.326
82.401
82.466
82.523
82.574
82.618
82.657
82.692
82.724
82.752
82.778
82.801
82.822
82.841
82.858
82.874
82.889
82.903
82.915
82.927
82.937
82.947
82.956
82.965
82.973
82.981
82.988
82.994
83.000
83.006
83.012
83.017
83.022
83.026
83.030
83.035
83.038
83.042
83.046
83.049
83.052
ТРИОКСИД
А'°(П = р(ХеO
Ф°(Г)
Дж • К~! • моль"
199.949
225.364
242.355
242.636
256.446
268.161
278.396
287.505
295.717
303.195
310.060
316.406
322.305
327.815
332.985
337.855
342.456
346.817
350.962
354.911
358.681
362.288
365.746
369.066
372.260
375.335
378.301
381.165
383.933
386.613
389.209
391.727
394.171
396.545
398.853
401.100
403.287
405.418
407.496
409.523
411.502
413.436
415.325
41Л172
418.979
420.748
422.480
424.177
425.840
427.470
429.068
430.637
432.177
433.689
435.173
436.632
438.066
439.475
440.861
442.224
443.565
?3(О)^(Хе(
S°{T)
234.304
265.251
287.850
288.231
306.943
322.669
336.152
347.904
358.292
367.584
375.979
383.631
390.656
397.147
403.178
408.808
414.087
419.055
423.747
428.190
432.411
436.429
440.264
443.931
447.444
450.816
454.057
457.178
460.185
463.089
465.895
468.609
471.238
473.787
476.261
478.663
480.998
483.269
485.480
487.634
489.734
491.782
493.780
495.733
497.640
499.505
501.329
503.113
504.861
506.572
508.249
509.893
511.505
513.087
514.639
516.162
517.659
519.128
520.572
521.992
523.388
КСЕНОНА ХеО:
Н°(Т)-7Н°(())
кДж * моль
3.435
7.978
13.564
13.678
20.199
27.254
34.654
42.280
50.060
57.950
65.919
73.948
82.022
90.131
98.269
106.430
114.609
122.804
131.012
139.231
147.460
155.696
163.940
172.189
180.444
188.704
196.968
205.235
213.506
221.780
230.056
238.335
246.616
254.899
263.184
271.471
279.759
288.048
296.340
304.632
312.925
321.219
3129.514
337.810
346.107
354.405
362.703
371.002
379.302
387.602
395.903
404.205
412.507
420.809
429.112
437.415
445.719
454.023
462.327
470.632
478.937
, (г)
э@) = 207.693
-94.5172
-38.4073
-19.5876
•19.3494
-9.7060
-3.8738
.0359
2.8399
4.9493
6.5938
7.9120
8.9922
9.8935
10.6570
11.3120
11.8802
12.3777
12.8169
13.2076
13.5573
13.8721
14.1571
14.4163
14.6531
14.8702
15.0699
15.2544
15.4253
15.5840
15.7318
15.8698
15.9989
16/1200
16.2339
16.3410
16.4421
16.5377
16.6281
16.7138
16.7952
16.8725
16.9462
17.0163
17.0833
17.1473
17.2085
17.2672
17.3233
17.3772
17.4290
17.4788
17.5266
17.5728
17.6172
17.6600
17.7014
17.7413
17.7799
17.8173
17.8534
17.8884
кДж'моль"*1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200.
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
OS
с*
On
Г-
ч—1
II
+
с-.
ОС
¦н
00
w
VO
CN
о
о
1
g
оо
+
1
<Ч
О
00
rt
II
ь
Табл
|
к
Ч
СЧ
СО
«О
11
о*
С
%
о
* <
ХА
Sa
к
О
+
С4
«о
00
Tf
1
со
о
5—1
1О
+
и
1
•
о
о
С)
f-
CNl
»О
II
X,
«О
оо
о
С4)
о
й
<f
ца 99
¦
§
т
?
О
00
II
о о S
п О 0{
со
-»
2
ЧО
V
ч/
500 <
i
о
9
II
X
w
157

Класс точности
VI Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ТЕТРОКСИД КСЕНОНА ХеО4
К^Г)= /НХе)'
Ф°(Л
Дж • К • моль
44.857 194.033
65.286 222 054
78.166 242.090
78.367 242.429
87.260 259.190
93.078 273.627
96.909 286.365
99.503 297.777
101.318 308.117
102.627 317.569
103.597 326.273
104.335 334.337
104.907 341.848
105.359 348.878
105.722 355.482
106.018 361.710
106.262 367.601
106.466 373.190
106.637 378.506
1С6.783 383.574
106.908 388.417
107.016 393.053
107.110 397.500
107.192 401.771
107.264 405.881
107.328 409.841
107.385 413.661
107.435 417.352
107.481 420.921
107.522 424.376
107.558 427.724
107.S92 430.973
107.622 434.126
107.650 437.191
107.675 440.171
107.698 443.071
107.719 445.896
107.739 448.649
107.757 451.333
107.773 453.953
107.789 456.511
107.803 459.009
107.816 461.452
107.829 463.840
107.840 466.177
107.851 468.464
107.861 470.705
107.871 472.900
107.880 475.050
107.888 477.160
107.896 479.228
107.903 481.258
107.910 483.251
107.917 485.208
107.923 487.130
107.929 489.018
107.935 490.874
107.940 492.698
107.945 494.493
107.950 496.258
107.954 497.995
/;4(О)\//(ХеО4) д^я
S' (Т)
-1
230.057
268.087
296.706
297.190
321.041
341.183
358.516
373.661
387.073
399.087
409.952
419.862
428.966
437.381
445.203
452.508
459.358
465.806
471.897
477.666
483.147
488.366
493.346
498.109
502.673
507.053
511.264
515.317
519.225
522.998
526.644
530.171
533.587
536.899
540.113
543.235
546.269
549.221
552.094
554.893
557.622
560.284
562.882
565.419.
567.898
570.322
572.692
575.012
577.283
579.508
581.688
583.824
585.920
587.975
589.992
591.973
593.918
595.828
597.705
599.551
601.365
H'\T)-Hr\Q)
кДж - моль
3.602
9.207
16.284
16.428
24.740
33.778
43.290
53.119
63.165
73.366
83.679
94.077
104.541
115.055
125.609
136.197
146.811
157.448
168.103
178.775
189.459
200.156
210.862
221.577
232.300
243.030
253.766
264.507
275.252
286.003
296.756
307.514
318.275
329.039
339.805
350.573
361.344
372.117
382.892
393.668
404.446
415.226
426.007
436.789
447.573
458.357
469.143
479.930
490.717
501.506
512.295
523.085
533.875
544.667
555.459
566.251
577.045
587.838
598.633
609.427
620.223
(г)
V()) - 337.854 кДж'моль
Г
К
-156.2539 100
-65.4722 200
-35.1485 298.15
-34.7653 300
-19.2730 400
-9.9245 500
-3.0691 600
.8097 700
4.1740 800
6.7933 900
8.8898 1000
10.6056 1100
12.0355 1200
13.2451 1300
14.2817 1400
15.1796 1500
15.9649 1600
16.6575 1700
17.2726 1800
17.8226 1900
18.3173 2000
18.7645 2100
19.1707 2200
19.5413 2300
19.8807 2400
20.1927 2500
20.4804 2600
20.7466 2700
20.9936 2800
21.2233 2900
21.4375 3000
21.6377 3100
21.8253 3200
22.0014 3300
22.1669 3400
22.3229 3500
22.4701 3600
22.6093 3700
22.7411 3800
22.8660 3900
22.984Ь 4000
23.0974 4100
23.2047 4200
23.3070 4300
23.4047 4400
23.4979 4500
23.5871 4600
23.6725 4700
23.7543 4800
23*.8327 4900
23.9081 5000
23.9804 5100
24.0500 5200
24.1170 5300
24.1815 5400
24.2437 5500
24.3036 5600
24.3615 5700
24.4174 5800
24.4715 5900
24.5237 6000
s
! Таблица 100
L
-1
i
с
— 2
•° *
с; Д -
2 *¦ ?
* § 1
=( о .
§ s s V
г ^» " &
Ю о< ^ Д
ON 5- V ^
- 3 * ^
И и ? 1о
—- . Г--
* ° % «
V с "
1 О' 0?
\ .
+
t
On
-* т
^ -a
" 1
+
V T
on * о
til ^^
? m *
О H \/
| ГЧ **"
v ъ V
? + о
s s
8 - о
I ? *¦
^t —¦ II
[ Wi ЧО Ц
rf ОС w
*¦ +
II ,
ь
о
158

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
' 1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛйЛЛ
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ДИФТОРИД КСЕНОНА XeF2
A'V) = /?(XeO?2(F)'//(XeF2
ф°(Т)
— 1
Дж К • моль
37.559 177.646
48.265 201.414
54.108 217.292
54.185 217.552
57.228 230.183
58.892 240.643
59.877 249.589
60.501 257.411
60.918 264.360
61.211 270.613
61.423 276.297
61.582 281.507
61.704 286.316
61.799 290.780
61.875 294.947
61.936 298.853
61.987 302.530
62.029 306.001
62.064 309.290
62.094 312.414
62.120 315.390
62.142 318.229
62.161 320.945
62.177 323.548
62.192 326.047
62.205 328.450
62.217 330.763
62.227 332.994
АО 94ft Q4*\ 1 At
OZ.ZOO 000.14/
62.244 337.229
62.252 339.244
62.258 341.195
62.265 343.088
62.270 344.924
62.275 346.708
62.280 348.443
62.284 350.130
62.288 . 351.774
62.292 353.374
62.295 354.935
62.298 356.458
62.301 357.944
62.304 359.396
62.306 360.815
62.309 362.203
62.311 363.560
62.313 364.888
62.315 366.188
62.316 367.462
62.318 368.711
62.320 369.935
62.321 371.135
62.323 372.313
62.324 373.469
62.325 374.604
62.326 375.718
62.327 376.813
62.329 377.889
62.330 378.947
62.331 379.988
62.331 381.011
S°iT)
-1
209.295
238.9 i 6
259.403
259.738
275.789
288.755
299.587
308.867
316.975
324.168
330.629
336.491
341.854
346.797
351.380
355.651
359.650
363.409
366.956
370.312
373.498
376.529
379.421
382.184
384.831
3&7.370
389.810
392.158
OQA ±0\
О9т.4? I
396.605
398.716
400.757
402.734
404.650
406.509
408.314
410.068
411.775
413.436
415.054
416.632
418.170
419.671
421.137
422.570
423.970
425.340
426.680
427.992
429.276
430.536
431.770
432.980
434.167
435.332
436.476
437.599
438.702
439.786
440.851
441.899
) v#
//°(Л-//°@)
кДж • моль
3.165
7.500
12.555
12.656
18.242
24.056
29.999
36,020
42.092
48.199
54.331
60.482
66.647
72.822
79.006
85.196
91.393
97.593
103.798
110.006
116.217
122.430
128.645
134.862
141.081
147.300
153.521
159.744
1 ft(\ QA7
ЮО.УО/
172.191
178.416
184.641
190.867
197.094
203.321
209.549
215.7.77
222.006
228.235
234.464
240.694
246.924
253.154
259.384
265.615
271.846
278.077
284.309
290.540
296.772
303.004
309.236
315.468
321.700
327.933
334.165
340.398
346.631
352.864
359.097
365.330
(г)
Таблица 101
'@) = 259.133 кДж'моль"*1
-126.1906
-57.4746
-34.6878
-34.4007
-22.8081
-15.8298
-11.1666
-7.8300
-5.3241
-3.3731
-1.8109
-.5318
.5347
1.4376
2.2118
2.8831
3.4707
3.9892
4.4503
4.8630
5.2344
5.5706
5.8762
6.1553
6.4112
6?6467
6.8640
7.0653
7 ОЧОО
7.4263
7.5888
7.7408
7.8833
8.0171
8.1432
8.2620
8.3742
8.4804
8.5810
8.6764
8.7671
8.8533
8.9355
9.0138
9.0886
9.1600
9.2284
9.2938
9.3565
9.4167
9.4744
9.5299
9.5833
9.6346
9.6841
9.7317
9.7777
9.8220
9.8648
9.9062
9.9462
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАА
ZO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
|
i ? т
• 5
S о S
П g 7
* - Т
? S 2 *
а. 2 ; *
s <= 1 ч
"¦ : « m
"II "Л S
5 о 2 *
On ™
II
ГЧ С
U* * Ч
4) Г4 О №
° Й
<1
+
г- ,«,
1О |
о л
f— с;
00 О
о 2
+ _*
1 х §
Я * °
о тн V
§ в ь
СП
1 о V
2 + S
12 S ¦ Т
«N <=> 2
VD | а
+ х ^
00 О
С- ,-• I'
СЧ On ,,
ОГ- *>
»-4 о
5 +
g
ъ
159

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
35Q0
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
54.878
77.509
89.956
90.123
96.732
100.385
102.561
103.944
104.873
105.524
105.997
106.352
106.623
106.836
107.006
107.144
107.257
107.351
107.429
107.496
107.554
107.603
107.646
107.683
107.716
107.745
107.771
107.793-
107.814
107.832
107.849
107.864
107.878
107.890
107.902
107.912
107.922
107.931
107.939
107.946
107.953
107.960
107.966
107.971
107.976
107.981
107.986
107.990
107.994
107.998
108.001
108.005
108.008
108.011
108.014
108.016
108.019
108.021
108.023
108.026
108.028
А'°G') = р(Хе)^
Ф°(Л
Дж • К • моль
204.302
236.617
260.088
260.484
279.985
296.552
310.957
323.698
335.115
345.455
354.901
363.594
371.646
379.143
386.157
392.745
398.957
404.832
410.406
415.707
420.761
425.590
430.213
434.647
438.906
443.004
446.954
450.763
454.444
458.003
461.449
464.788
468.028
471.174
474.230
477.203
480.096
4&2.914
485.661
488.339
490.952
493.504
495.997
498.435
500.818
503.150
. 505.432
507.668
509.858
512.004
514.109
516.174
518.200
520.189
522.142
524.060
525.945
527.797
529.619
531.410
533.172
ТЕТРАФТОРИД КСЕНОНА XeF4 (г)
>4(FOf1(XeF4
S°(T)
-!
244.791
290.452
323.981
324.538
351.468
373,484
391.994
407.915
421.860
434.252
445.395
455.515
464.781
473.324
481.248
488.636
495.554
502.060
508.198
514.008
519.524
, 524.772
529.779
534.565
539.149
543.546
547.773
551.840
555.761
559.545
563.201
566.737
570.162
573.482
576.703
579.831
582.871
585.828
588.706
591.510
594.243
596.909
599.511
602.051
604.534
606.960
609.333
611.656
613.929
616.156
618.338
620.477
622.574
624.632
626.651
628.632
630.579
632.491
634.370
636.216
638.032
) ArH
Н°{Т)~Н°(())
кДж • моль
4.049
10.767
19.050
19.216
28.593
38.466
48.622
58.952
69.396
79.917
90.495
101.113
111.762
122.436
133.128
143.836
154.556
165.286
176.025
186.772
197.524
208.282
219.045
229.811
240.581
251.354
262.130
272.908
283.689
294.471
305.255
316.041
326.828
337.616
348.406
359.196
369.988
380.781
391.574
402.369
413.164
423.959
434.756
445.552
456.350
467.148
477.946
488.745
499.544
510.344
521.144
531.944
542.744
553.545
564.347
575.148
585.950
596.752
607.554
618.357
629.159
'@) - 510.492
-247.0195
-111.5753
-66.6709
-66.1051
-43.2699
-29.5311
-20.3560
-13.7952
-8.8713
-5.0403
-1.9751
.5328
2.6224
4.3900
5.9047
7.2169
8.3646
9.3768
10.2761
11.0803
11.8037
12.4578
13.0520
13.5943
14.0910
14.5478
14.9691
15.3589
15.7207
16.0572
16.3711
16.6646
16.9395
17.1976
'17.4403
17.6690
17.8848
18.0888
18.2820
18.4650
18.6389
18.8040
18.9613
19.1111
19.2539
19.3904
19.5208
1-9.6455
19.7650
19.8795
19.9893
20.0947
20.1960
20.2934
20.3872
20.4774
20.5644
20.6482
20.7291
20.8072
20.8826
кДж'моль
Т
К
100
200
298 Л 5
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-1
<^
Г-
О
еч
м
+
!
С*
со
+
d
1
н
00
Tt
S
О
О
1
1
Й
со
VO
Os
io
с^
о
+
Os
(*"¦
<Ч
TJ-'
Ю
II
g
0
I а б
5
»
Os
со
О
<ч
I
II
о
U
0)
'6
О
<г
§
1
к
R.
со
X
Os
<ч
о
+
г»
I
н
со
g
О
О)
«¦и
+
Л И
s
Os
VD
О
<ч
1
II
?
in
со
On
сч
к
0
<»"}
4 1 1 f\~)
и, а 1 \)l
•
X,
А
з-
ос
—'
1
п
и О К
h со*
2
о
О
о
V
г*.
V
о
о
rf
1
э
II
-
160

Класс точности
VII-Е
Т
К
100
' 200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
80.815
113.064
131.168
131.412
141.124
W6.522
149.746
151.801
153.182
154.151
154.856
155.384
155.789
156.107
156.360
156.565
156.734
156.874
156.992
157.091
157.177
157.250
157.314
157.370
157.419
157.462
157.501
157.535
157.566
157.593
157.618
157.641
157.661
157.680
157.697
157.712
157.727
157.740
157.752
157.763
157.773
157.783
157.792
157.800
157.808
157.815
157.822
157.829
157.835
157.840
157.845
157.850
157.855
157.860
157.864
157.868
157.871
157.875
157.878
157.882
157.885
К°(Т)= р(Хе) •
Ф°(Т)
Дж • К • моль"
215.608
261.257
295.020
295.591
323.793
347.813
368.733
387.254
403.862
418.912
432.669
445.334
457.066
467.994
478.219
487.826
496.884
505.454
513.584
521.318
528.692
535.738
542.484
548.955
555.171
561.152
566.916
572.477
577.850
583.046
588.077
592.952
597.682
602.275
606.738
611.078
615.303
619.417
623.428
627.339
631.155
634.882
638.523
642.082
645.562
648.968
652.302
655.567
658.765
661.901
664.975
667.991
670.950
673.855
676.707
679.509
682.262
684.968
687.629
690.245
692.819
ГЕКСАФТОЕИД КСЕНОНА
p6(F).^(XeF6) Агм
SO(T)
'1
Н°(Т)-//°(())
кДж • моль
271.526 5.592
338.352 15.419
387.242 . 27.496
388.054 27.739
427.333 41.416
459.458 55.823
486.481 70.649
509.730 85.733
530.096 100.987
548.197 116.356
564.477 131.808
579.262 147.322
592.801 162.881
605.284 178.476
616.862 194.100
627.657 209.747
637.767 225.412
647.273 241.093
656.243 256.786
664.734 272.490
672.794 288.204
680.464 303.925
687.781 319;653
694.776 335.388
701.474 351.127
707.901 366.872
714.078 382.620
720.023 398.372
725.752 414.127
731.282 429.885
736.625 445.645
741.794 461.408
746.799 477.173
751.651 492.940
756.358 508.709
760.930 524.480
765.373 540.252
769.695 556.025
773.901 571.800
777.999 587.575
781.994 603.352
785.889 619.130
789.692 634.909
793.405 650.688
797.033 666.469
800.579 682.250
804.048 698.032
807.442 713.814
810.765 729.597
814.020 745.381
817.208 761.165
820.334 776.950
823.399 792.736
826.406 808.521
829.357 824.308
832.254 840.094
835.098 855.881
837.892 871.668
840.638 887.456
843.337 903.244
845.991 919.032
XeF6 (г)
Таб ли ца 103
ЭШ) = 735.674 кДж-моль
lg АГ°(Г)
-353.3733
-158.2876
-93.6572
-92.8431
-60.0003
-40.2551
-27.0788
-17.6643
-10.6045
-5.1161
-.7283
2.8586
5.8448
8.3688
10.5297
12.4003
14.0349
15.4752
16.7538
17.8962
18.9229
19.8505
20.6925
21.4601
22.1627
22.8081
23.4030
23.9529
24.4627
24.9367
25.3783
25.7908
26.1769
26.5390
26.8792
27.1995
27.5015
27.7867
28.0565
28.3120
28.5543
28,7844
29.0032
29.2114
29.4099
29.5992
29.7800
29.9528
30.1181
30.2764
30.4281
30.5736
30.7133
30.8475
30.9764
31.1005
31.2199
31.3350
31.4458
31.5528
31.6560
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
1 S '
о к
Ч? О
Ч о 2
г** *~1
о я Й а
° s ™ ¦ ¦
II " UO ~ .
^ Ч °° й
о" &
^ о
+
со
о
I Tg
Я . о
§ «w v
го „. ^
14 hue
+ 1.13
500 <
^ О тг
Г- ^ 1
Ю ЧО О
00 X
rf i-« II
СО CN
г^: «о х
II +
г
И &72
161

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
QQAA
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т
ДИОКСИД-ДИФТОРИД КСЕНОНА XeO2F
К°(Т)= р(Хе)-р
)
Ф°(Т)
Дж • К • моль"
45.097 210.821
68.530 239.138
82.428 259.742
82.627 260.092
90.948 277.494
95.998 292.504
99.195 305.722
101.312 317.533
102.77
328.204
103.814 337.935
104.583 346.874
105.164 355.141
105.613 362.827
105.968 370.009
106.251
376.747
106.482 383.093
106.672 389.090*
106.83
394.774
106.964 400.176
107.078 405.322
107.175 410.235
107.258 414.936
107.331
419.441
107.395 423.767
107.45
427.927
107.500 431.933
107.544 435.797
107.582
\ 439.528
1П7А1Й АА1 \1А
lU/.Olo 44а. 1о4
107.650 446.625
107.679 450.006
107.704 453.285
107.728 456.468
107.749 459.560
107.769 462.566
107.786 465.491
107.802
t 468.339
107.818 471.113
107.832 473.819
107.845 476.459
107.857 479.035
107.868 481.552
107.878 484.012
107.888 486.417
107.897
107.90S
г 48И.769
) 491.072
107.913 493.327
107.920 495.535
107.927 487.700
107.933 49/9.822
107.940 501.903
107.945 503.945
107.95
505.949
107.956 507.916
107.961
509.849
107.965 511.747
107.969 513.613
107.974 515.447
107.977 517.251
107.98
519.025
107.985 520.770
2(O)-p2(F)^1
s°m
-l
247.075
286.090
316.284
316.795
341.807
362.688
380.495
395.955
409.584
421.753
432.732
442.728
451.899
460.367
468.231
475.570
482.448
488.920
495.030
500.817
506.312
511.543
516.534
521.307
525.878
530.266
534.483
538.542
К АО A*\f\
546.233
549.883
553.414
556.834
560.149
563.366
566.490
569.527
572.481
575.356
578.157
580.888
583.551
586.151
588.689
591.170
593.594
595.966
598.287
600.559
602.785
604.965
607.103
609.199
611.255
613.273
615.254
617.200
619.111
620.989
622.834
624.649
(XeO2F2) Arn
//°(/')-//°@)
кДж * моль
3.625
9.390
16.858
17.011
25.725
35.092
44.864
54.896
65.104
75.436
85.858
96.347
106.886
117.466
128.078
138.715
149.373
160.048
170.738
181.440
192.153
202.875
213.604
224.341
235.083
245.831
256,583
267.339
ОТО АОО
278.099
288.863
299.629
310.398
321.170
331.944
342.720
353.497
364.277
375.058
385.840
396.624
407.410
418.196
428.983
439.771
450.560
461.351
472.142
482.933
493.725
504.518
515.312
526.106
536.901
547.697
558.492
569.289
580.085
590.883
601.680
612.478
623.276
э@) = 384.000
lgK°(T)
•181.2614
-78.5438
-44.3236
43.8916
-26.4385
•15.9183
•8.8840
-3.8499
-.0698
2.8726
5.2274
7.1543
8.7600
10.1184
11.2824
12.2908
13.1727
13.9505
14.6414
15.2592
15.8148
16.3171
16.7735
17.1898
17.5712
17.9217
18.2451
18.5442
1 Q OO1 Т"
1о.о217
19.0799
19.3207
19.5458
19.7566
19.9545
20.1405
20.3159
20.4813
20.6377
20.7857
20.9261
21.0593
21.1859
21.3064
21.4213
21.5308
21.6354
21.7354
21.8311
21.9228
22.0107
22.0950
22.1759
22.2538
22.3286
22.4006
22.4700
22.5369
22.6014
22.6637
22.7239
22.7820
2(г)
кДж'моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАА
2о00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ЧО
О\
(N
1—1
О
CS
II
т
со
тЧ
+
со
<N
rj-
Tf
т-4
О
1
s
8
+
CO
о
VO
«o
II
с
О
T a б л и
О
тё к
О 5^
Р о
• О
« г-
. *\ f^t
* iO
Ли "
^# я
о" Ь
° о"
& §
1
1
к
со
со
CS
+
г*
со
О)
1
н
00
О
VO
+
ца 104
§
•5
т
со
<N
^ п
о ос
2
о
о
VO
V
V
о
о
I
II
162

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ТРИОКСИД-ДИФТОРИД КСЕНОНА ХеО,
К°(Т)= р(Хе)-р
с;<т)
Ф°(Т)
Дж • К~' • моль"
50.029 206.221
79.141 236.670
97.425 259.694
97.693 260.091
109.055 279.976
116.057 297.382
120.521 312.866
123.488 326.805
125.538 339.469
127.005 351.065
128.087 361.756
128.906 371.669
129.539 380.908
130.038 389.556
130.439 397.684
130.764 405.351
131.033 412.603
131.256 419.485
131.445 426.031
131.605 432.273
131.742 438.237
131.860 443.947
131.963 449.423
132.053 454.684
132.132 459.746
1?2.201 464.623
132.263 469.328
132.319 473.874
• qо OAfi A7& ОАО
I32.00O 4/О.20У
132.413 482.525
132.453 486.649
132.490 490.650
132.523 494.534
132.553 498.308
132.580 501.978
132.606 505.550
132.629 509.029
132.650 512.420
132.670 515.726
132.688 518.952
132.705 522.102
132.720 525.179
132.735 528.187
132.749 531.129
132.761 534.007
132.773 536.824
132.784 539.582
132.794 542.285
132.804 544.934
132.813 547.531
132.822 550.079
132.830 552.579
132.838 555.033
132.845 557.442
132.852 559.809
132.858 562.134
132.864 564.419
132.870 566.666
132.875 568.876
132.881 571.049
132.885 573.188
Ь(О)-р2(?)-р~1
S°(T)
244.144
288.400
323.693
324.296
354.091
379.239
400.822
419.638
436.269
451.145
464.585
476.833
488.078
498.467
508.119
517.130
525.578
533.529
541.036
548.148
554.902
561.332
567.469
573.337
578.959
5В4.354
589.540
594.533
CvQQ 446
603.992
608.482
612.825
617.032
621.111
625.068
628.912
632.648
636.282
639.820
643.266
646.626
649.903
653.101
656.224
659.276
662.260
665.179
668.034
670.830
673.568
676.252
678.882
681.462
683.992
686.475
688.913
691.307
693.659
695.969
698.241
700.474
p /г\ Таблица 105
(XeO3F2) ArH°(Q) ^480.000 кДж'моль
H°{T)-,H°(())
кДж • моль
\gK°(T)
3.792 -225.2232
10.346 -96.7308
19.081 -53.9110
19.262 -53.3704
29.646 -31.5310
40.929 -18.3695
52.773 -9.5721
64.983 -3.2788
77.441 1.4448
90.072 5.1196
102.829 8.0591
115.680 10.4632
128.604 12.4654
141.584 14.1583
154.608 15.6081
167.669 16.8633
180.759 17.9605
193.874 18.9275
207.009 19.7860
220.162 20.5531
233.330 21.2427
246.510 21.865 В
259.701 22.4315
272.902 22.9473
286.111 23.4194
299.328 23.8531
312.551 24.2529
325.780 24.6226
OQQAIC OJ, Qfi?,A
352.254 25.2840
365.497 25.5810
378.744 25.858*
391.995 26.1181
405.249 26.3618
418.505 26.5907
431.765 26.8063
445.027 27.0096
458.290 27.2017
471.556 27.3834
484.824 27.55f>5
498.094 27.71S9
511.365 27.874,0
524.638 28.0216
537.912 28.165 i
551.188 28.29A
564.464 28.42'0
577.742 28.54(i2
591,021 28.662.0
604.301 28.7748
617.582 28.8820
630.864 28.9f>48
644.146 29.0834
657.430 29. \ 781
670.714 29.2692
683.999 2P.3568
697.284 ? 9.4412
710.570 29.5224
723.857 29.6008
737.144 29.6764
750.432 29.7493
763.720 29.8198
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОПА
ZOVJyJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Q Ef
• f
* со g
ON О *
on «• 7
S "* с •
- 5 * 3
II О oo S
^ с Я 3
C4 С ^
U_ II
О ь я
й. 9 «
о Ц.
+
7
й
О
со о
+ 2
<s *
1 1
$ U 2
2 х §
ГЧ1 >—f S
О * S
^ СП V /
Я х V
' : ь.
Н со* V
? + о
О ей
On оО ^
О  »о
СО f- 2
1 * ^
с^ оо
чо +
II
g
о
163

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
57.076
86.844
104.064
104.304
114.134
119.885
123.444
125.766
127.352
128.478
129.304 •
129.926
130.406
130.784
131.086
131.332
131.534
131.702
131.843
131.963
132.066
132.155
132.232
132.299
132.358
132.411
132.457
132.499
132.536
132.569
132.599
132.626
132.651
132.674
132.694
132.713
132.730
132J46
132.761
132.775
132.787
132.799
132.810
132.820
132.829
132.838
132.846
132.85.4
132.861
132.868
132.875
132.881
132.886
132.892
132.897
132.902
132.906
132.911
132.915
132.919
132.922
ОКСИД-ТЕТРАФТОРИД КСЕНОНА XeOF4
А'°(Г) = р(Хе) •
Ф°(Т)
Дж • К • моль
212.839
246.199
271.480
271.913
293.512
312.206
328.681
343.397
356.686
368.794
379.910
390.183
399.729
408.643
417.003
424.873
432.307
439.350
446.041
452.414
458.496
464.315
469.890
475.242
480.387
485.342
490.119
494.731
A f\f\ t Oi\
499.189
503.503
507.682
511.733
515.665
519.485
523.198
526.810
530.328
533.754
537.095
540.354
543.535
546.642
549.678
552.646
555.550
558.392
561.174
563.900
566.570
569.188
571.756
574.275
576.748
579.175
581.559
583.901
586.202
588.464
590.689
592.877
595.029
р(О) -p4(F)-
S°H)
-1
253.694
303.197
341.404
342.048
373.533
399.673
421.869
441.085
457.988
473.057
486.638
498.993
510.319
520.773
530.476
539.529
548.011
555.991
563.523
570.654
577.426
583.872
596.021
595.901
601.533
606.937
612.131
617.131
CO1 OCA
621.950
626.602
631.096
635.445
639.656
643.738
647.699
651.546
655.285
658.922
662.462
665.911
669.272
672.551
675.752
678.877
681.931
684.916
687.835
690.692
693.490
696.229
698.913
701.545
704.125
706.657
709.140
7П.579
713.974
716.326
718.6*8
720.910
723.144
p (XeOF4)
//Vw/°@)
кДж • моль
4.086
11.400
20.848
21.040
32.008
43.733
55.913
68.381
81.042
93.836
106.728
119.690
132.708
145.768
158.862
171.984
185.127
198.289
211.467
224.657
237.859
251.070
264.289
277.516
290.749
303.987
317.231
330.478
343.730
356.985
370.244
383.505
396.769
410.035
423.364
436.574
449.846
463.120
476.396
489.672
502.951
516.230
529.510
542.792
556.074
569.358
582.642
595.927
609.213
622.499
635.786
649.074
662.362
675.652
688.941
702.231
715.521
728.812
742.103
755.395
768.687
-267.3827
-118.2494
-68.7108
-68.0861
-42.8682
-27.6883
-17.5492
-10.2994
-4.8595
-.6282
2.7561
5.5239
7.8290
9.7781
11.4474
12.8928
14.1564
15.2701
16.2590
17.1429
17.9374
18.6555
19.3075
19.9021
20.4464
20.9466
21.4077
21.8341
22.2296
22.5973
22.9400
23.2602
23.5600
23.8413
24.1057
24.3546
24.5894
24.8112
25.0210
25.2199
25.4085
25.5877
25.7581
25.9205
26.0752
26.2228
26.3639
26.4987
26.6279
26.7515
26.8701
26.9838
27.0931
27.1981
27.2991
27.396a
27.4899
27.5801
27.6671
27.7510
27.8321
(г)
Таблица 106
560.000 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
280U
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
3
1
§ К А
оо 5
я - II *
и «о Z;
II /""ч • ^
w, о со Л
* * « 5
О • в
1 о °«
о *
< 2Ь
+
со
*о ^
СО *л
г4 о
+ 2
!» т
^ « 5
оо ' §
s й Z
¦ © rt* V
S *i V
Д -ч о
* "Г ^
S X
• 00 ^>
; 5 2
II +
•в»
164

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
?000
2100
2200
2300
2400
2500
2600
5700
QQAft.
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
ОЛ 7ЙА
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.787
20.787
20.788
20.788
20.789
20.790
20.791
20.792
РАДОН Rn (г)
Ф°(Т)
S°(T)
Дж • К. • моль"
H°(T)-H°@)
кДж • моль
\gK°(T)
132.631 153.417 2.079 —
147.039 167.825 4.157 —
155.338 176.124 6.197 —
155.467 176.253 6.236 -
161.447 182.233 8.314 —
166.085 186.871 10.393 —
169.875 190.661 12.472 —
173.079 193.865 14.550 —
175.854 196.640 16.629 —
178.303 199.089 18.707 —
180.493 201.279 20.786 —
182.474 203.260 22.865 —
184.282 205.068 24.943 —
185.946 206.732 27.022 —
187.487 208.273 29.100 —
188.921 209.707 31.179 —
190.262 211.048 33.258 —
191.522 212.308 35.336 -
192.710 213.496 37.415 —
193.834 214.620 39.493 —
194.900 215.686 41.572 —
195.915 216.701 43.651 —
196.882 217.668 45:729 —
197.805 218.592 47.808 —
198.690 219.476 49.886 —
199.539 220.325 51.965 —
200.354 221.140 54.044 —
201.138 221.924 56.122 —
9Л1 RQJ. 990 Ago ВД901
202.624 223.410 60.279 —
203.328 224.114 62.358 —
204.010 224.796 64.437 —
204.670 225.456 66.515 —
205.310. 226.096 68.594 —
205.930 226.716 70.672 —
206.533 227.319 72.751 —
207.118 227.904 74.830 —
207.688 228.474 76.908 —
208.242 229.028 78.987 —
208.782 229.568 81.065 —
209.308 230.094 83.144 —
209.821 230.608 85.223 —
210.322 231.108 87.301 —
210.811 231.597 89.380 —
21Г.289 232.075 91.459- —
211.756 232.542 93.537 —
212.213 232.999 95.616 —
212.660 233.446 97.694 —
213.098 233.884 99.773 —
213.527 234.312 101.852 —
213.946 234.732 103.930 —
214.358 235.144 106.009 —
214.762 235.548 08.087 —
215.158 235.944 110.166 —
215.546 236.332 1121245 —
215.928 236.714 114.324 —
216.302 237.088 116.402 —
216.670 237.456 118.481 —
217.032 237.818 120.560 —
217.387 238.173 122.639 —
217.736 933.523 124.71ft —
T
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
6200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 107
g
fvj О
<^ и
" © Я
^ II «О
° 2 ?
с Я "
rf С og
о OS
1 ^
§ §
i ^
v; r
« V
М <=>
о
& «•"
г** ~
© 'о
S
<*} ..
оо С-
с*
II
о
•е*
165

РАДОН Rn (г)
Таблица 107
(окончание)
с°р т
Ф°G)
S°(T)
Дж К~ * • моль"!
#°(Г)-#°@)
кДж; моль""
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.797
20.803
20.813
20.827
20.847
20.874
20.911
20.961
21.025
21.108
21.213
21.344
21.506
21.704
21.943
22.228
22.565
22.961
23.420
23.949
25.616
27.843
30.698
34.222
38.418
43.240
48.590
54.320
60.233
66.099
71.678
76.736
81.069
84.523
87.002
88.474
88.965
88.552
87.345
85.475
218.418
219.078
219.717
220.338
220.941
221.526
222.096
222.651
223.191
223.718
224.232
224.733
225.224
225.703
226.172
226.631
227.081
227.523
227.956
228.381
229.413
230.407
231.370
232.308
233.228
234.136
235.039
235.942
236.849
237.765
238.693
239.635
240.593
241.566
242.555
243.558
244.573
245.598
246.630
247.666
239.204
239.865
240.505
241.127
241.731
242.318
242.891
243.449
243.994
244.528
245.050
245.563
246.067
246.563
247.054
247.539
248.021
248.500
248.978
249.456
250.663
251.904
253.202
254.580
256.060
257.659
259.390
261.260
263.268
265.410
267.669
270.027
272.456
274.930
277.418
279.892
282.325
284.694
286.980
289.169
128.877
133.037
137.199
141.363
145.530
149.702
153.880
158.067
162.266
166.479
170.710
174.965
179.250
183.570
187.934
192.351
196.829
201.381
206.018
210.753
223.123
236.463
251.071
267.273
285.406
305.796
328.734
354.449
383.084
414.675
449.136
486.266
С 25.751
567.188
610.111
654.022
698.421
742.836
786.841
830.070
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
166

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.787
20.787
20.788
20.788
20.789
20.790
20.791
20.792
20.794
20.796
20.798
20.800
20.803
20.807
20.811
20.815
20.820
20.825
20.831
20.838
20.845
20.853
20.861
20.870
20.879
20.890
20.901
20.912
20.924
ПОЛОЖИТЕЛЬНЫЙ ИОН
К°(Т)= p(Rn)-
ф°(Т)
Дж • К~1 • моль'
166.865
166.993
172.973
177.611
181.401
184.605
187.381
189.829
192.019
194.000
195.809
197.472
199.013
200.447
201.788
203.048
204.237
205.360
206.427
207.441
208.408
209.332
210.216
211.065
211.880
212.665
213.420
214.150
214.855
215.536
216.196
216.836
217.456
218.059
218.644
219.214
219.768
220.308
220.834
221.348
221.849
222.338
222.816
223.283
223.740
224.187
224.624
225.053
225.473
225.885
226.289
226.685
227.073
227.455
227.830
228.198
228.560
228.915
229.265
pl(fi).pl{Kn
-1
187.650
187.779
193.759
198.397
202.187
205.391
208.167
210.615
212.805
214.786
216.595
218.258
219.799
221.233
222.574
223.835
225.023
226.146
227.213
228.227
229.194
230.118
23L002
231.851
232.666
233.451
234.207
234.936
235.641
236.322
236.982
237.622
238.242
238.845
239.431
240.000
240.555
241.095
241.621
242.135
242.636
243.125
243.603
244.071
244.528
244.976
245.414
245.844
246.264
246.677
247.082
247.479
247.869
248.252
248.628
248.997
249.361
249.718
250.070
//°(О-//С
РАДОНА Rn+ (г)
Дг//°@) - -1037,
кДж * моль
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.280
62.358
64.437
66.515
68.594
70.673
72.752
74.830
76.909
78.988
81.068
83.147
85.226
87.306
89.386
91.466
93.547
95.627
97.709
99.790
101.873
103.956
106.039
108.123
110.208
112.294
114.380
116.468
118.556
120.646
122.736
124.828
lgK°(T)
181.0821
179.9550
134.5007
107.1732
88.9184
75.8533
66.0351
58.3835
52.2502
47.2221
43.0238
39.4645
36.4076
33.7532
31.4260
29.3686
27.5363
25.8936
24.4124
23.0697
21.8466
20.7278
19.7003
18.7531
17.8771
17.0645
16.3085
15.6032
14.9438
14.3257
13.7452
13.1988
12.6836
12.1969
11.7364
11.2999
10.8857
10.4920
10.1172
9.7601
9.4194
9.0939
8.7826
8.4846
8.1991
7.9251
7.6622
7.4095
7.1664
6.9325
6.7071
6.4899
6.2803
6.0780
5.8825
5.6936
5.5108
5.3340
5.1627
073 кДж-моль 1
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
«о
&
as
СМ
CM
II
V©
см
о
О
1
2
со
О
§
о
О
4-
S
Г*-
о
СМ
+
СМ
СМ
О\
О\
со
см
II
%
Таб л и
i
л
1
к
г-*
р
со
о
II
о
Он
о
<
1
А
§
i
Ъ&
71
ГО
О
+
ё
со
о
1
а>
»о
см
о
+
т
л
Q
.
о
см
со
О
II
я
«о
об
см
С
с
Об
о
цаЮ8
о
1
«о
1
ЧО
\ /
V
V
о
«О
1
О
II
167

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
, 14600
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°{Т)
20.950
20.979
21.010
21.043
21.078
21.115
21.154
21.195
21.237
21.280
21.324
21.369
21.415
21.461
21.507
21.554
21.600
21.647
21.693
21.739
21.851
21.959
22.061
22.156
22.245
22.326
22.400
22.466
22.526
22.578
22.623
22.662
22.695
22.722
22.744
22.761
22.773
22'.782
22.787
22.788
ПОЛОЖИТЕЛЬНЫЙ ИОН РАДОНА Rn+ (г)
Дж К~1 • моль"
229.947
230.608
231.248
231.870
232.474
233.061
233.632
234.188
234.730
235.258
235.774
236.277
236.769
237.250
237.720
238.180
238.631
239.072
239.505
239.929
240.955
241.934
242.872
243.772
244.636
245.469
246.271
247.046
247.795
248.520
249.223
249.904
250.566
251.209
251.834
252.443
253.036
253.613
254.177
254.727
-1
Н°{Г)-Н°@)
кДж' моль*"
lgK°(T)
250.756 129.015 4.8358
251.422 133.208 4.5283
252.068 137.407 4.2383
252.695 141.612 3.9644
253.306 145.825 3.7053
253.900 150.044 3.4597
254.479 154.271 3.2265
255.044 158.506 3.0049
255.595 162.749 2.7938
256.133 167.000 2.5926
256.659 171.261 2.4006
257.173 175.530 2.2170
257.677 179.808 2.0414
258.170 184.096 1.8732
258.652 188.393
259.126 192.699
259.590 197.014
260.045 201.339
260.492 205.673
1.7120
1.5572
1.4086
1.2656
1.1281
260.931 210.016 .9957
261.994 220.913 .6851
263.013 23 Г.866 .4008
263.991 242.871 .1397
264.932 253.926 -.1007
265.839 265.026 -.3227
266.713 276.169 -.5280
267.557 287.351 -.7181
268.372 298.568 -.8942
269.162 309.816 -1
269.926 321.092 -1
270.667 332.393 -]
271.386 343.714
272.084 355.054
272.762 366.408 -1
273.421 377.775
274.062 389.151
.0575
.2088
.3491
.4792
.5998
.7115
.8150
.9110
274.686 400.535 -2.0000
275.293 411.924 -2.0827
275.885 423.316 -2.1595
276.462 434.710 -2.2407
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 108
(окончание)
1
00 ^
О Л
© |
X Т &н
го * О
00 • О
00 •? С?
S й 8
6 х V
jj 2 v
00 "*" О
С"} О\ «—«
<? + 2
г** X
VO »О ^
о ^ и
CN т^ ?
II 1
ь
168

Класс точности
V-B
К°(Т) =
СЕРА S (к, ж)
Таблица 109
АН°@) =274.785 кДж • моль 1
К
100
200
298.15
300
368.54
368.54
388.36
388.36
400
500
600
700
800
900
1000
1100
1200
1300
Ф°(Т)
S°(T)
Дж • К~1 • моль""
кДж • моль
-1
lgK°(T)
12.770
19.389
22.686
22.710
24.177
24.758
25.326
32.03Q
32.197
38.007
34.256
32.988
32.522
32.310
32.199
32.136
32.097
32.072
5.640
11.975
17.255
17.347
20.569
20.569
21.497
21.497
22.162
27.571
32.471
36.796
40.632
44.069
47.179
50.016
52.625
55.038
12.489
23.623
32.054
32.196
37.020
38.109
39.421
43.844
44.791
53.539
60.082
65.249
69.619
73.436
76.834
79.899
82.694
85.262
.685
2.330
4.412
4.454
6.063
6.464
6.961
8.678
9.051
12.984
16.567
19.917
23.189
26.430
29.654
32.871
36.082
39.291
-137.4587
-65.2561
-41.4478
-41.1484
-32.1774
•32.1774
-30.1765
-30.1765
-29.1010
-21.9427
-17.1983
-13.8245
-11.3045
-9.3524
-7.7969
-6.5292
т5.4772
-4.5906
100
200
298.15
300
368,54
368.54
388.36
388.36
400
500
600
700
800
900
1000
1100
1200 й
1300
4
о
II
о
и
2
«О
Н
to
169

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;<г)
21.356
23.387
23.673
23.669
23.233
22.741
22.338
22.031
21.800
21.624
21.489
21.386
21.307
21.249
21.209
21.186
21.178
21.184
21.203
21.234
21.276
21.327
21.386
21.452
21.523
21.598
21.676
21.756
21.837
21.919
21.999
22.078
22.155
22.230
22.303
22.372
22.439
22.502
22.561
22.618
22.670
22.720
22.766
22.808
22.847
22.884
22.917
22.947
22.974
22.999
23.021
23.040
23.057
23.072
23.085
23.096
23.105
23.112
23.117
23.121
23.124
Ф°(Т)
Дж • К • моль
121.897
136.598
145.389
145.528
151.999
157.057
161.193
164.682
167.694
170.340
172.698
174.823
176.756
178.528
180.164
181.683
183.100
184.429
185.679
186.860
187.978
189.041
190.053
191.020
191.945
192.831
193.683
194.503
195.292
196.055
196.791
197.504
198.195
198.864
199.514
200.146
200.760
201.358
201.940
202.508
203.062
203.603
204.131
204.647
205.152
205.646
206.130
206.603
207.067
207.522
207.968
208.405
208.835
209.256
209.670
210.077
210.477
210.870
211.256
211.636
212.010
S°iT)
142.782
158.283
167.715
167.864
174.620
179.750
183.859
187.278
190.204
192.761
195.032
197.075
198.933
200.636
202.209
203.671
205.038
206.322
207.533
208.681
209.771
210.810
211.804
212.756
213.670
214.550
215.399
216.218
217.011
217.779
218.523
219.246
219.948
220.631
221.296
221.943
222.574
223.190
223.791
224.378
224.951
225.511
226.060
226.596
227.120
227.634
228.138
228.631
229.114
229.588
230.053
230.509
230.957
231.396
231.827
232.251
232.667
233.076
233.478
233.874
234.262
СЕРА S (г)
// °(/')_//°@)
ЛДж • моль
К
2.088 — 100
4.337 — 200
6.657 — 298.15
6.701 — 300
9.048 — 400
11.346 — 500
13.599 — 600
15.817 — 700
18.008 — 800
20.179 — 900
22.334 — 1000
24.478 — 1100
26.612 — 1200
28.740 — 1300
30.863 — 1400
32.982 — 1500
35.100 — 1600
37.218 — 1700
39.338 — 1800
41.459 — 1900
43.585 — 2000
45.715 — 2100
47.850 — 2200
49.992 — 2300
52.141 — 2400
54.297 — 2500
56.461 — 2600
58.632 — 2700
60 812 2800
63.000 — 2900
65.196 — 3000
67.400 — 3100
69.611 — 3200
71.831 — 3300
74.057 — 3400
76.291 — 3500
78.532 — 3600
80.779 — 3700
83.032 — 3800
85.291 — 3900
87.555 — 4000
89.825 — 4100
92.099 — 4200
94.378 — 4300
96.661 — 4400
98.947 — 4500
101.237 — 4600
103.530 — 4700
105.826 — 4800
108.125 — 4900
110.426 — 5000
112.729 — 5100
115.034 — 5200
117.340 — 5300
119.648 — 5400
121.957 — 5500
124.267 — 4600
126.578 — 5700
128.890 — 5800
131.202 — 5900
133.514 — 6000
g
и
1
|
6
1
г»
8
р
О
со
+
00
го
CN
<N
II
Таблица 110
"Г1
с~ !S '
^ ^ о
s ! т'
5 ^ й
*"* 2 ^
О _-! II
00
- Os
•-¦ <N Д
0 в!
гЛ U Со
о ю
**? о
< ^
1
к
1
о
? О
b S
х V
го
VO V
1 о
g
чо 1
+ ?
(N И
ю х
О w
Г-
170

СЕРА S (г)
Таблица ПО
(окончание)
С°р (Г)
Ф°G)
s m
Дж К"*1 -моль"
Я°(Г)-Я°@)
кДж' моль
-1
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
23.125
23.121
23.113
23.101
23.086
23.068
23.049
23.027
23.003
22.979
22.953
22.926
22.898
22.870
22.842
22.813
22.784
22.755
22.725
22.696
212.740
213.448
214.135
214.802
215.450
216.080
216.694
217.292
217.875
218.444
218.998
219.540
220.069
220.586
221.092
221.587
222.071
222.545
223.010
223.465
235.020
235.755
236.466
237.156
237.825
238.475
239.107
239.721
240.319
240.901
241.468
242.021
242.560
243.086
243.600
244.102
244.592
245.072
245.540
245.999
138.139
142.763
147.387
152.008
156.627
161.243
165.854
170.462
175.065
179.663
184.256
188.844
193.426
198.003
202.574
207.140
211.700
216.253
220.801
225.344
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
5600
9800
10000
? i
8
©
d
g
SO
s
x
SO
SO
CO
О
+
•О
о
V
Ь^
V
о
О
171

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛЛЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
' 4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
22.783
22.785
22.649
22.365
22.091
21.864
21.683
21.539
21.426
21.335
21.261
21.201
21.151
21.110
21.075
21.045
21.020
20.998
20.979
20.962
20.948
20.935
20.924
20.914
20.904
20.896
20.889
20.882
20.876
20.87.1
20.866
20.861
20.857
20.853
20.850
20.847
20.844
20.841
20.838
20.836
20.833
20.831
20.829
20.827
20.826
20.824
20.823
20.821
20.820
20.819
20.817
20.816
20.815
20.814
20.813
20.812
20.811
20.810
20.810
ОТРИЦАТЕЛЬНЫЙ ИОН СЕРЫ S~ (г)
К°(Т) = piS) pie) p (S~)
• Ф°(Л
Дж • К • моль
143.129
143.263
149.544
154.457
158.484
161.889
164.834
167.427
169.741
171.830
173.732
175.478
177.092
178.591
179.990
181.303
182.538
183.705
184.811
185.861
186.861
187.816
188.729
189.604
190.443
191.251
1Q9 ПОЯ
192.777
193.501
194.200
194.876
195.532
196.167
196.784
197.383
197.965
198.531
199.083
199.620
200.144
200.654
201.153
201.640
202.116
202.581
203.036
203.481
203.917
204.344
204.763
205.173
205.576
205.970
206.357
206.738
207.111
207.478
207.839
208.193
S°(T)
-1
164.815
164.956
171.500
176.524
180.577
183.964
186.872
189.417
191.680
193.718
195.571
197.270
198.839
200.297
201.658
202.935
204.137
205.273
206.350
207.373
208.348
209.279
210.169
211.023
211.843
212.632
213.392
214.125
214.833
215.517
216.180
216.822
217.444
218.049
218.636
219.208
219.764
220.305
220.832
221.347
221.849
222.339
222.818
223.286
223.744
224.192
224.630
225.060
225.480
225.892
226.297
226.693
227.082
227.464
227.839
228.208
228.570
228.925
229.275
Таблица 111
ArM°(Q) = 200.430 кДж • моль 1
Н°(Т)-Н°ф)
кДж • моль" 1
6.466 -34.9917
6.508 -34.7682
8.782 -25.7216
11.033 -20.2371
13.256 -16.5437
15.453 -13.8792
17.630 -11.8613
19.791 -10.2766
21.939 ' -8.9966
24.077 -7.9395
26.206 -7.0503
28.329 -6.2910
30.447 -5.6341
32.560 -5.0596
34.669 -4.5524
36.775 -4.1008
38.878 -3.6958
40.979 -3.3303
43.078 -2.9984
45.175 -2.6955
47.270 -2.4178
49.365 -2.1620
51.458 -1.9255
53.549 -1.7061
55.640 -1.5018
57.730 -1.3111
*\Q Я9Л .1 1 494
O«7.OZU I.I O<Cx '
61.908 -.9647
63.996 -.8069
66.083 -.6580
68.170 -.5173
70.257 -.3840
72.343 -.2575
74.428 -.1373
76.513 -.0228
78.598 .0864
80.683 .1906
82.767 .2903
84.851 .3858
86.934 .4773
89.018 .5652
91.101 .64%
93.184 .7309
95.267 .8091
97.350 .8845
99.432 .9572
101.514 1.0275
103.597 1.0953
105.679 1.1610
107.761 1.2245
109.842 1.2861
111.924 1.3458
114.006 1.4037
116.087 1.4598
118.168 1.5144
120.250 1.5674
122.331 1.6190
124.412 1.6692
126.493 1.7180
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
ZO\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
g Д 'д
2 9 о
k s 1
S ? <=> •
• 8 *
? го II Д
го • Сц.
|| ^* Я ^>
^ 1-4
о «
СО | " «О
о" &
1
«и
'а
го *Г
8 е
• 5
? §
§ i I
1 «* V
? ^ v
^ ? s
I w
^ Г4
го X •-
12 ^ '
^ го 2
?> + ?
го с4)
сч .
II 1
Ф
172

ОТРИЦАТЕЛЬНЫЙ ИОН СЕРЫ S" (г)
Таблица 111
(окончание)
С°р(Т)
Дж К~г • моль"
Я°(Г)-Я°@)
кДж' моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8^00
8400
8600
8800
9000
9200
9400
9600
9800
10000
20.808
20.807
20.806
20.805
20.804
20.803
20.802
20.801
20.800
20.799
20.799
20.798
20.798
20.797
20.797
20.796
20.796
20.795
20.795
20.795
208.884
209.553
210.201
210.830
211.440
212.032
212.609
213.169
213.715
214.248
214.766
215.272
215.767
216.249
216.721
217.182
217.634
218.075
218.508
218.931
229.957
230.618
231.258
231.879
232.482
233.068
233.638
234.193
234.733
235.260
235.774
236.275
236.764
237.242
237.710
238.167
238.614
239.052
239.481
239.901
130.655
134.816
138.978
143.139
147.299
151.460
155.620
159.781
163.941
168.101
172.260
176.420
180.580
184.739
188.899
193.058
197.217
201.376
205.535
209.694
1.8120
1.9012
1.9862
2.0673
2.1448
2.2189
2.2899
2.3580
2.4235
2.4864
2.5470
2.6054
2.6618
2.7162
2.7688
2.8197
2.8690
2.9168
2.9631
3.0080
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
го
I
©
о
I
р
о
+
00
р
о
I
о
о
о
о
V
V
173

Класс точности
IV-A
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯОП
tOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.369
30.462
32.505
32.540
34.108
35.133
35.815
36.305
36.697
37.045
37.377
37.704
38.030
38.353
38.669
38.976
39.268
39.546
39.805
40.047
40.270
40.475
40.663
40.834
40.990
41.132
41.262
41.380
41.490
41.592
41.689
41.780
41.869
41.956
42.043
42.129
42.218
42.309
42.402
42.500
42.601
42.707
42.817
42.931
43.051
43.174
43.303
43.435
43.571
43.710
43.852
43.997
44.144
44.292
44.442
44.592
44.743
44.892
45.041
45.189
45.335
К°(Т)= p2(S) i
Ф°(Т)
Дж-К моль
164.261
185.302
197.425
197.615
206.522
213.585
219.471
224.531
228.976
232.944
236.531
239.806
242.821
245.617
248.224
250.668
252.968
255.143
257.205
259.166
261.037
262.826
264.539
266.184
267.766
269.290
270.760
272.179
273.552
274^881
276.170
277.421
278.635
279.815
280.964
282.081
283.171
284.233
285.269
286.281
287.270
288.236
289.181
290.106
291.011
291.898
292.768
293.620
294.456
295.276
296.082
296.873
297.650
298.414
299.165
299.904
300.631
301.346
302.050
302.744
303.427
f\s2)
s°m
194.948
215.506
228.055
228.256
237.847
245.576
252.046
257.605
262.480
266.822
270.743
274.320
277.615
280.672
283.526
286.204
288.729
291.118
293.386
295.545
297.604
299.574
301.462
303.273
305.014
306.691
308.306
309.866
311.373
312.831
314.242
315.611
316.938
318.228
319.482
320.702
321.890
323.048
324.177
325.280
326.357
327.411
328.441
329.450
330.438
331.407
332.357
333.290
334.206
335.106
335.990
336.860
337.716
338.558
339.387
340.204
341.009
341.802
342.584
343.356
344.116
ДИСЕРАв, (г)
V
//°G')-//°@)
кДж • моль
3.069
6.041
9.132
9.192
12.530
15.996
19.545
23.152
26.803
30.490
34.212
37.966
41.752
45.572
49.423
53.305
57.217
61.158
65.126
69.119
73.135
77.172
81.229
85.304
89.396
93.502
97.622
101.754
105.897
110.052
114.216
118.389
122.572
126.763
130.963
135.171
139.389
143.615
147.851
152.096
156.351
160.616
164.892
169.180
173.479
177.790
182.114
186.450
190.801
195.165
199.543
203.935
208.342
212.764
217.201
221.652
226.119
230.601
235.098
239.609
244.136
D@) = 421.277 кДж • моль
-215.8952
-105.4338
-68.9288
-68.4691
-49.9208
-38.7589
-31.2992
-25.9598
-21.9479
-18.8225
-16.3185
-14.2672
-12.5557
-11.1060
-9.8622
-8.7833
-7.8385
-7.0043
-6.2623
-5.5980
-4.9998
-4.4582
-3.9657
-3.5158
-3.1032
-2.7234
-2.3726
-2.0477
-1.7458
-1.4646
-1.2021
-.9563
-.7258
-.5091
-.305!
-.1126
.0694
.2415
.4048
.5597
.7070
.8472
.9808
1.1083
.2300
.3464
.4578
.5646
.6669
.7651
.8594
1.9501
2.0374
2.1213
2.2022
2.2802
2.3555
2.4281
2.4982
2.5660
2.6315
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
CS
S
VO
II
т
о
«о
ON
г»
р
о
+
д
СО
*н
СО
о
о
р
о
+
«о
00
со
+
ON
о
»о
со
о
II
Таблица 112
а I т-
5 к |
R о •
? s *
ON 00 v;
<N OI Д
00 * ^
/*^ г»
II «О °°.
1-4 СО
О 00
ON "
и сч
о и о к
т
л
о
.
1
д |
ON
4. \/
т V
с* О
Д S
5 ?
<N О
' Т
X ?
«о ^
•О •)
•о
Р X
»-| >—'
со
174

Класс точности
IV-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯП0
*оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.193
37.227
38.259
38.491
38.484
38.420
38.355
38.305
38.271
38.252
38.245
38.248
38.260
38.279
38.304
38.333
38.367
38.405
38.446
38.491
38.538
38.589
38.642
38.698
38.757
38.818
38.882
38.948
39.016
39.087
39.159
39.233
39.308
39.383
39.459
39.534
39.608
39.681
39.752
39.819
39.883
39.944
39.999
40.049
40.093
40.130
40.161
40.184
40.200
40.207
40.206
40.197
40.179
40.153
40.117
40.073
40.021
39.959
39.890
К°(Т)=р2
Ф°(Т)
ОТРИЦАТЕЛЬНЫЙ ИОН
(S) -p{e) -^(Sj)
S°(T)
Дж • К~1 • моль
196.129
196.329
205.803
213.416
219.783
225.251
230.041
234.300
238.134
241.619
244.814
247.763
250.501
253.056
255.451
257.705
259.835
261.852
263.769
265.595
267.338
269.006
270.604
272.140
273.616
275.039
276.411
277J36
279.018
280.260
281.463
282.630
283.764
284.865
285.937
286.981
287.997
288.989
289.956
290.900
291.823
292.724
293.606
294.469
295.313
296.140
296.951
297.745
298.525
299.289
300.039
300.775
301.498
302.209
302.907
303.593
304.268
304.931
305.584
228.318
228.548
239.430
248.000
255.019
260.947
266.073
270.587
274.621
278.268
281.596
284.657
287.492
290.132
292.603
294.926
297.118
299.194
301.165
303.042
304.833
306.548
308.191
309.769
311.288
312.752
314.165
315.531
316.852
318.133
319.375
320.581
321.753
322.894
324.004
325.086
326.142
327.172
328.177
329.160
330.120
331.059
331.978
332.877
333.758
334.621
335.466
336.294
337.106
337.903
338.683
339.449
340.200
340.937
341.660
342.370
343.067
343.750
344.421
П°{Т)~Н
дисеры s; (г)
АгН°@) = 581.277
°«»
кДж • моль
9.597
9.666
13.451
17.292
21 142
24.987
28.826
32.659
36.487
40.313
44.138
47.963
51.788
55.615
59.444
63.276
67.111
70.949
74.792
78.639
82.490
86.346
90.208
94.075
97.948
101.826
105.711
109.603
113.501
117.406
121.319
125.238
129.165
133.100
137.042
140.991
144.949
148.913
152.885
156.863
160.848
164.840
168.837
172.839
176.846
180.858
184.872
188.889
192.909
196.929
200.950
204.970
208.989
213.006
217.019
221.029
225.033
229.032
233.025
\%К°{Т)
-96.8879
-96.2492
-70.4536
-54.8994
-44.4812
-37.0058
-31.3745
-26.9756
-23.4416
-20.5380
-18.1083
-16.0439
-14.2673
-12.7214
-11.3632
-10.1601
-9.0864
-8.1220
-7.2505
-6.4590
-5.7366
-5.0744
-4.4651
-3.9023
-3.3807
-2.8959
-2.4440
-2.0216
-1.6258
-1.2541
-.9042
-.5743
-.2626
.0324
.3122
.5778
.8305
1.0711
1.3006
1.5197
1.7292
1.9297
2.1218
2.3061
2.4830
2.6530
2.8166
2.9741
3.1259
3.2722
3.4135
3.5499
3.6817
3.8093
3.9327
4.0523
4.1681
4.2804
4.3894
кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
64.1
и
г»
g
О
с*
00
о
о
+
VO
г-
со
О)
00
со
+
8
fN
со
II
С'
Таб л и
1
л
т 1
I k
R со
* .
Р^ со
S 1
*"Н ||
СП ^
1 U
II ^
О об
1 "сч ьГ
w | ^
о ел
<L^ о
<]
t
1
л
g
i
у»
ин
к
СО
о
»о
1
<ч
00
On
$
00
«о
1
1
ца 113
Т
•4
|
к
«о
00
II
о eg
1 ^
->
2
О
О
О
ЧО
V
W
V
о
о
%,
1
о
о
II
н
175

Класс точности
V-F.
Т
К
100
200
298 Л 5
300
400
500
600
700
800 .
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5l000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
34.721
42.123
48.087
48.173
51.691
53.724
54.963
55.762
56.302
56.683
56.961
57.170
57.331
57.457
57.557
57.639
57.706
57.762
57.809
57.849
57.883
57.912
57.938
57.960
57.979
57.997
58.012
58.026
58.038
58.049
58.059
58.068
58.076
58.Q83
58.090
58.096
58.102
58.107
58.112
58.117
58.121
58.125
58.128
58.132
58.135
58.138
58.140
58.143
58.145
58.148
58.150
58.152
58.154
58.155
58.157
58.159
58.160
58Л61
58.163
58.164
58.165
^n = p3<S).p-
Ф°G)
Дж • К~' • моль" 1
195.336
219.189
234.104
234.345
245.975
255.552
263.736
270.895
277.263
282.999
288.219
293.009
297.434
301.546
305.386
308.989
312.382
315.588
318.627
321.515
324.266
326.893
329.407
331.817
334.131
336.356
338.500
340.567
342.564
344.494
346.362
348.17а
349.928
351.633
353.288
354.899
356.465
357.991
359.477
360.927
362.341
363.722
365.071
366.390
367.679
368.940
370.174
371.383
372.567
373.728
374.866
375.982
377.077
378.152
379.207
380.244
381.262
382.263
383.247
384.215
385.167
>(s3)
S°(T)
228.859
255.085
273.110
273.407
287.795
299.568
309.481
318.018
325.501
332.156
338.143
343.582
348.564
353.158
357.420
361.394
365.116
368.616
371.919
375.046
378.014
380.839
383.534
386 110
388.577
390.944
393.219
395.408
397.519
399.556
401.524
403.428
405.271
407.059
408.793
410.477
412.113
413.705
415.255
416.765
418.236
419,671
421.072
422.440
423.776
425.083
426.361
427.611
428.835
430.034
431.209
432.360
433.490
434.597
435.684
436.752
437.800
438.829
439.840
440.835
441.812
ТРИСЕРА S3 (г)
//°(Г)-//°«))
кДж • моль
3.352
7.179
11.630
11.719
16.728
22.008
27.447
32.986
38.591
44.241
49.924
55.631
61.357
67.096
72.847
78.607
84.374
90.148
95.927
101.709
107.496
113.286
.119.078
124.873
130.670
136.469
142.269
148.071
153.875
159.679
165.484
171.291
177.098
182.906
188.714
194.524
200.334
206.144
211.955
217.767
223.578
229.391
235.203
241.016
246.830
252.643
258.457
264.271
270.086
275.900
281.715
287.530
293.345
299.161
304.976
310.792
316.608
322.424
328.240
334.057
339.873
э@) = 679.35*
\gK°(T)
-345.9555
-167.4711
•108.4641
-107.7211
-77.7433
-59.7082
-47.6591
-39.0374
•32.5614
-27.5179
-23.4783
-20.1695
-17.4095
-15.0718
-13.0663
-11.3267
-9.8033
-8.4579
-7.2611
•6.1893
-5.2239
-4.3498
-3.5544
-2.8275
-2.1606
•1.5465
-.9790
-.4531
.0358
.4914
.9171
1.3158
1.6900
2.0419
2.3736
2.6867
2.9827
3.2631
3.5291
3.7818
4.0222
4.2512
4.4696
4.6781
4.8774
5.0682
5.2509
5.4261
5.5942
5.7557
5.9110
6.0604
6.2043
6.3430
6.4767
6.6058
6.7305
6.8509
6.9674
7.0801
7.1892
> кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000*
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
оо
On
II
+
ё
с-
о
+
,2
to
I
о
On
On
со
00
•о
о
8
II
с
о
ф
Таб
i
л
g
к
о
о
о
«о
1-4
II
о
и
со
00
о
1
л
2
.
i
k
со
1О
с*
«о
ц
1
щ
у4
лица 114
_<
i.
л
§
? Т
? л
е* о
со *
СО Jjm
Я ^
00 и
с о g
00
о
Я
О
8
V
V
g
с?
«о
••
1
—*
II
176

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
N4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
A'om = /(S)-p~3
Ф°(Л
Дж • К • моль
39.758 201.756
55.583 227.753
65.943 245.521
66.089 245.817
72.068 260.392
75.519 272.758
77.624 283.530
78.983 293.078
79.903' 301.653
80.553 309.435
81.027 316.557
81.384 323.122
81.658 329.210
81.873 334.886
82.045 340.201
82.184 345.198
82.299 349.913
82.394 354.376
82.474 358.613
82.542 362.645
82.600 366.491
82.650 370.168
82.694 373.689
82.732 377.068
82.765 380.315
82.795 383.440
82.821 386.452
82.844 389.360
82.865 392.169
82.884 394.886
82.901 397.517
82.917 00.068
82.930 402.544
82.943 404.947
82.955 407.283
82.965 409.556
82.975 411.768
82.984 413.923
82.992 416.023
83.000 418.072
83.007 420.071
83.014 422.023
83.020 423.931
83.026 425.796
83.031 427.620
83.036 429.405
83.041 431.153
83.045 432.864
83.049 434.541
83.053 436.185
83.056 437.797
83.060 439.379
83.063 440.931
83.066 442.454
83.069 443.950
83.072 445.420
83.074 446.864
83.077 448.283
83.079 449.679
83.081 451.052
83.083 452.402
ТЕТРАСЕРА S4
(V
S°(T)
236.489
269.112
293.416
293.825
313.738
330.223
344.193
356.268
366.878
376.329
384.842
392.582
399.676
406.221
412.295
417.960
423.268
428.260
432.972
437.433
441.669
445.700
449.546
453.223
456.744
460.124
463.371
466.497
469.511
472.419
475.229
477.948
480.580
483.132
485.609
488.014
490.351
492.624
494.838
496.994
499.095
501.145
503.145
505.099
507,008
508.874
510.699
512.484
514.233
515.945
517.624
519.268
520.881
522.463
524.016
525.540
527.037
528.508
529.952
531.373
532.769
А
И°{Т)±Н°((
кДж • моль
3.473
8.272
14.280
14.402
21.338
28.733
36.398
44.233
52.180
60.205
68.285
76.406
84.559
92.736
100.932
109.144
117.368
125.603
133.846
142.097
150.354
158.617
166.884
175.155
183.430
191.708
199.989
208.272
916 SSft
At I UiVUU
224.845
233.135
241.426
249.718
258.012
266.307
274.602
282.900
291.197
299.496
307.796
316.096
324.397
332.699
341.001
349.304
357.608
365.911
374.216
382.520
390.825
399.131
407.437
415.743
424,049
432.356
440.663
448.970
457.278
465.586
473.894
482.202
(Г)
rH°@) = 960.140
3)
-l
igtfV)
-486.5888
-234.1160
-150.6579
-149.6073
-107.2231
-81.7363
-64.7175
-52.5464
-43.4093
-36.2974
-30.6043
-25.9440
-22.0588
-18.7701
-15.9503
-13.5057
-11.3662
-9.4779
-7.7991
-6.2966
-4.9440
-3.7199
-2.6068
-1.5902
-.6580
.1999
.9921
1.7259
2.4075
з!0425
3.6354
4.1903
4.7109
5.2001
5.6609
6.0956
6.5065
6.8954
7.2640
7.6141
7.9469
8.2637
8.5656
8.8538
9.1290
9.3923
9.6443
9.8858
10.1174
10.3398
10.5535
10.7590
10.9568
11.1472
11.3308
11.5079
11.6788
11.8439
12.0034
12.1576
12.3069
кДж • моль *
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб
Т
л
1
00 О
СЧ ^
»"Н о>
II ,-t
о
о
5:
+
ОО
V?> ^
<N A
+ ?
О .
On С-Ц.
S ***
О ^
1 ^
1 On
X ^
1 °
*! «о
- «
- н
сч X
Ф 3
II +
л и
i
о
гч
го
чо
»о
го
1!
Я
оо
On
ua 115
i
1
д
го
О
г-
II
О 5
о в;
Со
СЛ
0
я
о
S
V
к,
V
§
о
II
х
12 872
177

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
49.721
75.658
89.249
89.426
96.379
100.171
102.416
103.840
104.794
105.462
105.947
106.310
106.589
106.807
106.981
107.122
107.237
107.333
107.414
107.483
107.541
107.592
107.635
107.674
107.707
107.737
107.763
107.787
107.808
107.827
107.844
107.859
107.873
107.886
107.898
107.908
107.918
107.927
107.935
107.943
107.950
107.957
107.963
107.969
107.974
107.979
107.984
107.988
107.992
107.996
108.000
108.003
108.006
108.009
108.012
108.015
108.017
Л 08.020
108^022
108.024
108.026
Ф°(Т)
Дж • К~1 • моль
223.171
253.428
275.827
276.208
295.099
311.280
325.422
337.970
349.240
359.465
368.819
377.436
385.424
392.867
399.834
406.381
412.558
418.402
423.947
429.223
434.255
439.063
443.668
448.084
452.328
456.412
460.347
464.145
467.814
471.362
474.798
478.129
481.360
484.497
487.546
490.511
493.397
496.209
498.949
501.621
504.229
506.776
509.264
511.696
514.074
516.402
518.680
520.912
523.098
525.241
527.342
529.404
531.426
533.412
535.362
537.277
539.159
541.009
542.828
544.616
546.376
IIEHTACEPAS5 (г]
l(s5)
S°(T)
261.146
304.299
337.351
337.904
364.690
386.643
405.121
421.023
434.955
447.339
458.477
468.593
477.855
486.396
494.318
501.704
508.621
515.125
521.262
527.072
532.587
537.835
542.841
547.626
552.210
556.607
560.833
564.901
568.821
572.604
576.260
579.797
583.221
586.541
589.762
592.890
595.930
598.887
601.765
604.569
607.302
609.968
612.569
615.110
617.592
620.018
622.392
624.714
626.988
629.214
631.396
633.535
635.632
637.689
639.708
641.690
643.637
645.548
647.427
649.274
651.089
Н°(Т)-Н°@)
кДж • моль
3.798
10.174
18.343
18.509
27.836
37.681
47.820
58.138
68.572
79.087
89.658
100.272
110.918
121.588
132.278
142.983
153.701
164.430
175.167
185.912
196.663
207.420
218.182
228.947
239.716
250.488
261.263
272.041
282.820
293.602
304.386
315.171
325.958
336.746
347.535
358.325
369.116
379.909
390.702
401.496
412.290
423.086
433.882
444.678
455.476
466.273
477.071
487.870
498.669
509.468
520.268
531.068
541.869
552.669
563.470
574.272
585.073
595.875
606.677
617.480
628.282
"@) = 1245.925
-630.6171
-302.9603
-194.7144
-193.3522
-138.4158
-105.4002
-83.3654
-67.6145
-55.7953
-46.5994
-39.2411
-33.2200
-28.2022
-23.9563
-20.3171
-17.1634
-14.4042
-11.9698
-9.8062
-7.8705
-6.1285
-4.5527
-3.1201
-1.8123
-.6134
.4895
1.5076
2.4504
3.3258
4.1410
4.9020
5.6139
6.2815
6.9088
7.4994
8.0563
8.5825
9.0804
9.5523
10.0001
10.4257
10.8308
11.2167
11.5848
11.9364
12.2725
12.5942
12.9023
13.1977
13.4813
13.7536
14.0154
14.2673
14.5098
14.7435
14.9688
15.1862
15.3961
15.5988
15.7948
15.9844
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
§
'к
V©
со
§
р
+
со
i
о
р
о
1
1
о
г^
о
1-4
i
со
On
ю
II
Ь
Таблица 116
i
-н О
1 а
t^ 00
* 2
§ 2
00 Д
^ я
II 1^)
s 2
«Л г*
^ «л
*L °
1
А
О
1
к
со
«Й
О
+
с»
j
X
vo
VO
со
t—t
+
1
А
§
1
т
S
II
о 5
со
о
о
ЧО
\ /
V
V
о
о
1
о
II
178

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
59.683
95.733
112.554
112.762
120.691
124.824
127.208
128.697
129.684
130.371
130.867
131.237
131.520
131.741
131.917
132.059
132.176
132.273
132.354
132.423
132.482
132.533
132.577
132.616
132.649
132.679
132.706
132.729
132.750
132.769
132.786
132.802
132.816
132.829
132.840
132.851
132.861
132.870
132.878
132.886
132.893
132.900
132.906
132.912
132.917
132.922
132.927
132.931
132.935
132.939
132.943
132.946
132.949
132.952
132.955
132.958
132.960
132.963
132.965
132.967
132.969
*-V) = p<(s)
Ф°(Г)
Дж * К * моль
217.076
251.592
278.624
279.089
302.296
322.292
339.803
355.351
369.317
381.984
393.569
404.240
414.127
423.338
431.957
440.055
447.692
454.917
461.771
468.291
474.508
480.448
486.136
491.590
496.831
501.873
506.732
511.420
515.949
520.328
524.569
528.679
532.665
536.536
540.298
543.956
547.517
550.984
554.364
557.661
560.877
564.018
567.086
570.085
573.019
575.889
578.698
581.449
584.145
586.787
589.378
591.919
594.412
596.860
599.264
601.624
603.944
606.224
608.466
610.671
612.839
ГЕКСАСЕРА S.
о
258.293
311.977
353.776
354.473
388.131
415.552
438.539
458.268
475.522
490.839
504.602
517.093
528.525
539.061
548.831
557.937
566.464
574.480
582.043
589.201
595.995
602.460
608.626
614.520
620.165
625.581
630.785
635.794
640.621
645.280
649.781
654.136
658.352
662.439
666.405
670.256
673.998
677.639
681.182
684.634
687.998
691.280
694.483
697.610
700.666
703.653
706.574
709.433
712.232
714.973
717.659
720.291
722.873
725.405
727.891
730.330
732.726
735.079
737.392
739.665
741.900
/Лг)-/Ло
кДж * моль
4.122
12.077
22.407
22.615
34.334
46.630
59.242
72.042
84.964
97.969
111.032
124.138
137.277
150.440
163.623
176.822
190.034
203.257
216.488
229.727
242.973
256.223
269.479
282.739
296.002
309.268
322.537
335.809
349.083
362.359
375.637
388.917
402.197
415.480
428.763
442.048
455.333
468.620
481.907
495.196
508.484
521.774
535.064
548.355
561.647
574.939
588.231
601.524
614.817
628.111
641.405
654.699
667.994
681.289
694.585
707.880
721.176
734.472
747.769
761.065
774.362
(г)
,#°@) = 1544
)
1
о
-779.7378
-373.6325
•239.5238
-237.8365
-169.8037
•128.9329
•101.6646
•82.1785
-67.5604
-56.1900
-47.0939
-39.6526
-33.4527
•28.2078
-23.7134
-19.8194
-16.4132
-13.4088
-10,7390
-8.3511
-6.2026
-4.2594
-2.4933
-.8813
.5961
1.9549
3.2090
4.3700
5.4479
6.4514
7.3879
8.2639
9.0851
9.8566
10.5828
11.2674
11.9141
12.5260
13.1056
13.6557
14.1783
14.6756
15.1493
15.6010
16.0323
16.4446
16.8390
17.2168
17.5789
17.9264
18.260 i
18.5808
18.8893
19.1862
19.4722
19.7480
20.0139
20.2707
20.5186
20.7583
20.9901
.210 к Дж- моль
Г
К
100
200
298 Л 5
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
со
L92.
и
со
О\
со
4-
'х
Os
г-Н
О
.он
о
*—1
V©
V©
со
*—1
Os
VO
ЧО
II
ф
Табл и l
i
л
л 2
1 к
к ?
С^ со
г-> О
§ о
3 1
" 2
О об
То tT
со
s~*' ' VO
О W
Ч^ °
1
л
м
I
•с
V
к
ъ
о
«о
+
CN
*—i
|
i »
2996;
ia Ц7
i
А
т
k
«о
*"*
о в;
со
я
о
8
V
V
g
W
«О
^•*
1
II
н
179

Класс точности
VII-D
Г
К
100
2Q0
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ППЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°}(Т)
70.388
114.081
133.848
134.092
143.411
148.279
151.091
152.849
154.015
154.827
155.413
155.851
156.186
156.447
156.655
156.824
156.962
157.077
157.173
157.255
157.325
157.385
157.437
157.482
157.522
157.558
157.589
157.617
157.642
157.664
157.685
157.703
157-720
157.735
157.749
157.761
157.773
157.784
157.793
157.803
157.811
157.819
157.826
157.833
157.839
157.845
157.851
157.856
157.861
157.865
157.870
157.874
157.877
157.881
157.884
157.888
157.891
157.894
157.896
W7.899
157.901
A-m=V<s)
Ф°(Т)
Дж • К" 1 • моль"
240.795
279.907
311.450
311.996
339.290
362.881
383.575
401.967
418.498
433.500
447.224
459.869
471.588
482.507
492.726
502.329
511.386
519.954
528.085
535.819
543.194
550.241
556.988
563.460
569.678
575.661
581.426
586.989
592 363
597.560
602.592
607.470
612.201
616.795
621.260
625.601
629.827
633.943
637.955
641.867
645.685
649.412
653.054
656.614
660.096
663.503
666.837
670.103
673.303
676.439
679.514
682.531
685.491
688.397
691.250
694.052
696.806
699.513
702.174
704.791
707.365
ГЕПТАСЕРА S7
¦р~1 (s7)
-1
285.948
349.851
399.605
400.433
440.442
473.019
500.323
523.756
544.247
562.437
578.782
593.616
607.191
619.704
631.306
642.120
652.245
661.765
670.746
679.246
687.314
694.991
702.314
709.313
716.017
722.448
728.628
7347.576
740.308
745.841
751.186
756.357
761.364
766.218
770.927
775.500
779.944
784.267
788.475
792.574
796.569
800.466
804.269
807.983
811.612
815.159
818.628
822.023
825.346
828.601
831.791
834.917
837.983
840.990
843.941
846.838
849.683
852.478
855.224
857.923
860.577
А
//°(/')-//°((
кДж • моль
4.515
13.989
26.283
26.531
40.460
55.069
70.049
85.252
100.599
116.044
131.557
147.121
162.724
178.356
194.012
209.686
225.375
241.077
256.790
272.511
288.241
303.976
319.717
335.463
351.214
366.968
382.725
398.485
414 94ft
t I t.X.*tO
430.014
445.781
Ф 461.550
477.321
493.094
508.868
524.644
540.421
556.198
571.977
587.757
603.538
619.319
635.101
650.884
666.668
682.452
698.237
714.022
729.808
745.595
761.381
777.169
792.956
808.744
824.532
840.321
856.110
871.899
• 887.689
903.478
919.268
(г)
r//°((J) = 1811.495
))
l
\%K°{T)
-914.2230
-437.7834
-280.4706
-278 4917
•198.6998
-150.7720
-118,8002
-95.9562
-78.8218
-65.4960
-54.8372
-46.1189
-38.8559
-32.7128
-27.4494
-22.8898
-18.9020
-15.3851
-12.2604
-9.4660
-6.9522
-4.6788
-2.6131
-.7277
.9998
2.5885
4.0545
5.4115
fi fi712
U.U/ 1 *
7.8437
8.9378
9.9610
10.9202
11.82A
12.6689
13.4682
14.2230
14.9371
15.6135
16.2552
16.8649
17.4448
17 9972
18.5239
19.0268
19.5073
19.9670
20.4072
20.8291
21.2339
21.6226
21.9960
22.3552
22,700*
23.0339
23.3548
23.6643
23.9630
24.2515
24.5302
24.7998
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
MOO
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
j
?!
II
+
iO
q
1
J
00
vo
00
00
II
Ф
Таблица 118
i
Л
§
'us S "
Д S т
§ 2 *
^ 2 °°
11 2 ^
О » II
о сл
^ 0
<]
§
о
V. О
5*3 О
О ^
s V
t о
"¦" о
X
го '_,
« w
1 ?
U "
г- *{
180

Класс точности
VII- D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛП
ZOUV
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°<Т)
г
87.070
133.644
155.584
155.857
166.360
171.877
175.073
177.073
178.402
179.327
179.996
180.494
180.876
181.175
181.412
181.604
181.762
181.893
182.003
182.096
182.176
182.244
182.304
182.356
182.402
182.442
182.478
182.509
1А2 ^8
182.564
182.587
182.608
182.627
182.644
182.660
182.674
182.688
182.700
182.711
182.721
182.731
182.740
182.748
182.756
182.763
182.770
182.776
182.782
182.788
182.793
182.798
182.803
182.807
182.811
182.815
182.819
182.822
182.825
182.828
182.832
182.834
*-m = p«(s).|r
Ф°(Л
Дж • К • моль
236.341
283.756
321.324
321.970
354.161
381.845
406.058
427.537
446.818
464.297
480.277
494.990
508.620
521.315
533.191
544.349
554.870
564.821
574.262
583.241
591.801
599.981
607.811
615.321
622.535
629.476
636.165
642.618
fi4fi ftS 1
654.879
660.716
666.372
671.858
677.185
682.362
687.396
692.296
697.068
701.719
706.254
710.680
715.002
719.224
723.350
727.386
731.335
735.200
738.985
742.694
746.329
749.893
753.389
756.820
760.187
763.494
766.742
769.933
773.069
776.153
779.186
782.169
S'iT)
291.333
367.673
425.683
426.646
473.096
510.871
542.514
569.664
593.400
614.470
633.400
650.580
666.302
680.792
694.228
706.751
718.476
729.500
739.900
49.743
759.085
767.975
776.455
784.560
792.321
799.768
806.924
813.812
820 450
826.856
833.045
839.033
844.831
850.451
855.903
861.198
866.345
871.350
876.223
880.969
885.595
890.107
894.511
898.811
903.013
907.120
911.137
915.068
918.916
922.685
926.378
929.998
933.548
937.030
940.447
943,802
947.096
950.332
953.512
956.637
959.710
ОКТАСЕРА Sg (г)
Н°(Т)-Н°@)
кДж • моль
5.499
16.783
31.115
31.403
47.574
64.513
81.874
99.488
117.266
135.155
153.123
171.149
189.218
207.321
225.451
243.602
261.770
279.954
298.148
316.353
334.567
352.788
371.016
389.249
407.487
425.729
443.975
462.224
4ЯЛ 477
•tOV/.t * /
498.732
516.990
535.249
553.511
571.775
590.040
608.307
626.575
644.844
663.115
681.386
699.659
717.932
736.207
754.482
772.758
791.035
809.312
827.590
845.869
864.148
882.427
900.707
918.988
937.268
955.550
973.832
992.114
1010.396
1028.679
1046.962
1065.245
"@) ¦= 2094.
lgA'°(r)
-1055.2806
-504.6781
-322.9170
-320.6302
-228.4515
-173.0904
-136.1644
-109.7838
-89.9989
-74.6135
-62.3088
-52.2452
-43.8625
-36.7729
-30.6994
-25.4385
-20.8379
-16.7810
-13.1769
•9.9541
-7.0552
-4.4339
-2.0523
.1211
2.1124
3.9435
5.6330
7.1966
8.6480
9.9987
11.2590
12.4376
13.5422
14.5796
15.5558
16.4760
17.3449
18.1667
18.9452
19.6837
20.3851
21.0524
21.6878
22.2937
22.8719
23.4246
23.9531
24.4592
24.9443
25.4095
25.8562
26.2854
26.6981
27:0953
27.4778
27.8464
28.2018
28.5449
28.8761
29.1962
29.5056
180 кДж • моль *
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9&ЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
NO
*/">
II
+
|
00
гЗ
со
+
ОО
So
со
о
С"*
VO
со
с*
г-
со
i
•6*
Таб
i
л
§
к
о
о
?
и
о
00
w
О
1
л
i
•
™х
»о
г-*
о
г»
X
!
X
чо
00
лииа 119
i
л
м
к |
00 V
§5 к
и ^
2 §
00 ||
ил со
СО
о
я
о
g
V
V
8
.с
1
о
II
X
181

Класс точности
Ш-В
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.149
29.279
30.176
30.199
31.560
32.827
33.840
34.618
35.214
35.683
36.066
36.394
36.689
36.964
37.230
37.490
37.749
38.006
38.262
38.515
38.765
39.010
39.249
39.480
39.704
39.918
40.124
40.320
40.507
40.684
40.852
41.011
41.162
41.304
41.440
41.568
41.691
41.809
41.922
42.031
42.136
42.239
42.340
42.440
42.538
42.636
42.733
42.830
42.928
43.026
43.124
43.223
43.322
43.423
43.523
43.624
43.726
43.827
43.929
44.031
44.132
K°(T) = p(S) -p(C
Ф°(Л
Дж • К • моль
160.084
180.564
192.320
192.503
201.035
207.746
213.319
218.109
222.321
226.087
229.497
232.615
235.489
238.157
240.647
242.983
245.182
247.262
249.235
251.112
252.903
254.616
256.257
257.833
259.350
260,812
262.222
263.585
264.904
266.182
267.421
268.625
269.794
270.932
272.040
273.119
274.171
275.198
276.200
277.179
278.136
279.073
279.989
280.886
281.765
282.626
283.470
284.298
285.111
285.908
286.692
287.461
288.217
288.961
289.692
290.411
291.118
291.815
292.500
293.176
293.841
ОКСИД СЕРЫ SO
^.p^CSO)
S°(T)
189.784
209.998
221.830
222.016
230.888
238.071
244.149
249.427
254.090
258.266
262.046
265.499
268.679
271.626
274.375
276.953
279.380
281.677
283.856
285.932
287.914
289.811
291.632
293.381
295.066
296,692
298.261
299.779
301.249
302.673
304.056
305.398
306.702
307.971
309.206
310.409
311.582
312.726
313.842
314.932
315.998
317.040
318.059
319.056
320.033
320.990
321.928
322.848
323.751
324.637
325.508
326.362
327.203
328.029
328.841
329.641
330.428
331.203
331.966
332.718
333.459
//°(Л-//°@)
кДж • моль"
2.970
5.887
8.798
8.854
11.941
15.162
18.498
21.923
25.416
28.961
32.549
36.173
39.827
43.510
47.219
50.955
54.717
58.505
62.319
66.158
70.022
73910
77.823
81.760
85.719
89.700
93.703
97.725
101.766
105^826
109.903
113.996
118.105
122.228
126.365
130.516
134.679
138.854
143.040
147.238
151.446
155.665
159.894
164.133
168.382
172.641
176.909
181.187
185.475
189.773
194.080
198.398
202.725
207.062
211.410
215.767
220.134
224.512
228.900
233.298
237.706
(г)
//°@) = 517.000 кДж-моль
ЧК°(Т)
-266.'014
-130.5650
-85.7977
•85.2342
-62.5004
-48.8251
-39.6885
-33.1502
-28:2386
-24.4129
-21.3483
-18.8379
-16.7435
-14.9696
-13.4475
-12.12*2
-10.9710
-9.9499
-9.0416
-8.2284
-7.4960
-6.8329
-6.2297
-5.6787
-5.1734
-4.7082
-4.2786
-3.8807
•3.5110
-3.1667
-2.8452
-2.5443
-2.2621
-1.9969
-1.7473
-1.5118
-1.2893
-1.0788
-.8793
-.6899
-.5100
-.3387
-.1756
-.0200
.1285
.2706
.4064
.5366
.6614
.7811
.8960
1.0065
1.1128
1.9151
1.3136
1.4086
1.5002
1.5886
1.6740
t.7565
1.8363
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
щ
об
II
+
чо
<N
О
+
'«
СО
сч
*о
§
О
1
а
8
со
+
г-
о
о
со
II
ь
Т а б л и
А
§
Ё[ 1-н
X ^°
00 ^
ЧО 11
>w II
«о
* я
11 «о
О об
и г*
п ¦ ?
§ 6
о W
^ с
<]
1
А
о
.
k
ъ
чо
00
о
+
с*
1
<N
СО
о
*~*
ца 120
g
,_,
i
к
п
оо
о
II
о 5
со
2
о
чо
V
V
«о
<t
1
о
II
182

Класс точности
V-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.425
34.442
35.231
35.830
36.271
36.597
36.845
37.038
37.194
37.323
37.433
37.529
37.615
37.694
37.767
37.836
37.901
37.964
38.026
38.086
38.146
38.206
38.265
38.324
38.384
38.444
38.505
38.567
38.630
38.694
38.758
38.824
38.890
38.956
39.023
39.090
39.157
39.224
39.290
39.354
39.416
39.477
39.535
39.590
39.641
39.689
39.732
39.771
39.804
39.832
39.854
39.870
39.880
39.883
39.880
39.870
39.852
39.828
39.797
ОТРИЦАТЕЛЬНЫЙ
/r°(D = p(S) -р(О) -р(е) -р
Ф°(Г)
Дж • К • моль
191.815
192.011
201.261
208.589
214.676
219.891
224.458
228.523
232.187
235.523
238.587
241.419
244.054
246.516
248.82S
251.006
253.067
255.021
256.880
258.652
260.346
261.968
263.523
265.018
266.458
267.845
269.184
270478
271.730
272.943
274.120
275.261
276.370
277.448
278.498
279.520
280.516
281.487
282.435
283.360
284.265
285.149
286.014
286.860
287.689
288.501
289.296
290.076
290.841
291.592
292.328
293.052
293.763
294.461
295.147
295.821
296.485
297.137
297.780
S°(T)
-1
223.567
223.780
233.801
241.730
248.304
253.921
258.824
263.176
267.086
270.637
273.890
276.890
279.674
282.272
284.707
286.999
289.164
291.214
293.163
295.020
296.793
298.490
300.117
301.681
303.185
304.635
306.034
307.386
308.695
309.963
311.192
312.386
313.546
314.674
315.772
316.842
317.886
318.904
319.898
320.869
321.818
322.746
323.654
324.543
325.414
326.267
327.103
327.923
328.727
329.515
330.289
331.048
331.793
332.525
333.244
333.949
334.643
335.324
335.993
ИОН ОКСИДА
'(SO") V,
//Vw/°@)
кДж • моль""
9.467
9.531
13.016
16.570
20.177
23.821
27.493
31.188
34.900
38.626
42.364
46.112
49.869
53.635
57.408 .
61.188
64.975
68.768
72.568
76.373
80.185
84.002
87.826
91.655
95.491
99.332
1 ЛЧ 1 А(\
1 Uu. 1 OU
107.033
110.893
114.759
118.632
122.511
126.397
130.289
134.188
138,094
142.006
145.925
149.851
153.783
157.722
161.666
165.617
169.573
173.535
177.501
181.472
185.447
189.426
193.408
197.392
201.379
205.366
209.354
213.342
217.330
221.316
225.300
229.281
СЕРЫ SO"
(г)
Таблица 121
э@) = 622.200 кДж • Моль
-104.1975
-103.5143
-75.9265
-59.2936
-48.1542
-40.1624
-34.1431
-29.4419
-25.6656
-22.5636
-19.9684
-17.7639
-15.8670
-14.2167
-12.7673
-11.4836
-10.3382
-9.3096
-8.3804
-7.5367
-6.7668
-6.0613
-5.4123
-4.8130
-4.2578
-3.7418
л лл| л
-2.8118
-2.3910
-1.9959
-1.6242
-1.2738
-.9428
-.6296
-.3328
-.0510
.2169
.4719
.7151
.9472
1.1690
1.3812
1.5845
1.7794
1.9665
2.1463
2.3192
2.4856
2.6458
2.8004
2.9495
3.0934
3.2325
3.3670
3.4971
3.6231
3.7452
3.8635
3.9783
Г
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
*н А
§
и Й Т
s? *° i
О О *-н уу
чо О 1 Т
2 "Г " *
я ¦*
II II io 00
* s 2 S
о ,. оЗ
w о °°
VO
О 1-4
ЧО 1
о |
+
Щ к §
8 « S
S m* v
8 к.
а - v
; ' 8
00 « «О
• о ?
г** ел 1
+ ел 2
«о о *
t-H • *—'
СО О
, |
ф
183

Класс точности
IIL-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
?800
5900
6000
С°р(Т)
33.543
36.380
39.842
39.909
43.427
46.490
48.938
50.829
52.282
53.407
54.290
54.993
55.564
56.033
56.426
56.759
57.045
57.295
57.516
57.713
57.891
58.054
58.204
58.343
58.474
58.598
58.717
58.830
58.940
59.047
59.151
59.253
59.353
59.453
59.551
59.650
59.748
59.846
59.945
60.044
60.143
60.244
60.345
60.448
60.551
60.657
60.763
60.871
60.981
61.093
61.206
61.322
61.439
61.558
61.680
61.803
61.929
62.058
62.188
62.321
62.457
K°(T)=p(S) -р2
Ф°(Л
Дж • К" * • моль"
175.640
198.896
212.729
212.948
223.347
231.772
238.944
245.235
250.863
255.967
260.644
264.965
268.984
272.740
276.268
279.594
282.742
285.728
288.570
291.282
293.874
296.357
298.740
301.031
303.237
305.364
307.417
309.402
311.323
313.184
314.989
316.741
318.443
320.099
321.710
323.279
324.808
326.299
327.755
329.176
330.565
331.922
333.250
334.550
335.822
337.069
338.290
339.488
3*0.663
341.816
342.947
344.059
345.150
346.223
347.277
348.314
349.334
350.338
351.326
352.298
353.256
ДИОКСИД
СО) -^(SO^
S°(T)
208.932
232.947
248.110
248.358
260.327
270.358
279.060
286.752
293.638
299.864
305.538
310.747
315.557
320.024
324.191
328.095
331.768
335.234
338.515
341.630
344.595
347.424
350.128
352.718
355.204
357.594
359.894
362.112
364.254
366.324
368.328
370.269
372.152
373.979
375.756
377.483
379.165
380.803
382.401
383.959
385,481
386.967
388.420
389.841
391.232
392.594
393.92S
395.236
396.519
397.777
399.013
400.226
401.418
402.589
403.741
404.874
405.989
407.086
408.166
409.230
410.279
СЕРЫ SO2
) Arl/
UoO)-II°@)
кДж • моль
3.329
6.810
10.548
10.623
14.792
19.293
24.069
29.062
34.220
39.507
44.894
50.359
55.888
61.469
67.092
72.752
78.442
84.159
89.900
95.662
101.442
107.239
113.052
118.880
124.721
130.574
136.440
142.318
148.206
154.105
160.015
165.936
171.866
177.806
183.756
189.716
195.686
201.666
207.656
213.655
219.664
225.684
231.713
237.753
243.803
249.863
255.934
262.016
268.108
274.212
280.327
286.453
292.591
298.741
304.903
311.077
317.264
323.463
329.675
335.901
342.140
(г)
э@) = 1062.615
-545.9680
-267.2642
-175.2232
-174.0648
-127.3416
-99.2469
-80.4838
-67.0619
-56.9829
-49.1353
-42.8513
-37.7056
-33.4142
-29.7805
-26.6640
-23.9613
-21.5951
-19.5062
-17.6485
-15.9855
-14.4880
-ЬЗ.1326
-11.8998
-10.7737
-9.7410
-8.7905
-7.9128
-7.0997
-6.3444
-5.6408
-4.9839
-4.3691
-3.7925
-3.2505
-2.7403
-2.2590
-1.8042
-1.3738
-.9658
-.5787
-.2107
.1395
.4732
.7916
1.0956
1.3862
1.6643
1.9307
2.1862
2.4313
2.6667
2.8931
3.1108
3.3204
3.5223
3.7170
3.9049
4.0862
4.2614
4.4307
4.5944
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 122
Т
А
А «?
2 Д Т
к 1 !
а оо •
s ? т
Os <N Я &
* а к д
VO | /-, РЧ
II II hd ЧО
11 " * со
**ч /-s ^* C-J
"* ° 2 «
л 00
и й II
•ч CN
§ - °«
° ©
< %
+
Г- А
*-н О
СО Jg
+ 7
н . О
г- ^ *
? •=* о
я й v
° ^ К
1 ^ \/
JS /N О
? Я S
5 3 и
X 7 2
+ 1 о
оо X р-ч
со vS
*-¦ ? "
СО "™^
II ^"
184

Класс точности
V-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
41.795
41.877
45.902
48.934
51.102
52.647
53.764
54.589
55.211
55.689
56.063
56.362
56.602
56.800
56.963
57.099
57.215
57.313
57.398
57.471
57.536
57.593
57.643
57.689
57.731
5V.770
с 7 ftOfi
О 1 .OUU
57.841
57.875
57.908
57.941
57.975
58.009
58.045
58.081
58.119
58.159
58.201
58.245
58.290
58.338
58.388
58.439
58.493
58.548
58.605
58.665
58.725
58.787
58.851
58.916
58.981
59.048
59.116
59.184
59.254
59.323
59.393
59.463
ОТРИЦАТЕЛЬНЫЙ
К°(Т)= p(S) •
Ф°(Г)
Дж • К • моль
219.822
220.045
230.696
239.395
246.831
253.362
259.202
264.493
269.333
273.796
277.937
281.800
285.422
288.831
292.050
295.100
297.998
300.758
303.394
305.914
308.331
310.651
312.881
315.030
317.102
319.103
321.037
322.909
324.723
326.482
328.189
329.848
331.461
333.030
334.559
336.048
337.501
338.918
340.301
341.653
342.974
344.266
345.530
346.768
347.979
349.167
350.331
351.472
352.592
353.691
354.769
355.829
356.870
357.892
358.8Э8
359.886
360.859
361.816
362.758
Р2(О) -р{е)
S°(T)
-1
255.875
256.134
268.755
279.341
288.466
296.466
303.573
309.955
315.740
321.026
325.888
330.388
334.574
338.486
342.157
345.615
348.882
351.978
354.920
357.722
360.397
362.956
365.408
367.762
370.026
372.205
374.307
37б!з36
378.298
380.196
382.035
383.818
385.549
387.232
388.867
390.459
392.009
393.521
394.995
396.434
397.839
399.212
400.555
401.869
403.155
404.415
405.649
406.860
408.047
409.211
410.355
411.478
412.581
413.665
414.731
415.779
416.810
417.825
418.823
ИОН ДИОКСИДА СЕШ SO2"
•p'Hso;) лгн
H°{T)-H°@)
кДж • моль
10.749
10.827
15.223
19.973
24.981
30.173
35.496
40.916
46.408
51.953
57.542
63.164
68.812
74.483
80.171
85.874
91.590
97.317
103.052
108.796
114.546
120.303
126.065
131.831
137.602
143.377
149.156
154.939
160.724
166.513
172.306
178.102
183.901
189.704
195.510
201.320
207.134
212.952
218.774
224.601
230.432
236.268
242.110
247.956
253.808
259.666
265.529
271.399
277.275
283.156
289.045
294.940
300.841
306.749
312.664
318.586
324.515
330.451
336.393
э@) = 1168.415
igtfV)
-194.1250
•192.8458
-141.2181
-110.1322
-89.3428
-74.4503
-63.2506
-54.5173
-47.5134
-41.7691
-36.9711
-32.9018
-29.4060
-26.3696
-23.7069
-21.3523
-19.2548
-17.3740
-15.6777
•14.1397
-12.7385
•11.4564
-10.2787
-9.1930
-8.1886
-7.2566
-6.3894
-5.5803
-4.8235
-4.1140
-3.4475
-2.8200
-2.2282
-1.6690
-1.1397
-.6380
-.1616
.2913
.7225
1.1335
1.5258
1.9007
2.2593
2.6027
2.9319
3.2477
3.5511
3.8427
4.1233
4.3934
4.6538
4.9048
5.1471
5.3810
5.6071
5.8258
6.0373
6.2421
6.4406
(г)
к Дж • моль ~
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
JZOXtVJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<У\
*о
О
Tt
VO
II
4-
Т*
vS
т—1
»о
+
CS
3
О
о
1
1
*о
VO
+
«о
>г
<о
00
со
о
Таблица 123
Т
А
К
т 1
А
1 1 т
& § 1
S ! а
8 ¦ к
т я «
~ - я
° 8 «
U <N II
О 1 М °„ *
W О Со
о" 1
<
1
IfO
2
1 /-Ч
ж g
й s
« V
1 ь
<Ч V
? о
+ о
с* «о
Г*» ^н
1 ?
? X
О ^"^
об
185

Класс точности
V-C
Т
К
100
200
298.15
300
400
500
600
700
аоо
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9А00
ZOI/U
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.061
42.283
50.619
50.760
57.646
63.086
67.246
70.385
72.758
74.568
75.967
77.064
77.937
78.639
79.213
79.685
80.079
80.411
80.692
80.933
81.140
81.320
81.476
81.614
81.736
81.843
81.939
82.025
82.102
82.171
82.234
82.291
82.342
82.390
82.433
82.472
82.509
82.542
82.573
82.602
82.628
82.653
82.676
82.697
82.717
82.736
82.753
82.769
82.785
82.799
82.813
82.826
82.838
82.849
82.860
82.870
82.880
82.889
82.897
82.906
82.914
K'°(T) = p(S) -р3
Ф°(Т)
Дж -К • моль" 1
178.718
202.367
217.233
217.476
229.294
239.279
248.043
255.908
263.065
269.644
275.736
281.412
286.727
291.724
296.439
300.903
305.142
309.176
313.025
316.704
320.229
323.612
326.863
329.992
333.009
335.920
338.734
341.456
ода 0Q9
346.647
349.126
351.534
353.874
356.151
358.367
360.526
362.630
364.682
366.685
368.641
370.553
372.421
374.248
376.037
377.787
379.502
381.182
382.829
384.444
386.028
387.583
389.109
390.607
392.080
393.526
394.948
396.346
397.721
399.074
400.405
401.715
ТРИОКСИД СЕРЫ SO:
(О) .p-y(SO3)
5°G)
212.084
237.946
256.436
256.750
272.332
285.805
297.692
308.305
317.866
326.545
334.477
341.771
348.515
354.782
360.632
366.113
371.269
376.134
380.738
385.108
389.265
393.228
397.015
400.639
404.115
407.454
410.666
413.760
416.744
419^627
422.414
425.111
427.724
430.259
432.719
435.110
437.433
439.695
441.896
444.041
446.133
448.173
450.165
452.111
454.013
455.872
457.690
459.470
461.213
462.920
464.593
466.233
467.841
469.419
470.968
472.489
473.982
475.449
476.891
478.308
479.701
V
//°G')-//°@)
кДж • моль
3.337
7.116
11.688
11.782
17.215
23.263
29.789
36.678
43.841
51.211
58.741
66.395
74.146
81.976
89.870
97.815
105.804
113.829
121.885
129.966
138.070
146.193
154.333
162.488
170.656
178.835
187.024
195.222
ппо AOQ
ZyJO.^tZo
211.642
219.862
228.089
236.320
244.557
252.798
261.043
269.292
277.545
285.801
294.060
302.321
310.585
318.852
327.120
335.391
343.664
351.938
360.214
368.492
376.771
385.052
393.333
401.617
409.901
418.186
426.473
434.760
443.049
451.338
459./ч;28
467.919
1<г>
\0) -1405.287
lgK°(T)
-719.1771
-350.1845
-228.2637
-226.7291
-164.8267
-127.6047
-102.7484
-84.970$
-71.6232
-61.2331
-52.9152
-46.1058
-40.4284
-35.6225
-31.5016
-27.9290
-24.8022
-22.0424
-19.5888
-17.3930
-15.4164
-13.6277
-12.0013
-10.5161
-9.1545
-7.9016
-6.7449
-5.6736
д fiTftft
-*г.О / ОО
-3.7524
-2.8876
-2.0784
-1.3197
-.6068
.0642
.6971
1.2949
1.8606
2.3966
2.9052
3.3886
3.8485
4.2366
4.7044
5.1034
5.4848
5.8497
6.1992
6.5343
6.8558
7.16*45
7.4613
7.7468
8.0216
8.2863
8.5416
8.7878
9.0254
9.2550
9.4770
9.6916
кДж • моль 1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ZoVKJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
T а б
i
ё
чс
со
оо 2
•§ I
° ?
11 II
* s
о
U
го
о
с/э
о
а:
+
'х V
0529
юль"
CN
'х •
СО vj
CN jg.
со ЕЗ
гм X
я Я
О т*
1 ON
CN J?
2 ON
? CN
+ 1
со x
IO CO
CO CO
г-: <ч
r-i »o
^t" CNJ
II ¦+¦
о
•е-
л и
7
>Л
о
к
1-4
§
ON
uo
ON
со
1
II
00
ON
CS
с
(~\
\J
С/3
0
<\
ц а 124
1
1
к
CN
ON
со
CN
II
О а*
* со*
я
о
g
чо
V
V
о
о
1
о
II
186

Класс i очное ти
V-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
34.286
39.425
44.114
44.191
47.797
50.379
52.201
53.497
54.436
55.131
55.656
56.061
56.379
56.632
56.836
57.004
57.143
57.259
57.358
57.442
57.514
57.576
57.630
57.678
57.720
57.757
57.790
57.819
С7 QAfi
57.869
57.891
57.910
57.928
57.944
57.959
57.972
57.985
57.996
58.007
58.017
58.026
58.034
58.042
58.049
58.056
58.062
58.068
58.074
58.079
58.084
58.088
58.093
58.097
58.101
58.104
58.108
58.111
58.114
58.117
58.120
58.123
К°(Т)= p2(S)
Ф°(Л
Дж • К • моль
191.491
215.103
229.529
229.760
240.814
249.850
257.560
264.315
270.338
275.780
280.747
285.318
289.552
293.497
297.189
300.660
303.935
307.035
309.977
312.778
315.450
318.004
320.451
322.799
325.056
327.228
329.322
331.344
QOQ OQ7
ooo.Zvf
335.187
337.018
338.793
340.515
342.188
343.814
345.395
346.935
348.436
349.898
351.325
352.717
354.077
355.406
356.705
357.976
359.220
360.438
361.630
362.799
363.945
365.068
366.171
367.253
368.315
369.358
370.383
371.390
372.380
373.353
374.310
375.252
ОКСИД
р(О) -p'l(S2O)
224.929
250.203
266.854
267.127
280.361
291.320
300.676
308.826
316.034
322.488
328.325
333.649
338.541
343.064
347.269
351.196
354.880
358.348
361.624
364.727
367.675
370.483
373.163
375.725
378.181
380.538
382.804
384.985
OQ7 fiftQ
оо/ .иоэ
389.119
391.081
392.980
394.819
396.601
398.332
400.012
401.645
403.234
404.781
406.288
407.756
409.190
410.588
411.954
413.288
414.593
415.870
417.118
418.341
419.539
420.712
421.862
422.991
424.097
425.183
426.250
427.296
428.325
429.336
430.329
431.306
ДИСЕРЫ S20
V
//°G')-// °@)
кДж • моль"
3.344
7.020
11.128
11.210
15.819
20.735
25.869
31.158
36.557
42.037
47.578
53.164
58.787
64.438
70.112
75.804
81.512
87.232
92.963
98.703
104.451
110.205
115.966
121.731
127.501
133.275
139.052
144.833
1 f\fi fii ft
1OU.D1Q
156.402
162.190
167.980
173.772
179.566
185.°S1
191.157
196.955
202.754-
208.554
214.356
220.158
225.961
231.764
237.569
243.374
249.180
254.987
260.794
266.601
272.410
278.218
284.027
289.837
295.647
301.457
307.268
313.079
318.890
324.701
330.513
336.325
(г)
°М) -=- 839.553
\gK°(T)
-429.8571
-209.4750
-136.6563
-135.7396
-98.7593
-76.5172
-61.6600
-51.0307
-43.0477
-36.8313
-31.8529
-27.7757
-24.3750
-21.4951
-19.0247
-16.8821
-15.0060
-13.3494
-11.8758
-10.5565
-9.3683
-8.2925
-7.3139
-6.4197
-5.5995
<-4.8444
-4.1468
-3.5005
.9 AQQft
'?•0990
-2.3402
-1.8174
-1.3280
-.8688
-.4370
-.0303
.3535
.7163
1.0598
1.3856
1.6949
1.9890
2.2691
2.5361
2.7909
3.0344
3.2674
3.4904
3.7041
3.9092
4.1061
4.2954
4.4774
4.6526
4.8214
- 4.9841
5.1411
5.2927
5.4391
5.5806
5.7175
5.8499
кДж • моль
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
Ofififi
zouv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
©
00
Ii
+
7,,
со
00
•«¦
*¦?
*-*
+
'и
r*
CO
00
00
о
о
о
1
со
а
+
со
о
&
СО
0
Таблица 125
i
л
1 л S
* * 1
О} ' 1
% Т *
5 » *
* Q *
и Ьй г-
° ~- 2
оо •*
<Э и П
ы «ч о 05
со О ^
о со
* oW
< >
1
л
*¦ о
1 о
1 s
(Г) V
х v
+ §
т О
Р То
ко —
1 с
X
<Ч II
ОО Н
00 s~'
+
187

Класс точности
Н-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
29.967
32.620
32.479
32.467
31.769
31.346
31.287
31.507
31.898
32.372
32.873
33.366
33.834
34.270
34.671
35.037
35.373
35.679
35.961
36.221
36.462
36.687
36.899
37.099
37.290
37.473
37.651
37.824
37.995
38.165
38.335
38.506
38.680
38.857
39.039
39.226
39.419
39.618
39.824
40.037
40.258
40.486
40.721
40.963
41.212
41.467
41.728
41.993
42.263
42.536
42.811
43.089
43.368
43.645
43.923
44.199
44.471
44.740
45.007
45.266
45.519
К°(Т)= p(S) •
Ф°(Г)
Дж • К • моль
133.275
152.938
164.928
165.117
173.964
180.880
186.544
191.339
195.500
199.180
202.485
205.488
208.243
210.792
213.165
215.387
217.477
219.451
221.323
223.103
224.800
226.422
227.977
229.469
230.904
232.286
233.620
234.908
236.155
237.362
23S.533
239.670
240.774
241.848
242.893
243.912
244:905
245.874
246.820
247.745
248.648
249.533
250.399
251.247
252.078
252.893
253.693
254.478
255.248
256.006
256.750
257.482
258.202
258.911
259.609
260.296
260.973
261.640
262.298
262.946
263.586
гидрид
р(П) 'P~l(SE)
s°m
-1
И
СЕРЫ
SH(r)
Д №(()) = 351.000 кДж • моль
'(О)
кДж • моль
160.616
182.398
195.445
195.646
204.888
211.925
217.630
222.466
226.698
230.482
233.918
237.075
239.998
242.724
245.278
247.683
249.955
252.109
254.156
256.108
257.972
259.756
261.468
263.113
264.696
266Я22
267.695
269.119
/\МД Л ДЛ
270.498
271.834
273.131
274.391
275.616
276.809
277.971
279.106
280.214
281.296
282.355
283.393
284.409
285.406
286.384
287.345
288.290
289.219
290.133
291.034
291.921
292.795
293.657
294.508
295.347
296.176
296.994
297.803
298.602
299.392
300.172
300.944
301.707
2.734
5.892
9.099
9.159
12.370
15.522
18.651
21.789
24.958
28.171
31.434
34.746
38.106
41.511
44.959
48.445
51.965
55.518
59.100
62.710
66.344
70.001
73.681
77.381
81.100
84.839
88.595
92.369
96.160
99.968
103.793
107.635
111.494
115.371
119.266
123.1*79
127.111
131.063
135.035
139.028
143.043
147.080
151.140
155.225
159.334
163.468
167.627
171.813
176.026
180.266
184.534
188.829
193.152
197.503
201.882
206.289
210.723
215.184
219.673
224.187
228.727
lgK°(T)
-180.2208
-88.0570
-57.6129
-57.2296
-41.7629
-32.4507
-26.2212
-21.7567
-18.3978
-15.7776
-13.6755
-11.9511
-10.5107
-9.2891
-8.2397
-7.3285
-6.5296
-5.8235
-5.1947
-4.6313
-4.1233
-3.6631
-3.2440
-2.8609
-2.5092
-2.1852
-1.8857
-1.6081
1 ъ л лл
-1.о4УУ
-1.1093
-.8844
-.6738
-.4761
-.2902
-.1151
.0503
.2066
.3546
.4950
.6282
.7550
.8756
.9906
1.1004
1.2052
1.3054
1.4013
1.4932
1.5813
1.6658
1.7470
1.8250
1.9001
1.9723
2.0418
2.1088
2.1734
2.2357
2.2959
2.3540
2.4102
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1*800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
р
со
со
II
+
00
•00
о
со
о
!
00
о
о
р
о
+
в
«о
Ол
3
ON
<rs
VO
<4
II
с»
Ф
Таб
i
A
6
n
On
i-H
00
ON
»—1
II
о
X
о
1
i
•p
k
H
CO
t-H
+
X
<N
00
c*.
00
|
H
r^
CO
лица 126
A
О
«5
|
*=f §
CN
Г- _
CN |
S *?
V *
* g
Cog
SB *>
О
>
Я
о
V
V
о
о
•О
9
и
н
188

Класс точности
И-Н
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<гЛт)
29.146
29.147
29.240
29.504
29.959
30.551
3L209
31.874
32.511
33.103
33.643
34.130
34.568
34.962
35.317
35.639
35.931
36.198
36.443
36.670
36.882
37.080
37.268
37.446
37.617
37.782
37.943
38.100
38.254
38.408
38.561
38.714
38.869
39.027
39.187
39.350
39.517
39.688
39.864
40.045
40.231
40.422
40.618
40.819
41.025
41.235
41.450
41.670
41.893
42.118
42.347
42.578
42.811
43.045
43.280
43.514
43.748
43.981
44.211
ОТРИЦАТЕЛЬНЫЙ
A'°f7') = p(S) -I
Ф°(Л
Дж • К • моль
157.527
157.706
166.055
172.542
177.858
182.371
186.303
189.796
192.944
195.817
198.461
200.915
203.205
205.356
207.382
209.301
211.123
212.858
214.515
216.101
217.622
219.084
220.491
221.847
223.157
224.424
225 650
226.838
227.991
229.110
230.199
231.258
232.289
233.294
234.274
235.230
236.164
237.077
237.970
238.843
239.698
240.536
241.357
242.162
242.951
243.726
244.487
245.235
245.970
246.692
247.402
248.101
248.789
249.467
250.134
250.791
251.439
252.078
252.708
ЛН).р(е) -i
S°(T)
-i
186.525
186.705
195.100
201.650
207,066
2! 1.728
215.850
219.564
222.956
226.083
228.986
231.699
234.244
236.643
238.911
241.062
243.108
245.057
246.920
248.704
250.415
252.059
253.641
255.166
2*56.638
258.061
259.438
260.772
262.066
263.323
264.545
265.734
266.892
268.021
269.122
270.198
271.250
272.279
273.286
274.272
275.239
276.188
277.120
278.035
278.935
279.819
280.689
281.546
282.391
283.222
284.043
284.852
285.650
286.437
287.215
287.984
288.743
289.493
290.234
ИОН ГИДРИДА СЕРЫ SH
^(SH") Аун
Н°(Т)-Н°@)
кДж • моль
8.646
8.700
11.618
14.554
17.525
20.550
23.638
26.792
30.011
33.293
36.630
40.019
43.455
46.932
50.446
53.994
57.573
61.179
64.811
68.467
72.145
75.843
79.561
83.296
87.050
90.820
94.606
98.408
102.226
106.059
109.907
113.771
117.650
121.545
125.456
129.383
133.326
137.286
141.264
145.260
149.273
153.306
157.358
161.430
165.522
169.635
173.770
177.926
182.104
186.305
190.529
194.776
199.046
203.339
207.656
211.996
216.361
220.748
225.158
" (г)
70) = 573.060 кДж- моль *
lgtfV)
-96.1255
-95.4952
-70.0242
-54.6477
-44.3357
-36.9275
-31.3404
-26.9715
-23.4581
-20.5690
-18.1495
-16.0925
-14.3211
-12.7788
-11.4233
-10.2220
-9.1495
-8.1859
-7.3149
-6.5236
-5.8012
-5.1390
-4.5295
-3.9665
-3.4448
-2.9598
-9 ^077
-2.0851
-1.6891
-1.3173.
-.9674
-.6375
-.3258
-.0308
.2489
.5143
.7668
1.0071
1.2363
1.4551
1.6641
1.8642
2.0558
2.2395
2.4159
2.5853
2.7482
2.9049
3.0559
3.2014
3.3418
3.4772
3.6081
3.7346
3.8569
3.9753
4.0900
4.2011
4.3088
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
ZOUvJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ос
о
го
+
гч
г-
*о
о
6
О
го
го
ГЧ
О
о
6
1
ON
сч
о
г*-
сч
+
1О
00
*о
WO
сч
II
ь
Т п К
I а о
i
-а
'-Ч
сч
ОС
II
•—
W
о
л
-
п
го
О
ON
ГО
+
чо
о
СО
1
Г^
ЧО
гч
об
го
л и
1
0
=3
ос
ГО
ОС
ос
и
-—
ъс
—;
ОС
QN
о
<1
и а л "I
I
т
ч
о
г^
О Д
>)
2
О
О
О
чС
V
V
о
о
to
^*
1
о
к.
II
189

Класс точности
И-С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ср(Т)
33.293
33.441
34.248
34.270
35.661
37.291
39.052
40.873
42.673
44.385
45.968
47.405
48.694
49.845
50.868
51.779
52.590
53.316
53.967
54.553
55.084
55.566
56.007
56.412
56.785
57.131
57.453
57.754
58.036
58.302
58.553
58.792
59.019
59.236
59.444
59.644
59.837
60.024
60.204
60.379
60.550
60.716
60.879
61.038
61.194
61.347
61.497
61.645
61.791
61.935
62.077
62.218
62.357
62.494
62.631
62.767
62.901
63.035
63.168
63.300
63.432
К°(Т)= р2(Н)
Ф°(Т)
Дж • К • моль
136.034
159.008
172.297
172.504
182.161
189.756
196.068
201.511
206.324
210.661
214.625
218.286
221.696
224.894
227.909
230.764
233.479
236.067
238.542
240.915
243.194
245.387
247.500
249.541
251.514
253.424
255.275
257.070
258.814
260.509
262.158
263.763
265.328
266.853
268.342
269.795
271.215
272.603
273.961
275.290
276.592
277.866
279.115
280.340
281.541
282.720
283.878
285.014
286.130
287.228
288.306
289.367
290.410
291.436
292.447
293.442
294.421
295.386
296.337
297.273
298.197
СЕРОВОДОРОД H2S
• p(S) . р'1
-1
169.115
192.217
205.694
205.906
215.947
224.077
231.030
237.186
242.762
247.888
252.648
257.098
261.279
265.223
268.955
272.496
275.864
279.074
282.141
285.074
287.886
290.586
293.181
295.680
298.088
300.414
302.661
304.835
306.940
308.982
310.963
312.886
314.756
316.576
318.348
320.073
321.756
323.399
325.002
326.568
328.099
329.596
331.061
332.495
333.900
335.277
336.627
337.95 f
339.251
340.526
341.779
343.010
344.219
345.408
346.578
347.728
348.860
349.975
351.072
352.153
353.218
(H2s> ьгн
WYO-АЛО)
кДж • моль
3.308
6.642
9.957
10.021
13.514
17.161
20.977
24.973
29.151
33.505
38.023
42.693
47.499
52.428
57.464
62.597
67.817
73.113
78.477
83.904
89.386
94.919
100.498
106.119
111.779
117.475
123.205
128.965
134.755
140.572
146.415
152.282
158.173
164.085
170.020
175.974
181.948
187.941
193.953
199.982
206,028
212.092
218.172
224.267
230.379
236.506
242.648
248.805
254.977
261.163
267.364
273.579
279.807
286.050
292.306
298.576
304.860
311.156
317.466
323.790
330.126
(г)
э@) = 724.530кДж- моль
-371.7600
-181.4616
-118.5372
-117,7446
-85.7488
-66.4742
-53.5770
-44.3335
-37.3796
-31.9559
-27.6060
-24.0388
-21.0600
-18.5347
-16.3664
-14.4843
-12.8350
-11.3778
-10.0809
-8.9191
-7.8724
-6.9245
-6.0618
-5.2735
-4.5502
-3.8843
-3.2690
-2.6990
-2.1692
-1.6757
-1.2147
-.7832
-.3784
.0021
.3604
.6984
1.0179
1.3202
1.6068
1.8788
2.1374
2.3834
2.6178
. 2.8415
3.0550
3.2592
3.4546
3.6417
3.8211
•3.9932
4.1585
4.3174
4.4702
4.6173
4.7589
4.8955
5.0272
5.1543
5.2771
5.3957
5.5104
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ЧО
Г*
4.Q
со
II
<
+
1
Н
с-»
00
ЧО
о
о
V
со
00
со
г-
о
о
со
00
о
00
CN
II
Ф
Т а б л и
А
~ч О
Л
1 а
! i
ЧО 1
^ II
т я
II кг»
О об
ON
сч
S ^
§
§
т
со
СО
+
с*
н
00
со
ЧО
ЧО
1
Н
ЧО
00
+
ца 128
Т
§
т
V
00
СО
II
о а!
я
О
8
О
V
V
§
о
II
190

Класс точности
VI-D
СЕРНАЯ КИСЛОТА H2SO4
Таблица 129
• p(S)-p4(O) -р ^H.SOJ д я°@) - 2412.985 кДж • моль
-1
Ф°(Т)
S°(T)
Дж • К • моль
H°(T)-M°@)
кДж • моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
42.546
66.800
84.399
84.687
98.234
108.335
115.823
121.499
125.957
129.586
132.625
135.221
137.466
139.425
141.144
142.658
143.996
145.182
146.236
147.175
148.015
148.766
149.441
150.049
150.598
151.094
151.544
151.954
152.327
152.668
152.980
153.266
153.529
153.771
153.995
154.201
154.393
154.570
154.735
154.888
155.031
155.165
155.290
155.407
155.516
155.619
155.715
155.806
155.892
155.972
156.048
156.120
156.188
156.253
156.314
156.372
156.426
156.479
156.528
156.575
156.620
196.494
223.820
243.805
244.148
261.400
276.676
290.478
303.100
314.739
325.543
335.629
345.087
353.994
362.413
370.396
377.987
385.224
392.139
398.760
405.112
411.216
417.092
422.756
428.222
433.505
438.616
443.567
448.366
453.024
457.548
461.947
466.226
470.392
474.451
478.408
482.269
486.037
489.718
493.315
496.832
500.272
503.639
506.936
510.166
513.331
516.433
519.476
522.462
525.392
528.269
531.095
533.871
536.599
539.280
541.917
544.511
547.063
549.574
552.047
554.481
556.878
231.777
269.058
299.175
299.697
326.007
349.069
369.516
387.815
404.341
419.393
433.208
445.973
457.838
468.920
479.317
489.107
498.358
507.124
515.453
523.385
530.956
538.196
545.132
551.789
558.187
564.345
570.280
.576.007
581.540
586.891
592.072
597.093
601.963
606.692
611.285
615.752
620.099
624.332
628.456
632.477
636.400
640.230
643.971
647.626
651.200
654.696
658.118
661.468
664.749
667.964
671.116
674.207
677.239
680.215
683.136
686.005
688.823
691.592
694.314
696.990
699.622
3.528
9.048
16.508
16.665
25.843
36.196
47.422
59.301
71.682
84.465
97.580
110.975
124.612
138.459
152.489
166.681
181.015
195.475
210.047
224.718
239.479
254.318
269.229
284.204
299.237
314.322
329.454
344.630
375.094
390.376
405.689
421.029
436.394
451.782
467.192
482.622
498.070
513.536
529.017
544.513
560.023
575.546
591.080
606.627
622.184
637.750
653.326
668.911
684.504
700.106
715.714
731.330
746.952
762.580
778.214
793.854
809.500
825.150
840.805
856.465
-1233.0947
-598.7949
-389.1637
-386.5248
-280.0810
-216.0738
-173.3293
-142.7563
-119.8018
-101.9326
-87.6271
-75.9158
-66.1519
-57.8871
-50.8011
-44.6585
-39.2830
-34.5396
-30.3230
-26.5502
-23.1550
-20.0832
-17.2911
-14.7420
-12.4057
10.2567
-8.2734
-6.4373
-4.7327
-3.1460
-1.6655
-.2808
1.0171
2.2360
3.3830
4.4642
5.4850
6.4504
7.3648
8.2322
9.0559
9.8393
10.5852
11.2963
11.9749
12.6232
13.2432
13.8367
14.4054
14.9507
15.4742
15.9770
16.4604
16.9255
17.3733
17.8047
18.2207
18.6221
19.0095
19.3837
19.7455
100
298.1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
П
?
о
?
ON
II
II
О
О
со
00
On
О
On
On
О
оо 7
го 1-4*
г*-
S
0.03
1
1
о
On
ON
r-i
+
г-
о
ON
X
.372
г*
го
+
ъ
О
-94,
VO
оо
о
о
S
V
V
§
<t
1
о
II
191

Класс точности
IV-E
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.995
33.409
35.180
35.202
36.094
36.604
36.929
37.156
37.326
37^400
37.573
37.671
37.759
37.841
37.918
37.992
38.064
38.135
38.206
38.277
38.348
38.421
38.494
38.570
38.647
38.726
38.807
38.890
38.975
39.061
39.149
39.238
39.327
39.416
39.505
39.592
39.677
39.760
39.838
39.913
39.982
40.046
40.103
40.153
40.196
40.231
40.258
40.276
40.285
40.286
40.278
40.261
40.235
40.200
40.157
40.105
40.046
39.979
39.904
39.822
39.734
K°(T) = p(S) •
Ф°(Л
Дж • К • моль
160.419
180.989
193.407
193.603
202.888
210.280
216.436
221.716
226.341
230.458
234.169
237.547
240.648
243.514
246.179
248.670
251.007
253.209
255.292
257.267
259.145
260.936
262.647
264.285
265.857
267.368
268.821
270.223
271.576
272.883
274.149
275.374
276.563
277.717
278.838
279.928
280.989
282.023
283.030
284.013
284.972
285.909
286.824
287.719
288.595
289.452
290.291
291.113
291.919
292.709
293.483
294.243
294.989
295.722
296.442
297.148
297.843
298.526
299.197
299.857
300.507
ФТОРИД СЕРЫ SF (г)
p(F) 'P~\SF)
189.556
211.457
225.170
225.388
235.650
243.764
250.468
256.179
261.152
265.556
269.509
273.095
276.377
279.402
282.209
284.828
287.282
289.592
291.774
293.841
295.806
297.679
299.468
301.181
302.824
304.403
305.924
307.390
308.806
310.175
311.501
312.786
314.033
315.244
316.423
317.569
318.685
319.774
320.835
321.871
322.882
323.870
324.836
325.780
326.704
327.608
328.492
329.358
330.206
331.037
331.851
332.648
333.430
334.196
334.947
335.683
336.405
337.113
337.808
338.489
339.158
Таблица 130
A,.//°@) = 337.260 кДж- моль 1
H°(T)—H°U))
кДж • моль
; lgK°(T)
2.914 -172.2472
6.094 -83.7081
9.470 -54.4495
9.535 -54.0812
13.105 -39.2176
16.742 -30.2740
20.420 -24.2970
24.124 -20.0186
27.849 -16.8037
31.588 -14.2989
35.340 -12.2918
39.103 -10.6472
42.874 -9.2747
46.654 -8.1118
50.442 -7.1138
5Ф.238 -6.2477
58.040 -5.4890
61.850 -4.8187
65.667 -4.2223
69.492 -3.6880
73.323 -3.2066
77.161 -2.7706
'81.007 -2.3737
84.860 -2.0110
88.721 -1.6782
92.590 -1.3717
96.466 -1.0884
100.351 -.8258
104.244 -.5818
108.146 -.3543
112.057 -.1418
115.976 .0572
119.904 .2440
123.841 .4197
127.787 .5851
131.742 .7413
135.706 .8890
139.678 1.0288
143.658 1.1614
147.645 1.2873
151.640 1.4070
155.641 1.5210
159.649 16297
163.662 1.7334
167.679 1.8326
171.700 1.9274
175.725 2.0181
179.752 2.1051
183.780 2.1885
187.808 2.2687
191.836 2.3456
195.863 2.4197
199.888 2.4909
203.910 2.5596
207.928 2.6257
211.941 2.6896
215.948 2.7512
219.949 2.8107
223.944 2.8682
227.930 2.9239
231.908 2.9777
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
т
§
Т 2 7
I & I
ел «¦ 2 ~
ОО 1—^. rj" t>
О «О
О т-1 vy
* ° II *
*** оо С^
11 r-i Ъ4 g
^ || «Л ЧО
о °°'
Os ||
С ™
О v.^
1
Н
С* *н
OJ 1
2 1
00 х Я
Os * ^
1 ъ v
1 OS
н J V
JEj , Я
с**- с*
• ч© 1
ОО |А Q
со ^ 2
Г"- ^ч
S 00 II
^- о н
3s f—t N-'
CO "I"
II 1
о
192

Класс точности
IV-G
ОТРИЦАТЕЛЬНЫЙ ИОН ФТОРИДА СЕРЫ SF" (г)
Таблица 131
K°(T) = p(S) -p(F) -p(e) p^iSF')
э@) = 577.260 кДж • моль

Ф°(Л
S°(T)
Дж • К • моль
Н°(Т)-М°@)
кДж * моль
-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
31.769
31.803
33.450
34.618
35.422
35.990
36.406
36.722
36.971
37.175
37.346
37.495
37.628
37.748
37.860
37.966
38.067
38.165
38.261
38.357
38.452
38.547
38.643
38.739
38.836
38.933
39.029
39.124
39.218
39.309
39.396
39.478
39.555
39.624
39.686
39.739
39.782
39.815
39.837
39.847
39.845
39.830
39.803
39.763
39.710
39.644
39.566
39.476
39.375
39.262
39.138
39.004
38.861
38.708
38.548
38.379
38.203
38.021
37.833
186.472
186.656
195.320
202.203
207.951
212.904
217.262
221.159
224.685
227.907
230.874
233.624
236.187
238.588
240.846
242.978
244.997
246.915
248.741
250.485
252.153
253.753
255.288
256.766
258.189
259.562
260.889
262.172
263.415
264.619
265.788
266.924
268.028
269.102
270.148
271.167
272.160
273.130
274.077
275.001
275.905
276.789
277.654
278.500
279.329
280.141
280.937
281.717
282.482
283.232
283.968
284.691
285.401
286.098
286.782
287.455
288.116
288.766
289.405
216.234
216.430
225.817
233.415
239.802
245.307
250.142
254.449
258.331
261.864
265.107
268.102
270.886
273.486
275.926
278.224
280.397
282.458
284.418
286.287
288.073
289.785
291.427
293.007
294.528
295.996
297.413
298.785
300.112
301.400
302.649
303.863
305.043
306.190
307.307
308.395
309.456
310.490
311.498
312.482
313.442
314.379
315.295
316.189
317.062
317.916
318.749
319.564
320.361
321.139
321.900
322.645
323.372
324.084
324.780
325.461
326.127
326.778
327.416
8.873
8.932
12.199
15.606
19.110
22.683
26.303
29.960
33.646
37.353
41.079
44.822
48.578
52.347
5?.127
59.919
63.720
67.532
71.353
75.184
79.025
82.875
86.734
90.603
94.482
98.370
102.269
106.176
110.093
114.020
1*17.955
121.899
125.850
129.809
133.775
137.746
141.722
145.702
149.685
153.669
157.654
161.638
165.619
169.598
173.571
177.539
181.500
185.452
189.394
193.326
197.246
201.153
205.047
208.925
212.788
216.634
220.463
224.274
228.067
-96.1295
-95.4945
-69.8393
-54.3588
-43.9838
-36.5362
-30.9238
-26.5385
-23.0144
-20.1185
-17.6949
-15.6354
-13.8628
-12.3202
-10.9649
-9.7642
-8.6927
-7.7302
-6.8605
-6.0706
-5.3497
-4.6889
-4.0809
-3.5193
-2.0010
-2.5154
-2.0647
-1.6435
-1.2489
-.8784
-.5297
-.2010
.1095
.4034
.6819
.9464
1.1978
1.4372
1.6654
1.8833
2.0915
2.2908
2.4817
2.6648
2.8405
3.0093
3.1717
3.3280
3.4786
3.6239
3.7640
3.8993
4.0301
4.1566
4.2790
4.3975
4.5123
4.6237
4.7318
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
On
S
51.
II
1
§
2
о
о
CN
1^5
•О
см
1
II
О
1
1800
1900
2000
2100
2200
:>зоо
:»4оо
:.»5оо
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
юль"
г
SO
1Х
00
<ч
О
•О
о
V
V
S
х
00
о
со
II
A3 87?
193

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°т
г
33.934
38.875
44.414
44.506
48.631
51.336
53.107
54.299
55.130
55.727
56.169
56.504
56.764
56.969
57.133
57.267
57.377
57.469
57.547
57.613
57.669
57.718
57.760
57.797
57.830
57.859
57.884
57.907
57.928
57.946
57.963
57.978
57.991
58.004
58.015
58.026
58.035
58.044
58.052
58.060
58.066
58.073
58.079
58.085
58.090
58.095
58.099
58.103
58.107
58.111
58.115
58.118
58.121
58.124
58.127
58.130
58.132
58.135
58.137
58.139
58.141
К°(Т)= p(S) •
Ф°(Т)
Дж • К~ • моль
181.650
205.120
219.414
219.644
230.651
239.699
247.449
254.253
260.328
265.820
270.834
275.448
279.721
283.701
287.426
290.926
294.228
297.352
300.317
303.139
305.829
308.402
310.865
313.228
315.499
317.684
319.791
321.824
323.788
325.689
327.529
329.313
331.043
332.724
334.358
335.947
337.494
339.001
340.469
341.902
343.300
344.666
346.000
347.304
348.580
349.828
351.050
352.247
353.420
354.570
355.697
356.803
357.889
358.954
360.000
361.028
362.038
363.031
364.007
364.968
365.912
flMOTOPMflCEPblSF
p2(F) -p'VSF
S°iT)
-1
215.016
239.883
256.470
256.745
270.153
281.317
290.844
299.126
306.434
312.964
318.860
324.229
329.157
333.709
337.937
341.884
345.583
349.065
352.352
355.465
358.422
361.237
363.923
366.491
368.952
371.313
373.583
375.768
377.874
379.907
381.872
383.773
385.614
387.398
389.130
390.812
392.447
394.037
395.585
397.093
398.563
399.997
401.396
402.763
404.099
405.404
406.681'
407.931
409.154
410.352
411.526
412.677
413.806
414.912
415.999
417.066
418.113
419.142
420.153
421.147
422.124
a) v
.Н°(Т)-Н°Л)
кДж • моль
3.337
6.953
11.048
11.130
15.801
20.809
26.037
31.411
36.885
42.430
48.026
53.660
59.324
65.011
70.716
76.437
82.169
87.911
93.662
99.420
105.185
110.954
116.728
122.506
128.287
134.072
139.859
145.649
151.440
157.234
163.029
168.826
174.625
180.425
186.226
192.028
197.831
203.635
209.439
215.245
221.051
226.858
232.666
238.474
244.283
250.092
255.902
261.712
267.522
273.333
279.144
284.956
290.768
296.580
302.393
308.206
314.019
319.832
325.646
331.460
337.274
2(г)
!°@) = 720.335
\gK°(T)
-367.5221
-178.3234
* -115.7759
-114.9883
-83.2099
-64.0907
-51.3168
-42.1764
-35.3107
-29.9636
-25.6810
-22.1732
-19.2472
-16.769 Г
-14.6431
-12.7991
-11.1842
-9.7582
-8.4897
^7.3539
-6.3309
-5.4046
-4.5620.
-3.7920
-3.0857
-2.4354
-1.8347
-1.2781
-.7609
-.2790
.1712
.5926
.9880
1.3597
1.7098
2.0402
2.3525
2.6481
2.9284
3.1946
3.4476
3.6885
3.9181
4.1372
4.3466
4.5468
4.7384
4.9221
.5.0982
5.2674
5.4298
5.5861
5.7365
5.8813
6.0208
6.1555
6.2854
6.4108
6.5321
6.6493
6.7627
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
UO
о
о
г-
—1
гм
го
го
00
О
О
I
?
2
§5
II
•е-
Таблица 132
§
Т 2
^ Й ~
* <^ i
* го -
О On
О CN ^
9 i
0s || j-f
I Q п
11 ю 3
S 5 2
tb ~ о =*
ГА *V О 35
C/j C4 . "*
w ^ Co
о <Л
-t о
1
-Q
g
2
1 С
' ^ о
го К
о
° V
^ о
<s "°
ОС 1"
го i
Г4! О
го "^
1 к,
го "
г- ^
го
194

Класс точности
VI-Г
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
37.060
52.058
63.147
63.308
70.016
74.002
76.479
78.096
79,200
79.984
80.558
80.991
81.324
81.586
81.796
81.966
82.106
82.223
82.321
82.405
82.476
82.537
82.591
82.637
82.678
82.715
82.747
82.776
fiO Qf\ 1
82.801
82.824
82.845
82.864
82.881
82.897
82.911
82.924
82.936
82.947
82.958
82.967
82.976
82.984
82.991
82.998
83.005
83.011
83.017
83.022
83.027
83.032
83.036
83.040
83.044
83.048
83.052
83.055
83.058
83.061
83.064
83.067
83.069
АГ°(Л = p(S) .
Ф°(Л
Дж • К • моль
198.233
223.220
240.063
240.345
254.209
266.043
276.409
285.639
293.959
301.533
308.483
314.902
320.865
326.433
331.655
336.569
341.212
345.610
349.788
353.768
357.566
361.199
364.681
368.023
371.236
374.330
377.313
380.194
аал /ЧТО
382.978
385.672
388.281
390.812
393.268
395.653
397.972
400.228
402.425
404.565
406.652
408.687
410.674
412.615
414.511
416.365
418.179
419.954
421.692
423.394
425.063
426.698
428.302
429.876
431.420
432.937
434.426
435.889
437.327
438.740
440.129
441.496
•442.841
ТРИФТОРИД СЕРЫ SF
p3(F) -p-1 (SF
S°(T)
- 1
232.217
262.479
285.504
285.895
305.112
321.200
334.928
346.847
357.352
366.728
375.186
382.885
389.947
396.468
402.522
408.171
413.466
418.447
423.150
427.603
431.832
435.857
439.698
443.370
446.888
450.264
453.509
" 456.632
459.643
462.549
465.357
468.074
470.705
473.256
475.731
478.134
480.471
482.743
484.955
487.110
489.211
491.260
493.260
495.213
497.121
498.986
500.811
502.596
504.344
506.056
507.734
509.378
510.991
512.572
514.125
515.649
517.145
518.615
520.060
521.480
522.876
Н°(Т)-Н°@)
кДж • моль
3.398
7.852
13.548
13.665
20.361
27.578
35.112
42.846
50.714
58.675
66.704
74.782
82.898
91.044
99.214
107.402
115.606
123.823
132.050
140.287
148.531
156.781
165.038
173.299
181.565
189.835
198.108
206.384
214.663
222.944
231.228
239.513
247.801
256.089
264.380
272.672
280.964
289.259
297.554
305.850
314.147
322.445
330.744
339.044
347.344
355.645
363.946
372.248
380.550
388.853
397.157
405.461
413.765
422.069
430.374
438.680
446.985
455.291
463.598
471.904
480.211
.«
'@) - 1006
lgA'V)
-511.9922
-247.3424
-159.8636
-158.7624
-114.3420
-87.6344
-69.8024
-57.0508
-47.4787
-40.0287
-34.0653
-29.1838
-25.1144
-21.6699
-18.7166
-16.1564
-13.9158
-11.9384
-10-1803
-8.6071
-7.1909
-5.9095
-4.7443
-3.6803
-2.7049
-1.8073
-.9787
-.2113
.5014
1.1650
1.7845
2.3641
2.9076
3.4182
3.8989
4.3522
4.7804
5.1855
5.5694
5.9336
6.2797
6.6090
6.9227
7.2219
7.5075
7.7805
8.0417
8.2919
8.5316
8.7616
8.9825
9.1948
9.3989
9.5954
9.7847
9.9671
10.1431
10.3129
10.4769
10.6353
10.7886
.610 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
ос
+
7
ос
сч
о
ОС
+
ОС
сч
о
о
о
с
чО
сч
сч
ОС
о
ОС
I,
«е-
Таб
о
о
о
о
о
о
1
II
"¦"
..^
оо
о
-"
о
1
^р
го
+
с*
н
on
о
ГО
н
ЧО
го
о
го
+
лица 133
7
1
•
5 л
х 3
сч 2
о
*° i
11 5
wo <"}
ос —
ON
СЧ !!
~ =1
г», О Л
о
о
\ /
V
V
о
^."
О
II
195

Класс точности
VI-F
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г
64.066
64.225
70.750
74.566
76.913
73.436
79.472
80.205
80.741
81.144
81.455
81.699
81.894
82.052
82.182
82.290
82.382
82.459
82.525
82.582
82.631
82.675
82.713
82.746
82.776
82.803
82.827
82.848
82.867-
82.885
82.901
82.915
82.928
82.941
82.952
82.962
82.971
82.980
82.988
82.996
83.003
83.009
83.015
83.021
83.026
83.031
83.036
83.040
83.044
83.048
83.052
83.055
83.058
83.062
83.G64
83.067
83.070
83Г072
83.075
ОТРИЦАТЕЛЬНЫЙ
К9(Т) = p(S) •
Ф°(Л
Дж • К • моль
235.454
235.739
249.783
261.762
272.244
281.567
289.964
297.601
304.603
311.068
317.070
322.672
327.922
332.863
337.528
341.947
346.144
350.140
353.954
357.601
361.095
364.449
367.673
370.777
373.770
376.659
379.451
382.152
384.769
387.306
389.768
392.159
394.484
396.745
398.947
401.092
403.183
405.223
407.214
409.158
411.058
412.916
414.733
416.511
418.252
419.958
421.629
423.267
424.874
426.450
427.996
429.515
431.007
432.472
433.912
435.327
436.718
438.087
439.434
P3(F) -р(е)
S°(T)
-1
281.480
281.877
301.333
317.567
331.385
343.364
353.909
363.314
371.794
379.509
386.584
393.113
399.176
404.831
410.131
415.116
419.823
424.279
428.510
432.538
436.381
440.055
443.574
446.952
450.198
453.322
456.334
459.241
462.050
464.767
467.399
469.950
472.4J>6
474.830
477.166
479.439
481.652
483.807
485.908
487.958
489.958
491.911
493.819
495.685
497.510
499.295
501.043
502.71N
504.433
506.078
507 691
509.273
510.825
512.349
513.846
515.316
516.761
518.181
519.577
ИОН ТРИФТОРИДА СЕРЫ
•p-^SF") АгИ
Н°{Т)-Н°{0)
кДж • моль
13.723
13.841
20.620
27.902
35.485
43.258
51.156
59.142
67.191
75.286
83.416
91.574
99.754
107.952
116.164
124.388
132.621
140.864
149.113
157.368
165.629
173.894
182.164
190.437
198.713
206.992
215.273
223.557
231.843
240.130
248.420
256.710
265.003
273.296
281.591
289.886
298.183
306.481
314.779
323.078
331.378
339.679
347.980
356.282
364.584
372.887
381.190
389.494
397.799
406.103
414.408
422.713
431.019
439.325
447.631
455.938
464.245
472.552
480.859
э@) = 1286
lgK°(T)
-208.6726
-207.2624
-150.3513
-116.0962
-93.1971
-76.8008
-64.4761
-54.8701
-47.1700
-40.8578
-35.5880
-31.1208
-27.2850
-23.9548
-21.03&9
-18.4560
-16.1589
-14.1002
-12.2443
-10.5623
-9.0308
-7.6301
-6.3440
-5.1589
-4.0632
-3.0469
-2.1017
-1.2203
-.3963
.3759
1.1009
1.7832
2.4263
3.0337
3.6083
4.1527
4.6693
5.1603
5.6274
6.0725
6.4971
6.9026
7.2904
7.6615
8.0170
8.3580
8.6853
8.9997
9.3021
9.5931
9.8733
10.1435
10.4040
10.6555
lp.8984
11.1331
11.3601
11.5798
11.7925
SF; (г)
.610 кДж • моль"
7
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
чо
о
Os
00
И
+
Os
rf
с-»
+
«--
m
О
о
о
i
с
00
ЧО
$
00
+
О
ЧО
<N
1О
t>
^-
II
о
Ь
Таблица 134
-а
с;
Т »
1 к \д
ё. Я §
о о 1
8 S *
6 ' *
00 II Д-
(— C_q_
11 „ а
о 2 ^
w 00 *-<
ьГ °* и
м ^ II
*~" 1 ~ О «
w 'г_ «"> со
о сл
*"•* 0
1
л
|
|
О
* О
п §
m* v
2 v
+ §
vq О
о ?
196

Класс точности
VI-Г
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
56С»
j700
5800
5900
6000
elm
40.459
61.015
76.671
76.906
86.930
93.125
97.071
99.689
101.497
102.790
103.742
104.463
105.020
105.459
105.811
106.097
106.333
106.529
106.695
106.835
106.956
107.060
107.150
107.229
107.298
107.359
107.414
107.463
107.506
107.545
107.581
107.613
107.642
107.668
107.692
107.714
107.735
107.753
107.771
107.787
107.801
107.815
107.828
107.840
107.851
107.861
. 107.871
107.880
107.889
107.897
107.904
107.911
107.918
107.924
107.930
107.9J*
; i,7.94i
107.946
107.951
107.956
107.960
К°(Т) = p(S) -р4
Ф°(Л
Дж К ¦ моль
199.780
226.241
245.006
245.326
261.296
275.238
287.646
298.826
308.995
318.317
32Ь.918
334.900
342.344
349.316
355.873
362.059
367.915
373.473
378.761
383.805
388.62b
393.242
397.671
401.926
406.021
409.968
413.776
417.455
421.013
424.458
427.798
431.037
434.183
437.240
440.213
443.107
445.925
448.672
451.351
453.965
456.518
459.012
461.450
463.834
466.167
468.451
470.687
472,878
475.026
477.132
479.197
481.224
483.214
485.168
487.087
48Я.973
490.826
492.648
494.441
496.203
497.938
ТЕТРАФТОРИД СЕРЫ
(F).p(SF4
S°(T)
234.750
269.108
296.600
297.075
320.688
340.806
358.159
373.332
386.769
398.802
409.684
419.607
428.721
437.145
444.974
452.284
459.139
465.592
471.685
477.458
482.941
488.162
493.145
497.909
502.475
506.856
511.068
515.122
519.031
522.805
526.451
529.979
533.396
536.709
539.924
543.046
546.080
549.032
551.906
554.706
557.435
560.097
562.696
565.233
567.712
570.136
572.507
574.827
577.098
579.323
581.503
583.639
585.735
587.791
589.808
591.788
593.733
595.644
597.521
599.367
601.181
Hnm-H°i0)
кДж • моль
3.497
8.573
15.383
15.525
23.757
32.784
42.308
52.154
62.219
72.437
82.765
93.177
103.653
114.177
124.74 i
135.337
145.959
156.603
167.264
177.941
188.630
199.331
210.042
220.761
231.487
242.220
252.959
263.703
274.451
285.204
295.960
306.720
317.483
328.248
339.016
349.786
360.559
371.333
382.110
392.887
403.667
414.448
425.230
436.013
446.798
457.583
468.370
479.158
489.946
500.735
511.525
522.316
533.108
543.900
554.692
565.486
576.280
587.074
597.869
608.664
619.460
SF4 (г)
Н°@) - 1337.041
\gKQ(T)
-678.7410
-327.1059
-210.8667
-209.4034
-150.3799
-114.8951
-91.2062
-74.2695
-61.5585
-51.6676
-43.7524
-37.2749
-31.8764
-27.3081
-23.3923
-19.9988
-17.0296
-14.4099
-12.0816
-9.9986
-8.1242
-6.4285
-4.8872
-3.4802
-2.1906
1.0044
.0904
1.1039
2.0449
2.9208
3.7382
4.5027
5.2194
5.8925
6.5259
7.1231
7.6870
8.2203
8.7255
9.2047
9.6598
10.0928
10.5050
10.8980
11.2732
11.6315
11.9743
12.3025
12.6169
12.9184
13.2079
13.4860
13.7533
14.0106
14.2582
14.4969
14.7270
14.9489
15.1633
15.3703
15.5704
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
©
ос
о
ЧО
Г"»
С1
SO
с»
'<§
«о
оо
О
о
i
00
Г]
SO
О
-f.
С--
00
00
р
«о
«о
II
Таб
О
7
«о
СП
«о
1!
С/5
О
т
с?
о
.
к
с*
X
so
00
н
О
rs
vd
1
1
s
r-
л и и а 135
T
I
1 i
w1
о
о 7
S be
i
II ?S
Я ос
\ oj
с
о
8
ЧО
V
V
о
ту
1
II
197

Класс i
VI-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000,
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
лчности
1 !
45.926
79.023
100.083
100.372
112.022
118.627
122.625
125.195
126.933
128.158
129.051
129.721
130.237
130.642
130.965
131.227
131.442
131.621
131.772
131.900
132.009
132.103
132.185
132.256
132.319
132.375
132.424
132.468
1 49 *\(\7
132.542
132.574
132.603
132.629
132.653
132.675
132.695
132.713
132.730
132.746
132.760
132.773
132.786
132.797
132.808
132.818
132.827
132.836
132.844
132.852
132.859
132.866
132.872
132.878
132.884
132.889
132.894
132.899
132.904
132.908
132.912
132.916
к°т= p(S) •
Ф°(Т)
Дж • К • моль
207.792
236.733
259.131
259.522
279.296
296.781
312.406
326.495
339.303
351.031
361.840
371.859
381.191
389.924
398.128
405.861
413.176
420.113
426.710
432.998
439.004
444.754
450.266
455.560
460.653
465,559
470.291
474.861
A7Q 9ftft
*н у.лои
483.558
487.703
491.723
495.625
499.417
503.104
506.691
510.185
513.589
516.909
520.148
523.310
526.399
529.418
532.370
535.258
538.085
540.853
543.565
546.222
548.828
551.384
553.891
556.352
558.769
561.142
563.474
565.766
568.019
570.234
572.414
574.558
ПЕНТАФТОРИД СЕРЫ
p'(F).p*(SF
S°(T)
244.031
286.339
322.224
322.844
353.480
379.252
401.262
420.371
437.209
452.234
465.786
478.118
489.429
499.870
509.564
518.609
527.085
535.059
542.587
549.715
556.483
562.926
569.073
574.951
580.581
585.984
591.177
596.175
600.993
605.644
610.138
614.485
618.696
622.777
626.738
630.584
634.322
637.959
641.499
644.947
648.308
651.587
654.787
657.912
660.965
663.950.
666.870
669.727
672.523.
675.263
677.947
680.578
683.158
685.689
688.173
690.612
693.007
695.359
697.670
699.942
702.176
S> Дг
Но(Т)-Н°@)
кДж • моль
3.624
9.921
18.811
18.997
29.674
41.235
53.314
65.713
78.325
91.083
103.946
116.886
129.885
142.930
156.010
169.120
182.254
195.408
208.577
221.761
234.957
248.162
261.377
274.599
287.828
301.062
314.302
327.547
OAf\ 7QA
354.048
367.304
380.563
393.825
407.089
420.355
433.624
446.894
460.166
473.440
486.716
499.992
513.270
526.549
539.829
553.111
566.393
579.676
592.960
606.245
619.531
632.817
646.104
659.392
672.680
685.968
699.257
712.547
725.837
739.128
752.419
765.710
SF5 (г)
Н°@) = 1621
lgK°(T)
-821.6370
-395.1645
-254.2358
-252.4624
-180.9400
-137.9627
-109.2847
-88.7889
-73.4122
-61.4509
-51.8817
-44.0528
-37.5297
-32.0113
-27.2823
-23.1849
-19.6008
-16.4394
-13.6302
-11.1176
-8.8570
-6.8125
-4.9546
-3.2589
-1.7051
-.2761
1.0424
2.2627
О OQCC
4.4497
5.4333
6.3531
7.2150
8.0244
8.7859
9.5036
10.1812
10.8219
11.4286
12.0041
12.5505
13.0701
13.5648
14.0363
14.4863
14.9160
15.3269
15.7202
16.0970
16.4583
1^.8050
17.1380
17.4580
17.7659
18.0623
18.3477
18.6229
18.8884
19.1446
19.3920
19.6311
. 160 к Дж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛПЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
о
CN
II
+
со
О
00
со
+
1/-)
CN
Г*-
о
о
1
g
—н
о
00
со
о
(Л
со
II
Ф
I а б л и ц
Т
7. §
i §
о
Д в
О vO
О r-J
о 2
S °\
Т и
1. X
II
о со
Ei<
С/3 «л
^ о
<1 *Х
_
1
•
с*
го
;*>
00
г»
00
со
1
XI
со
о
а 136
_
i
g
1
с^
d
со
d
О о?
я
о
g
V
К
V
1
о
II
198

Класс точности
VI-F
ОТРИЦАТЕЛЬНЫЙ ИОН ПЕНТАФТОРИДА СЕРЫ SF; (г)
•Р5(Г)-Р(<?) -I
Таблица 137
°@) = 1917.160 кДж-моль"
Ф°(Л
s°m
Дж • К~ 1 • моль" *
кДж • моль
-1
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800*
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
101.063
101.346
112.722
119.135
123.003
125.486
127.162
128.342
129.203
129.848
130.345
130.734
131.045
131.297
131.504
131.676
131.821
131.944
132.049
132.139
132.218
132.287
132.347
132.400
132.447
132.490
132.527
132.561
132.592
132.620
132.645
132.668
132.689
132.708
132.726
132.742
132.757
132.771
132.784
132.795
132.806
132.817
132.826
132.835
132.844
132.852
132.859
132.866
132.872
132.878
132.884
132.890
132.895
132.900
132.904
132.909
132.913
132.917
132.921
253.063
253.459
273.466
291.127
306.887
321.082
333.974
345.771
356.638
366.704
376.078
384.847
393.081
400.842
408.181
415.140
421.756
428.061
434.083
439.847
445.372
450.678
455.782
460.698
465.440
470.020
474.447
478.732
482.884
486.911
490.820
494.617
498.310
501.903
505.401
508.810
512.135
515.378
518.544
521.637
524.660
527.615
530.507
533.337
536.108
538.823
541.483
544.092
546.650
549.160
551.624
554.042
556.418
558.752
561.046
563.301
565.519
567.700
569.846
316.955
317.581
348.459
374.364
396.455
415.616
432.488
447.538
461.107
473.453
484.773
495.222
504.923
513.973
522.453
530.431
537.961
545.092
551.862
558.307
564.456
570.335
575.966
581.370
586.564
591.564
596.383
601.034
605.528
609.876
614.087
618.169
622.130
625.977
629.716
633.352
636.892
640.341
643.703
646.982
650.182
653.307
656.360
659.346
662.265
665.122
667.919
670.659
673.343
675.975
678.555
681.086
683.570
686.009
688.404
690.756
693.067
695.340
697.573
19.050
19.237
29.997
41.618
53.741
66.174
78.811
91.590
104.469
117.423
130.434
143.488
156.578
169.695
182.836
195.995
209.170
222.358
235.558
248.768
261.985
275.211
288.442
301.680
314.922
328.169
341.420
354.675
367.932
381.193
394.456
407.722
420.990
434.260
447.531
460.805
474.080
487.356
500.634
513.912
527.192
540.474
553.756
567.039
580.323
593.608
606.893
620.180
633.466
646.754
660.042
673.331
686.620
699.910
713.200
726.491
739.782
753.073
766.365
-305.7718
-303.6720
-218.9653
-168.0243
-134.0016
-109.6628
-91.3846
-77.1516
-65.7530
-56.4176
-48.6309
-42.0363
-36.3790
-31.4719
-27.1747
-23.3802
-20.0046
-16.9821
-14.2599
-11.7950
-9.5526
-7.5037
-5.6242
-3.8938
-2.2953
-.8142
.5622
1.8445
3.0422
4.1635
5.2154
6.2043
7.1357
8.0145
8.8452
9.6314
10.3769
11.0846
11.7575
12.3980
13.0084
13.5909
14.1473
14.6794
15.1887
15.6767
16.1447
16.5940
17.0256
17.4406
17.8399
18.2244
18.5950
18.9523
19.2972
19.6302
19.9519
20.2630
20.5639
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
V©
, - о ос
«о
On
00
о
о
о
о
о
V
V
о
199

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с; сп
38.776
68.932
97.041
97.478
116.426
128.387
136.095
141.247
144.822
147.387
149.282
150.717
151.829
152.706
153.409
153.982
154.454
154.848
155.179
155.461
155.702
155.910
156.091
156.250
156.389
156.512
156.621
156.719
156.806
156.885
156.956
157.020
157.078
157.131
157.180
157.224
157.265
157.303
157.338
157.370
157.399 .
157.427
157.453
157.476
157.499
157.520
157.539
157.557
157.574
157.591
157.606
157.620
157.633
157.646
157.658
157.669
157.680
157.690
157.700
157.709
157.718
к'°\Т) = p(S) • р6
Ф°(Л
Дж • К • моль
188.768
214.902
234.741
235.094
253.283
270.018
285.461
299.738
312.972
325.280
336.766
347.523
357.630
367.156
376.161
384.696
392.807
400.532
407.904
414.955
421.709
428.191
434.422
440.419
446.200
451.779
457.170
462.384
467.433
472.328
477.076
481.687
486.168
490.526
494.768
498.900
502.926
506.854
510.686
514.428
518.084
521.658
525.152
528.572
531.919
535.197
538.409
541.557
544.643
547.671
550.641
553.557
556.421
559.233
561.996
564.713
567.383
570.009
572.592
575.133
577.635
ГЕКСАФТОРИД СЕРЫ
(F) •p~1(SF(
S°iT)
223.037
258.478
291.544
292.145
322,990
350.355
374.494
395.885
414.993
432.207
447.839
462.137
475.300
487.489
498.833
509.437
519.390
528.766
537.627
546.025
554.005
561.607
568.864
575.806
582.459
588.846
594.987
600.899
?Л? АЛЛ
oOo.bUU
612.104
617.424
622.572
627.558
632.392
637.084
641.640
646.070
650.380
654.575
658.663
662.647
666.534
670.328
674.033
677.654
681.194
684.656
688.044
691.361
694.611
697.795
700.916
703.976
706.979
709.926
712.819
715.660
718.451
721.194
723.890
726.540
Н°{Т)-М°(())
кДж • моль"
3.427
8.715
16.936
17.115
27.883
40.169
53.420
67.303
. 81.617
96.234
111.072
126.075
141.205
156.433
171.740
187.111
202.533
217.999
233.501
249.033
264.591
280.172
295.772
311.390
327.022
342.667
358.324
373.991
389.667
405.352
421.044 .
436.743
452.447
468.158
483.874
499.594
515.318
531.047
546.779
562.514
578.253
593.994
609.738
625.484
641.233
656.984
672.737
688.492
704.248
720.007
735.767
751.528
767.291
783.055
798.820
814.586
830.354
846.122
861.892
877.662
893.433
SF6 W
Н°@) = 1943.975
ig/r°cr)
-983.3331
-471.6410
-302.3725
-300.2411
-214.2544
-162.5497
-128.0311
-103.3529
-84.8340
-70.4261
-58.8983
-49.4666
-41.6076
-34.9589
-29.2614
-24.3251
-20.0072
-16.1987
-12.8148
-9.7883
-7.0656
-4.6033
-2.3659
-.3240
1.5468
3.2671
4.8544
6.3233
У.ОоОО
8.9553
10.1388
11.2454
12.2823
13.2559
14.1718
15.0349
15.8496
16.6199
17.3493
18.0410
18.6977
19.3221
! 9.9164
20.4829
21.0233
21.5394
22.0329
22.50,51
22.9574
23.3911
23.8072
24.2067
24.5907
24.9601
25.3156
25.6579
25.9879
26.3062
26.6133
26.9099
27.1964
кДж • моль 1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
19Q0
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
*/¦>
о
SO
Tt
II
<
+
ЧО
со
со
сч
»—1
1О
'н
VO
о>
W(
со
р
о
1
1
CN
г-
о
1-4
+
со
<N
ЧО
II
ф
Таблица 138
1
§ к -
§ 5 ¦*
2*5 г-» О
Л § 2
^Т /NJ V.V
ю 2 ^
КП | *
§ " 3
7 V ?
ми CD
II io «О
/—v "t ^О
О оо f^
С SS ii
tu о o*
СЛ О Co
w a-
O CO
\ °
T
e
1
i
к ё
5 §
CO y^
X w
r- V
+ v
о
On
2 о
x С
ЧО
CO II
4-
200

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.545
47.162
57.094
57.251
64.256
69.036
72.341
74.674
76.36*1
77.609
78.552
79.280
79.851
80.307
80.676
80.978
81.229
81.439
81.617
81.769
81.899
82.012
82.110
82.196
82.272
82.339
82.399
82.452
лп глл
82^43
82.582
82.617
82.649
82.678
82.705
82.730
82.752
82.773
82.792
82.810
82.826
82.841
82.856
82.869
82.831
82.893
82.903
82.913
82.923
82.932
82.940
82.948
82.955
82.962
82.969
82.975
82.981
82.987
82.992
82.997
83.002
К°(Т)= p(S) -
Ф°(Т)
Дж • К • моль
196.518
220.827
236.682
236.944
249.802
260.742
270.344
278.929
286.704
293.813
300.364
306.440
312.103
317.408
322.397
327.105
331.562
335.794
339.821
343.664
347.337
350.856
354.232
357.477
360.601
363.612
3.66.518
369.326
ото П4Ч
374.674
377.224
379.699
382.102
384 438
386.710
388.922
391.077
393.177
395.226
397.225
399.178
401.086
402.951
404.775
406.560
408.308
410.020
411.697
413.341
414.954
416.535
418.087
419.611
421.107
422.577
424.021
425.441
426.837
428.210
429.560
430.890
ОКСИД-ДИФТОРИД СЕРЫ
р(О) V(F) .
-1
230.173
258.236
279.025
279.379
296.872
311.757
324.654
335.991
346.079
355.148
363.376
370.898
377.822
384.232
390.198
395.774
401.009
405.940
410.600
415.017
419.215
423.213
427.031
430.683
434.183
437.542
440.773
443.884
446.883
449.779
^52.578
455.287
457.910
460.454
462.922
465.320
467.651
469.919
472.126
474.277
476.374
478.419
480.416
482.365
484.271
486.133
487.955
489.738
491.484
493.194
494.870
496.512
498.123
499.703
501.254
502.776
504.271
505.740
507.184
508.602
509.997
P~l(SOT2) ЛгИ
Я°(Г)-Я°@)
кДж • моль
3.366
7.482
12.625
12.730
18.828
25.508
32.586
39.944
47.500
55.201
63.012
70.905
78.862
86.871
94.921
103.004
111.115
119.249
127.402
135.571
143.755
151.950
160.157
168.372
176.595
184.826
193.063
201.306
217.805
226.062
234.322
242.585
250.852
259.120
267.392
275.666
283.943
292.221
300.501
308.783
317.066
325.351
333.637
341.925
350.214
358.503
366.794
375.086
383.379
391.672
399.967
408.262
416.558
424.854
433.152
441.449
449.748
458.047
466.346
474.646
SOF2 (г)
°@) - 1256
-642.2170
-312.3176
-203.3147
-201.9427
-146.6021
-113.3295
-91.1136
-75.2264
-63.2999
-54.0169
-46.5860
-40.5031
-35.4319
-31.1393
-27.4588
-24.2681
-21.4756
-19.0111
-16.8200
-14.8592
-13.0942
-11.4970
-10.0448
-8.7187
-7.5029
-6.3842
-5.3514
-4.3949
-3.5067
-2!б796
-1.9075
-1.1851
-.5077
.1287
.7278
1.2927
1.8264
2.3313
2.8097
3.2637
3.6951
4.1055
4.4965
4.8694
5.2254
5.5657
5.8912
6.2030
6.5019
6.7886
7.0639
7.3286
7.5831
7.8280
8.0640
8.2915
8.5109
8.7226
8.9271
9.1248
9.3159
.118 кДж • моль
7
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
«о
•2
00
II
о
С4)
оо
о
00
00
«о
О
о
1
00
V©
V©
ON
г»
00
00
со
II
о
Т а б л и ца 139
Т Я
л 2
о ^
7 Й
k ™
О ^
О 00
О »О
о 1
г? д
II 1Л
II 1/-)
О ©б
о "м
ъ Ъ
о $S
а: о
1
л
о
?
1
н
«о
00
о
|
X
со
со
4-
1
|
1
•
О
со
п
о о?
Я
о
S
V
V
о
о
1
о
II
201

Класс точности j
VI Е |
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;, л
35.854
51.572
65.784
66.012
76.471
83.936
89.290
93.175
96.040
98.193
99.838
101.119
102.131
102.944
103.604
104.147
104.599
104.978
105.300
105.575
105.811
106.016
106.195
106.352
106.490
106.612
106.721
106.819
106.906
106.985
107.056
107.120
107.179
107.233
107.281
107.326
107.368
107.406
107.441
107.473
107.503
107.531
107.557
107.581
107.604
107.625
107.645
107.663
107.681
107.697
107.712
107.727
107.740
107.753
107.766
107.777
107.788
107.798
107.808
107.818
107.826
ДИОКСИД-ДИФТОРИД СЕРЫ
K°(T) = p{S) i
Ф°(Т)
Дж • К • моль
196.995
221.567
238.187
238.467
252.436
264.649
275.595
285.544
294.672
303.108
310.948
318.272
325.142
331.611
337.721
343.510
349.010
354.248
359.247
364.028
368.608
373.004
377.231
381.300
385.222
389.008
392.667
396.207
399.635
402.959
406.184
409.316
412.360
415.322
418.204
421.013
423.750
426.420
429.026
431.571
434.057
436.488
438.865
441.192
443.469
445.700
447.886
450.028
452.129
454.190
456.212
458.198
460.147
462.063
463.944
465.794
467.613
469.402
471.161
472.892
474.597
72(О) р2(Г) •
S°(T)
-1
230.685
260.063
283.439
283.847
304.354
322.266
338.069
352.141
364.779
376.221
386.656
396.234
405.078
413.286
420.939
428.107
434.843
441.196
447.205
452.906
458.328
463.496
468.432
473.156
477.685
482.035
486.218
490.248
494.134
497.887
501.515
505.027
508.428
511.727
514.929
518.040
521.064
524.006
526.871
529.662
532.384
535.038
537.630
540.161
542.634
545.053
547.419
549.734
552.001
554.221
556.397
558.530
560.622
562.675
564.689
566.666
568.609
570.516
572.391
574.234
576.046
p!(SO2F2) Д
Н°(Т)-Н°@)
кДж • моль
3.369
7.699
13.492
13.614
20.767
28.809
37.484
46.618
56.086
65.802
75.707
85.758
95.922
106.177
116.506
126.894
137.332
147.812
158.326
168.870
179.440
190.031
200.642
211.269
221.912
232.567
243.234
253.911
264.597
275.291
285.994
296.702
307.417
318.138
328.864
339.594
350.329
361.068
371.810
382.556
393.304
404.056
414.810
425.568
436.327
447.088
457.852
468.617
479.384
490.153
500.924
511.696
522.469
533.244
544.020
554.797
565.575
576.354
587.135
597.916
608.698
SO2F2 (г)
.//"(()) - 1674.474 кДж •
-854.8232
-414.8619
-269.4579
-267.6277
-193.7973
-149.4059
-119.7660
-98.5706
-82.6606
-70.2783
-60.3677
-52.2561
-45.4948
-39.7725
-34.8670
-30.6153
-26.8948
-23.6120
-20.6940
-18.0832
-15.7336
-13.6079
-11.6756
-9.9115
-8.2945
-6.8070
-5.4340
-4.1629
-2.9826
-1.8839
-.8585
.1007
.9998
1.8444
2.6392
3.3886
4.0963
4.7657
5.3998
6.0014
6.5729
7.1165
7.6341
8.1277
8.5989
9.0491
9.4797
9.8920
10.2872
10.6662
11.0301
11.3797
11.7158
12.0393
12.3509
12.65П
12.9406
13.2200
13.4898
13.7504
14.0024
/•
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
чо
•о
о
гч
о
•"¦'
!|
<
+
•о
гч
го
+
ON
го
ЧО
ГЧ
о
о
1
g
«о
гч
о
+
ГЧ
—«
•о
1
1 аб
7
-а
g
г-
г*
1
о
и
гч
С
ЬО
О
-
1
—
н
чо
го
ЧО
OS
.ф.
с»
ЧО
ГО
^J*
гч
гч
!
О
U-)
с^
г-
1О
лица 140
7
о
о
<з
чО
i
и
S
«о
об
0s
гч
сГ
0
¦>,
^i
4
7
1
I
ГО
чО
г*~
ГО
—
О о-
со
2.
о
§
чО
V
V
о
о
«О
1
О
li
202

АЗОТ N (г)
! Таблицам!
Ф°ГЛ
S°iT)
Дж - К • моль
Нп(Т)-Н°@)
кДж • моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.788
20.790
20.793
20.797
20.804
20.813
20.826
20.843
20.864
20.924
20.963
21.010
21.064
21.126
21.197
21.277
21.365
21.463
21.569
21.685
21.809
21.941
22.082
22.231
22.388
22.551
22.722
22.899
23.081
23.269
23.461
23.657
23.858
24.061
24.266
24.474
24.682
24.892
25.102
25.312
25.521
109.697
124.104
132.404
132.532
138.512
143.150
146.940
150.144
152.920
155.368
157.558
159.539
161.348
163.012
164.552
1Ъ5.У86
167.328
168.588
169.776
170.900
171.966
172.980
173.947
174.871
175.756
176.604
177.420
178.205
178.961
179.691
180.396
181.078
181.739
182.380
183.002
183.606
184.193
184.765
185.322
185.865
186.395
186.912
187.417
187.911
188.394
188.868
189.331
189.785
190.231
190.668
191.097
191.518
191.932
192.340
192.740
193.134
193.522
193.904
194.281
194.652
195.018
130.483
144.890
153.190
153.318
159.298
163.936
167.726
170.930
173.706
176.154
178.344
180.325
182.134
183.798
185.338
186.772
188.114
189.374
190.562
191.686
192.752
193.767
194.734
195.659
196.544
197.394
198.211
198.998
199.757
200.491
201.201
201.889
202.557
203.206
203.838
204.454
205.054
205.641
206.215
206.776
207.327
207.867
208.397
208.919
209.432
209.937
210.434
210.925
211.409
211.886
212.359
212.825
213.286
213.743
214.194
214.641
215.084
215.523
215.958
216.389
216.816
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.494
41.573
43.652
45.731
47.811
49.892
51.974
54.057
56.143
58.230
60.321
62.415
64.514
66.618
68.727
70.843
72.967
75.099
77.240
79.392
81.554
83.729
85.916
88.118
90.333
92.564
94.811
97.075
99.355
101.654
103.972
106.308
108.664
111.040
113.436
115.852
118.289
120.747
123.226
125.725
128.246
130.788
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
О
о
00
о
о
о
00
«о
U °
~ ъс
с,
о
ОС
о
00
о
о
S
чО
V
V
8 х
с** —<
О 'О
i -¦
203

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
1350JO
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Т)
25.935
26.341
26.736
27.118
27.483
27.830
28.157
28.464
28.748
29.010
29.249
29.466
29.660
29.832
29.982
30.111
30.219
30.308
30.379
30.431
30.493
30.467
30.368
30.211
30.008
29.771
29.510
29.231
28.942
28.648
28.353
28.061
27.773
27.492
27.219
26.956
26.702^
26.458
26.224
26.001
Ф°G)
S°(T)
Дж К~1 • моль"Х
195.735 217.660
196.433 218.489
197.114 219.306
197.778 220.110
198.428 220.901
199.063 221.680
199.684 222.447
200.293 223.202
200.890 223.945
201.476 224.677
202.051 225.396
202.615 226.104
203.169 226.799
203.714 227.483
204.250 228.155
204.777 228.816
205.295 229.464
205.805 230.101
206.308 230.727
206.802 231.341
208.006 232.828
209.167 234.246
210.287 235.599
211.369 236.888
212.414 238.117
213.426 239.290
214.404 240.408
215.352 241.477
216 271 242 497
217.162 243.474
218.025 244.408
218.864 245.304
219.678 246.163
220.470 246.988
221.239 247,781
221.987 248.544
222.714 249.279
223.423 249.988
224.113 250.672
224.785 251.333
АЗОТ N (г)
#°(Г)-#°@)
кДж * моль""
lgA°G)
135.933 —
141.161 —
146.469 —
151.855 —
157.315 —
162.847 —
168.446 —
174.108 —
179.830 —
185.606 —
191.432 —
197.304 —
203.217 —
209.167 —
215.148 —
221.158 -
227.191 —
233.244 —
239.313 —
245.395 —
260.630 —
275.873 —
291.084 —
306.23Д —
321.288 —
336.234 —
351.055 —
365.741 —
380 284
394.682 —
408.932 -
423.035 —
436.994 —
450.809 —
464.487 —
478.030 —
491.444 —
504.734 —
517.904 —
530.960 —
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
1*0500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 141
(окончание)
1О 1
(N Л
го Е
СП О
г
г
с
с*
о
i
1 *¦ Я
и §
fr* X О
О {< rsj
? я v
1 ? -
г*
1 WK V
? Я 2
_ © "Ч
О X 1
го г- О
об ^ F*»«
Os О II
о
+ W
204

Класс точности
I-C
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
21.285
21.278
21.060
20.960
20.906
20.874
20.853
20.839
20.829
20.821
20.815
20.811
20.808
20.805
20.803
20.802
20.803
20.804
20.806
20.810
20.816
20.824
20.835
20.848
20.864
20.883
20.904
20.929
20.956
20.987
21.020
21.056
21.094
21.135
21.178
21.222
21.269
21.317
21.366
21.417
21.468
21.520
21.573
21.625
21.678
21.731
21.784
21.837
21.889
21.941
21.992
22.042
22.092
22.141
22.189
22.235
22.281
22.326
22.370
ПОЛОЖИТЕЛЬНЫЙ ИОН АЗОТА N+ (г)
*°<П = р<№.
Ф°(Т)
Дж • К • моль
135.818
135.965
142.727
147.849
151.968
155.410
158.365
160.954
163.257
165.332
167.218
168.948
170.545
172.028
173.413
174.711
175.933
177.088
178.181
179.220
180.210
181.155
182.058
182.925
183.756
184.556
185.326
18б'(N9
186.787
187.480
188.152
188.803
189.434
190.047
190.642
191.221
191.785
192.335
192.870
193.393
193.903
194.401
194.888
195.364
195.830
196.286
196.733
197.170
197.600
198.020'
198.433
198.839
199.237
199.628
200.012
200.390
200.761
201.127
201.486
p-4n*).p-4
S°(T)
159.687
159.818
165.905
170.593
174.409
177.629
180.415
182.870
185.065
187.050
188.861
190.527
192.069
193.505
194.847
196.109
197.298
198.422
199.490
200.505
201.473
202.398
203.285
204.136
204.954
205.741
206.501
207.235
207.945
208.633
209.300
209.947
210.576
211.188
211.784
212.365
212.932
213.485
214.025
214.553
215.070
215.57В
216.071
216.556
217.032
217.499
217.957
218.407
218.849
219.283
219.709
220.129
220.541
220.947
221.346
221.739
222.127
222.508
222.883
о а,*
н°{Т)-№@)
кДж • моль
7.116
7.156
9.271
11.372
13.465
15.554
17.640
19.724
21.808
23.890
25.972
28.053
30.134
32.215
34.295
36.376
38.456
40Г536
42.617
44.697
46.779
48.861
50.944
53.028
55.113
57.201
59.290
6L382
63.476
65.573
67.673
69.777
71.885
73.996
76.112
78.232
80.356
82.486
84.620
86.7.59
88.903
91.052
93.207
95.367
97.532
99г703
101.878
104.060
106.246
108.437
110.634
112.836
115.042
117.254
119.471
121.692
123.918
126.148
128.383
э@) = -1402.
\gK°(T)
245.4960
243.9733
182.5792
145.6871
121.0556
103.4356
90.2010
79.8923
71.6332
64.8659
59.2182
54.4324
50.3243
46.7587
43.6344
40.8736
38.4160
36.2139
34.2292
32.4308
30.7937
29.2967
27.9225
26.6565
25.4862
24.4010
23.3918
22.4510
21.5716
20.7478
19.9743
19.2468
18.5610
17.9136
17.3012
16.7211
16.1709
15.6481
15.1507
14.6770
14.2252
13.7939
13.3816
12.9871
12.6092
12.2470
11.8993
11.5655
11.2446
10.9359
10.6386
10.3523
10.0762
9.8098
9.5526
9.3041
9.0639
8.8316
8.6068
Таблица! 42
327 кДж ¦ моль 1
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
§
? z % *
о . _—
_J ГО «
г^ и 3
^ -оо _, Я
11 ""* ^ S
^и ю го
О оо °^
г. О^ II
Z . со
о S
^ о
го
§ S
'? ^ Я
оо • о
g * °
§ Ч
О сп V
О ^ г
го
v О W
* d о
; • s
го *"*
<ч г- <*
• оо 1
Я °) 2
00 ^
00 Г- И
S я а,
II 1
II 1
г
205

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
с; ел
ПОЛОЖИТЕЛЬНЫЙ ИОН АЗОТА N+ (г)
Ф°G)
S°(T)
Дж К~1 • моль""*
22.455
22.535
22.610
22.682
22.749
22.812
22.871
22.926
22.978
23.027
23.072
23.115
23.155
23.193
23.228
23.262
23.293
23.323
23.351
23.378
23.439
23.495
23.545
23.593
23.637
23.680
23.723
23.764
23.806
23.849
23.892
23.936
23.980
24.027
24.074
24.122
24.171
24.221
24.272
24.324
202.188
202.869
203.530
204.172
204.797
205.405
205.997
206.575
207.138
207.688
208.225
208.749
209.263
209.765
210.256
210.738
211.209
211.672
212.125
212.570
213.646
' 214.675
215.662
216.608
217.519
218.395
219.241
220.057
220.847
221.611
222.351
223.070
223.767
224.445
225.104
225.746
226.371
226.980
227.575
228.155
Я°(Г)-#°@)
кДж * моль
223.618 132.865 8.1781
224.332 137.364 7.7754
225.027 141.879 7.3962
225.703 146.408 7.0385
226.362 150.951 6.7005
227.003 155.507 6.3807
227.629 160.076 6.0775
228.240 164.656 5.7898
228.836 169.246 5.5162
229.418 173.846 5.2558
229.988 178.456 5.0076
230.544 183.075 4.7708
231.088 187.702 4.5446
231.621 192.337 ' 4.3283
232.143 196.979 4.1213
232.654 201.628 3.9229
233.154 206.284 3.7326
233.645 210.945 3.5499
234.126 215.613 3.3743
234.598 220.286 3.2055
235.740 231.990 2.8104
236.832 243.724 2.4496
237.878 255.484 2.1188
238.881 267.269 1.8143
239.845 279.076 1.5329
240.773 290.906 1.2719
241.667 302.756 1.0292
242.531 314.628 .8028
243 365 **9А R91 cq 1 t
ito.ouu OZO.OZl .ОУ1 1
244.173 338.435 .3925
244.956 350.370 .2058
245.715 362.327 .0299
246.452 374.306 -.1361
247.169 386.307 -.2932
247.866 398.332 -.4420
248.545 410.381 -.5833
249.206 422.454 -.7177
249.852 434.552 -.8457
250.481 446.676 -.9677
251.097 458.825 -1.0940
т
к
6200
6400
6600
6800
7000
7200
.7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 л елл
1 *tO\J\)
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
4
ч
IS
ОС
о
Таблица 142
(окончание)
ос
о 3
а
-
5 v: О
: & S
- ^ о
9 * fv|
6 rf \ /
j_ r- V
т
;.
W
ОС
¦»
1/
Г"
; -
3 «2 S
; В
: 6
? ? -
g «ч II
f
+ w
0
А.
206

Класс точности
ДИАЗОТ N2 (г)
"I абл и ца 143
Л Н[@) = 941.636 кДж-моль"
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ф°(Л
А'°1Л
Дж • К • моль
Н°(Т)~Н°@)
кДж • моль
29.104
29.107
29.124
29.125
29.249
29.580
30.109
30.754
31.433
32.090
32.696
33.241
33.723
34.147
34.517
34.842
35.127
35.377
35.598
35.795
35.969
36.126
36.267
36.394
36.509
36.614
36.710
36.799
36.881
36.956
37.027
37.093
37.155
37.213
37.268
37.320
37.369
37.417
37.462
37.505
37.547
37.588
37.628
37.667
37.705
37.743
37.780
37.817
37.855
37.893
37.931
37.971
38.011
38.053
38.096
38.141
38.188
38.238
38.291
38.346
38.405
130.678
150.811
162.418
162.598
170.967
177.466
182.792
187.316
191.260
194.765
197.927
200.811
203.466
205.929
208.228
210.385
212.418
214.341
216.165
217.902
219.560
221.145
222.664
224.123
225.526
226.878
228.182
229.442
230.661
231.841
232.984
234.094
235.172
236.220
237.239
238.232
239.198
240.141
241.061
241.958
242.835
243.692
244.530
245.350
246.153
246.939
247.709
248.464
249.204
249.929
250.642
251.341
252.028
252.702
253.365
254.017
254.658
255.288
255.908
256.518
257.118
159.700
179.874
191.498
191.678
200.070
206.628
212.065
216.754
220.905
224.646
228.059
231.201
234.115
236.831
239.375
241.768
244.026
246.163
248.192
250.122
251.962
253.721
255.405
257.020
258.571
260.064
261.502
262.889
264.229
265.524
266.778
267.994
269.172
270.316
271.428
272.509
273.561
274.586
275.584
276.558
277.508
278.436
279.342
280.228
281.094
281.942
282.772
283.585
284.381
285.162
285.928
286.680
287.417
288.142
288.853
289.553
290.241
290.917
291.582
292.237
292.882
2.902
5.813
8.670
8.724
11.641
14.581
17.564
20.607
23.716
26.892
30.132
33.430
36.778
40.172
43.606
47.074
50.573
54.098
57.647
61.217
64.806
68.411
72.030
75.663
79.309
82.965
86.631
90.307
93.991
97.683
101.382
105.088
108.800
112.519
116.243
119.972
123.707
127.446
131.190
134.938
138.691 ->
142.448
146.209
149.973
153.742
157.514
161.290
165.070
168.854
172.641
176.432
180.227
184.027
187.830
191.637
195.449
199.265
203.087
206.913
210.745
214.582
-487.2197
-240.8392
-159.6203
-158.5990
-117.4236
-92.6859
-76.1730
-64.3638
-55.4968
-48.5928
-43.0641
-38.5363
-34.7599
-31.5619
•28.8186
-26.4393
-24.3559
-22.5164
-20.8802
-19.4154
-18.0962
-16.9020
-15.8157
-14.8233
-13.9132
-13.0754
-12.3016
-11.5848
-10.9188
-10.2985
-9.7192
-9.1770
-8.6685
-8.1905
-7.7404
-7.3158
-6.9146
-6.5348
-6.1749
-5.8331
-5.5083
-5.1992
-4.9045
-4.6234
-4.3549
-4.0981
-3.8523
-3.6167
-3.3908
-3.1740
-2.9656
-2.7652
-2.5723
-2.3866
-2.2075
-2.0347
-1.8680
-1.7069
-1.5512
-1.4006
-1.2547
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
00
о
и
00
ON
р
О
ОС
оо
ЧО
чО
00
О
О
о
V
о
о
207

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
1350Q
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000.
19500
20000
38.534
38.680
38.846
39.035
39.249
39.491
39.763
40.068
40.407
40.784
41.198
41.652
42.146
42.681
43.257
43.874
44.531
45.227
45.959
46.727
48.780
50.984
53.273
55.574
57.810
59.907
61.795
63.420
64.740
65.728
66.374
66.684
66.673
66.368
65.802
65.010
64.032
62.903
61.659
60.331
ДИАЗОТ
Ф°G)
S°(T)
Дж К" -моль"
258.292 294.143
259.432 295.369
260.539 296.562
261.616 297.724
262.664 298.859
263.684 299.968
264.680 301.053
265.651 302.118
266.600 303.163
267.527 304.191
268.433 305.203
269.321 306.201
270.190 307.187
271.042 308.162
271.878 309.127
272.698 310.085
273.504 311.035
274.295 311.980
275.074 312.920
275.840 313.856
277.706 316.185
279.508 318.505
281.254 320.821
282.951 323.137
284.604 325.452
286.220 327.760
287.801 330.057
289.351 332.335
290.872 334.584
292.366 336.796
293.834 338.963
295.278 341.076
296.697 343.129
298.092 345.115
299.463 347.031
300.810 348.874
302.133 350.642
303.432 352.335
304.707 353.953
305.957 355.497
N2 (г)
#°(Л-Я°@)
кДж * моль""
222.276
229.997
237.749
245.537
253.365
261.239
269.164
277.146
285.193
293.312
301.509
309.793
318.172
326.654
335.248
343.960
352.800
361.775
370.893
380.161
404.030
428.966
455.028
482.240
510.590
540.026
570.461
601.776
633.829
666.459
699.497
732.774
766.125
799.395
832.446
865.156
897.422
929.169
960.301
990.800
\%К°{Т)
-.9768
-.7154
-.4693
-.2369
-.0171
.1911
.3887
.5765
.7552
.9256
1.0882
1.2436
1.3923
1.5347
1.6713
1.8023
1.9281
2.0490
2.1654
2.2774
2.5400
2.7800
я 0003
4.2028
3.3896
3.5622
3.7220
3.8702
4.0079
4.1360
4.2553
4.3667
4.4708
4.5682
4.6596
4.7455
4.8262
4.9023
4.9742
5.0422
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 143
(окончание)
'х -
sO I
О |
го
+ т
X . /-*
S ^ о
rf ^ О
чО f> О
00 X О
О О СМ
о Щ v
н 7 ^
— с* V
Г^ О о
•о »о ©
°°. . о
Г- X Ь
о о
29С
28.
и 1 ^
0
208

Класс точности
I-C
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯА0
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.137
29.139
29.321
29.752
30.379
31.098
31.820
32.497
33.11
1
33.660
34.153
34.603
35.025
35.431
35.832
36.236
36.649
37.074
37.512
37.962
38.423
38.891
39.364
39.838
40.309
40.775
41.232
41.678
42.111
42.530
42.934
43.321
43.693
44.049
44.389
44.716
45.030
45.332
45.625
45.908
46.183
46.451
46.715
46.975
47.232
47.487
47.742
47.997
48.252
48.508
48.766
49.026
49.288
49.553
49.819
50.088
50.359
50.631
50.906
К°(Т)= р2
Ф°(Т)
ПОЛОЖИТЕЛЬНЫЙ
(N) ^(N*) -p~l(e)
5°(Г)
Дж • К • моль
168.475
168.655
177.025
183.529
188.864
193.400
197.360
200.883
204.062
206.965
209.640
212.121
214.439
216.615
218.666
220.608
222.452
224.210
225.889
227.498
229.043
230.529
231.962
233.346
234.685
235.982
237.241
23&463
239.652
240.809
241.937
243.037
244.112
245.161
246.187
247.191
248.174
249.137
250.080
251.006
251.914
252.806
253.681
254.542
255.387
256.218
257.036
257.841
258.633
259.413
260.182
260.938
261.684
262.420
263.145
263.861
264.567
265.264
265.952
ИОН ДИАЗОТА N2+ (г)
АгИ
\Т)-Н°Ц))
кДж • моль
197.557
197.737
206.140
212.724
218.202
222.938
227.138
230.926
234.382
237.564
240.514
243.266
245.846
248.276
250.576
252.760
254.843
256.836
258.748
260.589
262.366
264.084
265.750
267.366
2Q8.938
270.468
271.959
273.Ф14
274.834
276.222
277.578
278.905
280.204
281.476
282.722
283.943
285.139
286.313
287.464
288.594
289.704
290.794
291.865
292.917
293.952
294.971
295.974
296.961
297.933
298.891
299.835
300.767
301.685
302.592
303.488
304.372
305.245
306.108
306.962
8.671
8.725
11.646
14.598
17.603
20.676
23.823
27.039
30.320
33.659
37.050
40.488
43.970
47.492
51.056
54.659
58.303
61.989
65.718
69.492
73.311
77.177
81.089
85.049
89.057
93.111
97 212
101.357
105.547
109.779
114.052
118.365
122.716
127.103
131.525
135.981
140.468
144.986
149.535
154.111
158.716
163.348
168.006
172.691
177.401
182.137
186.899
191.685
196.498
201.336
206.200
211.089
216.005
220.947
225.916
230.911
235.933
240.983
246.060
\0) - -561.674
\gK°(T)
103.4293
102.8198
78.2462
63.4795
53.6193
46.5644
41.2635
37.1326
33.8211
31.1058
28.8380
26.9146
25.2620
23.8262
22.5667
21.4524
20.4594
19.5684
18.7643
18.0347
17.3695
16.7603
16.2002
15.6833
15.2046
14.7599
14.3456
13.9586
13.5962
13.2559
12.9358
12.6340
12.3490
12.0793
11.8236
11.5809
11.3501
11.1304
10.9209
10.7209
10.5297
10.3467
10.1714
10.0033
9.8420
9.6870
9.5379
9.3944
9.2562
9.1229
8.9943
8.8702
8.7503
8.6343
8.5221
8.4136
8.3084
8.2065
8.1076
кДж • моль 1
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1О
<N
О
СО
II
Гн
00
VO
г-
~-1
о
+
''К
О
VO
VO
§
©
1
|
г»
оо
чо
On
+
CN
О
«—i
On
VD
СЧ
II
Ь
Таблица 144
Т
3
1 <?
л
о
* os 2
4ч- О
R. кг)
* on Т
2 g *
СО т—
3 " t§
2 Я -
II «О чО
/~^ - ОС
о » -
с ^ |!
¦ « с- о 5
\ °„
1
q
1
* Я
* 1
* S
™х V
ЧО V
1 о
°
X
г-
ГО t
О 1
^ 2
+ о
X ^
ГО II
*-*
14 872
209

г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р(Т)
51.458
52.013
52.566
53.115
53.656
54.184
54.695
55.186
55.653
56.092
56.500
56.873
57.210
57.508
57.764
57.977
58.146
58.270
58.349
58.383
58.272
57.896
57.280
56.456
55.461
54.331
53.101
51.806
50.472
49.124
47.782
46.462
45.176
43.934
42.740
41,599
40.513
39.484
38.510
37.591
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИАЗОТА N
ф°ОТ
Дж К • моль"
267.302
268.619
269.906
271.164
272.395
273.600
274.781
275.938
277.074
278.188
279.282
280.357
281.413
282.451
283.473
284.477
285.466
286.440
287.399
288.342
290.642
292.858
294.996
297.059
299.052
300.976
302.836
304.632
306.369
308.048
309.672
311.242
312,761
314.231
315.654
317.032
318.367
319.660
320.913
322.129
5° (Г)
-1
308.640
310.282
311.891
313.469
315.016
316.535
318.027
319.492
320.932
322.346
323.736
325.102
326.445
327.763
329.059
330.331
331.580
332.805
334.007
335.187
338.034
340.737
343.298
345.718
348.004
350.157
352.185
354.093
355.887
4v 357.576
359.165
360.661
362.071
363.401
364.657
365.845
366.970
368.036
369.049
370.012
Я°(Г)-Я°@)
к Дж' моль*1
256.296
266.643
277.101
287.669
298.346
309.131
320.019
331.007
342.092
353.267
364.527
375.864
387.273
398.746
410.274
421.848
433.461
445.104
456.767
468.440
497.616
526.668
555.471
583.913
611.899
639.352
666.213
692.442
71ft П1 ^
/ lO.vlO
742.912
767.137
790.697
813.605
835.881
857.547
878.629
899.155
919.152
938.648
957.672
2мг)
ig*°(r)
7.9186
7.7404
7.5720
7.4125
7.2613
7.1177
6.9811
6.8510
6.7269
6.6083
6.4950
6.3864
6.2824
6.1826
6.0867
5.9945
5.9058
5.8204
5.7380
5.6586
5.4716
5.2996
5.1407
4.9934
4.8565
4.7287
4.6093
4.4974
A QQO1
4.2933
4.2001
4.1121
4.0288
3.9500
3.8752
3.8042
3.7367
3.6725
3.6113
3.5433
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 А.*\(\(\
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 144
(окончание)
+
СО «ч
СО 1
ON *
гг% 5
*н О
о S
1 _'
™ к Я
J Й о
<ч (~ч ~
*° W §
8 х §
6 S м
, -н W
н 6
2 i ' к.
J3 1 Г*4
ON «V, V
со * v
? S <=>
• °° 2
г- • о
+ 1
^ х Т
оо и-> О
Г» ON ~*
О) «Л
Tj-  Ьч
V© Г- „
CN СМ
(N CN
II + ^
О

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
. 3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
30.868
32.009
36.174
36.255
40.392
43.917
46.856
49.282
51.271
52.897
54.229
55.323
56.226
56.977
57.606
58.136
58.585
58.970
59.300
59.586
59.834
60.052
60.243
60.411
60.561
60.695
60.814
60.921
61.018
61.105
61.184
61.256
61.321
61.381
61.436
61.487
61.533
61.576
61.616
61.653
61.687
61.718
61.748
61.775
61.801
61.825
61.848
61.869
61.889
61.907
61.925
61.942
61.957
61.972
61.986
61.999
62.012
62.024
62.035
62.046
62.056
К°(Т)= p3(N)
Ф°(Т)
Дж • К" • моль'
156.659
178.272
190.856
191.055
200.504
208.204
214.805
220.638
225.895
230.696
235.126
239.244
243.094
246.713
250.129
253.363
256.436
259.362
262.156
264.829
267.392
269.854
272.222
274.502
276.703
278.828
280.883
282.872
284.800
286.671
288.487
290.251
291.967
293.637
295.263
296.848
298.394
299.903
301.376
302.815
304.222
305.597
306.943
308.261
309.551
310.815
312.054
313.269
314.461
315.630
3f 6.778
317.905
319.013
320.100
321.170
322.221
323.255
324.272
325.272
326.257
327.227
S°iT)
188.019
209.424
222.957
223.181
234.191
243.594
251.869
259.280
265.995
272.131
277.776
282.997
287.851
292.382
296.628
300.621
304.388
307.952
311.332
314.546
317.609
320.533
323.331
326.013
328.587
331.062
333.445
335.742
337.960
340.102
342.175
344.183
346.129
348.016
349.850
351.631
353.364
355.051
356.693
358.294
359.856
361.379
362.867
364.320
365.741
367.130
368.489
369.819
371.122
372.398
373.649
374.875
376.079
377.259
378.417
379.555
380.672
381.770
382.848
383.909
384.952
ТРИАЗОТ N3
д
Н°(Т)-Н°((
кДж * моль
3.136
6.230
9.571
9.638
13.475
17.695
22.239
27.049
32.080
37.292
42.650
48.129
53.708
59.370
65.100
70.887
76.724
82.602
88.516
94.461
100.432
106.427
112.442
118.474
124.523
130.586
136.662
142.748
148.846
154.952
161.066
167.188
173.317
179.452
185.593
191,739
197.890
204.046
210.205
216.369
222.536
228.706
234.880
241.056
247.235
253.416
259.599
265.785
271.973
278.163
284.354
290.548
296.743
302.939
309.137
315.337
321.537
327.739
333.942
340.146
346.351
(г)
гИ°@) -973.021
))
•1
-499.2403
-243.9880
-159.6882
-158.6273
-115.8298
-90.0928
-72.9022
-60.6037
-51.3675
-44.1756
-38.4166
-33.7008
-29.7682
-26.4385
-23.5829
-21.1069
-18.9395
-17.0264
-15.3252
-13.8026
-12.4319
-11.1915
-10.0635
-9.0334
-8.0890
-7.2199
-6.4176
-5.6745
•4.9844
-4.3418
-3.7420
-3.1807
-2.6545
-2.1600
-1.6945
-1.2555
-.8409
-.4485
-.0767
.2762
.6115
.9306
1.2346
1.5246
1.8016
2.0664
2.3198
2.5626
2.7955
3.0190
3.2337
3.4402
3.6389
3.8303
4.0148
4.1928
4.3646
4.5306
4.6911
4.8463
4.9965
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
О
II
+
о
VO
+
V
X
«о
CN
Г^
»о
р
О
1
J5
о
го
+
Os
<ч
OS
р
чо
го
го
II
Ь
Таблица 145
"у4
'л ? Т.
1 & §
2 * §
Ч о Т
« 8 *
з ? а
ГО /-S т-Ч
гг & v©
11 2 5
о 2 "
* Я "
« ^ о 2
о 2
<
т
й
i
го о
s v
а. \/
+ V
"* §
ю
ON * *
°^ «*
ГО |
го о
' "Г
X Е^
«о
2 "
Р X
4-
211

Класс точности
I-B
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
480Q
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
32.283
30.445
29.862
29.858
29.954
30.493
31.243
32.031
32.770
33.425
33.990
34.473
34.883
35.234
35.533
35.792
36.016
36.212
36.384
36.537
36.673
36.796
36.907
37.009
37.102
37.188
37.267
37.342
О7 А\ 9
О/.41 ^
37.478
37.540
37.600
37.657
37.712
37.765
37.817
37.867
37.917
37.966
38.014
38.063
38.112
38.161
38.211
38.262
38.314
38.368
38.424
38.482
38.542
38.606
38.672
38.742
38.816
38.893
38.975
39.061
39.152
39.247
39.348
39.45*
к°(Т)= р(Ю •
Ф°(Л
Дж • К • моль
145.866
167.487
179.850
180.041
188.860
195.667
201.228
205.947
210.060
213.714
217.010
220.016
222.782
225.347
227.739
229.981
232.093
234.088
235.980
237.779
239.495
241.135
242.705
244.211
245.659
247.054
248.398
249.695
ne/ч QRH
252.164
253.340
254.480
255.587
256.663
257.709
258.727
259.719
260.685
261.628
262.547
263.445
264.323
265.181
266.020
266.841
267.645
268.433
269.204
269.961
270.703
271.432
272.146
272.848
273.537
274.215
274.881
275.536
276.180
276.813
277.437
278.051
ОКСИД АЗОТА N0
р(О) .^(NO
S°(T)
176.891
198.616
210.636
210.821
219.410
226.146
231.770
236.646
240.972
244.871
248.422
251.685
254.703
257.509
260.131
262.592
264.909
267.099
269.173
271.145
273.022
274.815
276.529
278.172
279.749
281.265
282.725
284.133
285.493
286.807
288.078
289.310
290.505
291.664
292.791
293.886
294.952
295.991
297.003
297.989
298.952
299.893
300.812
301.710
302.589
303.450
304.293
305.118
305.928
306.722
307.501
308.266
309.018
309.756
310.483
311.197
311.900
312.592
313.274
313.946
314.608
) v#
//V)-//°«.)
кДж • моль"
3.103
6.226
9.179
9.234
12.220
15.240
18.325
21.489
24.730
28.041
31.412
34.836
38.304
41.811
45.349
48.916
52.507
56.118
59.748
63.394
67.055
70.728
74.414
78.110
81.815
85.530
89.253
92.983
Qfi 791
УО. I Z\
100.465
104.216
107.973
111.736
115.505
119.278
123.058
126.842
130.631
134.425
138.224
142.028
145.837
149.650
153.469
157.293
161.121
164.955
168.795
172.640
176.491
180.349
184.212
188.083
191.961
195.846
199.740
203.641
207.552
211.472
215.402
219.342
(г)
D@) =626.840
-323.3698
-159.2213
-105.0679
-104.3866
-76.9124
-60.3953
-49.3636
-41.4705
-35.5415
-30.9235
-27.2242
-24.1939
-21.6657
-19.5242
-17.6868
• -16.0929
-14.6969
-13.4641
-12.3674
-11.3852
-10.5006
-9.6997
-8.9710
-8.3052
-7.6944
-7.1321
-6.6127
-6.1314
- ЛЛ1П
-5.2676
-4.8784
-4.5142
-4.1724
-3.8512
-3.5487
-3.2632
-2.9934
-2:7380
-2.4959
-2.2661
-2.0475
-1.8395
-1.6412
-1.4520
-1.2712
-1.0983
-.9328
-.7742
-.6220
-.4759
-.3356
-.2006
-.0706
.0546
.1752
.2917
.4040
.5126
.6176
.7191
.8173
Таблица 146
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЯПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
л
1
Т 2 7
с ' л
§ й |
7*7
- а *> 7
^ \> <*i v
8 ! j
со ^Т t^
° С4 \о
и а\ * Ji:
о со
U СЧ
О bog
So"
ь
+
о Т
СО А
СО О
О
"** 1
с* ^
г- Р^ о
1 \ "°
я S v
- •? s
ON °° *°
со р
^ о> Т
СО '"н ®
. 1
• ' о
«NX К
ЧО О
со ю и
VO О\
i з *
II 4-
С
О
•е-
212

ОКСИД АЗОТА NO (г)
Таблица 146
(окончание)
с; (г»
Ф°G)
s°cn
Дж К -моль
Н\Т)-Н°{й)
кДж' моль
\%К°{Т)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13^00
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
39.681
39.930
40.201
40.494
40.808
41.142
41.495
41.865
42.250
42.648
43.056
43.472
43.892
44.310
44.732
45.153
45.563
45.963
46.350
46.726
47.582
48.303
48.957
49.267
49.495
49.555
49.458
49.217
48.848
48.567
47.796
47.150
46.445
45.697
44.919
44.122
43.317
42.511
41.713
40.926
279.251
280.417
281.549
282.651
283.724
284.769
285.789
286.785
287.758
288.709
289.640
290.552
291.445
292.321
293.180
294.024
294.853
295.667
296.468
297.255
299.170
301.014
302.794
304.512
306.176
307.788
309.351
310.868
312.340
313.779
315.162
316.514
317.828
М9.107
320.351
321.561
322.739
323.886
325.003
326.091
315.905
317.169
318.402
319.606
320.785
321.939
323.071
324.183
325.275
326.350
327.408
328.450
329.478
330.491
331.491
332.480
333.456
334.419
335.371
336.311
338.612
340.843
343.016
345.092
347.108
349.051
350.920
352.714
354.435
3^6.131
357.660
359.168
360.608
361.983
363.296
364.550
365.748
366.893
367.987
369.033
227.255
235.216
243.228
251.297
259.427
267.622
275.885
284.221
292.632
301.122
309.692
318.345
327.081
335.895
344.797
353.796
362.867
372.020
381.252
390.560
414.141
438.118
462.550
486.958
511.655
536.424
561.182
585.856
610.376
635.283
658.726
682.464
705.864
728.899
751.553
773.809
795.670
817.126
838.180
858.837
1.0047
1.1807
1.3466
1.5031
1.6511
1.7912
1.9242
2.0505
2.1706
2.2851
2.3942
2.4985
2.5981
2.6935
2.7848
2.8724
2.9565
3.0372
3.1148
3.1895
3.3642
3.5238
3.6700
3.8045
3.9286
4.0435
4.1501
4.2492
4.3418
4.4279
4.5095
4.5857
4.6576
4.7254
4.7895
4.8503
4.9079
4.9628
5.0151
5.0651
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
00
со
о
О
1
ё
00
00
с-
+
389
«о
302
со
н
00
чо
1
г»
об
+
1
оо
со
It
н
213

Класс точности
I-B
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400-
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;т
29.123
29.124
29.243
29.567
30.088
30.726
31.402
32.058
32.665
33.212
33.698
34.124
34.499
34.827
35.115
35.370
35.594
35.794
35.972
36.132
36.275
36.405
36.523
36.631
36.730
36.821
36.905
' 36.984
37.056
37.125
37.189
37.249
37.306
37.361
37.412
37.461
37.509
37.554
37.598
37.640
37.681
37.720
37.759
37.797
37.834
37.870
37.906
37.942
37.977
38.013
38.048
38.084
38.119
38.156
38.193
38.231
38.271
38.312
38.355
ПОЛОЖИТЕЛЬНЫЙ
К°(Т)= p(N) •
Ф°(П
Дж • К • моль
169.042
169.222
177.590
184.089
189.415
193.938
197.881
201.384
204.544
207.427
210.080
212.542
214.840
216.996
219.028
220.949
222.773
224.509
226.165
227.750
229.269
230.727
232.130
233.481
234.785
236.044
237.263
238.443
239.586
240.696
241.774
242.821
243.841
244.833
245.800
246.743
247.662
248.560
249.437
250.295
251.133
251.953
252.756
253.542
254.312
255.067
255.808
256.534
257.246 _
257.946
258.633
259.308
259.971
260.623
261.264
261.894
262.515
263.125
263.727
р(О) .^(NQ
S°(T)
-1
198.122
198.302
206.693
213.249
218.683
223.368
227.515
231.252
234.661
237.801
240.712
243.427
245.969
248.361
250.618
252.755
254.783
256.713
25$.553
260:312
261.996
263.612
265.164
266.657
268.096
269.484
270.824
272.121
273.376
274.592
275.772
276.917
278.030
279.112
280.165
281.191
282.191
283.165
284.117
285.046
285.953
286.840
287.708
288.557
289.388
290.202
291.000
291.782
292.549
293.301
294.040
294.765
295.477
296.177
296.864
297.541
298.206
298.861
299.505
ИОН ОКСИДА
+ )-р~1(е) Art
Н°{Т)-Н°ф)
кДж • моль
8.670
8.724
11.641
14.580
17.561
20.601
• 23.708
26.881
30.117
33.412
36.758
40.149
43.581
47.048
50.545
54.070
57.618
61.188
64.776
68.381
к 72.002
75.636
79.282
82.940
86.608
90.286
93.972
97.667
101.369
105.078
108.794
112.516
116.243
119.977
123.715
127.459
131.208
134.961
138.718
142.480
146.246
150.016
153.790
157.568
161.350
165.135
168.924
172.716
176.512
180.312
184.115
187.921
191.732
195.545
199.363
203.184
207.009
210.838
214.672
, АЗОТА NO+ (г)
/°@) = -267.010 кДж • моль
\gK°(T)
52.0892
51.7986
40.0763
33.0225
28.3054
24.9248
22.3804
20.3938
18.7981
17.4869
16.3894
15.4565
14.6530 ,
13.9532
13.3379
12.7922
12.3047
11.8662
11.4695
11.1088
10.7790
10.4764
10.1975
9.9396
9.7002
9.4774
9.2694
9.0748
8.8921
8.7203
8.5585
8.4056
8.2610
8.1240
7.9940
7.8703
7.7526
7.6403
7.5332
7.4308
7.3328
7.2390
7.1490
7.0626
6.9796
6.8998
6.8230
6.7490
6.6777
6.6089
6.5425
6.4783
6.4163
6.3563
6.2983
6.2420
6.1876
6.1348
6.0836
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
600
5700
5800
5900
6000
-1
со
§
о
со
II
+
4993
о
+
й
со
О
со
О
о
о
1
1
«о
Os
П-
<N
00
+
""si-
•о
я
о
•е-
Т а б л и
i
§
к
п
V
VO
00
Os
II
О
С
1
О
Т
1
Т
го
Н
_;
*-*
Ч*
С4
&
ЧО
<ч
1
X
On
«
со
4-
т
§
1
со
о
со
о
On
On
II
«о
*~2
00
ON
<N
+о
Z
0
а?
•*
<1
Ца 147
i
§
Tf
ON
II
о 5
со
[0009
V
V
V
о
.о
»о
^-
1
о
II
214

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Г)
38.446
38.548
38.663
38.794
38.943
39.116
39.314
39.542
39.804
40.102
40.441
40.825
41.255
41.735
42.268
42.855
43.497
44.196
44.951
45.762
48.021
50.576
53.356
56.267
59.198
62.030
64.649
66.949
68.847
70^288
71.239
71.698
71.685
71.239
70.410
69.257
67.842
66.225
64.461
62.601
ПОЛОЖИТЕЛЬНЫЙ ИОН
фоG)
Дж К • моль"
264.901
266.041
267.148
268.225
269.273
270.293
271.288
272.258
273.205
274.131
275.035
275.920
276.787
277.636
278.468
279.285
280.086
280.874
281.648
282.409
284.263
286.051
287.784
289.470
291.114
292.723
294.301
295.852
297.378
298^881
300.364
301.825
303.266
304.685
306.083
307.460
308.814
310.145
311.453
312.736
-1
300.764
301.986
303.174
304.330
305.457
306.556
307.631
308.682
309.713
310.724
311.718
312.697
313.663
314.617
315.560
316.496
317.424
318.347
319.266
320.183
322.468
324.760
327.069
329.401
331.757
334.135
336.526
338.920
341.303
343.663
345.984
348.255
350.462
352.596
354.650
356.618
358.496
360.284
361.982
363.590
ОКСИДА АЗОТА NO+ (г)
#°(Г)-Я°@)
кДж • моль""
222.352 5.9856
230.051 5.8933
237.772 5.8059
245.517 5.7233
253.290 5.6449
261.096 5.5705
268.938 5.4998
276.823 5.4324
284.757 5.3682
292.747 5.3068
300.801 5.2482
308.927 5.1921
317.134 5.1384
325.432 5.0868
333.832 5.0373
342.343 4.9896
350.977 4.9438
359.746 4.8996
368.659 4.8569
377.730 4.8157
401.162 4.7184
425.800 4.6282
451.775 4.5440
479.177 4.4649
508.044 4.3901
538.357 4.3188
570.037 4.2506
602.951 4.1851
636 917 4 1217
671.719 4.0603
707.120 4.0007
742.873 3.9426
778.736 3.8860
814.482 3.8308
849.906 3.7769
884.833 3.7243
919.115 3.6730
952.636 3.6229
985.310 3.5740
1017.075 3.5167
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 147
(окончание)
1
'а т
V© Л
с- §
. А
СО
'11 g
1 s I
2 v
1 »' v •
? Л v
»—« On О
•о *o о
*-( CO О
*О *"Н *™^
•4* ' + *л
<N Г- О
as rt **
00 ") ?*"*
Os »-н it
CN CO "
II 1 3
g
?
215

Класс точности
IV-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.316
34.486
37.178
37.236
40.513
43.664
46.383
48.612
50.405
51.844
53.007
53.956
54.741
55.399
55.960
56.446
56.874
57.258
57.609
57.936
58.246
58.545
58.838
59.129
59.419
59.713
60.010
60.312
60.620
60.935
61.255
61.583
61.915
62.254
62.598
62.947
63.300
63.657
64.017
64.380
64.745
65.112
65.481
65.851
66.221
66.591
66.962
67.331
' 67.700
68.068
68.435
68.799
69.161
69.521
69.879
70.233
70.584
70.932
71.276
71.617
71.953
К°(Т)= p(N) •
Ф°(Л
Дж • К • моль
169.222
192.323
205.819
206.031
216.037
224.080
230.903
236.884
242.238
247.104
251.574
255.713
259.571
263.187
266.591
269.808
272.858
275.758
278.524
281.167
283.698
286.126
288.461
290.709
292.877
294.970
296.995
298.954
300.854
302.697
304.488
306.228
307.923
309.573
311.181
312.750
314.282
315.779
317.242
318.673
320.075
321.447
322.792
324.110
325.404
326.672
327.919
329.143
330.346
331.529
332.692
333.836
334.963
336.072
337.164
338.240
339.300
340.345
341.376
342.392
343.395
ДИОКСИД
р2 (О) • р (NO2)
и
АЗОТА
Д
°(П-//°((
кДж • моль
202.484
225.818
240.057
240.288
251.445
260.830
269.039
276.362
282.975
288.998
294.523
299.621
304.350
308.758
312.885
316.762
320.419
323.879
327.162
330.286
333.266
336.115
338.845
341.467
343.989
346.420
348.769
351.039
353.238
355.371
357.442
359.456
361.416
363.327
365.190
367.010
368.788
370.527
372.230
373.897
375.532
377.135
378.707
380.254
381.772
383.264
384.732
386.176
387.597
388.997
390.376
391.734
393.074
394.395
395.698
396.983
398.251
399.504
400.741
401.962
403.168
3.326
6.699
10.208
10.277
14.163
18.375
22.881
27.635
32.589
37.704
42.949
48.299
53.735
59.243
64.811
70.432
76.099
81.806
87.549
93.326
99.136
104.975
110.845
116.743
122.670
128.627
134.613
140.629
146.676
152.753
158.863
165.005
171.179
177.388
183.630
189.907
196.220
202.568
208.951
215.371
221.828
228.320
234.850
241.417
248.020
254.661
261.338
268.053
274.805
281.593
288.418
295.280
302.178
309.112
316.082
323.088
330.128
337.205
344.314
351.460
358.638
NO2 (г)
г//°@) = 927.384
))
'1
\%К°{Т)
-475.6333
-232.2552
-151.8490
-150.8369
-110.0051
-85.4442
-69.0355
-57.2941
-48.4746
-41.6059
-36.1047
-31.5991
-27.8410
-24.6584
-21.9285
-19.5609
-17.4879
-15.6578
-14.0301
-12.5730
-11.2610
-10.0734
-8.9934
-8.0069
-7.1022
-6.2697
-5.5010
-4.7891
-4.1278
-3.5120
-2.9372
-2.3993
-1.8950
-1.4212
-.9753
-.5547
-.1576
.2182
.5741
.9118
1.2326
1.5377
1.8283
2.1054
2.3699
2.6225
2.8642
3.0956
3.3172
3.5299
3.7339
3.9300
4.1185
4.2998
4.4744
4.6426
4.8048
4.9613
5.1123
5.2582
5.3992
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
g
и
+
00
<ч
+
00
О
00
s
о
о
1
j=j
ю
со
as
00
as
•о
со
о
ь
Таб
I
§
к
о
§
Г"»
со
II
о
С
гГ
jz;
о
а:
i
О
Г
к
ГО
СО
со
+
CN
(N
СО
1
X
00
VO
2
Л И
1
А
о
|
as
rf
СО
II
2"
WO
as
6
о
ца 148
i
л
§
I
к
со
^°.
ON
' со*
2
о
о
ЧО
V
V
§
1
о
II
w
216

Класс точности
Y-I
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2о00
2600
2700
ПОПА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000 .
37.214
37.282
41.096
44.555
47.328
49.458
51.080
52.320
53.280
54.034
54.632
55.114
55.508
55.832
56.102
56.330
56.524
56.690
56.834
56.962
57.075
57.178
57.274
57.364
57.451
57.538
57.624
57.714
57.806
57.904
58.007
58.116
58.233
58.357
58.488
58.628
58.775
58.931
59.094
59.264
59.441
59.625
59.814
60.009
60.209
60.413
60.621
60.831
61.044
61.258
61.473
61.688
61.903
62.117
62.330
62.540
62.748
62.952
63.154
ОТРИЦАТЕЛЬНЫЙ
к°(Т) = р(Ю ¦
Ф°(Т)
Дж • К • моль"
201.994
202.205
212.194
220.254
227.117
233.149
238.557
243.474
247.989
252.169
256.061
259.705
263.132
266.366
269.429
272.338
275.108
277.751
280.280
282.703
285.029
287.266
289.419
291.496
293.502
295.441
9Q7 Ч17
299.135
300.899
302.610
304.273
305.891
307.464
308.997
310.491
34.948
313.371
314.760
316.117
317.444
318.742
320.013
321.257
322.477
323.672
324.845
325.995
327.124
328.233
329.323
330.393
331.445
332.481
333.499
334.501
335.487
336.458
337.415
338.358
р2(О) -р{е)
S°iT)
-l
236.128
236.358
247.605
257.158
265.537
273.000
279.715
285.806
291.371
296.485
301.214
305.606
309.706
313.547
317.159
320.567
323.792
326.853
329.765
332.541
335.193
337.733
340.168
342.508
344.760
346.930
349.024
351.047
353.005
354.903
356.742
358.529
360.266
361.956
363.601
365.206
366.771
368.300
369.794
371.255
372.685
374.086
375.459
376.805
378.127
379.424
380.698
• 381.950
383.181
384.392
385.583
386.756
387.912
389.049
390.171
391.276
392.365
393.439
394.499
ИОН ДИОКСИДА АЗОТА
V(NO} АгИ
//°<Г)-#°<())
кДж • моль
10.177
10.246
14.164
18.452
23.052
27.896
32.927
38.100
43.382
48.749
54.183
59.671
65.203
70.771
76.368
81.990
87.633
93.293
98.970
104.660
110.362
116.074
121.797
127.529
133.270
139.019
1 Л.А 777
1 ft. ill
150.544
156.320
162.106
167.901
173.707
179.524
185.354
191.196
197.052
202.922
208.807
214.708
220.626
226.561
232.514
238.486
244.477
250.488
256.519
262.571
268.644
274.737
280.852
286.989
293.147
299.327
305.528
311.750
317.994
324.258
330.543
336.848
V(J) = 1155
\оК °(Т\
ЩЛ. \1 )
-191.5890
-190.3238
-139.2544
-108.4974
-87.9231
-73.1814
-62.0931
-53.4451
-46.5086
-40.8190
-36.0660
-32.0346
-28.5710
-25.5623
-22.9237
-20.5903
-18.5116
-16.6476
-14.9664
-13.4420
-12.0532
-10.7825
•9.6152
-8.5390
-7.5435
-6.6198
-5.7604
-4.9585
-4.2085
-3.5055
-2.8450
-2.2233
-1.6370
-1.0830
-.5588
-.0618
.4099
.8584
1.2853
1.6922
2.0806
2.4516
2.8065
3.1464
3.4721
3.7846
4.0847
4.3731
4.6506
4.9177
5.1751
5.4233
5.6628
5.8940
6.1175
6.3335
6.5426
6.7450
6.9410
NO2" (г)
.384 кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
V©
о
vo
II
+
о>
г-
s
»о
*—<
с*
'к
3
CN
о
о
1
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+
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ON
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II
Таб
1
2
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2
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и
о
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2
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2
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00
+
fH
Tf
1
о
vo
л и u
T
1
г.
к
8
CN
I
II
Ь4
*о
00
CN
С
1 М
О
2
о
а;
<\
1
а 149
|
со
ЧО
On
II
п
О BJ
to
я
О
о
о
VO
V
V
о
о
1
О
э
II
>:
217

-Класс точности
V-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
44.723
44.881
52.976
59.579
64.599
68.345
71.149
73.272
74.904
76.177
77.186
77.996
78.656
79.199
79.650
80.030
80.352
80.627
80.863
81.069
81.248
81.405
81.543
81.666
81.775
81.872
81.960
82.039
82.110
82.175
82.234
82.287
82.336
82.381
82.423
82.461
82.496
82.528
82.558
82.586
82.612
82.637
82.659
82.680
82.700
82.719
82.736
82.753
82.768
82.783
82.796
82.809
82.821
82.833
82.844
82.854
82.864
82.874
82.882
ОТРИЦАТЕЛЬНЫЙ
К°(Т)= p(N) •
Ф°(Л
Дж • К • ¦ моль
209.391
209.614
220.452
229.609
237.703
245.023
251.736
257.945
263.728
269.142
274.230
279.031
283.575
287.888
291.991
295.905
299.646
303.228
306.664
309.966
313.143
316.204
319.158
322.011
324.771
327.442
330.031
332.543
334.981
337.351
339.655
341.897
344.081
346.209
348.285
350.310
352.287
354.218
356.106
357.952
359.758
361.526
363.257
364.953
366.615
368.245
369.843
371.412
372.951
374.463
375.947
377.406
378.840
380.249
381.635
382.998
384.339
385.659
386.959
р3(О).р(е)
S°(T)
-1
245.523
245.800
259.847
272.409
283.737
293.990
303.308
311.817
319.625
326.826
333.499
339.711
345.516
350.961
356.088
360.928
365.512
369.864
374.006
377.956
381.732
385.347
388.814
392.145
395.351
398.439
401.418
404.295
407.078
409.771
412.381
414.912
417.370
419.757
422.078
424.337
426.537
428.680
430.770
432.809
434.799
436.743
438.644
440.501
442.319
444.098
445.839
447.545
449.217
450.857
452.464
454.041
455.589
457.109
458.602
460.068
461.509
462.926
464.319
ИОН ТРИОКСИДА АЗОТА
3 г
Н°(Т)-Н°@)
кДж • моль" 1
10.773
10.856
15.758
21.400
27.621
34.277
41.258
48.484
55.896
63.453
71.123
78.884
86.717
94.611
102.554
110.538
118.558
126.607
134.682
142.779
150.895
159.028
167.175
175.336
183.508
191.690
199.882
208.082
216.289
224.504
232.724
240.950
249.182
257.417
265.658
273.902
282.150
290.401
298.655
306.912
315.172
323.435
331.700
339.967
348.236
356.507
364.780
373.054
381.330
389.608
397.886
406.167
414.448
422.731
431.015
439.300
447.586
455.872
464.160
°@) = 1509.
о
-246.7272
-245.0731
-178.3110
-138.1126
-111.2326
-91.9819
-77.5098
-66.2293
-57.1867
-49.7742
-43.5860
-38.3408
-33.8374
-29.9280
-26.5019
-23.4742
-20.7788
-18.3635
-16.1865
-14.2139
-12.4181
-10.7761
-9.2687
-7.8800
-6.5963
-5.4060
-4.2992
-3.2673
-2.3028
-1.3993
-.5511
.2469
.9989
1.7090
2.3806
3.0168
3.6204
4.1938
4.7394
5.2591
5.7548
6.2282
6.6807
7.1138
7.5286
7.9265
8.3084
8.6752
9.0280
9.3674
9.6944
10.0095
10.3135
10.6069
10.8903
11.1643
11.4292
11.6857
11.9340
no; (г)
167 кДж- моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Я
о
ч©
II
+
00
со
+
г»
ЧО
CN
«О
О
О
js
CN
СО
Os
00
с^
Os
iO
1—4
,—1
ь
Таблица 150
Т
1
i j>
к * й
С} оо о
О
о со 7
00 „ &
OS "
CN y^ %
/""*•> '" 00
О 00 Г-
С S f
о ,; о?
5 о *э
° 5
«L °
< \
i
А
О
к §
(Г) О
00 V
CN
6 ^
+ V
2 S>
On *t
^ 'о
^ —<
1 о
Н ^
О II
с-
CN
218

Класс точности
I -С
Т
К
100
200
298.15
. 300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.352
33.618
38.628
38.712
42.703
45.876
48.483
50.653
52.465
53.979
55.246
56.310
57.209
57.974
58.629
59.196
59.690
60.123
60.508
60.851
61.159
61.439
61.695
61.929
62.147
62.349
62.538
62.716
62.884
63.044
63.197
63.344
63.484
63.620
63.752
63.880
64.005
64.126
64.246
64.363
64.477
64.591
64.702
64.813
64.922
65.030
65.137
65.244
65.350
65.455
65.560
65.665
65.769
65.873
65.977
66.080
66.184
66.287
66.391
66.495
66.598
К°(Т)= p2(N)
Ф°(Т)
Дж • К • моль
154.968
175.371
187.762
187.961
197.514
205.393
212.180
218.185
223.596
228.533
233.084
237.310
241.259
244.967
248.464
251.774
254.917
257.910
260.767
263.501
266.121
268.637
271.058
273.390
275.640
277.813
279.915
281.951
283.924
285.839
287.698
289.506
291.264
292.976
/ 294.644
296.270
297.856
299.405
300.918
302.397
303.843
305.258
306.643
307.999
309.328
310.631
311.908
313.162
314.392
315.599
16.785
317.950
319.095
320.221
321.328
322.417
323.489
324.543
325.582
326.604
327.612
ОКСИД
• р(О) -p-^N
S°(T)
184.082
205.506
219.896
220.135
231.842
241.724
250.326
257.968
264.853
271.123
276.878
282.195
287.134
291.744
296.065
300.130
303.966
307.598
311.046
314.327
317.456
320.447
323.311
326.059
828.699
331.240
333.689
336.053
338.337
340.546
342.686
344.761
346.774
348.730
350.631
352.481
354.282
356.037
357.749
359.419
361.050
362.644
364.202
365.725
367.217
368.677
370.107
371.509
372.884
374.233
375.556
376.855
378.132
379.385
380.618
381.829
383.021
384.193
385.347
386.483
387.601
ДИАЗОТА
2О) Д
Н°(Т)-Н°(
кДж * моль
2.911
6.027
9.581
9.652
13.731
18.166
92.888
27.848
33.006
38.331
43.794
49.373
55.051
60.811
66.642
72.534
78.478
84.470
90.501
96.570
102.670
108.801
114.958
121.139
127.343
133.568
139.812
146.075
152.355
158.652
164.964
171.291
177.632
183.987
190.356
196.738
203.132
209.539
215.957
222.388
228.830
235.283
241.748
248.223
254.710
261.208
267.716
274.235
280.765
287.305
293.856
300.417
306.989
313.571
320.163
326.766
333.379
340.003
346.637
353,281
359.936
N2O (г)
irH°@) = 1103
0)
-1
iCT К° (Т\
lgA {? )
-567.0363
-277.6110
-182.0536
-180.8512
-132.3596
-103.2102
-83.7473
•69.8273
-59.3760
-51.2399
-44.7260
-39.3930
-34.9464
-31.1821
-27.9542
-25.1558
-22.7065
-20.5448
-18.6230
-16.9031
-15.3550
-13.9542
-12.6806
-11.5177
-10.4516
-9.4709
-8.5655
-7.7272
-6.9488
-6.2241
-5.5477
-4.9150
-4.3218
-3.7646
-3.2402
-2.7458
-2.2788
-1.8371
-1.4187
-1.0217
-.6445
-.2858
.0560
.3818
.6929
.9901
1.2745
1.5468
1.8079
2.0583
2.2988
2.5299
2.7522
2.9662
3.1723
3.3710
3.5627
3.7478
3.9265
4.0993
4.2665
.390 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
сч
:44.0
II
+
о
ON
VO
+
'ч
S
S
со
Я
о
1
1
CN
СО
ЧО
+
со
сч
CN
CN
СО
?^
о
ь
Таб л и ца 151
Т
б
«§
К
9\
СЧ
О
*о
00
II
о
о
г»
о
<
Л
2
i
ми
к
ё
S
о
+
ЧО
о
о
+
CN
1
п .
Л 1
§ 1
* 7
О »н
V© ^
и сз
Q *>
*о г:
Г? 00
00 *"н
О\
СЧ II
К о?
о
Я
о
о
VO
V
V
о
о
• •
i
о
II
219

Класс точности j
j
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
c°pm
52.738
66.551
72.712
72.805
77.504
81.705
85.366
88.403
90.866
92.914
94.528
95.830
96.947
97.825
98.551
99.156
99.665
100.097
100.538
100.867
101.155
101.411
101.642
101.852
102.046
102.227
102.399
102.563
102.721
102.874
103.025
103.173
103.318
103.462
103.605
103.746
103.960
104.101
104.240
104.378
104.513
104.647
104.778
104.907
105.033
105,157
105.278
105.395
105.509
105.620
105.727
105.831
105.932
106.028
106.121
106.210
106.295
106.377
106.454
106.528
106.599
К°(Т)= P2(N)
Ф°(Т)
Дж • К ' • моль
203.370
235.494
257.212
257.568
274.755
288.963
301.184
311.925
321.547
330.334
338.372
345.806
352.759
359.241
365.333
371.082
376.525
381.693
386.667
391.369
395.867
400.177
404.315
408.293
412.125
415.820
419.388
422.838
426.177
429.412
432.549
435.596
438.555
441.434
444.235
446.963
449.662
452.256
454.788
457.260
459.676
462.037
464.347
466.608
468.821
470.989
473.113
475.196
477.238
479.242
481.209
483.141
485.038
486.902
488.733
490.534
492.306
494.048
495.762
497.450
499.111
ТРИОКСИД
• р3(О) • ^(N
S°(T)
-1
245.277
286.799
314.619
315.069
336.662
354.420
369.642
383.054
395.055
405.849
415.734
424.820
433.189
440.990
448.273
455.101
461.526
467.590
473.305
478.753
483.938
488.883
493.610
498.136
502.479
506.653
510.670
514.541
518.278
521.890
525.384
528.768
532.050
535.236
538.330
541.340
544.220
547.071
549.850
552.560
555.204
557.788
560.312
562.780
565.193
567.556
569.869
572.135
574.356
576.534
578.669
580.765
582.822
584.841
586.825
588.774
590.689
592.572
594.424
596.244
598.036
ДИАЗОТА N
о3) лги
кДж • моль
4.191
10.261
17.116
17.250
24.763
32.729
41.075
49.790
58.806
67.963
77.362
86.915
96.516
106.274
116.116
126.029
136.002
146.024
155.949
166.029
176.141
186.282
196.449
206.639
216.851
227.082
237.332
247.600
257.884
268.185
278.502
288.835
299.183
309.546
319.924
330.317
340.409
350.814
361.233
371.666
382.114
392.575
403.049
413.537
424.038
434.552
445.078
455.616
466.166
476.727
487.300
497.883
508.476
519.080
529.693
540.316
550.947
561.587
572.235
582.891
593.554
2О3 W
Ъ> = 1590.785
-812.2653
-394.5314
-256.6122
-254.8770
-184.8939
-142.8276
-114.7422
-94.6551
-79.5736
-67.8356
-58.4372
-50.7427
-44.3289
-38.8981
-34.2413
-30.2040
-26.6702
-23.5513
-20.7810
-18.2995
-16.0658
-14.0444
-12.2065
-10.5281
-8.9894
-7.5736
-6.2665
-5.0561
-3.9320
-2.8854
-1.9084
-.9944
-.1374
.6678
1.4257
2/1403
2.8133
3.4519
4.0569
4.6310
5.1765
5.6955
6.1899
6.6614
7.1116
7.5418
7.9535
8.3478
8.7258
9.0884
9.4367
9.7715
10.0936
10.4036
10.7023
10.9903
11.2681
11.5363
11.7955
12.0460 *
12.2884
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
3
II
+
X?
+
v
X
оо
о
со
Г"»
о
О
О
с
1
ON
r-
»—I
со
fN
•О
Таблица 152
л
~ о
л
? §
* . 1
о so iy
§ оо *
<N || *
ON V/» t^
11 «о <-"*
/-ч ? О
% g ON
о" * "
Zr ow о 2
Z ^ со
^ 0
<]
T
T
« I
00 v .
о V
+ v
w* I
CO
On ^•
со О
1 ,
00 II
о
о ^
о w
220

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
> 2300
2400
2500
2600
2700
ОСЛО
ZOUv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000 -
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
c°pm
47.535
65.204
79.157
79.389
90.461
99.018
105.448
110.245
113.843
116.561
118.629
120.251
121.531
122.547
123.374
124.051
124.619
125.097
125.498
125.837
126.126
126.373
126.585
126.769
126.928
127.067
127.489
127.296
127.390
127!б41
127.623
127.697
127.763
127.822
127.875
127.923
127.967
128.006
128.042
128.132
128.166
128.196
128.225
128.251
128.274
128.296
128.317
128.335
128.353
128.369
128.383
128.397
128.410
128.422
128.433
128.443
128.452
128.461
128.538
128.548
128.557
A'°m = p*(N)
Ф°(Л
Дж • К~1 • моль
191.544
227.454
248.190
248.539
265.754
280.610
293.834
305.795
316.733
326.820
336.204
344.944
353.146
360.875
368.161
375.054
381.619
387.877
393.843
399.545
405.004
410.240
415.272
420.115
424.782
429.286
433.638
437.848
441.924
445^936
449.777
453.508
457.134
460.661
464.093
467.437
470.696 .
473.875
476.978
480.045
483.007
485.904
488.736
491.508
494.221
496.878
499.482
502.034
504.537
506.992
509.401
511.766
514.088
516.370
518.612
520.815
522.981
525.112
527.251
529.315
531.346
ТЕТРОКСИД ДИАЗОТА N2O4 (г)
V@)V(N
S°(T)
-1
231.042
275.610
304.353
304.844
329.273
350.410
369.064
385.698
400.666
414.243
426.631
438.017
448.535
458.300
467.415
475.959
483.978
491.540
498.697
505.490
511.954
518.118
524.007
529.645
535.052
540.245
545.241
550.054
554.696
559.124
563.452
567.641
571.699
575.636
579.456
583.169
586.778
590.289
593.709
597.005
600.251
603.418
606.509
609.529
612.480
615.365
618.188
620.950
623.655
626.304
628.900
631.446
633.942
636.391
638.794
641.154
643.472
645.748
647.952
650.150
652.312
2О4) АгИ°@) = 1908.368 кДж мо
Я°(Г)-/Л<»
кДж • моль
Т
К
3.950 -971.5912 100
9.631 -470.2982 200
16.745 -304.5507 298.15
16.892 -302.4645 300
25.408 -218.3219 400
34.900 -167.7360 500
45.138 -133.9634 600
55.933 -109.8139 700
67.147 -91.6869 800
78.680 -77.5793 900
90.427 -66.2890 1000
102.380 -57.0474 1100
114.468 -49.3444 1200
126.652 -42.8258 1300
138.956 -37.2370 1400
151.358 -32.3925 1500
163.775 -28.1543 1600
176.227 -24.4149 1700
188.737 -21.0908 1800
201.297 -18.1164 1900
213.901 -15.4395 2000
226.542 -13.0175 2100
239.216 -10.8157 2200
251.919 -8.8055 2300
264.648 -6.9628 2400
277.398 -5.2677 2500
290.169 -3.7031 2600
302.957 -2.2544 2700
315 762 - 9094 2800
328.247 .3397 29Q0
341.023 1.5080 3000
353.811 2.6008 3100
366.609 3.6252 3200
379.417 4.5874 3300
392.234 5.4931 3400
405.059 6.3469 3500
417.892 7.1533 3600
430.732 7.9160 3700
443.578 8.6386 3800
456.145 9.3223 3900
468.975 9.9734 4000
481.809 10.5929 4100
494.648 11.1829 4200
507.492 11.7454 4300
520.339 12.2825 4400
533.190 12.7958 4500
546.045 13.2869 4600
558.903 13.7571 4700
571.765 14.2078 4800
584.629 14.6403 4900
597.496 15.0556 5000
610.365 15.4547 5100
623.237 1518385 5200
636.112 16.2081 5ГЭ0
648.988 16.5640 5400
661.867 16.9072 5500
674.747 17.2383 5600
687.630 17.5579 5700
700.062 17.8644 5800
712.925 18.1627 5900
725.789 18.4513 6000
1 Т а б л и и а 15 3
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221

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОПА
«оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
61.311
79.941
95.278
95.524
106.788
115.336
121.918
127.037
130.994
134.054
136.440
138.321
139.957
141.203
142.219
i43.055
143.863
144.464
144.972
145.404
145.775
146.095
146.373
146.615
146.965
147.162
147.337
147.493
117 fi°.9
It I .\JOdb
147.757
147.869
147.971
148.062
148.145
148.221
148.290
148.353
148.410
148.463
148.512
148.557
148.598
148.636
148.672
148.705
148.735
148.764
148.790
148.964
148.990
149.015
149.038
149.059
149.080
149.099
149.117
149.134
149.150
149.165
149.179
149.193
К°(Т)= р2(Ю
Ф°(Т)
Дж • К~1 - моль"
221.527
259.917
285.904
286.335
307.568
325.668
341.585
355.886
368.880
380.773
391.757
401.970
411.637
420.644
429.135
437.167
444.861
452.126
459.054
465.676
472.017
478.101
483.948
489.575
495.089
500.330
505.394
510.292
С 1 С Л ОС
01 OtMOv
519.634
524.095
528.427
532.637
536.733
540.719
544.602
548.387
552.079
555.682
559.201
562.638
565.999
569.286
572.502
575.651
578.735
581.756
584.719
587.705
590.556
593.353
596.100
598.797
601.446
604.049
606.608
609.124
611.598
614.032
616.427
618.784
ПЕНТОКСИД ДИАЗОТА
•р5(О) -р'1^
S°(T)
-1
272.588
320.692
355.651
356.241
385.343
410.121
431.763
450.939
468.161
483.792
498.081
511.225
523.268
534.535
545.056
554.920
564.131
572.879
581.161
589.022
596.503
603.637
610.454
616.980
623.173
629.181
634.961
640.529
АД С ПЛЛ
651.088
656.105
660.961
665.666
670.229
674.659
678.962
683.146
687.218
691.182
695.045
698.812
702.486
706.073
709.577
713.001
716.349
719.624
722.880
725.882
728.955
, 731.966
734.918
737.813
740.654
743.442
746.179
748.867
751.508
754.103
756.654
759.163
Н°(Т)-Н°@)
кДж * моль
5.106
12.155
20.795
20.972
31.110
42.227
54.106
66.537
79.425
92.717
106.325
120.180
133.957
148.059
162.290
176.629
190.832
205.280
219.792
234.358
248.971
263.624
278.312
293.031
307.403
322.127
336.873
351.639
осе 491
381.219
396.031
410.855
425.692
440.538
455.394
470.259
485.132
500.012
514.900
529.793
544,692
559.598
574.508
589.422
604.341
619.264
634.192
649.122
663.252
678.156
693.064
707.974
722.887
737.802
752.720
767.640
782.562
797.486
812.412
827.340
842.269
N2O5. (г)
Y°@) = 2152.672
lgtfV)
-1094.8243
-529.0424
-342.0925
-339.7394
-244.8352
-187.7789
-149.6834
•122.4414
-101.9909
-86.0718
-73.3282
-62.8961
-54.2052
-46.8457
-40.5358
-35.0662
-30.2833
-26.0599
-22.3055
-18.9461
-15.9225
-13.1869
-10.7000
-8.4294
-6.3527
-4.4383
-2.6713
-1.0352
.4840
1.8983
3.2182
4.4530
5.6105
6.6978
7.7211
8.6859
9.5971
10.4591
11.2757
12.0504
12.7865
13.4867
14.1536
14.7896
15.3967
15.9770
16.5321
17.0637
17.5691
18.0579
18.5273
18.9785
19.4124
19.8301
20.2325
20.6205
20.9948
21.3561
21.7051
22.0425
22.3688
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
об
о
*-н
II
+
о
ю
о
+
'*
со
о
о
1
а
VO
СО
ч
со
нк
со
VO
II
• >«s
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Табли
i
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i s
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T
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II
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V
v
о
о
О
II
222

Класс точности
1-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.305
29.219
29.193
29.193
29.204
29.282
29.476
29.800
30.232
30.737
31.276
31.822
32.356
32.865
33.345
33.794
34.211
34.600
34.964
35.305
35.628
35.934
36.228
36.51
36.786
37.055
37.319
37.580
37.839
38.098
38.355
38.612
38.869
39.127
39.384
39.640
39.895
40.149
40.400
40.648
40.892
41.132
41.365
41.592
41.812
42.023
42.226
42.418
42.601
42.772
42.933
43.081
43.218
43.342
43.453
43.552
43.639
43.712
43.774
43.823
43.860
К°(Т)= p(N)
Ф°(Г)
Дж • К • моль
121.082
140.781
152.268
152.446
160.758
167.222
172.514
176.999
180.897
184.349
187.453
190.278
192.873
195.276
197.517
. 199.618
201.597
203.469
205.247
206.939
208.555
210.102
211.587
213.013
214.388
215.713
216.994
218.232
219.432
220.596
221.726
222.825
223.894
224.934
225.949
226.938
227.904
228.848
229.771
230.673
231.557
232.422
233.270
234.102
234.918
235.718
236.504
237.276
238.035
238.781
239.515
240.236
240.946
241.645
242.334
243.012
243.679
244.337
544.986
245.625
246.256
ГИДРИД АЗОТА
р(Н) -p'^NH
S°iT)
149.172
169.455
181.115
181.296
189.694
196.218
201.572
206.138
210.144
213.734
217.000
220.007
222.799
225,409
227.862
230.178
232.373
234.459
236.447
238.346
240.166
241.911
243.590
245.206
246.766
248.273
249;732
251.145
252.516
253.849
255.145
256.406
257.636
258.836
260.008
261.154
262.274
263.371
264.444
265.497
266.529
267.542
268.536
269.512
270.471
271.413
272.339
273.249
274.144
275.024
275.890
276.741
277.579
278.404
279.215
280.013
280.799
281.572
282.332
283.081
283.818
) ^
Н°(Т)-Н°(
кДж • моль
2.809
5.735
8.601
8.655
11.574
14.498
17.435
20.397
23.398
26.446
29.547
32.702
35.911
39.172
42.483
45.840
49.241
52.681
56.160
59.674
63.220
66.799
70.407
74.044
77.709
81.401
85.119
88.864
92.635
96.432
100.255
104.103
107.977
111.877
115.803
119.754
' 123.731
127.733
131.760
135.813
139.890
143.991
148.116
152.264
156.434
160.626
164.838
169.071
173.322
177.590
181.876
186.177
190.492
194.820
199.160
203.510
207.870
212.237
216.612
220.992
225.376
NH (г)
гН°@) = 348.000 кДж-моль
»
-1
\%К°{Т)
-178.6542
-87.2910
-57.1043
-56.7242
-41:3858
-32.1502
-25.9716
-21.5432
-18.2408
-15.6108
-13.5244
-11.8125
-10.3820
-9.1685
-8.1259
-7.2202
-6.4261
-5.7239
-5.0986
-4.5381
-4.0328
-3.5749
-3.1579
-2.7767
-2.4267
-2.1044
-1.8064
-1.5302
-1.2735
-1.0342
-.8106
-.6013
-.4049
-.2203
-.0464
.1177
.2728
.4196
.5587
.6908
.8163
.9358
.0496
.1582
.2619
.3610
.4558
.5466
.6337
.7172
.7974
.8745
.9487
2.0201
2.0889
2.1552
2.2192
2.2809
2.3406
2.3982
2.4540
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1*00
1500
1600
1700
1800
1900
2000
,2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
чо
О
-н
II
+
«о
UO
О
1
00
со
О
О
О
х
с
со
»о
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чо
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II
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i
л
мол
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II
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л
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223

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°р (Г)
43.898
43.892
43.843
43.756
43.633
43.478
43.293
43.084
42.851
42.599
42.330
42.047
41.752
41.447
41.133
40.814
40.489
40.161
39.831
39.499
38.671
37.854
37.055
36.281
35.536
34.822
34.141
33.492
32.877
32.294
31.742
31.221
30.728
30.263
29.825
29.411
29.022
28.654
28.307
27.980
ГИДРИД АЗОТА NH (г)
Ф°G)
Дж< К • моль"
247.491
248.693
249.864
251.004
252.117
253.203
254.262
255.296
256.307
257.294
258.259
259.203
260.126
261.030
261.914
262.779
263.627
264.457
265.270
266.068
267.993
269.826
271.575
273.246
274.843
276.372
277.838
279.244
280.594
28L892
283.141
284.344
285.504
286.623
287.703
288.747
289.757
290.734
291.681
292.598
-1
#°(Л-#°@)
кДж * моль
285.257 234.152
286.651 242.932
288.001 251.706
289.308 260.467
290.575 269.206
291.802 277.918
292.991 286.595
294.143 295.233
295.259 303.827
296.341 312.373
297.389 320.866
298.406 329.304
299.392 337.684
300.348 346.004
301.276 354.262
302.177 362:457
303.051 370.587
303.900 378.652
304.725 386.651
305.526 394.584
307.433 414.127
309.213 433.257
310.878 451.983
312.439 470.316
313.905 488.269
315.284 505.857
316.586 523.097
317.816 540.004
318 980 556 594
320.085 572.886
321.134 588.893
322.134 604.633
323.087 620.119
323.997 635.366
324.868 650.387
325.703 665.195
326.503 679.802
327.272 694.220
328.012 708.459
328.724 722.530
\%К°(Т)
2.5603
2.6600
2.7539
2.8424
2.9261
3.0053
3.0804
3.1518
3.2197
3.2845
3.3463
3.4054
3.4620
3.5163
3.5684
3.6185
3.6667
3.7131
3.7579
3.8011
3.9030
3.9971
4.0843
4.1656
4.2417
4.3132
4.3805
4.4442
4.5045
4.5618
4.6164
4.6685
4.7183
4.7659
4.8117
4.8557
4.8980
4.9388
4.9781
5.0161
Т
К
6200
6400
6600
680Q
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 155
(окончание)
+
я й
со о
о
1 Т
8 * Я
2 ^ о
2 Лн о
о vo о
5 Г^ <N
? 2 V
2 + к.
? с* *"
? g V
? ° §
Я - S
+ i
»—Н О\ w
~Ч V© -Н
V© 00
Ji °) К
<N СО "
I. + S
hi
ъ
224

Класс точности
II-F
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
32.705
32.685
31.748
31.214
31.083
31.254
31.617
32.081
32.585
33.091
33.576
34.031
34.452
34.837
35.190
35.512
35.807
36.079
36.329
36.562
36.778
36.982
37.174
37.357
37.532
37.702
37.866
38.027
38.185
38.342
38.498
38.655
38.813
38.972
39.132
39.295
39.461
39.628
39.798
39.970
40.144
40.320
40.496
40.673
40.850
41.027
41.202
41.376
41.547
41.715
41.878
42.037
42.191
42.339
42.481
42.616
42.743
42.862
42.973
ПОЛОЖИТЕЛЬНЫЙ ИОН ГИДРИДА
Af°G') = p(N) •
Ф°(Т)
*" 1
Дж • К • моль
155.762
155.959
165.144
172.262
178.056
182.940
187.152
190.887
194.223
197.250
200.023
202.5*5
204.968
207.198
209.294
211.273
213.148
214.930
216.629
218.253
219.809
221.302
222.737
224.120
225.453
226.142
227.988
229.195
230.365
231.501
232.605
233,678
234.722
23Й.739
2313.731
237.699
330.643
230.566
240.468
241.350
242 214
243.059
243.888
244.700
245.496
24^.277
247.044
247.798
248.538
249.265
249.980
250.683
251.375
252.056
252.726
253.387
254.037
254.678
255.309
р(Н) -p^NH*
187.616
187.818
197.085
204.104
209.778
214.579
218.775
222.525
225.931
229.060
231.961
234.667
237.204
239.594
241.854
243.997
246.036
247.979
249.836
251.614
253.320
254.960
256.537
258.059
259.527
260.947
262.321
•263.653
264.944
266.199
267.419
268.606
269.762
270.890
271.990
273.064
274.114
275.142
276.147
277.132
278.097
279.044
279.973
280.885
281.780
282.661
283.527
284.378
285.215
286.040
286.851
287.650
288.438
289.213
289.977
290.730
291.472
292.204
292.925
)-р~1(е) ArI/
//°G')-//°@)
кДж • моль"
9.497
9.558
12.777
15.921
19.033
22.148
25.290
28.475
31.708
34.992
38.325
41.706
45.130
48.595
52.097
55.632
59.198
62.793
66.413
70.058
73.725
77.413
81.121
84.848
88.592
92.354
96.132
99.927
103.738
107.564
111.406
115.264
119.137
123.026
126.931
130.853
134.790
138.745
142.716
146.705
150.710
154.733
158.774
162.832
166.909
171.002
175.114
179.242
183.388
187.551
191.731
195.926
200.137
204.364
208.604
212.859
217.126
221.406
225.697
i
АЗОТА NH* (Г) I 1аблИиа156
J@) - -916.000 кДж • моль
lgtfV)
Г
К
164.1535 298.15
163.1604 300
123.1211 400
99.0684 500
83.0149 600
71.5352 700
62.9156 800
56.2037 900
50.8275 1000
46.4232 1100
42.7481 1200
39.6342 1300
36.9612 1400
34.6413 1500
32.6083 N00
30.8117 1700
29.2122 1800
27.7788 1900
26.4866 2000
25.3155 2100
24.2492 2200
23.2739 2300
22.3783 2400
21.5530 2500
20.7898 2600
20.0819 2700
19.4235 2800
18.8093 2900
18.2350 3000
17.6969 3100
17.1914 3200
16.7158 3300
16.2673 3400
15.8436 3500
15.4428 3600
15.0629 3700
14.7Q23 3800
14.3597 3900
14.0335 4000
13.7227 4100
13.4261 4200
13.1428 4300
12.8719 4400
12.6126 4500
12.3640 4600
12.1256 4700
11.8968 4800
11.6768 4900
11.4653 5000
11.2617 5100
11.0655 5200
10.8765 5300
10.6941 5400
10.5180 5500
10.3479 5600
10.1835 5700
10.0245 5800
9.8706 5900
9.7215 6000
т
5
Т 2
405
.852
1609
3 • s Д 5
2 2 * vo .
^ S оо «о
Z а ~
* С »
+ - et
X + о cs
Z X ^о
ow ?
<
+
^ §
о „/
1 'а
с*
II 1
1 <** s
в оо V
6 ^ к
+ 2 W
х + V
С О
^ % ©
00 ^ »О
г«* © • •
со Ч f
+ ' ?
^ н ^
«О ON „
^ ON j.
ГО  С-
«О 00
<N CO
II +
15 812
225

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000 •
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
.16500
17000
17500
18000
18500
19000
19500
20000
•
С°р (Т)
43.168
43.325
43.445
43.525
43.566
43.568
43.533
43.462
43.357
43.221
43.056
42.865
42.649
42.412
42.156
41.884
41.598
41.299
40.991
40.675
39.861
39.031
38.202
37.388
36.598
35.838
35.111
34.420
33.765
33.146
32.562
32.013
31.495
31.009
31.640
30.120
29.715
29.334
28.975
28.637
ПОЛОЖИТЕЛЬНЫЙ
Ф°(Г)
Дж < К~ 1 • моль"
256.545
257.748
258.918
260.059
261.171
262.256
263.314
264.348
265.359
266.346
267.312
268.256
269.181
270.086
270.972
271.840
272.690
273.524
274.341
275.142
277.077
278.923
280.685
282.370
283.982
285.527
287.008
288.429
289.795
291.108
292.372
293.590
294.765
295.898
296.993
298.050
299.074
300.064
301.024
301.954
-1
294.337
295.710
297.045
298.343
299.605
300.832
302.025
303.184
304.312
305.407
306.472
307.507
308.512
309.489
310.439
311.362
312.259
313.131
313.978
314.803
316.766
318.599
320.313
321.920
323.427
324.846
326.182
327.444
328.638
329.770
330.845
331.867
332.842
333.773
334.663
335.515
336.332
337.118
337.873
338.600
ИОН ГИДРИДА АЗОТА NH+ (г)
#°(Г)-#°@)
кДяс • моль"
234.311
242.959
251.635
260.331
269.038
277.750
286.457
295.154
30.3.833
312.488
321.112
329.701
338.248
346.749
355.201
363.600
371.942
380.226
388.449
396.609
416.726
436.430
455.717
474.591
493.063
511.146
528.855
546.210 "
563.226
579^924
596.320
612.432
. 628.277
643.871
659.228
674.362
689.287
704.016
718.559
732.928
Т
К
9.4372 6200
9.1697 6400
8.9175 6600
8.6794 6800
8.4542 7000
8.2409 7200
8.0385 7400
7.8461 7600
7.6631 7800
7.4887 8000
7.3224 8200
7.1637 8400
7.0119 8E00
6.8666 8800
6.7275 9000
6.5941 9200
6.4661 9400
6.3432 9600
6.2250 9800
6.1114 10000
5.8453 10500
5.6024 11000
5.3797 11500
5.1749 • 12000
4.9858 12500
4.8107 13000
4.6482 13500
4.4969 14000
4 1447 14ЛОО
t*OOOI ltO\J\t
4.2236 15000
4.0998 15500
3.9835 16000
3.8741 16500 .
3.7709 17000
3.6735 17500
3.5814 18000
3.4941 18500
3.4113 19000
3.3327 19500
3.2482 20000
Таблица 156
(окончание)
+
'ч
О 1
СО С
00 §
о 2
•
сч 1
1., к>
я я
¦—• „5- о
2 ^ о
СО „. о
о ** 1
? - V
1 + *-
S * V
и 5 О
^ CN g
^ /^ I-
<N °^ ^
, | .»
+ ' *
so >i i
%п со О
1О ^ ^
«О 00 ||
к
II + w
g
о
226

Класс точности
IV-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.361
33.469
33.857
33.869
34.772
36.005
37.409
38.913
40.469
42.025
43.538
44.976
46.319
47.561
48.702
49.749
50.711
51.596
52.415
53.177
53.890
54.561
55.196
55.799
56.375
56.927
57.457
57.966
58.457
58.931
59.387
59.828
60.253
60.662
61.057
61.437
61.803
62.155
62.493
62.817
63.129
63.427
63.714
63.988
64.250
64.501
64.741
64.971
65.190
65.400
65.600
65.792
65.976
66.151
66.319
66.479
66.633
66.780
66.921
67.057
67.187
К°(Т)= p(N) •
Ф°(Л
Дж • К • моль"
125.342
148.274
161.551
161.757
171.376
178.904
185.130
190.471
195.174
199.394
203.238
206.780
210.072
213.154
216.058
218.807
221.419
223.911
226.294
228.580
230.777
232.893
234.935
236.909
238.819
240.670
242.467
244.212
245.910
247.562
249.172
250.742
252.274
253.770
255.232
256.662
258.062
259.432
260.774
262.090
263.380
264.645
265.888
267.107
268.306
269.433
270.640
271.773
272.897
273.999
275.083
276.150
277.201
278.236
279.256
280.262
281.253
282.230
283.194
284.144
285.082
ДИГИДРИД
р2 (Н) . р'1 (NH2)
S°(T)
//<
АЗОТА
А
\Т)-П°((
кДж * моль
158.310
181.462
194.882
195.092
204.948
212.836
219.522
225.401
230.698
235.555
240.062
244.279
248.251
252.008
255.575
258.972
262.213
265.315
268.287
271.142
273.888
276.533
279.086
281.553
283.940
286.253
288.496
290.674
292.791
294.851
296.857
298.811
300.717
302.578
304.394
306.170
307.906.
309.604
311.266
312.893
314.488
316.050
317.582
319.085
320.559
322.006
323.426
324.821
326.191
327.537
328.860
330.161
331.441
332.699
333.937
335.156
336.355
337.536
338.698
339.843
340.971
3.297
6.638
9.936
10.000
13.429
16.966
20.635
24.451
28.420
32,545
36.823
41.250
45.815
50.510
55.324
60.247
65.271
70.387
75.588
80.868
86.222
91.645
97.133
102.683
108.292
113.957
119.676
125.448
131.269
137.139
143.055
149.016
155.020
161.066
167.152
173.276
179.439
185.636
191.869
198.135
204.432
210.760
217.117
223.502
229.914
236.352
242.814
249.300
255.808
262.337
268.887
275.457
282.046
288.652
295.276
301.916
308.571
315.242
321.927
328.626
335.338
NH2 (г)
г//°@) = 710.021
))
1
ig*°cr)
-364.2600
-177.7642
-116.1123
-115.3358
-83.9952
65.1180
-52.4870
-43.4336
-36.6215
-31.3074
-27.0442
-23.5471
-20.6260
-18.1490
-16.0215
-14.1743
-12.5552
•11.1244
-9.8507
-8.7096
-7.6813
-6.7499
-5.9023
-5.1276
-4.4169
-3.7625
-3.1580
-2.5979
-2.0775
-1.5928
-1.1401
-.7165
-.3192
.0541
.4056
.7371
1.0502
1.3464
1.6271
1.8934
2.1463
2.3870
2.6162
2.8348
3.0434
3.2427
3.4333
3.6159
3.7908
3.9585
4.1196
4.2743
4.4230
4.5662
4.7040
4.8368
4.9648
5.0884
5.2076
5.3229
5.4343
L кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
*о
<N
С^
О
VO
II
+
fN
1О
«О
Г*
+
С*
00
1—1
S
Я
О
1
С
г-
о
р
со
+
On
?
<N
vo
II
о
•е-
Т а б
Т
л
§
1
1=1
S
°°.
<У\
II
о
¦ d
Z
о
<г
т
i
о
1
VO
1О
О\
On
^»
о»
ё
Os
«О
ю
1
V?
со
1-4
СО
об
00
4-
лица 157
1
Л
§
s
• |
5 §
X 2
О *
§ 7
О 1
о ^
On
u-> оо
-? о
00 <N
О\
CN II
* о к
зГ *>
о
о
ЧО
V
V
о
о
1
к.
II
227

Класс точности
II--C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9АПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
49Q0
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.284
33.750
35.630
35.678
38.674
41.994
45.229
48.269
51.112
¦ 53.769
56.244
58.535
60.644
62.576
64.339
65.945
67.407
68.738
69.949
71.055
72.066
72.992
73.843
74.626
75.350
76.021
76.645
77.226
77.769
78.278
78.757
79.208
79.635
80.039
80.423
80.789
81.138
81.471
81.792
82.099
82.395
82.680
82.956
83.223
83.481
83.732
83.976
84.213
84.445
84.671
84.891
85.107
85.318
85.525
85.728
85.927
86.123
86.316
86.506
86.692
86.876
K°(T)=p(N) •
Ф°(Т)
Дж • К • моль
122.652
145.630
158.974
159.182
168.985
176.815
183.440
189.252
194.474
199.247
203.663
207.788
211.669
215.341
218.833
222.166
225.358
228.421
231.369
234.211
236.956
239.612
242.183
244.677
247.099
249.452
251.742
253.971
256.143
258.260
260.327
262.345
264.317
266.245
268.130
269.976
271.783
273.553
275.288
276.990
278.659
280.296
281.904
283.483
285.034
286.559
288.057
289.531
290.980
292.406
293.810
295.192
296.553
297.894
299.215
300.516
301.800
303.064
304.312
305.542
306.756
АММИАК NH3
Р3(Н) • р
S°(T)
155.730
178.879
192.659
192.880
203.538
212.524
220.469
227.672
234.305
240.480
246.275
251.744
256.929
261.860
266.564
271.058
275.361
279.489
283.452
287.264
290.935
294.474
297.890
301.189
304.381
307.471
310.464
313.368
316.187
318.925
321.587
324.176
326.698
329.155
331.550
333.886
336.167
338.395
340.572
342.700
344.783
346.821
348.817
350.772
352.688
354.567
356.410
358.218
359.994
361.737
363.450
365.133
366.788
368.415
370.016
371.591
373.140
374.666
376.169
377.650
379.108
l(NH3) A
//°(Л-//°((
кДж • моль"
3.308
6.650
10.043
10.109
13.821
17.854
22.217
26.893
31.864
37.110
42.612
48.352
54.313
60.475
66.822
73.338
80.007
86.815
93.750
100.801
107.958
415.211
122.554
129.978
137.477
145.046
152.680
160.374
168.123
175.926
183.778
191.676
199.619
207.603
215.626
223.686
231.783
239.913
248.077
256.271
264.496
272.750
281.032
289.340
297.676
306.036
314.422
322.832
331.264
339.720
348.198
356.698
365.219
373,762
382.324
390.907
399.509
408.132
416.772
425.432
434.111
(г)
г//°@) = 1157.870
))
-1
\о К° (Т\
JgA \1 )
•594.3341
-290.1235
-189.5371
-188.2702
-137.1329
•106.3328
-85.7270
-70.9611
-59.8539
-51.1916
-44.2447
-38.5480
-33.7910
•29.7583
•26.2958
-23.2903
-20.6567
-18.3299
-16.2591
-14.4044
-12.7334
-11.2202
-9.8434
-8.5854
-7.4314
-6.3690
-5.3878
-4.4787
•3.6342
-2.8476
-2.1131
-1.4258
-.7811
-.1754
.3948
.9327
1.4407
1.9214
2.3769
18091
3.2197
3.6104
3.9825
4.3374
4.6762
4.9999
5.3096
5.6062
5.8904
6.1630
6.4248
6.6763
6.9181
7.1508
7.3750
7.5910
7.7993
8.0003
8.1944
8.3819
8.5632
кДж • моль *
г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1*00
1900
2000
2100
2200
2300
'2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4300
4900
5000
5100
5200
?300
5400
5500
5600
5700
5800
5900
6000
о
со
о
р-
1-Н
II
+
§
VD
VO
+
00
о
CS
8
с?
о
1
1
X
?
со
i
4*
О
со
со
гН
СО
*О
О1
II
Таблица 158
i
л
V 5
1 &
1 д ¦-
* I §
s I;
?5 Z+ V>
8 Т *?
as ' *
00 " Д
со /-ч Ч
1 Н оо
11 2 3
О об Jg
. Os ™
tT cs „
и
« С
^• « п
*¦*-< ГО 0 К
Z X о?
1
I
S
•
1
*
Ъ 1
00 О
СО \0
г*»
со* V
т <-
<ч \/
870л:
500 -
о
7 2
чо и
Os
о *
«О
2.28

Класс точности
V-I
Т
К
298.15
300
400
500
600
700
800
900
ЮОО
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
. 3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ср<Т)
34.763
34.812
38.565
43.630
48.995
54.204
59.104
63.643
67.800
71.575
74.977
78.027
80.751
83.180
85.344
87.271
88.989
90.523
91.895
93.124
94.228
95.222
96.119
96.930
97.665
98.333
98.942
99.497
100.005
100.471
100.899
101.203
101.656
101.992
102.303
102.591
102.858
103.107
103.339
103.556
103.758
103.947
104.124
104.290
104.447
104.593
104.732
104.862
104.985
105.101
105.211
105.315
105.413
105.507
105.595
105.680
105.760
105.836
105.908
К°(Т) = p(N) •
Ф°(П
Дж • К" J • моль"
152.513
152.720
162.439
170.216
176.859
182.772
188.176
193.200
197.926
202.410
206.689
210.790
214.734
218.537
222.211
225.767
229.212
232.556
235.803
238.960
242.032
245.022
247.936
250.777
253.549
256.254
258.897
261.478
264.003
266.472
268.888
271.253
273.569
275.838
278.062
280.243
282.382
284.481
286.540
288.563
290.549
292.500
294.418
296.303-
298.156
299,979
301.772
303.537
305.274
306.983
308.667
310.325
311.959
313.569
315.155
316.719
318.261
319.782
321.282
АММОНИЙ
р4(И) p'NnII^)./
s°(T)
-1
И
1 ион nh;
4
*(T)-H°i0)
кДж • моль
185.981
186.196
196.678
205.814
214.243
222.190
229.752
236.979
243.903
250.545
256.922
263.046
268.930
274.585
280.024
285.257
290.295
295.148
299.827
304.341
308.699
312.910
• 316.982
320.922
324.738
328.437
332.024
335.506
338.888
342.175
345.372
348.482
351.512
354.464
357.341
360.148
362.888
365.563
368.176
370>30
373.228
375.672
378.064
380.406
382.700
384.947
387.151
389.312
391.432
393.512
395.554
397.559
399.528
401.463
403.365
405.235
407.074
408.882
410.662
9.979
10.043
13.695
17.799
22.431
27.593
33.261
39.402
45.977
52.949
60.279
67.932
75.874
84.073
92.501
101.134
109.948
118.925
128.048
137.300
146.668
156.142
165.710
175.363
185.093
194.893
204.758
214.680
224.656
234.680
244.749
254.858
265.006
275.189
285.404
295.649
305.921
316.220
326.542
336.887
347.253
3S7.638
368.042
378.462
388.899
399.352
409.818
420.298
430.790
441.294
451.810
462.336
472.873
483.419
493.974
504.538
515.110
525.690
536.277
(Г)
*@) = 684.954
1 п 1С ° i Т \
lgA ( / )
-101.4516
-100.6955
-70.1389
-51.6871
-39.3164
-30.4372
-23.7507
-18.5324
-14.3464
-10.9142
-8.0493
-5.6225
-3.5408
-1.7361
-.1570
1.2359
2.4734
3.5797
4.5744
5.4732
6.2892
7.0331
7.7139
8.3391
8.9151
9.4474
9.9406
10.3987
10.8254
11.2236
11.5960
11.9449
12.2725
12.5806
12.8709
13.1447
13.4034
13.6481
13.8800
14.1000
14.3089
14.5075
14.6966
14.8767
15.0485
15.2126
15.3694
15.5193
15.6628
15.8003
15.9322
16.0587
16.1802
16.2969
16.4091
16.5172
16.6211
16.7213
16.8179
кДж • моль '
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
I
|
j
WO
(->..
r»
ro
p
00
II
+
-•
•o
о
!2
+
ё
i
p
О
1
1
^t
IO
со
+
vO
s
о
Таблица i.^) j
7
-. 3
1 2
)? 3
? чО 2
S3 О
ч«» On
о ? Tv
8 S *
d " *
? a =5
ю ^ ^
О 00 <N
O^ CO
U ™ и
+ «• U
¦r - «=*
TZ + * -O *
5 i *э
A
§
T
* Я
ro о
* О
—< чо
оо . .
ю V
+ ^
V
об
" 2
Я
2 *
со
гч
229

Класс точности
VI -h
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
aOUv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
490С
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
On
33.258
33.418
35.044
35.096
38.758
43.268
47.820
52.127
56.117
59.790
63.163
66.259
69.101
71.707
74.089
76.256
78.215
79.973
81.538
82.917
84.124
85.169
86.066
86.831
87.476
88.017
88.466
88.836
89.138
89.382
89.577
89.731
89.851
89.943
90.011
90.060
90.093
90.114
90.124
90.126
90.120
90.109
90.094
90.075
90.053
90.028
90.001
89.973
89.943
89.912
89.879
89.845
89.811
89.775
89.738
89.701
89.663
89.624
89.584
89.543
89.502
К°(Т) = /;2(N)
Ф°(П
Дж • К • моль
148.315
171.370
184.689
184.896
194.642
202.443
209.091
214.979
220.328
225.267
229.884
234.236
238.364
242.300
246.068
249.687
253.171
256.533
259.783
262.929
265.978
268.938
271.813
274.608
277.327
279.975
282.555
285.069
287.521
289.914
292.251
294.532
296.762
298.942
301.073
303.159
305.200
307.198
309.155
311.073
312.953
314.796
316.603
318.377
320.117
321.825
323.503
325.151
326.770
328.361
329.926
331.464
332.977
334.465
335.930
337.372
338.791
340.189
34К565
342.921
344.257
ДИГИДРИД
•р2(Н) • р~х (N2
181.573
204.644
218.218
218.435
228.998
238.125
246.418
254.117
261.342
268.166
274.643
280.810
286.699
292.335
297.737
302.924
307.909
312.705
317.321
321.767
326.052
330.182
334.165
338.009
341.718
345.300
348.762
352.107
ОСС 'ХАЛ
358.476
361.510
364.450
367.300
370.067
372.753
375.363
377.900
380.369
382.772
385.113
387.395
389.620
391.792
393.911
395.982
398.005
399.984
401.919
403.813
405.667
407.483
409.263
411.007
412.718
414.395
416.042
417.658
419.244
420.803
422.334
423.838
ДИАЗОТА
н2) л
//°<Л-//°<(
кДж • моль
3.326
6.655
9.997
10.062
13.742
17.841
22.397
27.396
32.811
38.609
44.759
51.233
58.003
65.045
72.337
79.856
87.581
95.492
103.569
111.793
120.147
128.613
137.176
145.821
154.538
163.313
172.138
181.004
1 ЯО QO4
1 017. it\JO
198.829
207.778
216.743
225.723
234.712
243.710
252.714
261.722
270.732
279.744
288.757
297.769
ЗОбЛвО
315.791
324.799
333.806
342.810
351.811
360.810
369.806
378.799
387.788
396.774
405.757
414.736
423.712
432.684
441.652
450.617
459.577
468.533
477.485
N2H2 (г)
.//°@) "- 1154
)
1
lgA°(D
-592.0056
-288.6256
-188.3104
-187.0469
-136.0443
-105.3253
-84.7758
-70.0533
-58.9823
-50.3517
-43.4336
-37.7638
-33.0323
-29.0240
-25.5849
-22.6022
-19.9908
-17.6856
-15.6361
-13.8020
-12.1513
-10.6579
-9.3006
-8.0615
-6.9261
-5.8818
-4.9183
-4.0265
-3.1988
-2*4286
-1.7100
-1.0382
-.4087
.1824
.7384
1.2624
1.7570
2.2247
2.6675
3.0874
3.4862
3.8654
4.2263
4.5704
4.8986
5.2123
5.5121
5.7992
6.0742
6.3380
6.5912
6.8344
7.0682
7.2932
7.5099
7.7187
7.9200
8.1143
8.3020
8.4833
8.6586
.704 кДж • моль 1
r
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100'
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ON
ГЧ
О
о
го
^_
[x
ОС
00
сч
+
1
о
ОС
О
О
о
с
го
О
ос
+
СЧ
00
ГЧ
II
/-^
b
Т а б л и и
7
§
ul oq
о Z^
1 "
II ^
^ *-;
ON
U ГЧ
•yr 2E
/?-. -*-
О ^,
***- с
T
en
§
T
k
m*
о
о
ОС
+
00
p
о
1
H
00
p
?¦'
ГЧ
160
§
T
ГО
°^
О
II
о о;
со
о
о
о
V
W
V
о
о
•о
i
о
II
230

Класс точное ги
V 1
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
• 1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
->5800
5900
6000
33.258
33.418
35.043
35.095
38.738
43.157
47.494
51 448
54.963
58.061
60.780
63.158
65.237
67.052
68.640
70.032
71.255
72.336
73.297
74.156
74.932
75.639
76.288
76.893
77.460
77.999
78.514
79.012
7Q Л ЛГ
7У.4У5
79.968
80.432
80.888
81.339
81.784
82.224
82.658
83.087
83.509
83.924
84.331
84.730
85.119
85.499
85.867
86.224
86.569
86.901
87.220
87.525
87.817
88.094
88.357
88.606
88.841
89.061
89.266
89.458
89.636
89.800
89.952
90.090
транс
K°(T) = p2(N) i
Ф°(Т)
Дж • К • моль
148.315
171.370
184.688
184.896
194.642
202.442
209.084
214.962
220.289
225.197
229.769
234.062
238.118
241.969
245.638
249.145
252.505
255.733
258.838
261.830
264.719
267.510
270.212
272.830
275.369
277.834
280.229
282.559
284.827
287.036
289.190
291.291
293.343
295.348
297.307
299.224
301.099
302.936
304.736
306.499
308.229
309.926
311.592
313.227
314.833
316.412
317.964
319.490
320.991
322.468
323.922
325.353
326.763
328.151
329.520
330.868
332.197
333.508
334.800
336.075
337.333
-ДИГИДРИД
о2 (Н) • р~Х (N2b
181.573
204.644
218.218
218.435
228.996
238.111
246.367
253.991
261.095
267.751
274.013
279.920
285.506
290.801
295.830
300.614
305.174
309.527
313.689
317.675
321.499
325.172
328.706
.332.111
335.396
338.568
341.638
344.611
347.493
350.290
353.009
355.654
358.229
360.739
363.187
365.577
367.912
370.194
372.426
374.612
376.752
378.849
380.904
382.921
384.899
386.840
388.747
390.619
392.459
394.266
396.043
397.790
399.508
401.199
402.861
404.497
406.108
407.692
409.253
410.789
412.302
ДИАЗОТА
(/°( Л-//°@)
кДж • моль
3.326
6.65^
9.997
10.062
13.741
17.834
22.370
27.320
32.644
38.299
44.244
50.444
56.866
63.482
70.269
77.204
84.269
91.450
98.733
106.106
113.561
121.090
128.687
136.346
144.064
151.837
159.663
167.540
175.465
183.438
191.458
199.524
207.636
215.792
223.992
232.236
240.524
248.853
257.225
265.638
274.091
282.584
291.114
299.683
308.288
316.927
325.601
334.307
343.044
351.812
360.607
369.430
378.279
387.151
396.046
404.963
413.899
422.854
431.826
440.813
449.816
транс-N^H
/I°@) = 1154.
\gK°(T)
-592.0056
-288.6256
-188.3104
-187.0469
-136.0443
-105.3253
-84.7755
-70.0524
-58.9803
-50.3480
-43.4276
-37.7548
-33.0195
-29.0067
-25.5625
-22.5739
-19.9560
-17.6438
-15.5867
-13.7446
-12.0855
-10.5834
-9.2170
-7.9686
-6.8238
-5.7700
-4.7968
-3.8954
О ARQA
-o.OOoU
-2.2782
-1.5502
-.8689
-.2301
.3701
.9351
1.4679
1.9712
2.4473
2.8984
3.3264
3.7329
4.1197
4.4881
4.8393
5.1746
5.4950
5.8015
6.0949
6.3761
6.6458
6.9048
7.1536
7.3928
7.6230
7.8447
8.0584
8.2645
8.4633
8.6553
8.8409
9.0203
2(г)
704 кДж • моль
У
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300 ^
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
«N
fN
О
30.
II
н
Таблица 161
т
а
> .000
т—<
fN
II
с
ас
i
1
о
•Ча,
<|
<
h
О е
t О
00
»—< 1
-1
Г4
1.
- *
V
X 7Z
00 ЕЗ
О ^
го го
ОО *\
ГО 00
fN СО
О г^
о о
1 ^
>
+
о <=
S °>
со го
ст
н
с
1
0 СО
ГО »О
<4> ГО
Г-^ ГО
р
L
р
н О
1 +
Л
X
о
^о
00 _
*-н 1
—н Л
CN R
II ^
00
ON «
** СО
i
I *
0
a:
<г
о
о
V
V
500'
О
II
231

Класс точности
V-I
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
QQftft
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;<л
33.258
33.517
35.407
35.463
39.227
43.636
47.931
51.851
55.345
58.429
61.134
63.499
65.563
67.363
68.933
70.304
71.505
72.560
73.489
74.311
75.041
75.693
76.279
76.809
77.291
77.734
78.143
78.526
7ft ЯЙ7
/ О.ОО /
79.230
79.559
79.877
80.187
80.491
80.791
81.088
81.383
81.678
81.972
82.266
82.561
82.856
83.151
83.446
83.741
84.034
84.327
84.618
84.907
85.193
85.475
85.754
86.029
86.299
86.564
86.823
87.076
87.322
87.562
87.794
88.019
^с-ДИГИДРИДДИАЗОТА^с-^Н2 (г) -Таблица 162
К°(Т)= /?2(N)
Ф°(Л
Дж • К • моль
148.309
171.365
184.701
184.909
194.693
202.540
209.230
215.151
220.519
225.464
230.069
234.393
238.477
242.354
246.047
249.576
252.957
256.203
259.325
262.334
265.238
268.044
270.758
273.388
275.937
278.411
280.815
283.152
287.640
289.797
291.901
293.955
i<:-i,.959
297.917
299.832
301.704
303.536
305.331
307.088
308.810
310.498
312.154
313.780
315.375
316.942
318.481
319.994
321.481
322.944
324.383
325.799
327.193
328.566
329.917
331.249
332.562
333.855
335.131
336.389
337.630
•Р2(Н) р'Х (N2H2) ЛгН°@) ¦=• 1118.704 к Дж-моль '
Л°(Л
-1
181.566
204.653
218.317
218.536
229.224
238.448
246.788
254.476
261.633
268.334
274.633
280.573
286.189
291.509
296.560
301.364
305.940
310.308
314.482
318.478
322.308
325.986
329.521
332.924
336.203
339.367
342.424
345.380
Ч4Я 944
351.017
353.708
356.322
358.863
361.335
363.743
366.089
368.377
370.611
372.793
374.926
377.013
379.055
381.055
383.016
384.937
386.822
388.672
390.489
392.274
394.028
395.751
397.447
399.115
400.756
402.372
403.962
405.529
407.072
408.593
410.092
411.569
HriT)-H°i0)
кДж • моль
lg/r°G')
7
К
3.326 -573.2011 100
6.658 -279.2234 200
10.023 -182.0042 298.15
10.088 -180.7795 300
13.812 -131.3460 400
17.954 -101.5695 500
22.535 -81.6491 600
27.528 -67.3760 700
32.891 -56.6417 800
38.583 -48.2726 900
44.564 -41.5629 1000
50.799 -36.0626 1100
57.254 -31.4712 1200
63.902 -27.5803 1300
70.719 -24.2406 1400
77^682 -21.3428 1500
84.774 -18.8043 1600
91.979 -16.5623 1700
99.282 -14.5675 1800
106.673 -12.7813 1900
114.141 -11.1724 2000
121.678 -9.7158 2100
129.278 -8.3907 2200
136.932 -7.1802 2300
144.638 -6.0699 2400
152.389 -5.0480 2500
160.183 -4.1042 2600
168.017 -3.2299 2700
17<;ЯЯЙ -9 4178 9R00
1 / О.ООО ^-чг I/O ZOUU
183.794 -1.6613 2900
191.733 -.9551 3000
199.705 -.2942 3100
207.708 .3256 3200
215.742 .9080 3300
223.806 1.4563 3400
231.900 1.9734 3500
240.024 2.4619 3600
248.177 2.9242 3700
256.359 3.3621 а800
264.571 3.7778 3900
272.812 4.1727 4000
281.083 4.5485 4100
289.384 4.9064 4200
297.714 5.2478 4300
306.073 5.5737 4400
314.462 5.8852 4500
322.880 6.1832 4600
331.327 6.4686 4700
339.803 6.7422 4800
348.308 7.0047 4900
356.841 7.2568 5000
365.403 7.4990 5100
373.992 7.7319 5200
382.609 7.9562 5300
391.252 8.1722 5400
399.921 8.3804 5500
408.616 8.5812 5600
417.336 8.7750 5700
426.080 8.9623 5800
434.848 9.1432 5900
443.639 9.3182 6000
__ с;
1 *
fi t^- 0
1 Я z
in »
гм *° ^ '
Г4! w 4^
on г^ Ьь *
© " ^ i
s s 5 5
С О rn
м .- ;?
i fS '•
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a 1 о я
3 -4, <o
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\ «r
4-
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Г* r-f Л
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1—¦ o\ so
© гл V
О ГЧ .
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с ^ о
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+ *
ГО т—< h-
ГЧ ON
ON rf II
ON rj"
(^1 ON ^J,
m »—
ti ¦+•
%
232

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1000
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-JL- ,
Р
33.270
33.902
36.243
36.306
40.32?
44.763
48.910
52.579
55.795
58.621
61.112
63.311
65.253
66.968
68.483
69.823
71.011
72.065
73.003
73.840
74.590
75.264
75.872
76.422
76.922
77.378
77.795
78.177
78.529
78.853
79.154
79.432
79.691
79.932
80.157
80.367
80.564
80.748
80.921
81.083
81.236
81.380
81.515
81.642
81.762
81.876
81.983
82.083
82.179
82.269
82.354
82.434
82.510
82.582
82.650
82.714
82.775
82.832
82.887
82.938
82.986
1,1-ДИГИДРИД ДИАЗОТА
К°(Т)= р2(Щ р
Ф°(Л
Дж • К • моль
157.772
180.844
194.245
194.454
204.340
212.301
219.105
225.131
230.591
235.613
240.282
244.659
248.786
252.696
256.416
259.966
263.364
266.622
269.755
272.771
275.080
278.489
281.206
283.837
286.387
288.861
291.265
293.600
295.873
298.085
300.241
302.342
304.393
306.394
308.349
310.260
312.129
313.956
315.7Г46
317.497
319.214
320.896
322.545
324.163
325.750
327.308
328.838
330.341
331.818
333.269
334.696
336.099
337.479
338.837
340.173
341.489
342.785
344.061
345.318
346.557
347.778
2(H)V(N
S°(T)
191.030
214.213
228.120
228.344
239.314
248.790
257.325
265.146
272.381
279.120
285.428
291.358
296.952
302.244
307.263
312.035
316.580
320.917
325.063
329.033
332.840
336.496
340.011
343.396
346.660
349.809
352.852
355.795
358.645
361.406
364.085
366.685
369.211
371.667
374.056
376.383
378.650
380.860
383.015
385.120
387.174
389.182
391.145
393.064
394.943
396.781
398.582
400.346
402.075
403.771
405.434
407.065
408.667
410.239
411.783
413.300
414.791
416.257
417.698
419.115
420.510
2Н2> Д,
/Г<7)-/Л0)
кДж • моль
3.326
6.674
10.100
10.167
13.990
18.245
22.932
28.011
33.433
39.157
45.146
51.369
57.800
64.412
71.186
78.103
85.146
92.301
99.555
106.898
114.320
121.813
129.371
136.986
144.654
152.369
160.128
167.927
175.762
183.631
191.532
199.461
207.418
215.399
223.404
231.430
239.477
247.542
255.626
263.726
271.842
279.973
288.118
296.276
304.446
312.628
320.821
329.024
337.237
345.460
353.691
361.930
370.178
378.432
386.694
394.962
403.237
411.517
419.803
428.094
436.391
1,1-N2H2 (г]
1
Н°@) = 1082.704 кДж-моль
-554.8910
-270.3163
-176.1955
-175.0099
-127.1488
-98.3186
-79.0308
-65.2109
-54.8173
-46.7134
-40.2159
-34.8893
-30.4426
-26.6740
-23.4391
-20.6319
-18.1726
-16.0004
-14.0676
-12.3367
-10.7776
-9.3660
-8.0818
-6.9084
-5.8323
-4.8416
-3.9268
-3.0792
-9 9Q1 Q
*Z.Z9 I 57
-1.5585
- -.8738
-.2330
.3680
.9328
1.4645
1.9660
2.4398
2.8881
3.3130
3.7162
4.0994
4.4640
4.8114
5.1427
5.4591
5.7616
6.0510
6.3283
6.5941
6.8492
7.0942
7.3297
7.5563
7.7745
7.9847
8.1874
8.3830
8.5719
8.7544
8.9308
9.1015
Г
К.
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
tow
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
сч
ON
СМ
О
II
ЧО
гч
00
*?
сч
00
©
о
g
00
-н
ЧО
+
00
TJ-
СЧ
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1
"Т" п К.
1 а о
л
о
о
о
as
и
о
С
X
?Г
1
о
<
'й
о
i
*
ГО
со
1
ЧО
со
1
н
чо
о
о
сч
*""'
¦*¦
ли ц а 163
Т
§
чо g
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оо **
сч
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11 1
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z а.
1 0 05
о
2
о
8
чо
V
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V
о
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1
о
II
233

Класс точности
V-C
7
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4зоа
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
/'
34.531
40.473
48.425
48.593
57.811
66.195
73.241
79.128
84.152
88.538
92.449
95.908
99.018
101.779
104.237
106.426
108.374
110.113
111.665
113.048
114.283
115.388
116.379
117.268
118.069
118.792
119.445
120.038
120.576
121.066
121.513
121.988
122.370
122.721
123.044
123.341
123.616
123.870
124.106
124.325
124.528
124.776
124.956
125.124
125.282
125.429
125.567
125.697
125.819
125.933
126.041
126.143
126.239
126.329
126.415
126.496
126.573
126.645
126.714
126.780
126.842
к°(Т)= p2(N) •
Ф°(Т)
Дж ¦ К • моль
161.442
185.255
199.954
200.190
211.747
221.579
230.348
238.343
245.765
252.716
259.245
265.447
271.320
276.944
282.321
287.469
292.409
297.182
301.788
306.233
310.528
314.683
318.709
322.612
326.401
330.083
333.663
337.147
340.540
343.847
347.072
350.256
353.334
356.340
359.279
362.153
364.965
367.718
370.413
373.054
375.643
378.218
380.710
393.155
385.555
387.911
390.226
392.500
394.735
396.932
399.092
401.217
403.308
405.366
407.392
409.386
411.351
413.286
415.192
417.071
418.923
ГИДРАЗИН N2H4 {
Р4(Н) .р"
194.942
220.791
238.361
238.660
253.898
267.727
280.440
292.183
303.079
313.250
322.788
331.762
340.245
348.275
355.905
363.175
370.113
376.733
383.065
389.137
394.967
400.572
405.967
411.165
416.180
421.022
425.703
430.231
434.617
438.867
442.989
446.928
450.809
454.582
458.252
461.826
465.308
468.703
472.013
475.244
478.399
481.458
484.468
487.412
490.292
493.111
495.872
498.575
501.225
503.823
506.371
508.870
511.323
513.730
516.095
518.418
520.701
522.944
525.150
527.319
529.453
l(N2H4) ArU
//V>-//°<(»
кДж • моль
3.350
7.107
11.451
11.541
16.860
23.074
30.056
37.688
45.852
54.481
63.543
72.947
82.710
92.731
103.017
113.558
124.327
135.237
146.297
157.517
168.878
180.366
191.968
203.672
215.469
227.349
239.304
251.328
263.414
275.557
287.752
299.682
311.919
324.196
336.509
348.856
361.235
373.644
386.080
398.540
411.024
423.283
435.785
448.306
460.844
473.400
485.970
498.556
511.155
523.-767
536.392
549.028
561.675
574.332
586.999
599.675
612.360
625.054
637.755
650.464
663.180
(г)
J@) - 1696.438
-868.2312
-421.9013
-274.2147
-272.3539
-197.2406
-151.9948
-121.7278
-100.0432
-83.7375
-71.0262
-60.8351
-52.4825
-45.5095
-39.6016
-34.5309
-30.1308
-26.2762
-22.8728
-19.8452
-17.1342
-14.6925
-12.4819
-10.4711
-8.6342
-6.9496
-5.3991
-3.9673
-2.6411
-1.4093
-.2621
.8088
1.8090
2.7484
3.6311
4.4620
5.2455
5.9856
6.6858
7.3492
7.9787
8.5768
9.1439
9.6858
10.2025
10.6958
11.1673
11.6183
12.0503
12.4643
12.8615
13.2429
13.6094
13.9619
14.3012
14.6281
14.9431
15.2470
15.5403
15.8236
16.0974
16.3622
кДж • моль *
•/•
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
«о
сч
го
II
г-
чо
сч
VO
о
I
ЧО
го
ЧО
сч
ЧО
г-
«о
го
о
го
II
Таб
ьД
к
о
2
со
го
§
II
о
о
1
1
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00
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t^
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Т
л
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i
II
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со
2
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ЧО
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1
II
234

Класс точности
vi-i:
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1-800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
aOvU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5 Ю0
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.608
38.338
44.224
44.329
49.629
54.077
57.785
60.907
63.566
65.850
67.825
69.537
71.026
72.324
73.460
74.455
75 332
76.106
76.792
77.403
77.950
78.440
78.882
79.283
79.646
79.978
80.282
80.562
80.821
81.060
81.283
81.491
81.686
81.870
82.042-
82.206
82.361
82.509
82.651
82.786
82.916
83.041
83.162
83.278
83.391
83.501
Я3.609
83.713
83.815
83.915
84.013
84.110
84.204
84.298
84.390
84.481
84.571
84.660
84.749
84.836
84.924
f°iT\--- p*(N)
Ф°СЛ
Дж К • моль
165.001
188.340
202.502
202.730
213.658
222.708
230.550
237.530
243.855
249.658
255.033
260.047
264.754
269.191
273.393
277.384
281-. 187
284.819
288.296
291.633
294.839
297.926
300.902
303.774
306.552
309.239
31 1.844
314.369
316.821
319.203
321.520
323.775
325.970
328.111
330.198
332.235
334.224
336.167
338.067
339.925
341.743
343.523
345.267
346.975
348.650
350.293
351.904
353.486
355.039
356.564
358.062
359.535
360.982
362.406
363.806
365.184
366.540
367.874
369.189
370.484
371.759
ГИДРИД
* i /»
-1
198.294
222.804
239.222
239.496
252.994
264.562
274.759
283.908
292.219
299.841
306.884
313.430
319.546
325.284
330.686
335.789
340.623
345.213
349.583
353.752
357.736
36.1.551
365.211
368.727
372.108
375.367
378.509
381.545
384.479
387.320
390.072
392.740
395.331
397.847
400.294
402.674
404.992
407.251
409.453
411.602
413.699
415.748
417.751
419.709
421.625
423.500
425.337
427.136
428.899
430.629
432.325
433.989
435.624
437.228
438.805
440.354
441.877
443.375
444.848
446.298
447.724
ТРИАЗОТА
з> Л
//°</)-//°<0
кДж • моль
3.329
6.893
10.948
11.030
15.735
20.927
26.525
32.464
38.691
45.165
51.851
58.721
65.751
72.920
80.211
87.607
95.098
102.670
110.316
118.026
125.794
133.614
141.481
149.389
157.336
165.318
173.331
181.373
1 SQ 44*4
197.537
205.654
213.793
221.952
230.130
238.325
246.538
254.766
263.010
271.268
279.540
287.825
296.123
304.433
312.755
321.088
329.433
337.789
346.155
354.531
362.918
371.314
379.720
388.136
396.561
404.996
413.439
421.892
430.353
438.824
447.303
455.791
HN3 (г)
// @) = 1328.
)
1
}ok'°iT\
igA { I )
-681.4845
-332.8083
-217.6205
-216.1706
-157.6779
-122.4931
-98.9852
-82.1620
-69.5237
-59.6796
-51.7942
-45.3352
-39.9473
-35.3842
-31.4699
-28.0751
-25.1027
-22.4785
-20.1447
-18.0556
-16.1746
-14.4721
-12.9238
-11.5098
-10.2132
-9.0200
-7.9183
-6.8980
с ПСЛ4
-5.0679
-4.2442
-3.4735
-2.7508
-2.0718
-1.4326
-.8298
-.2605
.2782
.7886
1.2730
1.7332
2.1711
2.5883
2.9862
3.3660
3.7292
4.0766
4.4095
4.7285
5.0347
5.3288
5.6115
5.8835
6.1453
6.3977
6.6410
6.8758
7.1025
7.3216
7.5334
7.7383
198 кДж • моль
/
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
!
i
о
00
сч
о
СО
<*
+
н
00
*3-
г—
+
2
00
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CTs
О
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со
Ю
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00
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т
л
с*
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CN
О
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II
О
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го
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г-
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CN
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00
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00
T
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II
2
00
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T
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CO
со
со
о
^\ '
<3
Я
о
о
о
ЧО
V
V
8
1
о
II
235

Класс точности
IV-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г
33.277
33.330
33.881
33.901
•35.446
37.607
39.928
42.158
44.207
46.069
47.774
49.360
50.859
52.294
53.674
55.003
56.277
57.489
58.633
59.700
60.686
61.586
62.399
63.126
63.767
64.328
64.811
65.222
65.567
65.852
66.082
66.264
66.402
66.502
66.570
66.608
66.622
66.615
66.590
66.550
66.497
66.435
66.364
66.287
66.205
66.119
66.031
65.941
65.850
65.759
65.668
65.579
65.490
65.404
65.319
65.237
65.157
65.079
65.004
64.932
64.863
Ф°(Т)
Дж К • моль
151.133
174.169
187.459
187.665
197.296,
204.864
211.169
216.626
221.473
225.858
229.878
233.602
237.080
240.349
243.438
246.371
249.167
251.840
254.405
256.871
259.248
261.543
263.762
265.912
267.997
270.022
271.989
273.904
97«ч 7fift
*, 1 0.1 DO
277.584
279.355
281.082
282.769
284.416
286.025
287.599
289.138
290.643
292.117
293.560
294.974
296.360
297.717
299.049
300.355
301.636
302.894
304.129
305.341
306.532
307.703
308.852
309.983
311.095
312.188
313.264
314.322
315.364
316.389
317.399
318.393
ОКСИД-ГИДРИД АЗОТА 1
д N) р(О)¦р
S\T)
-1
184.348
207.423
220.805
221.014
230.958
239.093
246.154
252.479
258.244
263.560
268.503
273.132
277.492
281.620
285.546
289.295
292.885
296.334
299.652
302.852
305.939
308.922
311.806
314.597
317.297
319.912
322.444
324.898
327.276
329.583
331.819
333.989
336.095
338.140
340.126
342.057
343.933
345.759
347.535
349.264
350.948
352.589
354.190
355.750
357.273
358.760
360.213
361.632
363.019
364.376
365.703
367.003
368.275
369.522
370.744
371.942
373.116
374.269
375.400
376.511
377.601
1 (UNO) Л Н
Н°(Т)-Н°{0)
-1
кдж • моль
3.321
6.651
9.942
10.005
13.465
17.114
20.991
25.097
29.417
33.932
38.625
43.483
48.494
53.652
58.951
64.386
69.950
75.639
81.446
87.363
93.383
99.497
105.697
111.974
118.320
124.725
131.183
137.685
1 АА QOC
1 44.^x0
150.796
157.393
164.011
170.644
177.290
183.944
190.603
197.265
203.927
210.587
217.244
223.897
230.543
237.183
243.816
250.441
257.057
263.664
270.263
276.852
283.433
290.004
296.567
303.120
309.665
316.201
322.728
329.248
335.760
342.264
348.761
355.251
HNO (г)
"@) -- 828.63f
lgA'°G\>
-425.3358
-207.8059
-135.9179
-135.0127
-98.4847
-76.4948
-61.7906
-51.2590
-43.3411
-37.1694
-32.2224
-28.1678
-24.7838
-21.9165
-19.4559
-17.3212
-15.4518
-13.8010
-12.3329
-11.0187
-9.8356
-8.7649
-7.7915
-6.9027
-6.0880
-5.3386
-4.6470
-4.0069
о л 1 Ofi
-0.** 1 Z\}
-2.8595
-2.3435
-1.8609
-1.4087
-.9841
-.5846
-.2081
-.1473
.4834
.8017
1.1035
1.3902
1.6628
1.9223
2.1697
2.4059
2.6314
2.8472
3.0537
3.2516
3.4415
3.6237
3.7988
3.9672
4.1293
4.2853
4.4358
4.5809
4.7209
4.8561
4.9869
5.1133
> кДж • моль '
/
К
100
200
298.15
300 .
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
?
р
СО
II
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+
00
см
см
1
п
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см
см
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о
см
о
о
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см
см
+
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II
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§
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о
§
II
о
с
О
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3
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§
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2
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см
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II
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2
о
о
о
ЧО
V
V
о
о
^о
о
II
236

Класс точности
V -С
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
'2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.098
40.305
46.319
46.431
52.044
56.634
60.296
63.235
65.637
67.641
69.340
70.797
72.057
73.152
74.109
74.948
75.686
76.336
76.912
77.423
77.877
78.283
78.646
78.973
79.266
79.531
79.771
79.989
80.187
80.368
80.533
80.684
80.823
80.951
81.069
81.177
81.278
81.371
81.458
81.538
81.613
81.683
81.748
81.810
81.867
81.921
81.971
82.018
82.063
82.105
82.145
82.182
82.218
82.251
82.283
82.313
82.342
82.369
82.395
82.419
82.443
К°(Т)^ р(\\) ¦ р(
Ф°(Л
Дж • К • моль
175.115
200.010
215.059
215.300
226.855
236.403
244.662
251.999
258.634
264.707
270.318
275.539
280.427
285.026
289.370
293.487
297.403
301.136
304.704
308.121
311.400
314.553
317.588
320.515
323.341
326.074
328.718
331.280
333.765
336.178
- 338.522
340.801
343.019
345.180
347.285
349.338
351.342
353.298
355.209
357.078
358.905
360.692
362.443
364.156
365.836
367.482
369.096
370.679
372.232
373.757
375.255
376.726
378.172
379.592
380.989
382.363
383.715
385.044
386.353
387.642
388.911
АЗОТИСТАЯ
N) -р2 (О) р
S"H )
210.398
236.752
253.956
254.243
268.392
280.517
291.179
300.703
309.308
317.158
324.375
331.054
337.269
343.081
348.539
353.681
358.542
363.150
367.530
371.702
375.685
379.495
383.145
386.649
39G.016
393.257
396.381
399.396
402.308
405.126
407.853
410.496
413.060
415.549
417.968
420.319
422.607
424.836
427.007
429.124
431.189
433.205
435.174
437.099
438.980
440.820
442.621
444.385
446.112
447.805
449.464
451.091
452,687
454.254
455.791
457.301
458.785
460.242
461.675
463.084
464.469
КИСЛОТА
<(HNO2)
,/V>-//°«)
кДж • моль
3.528
7.348
11.597
11.683
16.615
22.057
27.910
34.092
40.540
47.206
54.058
61.066
68.210
75.472
82.836
90.290
97.823
105.424
113.087
120.805
128.570
136.378
144.225
152.106
160.019
167.959
175.924
183.912
191.921
199.949
207.994
216.055
224.131
232.219
240.320
248.433
256.556
264.688
272.829
280.979
289.137
297.302
305.474
313.652
321.835
330.025
338.219
346.419
354.623
362.831
371.044
379.260
387.480
395.704
403.930
412.160
420.393
428.629
436.867
445.107
453.351
HNO2 (г)
Д.//°@)=1253
)
1
-642.4226
-313.2875
-204.5149
-203.1456
-147.8995
-114.6651
-92.4603
- -76.5701
-64.6332
-55.3359
-47.8888
-41.7890
-36.7009
-32.3917
-28.6953
-25.4894
-22.6824
-20.2042
-18.0002
-16.0272
-14.25,07
-12.6427
-11.1804
-9.8447
-8.6200
-7.4928
-6.4521
-5.4882
-4.5929
-3.7591
-2.9807
-2.2524
-1.5695
-.9277
-.3236
.2461
.7843
1.2935
1.7761
2.2340
2.6692
3.0832
3.4776
3.853В
4.2130
4.5564
4.8849
5.1996
5.5013
5.7907
6.0688
6.3360
6.5931
6.8406
7.0790
7.3089
7.5307
7.7448
7.9517
8.1517
8.3451
.218 кДж • моль *
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
,3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
го
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237

Класс точности
V-C
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.601
39.129
46.130
46.252
52.116
56.733
60.366
63.265
65.629
67.600
69.273
70.711
71.958
73.045
73.997
74.834
75.5*?2
76.224
76.802
77.316
77.774
78.184
78.551
78.882
79.179
79.448
79.692
79.913
80.115
80.299
80.467
80.621
80.763
80.893
81.014
81.125
81.228
81.323
81.411
81.494
81.571
81.642
81.709
81.772
81.831
81.886
81.937
81.986
82.032
82.075
82.116
82.154
82.191
82.225
82.258
82.289
82.318
82.346
82.372
82.398
82.422
транс-АЗОТИСТАЯ КИСЛОТА
к'°(Т) = р(П) •
Ф°(Л
Дж • К • моль
174.065
197.432
211.725
211.955
223.105
232.411
240.512
247.739
254.291
260.300
265.858
271.037
275.889
280.456
284.772
288.865
292.758
296.472
300.022
303.423
306.687
309.826
312.848
315.764
318.579
321.301
323.936
326.489
плл QAK
331.370
333.706
335.978
338.190
340.344
342.443
344.491
346.489
348.440
350.346
352.210
354.032
355.816
357.561
359.271
360.947
362.58.
364.199
365.779
367.329
368.852
370.346
371.814
373.257
374.675
376.069
377.440
378.789
380.117
381.423
382.710
383.976
p(N) • р2 @) • р
5С(Л
207.365
232.041
248.998
249.284
263.425
275.571
286.249
295.780
304.388
312.235
319.446
326.118
332.325
338.129
343.577
348.712
353.566
358.167
362.540
366.707
370.685
374.489
378.135
381.634
384.998
388.236
391.356
394.368
397.278
400.093
402.818
405.459
408.021
410.508
412.925
415.275
417.562
419.788
421.958
424.074
426.139
428.153
430.122
432.045
433.926
435.765
437.566
439.328
441.055
442.747
444.405
446.032
447.627
449.193
450.731
452.240
453.723
455.181
456.613
458.021
459.406
-(нжу V/
//°(/-)-//°(П)
кДж • моль
3.330
6.922
11.113
11.199
16.128
21.580
27.442
33.629
40.077
46.742
53.588
60.589
67.723
74.975
82.328
89.770
97.291
104.882
112.534
120.240
127.995
135.793
143.630
151.502
159.406
167.337
175.294
183.275
1 01 97fi
1 J7 1 •? 1 \J
199.297
207.336
215.390
223.459
231.542
239.638
247.745
255.862
263.990
272.127
280.272
288.425
296.586
304.754
312.928
321.108
329.294
337.485
345.681
353.882
362.087
370.297
378.510
386.728
394.948
403.172
411.400
419.630
427.864
436.099
444.338
452.579
rpanc-HNO2
(г)
Таблица 168
r'@; = 1253.218 кДж- моль
]о к'°(Т\
IV. 1\ \ 1 )
-642.3678
-313.1528
-204.3408
-202.9709
-147.7036
-114.4566
-92.2435
-76.3475
-64.4063
-55.1057
-47.6559
-41.5538
-36.4638
-32.1530
-28.4551
-25.2479
-22.4398
-19.9606
-17.7556
-15.7818
-14.0045
-12.3958
-10.9328
-9.5965
-8.3712
-7.2435
-6.2023
-5.2379
-4.3421
-3.5080
-2.7292
-2.0005
-1.3172
-.6751
-.0707
.4993
1.0378
1.5473
2.0301
2.4883
2.9237
3.3379
3.7326
4.1090
4.4684
4.8119
5.1407
5.4555
5.7574
6.0470
6.3252
6.5926
6.8498
7.0974
7.3360
7.5660
7.7880
8.0022
8.2092
8.4093
8.6028
т
к
100
200
298.15
300
400
500
600
700
800
900
1000 .
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'?
7 2
? ос
1 S Т?
ОС О
го _ ? ^
^ ° ос" L
^ z <ч ri
< I С ^
i Z
а»
8. ^ о ?
о &
**¦• с
1 ^ 1
ОС "Z
™ о
© '2
+ L/
с*
'II §
го
о 5 v
6 ^ ^
? с* Я
ос Н g
sO °°
г^ to
г- © и
»О °. w
00 ©
ГО Р-
II +
{^
о
•е-
238

Класс точности
V-C
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
51(fo
5200
5300
5400
5500
5600
5700
5800
5900
6000
/
33.437
37.896
44.756
44.882
51.059
56.007
59.900
62.994
65.506
67.588
69.343
70.840
72.127
73.242
74.210
75.056
75.797
76.448
77.023
77.531
77.982
78.385
78.744
79.066
79.356
79.617
79.853
80.067
80.261
80.438
80.600
80.748
80.884
81.009
81.124
81.230
81.329
81.420
81.504
81.583
81.656
81.724
81.788
81.847
81.903
81.955
82.004
82.050
82.094
82.135
82.173
82.210
82.244
82.277
82.308
82.337
82.365
82.391
82.416
82.440
82.463
цис-АЗОТИСТАЯ КИСЛОТА цис-Н№2 (г)
К°(Т) = р(Н) р(*
Ф°(Л
Дж • К • моль
174.135
197.394
211.468
211.695
222.619
231.736
239.686
246.793
253.250
259.184
264.682
269.812
274.624
279.158
283.447
287.518
291.393
295.091
298.628
302.018
305.273
308.404
311.419
314.328
317.139
319.856
322.488
325.037
327.511
329.913
332.247
334.518
336.728
338.880
340.978
343.025
345.022
346.972
348.878
350.741
352.563
354.346
356.092
357.801
359.476
361.118
362.729
364.308
365.859
367.380
368.875
370.343
371.786
373.204
374.598
375.970
377.319
378.646
379.953
381.239
382.507
J)V@) р
5С(/)
207.412
231.627
248.038
248.315
262.102
274.048
284.618
294.093
302.674
310.513
317.728
324.409
330.329
336.447
341.912
347.061
351.929
356.544
360.931
365.109
369.097
372.912
376.567
380.074
383.446
386.691
389.818
392.836
395.751
398.570
401.300
403.946
406.511
409.002
411.423
413.776
416.065
418.295
420.468
422.585
424.652
426.669
428.639
430.564
432.447
434.288
436.090
437.854
439.582
441.275
442.935
444.562
446.159
447.726
449.264
450.775
452.258
453.716
455.150
456.559
457.944
j(hno2) ^
//°(Л-//°((
кДж • моль"
3.328
6.847
10.903
10.986
15.793
21.156
26.959
33.110
39.539
46.197
53.045
60.057
67.206
74.476
81.850
89.314
96.858
104.471
112.145
119.873
127.649
135.468
143.325
151.215
159.137
167.086
175.059
183.055
191.072
199.107
207.159
215.227
223.308
231.403
239.510
247.628
255.756
263.893
272.039
280.194
288.355
296.524
304.700
312.882
321.069
329.262
337.460
345.663
353.870
362.082
370.297
378.516
386.739
394.965
403.195
411.427
419.662
427.900
436.140
444.383
452.628
^//с@) - 1251.518
>)
1
\gK°(T)
-641.4834
-312.7067
-204.0296
-202.6613
-147.4562
-114.2437
-92.0523
-76.1712
-64.2410
-54.9487
-47.5056
-41.4091
-36.3537
-32.0169
-28.3225
-25.1184
-22.3130
-19.8362
-17.6335
-15.6617
-13.8862
-12.2792
-10.8178
-9.4830
-8.2590
-7.1325
-6.0925
-5.1292
-4.2345
-3.4013
-2.6234
-1.8956
-1.2131
-.5718
.0319
.6013
1.1391
1.6480
2.1302
2.5878
3.0226
3.4363
3.8305
4.2064
4.5654
4.9085
5.2368
5.5512
5.8527
6.1420
6.4198
6.6868
6.9437
7.1910
7.4293
7.6590
7.8806
8.0946
8.3013
8.5011
8.6944
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
со
О
г>-
;i
+
-
Н
</¦>
с-
ч©
со
ОС
+
ио
to
О
О
1
sO
On
s
vO
+
ОС
to
On
Tf
oc
со
о"*
•е-
ТабЛй ца 169
Т
л
о
1
Л L
1 5
? $ _
•*• г** —
о »> §
о s
г ? ?
¦- м. 5
« - CNl
i о" -
= ? 7
^ с
<г ^
т
?
о
i
? 5
? w
? V
+ V
N* 2
— и->
"* rt"
Ю 1
•О W
ON |l
•0 ^
On w
чО
239

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
C°iT)
33.901
42.830
54.115
54.316
64.168
72.051
78.197
82.927
86.625
89.484
91.750
93.542
94.973
96.173
97.115
97.920
98.602
99.160
99.646
100.071
100.437
100.747
101.020
101.261
101.474
101.663
101.830
ГО 1.986
i ло 1 ofi
1U*. 1 *и
102.251
102.364
102.465
102.556
102.638
102.712
102.780
102.840
102.895
102.945
102.990
103.031
103.069
103.102
103.133
103.162
103.187
103.211
103.232
103.251
103.269
103.353
103.373
103.391
103.408
103.424
103.439
103.452
103.464
103.476
103.487
103.497
К°(Т)= р(Н) •
Ф°(Т)
Дж • К • моль
188.345
211.969
226.938
227.185
239.331
249.836
259.261
267.84.6
275.758
283.128
290.016
296.482
302.589
308.351
313.842
319.050
324.013
328.769
333.310
337.656
341.835
345.869
349.750
353.489
357.097
360.581
363.952
367.232
QTfi Л 1 Л
О1\).*т 1 Ч
373.501
376.498
379.411
382.244
385.001
387.686
390.303
392.856
395.347
397.780
к 400.157
402.480
404.752
406.976
409.152
411.284
413.373
415.421
417.429
419.399
421.332
423.273
425.140
426.974
428.776
430.548
432.290
434.003
435.688
437.347
438.979
440.586
АЗОТНАЯ
p(N) • рЪ (О) • р~1
-1
i
221.689
247.543
266.783
267.119
284.132
299.340
313.053
325.485
336.796
347.172
356.726
365.558
373.761
381.407
388.572
395.304
401.646
407.635
413.315
418.715
423.856
428.759
433.450
437.946
442.263
446.413
450.410
454.252
457.958
461.540
465.006
468.362
471.617
474.775
477.841
480.822
483.721
486.542
489.291
491.970
494.583
497.132
499.622
502.054
504.431
506.756
509.030
511.257
513.437
515.573
517.602
519.650
521.659
523.630
525.565
527.464
529.330
531.164
532.965
534.737
536.479
КИСЛОТА
(HNO3)
Г/°(/')-//°@
кДж • моль
3.334
7.115
11.880
11.980
17.920
24.752
32.275
40.348
48.831
57.640
66.709
75.984
85.406
94.973
104.623
114.381
124.213'
134.073
144.009
154.012
164.042
174.068
184.139
194.251
204.399
214.580
224.791
.234.953
оль 1 99
Z40.1 ?*>
255.312
265.522
275.749
285.994
296.254
306.527
316.814
327.112
337.422
347.742
358.072
368.412
378.759
389.114
399.477
409.846
420.221
430.602
440.989
451.381
461.779
471.646
482.001
492.360
502.724
513.090
523.460
533.833
544.209
554.588
564.971
575.355
HNO3 (г)
)
1
\оК°(ТЛ
igA \I )
-792.9240
-385.0322
-250.1464
-248.4480
-179.9160
-138.6848
-111.1391
-91.4292
-76.6257
-65.0994
-55.8695
-48.3114
-42.0093
-36.6729
-32.0977
-28.1301
-24.6569
-21.5921
-1&.8664
-16.4265
-14.2302
-12.2434
-10.4366
-8.7864
-7.2732
-5.8807
-4.5950
-3.4050
-2.3000
-L2710
-.3104
.5885
1.4313
2.2233
2.9688
.3.6719
4.3361
4.9645
5.5599
6.1250
6.6620
7.1729
7.6596
8.1238
8.5671
8.9907
9.3961
9.7844
10.1567
10.5138
10.8547
11.1842
11.5012
11.8064
12.1004
12.3839
12.6574
12.9214
13.1765
13.4231
13.6616
1551.401 кДж
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
. 1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
• моль 1
00
С4
О
со
ЧО
II
+
о
On
ЧО
т1;
со
+
CN
СО
f-Ч
CN
СО
О
О
1
о
ON
+
ЧО
ЧО
ЧО
О)
со
чо
II
с
0
•6-
Таб
Т
§
с*
о
о
<Ч
(N
1
О
с-Г
о
w
И
Q
1
|
_
i
со
>>
1
+
о
On
со
1
CN
00
оо
ЧО
+
лица 170
Т
л
о
&
CN
О)
со
со
«—4
1
II
ни
об
<ч
С
со
о
2
X
0
<J
т
§
т
k
CN
ЧО
»о
»о
11
о о?
со
Я
о
g
ЧО
V
V
8
1
о
к.
II
х
240

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.277
39.611
46.471
46.605
53.604
59.674
64.770
69.156
73.071
76.649
79.946
82.979
85.750
88.261
90.521
92.540
94.335
95.923
97.325
98.558
99.643
100.595
101.431
102.165
102.810
103.377
103.875
104.315
104.703
105.045
105.348
105.616
105.855
106.067
106.255
106.424
106.574
106.709
106.830
106.938
107.036
107.124
107.203
107.275
107.340
107.398
107.452
107.500
107.545
107.585
107.622
107.656
107.686
107.715
107.741
107.764
107.786
107.806
107.825
107.842
107.858
K°(T) = p(N) V
Ф°(Л
Дж • К • моль
160.307
183.911
198.382
198.616
209.892
219.349
227.647
235.119
241.959
248.296
254.217
259J89
265.062
270.073
274.854
279.428
283.817
288.036
292.100
296.020
299.808
303.473
307.022
310.463
313.802
317.046
320.199
323.267
326.253
329.163
331.999
334.766
337.465
340.102
342.679
345.197
347.660
350.069
352.428
354.738
357.001
359.219
361.394
363.527
365.619
367.673
369.689
371.669
373.615
375.526
377.405
379.253
381.070
382.858
384.617
386.348
388.053
389.732
391.385
393.014
394.618
ГИДРОКСИЛАМИН NH 2 ОН (г)
(Н)-р(О).
193.745
218.999
236.067
236.354
250.736
263.370
274.713
285.034
294.528
303.344
311.593 .
319.357
326.698
333.663
340.288
346.603
352.634
358.402
363.925
369.221
374.304
379.189
383.889
388.414
392.776
396.985
401.049
404.978
408.779
412.459
416.025
419.484
422.841
426.102
429.271
432.354
435.354
438.276
441.123
443.900
446.608
449.252
451.835
454.358
456.825
459.238
461.599
463.910
466.174
468.392 .
470.566
472.697
474.788
476.840
478.853
480.831
482.773
484.680
486.556
488.399
490.212
jfVNF^OH) А.
Н°(Т)-Н°{())
кДж • моль
3.344
7.018
11.236
11.322
16.338
22.010
28.240
34.941
42.055
49.544
57.376
65.524
73.963
82.666
91.607
100.762
110.107
119.622
129.286
139.081
148.992
159.005
169.107
179.288
189.537
199.847
210.211
220.620
231.072
24L560
252.080
262.628
273.202
283.798
294.414
305.048
315.698
326.363
337.040
347.728
358.427
369.135
379.852 \
390.575
401.306
412.043
422.786
433.533
444.286
455.042
465.802
476.566
487.333
498.103
508.876
519.652
530.429
541.209
551.990
562.774
573.559
Я°@)= 1405.561
нк°(т)
-719.7373
-350.0560
-227.7608
-226.2203
-164.0411
-126.5977
-101.5566
-83.6205
-70.1355
-59.6245
-51.1997
-44.2952
-38.5330
-33.6512
-29.4623
-25.8285
-22.6464
-19.8369
-17.3381
-15.1013
-13.0875
-11.2649
-9.6076
-8.0942
-6.7067
•5.4301
-4.2517
•3.1605
-2.1473
-К2040
-.3236
.4999
1.2718
1.9970
2.6793
3.3227
3.9302
4.5048
5.0491
5.5654
6.0559
6.5223
6.9666
7.3901
7.7943
8.1806
8.5500
8.9037
9.2426
9.5677
9.8798
ЮЛ 796
10.4679
10.7454
11.0126
11.2701
11.5184
11.7580
11.9893
12.2129
12.4290
кДж • моль
Т -
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ос
Os
<N
О
СО
со
II
<
+
»о
00
со
оо
+
?*
00
г^
V©
г-
»о
о
о
1
1
тГ
г^
+
р-
L.003
со
и
t
°*
Таблица 171
i
л
о
*
&
00
«о
00
39.
1
II
о
з?
о
с*
о
Т
л
с;
|
к
с*
го
X
щ
Os
V©
+
ё
Os
°°.
Os
VO
i
Os
00
<N
+
-
Mil
|
a,
Д
V
000 i
о
и
00
ON
fN
и
о
г»
Z
w
О
<3
T
•S
i
T
со
О
00
sO
C^J
11
CO
о
о
о
V
v
о
о
»/*>
о
II
н
16 172.
241

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZOMU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.816
44.009
56.369
56.603
68.470
78.347
86.248
92.571
97.714
101.973
105.655
108.600
111.210
113.460
115.408
117.104
118.585
119.883
121.026
122.035
122.929
123.724
124.433
125.068
125.638
126.151
126.614
127.034
1 97 А1 *>
1 4bl mt 1 О
127.762
128.079
128.369
128.634
128.879
Г29.103
129.311
129.502
129.680
129.845
129.998
130.140
130.273
130.397
130.513
130.621
130.723
130.819
130.909
130.993
131.073
131.148
131.219
131.286
131.349
131.409
131.466
131.520
131.571
131.620
131.666
131.710
К°(Т)= p2(N).
Ф°(Л
Дж • К • моль
188.444
212.366
227.636
227.889
240.392
251.322
261.222
270.349
278.849
286.818
294.327
301.432
308.175
314.594
320.720
326.579
332.194
337.585
342.768
347.760
352.573
357.222
36L715
366.064
370.277
374.362
378.327
382.179
389.567
393.115
396.571
399.941
403.228
406.437
409.571
412.634
415.628
418.557
421.423
424.229
426.978
429.672
432.312
434.902
437.442
439.935
442.383
444.786
447.147
449.467
451.748
453.990
456.196
458.365
460.500
462.602
464.671
466.708
468.715
470.692
АМИНИЛ-НИТРОТШ2*Ю2 (г)
р2(Н).р2(О)./
S°(T)
-1
221.994
248.580
268.433
268.782
286.732
303.111
318.121
331.908
344.616
356.379
367.313
377.521
387.085
396.077
404.559
412.580
420.186
427.415
434.300
440.872
447.154
453.172
458.944
464.490
469.825
474.964
479.921
484.707
JOQ, О О Л
*гО«7.ОО*г
493.812
498.148
502.353
506.433
510.395
514.246
517.991
521.637
525.187
528.648
532.023
535.316
538.531
541.672
544.741
547.743
550.680
553.554
556.368
559.125
561.827
564.476
567.073
569.622
572.124
574.579
576.991
579.360
581.689
583.977
586.228
588.441
о г (NH2NO^ Дг//°@) = 1879.614 кДж •
//°(Л //°@)
кДж моль
lgA'V)
3.355 -960.8659
7.243 -466.5790
12.163 -303.0957
12.268 -301.0368
18.536 -217.9496
25.894 -167.9432
34.139 -134.5220
43.091 -110.6002
52.614 -92.6281
62.605 -78.6298
72.986 -67.4176
83.698 -58.2347
94.692 -50.5758
105.928 -44.0906
117.374 -38.5286
129.001 -33.7058
140.787 -29.4841
152.712 -25.7579
164.759 -22.4449
176.913 -19.4801
189.162 -16.8113
201.495 -14,3965
213.904 -12.2011
226.379 -10.1965
238.915 -8.3590
251.505 . -6.6686
264.144 -5.1083
276.826 -3.6637
OfiO КАСЪ 9 4995
2оУ.54У -Z.oZZo
302.308 -1.0738
315.100 .0914
327.923 1.1813
340.774 2.2029
353.649 3.1625
366.548 4.0655
379.469 4.9168
392.410 5.7206
405.370 6.4809
418.346 7.2010
431.338 7.8842
444.345 8.5330
457.366 9.1502
470.399 9.7379
483.445 10.2982
496.502 10.8330
509.569 11.3440
522.646 11.8328
535.732 12.3007
548.328 12.7492
561.931 13.1793
575.042 13.5923
588.160 13.9890
601.286 14.3706
614.417 14.7377
627.555 15.0914
640.699 15.4322
653.848 15.7609
667.003 16.0781
680.163 16.3844
693.327 16.6804
706.496 16.9667
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZOV/1/
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Г а б л и ц а 172
моль 1
л
Т
С l~"f
1 *
* 2 Т
Js О Л
П © g
__ гч *?
5.1 !
о ^ „ Т
Я 2 ~ *
о 1 Ь4
S об ^
И ° On О
.^ г*4 fvl •/")
^ ^ U °
с* м со
о ^ „
z. о "
о з
^ °*
ю о
in 5
О\ *
• т
й 5 2
СО С4 \ 1
° Т ь.
с * о
-^ '—' о
00 iJJ Ю
, со
<** -н *'
^ ^ т
1-н *"* О
ON | -н
2 1 и
5 2 ч
00 00 ч-^'
«о го
II +
L
ь
242

Класс тчности
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
29.110
29.286
30.228
30.252
31.646
32.930
33.954
34.739
35.339
35.805
36.174
36.473
36.720
36.930
37.113
37.277
37.427
37.567
37.703
37.836
37.969
38.104
38.241
38.382
38.526
38.674
38.825
38.979
39 135
39.291
39.447
39.601
39.751
39.898
40.038
40.172
40.297
40.414
40.520
40.615
40.698
40.770
40.829
40.875
40.909
40.930
40.938
40.934
40.917
40,889
40.850
40.799
40.739
40.668
40.589
40.500
40.404
40.300
40.189
40.072
39.949
К°(Т)= p(N)-/
Ф°(Л
Дж • К моль
151.785
171.949
183.602
183.784
192.268
198.954
204.515
209.298
213.507
217.272
220.683
223.803
226.680
229.350
231.841
234.177
236.377
238.455
240.425
242.299
244.084
245.790
247.424
248.990
250.496
251.946
253.344
254.693
пес QQ7
257.260
258.484
259.671
260.824
261.945
263.036
264.097
?65 132
266.141
267.126
268.087
-269.027
269.945
270.843
271.722
272.583
273.426
274.253
275.063
275.858
276.637
277.402
278.153
278.891
279.615
280.327
281.027
281.714
282.391
283.056
283.710
284.354
ФТОРИД АЗОТА
1 (F) • рХ (NF)
5°(Л
1
180.862
201.065
212.908
213.096
27I.S83
229.191
235.290
240.585
245.265
249.455
253.248
256.710
259.894
262.842
265.586
268.152
270.562
272.836
274.987
277.029
278.973
280.829
282.605
284.308
285.944
287.520
289.040
290.508
291.928
293.304
294.639
295.935
297.195
298.420
299.613
300.776
301.909
303.015
304.094
305.148
306.177
307.183
308.166
309.127
310.068
310.987
311.887
312.767
313.629
314.472
315.298
316.106
316.898
317.673
318.433
319.177
319.906
320.620
321.320
322.006
322.678
Д
//°(Л-//°«
кДж • моль
2.908
5.823
8.738
8.794
11.888
15.119
18.465
21.901
25.407
28.965
32.564
36.197
39.857
43.540
47.242
50.962
54.697
58.447
62.211
65.988
69.778
73.582
77.399
81.230
85.075
88.935
92.810
96.700
1 АА ААА
1 UU.OUO
104.527
108.464
112.417
116.384
120.367
124.364
128.374
132.398
136.433
140.480
144.537
148.603
152.676
156.756
160.841
164.931
169.023
173.116
177.210
181.303
185.393
189.480
193.563
197.640
201.710
205.773
209.827
213.873
217.908
221.932
225.946
229.947
NF (г)
г//°@) = 290.093
0
1
\gK°(T)
-147.7963
-71.5699
-46.3523
-46.0346
-33.2080
-25.4813
-20.3126
-16.6097
-13.8254
-11.6547
-9.9145
-8.4878
-7.2968
-6.2872
-5.4205
-4.6681
-4.0088
-3.4262
-2.9077
-2.4431
-2.0244
- .6451
-1.2999
-.9844
-.6948
-.4282
-.1818
.0466
OCQO
.ZOOO
.4566
.6413
.8143
.9765
.1291
.2727
.4082
.5363
.6576
1.7725
1.8816
1.9853
2.0840
2.1781
2.2678
2.3536
2.4355
2.5140
2.5892
2.6614
2.7306
2.7972
2.8612
2.9228
2.9822
3.0394
3.0947
3.1481
3.1996
3.2495
3.2978
3.3445
кДж • моль *
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5$00
5900
6000
о
о
р
со
со
и
'х
со
?ч
vq
+
'&
О
О
V
ЧО
СО
со
со
ON
о
СО
II
о
Таблица 173
i
§
'ё i 'ё
S •* 2
к °^ -*
CJ ^ '^
о <3 i
о к *3-
р „ R.
00 ^-ч "^
•/") к^ 00
CN ^ О
II *? *О
О °°
ON II
Z tu со
о 5»
Vu^ О
т
i
о
* 8
ч g
СО v ,
н V
<N
ON V
1 о
00 ^
°> 'о
* о
+ ?
СО II
о
СО >*"^
1
243

Класс точности
V-E '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
33.427
36.339
41.057
41.146
45.470
48.692
50.980
52.605
53.780
54.650
55.309
55.819
56.222
56.546
56.811
57.031
57.216
57.374
57.510
57.629
57.733
57.825
57.908
57.983
58.051
58.113
58Г170
58.223
58.272
58.318
58.362
58.403
58.442
58.479
58.514
58.548
58.580
58.612
58.642
58.671
58.700
58.728
58.755
58.781
58.807
58.832
58.857
58.881
58.905
58.929
58.952
58.975
58.998
59.020
59.042
59.064
59.085
59.107
59.128
59.149
Ъ9.170
К°(Т)= p(N) •
Ф°(Т)
Дж • К • моль
177.014
200.216
214.033
214.253
224.739
233.316
240.662
247.126
252.916
258.167
262.976
267.414
271.536
275.384
278.994
282.393
285.605
288.649
291.543
294.300
296.934
299.454
301.871
304.191
306.423
308.574
310.648
312.652
314.590
316.465
318.283
320.047
321.758
323.422
325.040
326.614
328.148
329.643
331.100
332.523
333.912
335.269
336.595
337.892
339.162
340.405
341.622
342.814
343.983
345.130
346.254
347.358
348.441
349.505
350.550
351.577
352.586
353.579
354.555
355.515
356.460
ДИФТОРИД
p2(F) .p'^Nl
S°(T)
-i
210.285
234.147
249.523
249.777
262.231
272.744
281.836
289.823
296.928
303.315
309.109
314.405
319.280
323.794
327.994
331.922
335.608
339.082
342.365
345.478
348.437
351.256
353.948
356.523
358.993
361.364
363.644
365.840
367.959
370.004
371.982
373.897
375.751
377.550
379.296
380.993
382.643
384.248
385.8i 2
387.336
388.821
390.271
391.687
393.069
394.421
395.743
397.036
398.302
399.542
400.757
401.948
.403.116
404.261
405.385
406.488
407.572
408.636
409.682
410.711
411.722
412.716
нс
АЗОТА
Л
\Т)-Н°(()
кДж • моль
3.327
6.786
10.581
10.657
14.997
19.714
24.704
29.888
35.210
40.634
46.133
51.691
57.294
62.933
68.601
74.293
80.006
85.736
91.480
97.237
103.005
108.783
114.570
120.365
126.166
131.974
137.789
143.608
149.433
155.263
161.097
166.935
172.777
178.623
184.473
190.326
196.182
202.042
207.905
213.770
219.639
225.510
231.384
237.261
243.141
249.023
254.907
260.794
266.683
272.575
278.469
284.365
290.264
296.165
302.068
307.973
313.881
319.790
325.702
331.616
337.532
NF2 (г)
гН°@) = 588.36$
)
1
\%К°{Т)
-298.9858
-144.2541
-93.0533
-92.4083
-66.3727
•50.6973
•40.2182
-32.7161
-27.0787
•22.6868
-19.1681
-16.2854
-13.8802
-11.8427
-10.0944
-8.5777
-7.2494
-6.0762
-5.0325
-4.0979
•3.2560
-2.4937
•1.8002
-1.1664
-.5851
-.0499
.4446
.9027
1.3284
1.7250
2.0955
2.4423
2.7676
3.0734
3.3615
3.6333
3.8901
4.1333
4.3638
4.5826
4.7907
4.9888
5.1776
5.3577
5.5298
5.6944
5.8520
6.0030
6.1478
6.2869
6.4205
6.5490
6.6727
6.7919
6.9067
7.0175
7.1245
7.2278
7.3277
7.4243
7.5178
\ кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1 а б л и и а 174
Т
§
1 «?
§ *
tt VO
° S з
§ о S
° 8 ¦
10 «> С4
и ^
-, II Ю
<=> 8
с ™
Гт. •
5 п.
° Ъ
^ 0
«О ,н
Tf 1
ON Л
CN g
s
I *
о 4r
a ^
1 VO
iO 2
+ 1
§ X
5 I
rO" 00
II 4.
С
о
T
§
т
00
О
2
0
0
VO
V
V
g
1
II
244

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
34.043
42.791
53.527
53.712
62.273
68.270
72.425
75.371
77.530
79.167
80.451
81.488
82.350
83.084
83.722
84.2891
84.801
85.269
85.704
86.112
86.499
86.868
87.223
87.567
' 87.901
88.228
88.548
88.862
89.173
89.480
89.784
90.086
90.386
90.685
90.983
91.280
91.576
91.872
92.169
92.465
92.761
93.059
93.356
93.654
93.954
94.253
94.554
94.856
95.159
95.463
95.769
96.075
' 96.383
96.692
97.003
97.315
97.629
97.944
98.260
98.578
98.898
к°(Т) = р(ю -
Ф°(Т)
Дж • К • моль
182.344
205.983
220.941
221.187
233.285
243.665
252.865
261.164
268.736
. 275.704
262.160
288.174
293.804
299.095
304.088
308.814
313.301
317.572
321.647
325.543
329.277
332.861
536.308
339.627
342.828
345.920
348.910
351.804
354.610
357.331
359.974
362.543
365.042
367.476
369.847
372.159
374.416
376.618
378.771
380.875
382.933
384.947
386.920
388.852
390.747
392.604
394.426
396.214
397.970
399.695
401.390
403.056
404.694
406.305
407.890
409.450
410.986
412.499
413.989
415.458
416.905
ТРИФТОРИД АЗОТА NF3 (г)
Таблица 175
р3(? ) • р (NF3) ArH°(i)) = 828.628 кДж • моль
S°(T)
-1
215.707
241.580
260.709
261.040
277.732
292.314
305.151
316.548
326.761
335.991
344.402
352.120
359.248
365.869
372.050
377.846
383.303
388.458
393.344
397.989
402.416
406.645
410.695
414.580
418.313
421.908
425.375
428.723
431.960
435.095
438.133
441.082
443.947
446.733
449.444
452.086
454 662
457.175
459.629
462.027
464.372
466.666
468.912
471.112
473.268
475.383
477.458
479.495
481.495
483.460
485.392
487.292
489.160
490.999
492.809
494.592
496.348
498.079
499.785
501.468
503.127
Н°(Т)-Н°(\))
кДж • моль
lgfC°(T)
3.336 -418.8325
7.119 -200.6110
11.857 -128.3617
11.956 -127.4514
17.779 -90.7118
24.324 -68.5984
31.372 -53.8225
38.769 -43.2507
46.420 -35.3120
54.258 -29.1319
62.242 -24.1844
70.340 -20.1345
78.533 -16.7584
86.806 -13.9011
95.147 -11.4516
103.548 -9.3287
112.003 -7.4713
120.507 -5.8326
129.056 -4.3762
137.647 -3.0735
146.277 -1.9013
154.946 -.8412
163.651 .1222
172.390 ' 1.0015
181.164 1.8070
189.970 2.5478
198.809 3.2312
207.679 3.8635
Р16 581 4.4504
225.514 4.9964
234.477 5.5056
243.471 5.9817
.252.494 6.4276
261.548 6.8462
270.631 7.2398
279.744 7.6106 *
288.887 7.9605
298.060 8.2912
307.261 8.6042
316.493 8.9008
. 325.755 9.1824
335.046 9.4499
344.366 9.7044
353.717 9.9469
363.097 10.1781
372.508 10.3987
381.948 10.6095
391.418 10.8112
400.919 11.0042
410.450 11.1891
420.012 11.3664
429.604 11.5366
439.227 11.7000
448.881 11.8570
458.566 12.00&1
468.281 12.1535
478.029 12.2935
487.807 12.4284
497.617 12.5585
507.459 12.6841
517.333 12.8052
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
'3600
3700
3800
3900
4000.
4100
. 4200
4300
- 4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
А
ё * Т
2 П л
? * §
V * •"•
* IO ^ V
s 3 7 *
*"* 7 Q °
|| »*» »-4
_ II Ю *>
^ ~ ^ ?
О со ^
чГ ? II
м CN "
СО U d
Urn О «
о 2
+
1**» С!
со О
+
Г» Т
* « 2
со . §
S3 п 2
о ** V
6 S ^
1 П V/
н + v
с + о
т; с* о
«^ ?! i
U об 2
СО '""*
+ 1 •
со X ^
»о го
«о г*- »
ОС On w
2 CN
? см
li +
245

Класс точности
V1-E
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ft00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.238
48.269
56.568
56.702
62.963
67.540
70.886
73.350
75.189
76.583
77.657
78.497
79.164
79.701
80.139
80.500
80.801
81.054
81.269
81.453
81.611
81.748
81.868
81.973
82.066
82.149
82.222
82.287
82.346
82.399
82.447
82.491
82.530
82.566
82.599
82.630
82.657
82.683
82.707
82.729
82.749
82.768
82.785
82.802
82.817
82.831
82.845
82.857
82.869
82.880
8? 390
82.900
82.909
82.918
82.926
82.934
82.941
82.948
82.955
82.961
82.967
Ф°(Г)
"~ 1
Дж • К • моль
183.780
208.681
224.940
225.207
238.236
249.216
258.795
267.328
275.041
282.087
288.575
294.590
300.198
305.4о1
310.392
315.057
319.473
323.668
327.661
331.472
335.116
338.607
341.958
345.180
348.281
351.271
354.158
356.948
осп А48
362.262
364.798
367.258
369.648
371.971
374.231
376.431
378.575
380.664
382.703
384.693
386.636
388.536
390.392
392.209
393.986
395.726
397.431
399.101
400.739
402.345
403.920
405.467
406.985
408.476
409.940
411.379
412.794
414.185
415.554
416.900
418.224
ДИФТОРИД
V(F) V(N2
217 879
247.204
268.101
268.451
285.667
300.235
312.860
323.982
333.903
342.843
350.970
358.412
365.272
371.630
377.553
383.095
388.300
393.207
397.846
402.245
406.427
410.412
414.218
417.860
421.350
424.702
427.925
431.030
434.023
436.914
439.708
442.412
445.032
447.572
450.037
452.432
454.760
457.026
459.231
461.380
463.474
465.518
467.513
469.461
471.364
473.226
475.047
476.828
478.573
480.282
481.956
483.598
485.207
486.787
488.337
489.859
491.353
492.821
494.264
495.682
497.076
ДИАЗОТА N
F2) V,
//V>-//°«»
кДж • моль
3.410
7.705
12.868
12.973
18.973
25.510
32.440
39.658
47.089
54.681
62.395
70.204
78.089
86.033
94.025
102.058
110.123
118.216
126.333
134.469
142.623
150.791
158.972
167.164
175.366
183.577
191.795
200.021
208.252
216.490
224.732
232.979
241.230
249.485
257.743
266.005
274.269
282,536
290.806
299.078
307.352
315.627
323.905
332.184
340.465
348.748
357.031
365.317
373.603
381.890
390.179
398.468
406.759
415.050
423.342
431.635
439.929
448.224
456.519
464.815
473.111
э@) = 1029.
о
-523.8659
-253.3421
-163.9355
-162.8100
-117.4068
-90.1019
-71.8662
-58.8226
-49.0289
-41.4048
-35.3010
-30.3039
-26.1375
-22.6105
-19.5862
-16.9642
-14.6693
-12.6439
-10.8431
-9.2315
-7.7808
6.4680
-5.2744
-4.1844
-3.1851
-2.2656
-1.4168
-.6307
.0992
.7790
1.4134
2.0070
2.5636
3.0865
3.5787
4.0428
4.4813
4.8961
5.2891
5.6620
6.0164
6.3536
6.6748
6.9811
7.2737
7.5533
7.8208
8.0771
8.3228
8.5585
8.У850
9.0027
9.2121
U4138
9.6081
9.7955
9.9763
10.1509
10.3196
10.4827
10.6405
126 кДж- моль'1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
О
О
SO
SO
II
•О
SO
ON
SO
О
г»
о
SO
О
О
ON
со
00
г-
со
00
°)
о
Таб
i
2
*
X
О
§
II
/—V
о
сч
Z
о
<
_
1
л
1
1
го
00
so
+
On
О
L
г
н
SO
00
лиц
'л
§
§
§
со
so
II
я
об
CN
Рн"
<S
z
о
а 176
Т
л
5
о
т
чо
О
го
¦
о о?
я
О
g
SO
V
к<
V
о
о
'О
1
о
II
W
246

Класс точности
vi-i:
г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
36.913
46.287
54.319
54.458
61.099
66.099
69.777
72.486
74.503
76.027
77.199
78.114
78.840
79.423
79.898
80.289
80.615
80.889
81.122
81.321
81.492
81.640
81.770
81.883
81.983
82.072
82.151
82.222
82.285
82.342
82.394
82.441
82.484
82.522
82.558
82.591
82.621
82.648
82.674
82.697
82.719
82.739
82.758
8^776
82.792
82.808
82.822
82.835
82.848
82.860
82.871
82.882
82.892
82.901
82.910
82.918
82.926
82.934
82.941
82.948
82.954
^с-ДИФТОРИД ДИАЗОТА
A°(/)-/72(N)
Ф°(Л
— 1
Дж • К • мопь
183.773
208.484
224.383
224.643
237.300
247.963
257.281
265.602
273.139
280.038
286.403
292.314
297.831
303.006
307.878
312.481
316.844
320.990
324.939
328.711
332.319
335.777
339.099
342.292
345.369
348.335
351.200
353.970
356.650
359.248
361.766
364.211
366.586
368.895
371.142
373.330
375.462
377.541
379.569
381.548
383.483
385.372
387.221
389.029
390.798
392.531
394.228
395.892
397.523
399.122
400.691
402.232
403.744
405.229
406.689
408.123
409.533
410.919
412.283
413.624
414.945
V(F) P~l(
-1
217.823
246.373
266.390
266.726
283.343
297.542
309.936
320.906
330.723
339.591
347.664
355.067
361.896
368.230
374.134
379.660
384.853
3.89.748
394.379
398.770
402.946'
406.925
410.727
414.364
417.851
421.199
424.420
427.522
430.513
433.402
436.194
438.896
441.515
444.053
446.517
448.911
451.238
453.502
455.707
457.854
459.948
461.991
463.985
465.933
467.836
469.697
471.517
473.298
475.042
476.751
478.425
480.066
481.676
483.255
484.804
486.326
487.820
489.288
490.730
492.148
493.542
w v
//°(/')-//°@)
кДж • моль
3.405
7.578
12.525
12.625
18.417
24.790
31.593
38.713
46.067
53.597
61 261
69.028
76.877
84.792
92.758
100.768
108.814
116.890
124.991
133.113
141.254
149.411
157.581
165.764
173.957
182.160
190.372
198.590
206.816
215.047
223.284
231.526
2.9.772
248.022
256.276
264.534
272.794
281.058
289.324
297.592
305.863
314.136
322.411
330.688
338.966
347.246
355.528
363.810
372.095
380.380
388.667
396.954
405.243
413.533
421.823
430.114
438.407
446.700
454.994
463.288
471.583
^wc-N2F2
'@) = 1029
ЫК°(Т)
-523.8656
-253.3317
-163.9064
-162.7805
-117.3579
-90.0364
-71.7871
-58.7323
-48.9296
-41.2978
-35.1876
-30.1850
-26.0139
-22.4828
-19.4548
-16.8297
-14.5320
-12.5040
-10.7009
-9.0873
-7.6347
-6.3Й02
-5.1250
-4.0336
-3.0330
-2.1123
-1.2623
-.4752
.2558
.9364
1.5718
2.1662
2.7235
3.2471
3.7400
4.2048
4.6439
5.0592
5.4528
5.8263
6.1812
6.5188
6.8405
7.1472
7.4402
7.7202
7.9881
8.2447
8.4908
8.7269
8.9537
9.1717
9.3814
9.5833
9.7779
9.9656
10.1466
10.3215
10.4904
10.6538
10.8119
(г)
.186 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2Э00
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
1200
4300
4400
4500
4600
4700
4800
900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
о
чО
чО
II
+
ЧО
2
+
с*
1
г-
ЧО
00
00
р
о
а
ЧО
г*~
со
Os
г-
+
О
со
Os
СО
И
о
•9"
Таблиц
л
с;
~ §
1 1
2 *
^ со
П о
^ fN
О чО
g "
г- С
|| »iO
S °°
\ '-*
~~сч ***
1 Z
S- ч->
* о
< 5-
3
i
а
00
со
+
ё
IT)
Г"»
1
н
OS
со
CN
ЧО
Os
+
а 177
Т
л
1
к
ЧО
О
СО
О о?
со
я
О
О
о
ЧО
V
V
о
о
«о
1
о
II
247

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
. 4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
35.324
44.933
53.397
53.539
60.316
65.435
69.225
72.030
74.125
75.712
76.933
77.888
78.645
79.254
79.750
80.159
80.500
80.786
81.029
. 81.237
81.416
81.571
81.706
81.825
81.930
82.023
82.165
82.179
82.246
82.305
82.359
82.409
82.453
82.494
82.531
82.565
82.596
82.625
82.652
82.677
82.699
82.721
82.740
82.759
82.776
82.792
82.807
82.821
82.834
82.847
82.859
82.870
82.880
82.890
82.899
82.908
82.916
82.924
82.932
82,939
82.945
трянс-ДИФТОРИД ДИАЗОТА
к°(Т)= Р2(Ю
Ф°(Л
Дж К • моль"
181.427
205.583
221.050
' 221.304
233.662
244.104
253.254
261.440
268.869
275.678
281.968
287.814
293.276
298.403
303.233
307.799
312.129
316.245
320.168
323.915
327.502
330.940
334.243
337.420
340.481
343.433
346.284
349.041
351.710
354.296
356.805
359.240
361.606
363.907
366.146
368.326
370.451
372.523
374.545
376.518
378.446
380.331
382.174
383.977 .
385.741
387.469
389.162
390.821
392.448
394.044
395.609
397.146
398.655
400.137
401.593
403.024
404.431
405.814
407.175
408.514
409.832
• P2(F) • fl (N
5°(Г>
-1
215.052
242.411
261.988
262.319
278.692
292.729
305.011
315.904
325.666
334.492
342.535
349.914
356.725
363.045
368.937
374.454 •
379.638
384.527
389.152
393.539
397.710
401.686
405.484
409.119
412.604
415.950
419.169
422.269
425.259
428.146
430.937
433.639
436.256
438.793
441.257
443.650
445.976
448.239
450.443
452.591
454.684
456.726
458.720
460.667
462.570
464.430
466.250
468.031
469.775
471.483
473.157
474.798
476.407
477.986
479.535
481.057
482.550
484.018
485.460
486.878
488.272
2F2> V
Я°(Г)-Я°@)
кДж * моль
3.362
7.365
12.206
12.304
18.012
24.312
31.055
38.125
45.437
52.933
60.568
68.311
76.139
84.035
91.986
99.982
108.015
116.080
124.171
132.285
' 140.417
148.567
156.731
164.908
173.095
181.293
189.500
197.714
205.935
214.163
222.396
230.635
238.878
247.125
255.376
263.631
271.889
280.150
288.414
296.681
304.949
313.220
321.493
329.768
338.045
346.324
354.603
362.885
371.168
379.452
387.737
396.023
404.311
412.600
420.889
429.179
437.470
445.762
454.055
462.349
470.643
Tpanc-N2F2
(г)
АО) = 1023.586 кДж- моль
lgK°(T)
-520.8181
-251.7176
-162.7512
-161.6311
-116.4366
-89.2499
-71.0892
-58.0971
-48.3409
-40.7451
-34.6634
-29.6841
-25.5322
-22.0173
-19.0033
-16.3901
-14.1029
-12.0841
-10.2892
-8.6828
-7.2368
-5.9282
-4.7384
-3.6519
-2.6558
-1.7392
-.8930
-.1094
.6183
1.2959
1.9284
2.5202
3,0750
3.5963
4.0870
4.5498
4.9868
5.4004
5.7922
6.1640
6.5173
6.8535
7.1737
7.4791
7.7708
8.0496
8.3163
8.5718
8.8168
9.0518
9.2776
9.4947
9.7035
9.9045
10.0983
10.2851
10.4654
10.6395
10.8077
10.9703
11.1277
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
180р
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
О
1—(
VO
II
+
***
г***
«о
+
1,.
CN
О
О
1
|
СО
чс?.
Г1-
Г»
+
1-4
Г^
<N
СО
со
II
с
с»
ф
Та б л и
i
л
о
о
о
\о
CS
с-
II
$
С
сч
С4)
1
3!
8.
о
<
с^
г-
о
00
1
А
00
. - О •
(N
+
Т
л
k
со
г^
VO
II
»О
об
О\
(N
Щ
С4
1
О
>.
ца 178
i
§
i
V
ин
k
1
О
со
II
о?
со
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о
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V
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><
248

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
49.076
70.594
88.381
88.665
101.425
109.979
115.720
119.660
122.443
124.465
125.972
127.122
128.016
128.725
129.295
129.760
130.144
130.465
130.736
130.966
131.164
131.334
131.482
131.612
131.727
131.827
131.917
131397
1 90 AAQ
132.134
132.192
132.245
132.293
132.337
132.376
132.413
132.447
132.478
132.506
132.533
132.557
132.580
132.601
132.621
132.639
132.656
132.672
132.687
132.701
132.715
132.727
132.739
132.750
132.760
132.770
132.780
132.788
132.797
132.805
132.812
132.820
/rV).= p'(N)
Ф°(П
Дж • К~1 • моль"
205.290
235.906
257.675
258.045
276.533
292.711
307.171
320.261
332.220
343.224
353.413
362.896
371.762
380.086
387.928
395.341
402.369
409.048
415.412
421.488
427.302
432.874
438.224
443.369
448.324
453.101
457.715
462.174
ААА AQA
470!б70
474.724
478.658
482.480
•486.196
489.810
493.330
496.760
500.103
503.364.
506.548
509.657
512.696
515.667
518.573
521.417
524.202
526.930
529.603
532.223
534.793
537.315
539.789
542.219
544.604
546.948
549.252
551.516
553.743
555.932
558.087
560.207
ТЕТРАФТОРИД ДИАЗОТД
•p4(F) .pN
S°{T)
-l
245.144
285.740
317.413
317.961
345.334
368.950
389.543
407.695
423.866
438.410
451.606
463.668
474.769
485.045
494.606
503.543
511.930
519.830
527.295
534.370
541.093
547.497
553.610
559.457
565.061
570.441
575.613
580.593
КАК QQR
OOvtUwv
990.030
594.511
598.846
603.046
607.117
611.068
614.906
618.637
622.266
625.800
629.242
632.598
635.871
639.066
642.186
645.236
648.217
651.132
653.986
656.780
659.516
662.197
664.826
667.403
669.932
672.414
674.850
677.243
679.593
681.903
684.173
686.405
2F4> M
Я°(Г)-#°@)
кДж • моль~
3.985
9.967
17.811
17.975
27.520
38.119
49.423
61.204
73.317
85.667
98.193
110.850
123.609
136.447
149.349
162.302
175.298
188.329
201.390
214.475
227.582
240.707
253.848
267.003
280.170
293.348
306.535
319.731
QQO QQA
346.144
359.360
372.582
385.809
399.041
412.276
425.516
438.759
452.005
465.255
478.507
491.761
505.018
518.277
531.538
544.801
558.066
571.332
584.600
597.870
611.140
624.412
637.686
650.960
664.236
677.512
690.790
704.068
717.348
730.628
743.908
757.190
^N2F4 (г)
D@) = 1264.228 кДж • моль
«V,
Т
К
-635.9030 100
-302.7643 200
-192.5344 298.15
-191.1462 300
-135.1369 400
•101.4502 500
-78.9564 600
-62.8726 700
-50.8016 800
-41.4093 900
•33.8939 1000
-27.7446 1100
-22.6205 1200
-18.2854 1300
-14.5703 1400
-11.3514 1500
-8.5358 1600
-6.0524 1700
-3.8457 1800
-1.8721 1900
-.0966 2000
1.5090 2100
2.9680 2200
4.2994 2300
5.5193 2400
6.6411 2500
7.6760 2600
8.6337 2700
О. KQQ& OQftA
10.3497 2900
11.1213 3000.
11.8427 3100
12.5187 3200
13.1533 3300
13.7503 3400
14.3129 3500
14.8440 3600
15.3461 3700
15.8216 3800
16.2724 3900
16.7006 4000
17.1076 4100
17.4951 4200
17.8645 4300
18.2169 4400
18.5535 4500
18.8754 4600
19.1835 4700
19.4787 4800
19.7617 4900
20.0334 5000
20.2944 5100
20.5453 5200
20.7866 5300
21.0191 5400
21.2430 5500
21.4589 5600
21.6673 5700
21.8685 5800
22.0628 5900
22.2507 6.000
о
о
о
s
II*
Таблица 179
Т
л
Т S
л
X о 2
^ 1 ж
со || ^
7* Q ЕЗ
II * СО
•О ON
® об Л
о S,
\ °
с
С
»/
? т
? 1
со «в
с*
К с Я
с*
а
ч^
3 о
<Ч to so
он .
С
5 »n v
1 V v
оо « §
<ч Н О
оо %г> ю
°» со
ON * ^
8 ? ^
о о
3 ?
1
/•
N.
+
249

Класс точности
VI- Ь
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
45.057
66.666
85.509
85.813
99.464
108.594
114.703
118.887
121.838
123.979
125.573
126.789
127.734
128.483
129.085
129.577
129.983
130.322
130.607
130.850
131.059
131.239
131.396
131.533
131.653
131.760
131.855
131.939
132.015
132.083
132.145
132.201
132.251
132.298
132.340
132.378
132.414
132.447
132.477
132.505
132.530
132.554
132.577
132.598
132.617
132.635
132.652
132.668
132.683
132.697
132.710
132.722
132.734
132.745
132.756
132.765
132.775
132.784
132.792
132.800
132.808
тряис-ТЕТРАФТОРИД ДИАЗОТА транс-NJ^ (г)
Л°(Л = р2(М)
Ф°(Л
Дж • К • моль
203.524
232.073
252.494
252.844
270.398
285.913
299.885
312.601
324.265
335.031
345.025
354.344
363.071
371.276
379.014
386.336
393.284
399.892
406.191
412.210
417.972
423.496
428.803
433.908
438.826
443.570
448.152
452.582
456.871
461.026
465.056
468.969
472.770
476.466
480.062
483.564
486.977
490.305
493.551
496.721
499.817
502.843
505.801
508.696
511.529
514.303
517.021
519.684
522.295
524.856
527.369
529.835
532.257
534.635
536.972
539.268
541.525
543.745
545.928
548.076
550.191
P4(F) V
-1
240.832
278.582
308.878
309.408
336.092
:*59.336
379.711
397.727
413.805
428.286
441.435
453.463
464.537
474.792
484.336
493.260
501.636
509.526
516.984
524.052
530.769
537.168
543.277
549.120
554.721
560.098
565.267
570.245
575.045
579.679
584,158
588.491
592.689
596.760
600.710
604.547
608.276
611.905
615.437
618.879
622.234
625.507
628.701
631.821
634.870
637.850
640.766
643.619
646.412
649.148
651.829
654.457
657.034
659.563
662.044
664.480
666.872
669.223
Ы 1.532
673.802
676.034
(N2F4) &rU
/Гт-и°A))
' кДж • моль
3.731
9.302
16.811
16.969
26.277
36.711
47.896
59.588
71.633
83.929
96.410
109.031
121.759
134.571
147.451
160.385
173.363
186.379
199.426
212.499
225.595
238.710
251.842
264.988
278.148
291.318
304.499
317.689
330.887
344.092
357.303
370.520
383.743
396.971
410.203
423.438
436.678
449.921
463.167
476.416
489.668
502.922
516.179
529.438
542.698
555.961
569.225
582.491
595.759
609.028
622.298
635.570
648.843
662.117
675.392
688.668
701.945
715.223
728.502
741.781
755.061
\()) = 1264.228 кДж • моль *
\gK°(T)
-635.8107
-302.5642
-192.2637
-190.8744
-134.8165
-101.0952
-78.5758
-62.4724
-50.3860
-40.9813
-33.4557
-27.2979
-22.1665
-17.8251
-14.1047
-10.8811
-8.0613
-5.5741
-3.3640
-1.3875
.3907
L9988
3.4601
4.7936
6.0154
7.1389
8.1755
9.1347
10.0250
10.8535
11.6263
12.3488
13.0259
13.6615
14.2595
14.8230
15.3550
15.8579
16.3342
16.7858
17.2146
17.6223
18.0105
18.3804
18.7334
19.0706
19.3930
19.7016
19.9973
20.2808
20.5529
20.8143
21.0656
21.3074
21.5402
21.7645
21.9808
22.1895
22 3910
22.5857
22.7739
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
S500
5600
5700
5800
5900
6000
i
L
о
о
о
р
о
II
+
2
«О
О)
+
со
1О
оо
<N
О
о
1
1
со
чо
<N
О)
+
чо
оо
t~~
со
о
ч?>
II
1 а Г)
Т
л
X
<N
On
rf
-н
II
О
zT
1
<^>
а:
8.
о
1
л
к
о
2?
Т
*
г*
О)
+
с*
н
г-
Г J
со
со
1
00
со
(^
+
Л И 1!
т
о
р
со
CN
1
I!
5
00
Os
сч
1
1
0
л 180
i
1
1
г*
к
и
¦—ч
со
VO
II
п
о «
со
я
о
о
о
ЧО
V
V
о
о
1
II
Н
250

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°}(Т)
48.842
71.151
88.327
88.605
101.183
109.724
115.493
119.468
122.282
124.329
125.856
127.022
127.930
128.650
129.229
129.702
130.093
130.419
130.694
130.928
131.129
131.303
131.454
131.586
131.702
131.805
131.896
131.978
132.051
132.117
132.176
132.230
132.279
132.323
132.364
132.401
132.436
132.467
132.496
132.523
132.548
132.571
132.593
132.613
132.631
132.649
132.665
132.681
132.695
132.708
132.721
132.733
132.744
132.755
132.765
132.775
132.784
132.792
132.800
132.808
132.815
гош-ТЕТРАФТОРИД ДИАЗОТА
К°(Т)= p2(N) p
Ф°(Л
Дж К - моль" !
203.504.
233.606
255.299
255.668
274.117
290.260
304.689
317.751
329.685
340.668
350.839
360.305
369.157
377.468
385.300
392.702
399.721
406.392
412.748
418.818
424.625
430.192
435.537
440.677
445.627
450.400
455.010
459.465
463.777
467.955
472.006
475.937
479.756
483.470
487.082
490.600
494.027
497.368
500.627
503.809
506.917
509.954
512.923
515.828
518.671
521.454
524.180
526.852
529.472
532.040
534.560
537.034
539.462
541.847
544.190
546.493
548.756
550.981
553.170
555.324
557.443
4(F) -р
s°m
242.153
283.137
314.903
315.450
342.775
366.333
386.882
405.002
421.149
435.676
448.858
460.910
472.003
482.272
491.828
500.761
509.145
.517.041
524.504
531.577
538.298
544.700
550.812
556.658
562.261
567.639
572.810
577.790
582.591
587.226
591.706
596.041
600.240
604.311
608.262
612.099
615.829
619.458
622.992
626.433
629.789
633.062
636.257
639.377
642.426
645.407
648.323
651.176
653.970
656.706
659.387
662.015
664.593
667.121
669.603
672.039
674.432
676.782
679.092
681.362
683.594
(N2F4) Дг//
//°СП-//°@)
кДж • моль
3.865
9.906
17.771
17.935
27.463
38.036
49.316
61.076
73.171
85.506
98.019
110.666
123.415
136.246
149.141
162.088
175.07*
188.104
201.160
214.242
227.345
240.467
253.604
266.756
279.921
293.096
306.282
319.475
332.677
345.885
359.100
372.320
385.546
398.776
412.010
425.249
438.490
451.736
464.984
478.235
491.488
504.744
518.003
531.263
544.525
557.789
571.055
584.322
597.591
610.861
624.132
637.405
650.679
663.954
677.230
690.507
703.785
717.064
730.343
743.624
756.905
eoui-N2F
°@) = 1262.
\%К°(Т)
-635.0304
-302.2546
-192.1488
-190.7622
-134.8159
-101.1664
-78.6969
-62.6301
-50.5718
-41.1892
-33.6815
-27.5385
-22.4195
-18.0887
-14.3773
-11.1616
-8.3488
-5.8678
-3.6632
-1.6916
.0821
1.6862
3.1438
4.4739
5.6927
6.8K3
7.8472
8.8041
9.6921
10.5184
11.2892
12.0100
12.6853
13.3193
13.9158
14.4778
15.0084
15.5100
15.9850
16.4355
16.8632
17.2699
17.6570
18.0260
18.3781
18.7144
19.0360
19.3438
19.6387
19.9215
20.1929
20.4536
20.7042
20.9454
21.1776
21.4013
21.6170
21.8252
22.0262
22.2204
22.4081
4(Г)
736 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
о
s
II
+
'&
с-»
со
+
со
о
1
|
«Л)
О)
об
о
со
гН
г-Н
?
Таблица 181
Т
л
'л
i d
Й *• 7
X © R
1 7 §
II xr>
О об ^
c* <fr »-«
1 ^T и
I ' о 5
о <5
о
5 §
~ °
{5 V
*+ V
М О
н о
00. ' *
CO •
*-< о
1
со "
251

Класс точности
IV-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
поо v
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°(Т)= p(F) •
*
Р
Ф°(Г)
Дж • К • моль
33.561 174.890
37.273 198.177
41.528 212.154
41.598 212.377
44.854 222.984
47.363 231.605
49.383 238.938
51.031 245.356
52.380 251.082
53.489 256.265
54.408 261.006
55.176 265.380
55.825 269.444
56.381 273&41
56.864 276.805
57.288 280.165
57.666 283.344
58.009 286.361
58.324 289.233
58.620 291.972
58.901 294.593
59.173 297.103
59.442 299.514
59.710 301.833
59.981 304.067
60.258 306.222
60.543 308.303
60.838 310.317
61.143 312.268
61.461 314.159
61.790 315.995
62.131 317.779
62.485 319.514
62.849 321.204
63.224 322.849
63.609 324.454
64.003 326.020
64.404 327.550
64.812 329.045 .
65.225 330.507
65.641 331.937
66.060 333.339
66.480 334.711
66.901 336.057
67.320 337.376
67.738 338.672
68.152 339.943
68.562 341.192
68.967 342.419
69.367 343.626
69.761 344.812
70.147 345.980
70.526 347.129
70.898 348.260
71.261 349.374
71.616 350.471
71.962 351.553
72.300 352.619
72.62$ 353.671
72.949 354.707
73.260 355.730
ОКСИД-ФТОРИД АЗОТА
P(N) р(О) .
-1
208.181
232.402
248.109
248.366
. 260.802
271.091
279.912
287.652
294.557
300.793
306.477
311.700
316.530
321.021
325.217
329.155
332.865
336.371
339.696
342.857
345.871
348.752
351.510
354.159
356.706
359.160
361.529
363.819
366.037
368.188
370.277
372.309
374.287
376.216
378.097
379.936
381.733
383.492
385.215
386.904
388.560
390.186
391.783
393.352
' 394.895
396.413
397.906
399.376
400.824
402.250
4Q3.656
405.041
406.407
407.754
409.082
410.393
411.687
412.963
414.224
415.468
416.696
р'1 (FNO) АгИ
н°т-н°т
кДж • моль"
3.329
6.845
10.720
10.797
15,127
19.743
24.584
29.607
34.780
40.075
45.472
50.952
56.503
62.114
67.777
73.485
79.233
85.017
90.834
96.681
102.557
108.461
114.392
120.349
126.334
132.346
138.386
144.455
150.554
156.684
162.846
169.042
175.273
181.539
187.843
194.184
200.565*
206.985
213.446
219.948
226.491
233.076
239.703
246.372
253.083
259.836
266.631
273.466
280.343
287.260
294.216
301.212
308.245
315.317
322.425
329.568
336.748
343.961
351.207
358.486
365.796
FNO (г)
Таблица 182
э@) = 857.508 кДж • моль
«V,
-439.4438
-214.3750
-140.0224
-139.0865
•101.3349
-78.6310
-63.4653
-52.6146
-44.4649
-38.1183
-33.0355
-28.8727
-25.4006
-22.4603
-19.9383
-17.7511
-15.8361
-14.1454
-12.6419
-11.2959
-10,0840
-8.9870
-7.9894
-7.0783
-6.2428
-5.4739
-4.7639
-4.1064
-3.4958
-2.9272
-2.3964
-1.8998
-1.4341
-.9967
-.5850
-.1969
.1697
.5164
.8449
1.1564
1.4524
1.7338
2.0018
2.2572
2.5010
2.7339
2.9566
3.1697
3.3739
3.5697
3.7575
3.9379
4.1113
4.2781
4.4387
4.5933
4.7423
4.8860
5.0247
5.1587
5.2881
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
.4900
5000
5100
5200
5300
5400
5500
5600
5700
5800.
5900
6000
i
л
7 §
1 5
Л * _
Е ' 1
О % А
? 3 §
Й о J
о * Я i
S s *? i
ON у© С-Ч
" » ^ Я
^ ^  1О
О 00 ¦""*
9 *{ п
Ь z ^
О NU
^ О^
'+
1
* §
лч ЧУ Ь^
00 О
00 * О
С*"* * О
О со V
н *• V
5 ^ о
+ S
со т S
^- г» %ri
*° »о о
ON + К,
00 5 "
S о н
^00 w
II +
0
252

Класс точности
IV-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
oftfiO
ZOl/v
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
33.659
40.251
49.091
49.245
56.544
62.112
66.347
-69.583
72.076
74.018
75.550
76.775
77.767
78.581 .
79.257
79.825
80.308
80.723
81.082
81.397
81.674
81.920
82.141
82.341
82.522
82.687
82.839
82.980
83.110
83^232
83.346
83.453
83.555
83.652
83.743
83.831
83.915
83.996
84.074
84.149
84.221
84.292
84.360
84.427
84.492
84.556
84.618
84.679
84.739
84.797
84.855
84.912
84.968
85.023
85.077
85.131
85.184
85.237
85.289
85.341
85.392
K°m = p(N) ¦
Ф°(Т)
Дж • К • моль
183.258
206.676
221.164
221.399
232.891
242.622
251.185
258.884
265.902
272.364
278.356
283.946
289.187
294.121
298.781
303.198
307.396
311.395
315.214
318.868
322.371
325.735
328.970
332.087
335.092
337.996
340.802
343.520
346.152
348.706
351.185
353.59.4
355.936
358.216
360.436
362.599
364.709
366.768
368.778
370.742
372.661
374.539
376.375
• 378.173
379.935
381.660
383.352
385.010
386.637
388.233
389.800
391.340
392.852
394.337
395.798
397.234
398.646
400.035
401.403
402.748
404.074
ГИДРИД4>ТОРИД АЗОТА
р(Н) p(F) •/:
S°(T)
-l
216.572
241.515
259.266
259.570
274.783
288.027
299.743
310.224
319.685
328.292
336.172
343.433
350.157
356.415
362.264
367.752
372.920
377.801
382.425
386.818
391.000
394.991
398.807
402.463
405.971
409.343
412.589
415.718
418.739
421.657
424.481
427.216
429.867
432.439
434.938
437.367
439.729
442.030
444.271
446.456
448.587
450.668
452.700
454.685
456.627
458.527
460.386
462.206
463.990
465.737
467.451
469.132
470.781
472.400
473.990
475.552
477.086
478.594
480.077
481.536
482.971
f^NHF) A^H
Я°<П-*°<0)
кДж • моль""
3.331
6.968
11.360
11.451
16.757
22.702
29.135
35.938
43.027
50.335
57.817
65.435
73.164
80.982
88.875
96.830
104.838
112.890
120.980
129.105
137.258
145.438
153.642
161.866
170.109
178.370
186.646
194.937
ллл 949
21L559
219.888
228.228
236.578
244.939
'253.308
261.687
270.074
278.470
286.873
295.285
303.Z03
312.129
320.561
329.001
337.447
345.899
354.358
362.823
371.294
379.770
388.253
396.741
405.235
413.735
422.240
430.750
439.266
447.787
456.313
464.845
473.381
NHF (г)
:>@) = 649.17*
\%К°(Т)
-583.8928
-283.0397
-183.5590
-182.3066
-131.7677
-101.3648
-81.0548
-66.5243
-55.6123
-47.1163
-40.3136
-34.7438
-30.0995
-26.1677
-22.7962
-19.8731
-17.3146
-15.0565
-13.0488
-11.2521
-9.6348
-8.1714
-6.8408
-5.6257
-4.5119
-3.4870
-2.5410
-1.6650.
. ОС1С
.ОО 1 О
-.0941
.6129
1.2742
1.8943
2.4767
3.0250
3.5419
4.0301
4.4919
4.9295
5.3447
5.7391
6.1143
6.4717
6.8125
7.1378
7.4488
7.7462
8.0311
8.3041
8.5661
8.8176
9.0594
9.2919
9.5156
9.7312
9.9390
10.1395
10.3330
10.5199
10.7005
10.8752
Таблица 186
> кДж* моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
о
1 •?¦
>Я
§ k
* из
5 О S
^ as •
о *¦¦¦' ^ Т
Оч гО —* i
СО ON I ^
°. s » *
2 ~ ? 5
II *О ^"
*у* л> СО
§ ом о 5
'JL. ру С/Э
о i
^ °
X I
00 л
Ss О
п ?
+ V
их Я
•о Cf О
^ го О
-н X чо
CN 00
' Й ^
х + V
В с* О
00 ^~ *°
(N 00 .,
+ | Т
оо X f—
^* 00
00 Tf II
1О ^ ^
¦^» со
II +
с
•е-
253

Класс точности
VI -
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
IJ500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
.3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
D
С°(Т)
41.648
54.719
66.949
67.152
76.686
83.836
89.218
93.294
96.385
98.723
100.520
101.858
102.850
103.50^
104.131
104.519
104.799
105.013
105.123
105.208
105.273
105.287
105.284
105.273
105.258
105.239
105.205
105.166
105.127
105.088
105.048
105.009
104.970
104.932
104.897
104.866
104.835
104.805
104.776
104.747
104.718
104.691
104.664
104.637
104.611
104.586
104.562
104.538
104.514
104.492
104.469
104.448
104.426
104.406
104.386
104.366
104.347
104.328
104.310
104.292
104.275
ТРИОКСИД-ФТОРИД АЗОТА FNO3 (г)
К (Т) = p(F) • j
Ф°(Т)
Дж • К • моль
199.671
226.509
244.618
244.918
259.710
272.424
283.715
293.905
303.223
311.813
319.761
327.195
334.165
340.716
346.903
352.763
358.326
363.610
368.670
373.494
378.101
382.540
386.803
390.896
394.834
398.627
402.305
405.864
409.304
412.634
415.860
418.988
422.024
424.974
427.848
430.657
433.392
436.056
438.653
441.187
443.660
446.076
448.436
450.744
453.002
455.212
457.376
459.495
461.572
463.609
465.606
467.565
469.488
471.376
473.230
475.052
476.842
478.602
480.333
482.035
483.710
p(N) V(O) '
5°(П
235.799
268.633
293.057
293.472
314.182
332.091
347.885
361.958
374.633
386.135
396.616
406.263
415.174
423.436
431.134
438.333
445.090
451.448
457.456
463.144
468.543
473.677
478.573
483.253
487.734
492.033
496.156
500.122
503.944
507.632
511.195
514.641
517.978
521.211
524.344
527.379
530.328
533.196
535.988
538.707
541.358
543.943
546.465
548.928
551.334
553.686
555.987
558.237
560.441
562.599
564.712
566.784
568.816
570.809
572.765
574.684
576.569
578.420
580.239
582.027
583.785
p-(FNO8) Л,/'
//V>-//°«»
кДж • моль
3.613
8.425
14.442
14.566
21.789
29.833
38.502
47.637
57.128
66.890
76.855
86.974
97.211
107.536
117.924
128.355
138.823
149.325
159.814
170.335
180.884
191.388
201.894
212.419
222.960
233.516
244.013
254.498
264.992
275.495
286.007
296.526
307.051
317.583
328.087
338.527
348.972
359.421
369.874
380.330
390,790
401.254
411.720
422.189
432.660
443.134
453.610
464.088
474.568
485.050
495.534
506.019
516.506
526.994
537.484
547.975
558.467
568.960
579.454
589.950
600.446
э@) = 1266.114
\gK°(T)
-642.2843
-309.0576
-198.8458
-197.4579
-141.4644
-107.7843
-85.2909
-69.2027
-57.1253
-47.7254
-40.2005
-34.0426
-28.9101
-24.5662
-20.8427
-17.6158
-14.7922
-12.3004
-10.0866
-8.1054
-6.3219
-4.7093
-3.2435
-1.9049
-.6777
.4516
1.4931
2.4572
3.3526
4.1863
4.9646
5.6927
6.3755
7.0169
7.6205
8.1889
8.7259
9.2340
9.7154
10.1723
10.6064
11.0194
11.4128
11.7881
12.1464
12.4889
12.8166
13.1305
13.4315
13.7202
13.9976
14.2642
14.5207
14.7676
15.0055
15.2349
15.4562
15.6699
15.8764
16.0760
16.2690
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
со
со
о
р
00
II
+
7
о
ON
«О
СО
см
00
О
ON
«о
СО
О
О
1
|
CN
Ю
S
О
О
II
I a G л и ц
А
о
т ^
«1 1
00 ~*
я я
о S
С ™
"со ^
О СО
z о
Ь §
Ь
i
А
О
?
1
С*
со
X
г-
ON
С*
X
«Л
1—1
00
On
"Г*
X
+
л 184
i
А
К
О
1
24
On
п
о о?
со
я
О
О
V
V
о
о
1
о
II
254

Класс тч
VI 1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ПОС1И
35.766
52.637
68.064
68.305
78.923
86.042
90.974
94.500
97.089
99.033
100.522
101.684
102.605
103.345
103.949
104.446
104.861
105.209
105.505
105.758
105.977
106.166
106.331
106.476
106.603
106.717
106.818
106.908
106.989
107.062
107.128
107.188
107.242
107.292
107.337
107.379
107.417
107.453
107.485
107.515
107.543
107.569
107.593
107.616
107.637
107.657
107.675
107.692
107.708
107.724
107.738
107.751
107.764
107.776
107.787
107.798
107.808
107.818
107.827
107.836
107.844
ОКСИД-ТРИФТОРИД АЗОТА
A°G')=p3(F) •
Ф°(Т)
~~ 1
Дж • К • моль
190.314
214.894
231.674
231.959
246.193
258.688
269.893
280.067
289.388
297.988
305.971
313.416
320.392
326.953
333.145
339.007
344.572
349.867
354.919
359.747
364.370
368.806
373.068
377.171
381.124
384.938
388.624
392.188
395.640
398.985
402.230
405.381
408.443
411.422
414.320
417.144
419.895
422.579
425.197
427.754
430.252
432.694
435.082
437.418
439.705
441.945
444.140
446.291
448.400
450.469
452.499
454.491
456.448
458.370
460.258
462.114
463.939
465.733
467.498
469.235
470.945
P(N) -p(O) •
-1
223.976
253.553
277.615
278.036
299.245
317.672
333.821
348.124
360.921
372.474
382.988
392.626
401.514
409.757
417.439
424.628
431.383
437.750
443.773
449.484
454.914
460.090
465.032
469.762
474.296
478.651
482.838
486.871
490.761
494.516
498.147
501.661
505.065
508.366
511.569
514.681
517.707
520.651
523.516
526.309
529.031
531.687
534.280
536.812
539.286
541.705
544.072
546.387
548.655
550.876
553.052
555.186
557.278
559.331
561.346
563.324
565.266
567.174
569.049
570.893
572.705
p^FgNO) Ar/I
//°<7')-//°@)
кДж • моль
3.366
7.732
13.697
13.823
21.221
29.492
38.357
47.640
57.226
67.037
77.018
87.130
97.346
107.645
118.011
128.431
138.897
149.401
159.938
170.501
181.088
191.695
202.320
212.961
223.615
234.281
244.958
255.644
266.339
277.042
287.751
298.467
309.189
319.915
330.647
341.383
352.122
362.866
373.613
384.363
395.116
405.872
416.630
427.390
438.153
448.918
459.684
470.452
481.223
491.994
502.767
513542
524.318
535.095
545.873
556,652
567.432
578.214
588.996
599.779
610.563
F3NO (г)
°@) = 1128.210
igtfV)
-569.7898
-272.5619
-174.1784
-172.9392
-122.9336
-92.8473
-72.7500
-58.3739
-47.5802
-39.1784
-32.4529
-26.9479
-22.3590
-18.4752
-15.1458
-12.2600
-9.7350
-7.5070
-5.5267
-3.7550
-2.1607
-.7184
.5926
1.7893
2.8862
3.8951
4.8261
5.6881
6.4883
7.2331
7.9281
8.5781
9.1874
9.7596
10.2980
10.8056
11.2848
11.7381
12.1674
12.5746
12.9614
13.3292
13.6795
14.0134
14.3321
14.6366
14.9279
15.2067
15.4739
15.7302
15.9762
16.2126
16.4399
16.6586
16.8692
17.0722
17.2680
17.4569
17.6393
17.8156
17.9860
кДж • моль *
/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900 .
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
8
ОС
II
+
1 v<
о
со
СО
+
^г
00
ГО
CN
О
1
н
—
г-
о
+
Tf
оо
о
II
с
о
•е-
Таблиц
т
§ *
S §
х о
00 00
С-* «—1
об 1
^ II
7 2
II ?
<—' ОО
On
g "-
п С
м* Z
s-^ ГО
о О
"*- о
-Q
§
го
оо
оо
н
Г4!
ч©
о
н
ОО
го
CN
-ь
а 185
_
i
л
§
i
ЧО
п
о о!
со
2
о
g
чо
V
к.
V
g
ю
1
II
255

Класс точности
IV-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
4500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500.
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600 -
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
. 4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°т
33.259
33.611
35.233
35.274
37.678
40.046
42.121
43.904
45.447
46.796
47.981
49.023
49.941
50.749
51.460
52.086
52.638
53.126
53.558
53.942
54.283
54.588
54.861
55.107
55.329
55.531
55.715
55.883
56.039
56.183
56.317
56.443
56.563
56.677
56.786
56.891 '
56.993
57.093
57.190
57.286
57.381
57.475
57.568
57.661
57.754
57.846
57.939
58.031
58.123
58.215
58.308
58.399
58.491
58.583
58.674
58.764
58.854
58.944
59.033
59.121
59.208
К°(Т) - p(N ) •
Ф°(Т)
Дж • К • моль
160.646
183.704
197.052
197.260
207.030
214.790
221.304
226.963
231.992
236.536
240.692
244.529
248.098
251.438
254.581
257.549
260.364
263.040
265.594
268.035
270.374
272.620
274.779
276.859
278.866
280.805
282.679
284.495
286.254
287.962
289.620
291.231
292.799
294.325
295.812
297.262
298.677 ,
300.058
301.406
302.724
304.013
305.274
306.509
307.718
308.902
310.063
311.201
312.318
313.414
314.490
315.547
316.585
317.605
318.608
319.594
320.564
321.51$
322.458
323.384
324.294
325.191
ГИДРИД-ФТОРИД АЗОТА
р(Н) • p(F) • р
S°iT)
-1
193.903
217.010
230.692
230.910
241.381
250.047
257.536
264.167
270.132
275.565
280.558
285.181
289.487
293.517
297.304
300.876
304.256
307.462
310.511
313.417
316.193
318.849
321.395
323.839
326.189
328.452
330.633
332.739
334.775 *
336.744
338.651
340.499
342.293
344.036
345.729
347.377
348.981
350.544
352.068
353.554
355.006
356.424
357.810
359.166
360.493
361.791
363.064
364.311
365.534
366.733
367.910
369.066
370.201
371.316
372.412
373.489
374.548
375.591
376.617
377.627
378.621
r'(NHF) ArH
H°lT)-H°«))
кДж • моль
3.326
6.661
10.030
10.095
13.740
17.629
21.740
26.043
30.512
35.126
39.866
44.717
49.667
54.702
59.813
64.991
70.228
75.517
80.851
86.227
91.638
97.082
102.555
108.053
113.575
119.118
124.681
130.261
135.857
141.468
147.093
152.731
158.382
164.044
169.717
175.401
181.035
186.799
192.513
198.237
203.971
209.714
215.466
221.227
226.998
232.778
238.567
244.366
250.173
255.990
261.817
267.652
273.496
279.350
285.213
291.085
296.966
302.856
308.755
314.662
320.579
NHF (г)
Таблица 1 86
'(()) ~ 649.175 кДж- моль
lgA'V)
-332.1070
-161.4982
-105.0631
-104.3521
-75.6501
-58.3590
-46.7901
-38.4998
-32.2640
-27.4010
-23.5013
-20.3035
-17.6333
-15.3695
-13.4257
-11.7383
-10.2596
-8.9529
-7.7897
-6.7477
-5.8086
-4.9580
-4.1838 .
-3.4762
-2.8268
-2.2287
-1.6761
-1.1639
-.6879
-.2442
.1702
.5583
.9224
1.2648
1.5873
1.8917
2.1794
2.4518
2.7100
2.9553
3.1884
3.4104
3.6220
3.8239
4.0169
4.2014
4.3780
4.5473
4.7097
4.8656
5.0154
5.1595
5.2982
5.4318
5.5605
5.6847
5.8046
5.9204
6.0323
6.1405
6.2453
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1*900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-
7Л 1
1 т
1 1 *
* ° -,'
О CN - •
О «/") CN У/(
^ ON *¦* .
rZ *t ~* •*
1 S
^ ~ Я ON
^ s 2 °
* ON
— U. ° В!
Z. X *э
*"*" О
+
Т -н
Н i
ON Л
"* К
о _/
+ 1
ON ^ 2
8 * 8
О fO О
Я & W
§ ? v
I 2 **"
х + V
>-Э с) О
—^ i* О
ON X ^
§ о
5 3 2
оо Ч Ь^
»—ц СО
со . *"*•
со ?
1 +
с
256

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
V
33.261
33.871
36.473
36.540
40.668
45.072
49.166
52.8 Н
56.037
58.884
61.397
63.614
65.568
67.287
68.801
70.134
71.309
72.348
73.267
74.082
74.808
75.455
76.034
76.554
77.021
77.443
7.7.824
78.170
78.484
78.770
79.032
79.271
79.491
79.693
79.879
80.051
80.210
80.357
80.494
80.621
80.739
80.849
80.952
81.048
81.138
81.223
81.302
81.377
81.447
81.513
81.576
81.635
81.691
81.743
81.793
81.840
81.885
81.928
81.969
82.007
82.044
ДИГИДРИД-ФТОРИД АЗОТА
A'°(f)=p(N) •
Ф°(Т)
Дж • К • моль
159.066
182.131
195.528
195.737
205.638
213.625
220.457
226.509
231.993
237.037
241.727
246.122
250.268
254.196
257.932
261.498
264.911
268.185
271.331
274.360
277.282
280.103
282.832
285.473
288.033
290.516
292.928
295.272
297.552
299.771
301.933
304.041
306.096
308.103
310.062
311.977
313.848
315.679
317.471
319.225
320.943
322.626
324.276
325.895
ч 327.482
329.040
330.570
332.072
333.547
334.997
336.423
337.824
339.202
340.558
341.892
343.205
344.498
345.771
347.025
348.261
349.478
p2(H)-p(F) •
s°m
192.324
215.478
229.419
229.645
240.704
250.254
258.840
266.698
273.965
280.734
287.070
293,028
298.649
303.967
309.010
313.803
318.368
322.723
326.884
330.868
334.687
338.352
341.876
345.268
348.536
351.689
354.734
357.677
360.526
363.285
365.96U
368.556
371.076
373.525
375.907
378.225
380.482
382.682
384.827
386.919
388.962
390.957
392.906
394.812
396.677
398.501
400.287
402.036
403.751
405.431
407.078
408.694
410.280
411.836
413.365
414.866
416.341
417.791
419.216
420.618
421.996
р'1 (NH2F)
// °(/')-//°@)
кДж • моль
3.326
6.669
10.105
10.172
14.026
18.314
23.030
28.132
33.578
39.327
45.344
51.597
58.058
64.703
71.509
78.457
85.530
92.714
99.996
107.364
114.809
122.323
129.898
137.528
145.207
152.931
160.694
168.494
176.327
184.190
192.080
199.996
207.934
215.893
223.872
231.869
239.882
247.910
255.953
264.008
272.077
280.156
288.246
296.346
304.456
312.574
320.700
328.834
336.975
345.123
353.278
361.438
369.605
377.776
385.953
394.135
402.321
410.512
418.707
426.905
435.108
NH2F (г)
V/°@)
о
-536.6589
-261.1230
-169.9632
-168.8147
-122.4448
-94.5060
-75.8107
-62.4129
-52.3353
-44.4769
-38.1757
-33.0095
-28.6965
-25.0409
-21.9030
-19.1797
-16.7940
-14.6867
-12.8116
-11.1324
-9.6198
-8.2502
-7.0042
-5.8659
-4.8217
-3.8606
-2.9729
-2.1505
-1.3866
-.6750
-.0106
.6112
1.1944
1.7424
2.2584
2.7450
3.2047
3.6398
4.0520
4.4433
4.8151
5.1689
5.5059
5.8274
6.1343
6.4277
6.7085
6.9774
7.2351
7.4825
7.7200
7.9483
8.1679
8.3794
8.5830
8.7794
8.9688
9.1517
9.3283
9.4990
9.6641
= 1048.051
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5^00
5800
5900
6000
Т а б
кДж • моль *
о
о
о
ГО
II
+
Г--
г-
г-
г—(
+
Ч?>
8
00
»—1
О
о
3
ч©
ЧО
ON
с-
•о
го
гч
го
и
i
л
§
*
г*
о
&
00
II
S
и*
с*
X
о
т
л
с
о
7
*
го
><>
чо
чо
ON
ГО
+
X
00
т—(

ON
1
н
го
+
л и
'й
о
к
о
(=>-
1
1
II
/—N
«о
*"?
00
*!
г
X
?
0
ца 187
Т
е
§
т
«о
го
чо
<N
||
* о «
со
я
о
о
о
чо
V
V
§
«о
^•'
1
о
II
11 872
257

Класс точности
V-F
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛ0
*оии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°т
г
33.587
37.416
43.383
43.502
49.748
55.078
59.341
62.727
65.457
67.696
69.561
71.132
72.466
73.607
74.589
75.437
76.173
76.816
77.378
77.873
78.310
78.697
79.042
79.349
79.625
79.872
80.095
80.297
80.480
80.646
80.798
80.936
81.063
81.180
81.287
81.386
81.477
81.561
81.640
81.712
81.780
81.843
81.902
81.957
82.008
82.056
82.102
82.144
82.184
82.222
82.257
82.291
82.322
82.352
82.381
82.407
82.433
82.457
82.480
82.502
82.523
ГИДРИД-ДИФТОРИД АЗОТА
A'°<7) = p(N) •
Ф°(Л
Дж • К~! • моль"
179.132
202.431
216.453
216.678
227.466
236.437
244.257
251.258
257.631
263.497
268.944
274.033
278.813
283.322
287.592
291.648
295.512
299.201
302.732
306.117
309.368
312.497
315.511
318.420
321.230
323.948
326.579
329.130
•x'w ллс
JO 1 •\j\jk}
334.009
336.344
338.617
340.828
342.983
345.083
347.131
349.130
351.082
352.990
354.855
356.679
358.464
360.211
361.923
363.600
365.243
366.855
368.437
369 989
371.512
373.008
374.478
375.923
377.342
378.738
380.111
381.461
382.790
384.098
385.386
386.654
р(Н) p2(F) •
S°(T)
-1
212.435
236.685
252.701
252.970
266.354
278.048
288.482
297.893
306.454
314.297
321.529
328.235
334.482
340.329
345.821
350.996
355.889
360.527
364.934
369.131
373.137
376.967
380.636
384.156
387.540
390.795
393.932
396.959
399.882
402.709
405.446
408.098
410.669
413.166
415.591
417.948
420.242
422.476
424.652
426.774
428.843
430.864
432.836
434.764
436.649
438.493
440.296
442.063
443.792
445.488
447.149
448.778
450.376
451.945
453.484
454.996
456.481
457.941
459.375
460.785
462.172
p^CNHFj) &rH°
H°(T)-H°@)
кДж • моль
3.330
6.851
10.807
10.888
15.555
- 20.806
26.535
32.645
39.058
45.720
52.585
59.622
66.804
74.109
81.520
89.022
96.603
104.254
111.964
119.727
127.537
135.387
143.275
151.194
159.143
167.118
175.117
183.137
1 Q1 1 7fi
1 У 1.1 /О
199.232
207.305
215.391
223.492
231.604
239.727
247.861
256.004
264.156
272.316
280.484
288.658
296.840
305.027
313.220
321.418
329.621
337.829
346.041
354.258
362.478
370.702
378.929
387.160
395.394
403.631
411.870
420.112
428.356
436.603
444.852
453.104
NHF2 (г)
@)-937.816
\gK°(T)
-477.9123
-231.1678
-149.5001
-148.4711
-106.9281
-81.9045
-65.1678
-53.1804
-44.1690
-37.1463
-31.5183
-26.9067
-23.0586
-19.7987
-17.0016
-14.5751
-12.4502
-10.5738
-8.9048
-7.4105
-6.0649
-4.8468
-3.7389
-2.7269
-1.7988
-.9447
-.1560
.5745
1 9^*41
1 .?OO1
1.8851
2.4751
3.0271
3.5449
4.0313
4.4893
4.9211
5.3291
5.7152
6.0810
6.4281
6.7579
7.0718
7.3707
7.6559
7.9281
8.1884
8.4373
8.6758
8.9044
9.1238
9.334*4
9.5369
9.7316
9.9191
10.0997
10.2738
10.4418
10.6039
10.7605
10.9119
11.0584
кДж • моль 1
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0Л
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
55JH
5600
5700
5800
5900
6000
о
CO
ю
+
1
X
<N
ON
ЧО
+
чо
«о
ON
О
О
1
V
1
CN
CN
<N
CO
ЧО
+
ЧО
s
о
ON
II
Таблица 188
T
>a
§
i .
О Сч
X о
о
V со
* о
3 '
чо II
1 ы
II in
X иГ
? ас
о 5
^ о
1
§
1
(Г)
X
г—I
чо
со
с4
CN
_j_
X
чо
<ч
чо
т^
ю
1
X
CN
О
Tf
Г*-
ЧО
+
§
1
V»
СО
VO
чо
(N
II
о о?
со
я
§
чо
V
к.
v
V
о
О
*о
1
о
II
5-;
258

Класс точности
IV-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.025
40.774
44.621
44.677
47.196
49.140
50.760
52.122
53.259
54.207
55.000
55.672
56.250
56.760
57.224
57.660
58.083
58.504
58.933
59.377
59.838
60.319
60.821
61.342
61.880
62.432
62.995
63.564
64.136
64.708
65.275
65.834
66.381
66.914
67.431
67.928
68.405
68.860
69.292
69.700
70.084
70.443
70.778
71.090
71.378
71.643
71.886
72.109
72.311
72.494
72.659
72.807
72.939
73.056
73.160
73.251
73.330
73.398
73.457
73.507
73.549
Л-°,П = р(С.).р
Ф°(Т)
Дж • К • моль
184.719
208.625
223.359
223.595
234.850
243.981
251.715
258.452
264.437
269.834
274.755
279.281
283.475
287.385
291.049
294.496
297.754
300.841
303.777
306.576
309.252
311.815
314.276
316.643
318.924
321.126
323.255
325.315
327.312
329.251
331.135
332.968
334.752
336.491
338.187
339.843
341.461
343.043
344.591
346.106
347.590
349.044
350.470
351.869
353.242
354.590
355.914
357.215
358.493
359.750
360.987
362.203
363.400
364.579
365.739
366.881
368.007
369.116
370.209
371.287
372.349
ОКСИД-ХЛОРИД АЗОТА C1NO (г)
>(N) P(O) •
S°(T)
218.333
244.413
261.474
261.751
274.969
285.716
294.823
302.753
309.789
316.119
321.872
327.147
332.016
336.539
340.763
344.726
348.461
351.995
355.351
358.549
361.606
364.537
367.355
370.070
372.692
375.229
377.689
380.077
382.399
384.659
386.862
389.012
391.111
393.162
395.167
397.129
399.049
400.930
402.772
404.577
406.347
408.082
409.783
411.452
413.090
414.697
416.275
417.823
419.343
420.836
422.302
423.743
425.158
426.548
427.915
429.258
430.579
431.877
433.154
434.410
435.646
jf!(ClNO)
Дг//°@) = 782.62
кДж • моль
3.361
7.158
11.364
11.447
16.047
20.867
25.865
2A.011
36.282
41.656
47.118
52.653
58.249
63.900
69.600
75.344
81.131
86.961
92.832
98.748
104.708
110.716
116.773
122.881
129.042
135.257
141.529
147.857
154.242
160.684
167.183
173.738
180.349
187.014
193.732
200.500
207.316
214.180
221.088
228.038
235.027
242.053
249.115
256.208
263.332
270.483
277.660
284.860
292.081
299.321
306.579
313.852
321.140
328.440
335.750
343.071
350.400
357.737
365.080
372.428
379.781
-400.4350
-194.9675
-127.1083
-126.2543
-91.8083
-71.0940
-57.2569
-47.3558
-39.9183
-34.1255
-29.4855
-25.6849
-22.5145
-19.8294
-17.5259
-15.5280
-13.7786
-12.2341
-10.8603
-9.6306
-8.5233
-7.5211
-6.6097
. -5.7774
«5.0142
-4.3120
-3.6639
-3.0637
-2.5064
-1.9877
-1,5037
-1.0510
-.6267
-.2283
.1464
.4996
.8330
1.1481
1.4465
1.7293
1.9979
2.2531
2.4960
2.7274
2.9481
3.1589
3.3603
3.5529
3.7374
3.9143
4.0839
4.2467
4.4031
4.5535
4.6982
4.8376
4.9719
5.1013
5.2263
5.3469
5.4634
. кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
О*.
«О
»о
so
II
т
X
<N
ГО
*
ON
о
О
JE;
Г-
ГО
sd
«О
О
го
«о
On
ГО
II
о
Т а б л и
Т
7 9
§ и
& °^
% so.
о Г1
2 "
II
О 00
О и
5 z
° S
^ о
т
л
о
i
•
го
X
On
го
СЧ
!
™Х
г-
1О
о
+

Tiro
as
ца 189
i
л
К
i
•
SO
О
SO
1О
II
о <=*
со
я
о
о
so
V
V
о
о
«О
1
II
Х^
259

Кг.асе точности
VI-D
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;;т
35.358
45.053
53.354
53.490
59.871
64.754
68.498
71.370
73.585
75.310
76.671
77.760
78.643
79.368
79.972
80.482
80.916
81.291
81.618
81.905
82.160
82.388
82.594
82.780
82.951
83.109
83.255
83.391
83.518
83.637
83.751^
83.858
83.960
84.058
84.151
84.241
84.328
84.413
84.494
84.573
84.650
84.726
84.799
84.871
84.942
85.011
85.079
85.146
85.212
85.277
85.341
85.405
85.467
85.530
85.591
85.652
85.712
85.772
85.831
85.890
85.949
ДИОКСИД-ХЛОРИД АЗОТА
К°(Т) = р(С\) ¦
Фсгл
_ j
Дж • К • моль
191.475
215.648
231.135
231.389
243.753
254.178
263.294
271.439
278.825
285.593
291.846
297.659
303.093
308.196
313.006
317.556
321.873
325.979
329.895
333.638
337.222
340.660
343.964
347.144
350.209
353.167
356.026
358.791
361.469
364.066
366.585
369.032
371.411
373.724
375.977
378.172
380.312
382.399
384.436
386.426
388.371
390.273
392.133
393.954
395.736
397.483
399.194
400.872
402.518
404.133
405.718
407.275
408.803
410.306
411.782
413.234
414.661
416.065
417.447
418.807
420.146
р(Ю -Р2(О)
Л'°< Л
-1
225.117
252.514
272.125
272.455
288.759
302.667
314.819
325.603
335.285
344.055
352.063
359.424
366.229
372.553
378.458
383.993
389.202
394.119
398.775
403.195
407.403
411.417
415.255
418.930
422.457
425.847
429.109
432.254
435.289
438.222
441.059
443.807
446.471
449.056
451.567
454.008
456.382
458.694
460.946
463.142
465.284
467.375
469.417
471.413
473.366
475.275
477.144
478.975
480.768
482.526
484.249
485.940
487.599
489.228
490.827
492.398
493.942
495.459
496.952
498.419
499.864
р 4C1NO2) Л.
//V>-//°<«>
кДж • моль
3.364
7.373
12.221
12.320
18.002
24.244
30.915
37.915
45.167
52.616
60.217
67.941
75.762
83.664
91.632
99.656
107.726
115.837
123.983
132.159
140.363
148.590
156.839
165.108
173.395
181.698
190.016
198.349
206.694
215.052
223.421
231.802
240.193
248.594
257.004
265.424
273.852-
282.289
290.735
299.188
307.649
316.118
324.594
333.078
341.568
350.066
358.571
367.082
375.600
384.124
392.655
401.192
409.736
418.286
426.842
435.404
443.972
452.547
461.127
469.713
478.305
C.NO2(r) | 'аГ"'"«190
11°@)= Ю66.118 кДж • моль
/
К
-542.9274 100
-262.6189 200
-169.9526 298.15
-168.7861 300
-121.7204 400
-93.4105 500
-74.4995 600
-60.9698 700
-50.8091 800
-42.8977 900
-36.5629 1000
-31.3760 1100
-27.0508 1200
-23.3891 1300
-20.2490 1400
-17.5266 1500
-15.1436 1600
-13.0404 1700
-11.1704 1800
-9.4970 19004
-7.9906 2000
-6.6274 2100
-5.3880 2200
-4.2563 2300
-3.2188 2400
-2.2643 2500
-1.3831 2600
-.5672 2700
.1905 2800
.8960 2900
1.5544 3000
2.1703 3100
2.7478 3200
3.2903 3300
3.8008 3400
4.2823 3500
4.7369 3600
5.1670 3700
5.5745 3800
5.9611 3900
6.3284 4000
6 6778 4100
7.0106 4200
7.3279 4300
7.6308 4400
7.9203 4500
8.1973 4600
8.4625 4700
8.7167 4800
8.9606 4900
9.1948 5000
9.4199 5100
9.6363 5200
9.8447 5300
10.0453 5400
10.2388 5500
10.4254 5600
10.6055 5700
10.7795 5800
10.9477 5900
11.1103 6000
— 5
i 1
?
7 2
? —
, ч о
? ос V
55 - ? =3
II _
II О
ч^, О ОС
9 \ "
f Cog
Ь Z со
+
т
н -
СО 1
О\ О
+ т
'? i Я
ON Я» О
<N Ё} О
О О
g + V .
-* % §
2 о Й
1С Я То
+ | Т
и +
•в*
260

К iacx i очное i и
1С,
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
зеоо
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
32.299
32.203
31.795
31.799
32.393
33.269
34.083
34.753
35.285
35.706
36.041
36.312
36.535
36.721
36.878
37.014
37.132
37.236
37.330
37.415
37.493
37.565
37.633
37.697
37.758
37.816
37.873
37.928
37.983
38.037
38.091
38.145
38.200
38.257
38.316
38.376
38.440
38.507
38.577
38.652
38.731
38.815
38.904
39.000
39.100
39.206
39.319
39.438
39.562
39.693
39.830
39.972
40.120
40.273
40.431
40.593
40.760
40.930
41.103
41.279
41.457
A"m = p,N).
Ф°(Л
Дж • К • моль
156.603
177.932
190.481
190.676
199.755
206.840
212.678
217.662
222.023
225.905
229.409
232.604
235.541
238.261
240.795
243.166
245.396
247.499
249.491
251.382
253.183
254.901
256.544
258.120
259.632
261.086
262.486
263.837
265.141
266.402
267.623
268.806
269.954
271.068
272.150
273.204
274.228
275.227
276.200
277.150
278.076
278.982
279.866
280.731
281.578
282.406
283.217
284.012
284.792
285.556
286.306
287.042
287.765
288.476
289.173
289.860
290.535
291.199
291.852
292.496
293.129
СУЛЬФИД АЗОТА
p(S) - р~1(Ш)
Л'°(/|
- 1
186.664
209.244
221.984
222.181
231.396
238.717
244.857
250.163
254.840
259.021
262.801
266.249
269.418
272.350
275.078
277.627
280.019
282.274
284.404
286.425
288.346
290.177
291.926
293.601
295.206
296.749
298.233
299.664
301.044
302.378
303.668
304.918
306.130
307.306
308.449
309.561
310.643
311.697
312.725
313.728
314.707
315.665
316.601
317.518
318.416
319.295
320.158
321.005
321.837
322.654
323.457
324.247
325.025
325.790
326.545
327.288
328.021
328.744
329.457
330.161
330.857
//°(/')_//°@
кДж • моль
3.006
6.262
9.393
9.451
12.656
15.939
19.308
22.751
26.253
29.804
33.392
37.010
40.653
44.316
47.996
51.691
55.398
59.116
62.845
66 582
70 328
74.081
77.841
81.607
85.380
89.159
92.943
96.733
100.529
104.330
108.136
111.948
115.765
119.588
123.416
127.251
131.092
134.939
138.793
142.655
146.524
150.401
154.287
158.182
162.087-
166.002
169.928
173.866
177.816
181.779
185.755
189.745
193.750
197.769
201.804
205.856
209.923
214.008
218.109
222.228
226.365
NS(r)
.//°@) - 479.000
)
1
igA'V)
-246.2835
-120.7770
-79.3571
-78.8358
-57.8096
-45.1632
-36.7141
-30.6677
-26.1253
-22.5870
-19.7525
-17.4303
-15.4929
-13.8516
-12.4433
- 1.2215
-10.1513
-9.2061
-8.3651
-7.6120
-6.9335
-6.3190
-5.7599
-5.2490
-4.7802
-4.3485
-3.9496
-3.5800
-3.2364
-2.9162
-2.6171
-2.3370
-2.0741
-1.8269
-1.5941
-1.3743
-1.1665
-.9697
-.7830
-.6058
-.4372
-.2767
-.1236
.0225
.1622
.2958
.4237
.5464
.6641
.7771
.8858
.9903
.0909
.1879
.2814
.3717
.4588
1.5430
1.6244
.7031
1.7793
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
чо
р
ЧО
Т а б
§
о
Jg
чо
сч
II
О
С
С/3
О
% т
s g
го о
¦\
г*
1
г
Т
1 ^
§ к
1
? ч
G- "ё
° Щ
J) +•
1* *\»
* S
П го
го О"*
4
1
Г- чо
ю оо
ЧО П"
о о
«-4
1
/-
?.
V.
{
л и ц а 191 •
\
!
л
г;
О
2 Т
Л о
О ,м"
»о 1
чо *
II ^3
/-^ ^О
*? *-*
оо
^ О о?
со °о
5-
с
О
о
О
V
о
о
1
о
II
261

Класс точности
I
ФОСФОР Р (г)
Таблица 192
Ф°{Т)
S°(T)
Дж • К • моль
HO(T)-H°(Q)
кДж • моль
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.788
20.791
20.797
20.810
20.831
20.865
20.914
20.981
21.068
21.178
21.312
21.471
21.653
21.859
22.088
22.337
22.605
22.890
23.189
23.500
23.821
24.148
24.480
24.814
25.148
25.480
25.808
26.129
26.444
26.749
27.045
27.329
27.601
27.860
28.106
28.338
28.555
28.758
28.947
29.121
29.281
29.426
29.557
29.675
29.779
29.871
29.950
30.016
30.072
30.116
119.595
134.003
142.302
142.431
148.411
153.049
156.839
160.043
162.818
165.267
167.457
169.438
171.246
172.910
174.451
175.885
177.227
178.488
179.677
180.802
181.870
182.887
183.858
184.786
185.677
186.533
187.356
188.151
188.919
189.662
190.382
191.081
191.761
192.422
193.066
193.694
194.307
194.906
195.492
196.065
196.627
197.178
197.718
198.248
198.769
199.280
199.783
200.278
200.765
201.244
201.715
202.180
202.638
203.089
203.534
203.972
204.405
204.832
205.253
205.669
206.079
140.381
154.789
163.085
163.217
169.196
173.835
177.624
180.829
183.604
186.052
188.243
190.224
192.033
193.697
195.239
196.675
198.020
199.287
200.484
201.621
202.704
203.740
204.735
205.694
206.620
207.516
208.388
209.236
210.063
210.871
21К663
212.438
213.200
213.948
214.684
215.408
216.121
216.823
217.516
218.199
218.872
219.536
220.191
220.838
221.475
222.104
222.724
223.336
223.940
224.535
225.121
225.699
226.269
226.831
227.385
227.930
228.468
228.997
229.519
230.032
230.538
2.079
4.157
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.944.
27.023
29.103
31.185
33.270
35.359
37.453
39.556
41.668
43.792
45.931
48.087
50.262
52.460
54.681
56.928
59.202
61.506
63.840
66.206
68.605
71.036
73.501
75.999
78.530
81.095
83.692
86.320
88.980
91.670
94.389
97.135
99.908
102.707
105.529
108.374
111.240
114.125
117.029
119.949
122.884
125.834
128.795
131.768
134.751
137.742
140.740
143.745
146.754
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
С
ж • мол
400 кД
ЧО
го
II
я
«о
г, 298.:
т
к
го
II
со
сч О
On 2
СЧ
О ~
А
о
о
V
V
н
On
СЧ
ON
262

ФОСФОР Р (г)
Таблица 192
(окончание)
С°р(Т)
Ф°G)
Дж К -моль
Я°(Г)-Я°@)
кДж' моль
\%К°{Т)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
30.174
30.193
30.179
30.135
30.065
29.972
29.860
29.732
29.591
29.439
29.278
29.110
28.938
28.761
28.583
28.403
28.223
28.044
27.866
27.690
206.884
207.669
208.435
209.183
209.914
210.628
211.325
212.008
212.675
213.328
213.967
214.592
215.205
215.805
216.393
216.969
217.534
218.088
218.631
219.164
231.527
232.485
233.414
234.314
235.187
236.032
236.852
237.647
238.417
239.165
239.890
240.593
241.276
241.939
242.584
243.210
243.819
244.441
244.988
245.549
152.784
158.821
164.859
170.891
176.911
182.915
188.899
194.858
200.791
206.694
212.566
218.405
224.209
229.979
235.714
241.412
247.075
252.702
258.292
263.848
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
On
о
V©
з ?
q <n
00
i
о
о
V
V
263

I
Класс точности
1-С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
• 1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
ZoUvJ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.120
30.101
32.033
32.068
33.680
34.774
35.506
36.009
36.368
36.633
36.837
36.998
37.129
37.238
37.332
37.413
37.486
37.551
37.612
37.669
37.725
37.779
37.834
37.89а
37.949
38.012
38.081
38.157
ол ОА 1
38.334
38.438
38.554
38.683
38.826
38.985
39.161
39.355
39.566
39.797
40.048
40.320
40.612
40.926
41.261
41.617
41.995
42.394
42.814
43.254
43.714
44.192
44.688
45.200
45.728
46.270
46.825
47.391
4f.966
48.549
49.139
49.733
к°т= р2(?) •
Ф°(П
•" 1
Дж • К • моль
156.156
176.355
188.143
188.328
197.027
203.943
209.719
214.693
219.068
222.977
226.512
229.740
232.711
235.463
238.026
240.425
242.681
244.809
246.824
248.736
250.556
252.293
253.954
255.545
257.072
258.541
259.955
261.318
ОАО А^Л.
263^907
265.139
266.333
267.491
268.616
259.709
270.772
271.808
272.817
273.800
274.761
275.699
276.616
277.512
278.390
279.250
280.092
280.918
281.729
282.525
283.307
284.075
284.830
285.574
286.305
287.026
287.736
288.435
289.125
289.806
290.478
291.141
ДИФОСФОР Р2 (г)
185.248
205.631
218.010
218.206
227.665
235.307
241.716
247.229
252.062
.256.361
260.232
263.751
266.976
269.952
272.716
275.294
277.711
279.985
282.133
284.169
286.102
287.944
289.703
291.386
293.001
294.550
296.042
297.481
298.870
300.214
301.515
302.777
304.003
305.196
306.357
307.490
308.596 ,
309.677
310.735
311.772
312.789
313.788
314.771
315.737
316.690
317.630
318.557
¦ 319.473
320.379
321.276
322.164
323.044
323.916
324.782
325.642
326.496
327.345
328.189
329.028
329.863
330.694
V
//Vn-//°«.)
кДж • моль
2.909
5.855
8.903
8.963
12.255
15,682
19.198
22.775
26.395
30.046
33.720
37.412
41.118
44.837
48.566
52.303
56.048
59.800
63.558
67.322
71.092
74.867
78.648
82.434
86.226
90.024
93.828
97.640
1 0 1 4.АП
1 U 1 .ЧО1/
105.289
109.127
112.977
116.833
120.714
124.604
128.511
132.437
136.383
140.351
144.343
148.361
152.407
156.484
160.593
164.737
168.917
173.137
177.397
181.700
186.048
190.444
194.887
199.382
203.928
208.528
213.182
217.893
222.661
227.486
232.371
237.314
Таблица 193
(О) - 485.606 кДж • моль
«V,
т
К
-249.3141 100
-122.0384 200
-80.0366 298.15
-79.5082 300
-58.2002 400
-45.3944 500
-36.8451 600
-30.7309 700
-26.1400 800
-22.5655 900
-19.7030 1000
-17.3587 1100
-15.4033 1200
- -13.7473 1300
-12.3266 1400
-11.0942 1500
-10.0150 1600
-9.0619 1700 .
-8.2140 1800
-7.4546 1900
-6.7706 2000
-6.1512 2100
-5.5875 2200
-5.0723 2300
-4.5995 2400
-4.1641 2500
-3.7616 2600
-3.3885 2700
о (\л\ с OftftO
-2.7180 2900
-2.4155 3000
-2.1321 3100
-1.8660 3200
-1.6155 3300
-1.3792 3400
-1.1560 3500
-.9447 3600
-.7444 3700
-.5542 3800
-.3733 3900
-.2010 4000
-.0367 4100
.1202 4200
.2702 4300
.4137 4400
.5513 4500
.6832 4600
.8099 4700
.9316 4800
1.0486 4900
1.1613 5000
1.2699 5100
1.3745 5200
1.4755 5300
1.5729 5400
1.6671 5500
1.7581 5600
1.8461 5700
1.9312 5800
2.0137 5900
2.0936 6000
т
о к §
2 § 2
с* к © т
г- X |> *
"I" <-> ГО V»
2 й 2 п
^ ^ II чо
11 3 2 й
55 1 2 =
0 00 II
<^ ? О В!
о"" *Г
'к
rf Т
Г- R
го О
О *
з * 1
3 тн V
a + о
^ ? Т
s s z
s ^
го оо
II ¦+"
о
•е-
264

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
9Q0
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.346
45.925
51.872
51.956
55.440
57.518
58.817
59.669
60.254
60.670
60.975
61.206
61.384
61.524
61.636
61.727
61.802
61.864
61.917
61.961
62.001
62.033
62.061
62.086
62.108
62.128
62.146
62.160
62.174
62.186
62.198
62.208
62.217
62.225
62.233
62.240
62.246
62.252
62.258
62.263
62.268
62.272
62.276
62.280
62.283
62.287
62.290
62.293
62.295
62.298
62.300
62.302
62.304
62.306
62.308
62.310
62.312
62.313
62.315
62.316
62.318
К°(Т)= р3(Р) l
Ф°G)
Дж • К • моль
185.109
207.965
223.149
223.398
235.488
245.532
254.154
261.718
268.460
274.542
280.083
285.172
289.876
294.251
298.340
302.177
305.791
309.208
312.447
315.527
318.462
321.265
323.947
326.519
328.989
331.365
333.654
335.862
ОО7 QQA
340.056
342.052
343.986
345.862*
347.683
349.452
351.173
352.848
354.478
356.068
357.617
359.129
360.606
362.048
363.457
364.836
366.184
367.504
368.797
370.064
371.305
372.522
373.716
374.887
376.037
377.166
378.275
379.364
380.435
381.488
382.523
383.541
ТРИФОСФОР Р3
оХ (Р3)
s()m
215.787
243.862
263.415
263.736
279.205
291.818
302.429
311.564
319.572
326.694
333.103
338.926
344.259
349.178
353.742
357.998
361.984
365.733
369.270
372.619
375.798
378.824
381.710
384.470
387.112
389.648
392.085
394.431
496 692
398.874
400.982
403.022
404.997
406.912
408.769
410.574
412.327
414.033
415.693
417.310
418.886
420.424
421.925
423.390
424.822
426.222
427.591
428.930
430.242
431.526
432.785
434.019
435.228
436.416
437.580
438.723
439.846
440.949
442.033
443.098
444.145
//оG)-//°(()
кДж • моль
3.068
7.180
12.005
12.101
17.487
23.143
28.965
34.892
40.890
46.937
53.020
59.130
65.259
71.405
77.563
83.732
89.908
96.091
102.281
108.475
114.673
120.874
127.079
133.286
139.496
145.708
151.922
158.137
1о4.о54
170.572
176.791
183.011
189.232
195.454
201.677
207.901
214.125
220.350
226.576
232.802
239.028
245.255
251.483
257.711
263.939
270.167
276.396
282.625
288.854
295.084
301.314
307.544
313.775
320.005
326.236
332.467
338.698
344.929
351.161
357.392
363.624
(г)
.//"@) -- 732.614
)
1
1р*°(Г)
-373.6014
-181.2010
-117.7063
-116.9077
-84.7127
-65.3768
-52.4776
-43.2593
-36.3431
-30.9622
-26.6565
-23.1330
-20.1963
-17.7111
-15.5807
-13.7341
-12.1181
-10.6921
-9.4245
-8.2901
-7.2689
-6.3448
-5.5046
-4.7371
-4.0333
-3.3855
-2.7873
-2.2329
1 71 7ft
-1.1 I/O
-1.2378
-.7894
-.3694
.0249
.3957
.7453
1.0754
1.3877
1.6837
1.9646
2.2318
2.4861
2.7287
2.9602
3.1815
3.3934
3.5964
3.7911
3.9781
4.1578
4.3307
4.4973
4.6578
4.8126
4.9621
5.1066
5.2462
5.3814
5.5122
5.6390
5.7619
5.8811
кДж • моль
У
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
oftOO
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
I
|
ОО
С4!
СМ
О)
as
и
+
i
X
CN
СО
+
с»
1.,
со"
ет\
О
00
8
О
о
1
^»
со
ЧО
+
CN
сч
СЧ*
о
•е-
1
1 а б л и ц a 194 jj
§
Т 2 Т
« » §
§ 5 §
7 *
v; О ,-н
^-ч о v
S ^ 5
Ч и |~ч
—« Q oo
fN "-1-» CN
II |2 r^
О OO it
ro — ° oi
Ь 'со ^
о &<
=*: ow
1 •JQ
о
УУ О
7s О
«K V
S v
о v
+ °
+ о
СЦ lO
X
00 '
- ?o
о
I ^
x
Ov ||
о H
4.
265

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАЛ
ZOWf
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р{Т)
37.139
55.501
67.080
67.232
73.210
76.452
78.361
79.567
80.374
80.938
81.347
81.652
81.886
82.070
82.216
82.334
82.431
82.512
82.580
82.637
82.686
82.729
82.765
82.797
82.826
82.851
82.873
82.892
Я9 Qlft
О*<9 I v
82.926
82.940
82.953
82.965
82.975
82.985
82.994
83.002
83.010
83.017
83.023
83.029
83.03
83.040
83.045
83.049
83.053
83.057
83.061
83.064
83.068
83.071
83.073
83.076
83.079
83.081
83.083
83.085
83.087
83.089
83.091
83.093
К°(Т) = р4(Р)
Ф°(Г)
Дж * К ¦ моль
189.837
215.007
232.411
232.704
247.182
259.547
270.350
279.938
288.554
296.374
303.531
310.128
316.244
321.945
327.283
332.300
337.034
341.515
345.767
349.813
353.672
357.361
360.893
364.282
367.539
370.672
373.693
376.608
O7Q АОА
Olv.'rZ't
382.148
384.786
387.343
389.824
392.233
394.574
396.851
399.068
401.227
403.332
405.384
407.387
409.343
411.254
413.123
414.950
416.738
418.488
420.203
421.882
423.529
425.143
426.727
428.281
429.807
431.305
432.777
434.223
435.644
437.042
438.416
439.768
ТЕТРАФОСФОР Р4
•Р~г(Г4)
S°{T)
-1
223.764
255.160
279.900
280.146
300.399
317.118
331.239
343.416
354.097
363.598
372.148
379.916
387.031
393.593
399.681
405.357
410.674
415.674
420.392
424.859
429.099
433.134
436.983
440.663
444.187
447.569
450.819
453.947
дч& Qfi9
459.872
462.683
465.403
468.037
470.590
473.067
475.473
477.811
480.085
482.299
484.456
486.558
488.608
490.609
492.563
494.472
496.339
498.164
499.950
501.699
503.412
505.090
506.735
508.348
509.931
511.484
513.008
514.505
515.976
517.421
518.841
520.238
М
Н°(Т)-Н°(())
кДж * моль"
3.393
8.031
14.100
14.233
21.287
28.785
36.534
44.434
52.434
60.501
68.616
76.767
84.944
93.143
101.357
109.585
117.823
126.071
134.325
142.586
150.852
159.123
167.398
175.676
183.957
192.241
200.527
208.816
917 lfifi
Z1 / . 11ДО
225.397
233.691
241.985
250.281
258.578
266.876
275.175
283.475
291.776
300.077
308.379
316.682
324.985
333.288
341.593
349.897
358.203
366.508
374.814
383.120
391.427
399.734
408.041
416.348
424.656
432.964
441.272
449.581
457.890
466.198
474.507
482.817
(г)
Таблица 195
э@) = 1196.012 кДж- моль
lg*V)
•609.6525
-295.5949
-191.9414
-190.6378
-138.0842
-106.5248
-85.4731
-70.4301
-59.1445
-50.3647
-43;3396
-37.5909
-32.7997
-28.7452
-25.2696
-22.2572
-19.6210
-17.2949
-15.2270
-13.3765
-11.7109
-10.2036
-8.8331
-7.5815
-6.4338
-5.3775
-4.4020
-3.4983
-1.8763
-1.1455
-.4613
.1808
.7847
1.3538
1.8910
2.3992
2.8806
3.3374
3.7715
4.1847
4.5785
4.9544
5.3135
5.6570
5.9860
6.3015
6.6042
6.8951
7.1748
7.4440
7.7033
7.9534
8.1946
8.4276
8,6527
8.8704
9.0811
9.2850
9.4826
9.6742
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
~ о Т
й • 5
R V{ О
« « s *
оо й •
Я 2 * й
™ it ^^
*- <Ч " с*
" vo О *^
w. VO ь*ц О
22 •
^ II «о со
/—ч *"? °^
о оо и
% ."OS
Он Со
С &*
^ с
+
со
О\ Л
12 §
+ ?
»о . о
8 к 8
оо ЕЗ *>
О **> \/
1 ? §
ИГ о
On м «о
C^J <Ч V—.
S3 ^ 2
S с^ "
^- ^н
|| 4-
w
О
266

Класс точности
I-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
32.287
32.203
31.761
31.764
32.328
33.193
34.007
34.681
35.218
35.643
35.982
36.255
36.479
36.665
36.822
36.957
37.073
37.175
37.267
37.348
37.423
37.491
37.555
37.615
37.671
37.725
37.777
37.828
37.878
37.928
37.978
38.029
38.082
38.136
38.192
38.252
38.314
38.381
38.451
38.526
38.606
38.690
38.781
38.877
38.978
39.086
39.201
39.321
39.449
39.582
39.723
39.869
40.022
40.182
40.347
40.519
40.696
40.879
41.066
41.259
41.457
К°(Т)= р(?) •
Ф°(Т)
Дж • К~! • моль"
157.272
178.593
191,139
191.333
200.409
207.487
213.319
218.297
222.652
226.529
230.028
233.217
236.151
238.867
241.396
243.764
245.990
248.090
250.079
251.967
253.765
255.481
257.122
258.694
260.204
261.655
263.053
264.402
265.704
266.963
268.181
269.362
270.507
271.619
272.700
273.751
274.774
275.770
276.741
277.689
278.613
279.516
280.399
281.262
282.107
282.933
283.743
284.536
285.313
286.076
286.824
287.559
288.280
288.988
289.685
290.369
291.043
291.705
292.357
293.000
293.631
ОКСИД
р(О) -р^СРО)
S°(T)
187.319
209.897
222.632
222.828
232.029
239.335
245.460
250.755
255.422
259.596
263.369
266.812
269.976
272.904
275.627
278.172
280.561
282.812
284.939
286.956
288.874
290.702
292.447
294.118
295.720
297.259
298.740
300.166
301.543
302.873
304.160
305.406
306.614
307.787
308.926
310.034
311.112
312.163
313.187
314.187
315.164
316.118
317.051
317.965
318.860
319.737
320.597
321.442
322.271
323.086
323.887
324.675
325.450
326.214
326.967
327.709
328.440
329.162
329.875
330.579
331.274
ФОСФОРА
А
Я°(Г)-/Л<
кДж • моль
3.005
6.261
9.390
9.448
12.648
15.924
19.285
22.720
26.216
29.760
33.342
36.954
40.591
44.249
47.923
51.613
55.314
59.027
62.749
66.480
70.218
73.964
77.717
81.475
85.239
89.009
92.784
96.564
100.350
104.140
107.935
111.736
115.541
119.352
123.168
126.991
130*19
134 Г>54
138.495
142.344
146.200
150.065
153.939
157.822
161.714
165.617
169.532
173.458
177.396
181.348
185.313
189.292
193.287
197.297
201.323
205.367
209.427
213.506
217.603
221.720
225.855
РО (г)
г#°@) = 590.000 кДж-моль
)
1
-304.2058
-149.6629
-98.6864
-98.0452
-72.1879
-56.6472
-46.2711
-38.8497
-33.2769
-28.9377
-25.4629
-22.6171
-20.2434
-18.2332
-16.5087
-15.0129
-13.7031
-12.5465
-П.5176
10.5964
-9.7666
-9.0153
-8.3317
-7.7071
-7.1341
-6.6065
-6.1191
-5.6674
-5.2475
-4.8562
-4.4907
-4.1483
-3.8270
-3.5248
-3.2401
-2.9713
-2.7171
-2.4763
-2.2478
-2.0308
-1.8243
-1.6276
-1.4399
-1.2607
-Г.0894
-.9254
-.7682
-.6175
-.4728
-.3338
-.2001
-.0714
.0525
.1720
.2873
.3986
.5061
.6100
.7105
.8078
.9020
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
со
г*-
On
vo
II
+
г?
С*
СО
о
+
ё
ON
3
р
о
1
J3
со
со
г»
«/•>
со
•о
о
г*
о
со
II
Табл и
i
^ о
1 ^
§ *
2 PJ
k s
s ~
7 Я
и «о
® 2
(н* ON
Q •
^ о
< ч
2
Т
ON
ON
«О
+
С»
X
f-
ON
On
|
X
00
О
*—i
+
uai96
о
2
k
00
t—i
G)
to
||
о 5
«о
я
о
VO
V
V
§
о
••
II
267

Класс точности
IV-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛАЛЛ
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.758
30.787
32.334
33.598
34.544
35.260
35.832
36.322
36.765
37.181
37.579
37.962
38.328
38.676
39.005
39.313
39.600
39.864
40.106
40.326
40.526
40.706
40.867
41.011
41.138
41.251
Л 1 OK I
4I.o51
41.439
41.515
41.582
41.641
41.692
41.736
'41.775
41.808
41.838
41.864
41.888
41.909
41.928
41.946
41.963
41.979
41.995
42.010
42.025
42.039
42.054
42.069
42.083
42.098
42.112
42.126
42.140
42.153
42.165
42.176
42.186
42.195
ОТРИЦАТЕЛЬНЫЙ ИОН ОКСИДА ФОСФОРА РО" (г)
К°(Т)=р(?) -Р(О) -р(е) -р'1
Ф°(Т)
S°(T)
Дж • К~ * • моль" *
192.844 222.283
193.026 222.473
201.567 231.546
208.321 238.903
213.949 245.117
218.795 250.498
223.060 255.244
226.876 259.494
230.333 263.344
233.497 266.868
236.415 270.120
239.125 273.143
241.657 275.970
244.034 278.626
246.275 281.133
248.396 283.507
250.410 285.762
252.328 287.911
254.158 289.961
255.910 291.924
257.590 293.804
259.204 295.610
260.757 297.346
262.255 299.017
263.700 300.628
265.097 302.183
О?? Л Л И ifl'X АЯ*ч
ZOu.44o OUO.ОоЭ
267.757 305.137
269.027 306.544
270.259 307.906
271.456 309.227
272.620 310.509
Й73.753 311.755
274.856 312.965
275.931 314.142
276.980 315.288
278.002 316.404
279.001 317.492
279.977 318.553
280.930 319.588
281.863 320.599
282.775 321.586
283.668 322.550
284.543 323.494
285.400 324.417
286.239 325.321
287.063 3?6.206
287.871 327.073
288.663 327.923
289.441 328.756
290.205 329.573
290.956 330.375
291.693 331.163
292.417 331.936
293.130 332.695
293.831 333.441
294.520 334.175
295.198 334.896
295.866 335.605
(PO") Arl/
/,V)-//O(())
кДж • моль
8.777
8.834
11.992
15.291
18.700
22.192
25.748
29.356
33.010
36.708
40.446
44.223
48.038
51.888
55.772
59.689
63.634
67.608
71.606
75.628
79.671
83.733
87.812
91.906
96.013
100.133
108.403
112.550
116.705
120.867
125.033
129.205
133,380
137.559
141.742
145.927
150.115
154.304
158.496
162.690
166.886
171.083
175.281
179.481
183.683
187.886
192.091
196.297
200.505
204.714
208.924
213.136
217.350
221.564
225.780
229.997
234.215
238.434
1 а и л и ц а 1У7
'(()) - 695.400 кДж-моль 1
igA'V)
-117.2366
-116.4742
-85.6887
-67.1360
-54.7162
-45.8097
-39.1042
-33.8693
-29.6662
-26.2150
-23.3290
-20.8786
-18.7713
-16.9390
-15.3305
-13.9067
-12.6372
-11.4977
-10.4691
-9.5356
-8.6845
-7.9050
-7.1883
-6.5270
-5.9148
-5.3461
A fit AA
-4.О100
-4.3220
-3.8590
-3.4246
-3.0160
-2.6310
-2.2675
-1.9237
-1.5979
-1.2887
-.9949
-.7152
-.4486
-.1941
.0491
.2818
.5046
.7183
.9234
1.1205
1.3101
1.4925
1.6683
1.8378
2.0014
2.1594
2.3120
2.4597
2.6026
2.7409
2.8750
3.0050
3.1312
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
л
о Д Т
^ * с
& *° 5
ЕЗ ?н 7
r-i * О ^
С- Tl" ^ 1
СО ?> ^Н V
г- о 1 .
• со и ъе,
vo го j>
Tf ,-н Q R
II ' 00
^11 Ю *Н
"^ /—s "^ ^
2 ^ °J*
^2
о ?«,
^ о
+
X 1
§ о
6 J
V ^
? * Я
S * §
г» <¦> о
ОХ О
О го w
S3 v
° 6 к
х 7 v
J5 с* о
1 i :¦
со ^^ il
+ | Т
оо X с*ч
i s "
гм го
II +
268

Класс точности
v-ь;
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000 .
г
33.494
36.198
39.523
39.587
42.988
45.991
48.414
50.293
51.735
52.846
53.711
54.391
54.934
55.372
55.731
56.027
56.275
56.484
56.663
56.819
56.956
57.078
57.190
57.294
57.393
57.489
57.584
57.679
57.776
57^876
57.979
58.087
58.199
58.316
58.438
58.565
58.697
58.834
58.976
59.122
59.271
59.424
59.580
59.739
59.899
60.061
60.224
60.388
60.552
60.715
60.877
61.038
61.197
61.354
61.509
61.661
61.810
61.956
62.098
62.236
62.370
К°(Т)=р(?) 1
Ф°(Т)
Дж • К • моль
181.357
204.593
218.391
218.609
228.963
237.340
244.463
250.706
256.288
261.350
265.987
270.270
274.251
277.973
281.467
284.761
287.877
290.833
293.646
296.328
298.891
301.346
303.702
305.965
308.144
310.244
312.272
314.231
316.126
317.962
319.742
321.470
323.148
324.779
326.367
327.913
329.419
330.889
332.322
333.722
335.090
336.427
337.736
339.016
340.269
341.498
342.702
343.882
345.040
346.176
347.292
348.388
349.465
350.524
351.564
352.588
353.595
354.586
355.561
356.522
357.468
ДИОКСИД
?2(О) -/Г1 (PCX,)
-1
214.645
238.583
253.650
253.895
265.754
275.679
284.288
291.898
298.712
304.872
310.487
315.639
320.396
324.811
328.928
332.784
336.408
339.826
343.060
346.127
349.045
351.827
354.485
357.030
359.470
361.815
364.072
366.247
368.346
370.375
372.339
374.242
376.088
377.881
379.624
381.319
382.971
384.581
386.152
387.686
389.184
390.650
392.084
393.488
394.863
396.211
397.532
398.829
400.102
401.353
402.581
403.788
404.975
406.142
407.290
408.420
409.533
410.628
411.707
412.769
413.817
ФОСФОРА
Д,
(/°(Л-//°<())
кДж • моль
3.329
6.798
10.513
10.586
14.716
19.170
23.895
28.834
33.939
39.170
44.500
49.906
55.374
60.890
66.446
72.034
77.649
83.288
88.945
94.619
100.308
106.010
111.724
117.448
123.182
128.927
134.680
140.443
1 J.fi 91 (\
151.999
157.791
i 63.595
169.409
175.235
181.072
186.922
192.785
198.662
204.552
210.457
216.377
222.312
228.262
234.228
240.210
246.208
252.222
258.253
264.300
270.363
276.442
282.538
288.650
294.777
300.921
307.079
313.253
319.441
325.644
331.860
338.091
РО2 (г)
/АО) -~ 1087.129 кДж- моль
\gK°(T)
-559.1914
-274.0995
-179.9749
-178.7906
-131.0236
-102.3080
-83.1336
-69.4193
-59.1216
-51.1043
-44.6847
-39.4280
-35.0442
-31.3323
-28.1486
-25.3877
-22.9705
-20.8364
-18.9385
-17.2394
-15.7094
-14.3244
-13.0646
-11.9138
-10.8583
-9.8867
-8.9893
-8.1579
-7.3855
-6.6658
-5.9937
-5.3646
-4.7744
-4.2196
-3.6970
-3.2039
-2.7378
-2.2966
-1.8782
-1.4810
-1.1033
-.7437
-.4009
-.0738
.2388
.5378
.8240
1.0984
1.3616
1.6143
1.8571
2.0907
2.3155
2.5320
2.7408
2.9421
3.1365
3.3243
3.5058
3.6813
3.8512
г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
Г-
On
II
+
ГО
ON
+
V
X
SO
го
О
О
1
Й
On
On
wo
00
«о
00
ГО
ON
чо
с-
го
II
Таб
i
R.
X
О
8
об
г-
7
и
i
о
т
1
т
го
го
«о
VO
об
1
к
1-4
О
?^
О
лица 198
г"
о о
W1 «-!
00 >
7 *
я 1
ON
2
о
2
§
S
V
V
I
•«.
i
о
II
269

Класс точности
V-I
ОТРИЦАТЕЛЬНЫЙ ИОН ДИОКСИДА ФОСФОРА РО; (г)
Таблица 199
"@) = 1397,129 кДж-моль
-1
Ф°(Л
Дж • К~ ! • моль""
кДж • моль"
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
40.516
40.590
44.363
47.453
49.793
51.527
52.814
53.783
54.523
55.098
55.552
55.916
56.212
56.456
56.661
56.836
56.989
57.126
57.253
57.375
57.496
57.618
57.745
57.880
58.023
58.177
58.341
58.520
58.710
58.912
59.126
59.351
59.586
59.831
60.083
60.343
60.608
60.877
61.150
61.424
61.698
61.971
62.243
62.511
62.775
63.034
63.286
63.532
63.770
64.000
64.221
64.433
64.636
64.828
65.011
65.183
65.345
65.496
65.638
213.621
213.841
224.324
232.846
240.114
246.494
252.201
257.375
262.112
266.484
270.546
274.339
277.897
281.249
284.418
287.422
290.278
293.000
295.600
298.089
300.476
302.769
304.976
307.102
309.154
311.136
313.051
314.908
316.709
318.457
320.155
321 806
323.416
324.981
326.507
327.995
329.448
330.867
332.254
333.612
334.939
336.240
337.514
338.763
339.988
341.189
342.369
343.527
344.665
345.783
346.883
347.964
349.028
350.074
351.105
352.120
353.119
354.104
355.074
249.219
249.470
261.676
271.921
280.790
288.603
295.572
301.851
307.557
312.782
317.596
322.058
326.213
330.100
333.750
337.190
340.443
343.528
346.462
349.258
351.930
354.488
356.943
359.303
361.576
363.769
365.884
367.934
369.921
371.850
373.723
376.546
377.325
379.056
380.745
382.395
384.008
385.585
387.130
388.644
390.127
391.582
393.010
394.412
395.788
397.141
398.471
399.778
401.064
402.329
403.574
404.800
406.006
407.194
408.364
409.516
410.651
411.769
412.871
10.614
10.689
14.941
19.538
24.406
29.476-
34.696
40.029
45.445
50.928
56.461
62.035
67.642
73.276
78.932
84.607
90.298
96.004
101.723
107.455
113.198
118.954
124.722
130.503
136.298
142.108
147.923
153.785
159.637
165.525
171.423
177.356
183.292
189.263
195.258
201.280
207.327
213.401
219.503
225.631
231.788
237.971
244.182
250.419
256.684
262.974
269.290
275.631
281.996
288.385
294.796
301.229
307.682
314.156
320.648
327.157
333.684
340.226
346.783
-234.0315
-232.5056
-170.9392
-133.8927
-109.1305
-91.4005
-78.0729
-67.6846
-59.3566
-52.5291
-46.8283
-41.9952
-37.8447
-34.2409
•31.0816
-28.2890
-25.8021
-23.5729
-21.5630
-19.7413
-18.0822
-16.5646
-15.1710
-13.8865
-12.6987
-11.5969
-10.5718
-9.6158
-8.7219
-7.8841
-7.0972
-6.3566
-5.6585
-4.9988
-4.3747
-3.7831
-3.2217
-2.6880
-2.1800
-1.6959
-1.2339
-.7926
-.3706
.0335
.4207
.7922
1.1489
1.4917
1.8214
2.1388
2.4446
2.7394
3.0238
3.2984
3.5637
3.8202
4.0683
4.3084
4.5410
298.15
300
400
500
600
700
800
900
1000
1100
1200
.1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
О)-
VO
II
О
о
о
00
00
?
о
00
ON
го Т
о
I
а I
S
о
о
о
V©
V
V
о
о
X
го г*-
00* <Ч
го
00
го
270

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
46.352
63.898
73.925
74.083
81.517
87.226
91.555
94.814
97.276
99.155
100.609
101.750
102.657
103.388
103.985
104.478
104.888
105.234
105.527
105.778
105.994
106.182
106.346
106.489
106.616
106.728
106.829
106.918
106.998
107.071
107.136
107.196
107.250
107.299
107.344
107.385
107.423
107.458
107.491
107.520
107.548
107.574
107.598
107.620
107.641
107.660
107.679
107.696
107.712
107.727
107.741
107.754
107.767
107.779
107.790
107.801
107.811
107.820
107.830
107.838
107.846
К°(Г) = р2(Р).
Ф°(Т)
_ i
Дж • К • моль
210.026
238.611
258.637
258.971
275.384
289.329
301.545
312.455
322.334
331.371
339.704
347.438
354.654
361.419
367.786
373.800
379.497
384.910
390.066
394.987
399.695
404.207
408.539
412.704
416.715
420.583
424.318
427.928
431.422
434.807
438.089
441.275
444,369
447.378
450.305
453.155
455.932
458.640
461.282
463.860
466.379
468.840
471.247
473.601
475.906
478.162
480.372
482.538
484.661
486.744
488.787
490.792
492.761
494.694
496.594
498.461
500.296
502.100
503.875
505.622
507.340
ТРИОКСИД ДИФОСФОРА
р3 (О) . р (Р2О3) Агн
S°(T)
-1
Я°(Г)-//°@)
кДж * моль
246.933 3.691
285.107 9.299
312.618 16.095
313.076 16.232
335.454 24.028
354.285 32.478
370.589 41.427
384.959 50.753
397.788 60.363
409.359 70.189
419.885 80.180
429.529 90.300
438.423 100.522
446.670 110.826
454.354 121.196
461.546 131.620
468.302 142.088
474.672 152.595
480.695 163.133
486.408 173.699
491.839 184.288
497.015 194.897
501.959 205.523
506.689 216.165
SH.224 226.821
515.579 237.488
519.767 248.166
523.800 258.853
527.690 269.549
531.446 280.253
535.077 290.963
538.591 301.680
541.995 312.402
545.296 323.130
548.500 333.862
551.612 344.598
554.638 355.339
557.581 366.083
560.448 376.830
563.240 387.581
565.963 398.334
568.619 409.090
571.211 419.849
573.743 430.610
576.218 441.373
578.637 452.138
581.003 462,905
583.319 473.673
585.587 484.444
587.808 495.216
589.984 505.989
592.118 516.764
594.211 527.540
596.264 538.318
598.278 549.096
600.256 559.875
602.199 570.656
604.107 581.438
605.982 592,220
607.826 603.004
609.638 613.788
Таблица 200
э@) - 2048.475 кДж • моль
lg*V)
Т
К
-1050.6486 100
-513.1950 200
-335.8368 298.15
-333.6059 300
-243.6602 400
-189.6266 500
-153.5720 600
-127.8016 700
-108.4644 800
-93.4191 900
-81.3797 1000
-71.5275 1100
-63.3164 1200
-56.3679 1300
-50.4119 1400
-45.2499 1500
-40.7333 1600
-36.7481 1700
-33.2059 1800
-30.0367 1900
-27.1846 2000
-24.6043 2100
-22.2587 2200
-20.1171 2300
-18.1540 2400
•16.3481 2500
-14.6810 2600
-13.1374 2700
-11.7040 2800
-10.3694 2900
-9.1236 3000
-7.9580 3100
-6.8651 3200
-5.8383 3300
-4.8716 3400
-3.9599 3500
-3.0986 3600
-2.2836 3700
-1.5113 3800
-.7782 3900
-.0815 4000
.5816 4100
1.2134 4200
1.8161 4300
2.3918 4400
2.9422 4500
3.4690 4600
3.9738 4700
4.4578 4800
4.9224 4900
5.3688 5000
5.7980 5100
6.2109 5200
6.6087 5300
6.9920 5400
7.3616 5500
7.7184 5600
8.0630 5700
8.3960 5800
8.7179 5900
9.0294 6000
i
'й. ?
2 к 7
* * §
!"•• О ^ 1
2 О S ^
ON Г- 1 *
8 ? Д *
"н ' 2 см
II " »л Os
_: os
* ?- 8 Я
о" и: -
аГ о" °, *
о gr
< <г
+
Os —
CN 1
О> А
^* К
^ 1
+
й ¦ 2
<Ч Л О
Я П О
О ъ
о Я V
1 °°. к,
1 + v
2 °* °
+ | Т
с- Н Ь.
ю г-
СО Os ||
5 3 н
п +
271

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
\ьоо
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
aOvV
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
47.293
70.164
85.130
85.^68
96.496
104.774
110.877
115.378
118.731
121.263
123.208
124.725
125.927
126.893
127.678
128.325
128.864
129.316
129.700
130.028
130.310
130.555
130.768
130.955
131.120
131.267
131.397
131.513
131.618
131.712
131.797
131.874
131.944
132.008
132.067
132.120
132.170
132.215
132.257
132.296
132.332
132.365
132.396
132.425
132.452
132.477
132.501
132.523
132.544
132.563
132.582
132.599
132.615
132.631
132.645
132.659
132.672
132.685
132.697
132.708
132.718
К°(Т)= р2(Р)
Ф°(Т)
Дж • К • моль
204.345
233.465
254.642
255.002
272.931
288.532
302.435
315.011
326.507
337.100
346.924
356.082
364.660
372.727
380.339
387.544
394.384
400.892
407.101
413.036
418.719
424.172
429.411
434.453
439.313
444.002
448.533
452.915
457.158
461.271
465.261
469.135
472.900
476.562
480.126
483.598
486.981
490.281
493.501
496.645
499.717
502.720
505.657
508.530
511.343
514.097
516.796
519.442
522.036
524.580
527.077
529.527
531.934
534.298
536.620
538.903
541.147
543.355
545.526
547.662
549.765
ТЕТРОКСИД
р4 (О) • р (Р20
241.411
281.777
312.751
313.279
339.439
361.907
381.578
399.025
414.661
428.798
44.1.680
453.497
464.403
474.522
483.955
492.787
501.087
508.913
516.316
523.3^7
530.014
536.378
542.456
548.273
553.850
559.206
564.357
569.318
574.103
578.723
583.190
587.513
591.701
595.762
599.704
603.532
607.255
610.877
614.404
617.840
621.189
624.457
627.648
630.763
633.808
636.785
639.697
642.547
645.337
648.070
650.74$
653.374
655.949
658.475
660.955
663.389
665.779
668.127
670.435
672.704
674.934
ДИФОСФОРА
4> V
//°<У')-//°(())
кДж • моль"
3.707
9.662
17.325
17.483
26.603
36.687
47.486
58.810
70.523
82.529
94.756
107.156
119.691
132.334
145.063
157.865
170.725
183.634
196.586
209.572
222.590
23&.633
248.700
261.786
274.890
288.009
301.143
314.288
327.445
340.611
353.787
366.970
380.161
393.359
406.563
419.772
432.987
446.206
459.430
472.657
485.889
499.124
512.361
525.603
538.847
552.093
565.342
578.593
591.847
605.102
618.359
631.618
644.879
658.141
671.405
684.670
697.937
711.205
724.474
737.744
751.015
Р2О4 (г)
°@) = 2541.258 кДж-моль
lgtfV)
-1301.8093
-634.8701
-414.7318
-411.9626
-300.3085
-233.2325
-188.4758
-156.4875
•132.4864
-113.8138
-98.8733
-86.6482
-76.4605
-67.8404
-60.4522
-54.0498
•48.4484
-43.5067
-39.1148
-35.1859
-31.6505
-28.4524
-25.5455
-22.8919
-20.4598
-18.2226
-16.1579
-14.2463
-12" 4714
-10.8191
-9.2771
-7.8346
-6.4822
-5.2118
-4.0161
-2.8887
-1.8238
-.8163
.1383
1.0442
1.9049
2.7239
3.5040
4.2481
4.9586
5.6378
6.2877
6.9102
7.5070
8.0798
8.6299
9.1586
9.6673
10.1571
10.6290
11.0839
11.5229
11.9468
12.3562
12.7521
13.1350
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
AOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
сч
ю
т|-
О)
»о
СЧ
"Н
II
+
со
•о
00
со
+
'*
г»
1О
Os
«о
о
со
о
1
С?
со
о
Ч*)
сч
+
3
т—1
СТч
II
г
Таблица 201
1
л
1
О
о
о
СО
СЧ
1
II
О
С
о*
О
т
л
Т
*
О
СЧ
+
сч
я
00
сч
1
сч
00
о
сч
сч
со
+
т
е
*
Os
«о
со
со
О">
1
II
«о
00
Os
сч
и
о.
ъ
о
•>,
1
g
^*
т
v>
ни
сч
II
о cs
со
2
о
о
о
V
h,
W
V
о
о
•о
«я-
1
о
II
272

Класс точности
VII-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
АЛЛА
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
61.625
88.622
105.935
106.197
118.179
126.955
133.470
138.328
141.982
144.766
146.917
148.603
149.945
151.026
151.908
152.636
153.243
153.754
154.187
154.558
154.878
155.156
155.398
155.610
1155.798
155.964
156.112
156.244
1 *>fi "Ч6Я
15&470
156.567
156.655
156.734
156.807
156.874
156.935
156.991
157.043
157.091
157.135
157.176
157.214
157.250
157.283
157.313
157.342
157.369
157.394
157.418
157.440
157.461
157.481
157.500
157.517
157.534
157.550
157.565
157.579
157.592
157.605
157.617
*-(Г) = р'(Р>-
Ф°(Л
Дж • К • моль"
227.556
265.396
292.504
292.962
315.657
335.211
352.493
368.023
382.145
395.104
407.082
418.220
428.628
438.397
447.600
456.301
464.550
472.393
479.867
487.005
493.837
500.386
506.676
512.727
518.555
524.176
529.606
534.855
UO9* vt/U
544.860
549.635
554.270
558.774
563.153
567.414
571.564
575.607
579.550
583.398
587.153
590.822
594.408
597.914
601.344
604.702
607.990
611.210
614.367
617.462
620.497
623.475
626.399
629.269
632.088
634.857
637.579
640.255
642.887
645.475
648.021
650.528
ПЕНТОКСИД
р5 @) . р'1 (Р20
S°(T)
276.121
327.595
366.458
367.115
399.401
426.763
450.515
471.473
490.194
507.085
522.453
536.538
549.528
561.574
572.800
583.306
593.177
602.483
611.284
619.631
627.567
635.130
642.353
649.266
655.893
662.256
668.376
674.270
679 955
685.444
690.750
695.885
700.860
705.684
710.366
714.914
719.336
723.639
727.827
731.908
735.887
739.769
743.558
747.258
750.874
754.410
757.869
761.253
764.567
767.813
770.994
774.112
777.171
780.171
783.115
786.006
788.845
791.634
794.375
797.069
799.718
ДИФОСФОРА Р2О5 (г)
5> V
//°(П-//°(())
кДж моль
4.857
12.440
22.050
22.246
33.497
45.776
58.813
72.415
86.439
100.782
115.371
130.150
145.080
160.131
175.279
190.507
205.802
221.152
236.550
251.988
267.460
282.962
298.490
314.040
329.611
345.199
360.803
376.421
АЛЛ ЛСО
407.693
423.345
439.007
454.676
470.353
486.037
501.728
517.424
533.126
548.832
564.544
580.260
595.979
611.702
627.429-
643.159
658.892
674.627
690.365
706.106
721.849
737.594
753.341
769.090
784:841
800.593
816.348
832.103
847.861
863.619
879.379
895.140
э@) - 2979.041
\gK°(T)
-1525.7507
-744.1171
-486.1776
-482.9333
-352.1349
-273.5725
-221.1600
-183.7048
-155.6055
-133.7470
i! 6.2592
-101.9514
-90.0292
-79.9425
-71.2982
-63.8080
-57.2555
-51.4753
-46.3387
-41.7440
-37.6099
-33.8706
-30.4722
-27.3701
-24.5273
-21.9126
-19.4997
-17.2660
-15 1923
-1з!гб21
-11.4608
-9.7761
-8.1968
-6.7134
-5.3175
-4.0013
-2.7584
-1,5826
-.4688
.5881
1.5921
2.5472
3.4570
4.3246
5.1529
5.9445
6.7019
7.4272
8.1225
8.7896
9.4302
10.0459
10.6381
11.2082
11.7574
12.2868
12.7975
13.2905
13.7667
14.2269
14.6721
кДж- моль
У
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<N
»П
OS
'х
ЧО
<ч
<ч
г»
OS
СО
о
о
й
S
|>
»о
OS
00
оо
S
11
Табли
Т
л
§
о S
о ^
^н II
II ю
О об
* OS
U Г4
о &
•^ о
т
со
со
с»
<N
со
со
1
X
оо
00
<ч
оо
4-
ца202
1
g
к
СО
fN
II
"» о о?
< со
я
о
о
о
V
{^
V
о
о
1
о
и
X
1В 872
273

Класс точности
VII-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
AQAA
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<г)
53.845
100.913
135.329
135.865
159.670
175.591
186.388
193.896
199.262
203.198
206.156
208.427
210.203
211.616
212.757
213.691
214.464
215.112
215.658
216.124
216.524
216.870
217.171
217.435
217.667
217.873
218.055
218.219
91 А ^fi*
л, 10.OOU
218.497
218.616
218.723
218.821
218.911
218.992
219.067
219.136
219.199
219.258
219.312
219.362
219.408
219.451
219.492
219.529
219.564
219.597
219.628
219.657
219.684
219.709
219.734
219.756
219.778
219.798
219.817
219.835
219.852
219.869
219.884
219.899
К°(Т)= р3(Р)
Ф°(Л
Дж К • моль
222.835
255.136
282.182
282.667
307.752
330.796
352.022
371.630
389.804
406.711
422.498
437.291
451.199
464.315
476.722
488.488
499.675
510.334
520.513
530.250
539.583
548.543
557.158
565.453
573.451
581.172
588.634
595.855
а09 Я48
UU4.O4O
609.628
616.207
622.597
628.808
634.849
640.731
646.460
652.045
657.493
662.810
668.002
673.075
678.035
682.885
687.632
692.279
696.830
701.289
705.661
709.947
714.152
718.279
722.329
726.307
730.215
734.054
737.828
741.539
745.188
748.778
752.310
755.787
ГЕКСОКСИД ТРИФОСФОРА Р.ОА (г)
.рб(О) V(p:
S°(T)
-1
261.007
313.323
360.430
361.269
403.844
441.301
474.331
503.661
529.921
553.630
575.199
594.959
613.173
630.057
645.782
660.494
674.311
687.332
699.644
711.317
722.413
732.985
743.081
752.741
762.000
770.890
779.439
787.671
795.610
803.275
810.684
817.855
824 800
831.535
838.072
844.421
850.593
856.598
862,444
868.140
873.694
879.111
884.399
889.563
894.609
899.543
904.369
909.092
913.716
918.246
922.684
927.036
931.303
935.489
939.597
943.630
947.591
951.482
955.306
959.065
962.761
А> V
//°(У).-//°@)
кДж • моль
3.817
11.637
23.330
23.581
38.437
55.253
73.3.85
92.421
112.094
132.226
152.701
173.435
194.370
215.463
236.684
258.008
279.417
300.897
322.436
344.026
365.658
387.328
409.031
430.762
452.517
474.294
496.091
517.904
К*}О 71A
561.577
583.433
605.300
627.177
649.064
670.959
692.862
714.772
736.689
758.612
780.540
802.474
824.412
846.356
868.303
890.254
912.209
934.167
956.128
978.092
1000.059
1022.029
1044.001
1065.976
1087.952
1109.931
1131.912
1153.894
1175.879
1197.865
1219.853
1241.842
Таблица 203
"@) = 3984.387 кДж • моль 
Г
К
-2038.4464 100
-992.3915 200
-647.1069 298.15
-642.7638 300
-467.6797 400
-362.5414 500
-292.4226 600
-242.3334 700
-204.7714 800
-175.5642 900
-152.2072 1000
-133.1056 1100
-117.1958 1200
-103.7411 1'300
-92.2155 1400
-82.2329 1500
-73.5038 1600
-65.8068 1700
-58.9697 1800
-52.8565 1900
-47.3585 2000
-42.3876 2100
-37.8717 2200
-33.7514 2300
-29.9771 2400
-26.5070 2500
-23.3060 2600
-20.3441 2700
1 7 ^Q^1* 9ЙПП
- 1 / .ОУОО ZO\)\J
-15.0380 2900
-12.6524 3000
-10.4219 3100
-8.3320 3200
-6.3698 3300
-4.5239 3400
-2.7843 3500
-1.1420 3600
.4109 3700
1.8815 3800
3.2762 3900
4.6007 4000
5.8603 4100
7.0596 4200
8.2028 4300
9.2939 4400
10.3362 4500
11.3332 4600
12.2875 4700
13.2020 4800
14.0791 4900
14.9211 5000
15.7300 5100
16.5078 5200
17.2563 5300
17.9770 5400
18.6715 5500~
19.3413 5600
19.9876 5700
20.6117 5800
21.2146 5900
21.7976 6000
i
л
^ el 7
оо *° " J>
оо 7* ^ С*
*-' bd ^н
и " СМ
i - 2 Я
"^ °„ °° 2
см „
2" > °«
w О СО
го
о Ом
^ о^
+
S 7Л
"^" С»
S к 2
s Ъ °
6 2 V
со Ьч
S + v
i "& 1
12 см
*^ о >
^t °о
чо о и
00
II +
274

Класс точности
VII-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
54.469
108.781
148.608
149.215
175.399
191.902
202.544
209.664
214.605
218.152
220.772
222.758
224.296
225.510
226.484
227.277
227.930
228.475
228.934
229.324
229.658
229.946
230.197
230.416
230.609
230.779
230.930
231.065
231.186
231.295
231.393
231.482
231.563
231.637
231.704
231.766
231.822
231.874
231.922
231.967
232.008
232.046
232.082
232.115
232.146
232.174
232.201
232.227
232.250
232.273
232.294
232.313
232.332
232.350
232.366
232.382
232.397
232.411
232.424
232.437
232.449
ГЕКСОКСИД
К°(Т) = р4 (Р)
Ф°(Т)
Дж • К • моль
212.006
244.747
273.144
273.660
300.527
325.425
348.433
369.699
389.400
407.708
424.782
440.762
455.767
469.903
483.260
495.915
507.936
519.381
530.302
540.743
550.743
560.338
569.559
578.432
586.984
595.236
603.209
610.920
fil ft 4ftfi
О 1 O.OOU
625.622
632.642
639.457
646.080
652.520
658.789
664.893
670.843
676.645
682.307
687.835
693.235
698.514
703.675
708.725
713.669
718.509
723.252
727.900
732.457
736.928
741.314
745.619
749.846
753.998
758.078
762.087
766.028
769.905
773.717
777.469
781.161
р6 @) • р <Р4
S°(T)
250.028
304.949
356.313
357.235
404.036
445.087
481.084
512.875
541.214
566.706
589.833
610.973
630.424
648.427
665.176
680.829
695.519
709.354
722.427
734.815
746.587
757.799
768.502
778.740
788.550
797.968
807.022
815.740
824.145
832.260
840.103
847.692
855.042
862.169
869.085
875.803
882.332
888.685
894.869
900.894
906.768
912.497
918.089
923.550
928.887
934.104
939.207
944.202
949.091
953.880
958.573
963.173
967.684
972.110
976.453
980.717
984.904
989.018
993.060
997.033
1000.940
ТЕТРАФОСФОРА Р4Об (г)
°б> V
//°G)~//°@)
кДж • моль
3.802
12.040
24.797
25.072
41.404
59.831
79.591
100.224
121.451
143.098
165.051
187.232
209.588
•232.080
254.682
277.371
300.132
322.954
345.825
368.738
391.687
414.668
437.676
460.706
483.758
506.827
529.913
553.013
C7fi I Ofi
О/О. I?ЛУ
599.250
622.384
645.528
668.681
691.841
715.008
738.181
761.361
784.546
807.736
830.930
854.129
877.332
900.538
923.748
946.961
970.177
993.396
1016.617
1039.841
1063.067
1086.295
1109.526
1132.758
1155.992
1179.228
1202.465
1225.704
1248.945
1272.186
1295.430
1318.674
Таблица 204
э@) - 4326.261 кДж • моль
Г
К
-2210.2085 100
-1074.1363 200
-699.0958 298.15
-694.3784 300
-504.1938 400
-389.9814 500
-313.8051 600
-259.3835 700
-218.5674 800
-186.8253 900
-161.4371 1000
-140.6706 1100
-123.3708 1200
-108.7378 1300
-96.2001 1400
-85.3386 1500
-75.8390 1600
-67.4606 1700
-60.0166 1800
-53.3592 1900
-47.3703 2000
-41.9543 2100
-37.0329 2200
-32.5414 2300
-28.4259 2400
-24.6413 2500
-21.1492 2600
-17.9171 2700
-14 Q168 9Я00
-12.1244 2900
-9.5189 3000
-7.0822 3100
-4.7983 3200
-2.6533 3300
-.6348 3400
1.2681 3500
3.0651 3600
4.7648 3700
6.3750 3800
7.9026 3900
9.3539 4000
10.7345 4100
12.0494 4200
13.3034 4300
14.5005 4400
15.6447 4500
16.7393 4600
17.7877 4700
18.7926 4800
19.7568 490Q
20.6828 5000
21.5727 5100
22.4287 5200
23.2527 5300
24.0466 5400
24.8118 5500
25.5501 5600
26.2628 5700
26.9512 5800
27.6167 5900
28.2602 6000
i
»н О
л
1 л ~
* о ?
^ OS.
¦* - § _."
2 Я ^ v
s s '
2 2 Д ?
7 * *
II II to ОО
*-, /-S —¦ °)
< О оо го
- on <N
сч „
О . я
«3- \О О о?
Ь ¦ О со
0 СЬ*
¦ ^ з-
+
т
ГО 1
о л
Г- Г!
го О
+ '
d |
1 х S^
? G
гч * О
1Л К °
ос ^ о
^ со чо
О И ч /
о 22 V
1 р к
х °° w
с + V
§ ё i
- 2 т
Я 2 2
+ i
^- ~* II
• О ><
Г- • w
Г» -4
ОО <^
!1 +
ь
275

Класс точности
VII-F
Т
К
. 100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
47Q0
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
57.798
116.497
159.240
159.899
188.774
207.586
220.073
228.617
234.651
239.038
242.313
244.814
246.764
248.309
249.554
250.571
251.412
252.114
252.706
253.211
253.644
254.018
254.343
254.628
254.879
255.100
255.297
255.473
255.631
255.773
255.901
256.017
256.123
256.219
256.307
-256.387
256.461
256.529
256.592
256.650
256.704
256.754
256.800
256.844
256.884
256.922
256.957
256.990
257.021
257.051
257.078
257.104
257.128
257.151
257.173
257.194
257.213
257.232
257.249
257.266
257.282
ГЕПТОКСИД
Л-G)=И(Р).
Ф°(П
Дж • К • моль
227.051
261.196
291.300
291.848
320.478
347.103
371.784
394.663
415.912
435.703
454.195
471.531
487.834
503.212
517.759
531.556
544.672
557.170
569.104
580.521
591.463
601.967
612.066
621.790
631.165
640.215
648.961
657.423
665.618
673.564
681.273
688.761
696.039
703.118
•710.009
716.721
723.265
729.647
735.876
741.958
747.901
753.711
759.393
764.953
770.396
775.727
780.950
786.069
791.090
796.015
800.847
805.591
810.250
814.826
819.322
823.7 М
828.087
832.360
836.564
840.700
844.771
р7(О).р(Р4
S°iT)
-1
266.011
324.741
379.743
380.730
430.981
475.273
514.299
548.905
579.848
607.753
633.116
656.333
677.722
697.536
715.985
733.239
749.438
764.701
779.129
792.806
805.805
818.190
830.014
841.327
852.169
862.578
872.588
882.226
891.520
900.493
909.166
917.559
925.689
933.572
941.222
948.653
955.876
962.904
969.746
976.412
982.911
989.250
995.438
1001.481
1007.386
1013.159
1018.807
1024.333
1029.744
1635.044
1040.237
1045.328
1050.321
1055.219
1060.026
1064.745
1069.380
1073.932
1078.406
1082.804
1087.128
ТЕТРАФОСФОРА Р4О7 (г)
о7) v,
//Yn-//°«o
кДж • моль
3.896
12.709
26.369
26.665
44.201
64.085
85.509
107.969
131.150
154.845
178.920
203.282
227.865
252.621
277.516
302.525
327.625
352.802
378.044
403.340
428.684
454.067
479.486
504.935
530.410
555.909
581.430
606.968
632.524
658.094
683.678
709.274
734.881
760.498
786.124
811.759
837.402
863.051
888.707
914.370 .
940.037
965.710
991.388
1017.070
1042.757
1068.447
1094.141
1119.839
1145.539
1171.243
1196.949
1222.658
1248.370
1274.084
1299.800
1325.519
1351.239
1376.961
1402.685
1428.411
1454.139
\0) - 4948.733
-2530.1933
-1230.8102
-801.8686
-796.4731
-578.9478
-448.3094
-361.1725
-298.9171
-252.2238
-215.9099
-186.8640
-163.1053
-143.3124
126.5703
112.2255
-99.7983
-88.9292
-79.3431
-70.8259
-63.2088
-56.3566
-50.1598
-44.5290
-39.3902
-34.6817
-30.3517
-26.3565
-22.6587
-19.2264
-16.0319
-13.0514
-10.2640
-7.6516
-5.1981
-2.8895-
-.7132
1.3418
3.2855
5.1267
6.8734
8.5327
10.1110
11.6141
13.0474
14.4157
15.7233
16.9742
18.1720
19.3202
20.4217
21.4794
22.4958
23.4734
24.4144
25.3208
26.1945
27.0372
27.8507
28.6364
29.3958
30.1301
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
О
ON
«О
го
И
+
го
00
««а-
00
+
as
т-\
00
•о
о
1
1
§
о
ON
об
ГО
On
с*
7 а б л и
7
i
| *
X
X 00
« ч
s s
§ 2
& '
as "
i О4
II 1Л
ii (/-)
о 5
^ и
II -Л ^П*»
Ц d Z\JJ
1
с:
i
*
as
го
*-?
<N
и
r-f
*t V- о о?
?j О
о оГ
wo
г
< <г
Т
л
1
Т
го
X
о
г-
^
4"
X
00
ON
1
х
1-4
С;
«¦о
2
о
о
V
V
о
о
«о
о
II
276

Класс точности
VII—1
т
к
100
200
298.15
300
400
500
600
700
800
900
moor
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
•
61.126
124.213
169.873
170.583
202.148
223.271
237.602
247..571
254.696
259.925
263.854
266.870
269.230
271.108
272.624
273.865
274.893
275.752
276.479
277.098
277.629
278.089
278.489
278.840
279.148
279.422
279.664
279.881
280 076
280.251
280.409
280.552
280.682
280.801
280.910
281.009
281.100
281.184
281.262
281.334
281.400
281.462
281.520
28..573
281.623
281.670
281.713
281.754
281.793
281.829
281.863
281.895
281.925
281.953
281.980
282.006
282.030
282.053
282.074
282.095
282.115
А°(П=р4(РЬ
Ф°СП
Дж • К • моль
233.657
269.206
301.017
301.599
331.990
360.341
386.696
411.187
433.984
455.258
475.169
493.861
511.462
528.082
543.819
558.756
572.969
586.520
599.468
611.861
623.744
635.157
646.135
656.708
666.906
676.753
686.273
695.486
704.411
713.066
721.466
729.626
737.558
745.276
752.789
760.110
767.247
774.209
781.005
787.642
794.128
800.469
806.671
812.741
818.684
824.504
830.208
835.800
841.283
846.663
851.942
857.125
862.214
867.214
872.128
876.957
881.706
886.376
890.971
895.492
899.943
октоксид
р8 (О) • р~1 (Р4
-1
273.554
336.093
394.734
395.787
449.487
497.020
539.075
576.495
610.044
640.360
667.959
693.254
716.580
738.207
758.356
777.209
794.917
811.609
827.392
842.357
856.584
870.142
883.088
895.475
907.349
918.750
929.714
940.273
950 455
960.286
969.790
978.987
987.896
996.535
1004.919
1013.064
1020.981
1028.684
1036.184
1043.491
1050.614
1057.564
1064.347
1070.972
1077.446
1083.775
1089.966
1096.026
1101.958
1107.768
1113.463
1119.045
1124.519
1129.889
1135.160
1140.334
1145.416
1150.407
1155.313
1160.135
1164.877
ГЕТРАФОСФОРА Р4О8 (г)
о8) V'
//°< Л-//°@)
кДж • моль
3.990
13.377
27.942
28.257
46.999
68.339
91.428
115.715
140.848
166.592
192.790
219.332
246.142
273.162
300.352
327.678
355.117
382.651
410.264
437.943
465.680
493.467
521.296
549.163
577.063
604.991
632.946
660.924
688.922
716.938
744.971
773.020
801.081
829.155
857.241
885.337
913.443
941.557
969.679
997.809
1025.946
1054.089
1082.238
1110.393
1138.553
1166.717
1194.887
1223.060
1251.237
1279.419
1307.603
1335.791
1363.982
1392.176
1420.373
1448.572
1476.774
1504.978
1533.184
1561.393
1589.603
'«)) ^ 5510.516
-2818.0352
-1371.1928
-893.5683
-887.5602
-645.3363
-499.8568
-402.8158
-333.4816
-281.4770
-241.0315
-208.6802
-182.2173
-160.1714
-141.5236
-125.5457
-111.7039
-99.5974
-88.9200
-79.4333
-70.9491
-63.3170
-56.4150
-50.1434
-44.4199
-39.1757
-343532
-29.9037
-25.7855
-21.9630
-18.4055
-15.0864
i 1.9824
-9.0734
-6.3415
-3.7710
-1.3480
.9400
3.1039
5.1535
7.0978
8.9448
10.7015
12.3744
13.9695
15.4922
16.9472
18.3390
19.6717
20.9490
22.1743
23.3508
24.4813
25.5685
26.6149
27.6228
28.5943
29.5313
30.4356
31.3090
32.1530
32.9691
I
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<N
ОС
»o
<N
II
*§¦
OS
nO
о
O4
+
CO
о
о
1
1
r-
co
г*-
о
r^
CN
«o
о
о
О
'""'
It
Г а б
1
2
о
о
rf
CN
CN
1-
II
О
u"
00
о
ь
о
<г
1
1
т
го
н
+
"->
о
|
ОО
fN
С»
+
Л И
Т
<N
<N
ci
со
1
II
2
т-Ч
со
OS
и
ц а 206
л
1
Tf
CN
*oo о я
о
ь
0
со
я
о
о
о
чО
V
\/
V
о
о
<»
1
с
к.
н
277

Класс точности
VII-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
.200'
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
(>()()()
c°tm
1
64.454
131.929
180.505
181.268
215.523
238.955
255.130
266.524
274.742
280.811
285.395
288.926
291.697
293.907
295.695
297.160
298.374
299.391
300.251
300.985
301.615
302.161
302.636
303.052
303.418
303.743
304.031
304.289
304.520
304.729
304.917
305.087
305.242
305.383
305.512
305.631
305.739
305.840
305.932
306.017
306.097
306.170
306.238
306.302
306.362
306.417
306.469
306.518
306.564
306.607
306.647
306.685
306.721
306.755
306.787
306.818
306.846
306.874
306.900
306.924
306.947
НОНОКСИД ТЕТРАФОСФОРА
К°(Т)=р4(?) •
Ф°(Т)
Дж К • моль
232.778
269.731
303.250
303.864
336.018
366.095
394.123
420.228
444.572
467.329
488.658
508.707
527.605
545.468
562.394
578.473
593.781
608.385
622.346
635.716
648.541
660.863
672.719
684.142
695.163
705.807
716.101
726.065
735.720
745.084
754.174
763.006
771.593
779.949
788.086
796.014
803.745
811.287
818.650
825.842
832.870
839.742
846.465
853.045
859.487
865.798
871.982
878.046
883.992
889.826
895.552
901.173
906.694
912.118
917.448
922.688
927.840
932.908
937.893
942.800
947.629
р9 (О) • р'1 (Р4
S°(D
-1
273.613
339.962
402.240
403.359
460.508
511.282
556.367
596.600
632.755
665.483
695.317
722.691
747.954
771.393
793.242
813.694
832.912
851.032
868.170
884.424
899.879
914.609
928.676
942.138
955.044
967.437
979.356
990.835
1001.905
1012.595
1022.929
1032.930
1042.619
1052.014
1061.132
1069.990
1078.601
1086.980
1095.137
103.085
1110.834
118.393
125.772
132.978
140.021
1146.906
1153.642
160.233
166.687
173.008
179.203
1185.276
1191.232
1197.074
1202.808
1208.438
1213.967
1219.398
1224.736
1229.982
1235.140
су лгн°(
//Л'/')-//"(())
кДж • моль
4.083
14.046
29.514
29.849
49.796
72.593
97.346
123.461
150.546
178.338
206.659
235.382
264.419
293.703
323.186
352.831
382.610
412.500
442.483
472.546
502.676
532.866
563.106
593.391
623.715
654.073
684.463
714.879
745.320
775.782
806.265
836.765
867.281
897.813
928.358
958.915
989.484
1020.063
1050.651
1081.249
1111.855
1142.468
1173.088
1203.716
1234.349
1264.988
1295.632
1326.282
1356.936
1387.594
1418.257
1448.924
1479.594
1510.268
1540.945
1571.625
1602.309
1632.995
1663.684
1694.375
1725.068
P4OS (г)
0) - 6063.299
igA'V)
-3102.3539
-1509.6176
-983.8256
-977.2115
-710.5502
-550.3864
-443.5458
-367.2074
-309.9474
-265.4138
-229.7920
-200.6534
-176.3784
-155.8448
-138.2512
-123.0095
-109.6787
-97.9216
-87.4756
-78.1335
-69.7297
-62.1299
-55.2244
-48.9223
-43.1482
-37.8385
-32.9394
-28.4052
-24.1967
-20.2801
-16.6259
-13.2088
-10.0064
-6.9990
-4.1694
-1.5022
1.0161
3.3978
5.6538
7.7936
9.8262
11.7593
13.6003
15.3555
17.0308
18.6316
20.1628
21.6289
23.0340
24*.3818
25.6758
26.9192
28.1149
29.2656
30.3739
31.4420
32.4722
33.4664
34.4265
35.3543
36.2513
кДж • моль 1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ЧО
00
оо
г-
'•О
CN
Ж!»
+
«о
»о
О
+
со
со
•/">
»о
г-
.07
о
1
чо
с^
р
+
00
ЧО
г-
•/">
о
и
I а б л и и
л
с;
о *
г. Гч
о 2
8 S
со i
00
й II
CN ^
II Ю
О об
U ^
°« V
Ъ °
о о?
^ oW
J
т
§
п
го
«о
г4
сч
+
сч
Н
г-
чо
но
!
CN
00
00
О\
•л 207
1
i
Л
с;
О
о
to
CN
||
о 5"
со
2
о
§
•о
V
V
о
О
•О
т
1
о
и
278

Класс точности
vi-i:
т
к
100
200
298.15
300
400
500
600
699
699
700
800
900
1000
1100
78.031
155.350
215.569
216.437
259.901
296.593
326.513
349.463
370.000
370.000
370.000
370.000
370.000
370.000
ДЕКОКСИД ТЕТРАФОСФОРА
*•"•>= рад
Ф°ГЛ
— 1
Дж • К • моль
37.288
77.640
116.226
116.937
154.483
190.030
223.625
255.091
255.091
255.443
289.398
320.960
350.329
377.727
-1
// °( /)_ //°(())
кДж • моль
78.622 4.133
157.260 15.924
231.000 34.220
232.336 34.620
300.716 58.493
362.778 86.374
419.601 117.586
471.258 151.101
501.301 172.101
501.831 172.471
551.237 209.471
594.817 246.471
633.800 283.471
669.065 320.471
r4U10 ^К'Ж
°@) - 107.000 кДж • моль
lgX°G')
-46.1340
-18.2925
-9.2680
-9.1558
-4.6873
-2.0879
-.4279
.6806
.6806
.6889
1.2661
1,6600
1.9353
2.1304
Г
К
100
200
298.15
300
400
500
600
699
699
700
800
900
1000
1100
Таблица 208
-1
т
~ О
I 3
гЗ ° ё
о ^ <? Т
SS S , «
00 ON "
2 ^ 2 §
^ " «о ю
II /-ч ^ О
^, О со ^
"^ - ON ^•
Ь гй "
о оГ
""^ о
О
1 ^
X '
со ЪС
об
со Д
со ^ "
+ й 7
Т on х ^
'х 2 о? 5
2 т v ^2
VO л ^ 00 i-i
0 е: + ч /
+ § v ; v
н а к
S L 2 8 v
СО Ь^ ON О
^ . см о о
rj- vj O ON
Т «ч 2 + Т
«о со > °S __
WO CO L^ ^ T
О со ^" tl
°> со !1 • К
ON ^ ^11
II 1 И
279

Класс точности
VII-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400 '
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
67.792
139.701
191.191
192.006
228.938
254.670
272.682
285.495
294.801
301.709
306.945
310.990
314.171
316.712
318.770
320.458
321.859
323.033
324.027
324.875
325.603
326.234
326.784
327.266
327.690
328.066
328.400
328.699
328 966
329.208
329.425
329.623
329.802
329.966
330.116
330.253
330.379
330.495
330.602
330.702
330.794
330.879
330958
331.032
331.101
331.165
331.226
331.282
331.335
331.385
331.432
331.476
331.518
331.558
331.595
331.630
331.663
331.695
331.725
331.754
331.781
Ф°(Т)
ДЕКОКСИД
(Р) -pl0(O) -р
S°iD
Дж • К" 1 - моль" 1
224.079
262.441
297.677
298.324
332.251
364.062
393.770
421.492
447.390
471.632
494.383
515.790
535.988
555.094
573.212
590.434
606.839
622.497
637.473
651.819
665.587
678.818
691.553
703.827
715.671
727.114
738.181
748.897
759.282
769.356
779.137
788.641
797.884
806.878
815.638
824.175
832.499
840.621
848.552
856.298
863.870
871.273
878.516
&*85.606
892.548
899.350
906.015
912.550
918.959
925.248
981.421
937 481
943.433
949.281
955.029
960.679
966.235
971.699
977.076
982.367
987.576
265.852
336.034
401.973
403.159
463.770
517.793
565.912
608.963
647.724
682.865
714.937
744.390
771.591
796.842
820.391
842.443
863.171
882.720
901.213
918.756
935.439
951.340
966.530
981.067
995.004
1008.389
1021.263
1033.662
1045.621
1057.169
1068.334
1079.139
1089.607
1099.758
1109.611
1119.182
1128.487
1137.541
1146.356
1154.945
1163.319.
1171.488
1179.462
1187.251
1194.862
1202.303
1209.583
1216.707
1223.682
1230.514
1237.210
1243.773
1250.210
1256.526
1262.724
1268.808
1274.784
1280.655
1286.424
1292.095
1297.671
ТЕТРАФОСФОРА
<Р4°10> V
//Y/v/Л.»
кДж • моль
4*. 177
14.718
31.096
31.450
52.608
76.865
103.285
131.229
160.268
190.110
220.554
251.460
282.724
314.272
346.050
378.014
410.132
442.378
474.733
507.179
539.704
572.296
604.948
637.651
670.399
703.187
736.011
768.866
801.750
834.659
867.591
900.543
933.515
966.503
999.508
1032.526-
1065.558
1098.601
1131.657
1164.722
1197.796
1230.880
1263.972
1297.072
1330.179
1363.292
1396.412
1429.537
1462.668
1495.804
1528.945
1562.091
1595.240
1628.394
1661.552
1694.713
1727.878
1761.046
1794.216
1827.391
1860.567
'.O..W
'@) = 6600.082
-3376.0640
-1642.5336
-1070.2541
-1063.0549
-772.8069
-598.4690
-482.1691
-399.0694
-336.7368
-288.2568
-249.4781
-217.7568
-191.3299
-168.9760
-149.8228
-133.2300
-118.7175
-105.9181
-94.5462
-84.3761
-75.2276
-66.9543
-59.4369
-52.5766
-46.2909
-40.5110
-35.1781
-30.2425
-25.6615
-21.3983
-17.4209
-13.7016
-10.2160
-6.9429
-3.8633
-.9606
1.7801
4.3720
6.8269
9.1554
11.3670
13.4704
15.4734
17.3830
19.2057
20.9472
22.6129
24.2076
25.7359
27.2019
28.6092
29.9614
31.2617
32.5130
33.7181
34.8795
35.9996
37.0805
38.1242
39.1328
40.1078
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
S
ON
00
00
со
00
CN
II
1
1
^о
1-Н
"-•
¦ч
00
ON
00
©
1
СО
ЧО
СО
со
со
CN
О
II
ь
Т аб л и
i
л
Е
Т s
% «о
о g
У* ON
? II
1 *V
1 м5
II IO
r-s '—'
О 00
ON
* <N
О ьТ
1
ца 209
i
л
Т
•о
о
<N
II
о" о п
Ь о
со
ь
§
со
со
ON
CN
+
С*
00
I
СО
ON
ОО
00
r-
"*¦
—>
2
о
о
о
V
V
V
§
1
о
II
280

Класе точности
II—F
Т
К
100
200
-298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОйПП
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г;,л
29.192
29.155
29.175
29.176
29.328
29.709
30.297
31.001
31.733
32.442
33.104
33.709
34.261
34.768
35.236
35.674
36.088
36.482
36.861
37.228
37.583
37.930
38.267
38.598
38.920
39.235
39.543
39.843
40 1 Ч**
4t\J. 1 ОО
40.419
40.693
40.958
41.212
41.455
41.686
41.903
42.107
42.296
42.469
42.627
42.768
42.892
43.000
43.089
43.161
43.216
43.254
43.275
43.280
43.269
43.242
43.201
43.147
43.079
42.998
42.906
42.804
42.691
42.569
42.439
42.302
А'°т= р(Р) •,
Ф°(Л
— 1
Дж • К • моль
135.719
155.699
167.266
167.445
175.797
182.291
187.617
192.146
196.098
199.613
202.787
205.684
208.355
210.834
213.150
215.326
217.378
219.321
221.168
222.928
224.610
226.222
227.769
229.257
230.692
232.076
233.414
234.709
ZOO. У DO
237.183
238.367
239.518
240.639
241.730
242.794
243.833
244.847
245.838
246:807
247.754
248.682
249.591
250.481
251.353
252.209
253.049
253.872
254.681
255.476
256.256
257.022
257.776
258.517
259.246
259.962
260 667
261.361
262.044
262.716
263.378
264.030
ГИДРИД
р(н) p'Um)
S°(/ )
164.410
184.628
196.270
196.451
204.860
211.441
216.907
221.629
225.816
229.596
233.048
236.232
239.189
241.952
244.546
246.992
249.308
251.508
253.604
255.606
257.525
259.367
261.139
262.848
264.497
266.092
267.637
269.135
270.589
272.003
273.378
274.716
276.021
277.293
278.534
279.745
280.929
282.085
283.215
284.320
285.402
286.459
287.494
288.507
289.498
290.469
291.419
292.350
293.261
294.153
295.027
295.883
296.721
297.543
298.347
299.135
299.908
300.664
301.406
302.132
302.844
ФОСФОРА
кДж • моль
2.869
5.786
8.648
8.702
11.625
14.575
17.574
20.638
23.775
26.984
30.262'
33.603
37.002
40.454
43.954
47.500
51.088
54.717
58.384
62.088
65.829
69.605
73.415
77.258
81.134
85.042
88.981
92.950
96.949
100.977
105.033
109.115
113.224
117.357
121.514
125.694
129.895
134.115
138.353
142.608
146.878
151.161
155.456
159.760
164.073
168.392
172.716
177.042
181.370
185.697
190.023
194.345
198.663
202.974
207.278
211.574
215.859
220.134
224.397
228.648
232.885
РН (г)
11°@) - 300.000
)
1
lgA'°(n
-153.8296
-75.0171
-48.9614
-48.6332
-35.3863
-27.4059
-22.0648
-18.2356
-15.3538
-13.1053
-11.3011
-9.8209
-8.5843
-7.5355
-6.6346
-5.8522
-5.1663
-4.5600
-4.0202
-3.5365
-3.1005
-2.7055
-2.3459
-2.0172
-
-
1.7155
1.4376
-1.1808
-.9428
-.7215
-.5152
-.3225
-.1420
.0274
.1867
.3368
.4785
.6125
.7394
.8599
.9742
1.0831
.1867
.2856
.3800
.4703
.5567
.6395
.7190
.7952
.8685
.9390
2.0068
2.0722
2.1353
2.1961
2.2549
2.3117
2.3666
2.4198
2.4713
2.5212
кДж • моль
/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5?00
5300
5400
5500
5600
5700
5800
5900
6000
ЧО
ЧО
ОО
ON
го
II
-4-
00
00
о
+
ON
ГО
о
р
О
1
JS
ON
«О
ON
+
ON
О
VO
ON
*О
VO
II
о
ь
I а б л и
§
О *
8 3
»-~. ГО
ON <^
*О ||
го /**4
и «о
О °°
ON
X С
Ъ х
о Ь
<г ч
т
§
i
•-ч
го
Н
<N
го
1
г»
>i
tJ-
*о
чэ
го
1
X
VO
00
ца 210
I
1
д
On
го
к
о oi
2
о
о
о
ЧО
V
у
о
о
«о
1
о
II
><
281

Класс точности
IV-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;т
ДИГИДРИД ФОСФОРА
К°(Т) = Р(?) • р2 (Н) • р'1 (РН2) Аг//
Ф°(Т)
S°(T)
Дж • К • моль
33.258
33.447
34.449
34.475
36.103
37.998
40.007
41.999
43.870
45.561
47.053
48.352
49.473
50.438
51.268
51.984
52.603
53.141
53.609
54.019
54.380
54.699
54.982
55.235
55.463
55.670
55.858
56.031
56.192
56.341
56.482
56.616
56.743
56.866
56.985
57.101
57.214
57.326
57.436
57.545
57.653
57.761
57.867
57.974
58.080
58.185
58.291
58.395
58.499
58.603
58.706
58.808
58.909
59.009
59.108
59.206
59.302
59.397
59.491
59.583
59.673
II °('П -//°@)
кДж • моль
142.648 175.906 3.326
165.704 198.985 6.656
179.021 212.499 9.981
179.228 212.712 10.045
188.916 222.844 13.571
196.551 231.100 17.275
202.914 238.205 21.174
208.415 244.523 25.275
213.292 250.255 29^.570
217.696 255.522 34.043
221.725 260.401 38.676
225.450 264.948 43.448
228.921 269.204 48.340
232.175 273.203 53.337
235.241 276.972 58.423
238.143 280.534 63.587
240.899 283.910 68.817
243.524 287.115 74.105
246.032 290.166 79.443
248.432 293.076 84.824
250.734 295.856 90.245
252.946 298.517 95.699
255.076 301.068 101.183
257.129 303.518 106.694
259.112 305.874 112.230
261.028 308.142 117.786
262.882 310.329 123.363
264.679 312.441 128.957
266 421 314 481 134 569
268.112 316.456 140.195
269.756 318.368 145.837
271.354 320.223 151.492
272.910 322.022 157.160
274.424 323.770 162.840
275.901 325.469 168.533
277.341 327.123 174.237
278.746 328.733 179.953
280.119 330.302 185.680
281.459 331.832 191.418
282.770 333.326 197.167
284.052 334.784 202.927
285.307 336.209 208.698
286.536 337.602 214.479
287.739 338.965 220.271
288.919 340.299 226.074
290.075 341.606 231.887
291.209 342.885 237.711
292.322 344.140 243.545
293.414 345.371 249.390
294.487 346.578 255.245
295.541 347.763 261.110
296.576 348.927 266.986
297.594 350.069 ?72.872
298.595 351.192 278.768
299.579 352.296 284.674
300.548 353.382 290.589
301.500 354.450 296.515
302.439 355.500 302.450
303.362 356.534 308.394
304.272 357.552 314.348
305.169 358.554 320.311
РН2 (г)
D@) =624.231
-319.8354
-155.7519
-101.4780
-100.7943
-73.1916
-56.5605
-45.4303
-37.4522
-31.4495
-26.7673
-23.0117
-19.9316
-17.3593
-15.1784
-13.3057
-11.6799
-10.2550
-8.9959
-7.8750
-6.8708
-5.9658
-5.1460
-4.3998
-3.7176
-3.0915
-2.5148
-1.9819
-1.4878
-1.0284
-.6002
-.2000
.1748
.5267
.8577
1.1696
1.4642
1.7427
2.0066
2.2570
2.4949
2.7213
2.9369
3.1426
3.3391
3.5270
3.7068
3.8790
4.0442
4.2029
4.3553
4.5018
4.6429
4.7787
4.9097
5.0360
5.1580
5.2758
5.3897
5.4998
5.6064
5.7096
т n к п и и 't тп
1 а о л и ц a zl 1
кДж • моль 1
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
Л ' Т
о % л
? * i
v; CO
уо ЕЗ to V
ю х -; v
S © «-< .
Лч О "-< ^
On zZ, Stf
?с со El
Я д ю
II *""* »—Н
^ II «о со
л4 «у! ^
О 00 »"Н
г " S II
Си CN "
с* ?н а
Ъ х~ *
О ?н
^ о
<1 ^
+
Т ^
х Т
2 g
vO о
00
о ^,*
+ 1
& & 2
)° ?[ о
со о
VO СО ^
т-Ч X
| Я v
О
g + V
* Ъ §
о «
On Kri I
S ю о
vo X ^
ON* 5 "
об *~i X
On VO w
<N VO
II +
282

Класс точности
V-E
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
34.123
34.144
35.500
37.102
38.829
40.602
42.339
43.974
45.471
46.813
48.002
49.049
49.966
50.769
51.472
52.088
52.631
53.109
53.532
53.907
54.241
54.539
54.806
55.046
55.262
55.458
ее аък
ОО.\ЮО
55.796
55.942
56.076
56.199
56.312
56.415
56.510
56.598
56.680
56.755
56.826
56.891
56.951
57.008
57.061
57.1
1
57.157
57.200
57.241
57.280
57.316
57.350
57.382
57.413
57.442
57.469
57.495
57.519
57.542
57.564
57.585
57.605
ОТРИЦАТЕЛЬНЫЙ
к*т = рт-Р
Ф°(Т)
— 1
Дж • К • моль
171.764
171.971
181.625
189.209
195.509
200.936
205.734
210.054
214.001
217.641
221.031
224.207
227.199
230.030
232.719
235.281
237.728
240.072
242.321
244.484
246.566
248.575
250.515
252.392
254.208
255.969
257.677
259.337
260.949
262.518
264.045
265.533
266.984
268.399
269.780
271.130
272.448
273.737
274.998
276.233
277.442
278.625
279.786
280.924
282.039
283.134
284.208
285.263
286.300
287.318
288.318
289.302
290.269
291.221
292.157
293.078
293.985
294.878
295.757
>2(Н) р(е)
205.170
205.381
215.380
223.471
230.387
236.506
242.041
247.124
251.836
256.234
260.359
264.244
267.913
271.388
274.687
277.827
280.820
283.678
286.413
289.035
291.550
293.968
296.295
298.537
300.701
302.790
404 810
306.765
308.659
310.496
312.278
314.009
315.692
317.328
318.922
320.474
321.986
323.461
324.901
326.306
327.679
329.021
330.334
331.618
332.875
334.105
335.311
336.492
337.651
338.787
339.901
340.995
342.069
343.124
344.160
345.178
346.179
347.163
348.131
ИОН ДИГИДРИДА ФОСФОРА
V(PH-) Аг/Г
//V)-//°((»
кДж • моль
9.960
10.023
13.502
17.131
'20.927
24.898
29.046
33.363
37.836
42.452
47.194
52.047
57.000
62.037
67.150
72.328
77.565
82.852
88.185
93.557
98.965
104.404
109.872
115.364
120.880
126.416
131.971
137.543
143.130
148.731
154.344
159.970
165.606
171.253
176.908
182.572
188.244
193.923
199.609
205.301
211.000
216.703
222.411
228.125
233.843
239.565
245.291
251.020
256.754
262.490
268.230
273.973
279.718
285.467
291.217
296.970
302.726
308.483
314.243
рн; (г)
'(О) = 746.831 кДж • моль
-122.5734
-121.7505
-88.4971
-68.4192
-54.9531
-45.2791
-37.9837
-32.2798
-27.6938
-23.9238
-20.7677
-18.0853
-15.7763
-13.7670
-12.0017
-10.4380
-9.0427
-7.7896
-6.6576
-5.6297
-4.6919
-3.8326
-3.0421
-2.3123
-1.6362
-1.0081
-.4228
.1241
.6363
1.1171
1.5695
1.9960
2.3987
2.7799
3.1411
3.4840
3.8101
4.1205
4.4165
4.6991
4.9b92
5.2277 .
5.4754
5.7129
5.9409
6.1601
6.3708
6.5738
6.7693
6.9579
7.1399
7.3157
7.4856
7.6499
7.8089
7.9630
8.1122
8.2570
8.3974
г
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
,-н
О
On
CN
СО
II
+
1-Н
V©
00
«Я
о
X
О
«о
о
о
о
1
со
р
со
+
ON
*}
00
С4!
"
о
•е-
Табли
л
§
моль"
5 кДж
3 i
о "
00 Q
о *
II "">
° ?
i « ь
? X
о- ?
^ о
< ч
л
о
?
k
со
н
VO
ON
VO ¦
+
м
X
с-
со
VO
w
1
см
00
ON
ца 212
Т
А
•
1
д
Ю
1-Н
СО
""*
II
о 5
Я
S
V
v
S
«о
т
о
II
283

Класс точности
IV-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПОЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5i00
5200
5300
5400
5500
5600
5700
5800
5900
6000
33:259
33.726
35.810
35.861
38.769
41.549
43.968
46.019
47.740
49.178
50.376
51.377
52.216
52.921
53.516
54.023
54.456
54.828
55.150
55.429
55.674
55.890
56.080
56.250
56.403
56.541
56.667
56.78*4
56.891
56^992
57.088
57.180
57.268
57.354
57.438
57.521
57.603
57.685
57J67
57.850
57.933
58.016
58.100
58.185
58.271
58.357
58.444
58.531
58.619
58.707
58.795
58.883
58.97 k
59.06а
59.147
59.235
59.322
59.408
59.493
59.578
59.661
К°(Т) = Р(Я)Ч
Ф°(Т)
Дж • К • моль
165.385
188.446
201.816
202.024
211.852
219.702
226.325
232.105
237.264
241.940
246.228
250.194
253.890
257.351
260.609
263.688
266.607
269.383
272.030
274.559
276.982
279.306
281.540
283.691
285.764
287.766
289.700
291.572
295.144
296.851
298.509
300.121
301.689
303.217
304.705
306.157
307.573
308.956
310.306
311.627
312.918
314.181
315.418
316.629
317.816
318.980
320.121
321.240
322.339
323.418
324.477
325.518
326.541
327.547
328.536
329.509
330.467
331.409
332.337
333.251
ОКСИД-ГИДРИД ФОСФОРА НРО (г)
9(Р).р@)р-
S°(T)
198.643
221.767
235.573
235.795
246.506
255.461
263.256
270.192
276.453
282.161
287.407
292.256
296.764
300.972
304.916
308.626
312.127
315.440
318.583
321.572
324.422
327.144
329.748
332.245
334.642
336.947
339.167
341.308
345.373
347.307
349.181
360.997
352.761
354.475
356.141
357.762
359.342
360.881
362.383
363.848
365.280
366.679
368.047
369.386
370.696
371.980
373.237
374,471
375.680
376.867
378.032
379.177
380.301
381.406
382.492
383.560
384.611
385.644
386.662
387.664
l(HPO) Ar/I(
//°CO-//°@)
кДж • моль""!
3.326
6.664
10.065
10.131
13.861
17.880
22.159
26.661
31.352
36.200
41.179
46.268
51.449
56.707
62.030
67.407
72.832
78.296
83.796
89.325
94.880
100.459
106.057
111.674
117.307
122.954
128.615
134.288
1 OQ Q71
1 О«7.<7/ 1
145.666
151.370
157.083
162.805
168.536
174.276
180.024
185.780
191.545
197.317
203.098
208.887
214.685
220.491
226.305
232.128
237.959
243.799
249.648
255.505
261.371
267.246
273.130
279.023
284.924
290.835
296.754
302.682
308.618
314.563
320.517
326.479
э@) = 831.380 кДж- моль
lgK°(T)
-426.9973
-208.7515
-136.6317
-135.7237
-99.0865
-77.0396
-62.3042
-51.7554
-43.8281
-37.6517
-32.7028
-28.6478
-25.2643
-22.3979
-19.9383
-17.8044
-15.9353
-14.2847
-12.8161
-И.5009
-10.3163
-9.2436
-8.2676
-7.3758 •
-6.5576
-5 8043
-5.1083
-4.4633
-3.8639
-3.3054
-2.7836
-2.2950
-1.8365
-1.4053
-.9992
-.&156
-.2533
.0900
.4156
.7248
1.0189
1.2991
1.5662
1.8213
2.0650
2.2983
2.5217
2.7359
2.9415
3.1389
3.3288
3.5114
3.6873
3.8568
4.0203
4.1780
4.3304
4.4776
4.6199
4.7577
4.8910
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
470С
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
тН
00
О)
г^

Till
+
со
00
fN
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II
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со
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1
II
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ч
со
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со
<ч
со
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&
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со
о
. - "<t
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CN
с
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284

1
Класс точности
IV-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
сЛт)
29.128
29.856
31.619
31.653
33.286
34.458
35.267
35.836
36.251
36.566
36.819
37.035
37.229
37.415
37.599
37.785
37.976
38.172
38.373
38.578
38.785
38.994
39.203
39.410
39.615
39.317
40.015
40.209
40.398
40.581
40.760
40.933
41.101
41.264
41.422
41.575
41.724
41.869
42.010
42.147
42.281
42.411
42.538
42.662
42.782
42.900
43.013
43.124
43.231
43.334
43.433
43.529
43.620
43.707
43.789
43.866
43.938
44.С05
44.066
44.122
44.172
К°(Т) = р(?) .p(F)
Ф°G)
Дж • К • моль
162.923
183.271
195.073
195.257
203.929
210.809
216.550
221.494
225.843
229.730
233.247
236.460
239.418
242.160
244.716
247.110
249.363
251.490
253.506
255.422
257.248
258.992
260.662
262.264
263.805
265.288
266.718
268.100
269.436
270.729
271,983
273.200
274.382
275.531
276.650
277.739
278.801
279.837
280.848
281 836
282.801
283.745
284.669
285.573
286.456
287.326
288.177
289.012
289.831
290.635
291.424
292.200
292.962
293.711
294.447
295.172
295.885
296.587
297.278
297.958
298.628
ФТОРИД
• р'1 (PF)
192.330
212.655
224.894
225.090
234.430
241.992
248.350
253.832
258.645
262.934
266.800
270.320
273.551
276.538
279.317
281.918
284.362
286.671
288.858
290.938
292.922
294.820
296.639
298.386
300.067
301.689
303.254
304.768
306.234
307.655
309.033
310.373
311.675
312.942
314.176
315.379
316.553
317.698
318.816
319.909
320.978
322.024
323.047
324.050
325.032
325.995
326.939
327.865
328.774
329.666
330.543
331.404
332.250
333.082
333.900
334.704
335.495
336.273
337.039
337.793
338.535
ФОСФОРА
,/°(/')-//°@)
кДж • моль
2.941
5.877
8.891
8.950
12.201
15.591
19.080
22.637
20.242
29.884
33.553
37.246
40.960
44.692
48.443
52.212
56.001
59.807
63.634
67.482
71.350
75.239
79.149
83.079
87.031
91.002
94.994
99.005
103.036
107.085
111.152
115.236
119.338
123.456
127.591
131.740
135.905
140.085
144.279
148.487
152.708
156.943
1-61.191
165.451
169.723
174.007
178.303
182.610
186.927
191.256
195.594
199.942
204.300
208.666
213.041
217.424
221.814
226.211
230.614
235.024
239.439
PF(r)
//°@) = 440.000
igAfV)
-226.1634
-110.7954
-72.6972
-72.2177
-52.8757
-41.2440
-33.4746
-27.9158
-23.7405
-20.4887
-17.8839
-15.7503
-13.9703
-12.4626
-11.1690
-10.0468
-9.0640
-8.1961
-7.4239
-6.7325
-6.1098
-5.5460
-5.0330
-4.5643
-4.1344
-3.7386
-3.3730
-3.0343
-2.7195
-2.4262
-2.1523
.8958
.6552
1.4289
.2158
.0146
-.8245
-.6445
-.4737
-.3116
-.1573
-.0105
.1296
.2633
.3911
.5133
.6304
.7427
.8504
.9538
1.0533
.1490
.2411
.3299
.4156
.4982
.5780
.6551
.7296
.8018
.8716
кДж • моль *
'/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
CN
г-
ON .
On
II
+
Сч
ОО
со
со
о
+
?*
СО
V©
сч
р
о
1
ON
<ч
со
00
со
+
со
00
On
О)
1-Н
II
о
Таблица _Ч4
о
к
<N
VO
1
II
о
и
uT
Он
о
<
1
g
i
00
со
1
S
со
•о
+
ё
S
+
л
с:
о
* т
л
со
° ^
оо *
"Э- •
1 ?
II CJ
* с;
On "
с о g
СО
Си
О
о
§
V
V
о
о
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t>
к.
II
><
285

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.149
39.048
44.303
44.392
48.431
51.139
52.936
54.156
55.010
55.627
56.084
56.432
56.702
56.915
57.086
57.225
57.340
57.436
57.517
57.586
57.645
57.696
57.740
57.779
57.813
57.843
57.870
57.894
57.915
57.934
57.952
57.967
57.982
57.995
58.006
58.017
58.027
58.037
58.045
58.053
58.060
58.067
58.073
58.079
58.085
58.090
58.094
58.099
58.103
58.107
58.111
58.114
58.118
58.121
58.124
58.126
58.129
58.132
58.134
58.136
58.138
AV) = p(P).,
Ф°(Л
Дж • К~1 • моль"
186.981
210.527
224.879
225.109
236.137
245.189
252.935
259.731
265.798
271.282
276.289
280.895
285.163
289.137
292.857
296.352
299.650
302.770
305.731
308.549
311.237
313.806
316.267
318.628
320.896
323.080
325.184
327.216
329.178
331.077
332.916
334.698
336.427
338.107
339.739
341.327
342.873
344.379
345.847
347.278
348.676
350.040
351.373
352.677
353.952
355.199
356.421
357.617
358.789
359.938
361.065
362.171
363.256
364.320
365.366
366.394
367.403
368.395
369.371
370.331
371.275
ДИФТОРИД ФОСФОРА
?2(F) •P~1(PF2
s°m
-1
220.392
245.449
262.046
262.320
275.680
286.799
296.292
304.549
311.840
318.357
324.242
329.605
334.527
339.074
343.299
347.242
350.939
354.418
357.704
360.815
363.771
366.585
369.270
371.837
374.297
376.658
378.927
381.111
383.217
385.250
387.214
389.115
390.955
392.740
394.471
396.153
397.787
399.377
400.925
402.433
403.903
405.337
406.736
408.102
409.438
410.743
412.020
413.269
414.493
415.691
416.865
418.016
419.144
420.251
421.337
422.404
423.451
424.480
425.491
426.485
427.462
) V'
//°(/)-//°@)
кДж моль
3.341
6.984
11.081
11.163
15.817
20.805
26.015
31.373
36.834
42.367
47.954
53.580
59.237
64.919
70.619
76.335
82.063
87.802
93.550
99.305
105.067
110.834
116.606
122.382
128.162
133.944
139.730
145.518
151.309
157.101
162.896
168.691
174.489
180.288
186.088
191.889
197.691
203.494
209.299
215.103
220.909
226.715
232.522
238.330
244.138
249.947
255.756
261.566
267.376
273.186
278.997
284.808
290.620
296.432
302.244
308.057
313.870
319.683
325.496
331.309
337.123
PF2 (г)
Таб ли ца 215
D@) = 980.113 кДж- моль
\?К°(Т)
-503.6133
-246.5875
-161.7340
-160.6663
-117.6071
-91.7253
-74.4462
-62.0895
-52.8126
-45.5909
-39.8089
-35.0748
-31.1269
-27.7843
-24.9175
-22.4315
-20.2550
-18.3335
-16.6245
-15.0947
-13.7170
-12.4699
-11.3356
-10.2993
-9.3489
-8.4740
-7.6659
-6.9172
-6.2215
-5.5734
-4.9680
-4.4014
-3.8697
-3.3699
-2.8990
-2.4548
-2.0348
-1.6372
-1.2601
-.9021
-.5616
-.2374
.0717
.3667
.6486
.9183
1.1766
1.4241
1.6617
1.8898
2.1090
2.3199
2.5230
2.7186
2.9072
3.0892
3.2649
3.4347
3.5988
3.7576
3.9113
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
л
** 5
1 Л
? а о
1 ^ ;
1О о ,-ц v>
О о U0 *
g; о | •
оо 2 » а
^ *? я <*
II • *** 00
^ II W> (N
s- ? 7
и сч "
с< ?-< Ч
[X о о?
oW &
•^ о
<J "^
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ОО >js
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+
V *•" Я
СО ^ g
йЗ °
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1 1О \/
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X гН О
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!о ^ "Г
+ i &-«
5 ? "
СМ «О v
g; g °
СО Tt
1 +
t I
286

Класс точности
V-G
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
44.379
44.472
48.598
51.308
53.084
54.281
55.115
55.715
56.159
56.496
56.757
56.962
57.128
57.262
57.373
57.466
57.544
57.610
57.667
57.716
57.758
57.795
57.828
57.857
57.883
57.906
57.926
57.945
57.961
57.976
57.990
58.003
58.014
58.025
58.034
58.043
S8.051
58.059
58.066
58.072
58.078
58.084
58.089
58.094
58.099
58.103
58.107
58.11
1
58.114
58.118
58.121
58.124
58.127
58.129
58.132
58.134
58.137
58.139
58.141
ОТРИЦАТЕЛЬНЫЙ
К°(Т)=р(?).р
Ф°СГ)
Дж • К • моль
219.130
219.359
230.361
239.405
247.151
253.952
260.024
265.514
270.526
275.138
279.409
283.388
287.112
290.611
293.912
297.035
300.001
302.820
305.510
308.082
310.544
312.907
Ъ15.178
317.363
319.469
321.502
323.466
325^366
327.205
328.989
330.720
332.400
334.034
335.622
337.169
338.676
340.144
341.577
342.975
344.340
345.67'
346.978
348.254
349.502
350.724
351.921
353.093
354.243
355.370
356.476
357.561
358.627
359.673
360.701
361.711
362.704
363.680
364.640
365.584
2(F) .р(е)
S°(T)
-1
256.172
256.447
269.846
281.003
290.525
298.804
306.110
312.638
318.532
323.901
328.829
333.380
337.608
341.554
345.253
348.734
352.021
355.134
358.091
360.905
363.592
366.160
368.620
370.981
373.251
375.436
377.542
379.575
381.540
383.441
385.282
387.066
388.798
390.480
392.115
393.705
395.253
396.761
398.231
399.665
401.064
402.431
403.766
405.072
406.349
407.598
408.821
410.020
411.194
412.345
413.473
414.580
415.667
416.733
417.781
418.810
419.821
420.815
421.792
ИОН ДИФТОРИДА ФОСФОРА PF2" (г)
•^(PF") ZW/
//°<П-//°(())
кДж • моль
11.044
11.127
15.794
20.799
26.024
31.396
36.869
42.412
48.007
53.640
59.303
64.990
70.694
76.414
82.146
87.888
93.639
99.396
105.160
110.929
116.703
122.481
128.262
134.046
139.833
145.623
it I л 1 Л
157.208
163.003
168.800
174.599
180.398
186.199
192.001
197.804
203.608
209.412
215.218
221.024
226.831
232.639
238.447
244.256
250.065
255.874
261.684
267.495
273.306
279.117
284.928
290.740
296.553
302.365
308.178
313.991
319.804
325.618
331.432
337.246
°@) - 1170.113 кДж-моль 1
ЧК°{Т)
-194.7162
-193.4365
-141.7932
-110.7065
-89.9214
-75.0345
-63.8407
-55.1130
-48.1142
-42.3746
-37.5807
-33.5152
-30.0229
-26.9895
-24.3296
-21.9775
-19.8824
-18.0037
-16.3094
-14.7731
-13.3736
-12.0930
-10.9167
-9.8321
-8.8288
-7.8979
7 ПЯ 1 ^
• / .\)О 1 О
-6.2231
-5.4670
-4.7580
-4.0919
-3.4647
-2.8731
-2.3140
-1.7847
-1.2829
-.8064
-.3532
.0784
.4898
.8827
1.2582
1.6175
1.9617
2.2917
2.6085
2.9128
3.2055
3.4872
3.7585
4.0200
4.2723
4.5159
4.7512
4.9787
5.1987
5.4117
5.6180
5.8180
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Г-
О\
об
VO
II
-\
1>
г.
Таб л и
1
к
к
8
о
о
1
i
и
о
С
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Urn
о
о
с*
'>
о
V
О v;
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о л
О ,-н
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00 jj
я <*>
•4
I
г* *
<N О
^ л.
CN
Os ^
со со
-s
ь
Л
k
СО
СО
со
S
о
г-
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II
об
ON
<N
Ui
1 с*
["т,
Сц
О
><;
<\
ца 216
i
1
v>
On
00
CN
О ос
со
2
о
•о
V
v
8
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1
о
II
н
w
287

Класс точности
VI- D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
36.568
48.612
58.685
58.846
66.067
70.824
73.964
76.093
77.582
78.657
79.454
80.060
80.530
80.902
81.200
81.443
81.644
81.811
81.952
82.072
82.175
82.264
82.341
82.408
82.468
82.520
82.567
82.608
82.646
82.679
82.709
82.737
82.762
82.784
82.805
82.824
82.842
82.858
82.872
82.886
82.899
82.911
82.921
82.932
82.941
82.950
82.958
82.966
82.974
82.980
82.987
82.993
82.999
83.004
83.009
83.014
83.019
83.023
83.027
83.031
83.035
Ф°(Л
~* 1
Дж • К • моль
188.639
213.329
229.559
229.828
243.011
254.237
264.088
272.891
280.855
288.128
294.822
301.022
306.796
312.199
317.275
322.060
326.588
330.883
334.968
338.862
342.584
346.147
349.564
352.847
356.005
359.048
361.984
364.821
367.564
370.219
372.793
375.289
377.713
380.069
382.360
384.589
386.760
388.876
390.940
392.954
394.920
396.840
398.718
400.554
402.351
404.109
405.832
407.519
409.172
410.794
412.384
413.945
415.477
416.981
418.459
419.911
421.338
422.740
424.120
425.477
426.812
ТРИФТОРИД ФОСФОРА PF3 (г)
*F)V(FF3
s°tn
222.538
251.569
272.947
273.311
291.299
306.589
319.799
331.371
341.634
350.837
359168
366.770
373.757
380.219
386.225
391.836
397.099
402.054
406.734
411.168
415.381
419.392
423.221
426.883
430.391
433.759
436.996
440.113
443.118
446.019
448.822
451.535
454.162
456.709
459.181
461.581
463.915
466.185
468.395
470.548
472.646
474.693
476.692
478.643
480.549
482.413
484.237
486.021
487.768
489.479
491.155
492.799
494.410
495.991
497.543
499.066
500.562
502.031
503.475
504.894
506.290
) V'
/Ал-//°«о
кДж • моль
3.390
7.648
12.936
13.045
19.315
26.176
33.426
40.936
48.624
56.438
64.346
72.323
80.353
88.426
96.531
104.664
112.819
120.992
129.180
137.381
145.594
153.816
162.046
170.284
178.527
186.777
195.031
203.290
211.553
219.819
228.088
236.361
244.636
252.913
261.192
269.474
277.757
286.042
294.328
302.617
310.906
319.196
327.488
335.780
344.074
352.369
360.664
368.960
377.257
385.555
393.853
402.152
410.452
418.752
427.053
435.354
443.656
451.958
460.260
468.563
476.867
э@) = 1499.127
-768.8722
-375.5917
-245.7619
-244.1285
-178.2598
-138.6793
-112.2631
-93.3788
-79.2065
-68.1780
-59.3516
-52.1275
-46.1057
-41.0091
-36.6397
-32.8522
-29.5376
-26.6124
-24.0120
-21.6850
-19.5905
-17.6952
-15,9720
-14.3985
-12.9559
-11.6285
-10.4031
-9.2683
-8.2143
-7.2328
-6.3166
-5.4594
-4.6555
-3.9001
-3.1890
-2.5183
-1.8846
-1.2851
-.7168
-.1775
.3350
.8227
1.2874
1.7307
2.1540
2.5588
2.9461
3.3171
3.6728
4.0142
4.3422
4.6574
4.9607
5.2527
5.5341
5.8054
6.0671
6.3198
6.5640
6.8000
7.0283
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2S00
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
00
?
оо
+
ЧО
со
со
s
CN
с»
V©
VO
г-(
о
О
|
ON
ON
00
со
VO
СО
ЧС
1
0
Т а б л и
i
л
~ о
л
1 *
s ч
*=* I
со ?
• 1
КГ> II
? Q
в." и:
Й «•
о Си
^ о
^ <Л
§
го
г*
г^
CN
о.
X
•о
«о
чо
1
00
00
о
ца 217
i
А
§
_
i
р
со
II
0 «
2
о
о
о
V
&-.
V
§
о
«о
т
—«
II
288

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
.900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
44.576
65.088
84.701
85.018
99.123
108.447
114.640
118.862
121.830
123.979
125.578
126.795
127.741
128.490
129.093
129.584
129.989
130.328
130.613
130.856
131.064
131.244
131.400
131.537
131.657
131.763
131.858
131.942
132.018
132.086
132.147
132.203
132.254
132.300
132.342
132.380
132.416
132.448
132.478
132.506
132.532
132.556
132.578
132.599
132.618
132.636
132.653
132.669
132.684
132.698
132.711
132.723
132.735
132.746
132.756
132.766
132.776
132.785
132.793
132.801
132.808
АЛЛ=Р(Р)-Р
Ф°(Л
Дж • К • моль
197.148
225.382
245.451
245.795
263.097
278.442
292.294
304.923
316.522
327.237
337.190
346.475
355.175
363.356
371.075
378.379
385.312
391.906
398.194
404.202
409.954
415.470
420.769
425.867
430.779
435.517
440.093
444.518
448.802
452.953
456.979
460.887
464.685
468.377
471.971
475.470
478.880
482.204
485.449
488.616
491.710
494.734
497.690
500.583
503.414
506.186
508.902
511.564
514.173
516.733
519.244
521.709
524.129
526.506
528.841
531.136
533.393
535.611
537.794
539.941
542.054
ПЕНТАФТОРИД ФОСФОРА
s(F)-p-4ffs>
s°m
234 269
271.106
300.918
301.443
327.968
351.161
371.517
389.526
405.603
420.083
433.232
445.261
456.335
466.591
476.136
485.060
493.436
501.327
508.785
515.853
522.571
528.970
535.079
540.923
546.524
551.900
557.070
562.048
. 566.848
571.482
575.961
580.295
584.493
588.563
592.514
596.351
600.080
603.709
607.241
610.683
614.038
617.311
620.505
623.625
626.674
629.654
632.570
635.423.
638.216
640.952
643.633
646.261
648.839
651.367
653.848
656.285
658.677
661.027
663.336
665.607
667.839
v°
//°сл-//°(о)
кДж * моль
3.712
9.145
16.537
16.694
25.948
36.359
47.534
59.222
71.265
83.561
96.043
108.664
121.393
134.206
147.086
160.021
173.001
186.016
199.064
212.137
225.233
238.349
251.481
264.626
277.788
290.959
304.140
317.331
330.529
343.734
356.946
370.163
383.386
396.614
409.846
423.082
436.322
449.565
462.812
476.061
489.313
502.567
515.824
529.083
542.343
555.606
568.871
582.137
595.404
608.673
621.944
635.216
648.489
661.763
675.038
688.314
701.591
714.869
728.148
741.428
754.708
PF5 (г)
@) =2284.353
\gK°(T)
-1167.6130
-567.9133
-369.8696
-367.3776
-266.8842
-206.4965
-166.1969
-137.3919
-115.7784
-98.9633
-85.5090
-74.5002
-65.3262
-57.5640
-50.9113
-45.1464
-40.1029
-35.6535
-31.6993
-28.1621
-24.9792
-22.1002
-19.4835
-17.0949
-14.9059
-12.8924
-11.0343
-9.3142
-7.7172
-6.2308
-4.8437
-3.5463
-2.3303
-1.1881
-.1133
.8999
1.8567
2.7617
3.6190
4.4322
5.2047
5.9395
6.6392
7.3064
7.9432
8.5517
9.1337
9.6909
10.2249
10.7372
11.2289
11.7014
12.1557
12.5929
13.0139
13.4196
13.8109
14.1884
14.5529
14.9051
15.2456
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VO
Г*»
V©
On
,—i
II
+
•о
8
is
s
о
1
со
о
§
ft
о
«о
ON
«О
II
ф
Т а б
Т
k
И
«о
00
1
II
О
с-Г
«л
Он
о
Л
о
к
го
1
ё
со
1
On
<N
«О
+
лица Z15
i
i
2
8
со
со
1
II
??
ю
00
ON
«Л
и*
О
т
л
К
§
1
ON
!о
II
о 5
со
я
о
8
VO
V
к
V
8
«о
т
II
н
19 872
289

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я00
/CO\t\f
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
C°iT)
37.625
55.121
68.872
69.092
79.148
86.255
91.270
94.852
97.461
99.400
100.871
102.009
102.903
103.618
104.198
104.673
105.068
105.398
105.678
105/917
106.122
106.300
106.455
106.591
106.710
106.816
106.910
106.994
107 070
I V# »vf V
107.138
107.199
107.255
107.306
107.352
107.394
107.433
107.468
107.501
107.531
107.559
107.585
107.609
107.631
107.652
107.672
107.690
107.707
107.723
107.738
107.752
107.765
107.777
107.789
107.800
107.811
107.821
107.830
107.839
107.847
107.855
107.863
ОКСИД-ТРИФТОРИД ФОСФОРА POF3 (г)
ЛГ°(Г)=Р(Р) •
Ф°(П
Дж • К • моль"
195.074
220.364
237.795
238.089
252.735
265.491
276.878
287.188
296.618
305.308
313.366
. 320.877
327.910
334.521
340.757
346.659
352.259
357.587
362.667
367.522
372.170
376.628
380.912
385.033
389.003
392.835
396.535
400.114
А(\% СТО
tVJO.Dl J7
406.937
410.194
413.356
416.429
419.417
422.325
425.158
427.918
430.609
433.236
435.800
438.305
440.753
443.148
445.490
447.783
450.029
452.229
454.385
456.499
458.572
460.607
462.604
464.565
466.491
468.383
470.243
472.071
473.869
475.638
477.378
479.091
р(О) -p3(F)
S°(T)
-l
229.155
260.595
285.308
285.735
307.070
325.542
341.737
356.091
368.936
380.532
391.085
400.754
409.670
417.936
425.637
432.842
439.611
445.991
452.023
457.744
463.182
468.364
473.313
478.048
482.587
486.945
491.137
495.173
4QQ Ofifi
*T?7l7.VvW
502.824
506.457
509.973
513.379
516.682
519.887
523.001
526.028
528.973
531.840
534.634
537.357
540.014
542.607
545.140
547.615
550.035
552,402
554.719
556.987
559.208
561.385
563.520
565.613
567.666
569.681
571.659
573.602
575.511
577.386
579.230
581.043
• p'l(?OF^)
//°('П-//°@)
кДж • моль
3.408
8.046
14.166
14.294
21.734
30.025
38.916
48.232
57.854
67.702
77.718
87.865
98.112
108.439
118.831
129.276
139.763
150.287
160.841
171.421
182.023
192.645
203.283
213.935
224.600
235.277
245.963
256.658
9А7 ЧЛ9
278.072
288.789
299.512
310.240
320.973
331.710
342.451
353.196
363.945
374.696
385.451
396.208
406.968 '
417.730
428.494
439.260
450.028
460.798
471.570
482.343
493.117
503.893
514.670
525.449
536.228
547.008
557.790
568.573
579.356
590.140
600.926
611.712
Таблица 219
Д/,У/°(О)= 2037.399 кДж • моль *
lgK°(T)
-1044.4267
-509.7834
-333.2651
-331.0442
-241.4845
-187.6667
-151.7487
-126.0725
-106.8040
-91.8110
-79.8128
-69.9939
-61.8101
-54.8846
-48.9482
-43.8030
-39.3011
-35.3288
-31.7980
-28.6390
-25.7961
-23.2241
-20.8861
-18.7515
-16.7950
. -14.9951
-13.3337
-11.7955
-10 4fi79
I U.OU / Z,
-9.0375
-7.7965
-6.6355
-5.5471
-4.5246
-3.5623
-2.6549
-1.7978
-.9870
-.2189
.5100
1.2025
1.8614
2.4889
3.0874
3.6587
4.2048
4.7273
5.2276
5.7072
6.1674
6.6092
7.0338
7.4423
7.8354
8.2140
8.5791
8.9311
9.2710
9.5992
9.9164
10.2231
r
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
4 1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЙПП
Zo\J\J
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600*
5700
5800
5900
6000
i
о
т §
Й к
§ й -
7 tf i
5 § §
vo со ю
CO <N «NT*
00 <N *н '
VO CO 1 ^
°* ¦* II
CO <N " ?
2 7 о п
1—1 | Й5
II II 1Л °°
II ii ^ О
5 °. ? «
О « о g
e^ ? *>
о Си
< <^
+
1 -
00 |
1-4 Л
jo t:
CO IS
+
я • *
CO Д" §
^ м. о
о н \/
6 °° v
о r
I Г": ^
H ^ v
5 .+ о
00 «V О
*o ^ <o
г- о
5 5 т
+ i Z
S 00 »
00 <N i-
»O ^
00 . ^-^
^н О
«О <N
II +
r
°^
290

Класс точности
IV -F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.386
31.782
33.991
34.023
35.317
36.069
36.538
36.854
37.085
37.269
37.431
37.585
37.742
37.907
38.084
38.273
38.472
38.681
38.897
39.118
39.342
39.567
39.791
40.013
40.231
40.444
40.652
40.853
41.047
41.233
41.410
41.578
41.736
41.884
42.021
42.147
42.261
42.363
42.453
42.530
42.595
42.648
42.687
42.715
42.730
42.733
42.725
42.705
42.675
42.633
42.582
42.522
42.453
42.375
42.289
42.196
42.097
41.991
41.879
41.763
41.642
ХЛОРИД
К°(Т)= р(Р)-р(С1) -р'ЧРСО
Ф°(Л
— 1
Дж • К • моль
172.529
193.362
205.609
205.802
214.897
222.134
228.168
233.351
237.899
241.952
245.610
248.943
252.006
254.840
257.477
259.945
262.263
264.451
266.521
268.488
270.361
272.149
273.860
275.502
277.079
278.596
280.060
281.473
282.839
284.161
285.442
286.686
287.893
289.067
290.210
291.322
292.406
293.463
294.495
295.502
296.486
297.448
298.389
299.310
300.212
301.095
301.961
302.809
303.641
304.457
305.258
306.045
306.817
307.575
308.320
309.052
309.772
310.479
311.175
311.860
312.533
S°tT)
202.629
223.635
236.771
236.982
246.964
254.933
261.554 {
267.211
272.148
276.527
280.462
284.037
287.314
290.341
293.157
295.791
298.268
300.606
302.823
304.932
306.944
308.869
310.715
312.489
314.196
315.843
317.433
318.971
320.460
321.904
323.305
324.665
325.988
327.275
328.527
329.747
330.936
332.095
333.226
334.330
335.408
336.460
337.488
338.493
339.475
340.436
341.375
342.293
343.192
344.072
344.932
345.775
346.600
347.408
348.199
348.975
349.734
350.478
351.207
351.922
352.623
ФОСФОРА
д;
//°СО-//°(()
кДж • моль"
3.010
6.055
9.291
9.354
12.827
16.400
20.032
23.702
27.400
31.118
34.853
38.604
42.370
46.152
49.952
53.769
57.607
61.464
65.343
69.244
73.167
77.112
81.080
85.070
89.083
93.116
97.171
101.246
105.341
109.456
113.588
117.737
121.903
126.084
130.279
134.488
138.708
142.940
147.180
151.430
155.686
159.948
164.215
168.485
172.758
177.031
181.304
185.576
189.845
194.110
198.371
202.626
206.875
211.116
215.350
219.574
223.789
227.993
232.187
236.369
240.539
РС1 (г)
7'°@) = 300.000 кДж • моль
)
1
lg*V)
-159.3789
-81.3632
-55.7738
-55.4530
-42.5514
-34.8442
-29.7294
-26.0932
-23.3793
-21.2790
-19.6074
-18.2470
-17.1194
-16.1706
-15.3620
-14.6653
-14.0592
-13.5277
-13.0582
-12.6408
-12.2676
-11.9321 -
-11.6292
-11.3546
-11.1046
-10.8763
-10.6671
-10.4749
-10.2977
-10.1340
-9.9825
-9.8419
-9.7111
-9.5893
-9.4757
-9.3694
-9.2700
-9.1767
-9.0891
-9.0068
-8.9294
-8.8564
-8.7875
-8.7225
-8.6610
-8.6028
-8.5477
-8.4955
-8.4460
-8.3989
-8.3543
-8.3118
-8.2713
-8.2328
-8.1962
-8.1612
-8.1278
-8.0960
-8.0656
-8.0365
-8.0088
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ОО
чо
<ч
Tf
ЧО
ЧО
II
+
1—4
о
+
X
г^
О
о
. о
о
о
о
1
н
Я
<N
О
ОО
00
1О
го
+
ЧО
ON
00
<о
С4)
ГО
II
ол
Т а б л и
t
о
7
д
со
1-4
3
II
О
(PCI,
о
г
§
1
а
со
X
со
г-
,-4
об .
1 "
X
On
tJ-
<Ч
ON
+
X
о
ЧО
1—4
ю
+
1
• л
о
А
1=1
»о
Tf
со
1—4
II
я
об
<N
С
(РС1,
о
^\
ца 220
А
g
Т
v
ми
с*
го
00
||
о «
СП
2
о
о
ЧО
V
V
о
о
1
и
291

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
24С0
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500.
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5909
6000
1
36.159
45.504
50.934
51.004
53.741
55.208
56.067
56.607
56.968
57.220
57.402
57.538
57.642
57.724
57.789
57.841
57.884
57.920
57.950
57.976
57.998
58.017
58.033
58.047
58.060
58.071
58.080
58.089
58.097
58.104
58.110
58.116
58.121
58.126
58.130
58.134
58.138
58.141
58.144
58.147
58.150
58.152
58.155
58.157
58.159
58.161
58.162
58.164
58.165
58.167
58.168
58.170
58.171
58.172
58.173
58.174
58.175
58.176
58.177
58.177
58.178
К°(Т) = р(?) l
Ф°(Т)
Дж • К~! • моль"
203.783
228.249
243.899
244.153
256.399
266.453
275.005
282.454
289.055
294.982
300.360
305.283
309.822
314.033
317.960
321.638
325.098
328.364
331.456
334.392
337.188
339.855
342.405
344.849
347.194
349.448
351.618
353.710
355.730
357.682
359.570
361.399
363.172
364.893
366.565
368.190
369.771
371.310
372.809
374.271
375.697
377.088
378.448
379.776
381.075
382.345
383.588
384.805
385.997
387.166
388.311
389.435
390.536
391.618
392.680
393.722
394.747
395.753
396.743
397.716
398.673
ДИХЛОРИД ФОСФОРА РС12 (г)
>2(C1) p'^PCl
S°{T)
-1
237.641
265.675
284.980
285.296
300.387
312.552
322.700
331.386
338.970
345.696
351.734
357.212
362.223
366.840
371.120
375.109
378.844
382.354
385.665
388.800
391.774
394.604
397.303
399.883
402.354
404.724
407.002
409.194
411.307
413.346
415.316
417.221
419.066
420.855
422.590
424.275
425.913
427,506
429.057
430.567
432.039
433.475
434.876
436.245
437.582
438.889
440.167
441.418
442.643
443.842
445.017
446.169
447.299
448.407
449.494
450.561
451.610
452.639
453.651
454.646
455.624
2> V
//°('О-//°@)
кДж * моль
3.386
7.485
12.249
12.343
17.595
23.050
28.617
34 253
39.932
45.643
51.374
57.121
62.881
68.649
74.425
80.206
85.993
91.783
97.577
103.373
109.172
114.972
120.775
126.579
132.384
138.191
143.998
149.807
155.616
161.426
167.237
173.048
178.860
184.672
190.485
196.299
202.112
207.926
213.740
219.555
225.370
231.185
237.000
242.816
248.632
254.448
260.264
266.080
271.896
277.713
283.530
289:347
295.164
300.981
306.798
312.615
318.433
324.250
330.068
335.886
341.704
D@) = 606,803 кДж • моль 1
\gK°{T)
-308.6848
-149.2258
-96.5668
-95.9042
-69.1820
-53.1168
-42.3872
-34.7104
-28.9438
-24.4521
-20.8539
-17.9062
-15.4469
-13.3635
-11.5758
-10.0248
-8.6664
-7.4665
-6.3990
-5.4430
-4.5817
-3.8017
-3.0920
-'2.4434
-1.8482
-1.3001
-.7937
-.3243
.1121
.5187
.8988
1.2547
1.5888
1.9030
2.1992
2.4788
2.7432
2.9937
3.2314
3.4573
3.6722
3.8769
4.0723
4.2588
4.4372
4.6080
4.7716
4.9286
5.0793
5.2241
5.3635
5.4976
5.6268
5.7513
5.8715
5.9876
6.0998
6.2082
6.3131
6.4146
6.5130
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
.2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
540fr
5500
5600
5700
5800
5900
6000
00
On
г-
00
»—i
II
+
со
ON
ю
г^
о
ц.
с*
'к
г-
г».
ю
со
о
о
о
1
С4!
о
о
об
+
1
00
CN

Till
TaG
i
л
§
А
8
О
•О
II
w
О
<Г
1
§
т
го
ГЧ
О
+
МО
О
1
со
О
+
Л И
Т
А
CN)
ON
II
я
«о
об
ON
<ч
f
г
0
<
ца 221
Т
§
т
А-
со
см
о
об
со
II
ч о в;
со
Q
60001
V
V
о
о
t
С"ч
II
292

Класс точное i и
V-G
ОТРИЦАТЕЛЬНЫЙ ИОН ДИХЛОРИДА ФОСФОРА РС12" (г)
р2(С1) • р(е) р~1(?С\~) А //°@) = 902.803 кДж • моль
Таблица 222
Ф°(Г)
S°(T)
Дж • К~ * • моль
кДж * моль
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
50.860
50.928
53.613
55.095
55.975
56.534
56.908
57.170
57.361
57.503
57.613
57.698
57.767
57.822
57.867
57.905
57.937
57.964
57.987
58.006
58.024
58.039
58.052
58.063
58.074
58.083
58.091
58.099
58.105
58.111
58.117
58.122
58.126
58.131
58.134
58.138
58.141
58.144
58.147
58.150
58.152
58.154
58.156
58.158
58.160
58.162
58.164
58.165
58.166
58.168
58.169
58.170
58.171
58.172
58.173
58.174
58.175
58.176
58.177
239.564
239.823
252.235
262.383
270.994
278.482
285.111
291.059
296.454
301.390
305.940
310.160
314.094
317.779
321.244
324.514
327.611
330.551
333.350
336.020
338.573
341.018
343.366
345.622
347.794
349.888
351.909
353.862
355.752
357.582
359.357
361.079
362.751
364.377
365.959
367.499
369.000
370.461
371.888
373.280
374.640
375.969
377.268
378.540
379.783
381.001
382.194
383.362
384.508
385.632
386.734
387.816
388.878
389.921
390.946
391.953
392.943
393.916
394.873
281.332
281.647
296.705
308.843
318.973
327.646
335.221
341.940
347.974
353.448
358.456
363.071
367.350
371.337
375.070
378.580
381.891
385.024
387.997
390.827
393.526
396.106
398.576
400.946
403.224
405.416
407.528
409.567
411.536
413.442
415.287
417.075
418.810
420.495
422.133
423.726
425.276
426.787
428.259
429.695
431.096
432.464
433.801
435.108
436.386
437.637
438.862
440.061
441.236
442.388
443.517
444.626
445.713
446.780
447.828
448.858
449.870
450.864
451.842
12.453
12.547
17.788
23.230
28.788
34.415
40.088
45.793
51.520
57.263
63.019
68.785
74.559
80.338
86.123
91.911
97.703
103.498
109.296
115.096
120.897
126.700
132.505
138.311
144.118
149.925
155.734
161.544
167.354
173.164
178.976
184.788
190.600
196.413
202.226
208.040
213.854
219.668
225.483
231.298
237.113
242.928
248.744
254.560
260.375
266.191
272.008
277.824
283.640
289.457
295.274
301.091
306.908
312.725
318.543
324.360
330.178
335.995
341.813
-148.1934
-147.2045
-107.2943
-83.2611
-67.1829
-55.6595
-46.9884
-40.2226
-34.7930
-30.3369
-26.6123
-23.4514
-20.7341
-18.3723
-16.2999
-14.4660
-12.8314
-11.3647
-10.0411
-8.8402
-7.7454
-6.7431
-5.8217
-4.9718
-4.1850
-3.4544
-2.7742
-2.1391
-1.5446
-.9869
-.4625
.0315
.4978
.9388
1.3565
1.7528
2.1293
2.4877
2.8291
3.1549
3.4662
3.7639
4.0489
4.3221
4.5843
4.8361
5.0782
5.3111
5.5354
5.7517
5.9602
6.1616
6.3561
6.5441
6.7260
6.9020
7.0726
7.2379
7.3981
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5300
5000
6000
о
00
оо
II
р
об
со
I ? V
§
о
I
«о
00
о
*? о
^ I
О On
"* О
I
V
V
S
293

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
46.454
62.956
71.591
71.703
76.044
78.376
79.742
80.603
81.177
81.578
81.869
82.086
82.252
82.383
82.486
82.570
82.639
82.696
82.744
82.785
82.820
82.850
82.876
82.899
82.919
82.936
82.952
82.966
82.978
82.989
83.001
83.009
83.017
83.025
83.032
83.038
83.044
83.049
83.054
83.059
83.063
83.067
83.070
83.074
83.077
83.080
83.083
83.085
83.088
83.090
83.092
83.094
83.096
83.098
83.099
83.101
83.103
83.104
83.105
83.107
83.108
АЛП = Р<Р)-Р
Ф°(Т)
Дж • К • моль
209.516
238.251
258.160
258.491
274.642
288.159
299.797
310.015
319.122
327.336
334.815
341.679
348.022
353.917
359.424
364.588
369.452
374.048
378.403
382.542
386.484
390.249
393.851
397.304
400.619
403.807
406.877
409.838
412.698
415.462
418.138
420.730
423.244
425.684
428.055
430.360
432.602
434.786
436.914
438.989
441.014
442.990
444.921
446.808
448.652
450.457
452.224
453.954
455.648
457.309
458.937
460.534
462.100
463.638
465.148
466.631
468.088
469.520
470.928 ,
472.312 *
473.674
ТРИХЛОРИД ФОСФОРА РС13
^Cl) V(PCL
S°iT)
-1
246.912
284.650
311.597
312.040
333.332
350.575
364.996
377.358
388.161
397.747
406.357
414.171
421.321
427.910
434.019
439.713
445.044
450.056
454.784
459.259
463.506
467.548
471.403
475.087
478.616
482.001
485.254
488.385
491.403
494.314
497.128
499.850
502.485
505.040
507.519
509.926
512.265
514.540
516.755
518.912
521.016
523.067
525.068
527.023
528.933
530.800
532.626
534.413
536.162
537.875
539.554
541.199
542.813
544.396
545.949
547.474
548.971
550.442
551.887
553.308
554.705
>> V
//Vn-//°«»
кДж • моль
3.740
9.280
15.932
16.065
23.476
31.208
39.120
47.140
55.231
63.370
71.543
79.741
87.958
96.190
104.434
112.687
120.947
129.214
137.486
145.763
154.043
162.327
170.613
178.902
187.193
195.485
203.780
212.076
99П 47*4
ZZU.O / О
228.671
236.971
245.271
253.572
261.874
270.177
278.481
286.785
295.089
303.394
311.700
320.006
328.313
336.620
344.927
353.234
361.542
369.850
378.159
386.467
394.776
403.085
411.394
419.704
428.014
436.324
444.634
452.944
461.254
469.565
477.875
486.186
I а б л и ца 223
°@) = 960.725 кДж • моль 1
\gK°(T)
Г
К
-487.5168 100
-235.0941 200
-151.7925 298.15
-150.7448 300
-108.5027 400
-83.1250 500
-66.1878 600
-54.0780 700
-44.9879. 800
-37.9125 900
-32.2484 1000
-27.6115 1100
-23.7455 1200
-20.4727 1300
-17.6664 1400
-15.2333 1500
-13.1037 1600
-11.2240 1700
-9.5527 1800
-8.0570 1900
-6.7105 2000
-5.4919 2100
-4.3839 2200
-3.3719 2300
-2.4441 2400
-1.5902 2500
-.8019 2600
-.0717 2700
fiOfifi 9ЯПП
1.2382 2900
1.8280 3000
2.3799 3100
2.8975 3200
3.3840 3300
3.8421 3400
4.2742 3500
4.6825 3600
5.0689 3700
5.4353 3800
5.7830 3900
6.1136 4000
6.4282 4100
6.7281 4200
7.0142 4300
7.2875 4400
7.5489 4500
7.7991 4600
8.0389 4700
8.2688 4800
8.4896 4900
8.7017 5000
8.905*7 5100
9.1020 5200
9.2910 5300
9.4732 5400
9.6490 5500
9.8186 5600
9.9825 5700
10.1408 5800
10.2939 5900
10.4421 6000
i
т
л
Т о
к . ^
? о
ОО ГЧ -J Т
гч о SJ «V
го • го °2 *
^ *> 7 и
г-~ оо *
го гч II Й
Л » * 2
< ,-v, -Н Tf
О об *°
? Я "
ь
+
о ^
S 'g
+ ?
о и ?
v© . О
оо * о
оо ;*; о
8 ч *>
о « V
° 8 ь
а " V
но v
Л . о
s « °
°^ ГО
гч оо L-
«•2 2
о ' С
оо X
й ? "
го *° ;<{
ЧЧ О
!|
294

Класс точности
VII-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙАЛ
ZoKJK)
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
c°pm
64.531
97.889
113.316
113.510
120.986
124.959
127.278
128.736
129.707
130.386
130.877
131.244
131.525
131.744
131.920
132.061
132.178
132.274
132.355
132.424
132.483
132.534
132.578
132.616
132.650
132.679
132.706
132.729
1 *^9 7ЧП
1 OZ. / D\J
132.769
132.786
132.802
132.816
132.829
132.840
132.851
132.861
132.870
132.878
132.886
132.893
132.900
132.906
132.912
132.917
132.922
132.927
132.931
132.935
132.939
132.943
132.946
132.949
132.952
132.955
132.958
132.960
132.963
132.965
132.967
132.969
К°(Т)= р(?) • i
Ф°(Т)
— 1
Дж К • моль
223.160
260.542
288.949
289.433
313.411
333.886
351.722
367.503
381.645
394.449
406.144
416.905
426.867
436.141
444.815
452.960
460.639
467.900
474.787
481.336
487.579
493.542
499.251
504.725
509.984
515.043
519.917
524.619
COQ 1 С 1
ozy. 1 о 1
533.553
537.805
541.925
545.922
549.802
553.573
557.239
560.808
564.283
567.670
570.973
574.196
577.342
580.417
583.421
586.360
589.235
592.049
594.805
597.504
600.151
602.746
605.291
607.788
610.239
612.646
615.011
617.334
619.617
621.861
624.069
626.240
ПЕНТАХЛОРИД ФОСФОРА
о5(С\)-р~1(?С\5)
S°(T)
-1
II
V
кДж • моль
268.521
324.764
367.114
367.816
401.616
429.082
452.088
471.825
489.083
504.402
518.166
530.658
542.090
552.627 .
562.397
571.503
580.030
588.046
595.609
602.767
609.561
616.026
622.193
628.087
633.732
639.147
644.352
649.360
сел 1 ЙЙ
DO4-. 1 ОО
658.847
663.348
667.702
671.919
676.006
679.972
683.822
687.565
691.205
694.749
698.201
701.565
704.847
708.049
711.177
714.232
717.219
720.141
723.001
725.799
728.540
731.225
733.858
736.440
738.972
741.457
743.897
746.293
748.646
750.958
753.231
755.466
4.536
12.844
23.305
23.515
35.282
47.598
60.219
73.025
85.951
98.957
112.022
125.128
138.267
151.431
164.615
177.814
191.026
204.249
217.480
230.720
243.965
257.216
270.471
283.731
296.995
310.261
323.530
336.802
оел лур
363.352
376.630
389.909
403.190
416.472
429.756
443.040
456.326
469.613
482.900
496.188
509.477
522.767
536.057
549.348
562.640
575.932
589.224
602.517
615.810
629.104
642.398
655.692
668.987
682.282
695.578
708.873
722.169
735.465
748.762
762.058
775.355
PCI 5 (г)
э@) - 1284.658
-644.7629
-306.6843
-195.1037
-193.7003
-137.1306
-103.1559
-80.4892
-64.2894
-52.1342
-42.6775
-35.1106
-28.9191
-23.7594
-19.3939
-15.6525
-12.4105
-9.5745
-7.0727
-4.8496
-2.8611
-1.0721
.5460
2.0164
3.3585
4.5883
5.7193
6.7629
7.7288
8.6255
9.4600
10.2386
10.9668
11.6493
12.2902
12.8933
13.4618
13.9986
14.5062
14.9871
15.4433
15.8766
16^2887
16.6811
17.0653
17.4124
17.7537
18.0801
18.3926
18.6921
18.9794
19.2552
19.5202
19.7750
20.0203
20.2564
20.4840
20J035
20.9153
21.1199
21.3175
21.5085
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
00
со
CN
об
О
<N
II
+
со
J^
CN
С*
{н
00
«о
ON
ON
8
О
н
00
«о
ЧО
со
о
ON
чо
ON
00
ЧО
II
Таблица 224
Т
л
— 2
i . 2
л
§ * т
* * §
? О 5?
„5- о
5 Щ j
ю S Т
On со ни
ON |
S » «1
СО ^*v ^
1 г* >о
II «О ^
О^ °0 00
to (-* п
U Тл ° «s
ь и *>
о ^
^ 0
т
§
1 ^^
О
го \у
О *-
+ §
о
С"» U")
00 *f
^ О
*-ч ~^
1 ?
+
295

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
49.318
72.147
84.354
84.521
91.517
95.898
98.819
100.848
102.301
103.372
104.178
104.800
105.287
105.675
105.990
106.247
106.460
106.639
106.790
106.919
107.030
107.126
107.209
107.282
107.347
107.404
107.454
107.500
107.540
107.577
107.610
107.640
107.667
107.692
107.715
107.735
107.755
107.772
ИO.788
107.803
107.817
107.830
107.842
107.854
107.864
107.874
107.883
107.891
107.899
107.907
107.914
107.921
107.927
107.933
107.939
107.944
107.949
107.954
107.958
107.963
107.967
ОКСИД-ТРИХЛОРИД ФОСФОРА РОС13 (г)
А'°(Л=р(Р) р(О) р3(С1) ч
Ф°(Т)
"* 1
Дж • К • моль
213.147
243.148
264.932
265.300
283.473
298.979
312.526
324.563
335.396
345.246
354.276
362.613
370.355
377.582
384.358
390.735
396.758
402.464
407.885
413.047
417.975
422.688
427.205
431.541
435.710
439.725
443.596
447.333
450.946
454.442
457.828
461.112
464.300
467.395
470.405
473.334
476.185
478.963
481.671
484.313
486.893
489.412
491.874
494.281
496.636
498.940
501.196
503.407
505.573
507.696
509.779
511.822
513.828
515.796
517.730
519.630
521.497
523.332
525.137
526.912
528.658
-1
251.130
293.021
324.350
324.873
350.231
371.158
388.917
404.312
417.878
429.992
440.927
450.887
460.027
468.471
476.314
483.636
490.500
496.959
503.059
508.836
514.323
519.548
524.533
529.301
533.868
538.251
542.465
546.521
550.431
554.205
557.853
561.382
564.800
568.113
571.329
574.452
577.487
580.439>
583.314
586.114
588.843
591.506
594.104
596.642
599.121
601.546
603.917
606.237
608.509
610.734
612.913
615.051
617.146
619.202
621.220
623.200
625.145
627.056
628.934
630.779
632.594
о1 (РОС1з) Аг
//°('Л-//°(())
кДж • моль"
3.798
9.974
17.716
. 17.872
26.703
36.090
45.835
55.824
65.985
76.272
86.651
97.101
107.606
118.155
128.739
139.351
149.987
160.642
171.314
182.000
192.697
203.405
214.122
224.846
235.578
246.315
257.058
267.806
278.558
289.314
300.073
310.836
321.601
332.369
343.140
353.912
364.687
375.463
386.241
397.021
407.802
418.584
429.368
440.152
450.938
461.725
472.513
483.302
494.092
504.882
515.673
526.464
537.257
548.050
558.843
569.638
580.432
591.228
602.023
612.819
623.616
Таблица 225
f/°@) = 1483.870 кДж • моль
ЫК°(ТУ
-755.0234
-365.2230
-236.5691
-234.9507
-169.7054
-130.5095
-104.3533
-85.6559
-71.6243
-60.7056
-51.9674
-44.8159
-38.8551
-33.8106
-29.4862
-25.7383
-22.4587
-19.5650
-16.9928
-14.6915
-12.6205
-10.7468
-9.0436
-7.4886
-6.0633
-4.7521
-3.5418
-2.4213
-1.3808
-.4121
.4919
1.3377
2.1306
2.8755
3.5766
4.2377
4.8621
5.4529
6.0126
6.5437
7.0484
7.5285
7.9859
8.4221
8.8386
9.2367
9.6176
9.9824
10.3321
10.6677
10.9899
11.2997
11.5976
11.8844
12.1607
12.4271
12.6841
12.9321
13.1717
13.4033
13.6273
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
?
'ё *
о *
И А
% О Е
00
со • 1 л
m- 2 " i
2 7 я п
11 ^ а
И _ 1-4 О
ц^ ^ * СО
S *-> 00
^ , • ON *•
О -^ о ^
° ь
^ о
< 5-
+
vo •
со н
+ •
5 • Я
? Д §
со Сч О
i ъ v
| « V
« „ §
00 О
+ 1 Т
я ей ^
со со
со «о и
с*- о
«О гн
II +
оГ
296

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5960
6000
С°(Т)
34.977
42.127
47.535
47.615
51.037
53.142
54.480
55.366
55.977
56.414
56.736
56.979
57.167
57.315
57.434
57.530
57.610
57.676
57.732
57.779
57.820
57.855
57.885
57.912
57.935
57.956
57.974
57.990
СО ЛЛС
58.005
58.018
58.030
58.041
58.051
58.060
58.068
58.075
58.082
58.088
58.094
58.100
58.105
58.109
58.114
58.118
58.121
58.125
58.128
58.131
58.134
58.137
58.139
58.142
58.144
58.146
58.148
58.150
58.152
58.153
58.155
58.157
58.158
ФТОРИД-ХЛОРИД ФОСФОРА PFC1 (г)
К°(Т)= pi?) -
Ф°(Т)
Дж • К • моль
201.524
225.465
240.418
240.660
252.265
261.796
269.930
277.041
283.366
289.064
294.251
299.011
303.410
307.499
311.319
314.904
318.280
321.471
324.496
327.372
330.112
332.729
335.233
337.634
339.940
342.157
344.294
346.355
348.345
350.270
352.132
353.938
355.689
357.388
359.040
360.646
362.208
363.730
365.214
366.660
368.071
369.449
370.795
372.111
373,397
374.655
375.888
377.094
378.276
379.435
380.570
381.684
382.777
383.851
384.904
385.939
386.956
387.955
388.937
389.904
390.854
p(F) р(С\)р
S°(T)
-1
235.101
261.521
279.426
279.720
293.927
305.560
315.376
323.846
331.281
337.901
343.862
349.281
354.248
358.829
363.081
367.048
370.763
374.258
377.556
380.679
383.644
386.465
389.157
391.731
394.196
396.562
398.835
401.023
403.133
405.168
407Л35
409.039
410.881
412.668
414.401
416.085
417.721
419.312
420.861
422.371
423.841
425.276
426.677
428.044
429.380
430.686
431.964
433.214
434.438
435.637
436.811
437.963
439.092
440.199
441.286
442.353
443.401
444.430
445.442'
446.436
447.413
^PFCl) Ar/1
//°G')~//°(())
кДж ' моль
3.358
7.211
11.630
11.718
16.665
21.882
27.268
32.763
38.332
43.953
49.611
55.297
61.005
66.730
72.467
78.216
83.973
89.737
95.507
101.283
107.063
112.847
118.634
124.424
130.216
136.011
141.807
147.605
153.405
159.206
165.009
170.812
176.617
182.422
188.229
194.036
199.844
205.652
211.461
217.271
223.081
228.892
234.703
240.515
246.327
252.139
257.952
263.765
269.578
275.391
281.205
287.019
292.833
298.648
304.463
310.277
316.093
321.908
327.723
333.539
339.355
Т а б л и ц а 226
э@) = 793.000 кДж • моль 1
lgtfV)
-406.2306
-198.1045
-129.3851
-128.5204
-93.6480
-72.6853
-58.6882
-48.6765
-41.1585
-35.3048
-30.6171
-26.7780
-23.5761
-20.8644
-18.5383
-16.5208
-14.7542
-13.1943
-11.8068
-10.5644
-9.4455
-8.4325
-7.5109
-6.6689
-5.8965
-5.1853
-4.5284
-3.9196
-3.3539
-2.8267
-2.3343
-1.8732
-1.4406
-1.0337
-.6504
-.2887
.0534
.3773
.6845
.9763
1.2539
1.5182
1.7703
2.0110
2.2410
2.4612
2.6720
2,8742
3.0682
3.2546
3.4338
3.6062
3.7722
3.9323
4.0866
4.2356
4.3794
4.5185
4.6529
4.7830
4.9090
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
' 4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т
ё
о
1 **
о Д Т
^ И ё
* СО* *
г\) 00 1
^ ? 7 ^
«о "} 1
^00 St
Е 7 ? *
00 1. мн ч©
II .. «О »О
. » 1-» VO
~ /^ ОО Г"»
О ON <Ч
с ™ „
' б ^ п
Й 0 о g
О w
+
«о
а т
8 ё
о 2
+ f
1 х 1 /—
й * й
10604!
Дж-
:боо(
ON il
| 00 К
So V
ON ^
I2 s ?о
•? rJ 2
+ 1 •
VO Н
00 CS
^- <N
II 4*
О
297

Класс точности
VI-G
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
12С0
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙПЛ
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
47.800
47.878
51.223
53.281
54.586
55.449
56.044
56.468
56.781
57.017
57.199
57.343
57.458
57.551
57.628
57.693
57.747
57.792
57.832
57.866
57.895
57.921
57.944
57.964
57.981
57.997
со п 1 1
OO.xf 1 1
58.024
58.036
58.046
58.056
58.064
58.072
58.079
58.086
58.092
58.098
58.103
58.108
58.112
58.116
58.120
58.124
58.127
58.130
58.133
58.136
58.139
58.141
58.144
58.146
58.148
58.150
58.152
58.153
58.155
58.157
58.158
58.159
ОТРИЦАТЕЛЬНЫЙ ИОН
К°(Т)=р(?) -p(F) -p(Cl)-
Ф°(Т)
*-1
Дж • К • моль
235.158
235.402
247.111
256.713
264.899
272.050
278.406
284.130
289.338
294.116
298.529
302.631
306.463
310.057
313.442
316.640
319.672
322.554
325.300
327.922
330.431
332.836
335.146
337.367
339.507
341.571
345.492
347.357
349.165
350.918
352.620
354.273
355.881
357.445
358.969
360.454
361.902
363.314
364.694
366.041
367.358
368.645
369.905
371.138
372.346
373.529
374.688
375.825
376.940
378.034
379.108
380.162
381.198
382.216
383.216
384.199
385.165
386.116
S°(T)
274.543
274.839
289.110
300.780
310.618
319.101
326.547
333.173
339.140
344.563
349.533
354.117
358.371
362.338
366.055
369.551
372.850
375.974
378.939
381.761
384.454
387.028
389.494
391.859
394.133
396.322
OQO AO1
057О.ЧО 1
400.467
402.434
404.338
406.181
407.967
409.701
411.384
413.020
414.612
416.161
417.670
419.142
420.576
421.977
423.344
424.681
425.987.
427.264
428.515
429.739
430.937
432.112
433.263
434.392
435.500
436.587
437.654
438.702
439.731
440.742
441.736
442.714
ФТОРИД-ХЛОРИДА ФОСФОРА PFCP (г)
р(е).р>РСГ) Д
//V)-//°@)
кДж * моль
11.743
11.831
16.800
22.033
27.431
32.936
38.512
44.139
49.802
55.493
61.204
66.931
72.671
78.422
84.181
89.947
95.719
101.496
107.278
113.063
118.851
124.641
130.435
136.230
142.027
147.826
1 **Ч fi97
1 OO.\J?i 1
159.428
165.231
171.036
176.840
182.647
188.453
194.261
200.06J
205.878
211.688
217.498
223.308
229.119
234.931
240.742
246.555
252.367
258.180
263.993
269.807
275.620
281.435
287.249
293.063
298.878
304.693
310.508
316.323
322.138
327.954
333.770
339.586
П°(())= 1033.000 кДж • моль
-171.1525
-170.0219
-124.3958
-96.9265
-78.5554
-65.3936
-55.4938
-47.7724
-41.5784
-36.4972
-32.2518
-28.6503
-25.5556
-22.8667
-20.5081
-18.4219
-16.5630
-14.8957
-13.3915
-15.0273
-10.7841
-9.6463
-8.6008
-7.6366
-6.7444
-5.9162
-5.1453
-4.4258
-3.7526
-3.1213
-2.5279
-1.9690
-1.4417
-.9432
-.4712
-.0235
.4017
.8063
1.1916
1.5591
1.9101
2.2457
2.5669
2.8747
3.1699
3.4533
3.7257
3.9877
4.2400
4.4830
4.7174
4.9435
5.1619
5.3730
5.5771
5.7746
5.9658
6.1510
6.3306
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
г-
«о
to
00
II
~х
r"j
00
т-Ч
О)
О
г»
1Х
со
00
оо
§
о
1
JS
о
г-
+
я
со
со
1
W
ь
Т а б л и
1
1
'§ 1
• й
•=* со
*П 1
о „
«О r-v
1 Ъ4
1°,
О 00
lS ?
0 i л
ей 0
о Си
1
Л
о
1
V
нч
го
00
О
+
X
г*
<У\
1
X
о
4-
ца 227
i
л
к
Т
НИ
k
VO
«О
VO
|>
II
о?
со
о
о
VO
V
V
8
«о
1
о
II
н
298

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПО
ZOUv
2900
3000
3100
3200
3300
3400
3500
3600
3700
<3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
39.247
53.382
63.100
63.246
69.525
73.460
75.990
77.678
78.848
79.687
80.307
80.776
81.139
81.425
81.655
81.842
81.996
82.125
82.233
82.325
82.403
82.471
82.530
82.582
82.627
82.667
82.703
82.735
82.763
82.789
82.812
82.833
82.852
82.869
82.885
82.900
82.913
82.925
82.937
82.947
82.957
82.966
82.974
82.982
82.989
82.996
83.002
83.008
83.014
83.019
83.024
83.029
83.033
83.037
83.041
83.045
83.048
83.052
83.055
83.058
83.061
ДИФТОРИД-ХЛОРИД ФОСФОРА ?F2C1 (г)
К°(Т)=р(?) -р
Ф°(Т)
Дж • К • моль
205.316
231.076
248.428
248.717
262.845
274.815
285.252
294.522
302.866
310.452
317.408
323.830
329,795
335.363
340.583
345.496
350.136
354.532
358.708
362.685
366.482
370.112
373.592
376.932
380.143
383.235
386.216
389.095
391.877
394.570
397.178
399.707
402.161
404.545
406.863
409.118
411.313
413.452
415.537
417.572
419.558
421.497
423.393
425.246
427.059
428.833
430.570
432.272
433.940
435.574
437.178
438.751
440.294
441.810
443.299
444.761
446.198
447.611
449.001
450 366
451.710
2(F) -p(C\)-p
s°<n
-1
239.964
271.710
294.969
295.360
314.485
330.452
344.088
355.937
366.391
375.729
384.158
391.835
398.880
405.386
411.429
417.069
422.357
427.332
432.029
436.477
440.702
444.724
448.562
452.232
455.748
459.121
462,364
465.486
468.496
471.400
474.208
476.923
479.553
482.103
484.577
486.980
489.316
491.588
493.799
495.954
498.054
500.102
502.102
504.054
505.962
507.827
509.652
511.437
513.184
514.896
516.573
518.217
519.830
521.411
522.964
524.488
525.984
527.454
528.898
530.318
531.714
'(PF2G) V/
//°(У)-//°«»
кДж • моль
3.465
8.127
13.876
13.993
20.656
27.820
35.302
42.990
50.820
58.749
66.750
74.806
82.902
91.031
99.185
107.360
115.553
123.759
131.977
140.205
148.441
156.685
164.935
173.191
181.451
189.716
197.985
206.257
214 532
222^809
231.089
239.372
247.656
255.942
264.229
272.519
280.809
289.101
297.394
305.689
313.984
322.280
330.577
338.875
347.173
355.473
363.773
372.073
380.374
388.676
396.978
405.281
413.584
421.887
430.191
438.496
446.800
455-105
463.411
471.716
480.022
Т а б л и ц а 228
э@) = 1320.000 кДж • моль !
\gK°(T)
-675.7726
-329.3413
-214.9861
-213.5474
-155.5372
-120.6810
-97.4180
-80.7875
-68.3060
-58.5927
-50.8184
-44.4551
-39.1506
-34.6609
-30.8116
-27.4747
-24.5544
-21.9772
-19.6859
-17.6356
-15.7899
-14.1198
-12.6013
-11.2147
-9.9434
-8.7736
-7.6936
-6.6934
с 764*»
-О. 1 WrO
-4.8995
-4.0919
-3.3362
-2.6276
-1.9617
-1.3348
-.7435
-.1849
.3438
.8448
1.3204
1.7723
2.2025
2.6123
3.0033
3.3767
3.7337
4.0754
4.4028
4.7166
5.0179
5.3073
5.5855
5.8532
6.1109
6.3593
6.5988
6.8299
7.0530
7.2686
7.4771
7.6787
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
1
Т| к „
к ? Й
Ч vo 2
Я 8 Р L
3 2 > ?
° Т ""¦> И"
'-' ' id
II ON
II «Or-»
^ °л об со
Ь. ON CO
0 С "
ы** г-? С*
^ с со
о Си
'к
00 Л
+1 ^
? i §
On V
о * ь.
' Ц v
С ^ О
*—* + о
ЧО ^
°°. ? Т
'-•со О
^ ' ^
00 Г- "
• СО J\
II 4-
о
299

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5ОО0Г
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
49.161
74.015
S3.003
93.291
105.741
113.582
118.640
122.024
124.374
126.060
127.307
128.252
128.983
129.561
130.024
130.401
130.712
130.971
131.189
131.375
131.534
131.671
131.790
131.895
131.986
132.067
132.139
132.204
132.261
132.313
132.360
132.402
132.440
132.475
132.507
132.537
132.564
132.588
132.611
132.632
132.652
132.670
132.687
132.703
132.718
132.731
132.744
132.756
132.767
132.778
132.788
132.797
132.806
132.815
132.823
132.830
132.837
132.844
132.850
132.856
132.862
ТЕТРАФТОРИД-ХЛОРИД ФОСФОРА PF4C!
К°(Т)г Р(Р) '
Ф°(Л
Дж • К~' • моль"
212.717
243.107
265.314
265.695
284.788
301.546
316.515
330.040
342.366
353.684
364.142
373.857
382.925
391.426
399.425
406.977
414.129
420.920
427.385
433.554
439.451
445.100
450.520
455.730
460.744
465.578
470.243
474.750
479.111
483.333
487.427
491.398
495.255
499.004
502.650
506.199
509.656
513.026
516.313
519.520
522,653
525.713
528.705
531.631
534.494
537.207
540.042
542.732
545.369
547.955
550.491
552.980
555.423
557.822
560.179
562.495
564.771
567.009
569.210
571.375
573.505
/(F) -р(С1
S°(T)
251.668
293.426
326.761
327.337
356.018
о80.532
401.710
420.269
436.725
451.477
464.827
477.007
488.199
498.547
508.166
517.150
525.576
533.508
541.000
548.099
554.841
561.262
567.391
573.251
578.867
584.256
589.437
594.426
599.235
603.877
608.363
612.704
616.908
620.984
624.939
628.781
632.515
636.147
639.684
643.129
646.487
649.762
652.960
656.082
659.133
662.116
665.033
667.888
670.683
673.421
676 103
678.733
681.312
683.842
686.324
688.762
691.155
693.506
695.817
698.088
700.321
) • p-\j>FAC$
//V')-//°@)
кДж • моль
3.895
10.064
18.320
18.493
28.492
39.488
51.117
63.161
75.487
88.014
100.685
113.465
126.328
139.256
152.236
165.258
178.314
191.399
204.507
217.636
230.781
243.942
257.115
270.299
283.493
296.696
309.906
323.124
336.347
349.576
362.809
376.048
389.290
402.536
415.785
429.037
442.292
455.549
468.809
482.072
495.336
508.602
521.870
535.140
548.411
561.683
574.957
588.232
601.508
614.785
628.064
641.343
654.623
667.904
681.186
694.469
707.752
721.036
734.321
747.606
760.892
(г)
Д г//°@) =2100.000 кДж
lgA'°(r)"
-1071.7258
-520.2965
-338.2301
-335.9394
-243.5763
-188.0842
-151.0566
-124.5926
104.7369
-89.2900
-76.9310
-66.8186
-58.3919
-51.2621
-45.1516
-39.8566
-35.2244
-3J.1379
-27.5063
-24.2577
-21.3347
-18.6907
-16.2877
-14.0942
-12.0840
-10.2351
-8.5289
-6.9494
-5.4831
-4.1182
-2.8446
-1.6535
-.5369
.5117
1.4985
2.4288
3.3073
4.1381
4.9252
5.6718
6.3810
7.0556
7,6980
8.3104
8.8951
9.4537
9.9880
10.4996
10.9898
11.4601
11.9115
12.3453
12.7624
13.1637
13.5503
13.9227
14.2819
14.6285
14.9632
15.2865
15.5991
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 229
• моль *
Т
л
V 2
1 к
й * §
г- S
S ^ ? L
3 7 ? ?
II «J ^
* ° 8 5
Чг с- "„
Ь* С о?
°^ -
< %
+
so Т
? Й
со |
+
* "С
« * g
I a I
О ^ V /
Ш $ V
а• « v
« + §
2"х 8
О 00 |
СО -уГ О
+ • •
оо X Ь*
о »о
v© 00 1!
Сл ГО
со О w
II +*
300

Класс том
VI
т
к
100
200
298.15
300
100
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
55Q0
5600
5700
5800
5900
6000
ности
р
42.465
58.160
67.434
67.563
72.888
76.010
77.943
79.204
80.065
80.676
81.125
81.462
81.722
81.927
82.091
82.224
82.333
82.424
82.501
82.566
82.622
82.670
82.712
82.748
82.780
82.809
82.834
82.856
82.876
82.894
82.911
82.925
82.939
82.951
82.962
82.972
82.982
82 990
82.998
83.006
83.012
83.019
83.025
83.030
83.035
83.040
83.045
83.049
83.053
83.056
83.060
83.063
83.066
83.069
83.072
83.074
83.077
83.079
83.081
83.084
83.086
ФТОРИД-ДИХЛОРИД ФОСФОРА PFC12 (г)
*em=p(D-p<F
Ф°(Т)
Дж • К~ • моль"
212.304
239.375
257.940
258.249
273.361
286.094
297.128
306.871
315.596
323.497
330.716
337.361
343.516
349.249
354.613
359.653
364.407
368.904
373.170
377.229
381.099
384.798
388.339
391.736
395.000
398.140
401.167
404.088
406.909
409.638
412.280
414.841
417.326
419.738
422.083
424.363
426.582
428.744
430.851
432.906
434.912
436.870
438.783
440.653
442.483
444.272
446.024
447.740
449.421
451.069
452.685
454.270
455.826
457.353
458.652
460.325
461.772
463.195
464.593
465.968
467.322
) V(C1)
s\n
248.065
282.684
307.806
308.224
328.460
345.089
359.132
371.248
381.884
391.352
399.876
407.625
414.724
421.274
427.352
433.020
438.330
443.324
448.038
452.500
456.737
460.769
464.616
468.294
471.816
475.196
478.444
481.571
484.584
487.493
490.303
493.022
495.655
498.208
500.684
503.089
505.427
507.700
509.914
512.070
514.171
516.221
518.222
520.176
522.084
523.951
525.776
527.562
529.310
531.023
532.701
534.346
535.958
537.541
539.094
540.618
542.115
543.585
545.030
546.450
547.847
p-^PFCL,) ArH
//°G')—//°@)
кДж • моль
3.576
8.662
14.868
14.992
22.040
29.498
37.202
45.064
53.030
61.069
69.160
77.290
85.450
93.633
101.834
110.050
118.278
126.516
134.762
143.016
151.275
159.540
167.809
176.082
184.358
192.638
200.920
209.204
217.491
225.780
234.070
242.362
250.655
258.949
267.245
275.542
283.839
292.138
300.437
308.738
317.039
325.340
333.642
341,945
350.248
358.552
366.856
375.161
383.466
391.771
400.077
408.384
416.690
424.997
433.304
441.611
449.919
458.227
466.534
474.843
483.151
°@) - 1140.000
-581.7106
-282.3691
-183.5685
-182.3256
-132.2139
•102.1058
-82.0118
-67.6461
-56.8636
-48.4720
-41.7550
-36.2567
-31.6729
-27.7930
-24.4662
-21.5822
-19.0581
-16.8304
-14.8498
-13.0774
-11.4819
-10.0380
-8.7252
-7.5263
-6.4271
-5.4157
-4.4818
-3.6169
-2.8136
-2.0655
-1.3671
-.7135
-.1006
.4754
1.0177
1.5292
2.0125
2.4699
2.9034
3.3149
3.7061
4.0783
4.4331
4.7715
5.0948
5.4038
5.6997
5.9831
6.2550
6.5159
6.7665
7.0075
7.2394
7.4628
7.6780
7.8856
8.0859
8.2793
8.4662
8.6469
8.8217
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
см
00
с-»
оо
о
см
II
00
со
см
т—1
со
00
«о
00
о
о
1
г-
со
оо
см
°)
о
«о
II
Таблица 230
§ ?
• d т
* g §
см .
см см
°) *-< V
С"** *^ о
о 1 «
•О и *
II ^ "
/-N ^ 00
об ^
** см *•
"с* и "
Р « п
О w
ч^ о
§
*п V
° V
+ 8
Г) (О
X
^ о
7 ?
X
СО II
ЧО
V?> Н
^ w
см
301

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
50.111
78.103
97.347
97.625
109.277
116.318
120.757
123.688
125.706
127.146
128.206
129.008
129.627
130.114
130.505
130.823
131.085
131.303
131.486
131.642
131.776
131.891
131.991
132.079
132.156
132.224
132.284
132.338
132 386
132.430
132.469
132.504
132.536
132.566
132.593
132.617
132.640
132.660
132.680
132.697
132.714
132.729
132.743
132.756
132.769
132.780
132.791
132.801
132.810
132.819
132.828
132.835
132.843
132.850
132.856
132.863
132.869
132.874
132.880
132.885
132.890
ТРИФТОРИД-ДИХЛОРИД ФОСФОРА PF3 Cl 2
К°(Т)=р(?).рЪA
Ф°(Т)
Дж • К~' • моль
217.545
248.448
271.447
271.843
291.702
309.101
324.591
338.538
351.212
562.819
373.520
383.442
392.689
401.345
409.481
417.153
424.412
431.299
437.850
444.096
450.064
455.778
461.258
466.522
471.587
476.467
481.175
485.723
490.121
494.379
498.505
502.508
506.393
510.169
513.841
517.415
520.895
524.287
527.595
530 822
533.974
537.052
540.061
543.004
545.883
548.701
551.460
554.164
556.814
559.412
561.961
564.461
566.916
569.326
571.693
574.019
576.305
578.553
580.763
582.937
585.076
Ween.,"
256.732
300.247
335.330
335.933
365.758
390.962
412.591
431.441
448.097
462.991
476.444
488.703
499.956
510.352
520.009
529.024
537.476
545.429
552.940
560.053
566.809
573.241
579.379
585.248
590.871
596.268
601.455
606.448
611.262
615.908
620.398
624.743
628.950
633.029
636.987
640.831
644.567
648.201
651.739
655.186
658.546
661.823
665.022
668.145
671.197
674.181
677.100
679.956
682.752
685.490
688.174
690.804
693.384
695.914
698.397
700.835
703.229
705.581
707.892
710.164
712.397
"(PF3C12)
кДж • моль
3.919
10.360
19.047
19.227
29.622
40.930
52.800
65.032
77.508
90.154
102.925
115.787
128.720
141.708
154.740
167.807
180.902
194.022
207.162
220.318
233.489
246.673
259.867
273.070
286.282
299.501
312.727
325.958
339Л94
352.435
365.680
378.929
392.181
405.436
418.694
431.954
445.217
458.482
471.749
485.018
498.288
511.561
524.834
538.109
551.385
564.663
577.942
591.221
604.502
617.783
631.065
644.348
657.632
670.917
684.203
697.488
710.775
724.062
737.350
750.638
763.927
Аг//°@) =
-967.1042
-467.9464
-303.1320
-301.0586
-217.4531
-167.2252
-133.7107
-109.7577
-91.7858
-77.8043
-66.6176
-57.4644
-49.8369
-43.3834
-37.8524
-33.0597
-28.8669
-25.1681
-21.8811
-18.9407
-16.2951
-13.9021
-11.7273
-9.7421
-7.9228
-6.2495
-4.7054
-3.2760
-1.9491
-.7139
.4386
1.5165
2.5268
3.4757
4.3687
5.2104
6.0053
6.7571
7.4693
8.1448
8.7865
9.3969
9.9781
10.5323
11.0613
11.5667
12.0502
L2.5131
12.9567
13.3822
•13.7906
14.1831
14.5605
14.9237
15.2734
15.6104
15.9354
16.2491
16.5519
16.8445
17.1273
(г)
1900.000 кДж
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 231
• моль"
о
«о
г-
00
об
1О
II
+
X
00
го
+
'х
00
ЧО
О\
о
о
g
с
t—I
rj-
О
rH
ГО
го
чо
с-
00
Tf
чо
о
i
л
к
о
т
§ и
i, g
ж о
И <Ч
сч ?|
Г- ,__,
"! 7
2 и
7 ^
п 2
/-s 00
о" .>
го • (J
О ч*>
^ о
i
л
^'
i
•
го
X
го
00
+
™х
CN
го
ЧО
1
ё
о
ГО
4-
т
го
WO
«л
II
п
О 05
со
Я
о
ЧО
V
V
§
«о
1
о
II
302

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
f)Q(\f\
zoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<т)
53.369
83.401
102.181
102.442
113.080
119.235
123.009
125.457
127.122
128.301
129.163
129.81
1
130.311
130.703
131.017
131.272
131.481
131.656
131.802
131.927
132.033
132.125
132.205
132.275
132.336
132.390
132.438
132.481
1 49 *\ 1 Q
1 OZ.O 1 а
132.554
132.585
132.613
132.639
132.662
132.683
132.703
132.721
132.737
132.752
132.766
132.779
132.791
132.803
132.813
132.823
132.832
132.840
132.848
132.856
132.863
132.870
132.876
132.882
132.887
132.893
132.898
132.902
132.907
132.911
132.915
132.919
ДИФТОРИД-ТРИХЛОРИД ФОСФОРА PF2C13
А*°(Г)=р(Р).р2
Ф°(Л
Дж -K~l • моль"
213.617
246.080
270.453
270.872
291.840
310.099
326.262
340.744
353.852
365.816
376.815
386.990
396.455
405.299
413.598
421.416
428.803
435.805
442.460
448.800
454.853
460.644
466.194
471.524
476.649
481.584
486.344
490.940
AQKQft^
499.682
503.848
507.887
511.807
515.616
519.319
522.921
526.429
529.847
533.179
536.430
539.604
542.704
545.733
548.695
551.593
554.429
557.205
559.925
562.591
565.204
567.767
570.282
572.750
575.173
577.553
579.891
582.188
584.447
586.668
588.852
591.001
(F).p3(Cl)V<
S°(T)
-l
254.314
300.934
338.086
338.719
369.792
395.745
417.844
437.003
453,871
468.915
482.480
494.822
506.140
516.586
526.284
535.332
543.812
551.788
559.317
566.447
573.217
579.661
585.809
591.687
597.318
602.722
607.915
612.914
617 733
622.384
626.878
631.226
635.437
639.518
643.479
647.326
651.064
654.701
658.241
661.689
665.051
668.330
671.530
674.655
677.708
680.693
683.613
686:470
689.267
692.006
694.691
697.322
699.902
702.433
704.917
707.356
709.750
712.103
714.414
716.686
718.920
PF2C13) Д,//
//°(Л-//°(())
кДж • моль
4.070
10.971
20.165
20.354
31.181
42.823
54.949
67.381
80.015
92.789
105.665
118.615
131.622
144.674
157.760
170.875
184.013
197.170
210.343
223.530
236.728
249.936
263.152
276.376
289.607
302.843
316.085
329.331
ол.9 ^ft 1
355.834
369.092
382.351
395.614
408.879
422.146
435.416
448.687
461.960
475.234
488.510
501.787
515.066
528.346
541.626
554.908
568.191
581.475
594.759
608.044
621.330
634.617
647.904
661.192
674.480
687.769
701.059
714.349
727.639
740.930
754.222
767.513
(г)
°@) = 1700.000 к Дж-моль
lgtfV)
-862.0253
-415.1938
-267.6618
-265.8058
-190.9758
-146.0236
-116.0303
-94.5941
-78.5106
-65.9980
-55.9865
-47.7949
-40.9686
-35.1930
-30.2432
-25.9540
-22.2017
-18.8916
-15.9500
-13.3188
-10.9513
-8.8099
-6.8638
-5.0875
-3.4596
-1.9624
-.5808
.6980
1.8853
2.9903
4.0214
4.9857
5.8896
6.7385
7.5373
8.2903
9.0014
9.6739
10.3110
10.9153
11.4893
12.0353
12.5552
13.0509
13.5241
13.9762
14.4087
14.8227
15.2195
15.6001
15 9655
16.3166
16.6542
16.9791
17.2919
17.5934
17.8842
18.1647
18.4356
18.6974
18.9504
Г
к
100
200
- 298.15
300
400
500
600
700
800
900
1000
1100
1200 "
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
чо
ст^
<N
СО
«О
(^»
II
и
1/
Г а б л
Т
л
v;
р^
<N
О
г-
00
1
II
о
с
го
и
1 -1
См
О
* с
<
•)
со „
СО 1
о
<* л
с
^ о
+ 5
1 у. ^
ЧО Я
я *
о Ч*
>
о
Ч?
чо
s °°.
«—• о>
СО CN
г L
о г*-'
чо ^о
чо
00
ЧО ^"
1
о
•€
4-
"г
И
л
о
г.
с*
г^
г-»
00
00
г-
00
1
II
я
00
О
CN
CJ
с
)
ца 232
т
с?
о
ч>
ИИ
k
f~
чо
чо
О 05
>» Со
я
о
g
чо
V
V
о
о
«о
^-
1
о
II
н
303

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
Oftftfl
ZOUv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(т)
58.906
90.834
107.848
108.074
117.095
122.142
125.178
127.124
128.437
129.362
130.035
130.541
130.929
131.234
131.477
131.674
131.836
131.971
132.084
132.180
132.262
132.333
132.395
132.448
132.496
132.537
132.574
132.607
132.637
132*664
132.688
132.709
132.729
132.747
132.763
132.778
132.792
132.805
132.816
132.827
132.837
132.847
132.855
132.863
132.871
132.878
132.884
132.891
132.896
132.902
132.907
132.912
132.916
132.920
132.924
132.928
132.932
132.935
132.939
132.942
132.945
ФТОРИД-ТЕТРАХЛОРИД ФОСФОРА PFC14
К°(Т) = рФ)-Р(*
Ф°(Г)
Дж-К моль
223.828
258.617
284.993
285.444
307.920
327.291
344.295
359.431
373.059
385.446
396.796
407.267
416.982
426.043
434.531
442.514
450.048
457.181
463.952
470.398
476.547
482.425
488.055 .
493.458
498.650
503.648 *
508.465
513.115
517.608
521*954
526.163
530.243
534.202
538.047
541.784
545.419
548.957
552.404
555.764
559.041
562.240
565.364
568.415
571.399
574.317
577.172
579.968
582.706
585.389
588.019
590.598
593.128
595.611
598.048
600.442
601793
605.104
607.375
609.608
611.804
613.964
1 V(cn
S°(T)
266.545
318.080
357.887
358.555
391.014
417.736
440.295
459.748
476.814
491.998
505.664
518.083
529.459
539.951
549.686
558.764
567.267
575.264
582.810
589.955
596.736
603.191
609.349
615.235
620.873
626.283
631.482
636.486
641.309
645.964
650.462
654.813
659.027
663.111
667.074
670.923
674.664
678.302
681.844
685.294
688.657
691.937
695.139
698.265
701.320
704.306
707.226
710.084
712.882
715.622
718.308
720.939
723.520
726.052
728.537
730.976
733.371
735.724
738.036
740.308
742.543
p~l(?FCl4) ArI/
//°G>-//o(())
кДж * моль
4.272
11.893
21.733
21.933
33.238
45.222
57.600
70.222
83.004
95.897
108.868
121.898
134.972
148.081
161.217
174.375
187.551
200.741
213.944
227.157
240.380
253.609
266.846
280.088
293.335
306.587
319.843
333.102
ЧАЛ ЧЛА
359.629
372.897
386.166
399.438
412.712
425.988
439.265
452.543
465.823
479.104
492.386
505.670
518.954
532.239
545.525
558.812
572.099
585.387
598.676
611.965
625.255
638.546
651.837
665.128
678.420
691.712
705.004
718.298
731.591
744.885
7.58.179
771.473
(г)
D@) = 1511.000 кДж • моль
lgK°(T)
-757.6853
-363.2197
-233.0032
-231.3653
-165.3315
-125.6679
-99.2046
-80.2914
-66.1007
-55.0605
-46.2270
-38.9991
-32.9759
-27.8797
-23.5122
-19.7276
-16.4168
-13.4962
-10.9008
-8.5793
-6.4905
-4.6013
-2.8844
-1.3173
.1187
1.4395
2.6582
3.7863
A W\V\
ttOOOO
5.8082
6.7177
7.5682
8.3654
9.1141
9.8186
10.4827
11.1098
11.7029
12.2647
12.797*
13.3038
13.7853
14.2438
14.6809
15.0982
15.4969
15.8783
16.2434
16.5933
16.9290
17.2512
17.5608
17.8585
18.1450
18.4209
18.6868
18.9432
19.1906
19.4296
19.6604
19.8836
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
,7842
т—|
О\
ч—(
II
+
00
1
С4!
СО
1-4
1
3
с*
щ
СО
+
;.ооз(
Г^
VD
II
с
Таб ли ца 233
Т
§
*
Й
<N
00
vo
о^
со
1
II
о
i
О
<
1
Л
i
им
k
<•>
«и
<ч
+
со
О
°9
г^
1
X
«о
со
+
1
л
§
*
к
8
VO
г
и
я
«о
«—i
00
ГЦ
С
_>
2
ь
0
1
i
V
k
VO
s
VO
to
2
О
§
О
VO
V
500 -
...
i
о
9
и
X
304

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯЛП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
39.081
58.995
73.064
73.278
82.762
89 Л 83
93.613
96.740
99.000
100.670
101.934
102.909
103.674
104.285
104.780
105.185
105.521
105.803
106.041
106.244
106.419
106.570
106.701
106.817
106.918
107.008
107.088
107-160
107.224
107.282
107.334
107.381
107.424
107.463
107.499
107.532
107.562
107.590
107.615
107.639
107.661
107.682
107.701
107.718
107.735
107.750
107.764
107.778
107.791
107.803
107.814
107.824
107.834
107.844
107.853
107.861
107.869
107.877
107.884
107.891
107.897
ОКСИД-ДИФТОРИД-ХЛОРИД
К°(Т)=р(?)-р(О)
Ф°(Т)
Дж К - моль" *
210.728
236.652
254.900
255.209
270.622
284.022
295.937
306.682
316.471
325.463
333.776
341.506
348.728
355.504
361.885
367.915
373.630
379.060
384.234
389Л72
393.897
398.425
402.772
406.952
410.978
414.860
418.607
422.230
425.736
429Л32
432.424
435.620
438.725
441.743
444.679
447.538
450.323
453.039
455.688
458.274
460.800
463.268
465.681
468.042
470.352
472.614
474.829
477.000
479.129
481.216
483.264
485.274
487.248
489 Л 85
491.089
492.960
494.800
496.608
498.387
500.136
501.859
V(F)
S°(T)
245.170
278.492
304.861
305.314
327.784
346.987
363.663
378.342
391.415
403.176
413.852
423.614
432.603
440.926
448.673
455.917
462.716
469.122
475.176
480.916
486.370
491.566
496.526
501.272
505.820
510.187
514.385
518.428
522.327
526.090
529.728
533.248
536.658
539.964
543.173
546.290
549.320
552.267
555.136
557.932
560.658
563.316
565.911
568.446
570.922
573.344
575.712
578.030
580.299
582.522
584.700
586.835
588.929
590.983
592.999
594.978
596.921
598.831
600.707
602.551
604.365
p(Cl)p(POF2
//°(П-//°
ФОСФОРА POF2
Cl) 'Д#°@) =
@)
кДж * моль
3.444
8.368
14.896
15.031
22.865
31.482
40.636
50.162
59.955
69.942
80.075
90.32Q
100.650
111.049
121.503
132.002
142.538
153.105
163.697
174.312
184.945
195.595
206.258
216.934
227.621
238318
249.023
259.735
07П АЧА.
ZlXj.'tO't
281.180
291.910
302.646
313.386
324.131
334.879
345.631
356.385
367.143
377.903
388.666
399.431
410.198
420.967
431.738
442.511
453.285
464.061
474.838
485.616
496.396
507.177
517.959
528.742
539.526
550.310
561.096
571.883
582.670
593.458
604.247
615.036
-947.4750
-461.5571
-301.1230
-299.1045
-217.7106
-168.8018
-136.1606
-112.8268
-95.3159
-81.6902
-70.7861
-61.8623
-54.4246
-48.1303
-42.7348
-38.0585
-33.9668
-30.3564
-27.1473
-24.2761
-21.6922
-19.3546
-17.2296
-15.2895
-13.5112
-11.8753
-10.3653
-8.9673
7 fifiQI
- / .QO<7 1
-6.4605
-5.3326
-4.2774
-3.2881
-2.3588
-1.4841
-.6594
.1196
.8566
1.5548
2.2173
2.8468
3.4457
4.0161
4.5601
5.0795
5.5760
6.0509
6.5058
6.9418
7.3601
7.7618
8.1479
8.5193
8.8767
9.2210
9.5529
9.8731
10.1822
10.4806
10.7691
11.0481
Cl (r)
1851.000 к Дж
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
полл
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб л
• моль
о
со
СМ
©
см
II
+
1
СО
см
O^
см
+
с-
СМ
см
о
1
X
V©
см
ON
V©
со
о
+
V©
см
Os
со
со
ю
II
с
о
о
?*
V
ни
•^-
СО
^>
О
7
и
о
(POP
о
1
§
I
1
*-<
X
V©
V©
см
S©
+
X
V©
1
X
см
00
г*»
^©
V©
4-
и ца 234
о
к
уу ^н
1
S §
о „•
т '*
II
2 п
об *П
^ СО
см со
fj4 II
0 п
с» о о?
И, со
8
)
*
Я
О
g
V©
V
V
о
о
«о
i
о
II
><
Уг20
872
305

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
44.755
66.347
79.232
79.419
87.500
92.800
96.410
98.942
100.767
102.115
103.134
103.919
104.536
405.027
105.425
105.752
106.022
106.249
106.441
106.604
106.745
106.866
106.972
107.065
107.147
107.219
107.284
107.341
107.393
107.439
107.481
107.519
107.554
107.585
107.614
107.640
107.665
107.687
107.708
107.727
107.744
107.761
107.776
107.790
107.804
107.816
107.828
107.838
107.849
107.858
107.867
107.876
107.884
107.891
107.899
107.905
107.912
107.918
107.924
107.929
107.934
ОКСИД-ФТОРИД-ДИХЛОРИД ФОСФОРА POFC12 (г)
К°(Т)=р(Р)р(О)
Ф°(Т)
Дж • К - моль" *
216.785
244.919
265.123
265.465
282.399
296.956
309.765
321.217
331.576
341.036
349.740
357.800
365.305
372.327
378.922
385.141
391.023
396.604
401.911
406.972
411.807
416.436
420.875
425.140
429.243
433.197
437.011
440.696
444.260
447.710
451.054
454.298
457.447
460.507
463.484
466.380
469.201
471.951
474.632
477.248
479.803
482.299
484.738
487.124
489.458
491.744
493.981
496.174
498.322
500.430
502.496
504.524
506.515
508.470
510.390
512.276
514.131
515.953
517.746
519.510
521.245
•p(F).p'(C.).
s\n
253.044
291.201
320.310
320.800
344.840
364.974
382.233
397.296
410.633
422.583
433.397
443.266
452.335
460.723
468.521
475.806
482.640
489.075
495.153
500.913
506.384
511.596
516.569
521.327
525.885
530.260
534.467
538.517
542.422
546.191
549.834
553.359
556.773
560.083
563.295
566.415
569.448
572.398
575.270
578.068
580.796
583.457
586.054
588.590
591.068
593.491
595.860
598.180
600.450
602.674
604.853
606.989
609.084
611.139
613.156
615.136
617.080
618.990
620.867
622.712
624.526
р 1(РО?С\2)
//°G')—//°@)
кДж • моль
3.626
9.256
16.454
16.601
24.976
34.009
43.481
53.255
63.246
73.393
83.658
94.012
104.436
114.915
125.438
135.998
146.587
157.201
167.835
178.488
189.155
199.836
210.528
221.230
231.941
242.659
253.384
264.115
274.852
285.594
, 296.340
307.090
317.843
328.600
339.360
350.123
360.888
371.656
382.426
393.197
403.971
414.746
425.523
436.301
447.081
457.862
468.644
479.428
490.212
500.997
511.734
522.571
533.359
544.148
554.937
565.727
576.518
587.310
598.102
608.894
619.687
v°ro> ¦
-850.7528
-413.2774
-268.8666
-267.0499
-193.8002
-149.7908
-120.4211
-99.4265
-83.6711
-71.4114
-61.6002
-53.5708
-46.8784
-41.2149
-36.3600
-32.1522
-28.4704
-25.2217
-22.3344
-19.7506
-17.4255
-15.3221
-13.4100
-11.6642
-10.0641
-8.5921
1 -7.2334
-5.9755
-4.8074
-3^7199
-2.7049
-1.7555
-.8653
-.0291
.7580
1.5001
2.2011
2.8642
3.4925
4.0887
4.6552
5.1941
5.7075
6.1971
6.6645
7.1113
7.5388
7.9482
8.3406
8.7172
9.0788
9.4263
9.7606
10.0824
10.3924
10.6912
10.9795
П.2577
11.5265
11.7863
12.0375
1666.000 к Дж
/
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
•1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400-
5500
5600
5700
5800
5900
6000
• моль
Г"—
оо
го
II
+
го
+
V
00
р
го
о
1
+
о
го
vq
v2
ю
1
Таблиц
-1
Т
Т s
<? го
^2 *-
00 "
^ 2
II to
О об
>-* оч
0 -
5 С*
ow 2
1
§
ми
ГО
к
«о
+
Г>1
*0
ZH
1
X
,-н
го
а 235
1
А
§
2
1
у
мч
?^
гч
О)
го
о g
со
о
V
\/
V
1
1
о
II
306

Класс точности
Н-К
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200 '
2300
2400
2500
2600
2700
9800
aOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.838
33.960
35.242
35.259
36.002
36.469
36.779
36.995
37.154
37.277 •
37.376
37.458
37.529
37.592
37.649
37.701
37.751
37.798
37.844
37.889
37.933
37.977
38.023
38.069
38.117
38.168
38.223
38.281
38.344
38.413
38.488
38.570
38.661
38.759
38.867
38.984
39.111
39.249
39.397
39.556
39.725
39.905
40.096
40.297
40.508
40.728
40.958
41.196
41.442
41.695
41.955
42.221
42.492
42.768
43.047
43.329
43.612
43.897
44.183
44.468
44.751
Л'°(Л = р(Р) -p(S
<1Лл
Дж • К • моль
168.141
189.063
201.703
201.903
211.309
218.770
224.967
230.273
234.915
239.042
242.760
246.141
249.244
252.109
254.772
257.260
259.593
261.792
263.869
265.839
267.711
269.495
271.199
272.831
274.395
275.898
277.344
278.737
980 081
ZOU.UO 1
281.380
282.637
283.853
285.033
286.178
287.290
288.371
289.423
290.447
291.446
292.420
293.370
294.299
295.206
296.093
296.962
297.812
298.645
299.461
300.262
301.047
301.819
302.576
303.320
304.052
304.771
305.479
306.175
306.861
307.536
308.202
308.857
СУЛЬФИД
)V<ps)
j
197.625
220.130
233.956
234.174
244.428
252.515
259.193
264.880
269.831
274.214
278.147
281.713
284.976
287.982
290.770
293.370
295.804
298.094
300.256
302.303
304.248
306.100
307.868
309.559
311.180
312.737
314.235
315.679
317.072
318.419
319.722
320.985
322.212
323.403
324.561
325.690
326.789
327.863
328.912
329.937
330.941
331.924
332.888
333.833
334.762
335.675
336.573
337.456
338.326
339.183
340.028
340.861
341.684
342.496 -
343.298
344.091
344.874
345.648
346.414
347.172
347.922
ФОСФОРА PS (г)
V
/V>-//°<0)
кДж • моль
2.948
6.213
9.616
9.681
13.247
16.873
20.536
24.225
27.933
31.655
35.388
39". 129
42.879
46.635
50.397
54.165
57.937
61.715
65.497
69.283
73.074
76.870
80.670
84.475
88.284
92.098
95.918
99.743
1 04 ^74
107.412
111.257
115.110
118.971
122.842
126.723
130.616
134.520
138:438
142.371
146.318
150.282
154.264
158.263
162.283
166.323
170.385
174.469
178.577
182.708
186.865
191.048
195.256
199.492
203.755
208.046
212.364
216.712
221.087
225.491
229.924
234.384
"@) = 440.000
-225.9979
-110.6558
-72.5937
-72.1149
-52.8033
-41.1951
-33.4438
-27.8992
-23.7353
-20.4927
-17.8957
-15.7685
-13.9940
-12.4909
-11.2013
-10.0826
-9.1027
-8.2373
-7.4673
-6.7777
-6.1565
-5.5939
-5.0818
-4.6138
-4.1844
-3.7888
-3.4232
-3.0843
-2.7691
-2.4753
-2.2007
-1.9434
-1.7017
-1.4744
-1.2601
-1.0576
-.8660
-.6845
-.5121
-.3483
-.1923
-.0437
.0982
.2337
.3634
.4876
.6067
.7209
.8306
.9361
1.0375
1.1352
1.2294
1.3201
1.4077
1.4923
1.5740
1.6530
1.7294
1.8034
1.8750
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400 •
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
—
1 j
с;
о
к
п
2 ОС
со со
О
II ^
^ II
О
и
t
о
Г- 1
тг -а
r-i п;
г-; о
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ОС
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<=> ?
JS "*
ОС ^
го 2
Г^ О
^ со'
со ~
чО rv,
СО ^
II +
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W
блиц
о
•-ч
СМ
О4,
о
II
ОС
и
со
Си
о
а 236
—
О
—
и:
оо
II
о х
со
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о
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V
V
1
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II
307

Класс точности
I-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1.300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.105
29.164
29.691
29.706
30.773
31.949
32.991
33.841
34.514
35.047
. 35.470
35.811
36.088
36.318
36.510
36.673
36.813
36.935
37.042
37.137
37.223
37.301
37.372
37.437
37.498
37.556
37.610
37.661
37.710
37.758
37.804
37.849
37.894
37.939
37.984
38.031
38.078
38.127
38.178
38.232
38.290
38.351
38.416
38.487
38.562
38.644
38.732
38.828
38.930
39.041
39.161
39.289
39.426
39.573
39.730
39.897
40.075
40.263
40.462
40.671
40.892
К°(Т)= р(?) рО
Ф°(Л
Дж К • моль" 1
150.048
170.206
181.836
182.016
190.445
197.055
202.532
207.233
211.364
215.057
218.402
221.461
224.283
226.901
229.346
231.638
233.797
235.837
237.771
239.610
241.363
243.038
244.641
246.178
247.656
249.077
250.448
251.770
253.047
254.283
255.480
256.640
257.766
258.860
259.923
260.957
261.964
262.945
263.902
264.836
265.747
266.637
267.507
268.358
269.190
270.005
270.803
271.586
272.352
273.104
•273.842
274.567
275.278
275.976
276.663
277.338
278.002
278.655
279.298
279.931
280.554
НИТРИД
О /ГЧрм)
S°iT)
179.119
199.301
211.022
211.206
219.890
226.885
232.804
237.956
242.521
246.618
250.333
253.731
256.859
259.756
262.455
264.980
267.351
269.587
271.701
273.706
275.613
277.432
279.168
280.831
282.426
283.958
285.432
286.852
288.223
289.547 '
290.828
292.068
293.270
294.437
295.570
296.672
297.744
298.788
299.806
300.798
301.767
302.713
303.638
304.542
305.428
306.296
307.146
307.980
308.799
309.602
310.392
311.169
311.933
312.685
313.427
314.157
314.878
315.588
316.291
316.984
317.669
ФОСФОРА
//°ГП-//°«))
кДж • моль
2.907
5819
8.702
8.757
11.778
14.915
18.163
21.507
24.926
28.405
31.931
35.496
39.091
42.712
46.354
50.013
53.688
57.375
61.074
64.783
68.501
72.227
75.961
79.702
83.448
87.201
90.959
94.723
98.492
102.265
106.043
109.826
113.613
117.405
121.201
125.001
128.807
132.617
136.432
140.253
144.079
147.911
151.749
155.594
159.447
163.307
167.176
171.054
174.941
178.840
182.750
186.672
190.608
194.558
198.523
202.504
206.503
210.520
214.556
218.612
222.690
PN (г)
//°Г0) - 614.000
lgA'V)
-316.5771
-155.7668
-102.7179
-102.0505
-75.1397
-58.9646
-48.1643
-40.4390
-34.6377
-30.1205
-26.5029
-23.5401
-21.0689
-18.9760
-17.1805
-15.6232
-14.2595
-13.0553
-11.9841
-11.0249
-10.1609
-9.3787
-8.6671
-8.0168
-7.4202
-6.8709
-6.3634
-5.8931
-5.4560
-5.0487
-4.6681
-4.3117
-3.9772
-3.6626
-3.3662
-3.0864
-2.8217
-2.5710
-2.3332
-2.1072
-1.8922
-1.6874
-1.4920
-1.3053
-1.1269
-.9560
-.7923
-.6352
-.4844
-.3395
-.2001
-.0659
.0635
.1882
.3085
.4247
.5370
.6457
.7508
.8525
.9511
кДж • моль
/'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
>
ЧО
О
СО
Os
II
+
со
го
"^
о
гм
'х
го
со
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о
о
О
I
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+
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CN
II
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1 а б л и
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ГО
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308

ДОПОЛНЕНИЕ
Таблица Д. 1
Таблица Д. 2
ОРТОВОДОРОД о-Н2 (г)
М =2,0158
ПАГаВОДОРОД л-Н2 (г)
ЛГ = 2,0158
т
к
10
20
30
40
50
60
70
80
90
100
ПО
120
130
140
150
160 .
170
180
190
200
250
298,15
300
400
500
600
700
800
900
1000
Ср°(Т)
Дж
20,786
20,786
20,786
20,786
20,786
20,789
20,802-
20,842
20,929
21,082
21,314
21,625
22,011
22,460
22,955
23,479
24,016
24,549
25,066
25,558
27,468
28,460
28,485
29,130
29,253
29,326
29,440
29,623
29,880
30,204
•К моль"*1
-97,360
-12,072
19,982
37,775
49,502
58,017
64,596
69,904
74,322
78,090
81,364
84,255
86,839
89,176
91,308
93,269
95,086
96,779
98,366
99,861
106,276
111,294
111,470
119,670
126,060
131,302
135,747
139,609
143,025
146,090
65,186
79 594
#8,022
94,001
98,640
102,430
105,635
108,415
110,874
113,087
.115,106
116,973
118,719
120,366
121,933
123,431
124,870
126,258
127,599
128,898
134,824
139,757
139,933
148,242
154,759
160,098
164,627
168,569
172,072
175,237
Н°(Т)-Н°@)
кДж • моль
1,625
1,833
2,041
2,249
2,457
2,665
2,873
3,081
3,290
3,500
3,712
3,926
4,144
4,367
4,594
4,826
5,063
5,306
5,554
5,807
7,137
8,486
8,539
11,429
14,349
17,278
20,216
23,168
26,143
29,147
Т
К
10
20
30
40
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
250
298,15
300
400
500
600
700
800
900
1000
Дж«
20,786
20,786
20,786
20,805
20,947
21,396
22,289
23,617
25,251
26,997
28,672
30,131
31,294
32,132
32,664
32,930
32,984
32,882
32,671
32,395
30.883
29,952
29,928
29,334
29,279
29,329
29,440
29,623
29,880
30,204
Ф°(Т)
S°(T)
К" моль
26,132 46,918
40,540 61,325
48,967 69,753
54,947 75,735
59,587 80,389
63,384 84,241
66,608 87,601
69,425 90,659
71,946 93,533
74,243 96,284
76,368 98,937
78,356 101,496
80,231 103,956
82,010 106,308
83,705 108,544
85,325 110,662
86,875 112,661
88,360 114,544
89,785 116,317
91,154 117,986
97,258 125,047
102,193 130,398
102,368 130,584
110,539 139,086
116,926 145,622
122,168 150,964
126,613 155,492
130,474 159,435
133,890 162,938
136,956 166,102
И°(Т)-Н°@)
кДж • моль"
0,208
0,416
0,624
0,831
1,040
1,251
1,469
1,699
1,943
2,204
2,483
2,777
3,084
3,402
3,726
4,054
4,384
4,713
5,041
5,366
6,947
8,409
8,465
11,419
14,348
17,278
20,216
23,168
26,143
29,147
309

Таблица Д. 3
ВОДАН2О (к, ж)
М= 18,0152
Ф°(Т) S°(T)
Н° (Т) -#° @)
ср(т>
Ф°(Т)
Н° (Т) -Н° @)
к
Дж • К 1 • моль
кДж • моль"
Дж • К х • моль
кДж • моль~
0
5
10
15
20
25
30*
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
I
0
0,02
0,27
1,00
1,98
3,11
4,10
5,15
6,12
7,03
7,90
9,61
11,26
12,82
14,38
15,83
17,22
18,49
19,71
20,82
21,95
23,14
24,37
25,61
26,84
28,12
О
3,408
3,424
3,483
3,586
3,739
3,959
4,202
4,497
5,118
5,121
5,791
6,508
7,235
7,985
8,745
9,510
10,280
11,049
11,816
12,579
13,340
14,095
14,847
15,593
16,336
3,408
3,420
3,484
3,716
.4,136
4,699
5,359
6,059
6,822
7,918
8,381
9,974
11,579
13,185
14,785
16,375
17,9.49
19,504
21,031
22,535
24,007
25,464
26,901
28,332
29,747
31,158
О
0,00006
0,0006
0,0035
0,011
0,024
0,042
0,065
0,093
0,126
0,163
0,251
0,355
0,476
0,612
0,763
0,928
1,107
1,298
1,501
1,714
1,940
2,177
2,427
2,689
2,964
210
220
230
240
250
260
270
273,16
273,16
280
290
298,15
300
320
340
360
380
400
420
440
460
480
500
520
540
560
580
600
29,49
30,82
32,11
33,41
34,71
36,03
37,36
37,78
75,99
75,74
75,45
75,30
75,28
75,23
75,47
75,90
76,43
77,03
77,72
78,58
79,71
81,32
83,63
86,95
91,64
98,14
106,91
118,53
17,075
17,812
18,543
19,275
20,001
20,786
21,447
21,675
21,675
22,715
24,227
25,432
25,708
28,655
31,535
34,335
37,070
39,729
42,320
44,843
47,301
49,700
52,041
54,333
56,579
58,784
60,919
63,111
32,560
33,966
35,361
36,759
38,146
39,536
40,917
41,354
63,356
65,233
67,886
69,950
70,416
75,271
79,838
84,163
88,281
92,216
95,991
99,625
103,142
106,567
109,930
113,271
116,636
120,Q80
123,629
127,480
3,252
3,554
3,868
4,196
4,536
4,891
5,257
5,376
11,386
11,905
12,661
13,273
13,412
14,917
16,423
17,938
19,460
20,995
22,542
24,104
25,687
27,296
28,944
30,648
32,431
34,326
36,372
38,622
310

Таблица Д. 4
ПЕРЕКИСЬ ВОДОРОДА
М =34,0146
(к, ж)
Ф°(Т)
SQ(TJ
Н°(Т)-И° @)
с°р<т>
Ф°(Т)
S°(T)
Н°(Т)-Н°@)
Дж К 1 моль
кДж моль
Дж • К 1 - моль
кДж • моль
-1
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
I
0,02
0,15
0,52
1,23
2,31
3,65
5,21
6,90
8,67
10,48
14,11
17,52
20,48
23,30
25,71
27,93
29,97
31,86
33,64
35,31
36,91
38,46
39,98
41,49
43,02
0,001
0,002
0,023
0,058
0,145
0,294
0,489
0,731
1,008
1,328
2,076
2,951
3,915
4,950
6,027
7,160
8,303
9,466
10,633
11,807
12,982
14,155
15,325
16,488
17,641
0,007
0,050
0,170
0,408
0,785
1,327
2,003
2,806
3,719
4,728
6,959
9,394
11,928
14,506
17,087
19,642
22,161
24,635
27,062
29,440
31,770
34,055
36,297
38,499
40,666
0,00003
0,00048
0,0022
0,007
0,016
0,031
0,053
0,083
0,122
0,170
0,293
0,451
0,641
0,860
1,106
1,373
1,663
1,972
2,300
2,645
3,006
3,383
3,775
4,182
4,605
210
220
230
240
250
260
270
272,74
272J4
280
290-
298,15
300
320
340
360
380
400
420
440
460
480
500
520
540
560
580
600
44,59
46,21
47,85
49,61
51,46
53,39
55,40
55,98
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
89,33
18,789
19,929
21,062
22,187
23,306
24,417
25,521
25,821
25,821
27,820
30,502
32,631
33,107
38,107
42,851
47,357
51,651
55,749
59,672
63,429
67,039
70,507
73,847
77,069
80,177
83,185
86,092
88,909
42,803
44,915
47,005
49,079
51,142
53,198
55,251
55,813
104,644
103,991
107,126
109,602
110,154
115,923
124,342
126,451
131,283
135,867
140,227
144,384
148,356
152,159
'155,807
159,311
162,683
165,933
169,068
172,097
5,043
5,497
5,967
6,454
6,959
7,483
8,027
8,180
20,680
21,328
22,221
22,949
23,114
24,901
26,687
28,474
30,260
32,047
33,833
35*620
37,406
39,193
40,980
42,766
44,553
46,339
48,126
49,913
311

Таблица Д. 5
Таблица Д. 6
ОРТОДЕЙТЕРИЙ o-D2 (г)
М = 4,028204
ПАРАДЕЙТЕРИЙ п-Т>2 (г)
М = 4,028204
с; т
Ф°т
Дж • К • моль
Н° (Т) -Н° @)
кДж • моль ~
10
20
30
40
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
250
298,15
300
400
500
600
700
800
900
1000
20,786
20,803
21,356
^3,492
26,815
29,962
32,027
32,895
32,897
32,435
31,808
31,189
30,657
30,234
29,915
29,682
29,518
29,404
29,326
29,275
29,19.3
29,196
29,196
29,243
29,368
29,621
30,011
30,505
31,061
31,640
49,663
64,071
72,507
78,544
83,354
87,455
91,098
94,401
97,427
100,214
102,789
105,177
107,397
109,469
111,409
113,231
114,948
116,571
118,109
119,571
125,949
131,004
131,182
139,468
145,918
151,204
155,688
159,588
163,047
166,160
70,449
84,858
93,359
9,754
105,343
110,522
115,312
119,657
123,538
126,983
130,045
132,786
135,261
137,517
139,591
141,514
143,308
144,992
146,579
148,082
154,603
159,744
159,925
168,330
174,866
180,241
184,835
188,874
192,498
195,801
0,208
0,416
0,626
0,848
1,099
1,384
1,695
2,021
2,350
2,677
2,998
3,313
3,622
3,927
4,227
4,525
4,821
5,116
5,409
5,702
7,163
8,569
8,623
11,545
14,474
17,422
20,403
23,428
26,506
29,641
т
к
10
20
30
40
50
. 60
70
80 ,
90
100
110
120
130
140
150
160
170
180
190
200
250
298,15
300
400
500
600
700
800
900
1000
Ср<Т
20,786
20,786
20,788
20,836
21,057
21,570
22,371
23,365
24,420
25,427
26,315
27,051
27,634
¦28,078
28,407
28,644
28,812
28,929
29,010
29,065
29,169
29,193
29,194
29,243
29,368
29,621
30,011
30,505
31,061
31,640
)
Ф°(Т)
Дж • К ~* • моль
1 I
18,485
31,682
52,030
63,970
72,188
78,373
83,307
87,409
90,924
94,008
96,762
99,257
101,541
103,651
105,614
107,449
109,174
110,801
112,342
113,805
120,186
125,241
125,419
133,705
140,155
145,441
149,925
153,825
157,284
160,397
-1
73,820
88,228
96,656
102,641
107,309
111,189
114,571
117,621
120,434
123,060
125,526
127,849
130,038
132,103
134,052
135,893
137,635
139,286
140,852
142,341
148,842
153,982
154Д62
162,567
169,103
174,478
179,072
183,110
186,735
190,038
if (T) -Н° @)
кДж • моль
0,923
1,131
1,339
1,547
1,756
1,969
2,188
2,417
2,656
2,905
3,164
3,431
3,705
3,983
4,266
4,551
4,838
5,127
5,417
5,707
7,164
8,569
8,623
11,545
14,474
17,422
20,403
23,428
26,506
29,641
312

Таблица Д. 7
Таблица Д. 8
ОРТОТРИТИЙ о Т2 (г)
М = 6,032100
ПАРАТРИТИЙ п-Т2 (г)
И = 6,032100
Г
к
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
250
298,15
300
400
500
600
700
800
900
1000
с;т
Дж
i
20,786
20,788'
20,909
21,543
22,802
24,356
25,824
26,995
27,827
28,371
28,706
28,904
29,017
29,080
29,115
29,135
29,147
29,154
29,159
29,163
29,178
29,199
29,200
29,316
29,609
30,098
30,721
31,404
32,089
32,742
Ф°(Т)
• К • мол!
10,140
48,513
64,930
74,918
81,999
87,485
91,984
95,821
9,180
102,177
104,887
107,363
109,643
111,757
113,728
115,574
117,310
118,949
120,500
121,973
128,393
133,474
133,653
141,973
148,447
153,757
158,270
162,205
165,702
168,857
S°(TJ
-1
>
78,856
93,264
101,706
107,791
112,724
117,018
120,885
124,414
127,645
130,607
133,328
135,835
138,154
140,307
142,314
144,194
145,961
147,627
149,203
150,699
157,208
162,349
162,530
170,943
177,512
182,951
187,636
191,783
195,521
198,936
Н°(Т)-Н°@)
к Дж • моль "*
0,687
0,895
1,103
1,315
1,536
1,772
2,023
2,287
2,562
2,843
3,129
3,417
3,706
3,997
4,288
4,579
4,871
5,162
5,454
5,745
7,204
8,609
8,663
11,588
14,532
17,516
20,556
23,662
26,837
30,079
10
20
30
40
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
250
298,15
300
400
500
600
700
800
.900
1000
Ф°(Т) S°(T)
Дж • К ~1 • моль
Н° (Т) -Я° @)\
кДж • моль
-1
20,786
21,335
25,001
29,869
32,556
32,908
32,158
31,217
30,449
29,920
29,589
29,393
29,282
29,222
29,190
29,174
29,167
29,164
29,164
29,165
29,178
29,199
29,200
29,316
29,609
30,097
30,721
31,403
32,089
32,742
39,802
54,217
62,767
69,153
74,475
79,107
83,201
86,848
90,119
93,076
95,768
98,235
100,512
102,625
104,595
106,441
108,176
109,815
111,366
112,839
119,259
124.340
124,518
132,839
13^,313
144,623
149,136
153,070
156,56В
159,723
60,587
75,066
84,297
92,180
99,185
105,17^
110,202
114,434
118,064
121,243
124,077
126,643
128,991
131,158
133,173
135,057
136,825
138,492
140,069
141,565
148,074
153,215
153,396
161,809
168,378
173,817
178,502
182,648
186,387
189,802
0,208
0,417
0,646
0,921
1,236
1,564
1,890
2,207
2,515
2317
3,114
3,409
3,702
3,995
4,287
4,579
4,870
5,162
5,454
5,745
7,204
•8,609
8,663
11,588
14,532
17,516
20,556
23,662
26,837
30,079
21 872
313

ДИФТОРИД ДИВОДОРОДА H2F2
М = 40.01260
Таблица Д. 9
(г)
ТРИФТОРИД
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
с°рт
Ф°(Т)
S°(T)
Дж • К 1 • моль"*1
П°(Т)-Н° @)
кДж • моль"
42.470
52.437
58.130
58.207
61.258
62.965
64.047
64.870
65.624
66.394
67.205
68.051
68.915
69.776
70.618
71.428
72.198
72.922
73.598
74.227
74.810
75.348
75.844
76.301
76.723
77.111
77.469
77.798
78.103
78.384
78.644
169.578
196.572
214.241
214.529
228.412
239.827
249.547
258.020
265.537
272.298
278.445
284.087
289.304
294.161
298.708
302.985
307.025
310.856
314.499
317.974
321.297
324.481
327.540
330.482
333.317
336.054
338.698
341.257
343.736
346.141
348.475
205.885
238.643
260.758
261.118
278.326
292.195
303.777
313.713
322.425
330.198
337.235
343.680
349.638
355.188
360.390
365.290
369.925
374.324
378.511
382.508
386.330
389.993
393.510
396.892
400.148
403.288
406.319
409.249
412.084
414.830
417.492
3.631
8.414
13.869
13.977
19.966
26.184
32.538
38.985
45.510
52.111
58.790
65.553
72.401
79.336
86.356
93.458
100.640
107.896
115.223
122.614
130.067
137.575
145.135
152.742
160.394
168.086
175.815
183.578
191.374
199.198
207.050
ТРИВОДОРОДАН3Р3
М = 60.01890
Таблица Д. 10
(г)
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
Ф°(Т)
S (Т)
Дж • К 1 • моль
1
7
Я° (Т) -Я° @)
кДж • моль
41.595
60.173
73.881
74.098
83.828
90.529
95.396
99.247
102.518
105.411
108.011
110.354
112.463
114.353
116.042
117.549
118.892
120.089
121.157
122.111
122.964
123.729
124.415
125.033
125.591
126.096
126.553
126.968
127.347
127.692
128.008
184.111
210.885
229.660.
229.977
245.730
259.387
271.519
282.461
292.444
301.635
310.160
318.119
325.587
332.629
339.293
345.621
351.648
357.404
362.912
368.196
373.272
378.157
382.867
387.413
391.806
396.058
400.176
404.170
408.046
411.812
415.474
219.365
254.122
280.851
281.308
304.046
323.515
34Q.471
355.476
368.946
381.192
392.435
402.841
412.535
421.613
430.151
438.209
445.839
453.083
459.978
466.555
472.841
478.859
484.631
490.175
495.509
500.646
505.600
510.385
515.009
519.484
523.818
3.525
8.647
15.263
15.399
23.326
32.064
41.371
51.110
61.202
71.601
82.274
93.195
104.337
115.680
127.201
138.882
150.705
162.656
174.719
186.883
199.138
211.473
223.881
236.354
248.886
261.470
274.103
286.780
299.496
312.248
325.033
314

Таблица Д. 11
ТЕТРАФТОРИД ТЕТРАВОДОРОДА H4F4 (г)
М =80.02520
Таблица Д. 12
ПЕНТАФТОРЙД ПЕНТАВОДОРОДА HgF5 (г)
М =100.03150
S°(T)
Дж-К моль
Н°(Т)-Н°@)
кДж • моль
-1
100
200
298.15
300
400
500
600
700
800
900
10,00
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
60.720
85.703
104.019
104.308
117.296
126.237
132.730
137.866
142.229
146.087
149.554
152.680
155.491
158.011
160.264
162.274
164.065
165.661
167.085
168.357
169.494
170.514
171.429
172.254
172.997
173.670
174.280
174.834
175.338
175.799
176.220
212.661
250.516
277.190
277.640
299.946
319.217
336.285
351.645
365.633
378.490
390.402
401.509
411.923
421.732
431.008
439.812
448.191
456.187
463.838
471.171
478.214
484.990
491.520
497.820
503.908
509.797
515.500
521.029
526.394
531.606
536.672
261.906
311.984
349.816
350.460
382.364
409.558
433.175
454.034
472.735
489.714
505.288
519.691
533.099
545.646
557.440
568.567
579.098
589.093
598.603
607.672
616.337
624.632
632.586
640.224
647.572
654.647
661.471
668.059
674.426
680.588
686.555
4.925
12.294
21.653
21.846
32.967
45.170
58.134
71.672
85.681
100.101
. 114.886
130.000
145.411
161.089
177.005
193.133
209.452
225.940
242.579
259.352
276.245
293.247
310.345
327.529
344.793
362.127
379.525
396.981
414.490
432.047
449.648
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
Ф (Т) \ S (Т)
Дж-К моль
Н°(Т)-Н° @)
кДж • моль "
79.845
111.232
134.157
134.518
150.763
161.944
170.064
176.485
181.940
186.763
191.098
195.005
198.520
201.670
204.486
206.998
209.237
211.233
213.013
214.603
216.024
217.299
218.443
219.474
220.404
221.244
222.007
222.699
223.330
223.906
224.432
239.633
288.567
323.142
323.725
352.585
377.469
399.473
419.251
437.243
453.768
469.066
483.321
496.680
509.256
521.145
532.424
543.155
553.393
563.184
572.568
581.578
590.245
598.594
606.649
614.431
621.957
629.245
636.309
643.164
649.821
656.291
302.870
368.268
417.203
418.034
459.105
494.022
524.300
551.013
574.944
596.657
616.563
634.963
652.084
668.101
683.151
697.347
710.779
723.525
735.650
747.210
758.255
768.826
778.962
788.695
798.056
807.070
815.763
824.155
832.265
840.112
847.712
6.324
15.940
28.044
28.293
42.608
58.277
74.896
92.234
110.161
128.601
147.497
166.806
186.485
206.498
226.808
247.385
268.199
289.224
310.438
331.820,
353.353
375.020
396.808
418.705
440.700
462.783
484.946
507.182
529.484
551.846
574.264
315

Таблица Д. 13
ГЕКСАФТОРИД ГЕКСАВОДОРОДА H6F6 (г)
М = 120.03780
Таблица Д. 14
ГЕПТАФТОРИД ГЕПТАВОДОРОДА H?F7 (г)
М =140.04410
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
с;т
Ф°(Т)
&Г (Г)
Дж • К " • моль "*1
(Т) ~Н° @)
кДж • моль"
98.601
135.927
163.730
164.168
183.823
197.327
207.102
214.802
221.321
227.079
232.254
236.923
241.131
244.909
248.292
251.316
254.016
256.425
258.577
260.501
262.224
263.770
265.159
266.411
•267.541
268.564
269.492
270.336
271.104
271.806
272.449
268.864
328.973
371.341
372.054
407.362
437.776
464.650
488.790
510.740
530.891
549.538
566.909
583.181
598.497
612.971
626.698
639.757
652.215
664.126
675.540
686.498
697.037
707.189
716.983
726.443
735.592
744.451
753.037
761.368
769.459
777.322
346.566
426.736
486.496
487.510
537.609
580.169
617.051
649.574
678.692
705.099
729.296
751.656
772.454
791.907
810.183
827.418
843.726
859.199
873.918
887.951
901.358
914.190
926.493
938.308
949.670
960.613
971.165
981.352
991.197
1000.723
1009.948
7.770
19.553
34.333
34.637
52.099
71.196
91.441
112.548
134.362
156.788
179.759
203.221
227.128
251.433
276.096
301.080
326.349
351.873
377.625
403.581
429.719
456.020
482.468
509.047
535.746
562.552
589.456
616.447
643.520
670.666
697.879
Ф°(Т)
S°(T)
Дж
К '¦ моль
if (Г)-It @)
кДж • моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
15Q0
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
118.095
162.290
194.432
194.939
217.698
233.36С
244.732
253.724
261.361
268.116
274.185
279.656
284.577
288.988
292.930
296.447
299.582
302.376
304.869
307.094
309.085
310.869
312.472
313.914
315.216
316.393
317.460
318.430
319.313
320.119
320.857
290.012
361.106
411.482
412.330
454.296
490.406
522.285
550.897
576.898
600.757
622.827
643.380
662.628
680.741
697.855
714.083
729.518
744.239
758.313
771.797
784.742
797.189
809.178
820.743
831.912
842.714
853.171
863.306
873.138
882.686
891.965
381.231
477.271
548.412
549.617
609.021
659.385
702.985
741.408
775.798
806.979
835.548
861.942
886.490
909.445
931.009
951.341
970.576
988.823
1006.178
1022.723
1038.526
1053.650
1068.150
1082.072
1095.460
1108.352
1120.782
1132.782
1144.378
1155.598
1166.463
9.122
23.233
40.826
41.186
61.890
84.489
108.420
133.357
159.120
185.600
212.721
240.418
268.633
297.316
326.416
355.888
385.692
415.793
446.157
476.758
507.568
538.568
569.736
601.057
632.515
664.096
695.789
727.585
759.473
791.445
823.494
316

Таблица Д. 15
ДИБРОМ Вг2 (к, ж)
М =159,808
Таблица Д. 16
ДИИОД 12 (к, ж)
М = 253,8090
т
к
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
265,9
265,9
270
280
290
298,15
300
320
340
360
380
400
420
440
460
480
500
0,33
2,56
7,22
12,72
18,03
22,44
26,05
28,99
31,38
33,34
36,33
38,61
40,51
42,15
43,60
44,89
46,07
47,17
48,20
49,18
50,13
51,05
51,95
52,85
53,77
54,71
55,71
56,78
57,94'
59,23
60,69
61,64
77,74
77,35
76,57
76,00
75,68
75,63
75,86
76,07
76,69
77,71
79,13
80,95
83,17
85,79
88,81
92,24.
;
Ф°(Т)
Дж • К • моль
1
0,0282
0,223
0,717
1,548
2,677
4,028
5,526
7,114
8,751
10,410
13,721
16,952
20,066
23,050
25,907
28,644
31,264
33,777
36,191
38,511
40,747
42,904
44,988
47,005
48,959
50,855
52,696
54,488
56,233
57,935
59,597
60,561
60,560
61,828
64,837
67,733
69,970
70,522
75,813
80,760
85,407
89,789
93,937
97,879
101,637
105,234
108,686
112,010
S°(T) ¦
-1
0,111
0,879
2,728
5,543
8,955
12,641
16,379
20,055
23,612
27,023
33,381
39,161
44,445
49,315
53,833
58,053
62,014
65,747
69,283
72,644
75,850
78,917
81,862
84,696
87,431
90,077
92,645
95,144
97,584
99,976
102,329
103,700
143,461
144,648
147,447
150,125
152,210
152,695
157,595
162,198
166,561
170,733
174,753
178,656
182,471
186,225
189,938
193,632
Я° (Т) -Н° @)
кДж • моль!
0,004
0,0066
0,030
0,080
0,157
0,258
0,380
0,518
0,669
0,831
1,180
1,555
1,950
2,364
2,793
3,235
3,690
4,156
4,633
5,120
5,616
6,122
6,637
7,161
7,694
8,237
8,789
9,351
9,924
10,510
11,110
11,471
22,043
22,361
23,131
23,894
24,520
24,652
26,170
27,689
29,216
30,759
32,327
33,927
35,567
37,256
39,000
40,811
Т
К
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
298,15
300
320
340
360
380
386,75
386,75
400
420
440
460
480
500
0,58
4,03
10,25
16,18
21,51
25,76
28,91
31,62
33,93
35,86
39,09
41,65
43,32
' 44,74
45,65
46,86
47,73
48v,48
49,02
49,59
50,07
50,49
50,87
51,23
51,57
52,05
52,46
52,79
53,05
53,25
53,42
53,61
53,86
54,15
54,44
54,51
55,70
56,95
58,79
60,81
61,53
79,56
79,56
79,56
79,56
79,56
79,56
79,56
п
Ф°(Т)
Дж • К • моль
1 I
0,048
0,377
1,159
2,385
3,925
5,665
7,519
9,297
11,343
13,259
17,012
20,627
24,079
27,368
30,497
33,476
36,313
39,020
41,602
44,078
46,451
48,727
50,919
53,024
55,057
57,015
58,911
60,743
62,522
64,245
65,915
67,542
69,120
70,655
71,879
72,153
75,036
77,783
80,411
82,934
83,764
83,764
86,716
90,977
95,022
98,872
102,546
106,059
-1
0,192
1,464
4,226
8,000
12,201
16,518
20,732
24,773
28,635
32,317
39,146
45,380
51,053
56,237
61,007
65,421
69,538
73,387
77,002
80,400
83,617
86,663
89,563
92,324
94,960
97,487
99,910
102,249
104,504
106,671
108,763
110,784
112,738
114,629
116,139
116,474
120,022
123,425
126,731
129,963
131,040
171,544
174,224
178,105
181,806
185,342
188,728
191,976
Н°(Т)-Н° @)
кДж • моль -1
0,0007
0,011
0,046
0,112
0,207
0,326
0,462
0,619
0,778
0,953
1,328
1,733
2,158
2,598
3,051
3,514
3,987
4,468
4,956
5,448
5,947
6,449
6,956
7,467
7,981
8,499
9,020
9,546
10,076
10,606
11,141
11,675
12,213
12,752
13,196
13,296
14,396
15,518
16,675
17,871
18,284
33,949
35,003
36,594
38,185
39,776
41,367
42,958
317

Таблица Д. 16
(окончание)
Таблица Д. 17
Ф (Т)
s°m
Дж -К моль
Н°(Т)-Н°@)
кДж • моль"
520
540
560
580
600
620
640
660
680
700
720
740
760
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
79,56
109,424
112,653
115,756
118,744
121,624
124,403
127,090
129,688
132,205
134,645
137,012
139,311
141,546
195,096
198,098
200,992
203,783
206,480
209,089
211,615
214,063
216,438
218,744
220,985
223,165
225,286
44,549
46,141
47,732
49,323
50,914
52,505
54,096
55,687
57,278
58,869
60,460
62,052
63,643
К
100
200
298,15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
ДИКСЕНОНХе2 (г)
М =262.60
S°(T)
Дж -К" • моль
I
Н° (Т) -if @)
кДж • моль "
27,918
22,741
21,682
21,671
21,288
21,109
21,011
20,952
20,913
20,887
20,868.
20,854
20,843
20,835
20,828
20,822
20,818
20,814
20,811
20,809
20,807
213,066
235,373
246,675
246,843
254,426
260,053
264,514
268,202
271,344
274,079
276,500
278,670
280,637
282,436
284,091
285,626
287,055
288,393
289,650
290,836
291,958
247,627
264,957
273,799
273,932
280,107
284,836
288,675
291,909
294,704
297,166
299,365
301,353
303,167
304,836
306,379
307,816
309,160
310,422
311,611
312,736
313,804
3,456
5,917
8,087
8,127
10,272
12,391
14,497
16,595
18,688
20,778
22,865
24,951
27,036
29,120
31,203
33,286
35,368
37,449
39,531
41,612
43,692
318

Таблица Д. 18
ФТОРИД КСЕНОНА XeF (г)
М =150.298
ДИФТОРИД КСЕНОНА XeF
М =169,297
Таблица Д. 19
(к, ж)
К
100
200
298,15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
Ф°(Т)
Дж • К • моль
-Я° @)
кДж • моль"
33,703
37,922
36,831
36,777
33,386
30,355
28,127
26,541
25,399
24,559
23,926
23,438
23,055
22,748
22,500
22,296
22,126
21,983
21,862
21,758
21,668
183,123
205,205
218,853
219,069
229,122
236,851
243,027
248,114
252,406
256,098
259,326
262,185
264,746
267,060
269,169
271,104
272,891
274,548
276,093
277,540
278,899
213,627
238,586
253,668
253,896
264,021
271,130
276,456
280,666
284,132
287,072
289,625
291,882
293,904
295,737
297,413
298,959
300,392
301,729
302,982
304,161
305,275
3,050
6,676
10,380
10,448
13,959
17,140
20,058
22,787
25,381
27,877
30,299
32,666
34,990
37,280
39,542
41.781
44,002
46,207
48,400
50,580
52,752
т
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
298,15
300
320
340
36.0
380
400
402,18
402,18
420
440
460
480
500
520
540
560
580
600
Дж-
J
0,183
1,672
5,16
9,56
13,89
17,98
21,59
24,76
27,57
30,11
34,58
38,41
41,69
44,54
47,08
49,41
51,59
53,63
55,63
57,31
58,97
60,53
62,01
63,40
64,72
65,99
67,20
68,37
69,51
70,61
71,67
72,68
73,69
74,72
75,60
75,80
78,01
80,21
82,41
84,61
86,82
87,06
100,00
100,00
100,00
100,00
100,00
100,00
100,00
100,00
100,00
100,00
100,00
Ф°(Т)
К • моль
0,015
0,131
0,456
1,043
1,868
2,879
4,028
5,275
6,587
7,944
10,726
13,537
16,330
19,082
21,779
24,414
26,984
29,489
31,931
34,313
36,635
38,901
41,113
43,274
45,385
47,449
49,469
51,446
53,382
55,277
57,139
58,963
60,751
62,510
63,918
64,235
67,599
70,854
74,010
77,073
80,054
80,375
80,375
84,742
89,427
93,901
98,184
102,291
106,236
110,031
113,688
117,216
120,623
S°(T)
-1
0,061
0,541
1,818
3,901
6,503
9,404
12,453
15,547
18,629
21,667
27,563
33,189
38,537
43,616
48,443
53,041
57,435
61,646
65,<?90
69,583
73,335
76,957
80,459
83,849
87,136
90,324
93,422
96,435
99,369
102,229
105,020
107,744
110,405
113,010
115,090
115,558
120,521
125,316
129,963
134,478
138,874
139,346
181,118
185,454
190,106
194,551
198,8С7
202,889
206,811
210,585
214,222
217,731
221,121
Я° (Т) -Н° @)
кДж • моль ~*
0,00023
0,00410
0,0204
0,0572
0,116
0,196
0,295
0,-Wl
0,542
0,686
1,010
1,376
1,777
2,208
2,666
3,149
3,654
4,180
4,726
5,291
5,872
6,470
7,082
7,709
8,350
9,004
9,670
10,348
11,037
11,738
12,449
13,171
13,903
14,645
15,257
15,397
16,935
18,517
20,143
21,814
23,528
23,717
40,517
42,299
44,299
46,299
48,299
50,299
52,299
54,299
56,299
58,299
60,299
319

Таблица Д. 20
Таблица Д. 21
ТЕТРАФТОРИД КСЕНОНА XeF4 (к, ж)
М = 207,294
ГЕКСАФТОРИД КСЕНОНА XeF6 (к, ж)
М = 245,290
т
к
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140 .
150
160
170
180
190
200
210
220
230
240
250
260
270.
280
290
298,15
300
320
340
360
380
390,25
390,25
400
420
440
460
480
500
520
540
560
580
600
Ф°(Т)
S°(T)
Дж • К ~* • моль ~1
0,304
2,29
6,45
11,62
16,92
22,11
27,00
31,58
35,89
39,97
47,44
54,02
59,72
64,68
69,09
73,12
76,86
80,37
83,67
86,77
89,70
92,45
95,05
97,51
99,82
102,01
104,10
106,11
108,07
109,97
111,80
113,57
115,28
116,99
118,39
118,71
122,18
125,64
129,11
132,58
134,36.
170,00
170,00
170,00
170,00
170,00
170,00
170,00
170,00
170,00
170,00
170,00
170,00
0,025
0,201
0,646
1,400
2,429
3,676
5,092
6,635
8,274
9,983
13,545
17,218
20,936
24,658
28,353 •
32,005
35,603
39,140
42,613
46,022
49,368
52,649
55,865
59,024
62,126
65,164
68,153
71,085
73,965
76,792
79,576
82,310
84,997
87,639
89,757
90,236
95,324
100,260
105,063
109,735
112,084
112,084
115,318
121,781
128,027
134,065
139,907
145,567
151,05i
156372
161,537
166,556
171,437
0,101
0,797
2,445
5,002
8,165
11,712
15,492
19,400
23,372
27,366
35,327
43,146
50,741
58,069
65,116
71,893
78,417
84,709
90,787
96,666
102,362
107,884
113,243
118,450
123,511
128,435
133,230
137,902
142,461
146,912
151,261
155,514
159,676
163,746
167,000
167,733
175,505
183,016
190,296
197,370
200,922
242,690
246,885
255,179
263,088
270,645
277,880
284,820
291,487
297,903
304,085
310,051
315,814
Н° (Т) -Н° @)
кДж «моль
0,00038
0,00595
0,02698
0,07204
0,1434
0,2411
0,364
0,511
0,679
0,869
1,307
1,815
2,384
3,007
3,676
4,388
5,138
5,924
6,744
7,597
8,479
9,390
10,328
11,291
12,277
13,287
14,317
15,368
16,439
17,530
18,638
19,765
20,910
22,071
23,030
23,249
25,658
28,137
30,684
33,301
34,669
50,969
Sljbll
56,027
59,427
62,827
66,227
69,627
73,027
76,427
79,827
83,227
86,627
Т
К
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
110
120
130
.140
.150
160
170
180
190
200
201
220
230
240
250
253,8
253,8
260
270
280
290
298,15
300
320
322,63
322,63
340
360
380
400
420
440
460
480
500
Ср°(Т)
Дж •
1,26
5,54
10,73
15,87
20,69
25,20
29,45
33,49
37,37 •
41,15
48,63
55,90
62,94
69,74
76,27
82,54
88,55
94,28
99,75
104,97
109,93
114,67
119,19
123,51
127,67
131,69
135,60
139,45
143,26
147,09
148,55
147,83
150,49
154,79
159,08
163,38
171,59
172,24
179,28
180,21
324,80
413,31
479,56
515,11
525,95
516,66
490,83
451,27
400,21
339,46
Ф°(Т)
К моль
0,106
0,724
1,833
3,274
4,928
6,719
8,598
10,532
12,502
14,493
18,505
22,529
26,545
30,543
34,517
38,461
42,373
46,251
50,093
53,897
57,664
61,391
65,079
68,728
72,336
75,905
79,435
82,926
86,378
89,793
91,081
91,081
93,263
96,744
100,180
103,580
106,409
107,053
113,934
114,827
114,827
121,811
130,974
139,242
148,661
158,435
168,435
178,534
188,606
198,543
S°(T)
0,422
2,511
5,729
9,526
13,591
17,767
21,973
26,171
3Q,341
34,474
42,641
50,686
58,613
66,421
74,109
81,675
89,117
96,433
103,622
110,683
117,617
124,425
131,110
137,672
144,114
150,441
156,659
162,772
168,788
174,710
176,940
180,770
184,370
190,130
195,840
201,490
210,380
211,443
222,784
224,256
242,057
261,529
287,192
314,197
340,989
366,499
389,996
410,98*
429,15:
444,28S
И° (Т) -Н° @)
кДж • моль ~*
0,00158
0,0179
0,0584
0,1250
0,2166
0,3314
0,468
0,626
0,803
0,999
1,448
1,971
2,565
3,229
3,959
4,754
5,609
6,524
7,494
8,518-
9,593
10,716
11,885
13,099
14,355
15,652
16,988
18,364
19,777
21,229
21,791
22,763
23,687
25,214
26,783
28,395
30,999
31,317
34,832
35,305
41,048
47,505
56,491
66,483
76,931
87,387
> 97,487
\ 106,929
\ 115,462
) 122,873
320

НИТРАТ АММОНИЯ NH4N
М = 80,0432
(к, ж)
Таблица Д. 22
т
к
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
210
220
230
240
250
256,2
256,2
260
270
280
290
298,15
300
С; (Т)
Дж
0,07
0,55
1,83
4,21
7,57
11,53
15,77
20,07
24,06
27,95
35,61
42,38
48,74
54,60
59,87
64,41
68,78
73,62
78,45
82,92
87,28
91,67
96,06
100,51
105,02
109,58
114,18
118,82
123,47
128,13
131,04
123,47
125,10
129,07
132,84
136,33
139,08
139,65
Ф°(Т)
К моль
1
0,005 0,023
0,042 0,182
0,155 0,615
0,342 1,442
0,685 2,725
1,173 4,473
1,790 6,561
2,545 8,970
3,405 11,561
4,352 14,312
6,485 20,102
8,856 26,113
11,393 32,206
14,052 38,296
16,781 44,321
19,560 50,242
22,350 56,067
25,165 61,765
27,986 67,436
30,802 73,002
33,609 78,515
36,410 83,939
39,205 89,299
41,981 94,613
44,741 99,881
47,489 105,113
50,234 110,320
52,966 115,505
55,66J 120,650
58,369 125,785
60,051 128,970
60,051 130,820
61,087 132,641
63,825 137,436
66,541 142,198
69,231 146,921
71,447 150,810
71,969 151,672
Я° (Т) -Я° @) | Т
кДж • моль ~* 1 К
0,00009 305,38
0,0014 305,38
0,0069 320
0,022 340
0,051 357,25
0,099 357,25
0,167 360
0,257 380
0367 399
0,498 399
0,817 400
1,208
1,665 420
2,182 440
2,754 «2.8*
442,85
3,375 460
4,046 480
4,758 500
5,523 520
6,330 540
7,185 560
8,080 580
9,017 600
10,000
640
12,101 660
13,219 680
14,384 700
15,596 720
16,854 740
17,657 760
18,131 780
18,604 800
19,875
21 184
' 840
23>662 III
"*" III
Дж
141,27
119,36
122,22
126,12
129,48
147,31
147,33
148,79
153,42
159,50
159,70
162,30
164,90
165,27
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
161,00
Ф°(Т)
•К -моль
73,398
73,398
77,472
82,867
87,371
87,371
88,101
93,294
98,169
98,169
98,460
104,007
109,400
110,158
110,158
115,143
120,774
126,222
134,490
136,615
141,579
146398
151,081
155,635
160,068
164,383
168,587
172,689
176,689
180,595
184,409
188,135
191,779
195,343
198,831
202,247
205,592
208,869
S°(T)
-1
154,169
159,736
165,385
172,914
179,242
183,015
184,145
192,062
199,420
210,530
210,940
218,797
226,409
227,475
240,707
246,830
253,682
260,254
266,559
272,645
278,500
284,150
289,608
294,887
299,999
304,953
309,758
314,426
318,961
323,373
327,667
331,848
335,924
339,899
343,779
347,568
351,269
354,887
H°(T)-tf @)
кДж -моль
24,666
26,366
28,132
30,616
32,821
34,169
34,576
37,531
40,399
44,832
44,992
48,212
51,484
51,954
57,814
60,576
63,796
67,016
70,236
73,456
76,676
79,896
83,116
86,336
89,556
92,776
95,996
99,216
102,436
105,656
108,876
112,096
115,316
118,536
121,756
124,976
128,196
131,416
321

Таблица Д.
ФТОРИД АММОНИЯ NH4F (к, ж)
М = 37,03670
т
к
5
10
15
20
25
30
35
40
45
50
60
70
80
90
100
ПО
120
130
140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
298,15
300
сЦт)
Дж.-
0,049
0,393
1,35
2,88
4,66
6,44
8,12
9,69
11,33
12,91
16,10
19,31
22,48
25,56
28,46
31,23
33,89
36,40
38,84
41,16
43,35
45,40
47,40
49,20
50,96
52,68
54,31
55,86
57.36
58,83
60,25
61,63
62,97
64,27
65,27
65,59
Ф°(Т)
К~ • моль
0,004
0,049
0,140
0,259
0,485
0,788
1,176
1,591
2,048
2,541
3,619
4,772
5,981
7,237
8,535
9,849
11,173
12,510
13,860
15,215
16,569
17,924
19,277
20,626
21,974
23,312
24,642
25,962
27,275
28,579
29,874
31,160
32,435
33,700
34,714
34,945
S°(T)
-i
0,016
0,149
0,473
1,059
1,885
2,888
4,005
5,191
6,426
7,701
10,336
13,058
15,844
18,670
21,515
24,358
27Д90
30,002
32,789
35,548
38,275
40,965
43,616
46,226
48,794
51,322
53,810
56,258
58,667
61,039
,63,374
65,675
67,942
70,176
71,970
72,375
Н° (Т) -Н° @)
кДж • моль
0,00006
0,0012
0,0056
0,0162
0,035
0,063
0,099
0,144
0,197
0,258
0,403
0,580
0,789
1,029
1,298
1,596
1,922
2,274
2,650
3,050
3,473
3,917
4,381
4,864
5,364
5,882
6,417
6,968
7,534
8,115
8,710
9,319
9,942
10,578
11,108
11,229
т
К
320
340
360
380
400
420
440
460
480
500
511
511
520
540
560
580
600
620
640
660
680
700
720
740
760
с°рт
Дж
69,10
72,61
76,11
79,62
83,12
86,63
90,14
93,64
97,15
100,68
102,58
113,00
113,00
113,00
113,00
113,00
113,00
113,00
113,00
1В,00
113,00
113,00
113,00
113,00
113,00
Ф° (Т)
• К • моль
37,420
39,858
42,264
44,636
46,983
49,305
51,602
53,877
56,133
58,369
59,592
59,592
61,019
64,131
67,172
70,141
73,043
75,878
78,651
81,363
84,016
86,611
89,153
91,642
94,081
S°(T)
-1
76,720
81,014
85,264
89,473
93,646
97,786
101,897
105,981
110,041
114,077
116,289
140,947
142,921
147,185
151,295
155,260
159,091
162,796
166,384
169,861
173,235
176,510
179,693
182,789
185,803
Н° (Т) -Н° @)
кДж • моль
12,576
13,993
15,480
17,038
18,665
20,362
22,130
23,968
25,876-
27,854
28,972
41,572
42,589
44,849
47,109
49,369
51,629
53,889
56,149
58,409
60,669
62,929
65,189
67,449
69,709
322

ФОСФОР Р (к, белый; ж)
М = 30,97376
Таблица Д. 24
т
к
5
10
15
20
25
30
35
40
45
50,
60
70
80
90
100
ПО •
120
130
140
150
160
170
180
190
195,4
195,4
200
210
220
230
240
250
260
270
280
290
298,15
300
Ф°(Т)
S°(T)
Дж • К • моль
I I
0,108 0,008 0,0344
1,122 0,079 0,344
3,000 . 0,293 1,130
4,694 0,633 2,223
6,309 1,071 3,446
7,611 1,573 4,715
8,615 2,112 5,966
9,393 2,670 7,169
10,000 3,234 8,312
10,498 3,797 9,392
11,255 4,898 11,377
11,883 5,954 13,161
12,468 6,959 14,787
13,075 7,914 16,291
13.728 8,823 17,702
14,410 9,692 19,043
15,121 10,525 20,327
15,845 11,327 21,566
16,564 12,103 22,768
17,309 12,853 23,937
18,100 13,582 25,079
18,916 14,292 26,201
19,769 14,984 27,307
20,698 15,661 28,400
21,117 16,022 28,986
20,920 16,019 31,652
21,092 16,385 32,141
21,393 17,160 33,177
21,694 17,911 34,180
21,987 18,640 35,151
22,280 19,348 36,093
22,564 20,036 37,008
22,840 20,706 37,899
23,108 21,359 38,766
23,372 21,996 39,611
23,627 22,618 40,436
23,824 '23,112 41,090
23,849 23,224 41,237
Н°(Т)-Н° @)
кДж -моль"
0,0001
0,003
0,013
0,032
0,059
0,094
0,135
0,180
0,229
0,280
0,389
0,504
0,626
0,754
0,888
1,029
1,176
1,331
1,493
1,663
1,840
2,025
2,218
2,420
2,533
3,054
3,151
3,364
3,579
3,798
4,019
4,243
4,470
4,700 .
4,932
5,167
5,360
5,404
Г
К
317,3
317,3
320
340
360
380
400
420
440
460
480
500
520
540
560
580
600
620
640
660
680
700
720
740
760
780
800
820
840
860
880
900
24,267
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
62,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
26,117
Ф°(Т)
S°(T)
:-К~1 -моль
24,243 42,586
24,243 44,662
24,416 44,883
25,667 46,466
26,864 47,959
28,012 49,371
29,114 50,711
30,173 51,985
31,192 53,200
32,174 54,361
33,122 55,472
34,038 56,539
34,923 57,563
35,780 58,548
36,610 59,498
37,415 60,415
38,197 61,300
38,956 62,157
39,694 62,986
40,412 63,789
41,111 64,569
41,792 65,326
42,456 66,062
43,104 . 66,777
43,736 67,474
44,353 68,152
44,957 68,813
45,546 69,458
46,123 70,088
46,688 70,702
47,240 71,302
47,782 71,889
Я° (Т) -Н° @)
кДж • моль ~*
. 5,820
6,479
6,549
7,072
7,594
8,116
8,639
9,161
9,683
10,206
10,728
11,250
11,773
12,295
12,817
13,340
13,862
14,384
14,907
15,429
15,951
16,474
16,996
17,518
18,041
18,563
19,085
19,608
20,130
20,652
21,175
21,697
-
323

КОНСТАНТЫ АППРОКСИМАЦИОННОГО УРАВНЕНИЯ
В*= ЪЪкТ~к+ А G);
Вещество
Температурный
интервал, К
0 -i
• моль
о2
О3
112
Н2О
Н2О2
°2 а
D2Od
D2O2
HD,T2,HT,DT
Г2
F2O
HF
Cl2
C12O
HC1
C1F§
C1F5
Br2
HBr
HI
Hcr
No
Ar
Kr
Xe
SB
so2
so3
H2S
N26
NO
N2O
^ 2NO + 6*
NH3
N2H4
NI3
N2F4
FNO
FNO2
F3NO
NHF2
pB
PF3
PCl3
PF2C1
PFC12
300-2000
400-3000
100-3000
600-3000
273,15-2000
98-400
273,15-1000
700-2000
30-150
300-3000
200-500
600-3000
300-3000
400-1000
300-3000
300-5000
400-1000
300-3000
300-3000
800-3000
300-3000
20-1500
100-1300
100-4500
100-6000
150-8500
800-1300
200-2000
300-1800
370-1800
250-1000
100-1000
190-10000
380-6000
154,576
205
33,19
288,1
708,5
38,34
643,89
717
6
144,31
215,2
461
417,15
465
324,69
160
416
584,15
363,15
819,15
423,85
5,1994
122,1
407,76
567,5
791
1313
455
490,85
926
318,7
126,2
100
189
270-580
300-3000
273,15-1500
200-600
250-700
200-650
300-750
300-850
300-850
.. 250-750
350-1000
700-1400
270-700
550-1100
360-900
4504100
431,35
100
653,15
233,9
272,15
260,15
309,35
348,15
349,5
302,65
403,15
993,8
271,1
563,15
362,32
462,99
0,0734
0,08095
0,06695
0,034108
0,0975
0,05771
0,0561
0,426
б
0,0662
0,361
0,069
0,124
0,588
0,0858
0,1644
0,656
0,127
0,0921
0,155
0,129
0,057614
0,0121
0,0214
0,0261
0,0338
0,600
0,03029
0,497
0,0627
0,2001
0,08947
0,058
0,122
1,817Д
0,07246
0,1389
0,1238
0,391
0,388
0,693
0,363
0,312
0,391
0,356
0,7948
0,521
0,264
0,666
0,771
0,208313519
0,471587
0,2722749616
0,574253225
0,616501
0,3675120519
0,7808913
0,225625
0,1445
0,442803456
0,225625
-0,465753462
0,443272980
0,225625
0,269193240
0,471587
0,225625
0,4571716
0,395997695
0,51798660
0,413521772
0,3035636
1,211472
1,211472
1,211472
1.211472
0,3452
0,6813145
0,18173
0,8523447
0,646394020
0,397*526
ЧУ,4120689
0,471587
-0,7109383
0,091954181
0,5403462
0,743977
0,225625
0,225625
0,225625
0,225625
0,225625
0,225625
0,225625
0,3452
0,225625
0,333
0,225625
0,225625
5,17156941
3,43482
-0,0822834993
-0,239414617
-1,78661
-0,9800981848
-1,7649164
-0,5625
-0,33
2,55504241
-0,5625
20,6854316
-0,227362066
-0,5625
1,69613468
3,43482
-0,5625
-1,3938259
0,352705728
-2,7091160
-0,191545910
-1,335531
-0,1767558
-0,1767558
-"О7Г7ТГ7358"
-0,1767558
-0,73193
-1,785659
-0,0954
-0,709039
-1,508668435
-0.2705628
3,6603448
3,43482
0,7039724
3,1508418
-1,1439025
-1,77164
-0,5625
-0,5625
-0,5625
-0,5625
-0,5625
-0,5625
-0,5625
-0,73193
-0,5625
-1,125
-0,5625
-0,5625
-62,8503584
-66,3288
-4,697369688
-20,0452252 .
0,1969006249
-0,1385
-33,5268703
-165,619309
-5,53699943 -
-19,9226234
-66,3288
1,4773251
-10,9225107
23,1947099
-4,42415747
-0,0101968
-1,495367
-1,495367
-T,495367~
-1,495367
-3,701418
-0,3935
-0,139042
0,485155693
-2.956163
-64,35862
-66,3288
2,1763918
-93,143803
Для D2О функция А (Г) = -0,48951 347~4'82
Параметры приведения Го, VQ для изотопов водорода зависят от температуры (см. раздел П3.4)
Для паров GF3, серы, четырехокиси азота и фосфора в таблице приведены данные для "физической" части второго вириального
коэффициента, учитывающей отклонения от свойств идеальной реагирующей смеси (см. раздел П3.5) .
Для Не функция А G) = -0,2823762* + 0,0810073Jf2 - 4,1242084Х6, где X = Г/A00 + 1,8 7 )
324

ДЛЯ ВТОРОГО ВИРИАЛЬНОГО КОЭФФИЦИЕНТА
В*= B/Vo; T=T/TQ
- *э
333,871478
476,748
7,747196685
46,1789884
-0,9218444623
-0,0121
149,457156
631,851059
19,2584102
70,3694151
476,748
-1,3546612
44,7579241
-130,606345
7,46458205
-0,00006945
0,5705028
0,5705028
0,5705028
0,5705028
2,812570 '
-0,06157
-0,0042637
- 1,080174055
3,066081
327,1862
476,748
-2,8956604
618,61716
*4
-1016,34265
-2224,88
-123,286999
-390,595370
-1318,63692
-51,3522749
-114,655053
-2224,88
-7,2183575
-108,848744
351,443978
1,04962311
-0,1183557
-0,1183557
-0,1183557
-0,1183557
-4,870347
0,2601538455
-1,877000
-2224,88
-2302,1253
1748,15769
6573,78
-9,735481969
159,057637
0,2059216454
571,524075
1493,57992
85,5976102
15,8136970
6573,78
17,030784
142,753983
'-494,898818
-28,5665701
0,008502477
0,008502477
0,008502477
0,008502477
4,223481
0,7416446
1260,3827
6573,78
2735,8542
-1570,13970
-11865,6
-116,536243
-0,4631916249
-419,342633
-857,888657
-83,1675096
192,380089
-11865,6
-15,259323
-93,8129182
344,013074
45,5647594
-2,859176
-0,3944179
-693,32241
-11865,6
- -
565,724301
11917,5
0,001566483057
108,527388
193,146456
42,5724956
-228,281099
11917,5
6,2989558
24,1876681
-92,1216299
-29,2561165
1,024578
0,1301370
11917,5
-
Таблица Д.25
-5096,57
—
-8,80620651
80,8738351
-5096,57
-0,9952138
6,84818951
-0,1818336
-0,003723
-5096,57
-
д Значение В{Т) и Ко для четырехокиси азота даны в дм • кг"
е Для N2H4 функция А (Г) = -8,0435058 • | е"'475 Т
А А
Для NF3 фнукция А (Г) =-27,9731-А «Г5'475Г/
325

Таблица Д. 26
КРИТИЧЕСКИЕ ПОСТОЯННЫЕ
Вещество
°2
о3
х-Н2
л-Н
н2о
Н2°2
2
D2O
D2°2
HD
Т2
нт
DT
F2
F2°
HF
ci2
ci2o
HCl
C1F3
C1F5
Br2
HBr
I2
HI
He
Ne
Гкр
К
154,576
261
33,19
32,976
647,13
708,5
38,34
38,262
643,89
717
35,908
40,44
37,13
39,42
144,31
215,2
461,15
417,15
465
324,69
447,15
415,75
584,15
363,15
819,15
423,85
5,1900в
44,4
* Модификация, содержащая
Ркр
МПа
5,043
5,573
1,315
1,293
22,06
15,54
1,665
1,650
21,66
14
1,484
1,850
1,571
1,773
5,215
4,95
6,49
7,70
6,576
8,306
5,78
5,26
10,34
8,552
—
8,31
0,22746
2,654
укр | всщст
дм3- моль"
0,0734 Аг
0,089 Кг
0,06695 Хе
0,06414 S
0,05591 SO2
0,0975 SO3
0,05771 H2S
0,0603 SF6
0,0561 N2
NO
0,0628 N2O
0,0553 N2O4
NH3
0,0578 N2H4
0,0662 NF3
0,0976 uuc-N2F2
0,0696 TpaHC-N2F4
0,124 N2F4
0,167 FNO
0,0858 FNO2
F3NO
0,231 NHF2
0,127 P
PF3
0,155 PC13
pf2q
0,057474 PFC12
0,0417
97,8% O-D. и2,2%И-Ц,.
Гкр
К
150,725
209,286
289,734
1313
430,65
490,85
373,15
318,687
126,2
180,15
309,584
431,35
405,4
653,15
233,90
272,15
260,15
309,35
348,15
349,5
302,65
403,15
993,8
271,1
563,15
362,3
463
Ркр
МПа
4,865
5,4931
5,8400
18,21
7,884
8,207
8,94
3,7605
3,4
6,48
7,2545
10,128
11,333
14,7
0,531
5,78
$,57
3,708
7,98
9^23
6,43
9,42
10,396
4,326
-
4,52
4,995
Ккр
дм3 • моль
0,07467
0,09229
0,11829
0,158г
0,122
0,1271
0,0985
0,2001
0,08947
0,0580
0,0973
0,167д
0,07246
0,139
0,1238
0,118
0,113
0,181
0,0823
0,108
0,147
0,215г
-
0,264
-
-
Мольный объем фтористого водорода*определен как произведение удельного объема на молекулярный вес HF
|В Значение Тк
п соответствует температурной шкале [399J.
|Г Мольный объем паров серы и фосфора определен как произведение удельного объема на мольный вес соответствующей
смеси полимеров.
д Мольный объем четырехокиси азота определен как произведение удельного объема на молекулярный вес
326

СОДЕРЖАНИЕ
ВВЕДЕНИЕ 5
УКАЗАТЕЛЬ ТАБЛИЦ 6
ТАБЛИЦЫ ТЕРМОДИНАМИЧЕСКИХ СВОЙСТВ 9
ДОПОЛНЕНИЕ '. 309

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
Том I
Книга 2
Утверждено к печати
Институтом высоких температур
Академии наук СССР
Редактор издательства В.П. Сироткина
Художник В.Г. Виноградов
Художественный редактор Т.П. Поленова
Технический редактор НА. Посканная
Оригинал-макет издания подготовлен
с применением наборно-печатающей техники
В.В. Тарасовой и О.Г. Ивановой
по технологии, разработанной
В.И. Васильевым,
на основе таблиц, полученных фотонабором с ЭВМ
ИБ № 16102
Подписано к печати 01.11.78. Т - 17541
Формат 84 х 108 1/16. Бумага офсетная № 1
Усл. печл. 34,4. Уч.-издл. 53,6. Тираж 8000 экз.
Тип. зак. 872. Цена I т. (кн. 1 и 2) 7 р. 90 к.
Книга издана офсетным способом
Издательство "Наука", 117485, Москва, В-485,
Профсоюзная ул., 94а
Ордена Трудового Красного Знамени
1-я типография издательства "Наука", 199034, Ленинград,
В-34, 9-я линия, 12